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Research Methodology and Analysis of Innovative Pedagogical Models in Mechanical Engineering Courses for International Students at the School of Mechanical Engineering and Automation, Beihang University
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作者 Zhao Rui 《Contemporary Social Sciences》 2023年第5期141-155,共15页
Taking the engineering courses“Introduction to Mechanical Engineering”and“Machining Process”taught by the author at Beihang University’s International School as examples,this article systematically analyzed the c... Taking the engineering courses“Introduction to Mechanical Engineering”and“Machining Process”taught by the author at Beihang University’s International School as examples,this article systematically analyzed the current status and background of international student education,focused on research strategies for interdisciplinary education and industry-education integration innovation models from the perspectives of technical demands,student needs,and societal requirements.This article aims to cultivate highly qualified international students who come to China for their studies,help them better adapt to China’s social employment environment,and enhance their capabilities for career development in China.This article proposes a comprehensive set of innovative teaching models for mechanical engineering courses for international students at Beihang University,which encompasses eight key aspects,including talent development programs,curriculum outline reforms,optimization of classroom teaching content,respect for individual student characteristics,the establishment of practical teaching components,the use of open-ended assignments to stimulate enthusiasm for learning,the cultivation of international students’interest in China,their belief in developing friendships with China,and their goals of staying in China,and the incorporation of external experts to facilitate industry-education integration. 展开更多
关键词 international students mechanical courses teaching models strategies and practices
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Evaluation Principles,Standards and Operating Strategies of Ideological and Political Teaching in Science and Engineering Courses
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作者 Jie Shen 《Proceedings of Business and Economic Studies》 2020年第6期56-60,共5页
The reform of ideological and political education in science and engineering courses continues to deepen,and the establishment of a practical teaching evaluation system is the main goal.Combining the relevant requirem... The reform of ideological and political education in science and engineering courses continues to deepen,and the establishment of a practical teaching evaluation system is the main goal.Combining the relevant requirements of the ideological and political education in science and engineering courses,establishing a teaching evaluation system needs to follow the corresponding principles to ensure that the teaching content is reasonable and the teaching objectives are clear.The selected teaching method is flexible and effective,which facilitates the improvement of teaching quality and feedback of teaching situation.In this regard,the paper mainly analyzes the principles and standards of ideological and political teaching evaluation for science and engineering courses,and chooses reasonable and operable measures in-line with actual requirements to apply them in practice,and strive to serve as a reference for subsequent related research. 展开更多
关键词 Teaching evaluation Science and engineering courses Evaluation standard Ideological and political education
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Construction and Innovation of Comprehensive Evaluation Means of PBL+OBE-based Software Engineering Practical Courses
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作者 Yixian Liu Jun Guo Dongming Chen 《计算机教育》 2023年第12期106-113,共8页
Software engineering is an engineering discipline that guides software developers to carry out software development,software maintenance,and software management.The traditional evaluation methods of software engineeri... Software engineering is an engineering discipline that guides software developers to carry out software development,software maintenance,and software management.The traditional evaluation methods of software engineering courses do not highlight the training goal of outcomebased education(OBE).This paper systematically studies the evaluation methods for practical courses in software engineering from three aspects:course evaluation guidelines,course evaluation methods and course evaluation effects;establishes a comprehensive,scientific,and objective system of course evaluation;effectively measures students’learning effect;promotes teachers to continuously improve the teaching process;and thus improves the teaching quality of software engineering courses.Besides the general approach,this paper also takes software project construction practice as an example to demonstrate the effect of the proposed approach. 展开更多
关键词 Comprehensive evaluation PBL OBE Software engineering Practical coursess
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Teaching Reform Based on the Competency Model for Software Engineering-related Courses
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作者 Xue Han Buqing Cao +2 位作者 Jianyong Yu Miao Liao Wei Liang 《计算机教育》 2023年第12期158-166,共9页
This paper explores the reform and practice of software engineering-related courses based on the competency model of the Computing Curricula,and proposes some measures of teaching reform and talent cultivation in soft... This paper explores the reform and practice of software engineering-related courses based on the competency model of the Computing Curricula,and proposes some measures of teaching reform and talent cultivation in software engineering.The teaching reform emphasizes student-centered education,and focuses on the cultivation and enhancement of students’knowledge,skills,and dispositions.Based on the three elements of the competency model,specific measures of teaching reform are proposed for some professional courses in software engineering,to strengthen course relevance,improve knowledge systems,reform practical modes with a focus on skill development,and cultivate good dispositions through student-centered education.The teaching reform’s attempts and practice are conducted in some courses such as Advanced Web Technologies,Software Engineering,and Intelligent Terminal Systems and Application Development.Through the analysis and comparison of the implementation effects,significant improvements are observed in teaching effectiveness,students’mastery of knowledge and skills are noticeably improved,and the expected goals of the teaching reform are achieved. 展开更多
关键词 Competency model Software engineering Reform practice Computing Curricula
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College English Curriculum Reform in the Context of New Engineering Education:Taking Wuhan University of Technology as an Example
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作者 WANG Hai-yan SHE Ran-ran 《Journal of Literature and Art Studies》 2024年第4期302-305,共4页
With the introduction of“new engineering,new medical science,new agricultural science,and new liberal arts”construction,the reform of college English teaching is also imperative.Scholars nationwide have conducted at... With the introduction of“new engineering,new medical science,new agricultural science,and new liberal arts”construction,the reform of college English teaching is also imperative.Scholars nationwide have conducted attempts in different aspects of college English teaching and produced fruitful results.Yet,more efforts should be made.This paper discusses the reforms made by Wuhan University of Technology,focusing on the reformation of curriculum. 展开更多
关键词 new engineering construction CURRICULUM specialized purpose courses
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Reform and Reconstitution of Core Courses in Mechanical and Electronic Engineering Under the Background of New Engineering
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作者 Yali Yu Keyi Wang Yong Yang 《Journal of Contemporary Educational Research》 2023年第12期214-219,共6页
With the arrival of the intelligence era of Industry 4.0,social development has shown complex and diversified characteristics,gradually forming an innovation ecological environment constructed by vertical interaction ... With the arrival of the intelligence era of Industry 4.0,social development has shown complex and diversified characteristics,gradually forming an innovation ecological environment constructed by vertical interaction of multi-layer innovation systems and horizontal collaboration of multiple organizations and departments,which has posed extremely challenging requirements for higher engineering education to cultivate engineering talents with comprehensive engineering qualities who can solve complex engineering problems.However,practical engineering problems may involve a complex knowledge chain of interdisciplinary and multi-disciplinary cross-coupling.Therefore,higher engineering education needs to form a new interdisciplinary and multi-disciplinary integrated engineering innovation talent training system.Based on the characteristics of the mechanical and electronic engineering major,we will reshape and reconstruct the core courses of the mechanical and electronic engineering major.Two core courses are formed:Drive and Measurement and Control I and Drive and Measurement and Control II,with information flow and energy flow as the main lines,following up with the comprehensive practical curriculum system based on the unity of knowledge and practice and ability-oriented thinking,supporting teaching objectives,promoting students’individual development,and providing guidelines for relevant curriculum reforms. 展开更多
关键词 New engineering Mechanical and electronic engineering CROSS-COUPLING Major integration
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Research on the Development of Fibroin and Nano-Fiber from Silk Cocoons for Regenerated Tissue Engineering Applications by Electro-Spinning
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作者 Md Kamrul Hasan Xinbo Ding 《Advances in Nanoparticles》 CAS 2024年第1期1-9,共9页
In this paper, the main goal is to prepare silk fibroin nano-fiber, which is used for regenerated tissue applications. Silk scaffold nano-fibers made by electro-spinning technology can be used in regenerated tissue ap... In this paper, the main goal is to prepare silk fibroin nano-fiber, which is used for regenerated tissue applications. Silk scaffold nano-fibers made by electro-spinning technology can be used in regenerated tissue applications. The purpose of the research is to prepare a silk-fibroin nano-fiber solution for potential applications in tissue engineering. Using a degumming process, pure silk fibroin protein is extracted from silk cocoons. The protein solution for fibroin is purified, and the protein content is determined. The precise chemical composition, exact temperature, time, voltage, distance, ratio, and humidity all have a huge impact on degumming, solubility, and electro-spinning nano-fibers. The SEM investigates the morphology of silk fibroin nano-fibres at different magnifications. It also reveals the surface condition, fiber orientation, and fiber thickness of the silk fibroin nano-fiber. The results show that regenerated silk fibroin and nano-fiber can be used in silk fibroin scaffolds for various tissue engineering applications. 展开更多
关键词 Silk fibroin SCAFFOLD electro-spinning nano-fiber Tissue engineering
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Biomimetic natural biomaterials for tissue engineering and regenerative medicine:new biosynthesis methods,recent advances,and emerging applications
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作者 Shuai Liu Jiang-Ming Yu +11 位作者 Yan-Chang Gan Xiao-Zhong Qiu Zhe-Chen Gao Huan Wang Shi-Xuan Chen Yuan Xiong Guo-Hui Liu Si-En Lin Alec McCarthy Johnson V.John Dai-Xu Wei Hong-Hao Hou 《Military Medical Research》 SCIE CAS CSCD 2024年第1期50-79,共30页
Biomimetic materials have emerged as attractive and competitive alternatives for tissue engineering(TE)and regenerative medicine.In contrast to conventional biomaterials or synthetic materials,biomimetic scaffolds bas... Biomimetic materials have emerged as attractive and competitive alternatives for tissue engineering(TE)and regenerative medicine.In contrast to conventional biomaterials or synthetic materials,biomimetic scaffolds based on natural biomaterial can offer cells a broad spectrum of biochemical and biophysical cues that mimic the in vivo extracellular matrix(ECM).Additionally,such materials have mechanical adaptability,micro-structure interconnectivity,and inherent bioactivity,making them ideal for the design of living implants for specific applications in TE and regenerative medicine.This paper provides an overview for recent progress of biomimetic natural biomaterials(BNBMs),including advances in their preparation,functionality,potential applications and future challenges.We highlight recent advances in the fabrication of BNBMs and outline general strategies for functionalizing and tailoring the BNBMs with various biological and physicochemical characteristics of native ECM.Moreover,we offer an overview of recent key advances in the functionalization and applications of versatile BNBMs for TE applications.Finally,we conclude by offering our perspective on open challenges and future developments in this rapidly-evolving field. 展开更多
关键词 Biomimic SCAFFOLD BIOSYNTHESIS Natural biomaterial Tissue engineering
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Engineering of ovarian tissue for ovarian dysfunctions:A review
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作者 Aliya Zhylkybekova Gulbakit KKoshmaganbetova +5 位作者 Myltykbay SRysmakhanov Nurgul Abdullayevna Abenova Nadiar Maratovich Mussin Asset Askerovich Kaliyev Mahdi Mahdipour Amin Tamadon 《Asian pacific Journal of Reproduction》 CAS 2024年第1期3-11,共9页
This review explores tissue engineering as a potential solution for reproductive health issues in women caused by genetic or acquired diseases,such as premature ovarian failure or oophorectomy.The loss of ovarian func... This review explores tissue engineering as a potential solution for reproductive health issues in women caused by genetic or acquired diseases,such as premature ovarian failure or oophorectomy.The loss of ovarian function can lead to infertility,osteoporosis,and cardiovascular disease.Hormone replacement therapy is a common treatment,but it has limitations and risks.The review focuses on two main approaches in tissue engineering:scaffold-based(3D printing,electrospinning,decellularization)and scaffold-free(stem cell transplantation,organoid cultivation).Both approaches show promise in preclinical studies for creating functional ovarian tissue.Challenges include vascularization,innervation,long-term function,and safety.Despite these challenges,tissue engineering offers a potential avenue for restoring fertility and hormone balance in women with ovarian dysfunction. 展开更多
关键词 Female gonads Tissue engineering ESTROGEN Reproductive system
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A Review on Silk Fibroin as a Biomaterial in Tissue Engineering
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作者 Tkhu Chang Le Qian Zhang +3 位作者 Qingdi Qu Wentong Ding Sergej Anatolyevich Lazarev Shuang Pan 《Journal of Biosciences and Medicines》 2024年第3期275-290,共16页
Regenerative medicine progress is based on the development of cell and tissue bioengineering. One of the aims of tissue engineering is the development of scaffolds, which should substitute the functions of the replace... Regenerative medicine progress is based on the development of cell and tissue bioengineering. One of the aims of tissue engineering is the development of scaffolds, which should substitute the functions of the replaced organ after their implantation into the body. The tissue engineering material must meet a range of requirements, including biocompatibility, mechanical strength, and elasticity. Furthermore, the materials have to be attractive for cell growth: stimulate cell adhesion, migration, proliferation and differentiation. One of the natural biomaterials is silk and its component (silk fibroin). An increasing number of scientists in the world are studying silk and silk fibroin. The purpose of this review article is to provide information about the properties of natural silk (silk fibroin), as well as its manufacture and clinical application of each configuration of silk fibroin in medicine. Materials and research methods. Actual publications of foreign authors on resources PubMed, Medline, E-library have been analyzed. The selection criteria were materials containing information about the structure and components of silk, methods of its production in nature. This article placed strong emphasis on silk fibroin, the ways of artificial modification of it for use in various sphere of medicine. 展开更多
关键词 Tissue engineering Biomaterial SCAFFOLD SILK Fibroin
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Phase engineering of Ni-Mn binary layered oxide cathodes for sodiumion batteries
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作者 Feifei Hong Xin Zhou +9 位作者 Xiaohong Liu Guilin Feng Heng Zhang Weifeng Fan Bin Zhang Meihua Zuo Wangyan Xing Ping Zhang Hua Yan Wei Xiang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第4期501-511,共11页
Nickel-manganese binary layered oxides with high working potential and low cost are potential candidates for sodium-ion batteries,but their electrochemical properties are highly related to compositional diversity.Dive... Nickel-manganese binary layered oxides with high working potential and low cost are potential candidates for sodium-ion batteries,but their electrochemical properties are highly related to compositional diversity.Diverse composite materials with various phase structures of P3,P2/P3,P2,P2/O3,and P2/P3/O3 were synthesized by manipulating the sodium content and calcination conditions,leading to the construction of a synthetic phase diagram for Na_(x)Ni_(0.25)Mn_(0.75)O_(2)(0.45≤x≤1.1).Then,we compared the electrochemical characteristics and structural evolution during the desodiation/sodiation process of P2,P2/P3,P2/03,and P2/P3/O3-Na_(x)Ni_(0.25)Mn_(0.75)O_(2).Among them,P2/P3-Na0.75Ni0.25Mn0.75O2exhibits the best rate capability of 90.9 mA h g^(-1)at 5 C,with an initial discharge capacity of 142.62 mA h g^(-1)at 0.1 C and a capacity retention rate of 78.25%after 100 cycles at 1 C in the voltage range of 2-4.3 V.The observed superior sodium storage performance of P2/P3 hybrids compared to other composite phases can be attributed to the enhanced Na^(+)transfer dynamic,reduction of the Jahn-teller effect,and improved reaction reversibility induced by the synergistic effect of P2 and P3 phases.The systematic research and exploration of phases in Na_(x)Ni_(0.25)Mn_(0.75)O_(2)provide new sights into high-performance nickel-manganese binary layered oxide for sodium-ion batteries. 展开更多
关键词 Phase engineering Ni-Mn layered oxide CATHODE Sodium-ion batteries
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Engineering the spectra of photon triplets generated from micro/nanofiber
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作者 瞿川 郭东琴 +4 位作者 李笑笑 刘振旗 赵义 张胜海 卫正统 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第3期408-414,共7页
Quantum light sources are the core resources for photonics-based quantum information processing.We investigate the spectral engineering of photon triplets generated by third-order spontaneous parametric down-conversio... Quantum light sources are the core resources for photonics-based quantum information processing.We investigate the spectral engineering of photon triplets generated by third-order spontaneous parametric down-conversion in micro/nanofiber.The phase mismatching at one-third pump frequency gives rise to non-degenerate photon triplets,the joint spectral intensity of which has an elliptical locus with a fixed eccentricity of√6/3.Therefore,we propose a frequency-division scheme to separate non-degenerate photon triplets into three channels with high heralding efficiency for the first time.Choosing an appropriate pump wavelength can compensate for the fabrication errors of micro/nanofiber and also generate narrowband,non-degenerate photon triplet sources with a high signal-to-noise ratio.Furthermore,the long-period micro/nanofiber grating introduces a new controllable degree of freedom to tailor phase matching,resulting from the periodic oscillation of dispersion.In this scheme,the wavelength of photon triplets can be flexibly tuned using quasi-phase matching.We study the generation of photon triplets from this novel perspective of spectrum engineering,and we believe that this work will accelerate the practical implementation of photon triplets in quantum information processing. 展开更多
关键词 photon triplets micro/nanofiber spectrum engineering
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Reform of the Comprehensive Practical Course System for Mechanical and Electronic Engineering Majors Under the Background of New Engineering
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作者 Yali Yu Keyi Wang Yong Yang 《Journal of Contemporary Educational Research》 2024年第2期85-90,共6页
Under the background of new engineering,the reform of the comprehensive practical course system for mechanical and electronic engineering majors actively responds to the challenges posed by the new round of technologi... Under the background of new engineering,the reform of the comprehensive practical course system for mechanical and electronic engineering majors actively responds to the challenges posed by the new round of technological revolution and industrial transformation to higher education,cultivating top-notch innovative intellectuals with comprehensive engineering qualities,meeting the requirements of being able to solve complex engineering problems rather than just cognitive capabilities,forming two core courses through reconstructing and reshaping the core courses of the major.The core courses include Drive,Measurement,and Control I and Drive,Measurement,and Control II,which highlight the comprehensive framework of mechanical and electronic engineering professional knowledge,continuing the comprehensive practical course system based on the unity of knowledge and practice,following the trend of new engineering,highlighting the practicality of professional innovation,assisting engineering education reform,and promoting high-quality development of new engineering professionals cultivation. 展开更多
关键词 Comprehensive engineering quality Mechanical and Electronic engineering Practical course system New engineering
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Solvation Engineering via Fluorosurfactant Additive Toward Boosted Lithium-Ion Thermoelectrochemical Cells
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作者 Yinghong Xu Zhiwei Li +2 位作者 Langyuan Wu Hui Dou Xiaogang Zhang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第4期253-268,共16页
Lithium-ion thermoelectrochemical cell(LTEC), featuring simultaneous energy conversion and storage, has emerged as promising candidate for low-grade heat harvesting. However, relatively poor thermosensitivity and heat... Lithium-ion thermoelectrochemical cell(LTEC), featuring simultaneous energy conversion and storage, has emerged as promising candidate for low-grade heat harvesting. However, relatively poor thermosensitivity and heat-to-current behavior limit the application of LTECs using LiPF_6 electrolyte. Introducing additives into bulk electrolyte is a reasonable strategy to solve such problem by modifying the solvation structure of electrolyte ions. In this work, we develop a dual-salt electrolyte with fluorosurfactant(FS) additive to achieve high thermopower and durability of LTECs during the conversion of low-grade heat into electricity. The addition of FS induces a unique Li~+ solvation with the aggregated double anions through a crowded electrolyte environment,resulting in an enhanced mobility kinetics of Li~+ as well as boosted thermoelectrochemical performances. By coupling optimized electrolyte with graphite electrode, a high thermopower of 13.8 mV K^(-1) and a normalized output power density of 3.99 mW m^(–2) K^(–2) as well as an outstanding output energy density of 607.96 J m^(-2) can be obtained.These results demonstrate that the optimization of electrolyte by regulating solvation structure will inject new vitality into the construction of thermoelectrochemical devices with attractive properties. 展开更多
关键词 Solvation engineering FLUOROSURFACTANT Ionic thermoelectric Lithium-ion thermoelectrochemical cell Low-grade heat
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Constructing a biofunctionalized 3D-printed gelatin/sodium alginate/chitosan tri-polymer complex scaffold with improvised biological andmechanical properties for bone-tissue engineering
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作者 Amit Kumar Singh Krishna Pramanik Amit Biswas 《Bio-Design and Manufacturing》 SCIE EI CAS CSCD 2024年第1期57-73,共17页
Sodium alginate(SA)/chitosan(CH)polyelectrolyte scaffold is a suitable substrate for tissue-engineering application.The present study deals with further improvement in the tensile strength and biological properties of... Sodium alginate(SA)/chitosan(CH)polyelectrolyte scaffold is a suitable substrate for tissue-engineering application.The present study deals with further improvement in the tensile strength and biological properties of this type of scaffold to make it a potential template for bone-tissue regeneration.We experimented with adding 0%–15%(volume fraction)gelatin(GE),a protein-based biopolymer known to promote cell adhesion,proliferation,and differentiation.The resulting tri-polymer complex was used as bioink to fabricate SA/CH/GEmatrices by three-dimensional(3D)printing.Morphological studies using scanning electron microscopy revealed the microfibrous porous architecture of all the structures,which had a pore size range of 383–419μm.X-ray diffraction and Fourier-transform infrared spectroscopy analyses revealed the amorphous nature of the scaffold and the strong electrostatic interactions among the functional groups of the polymers,thereby forming polyelectrolyte complexes which were found to improve mechanical properties and structural stability.The scaffolds exhibited a desirable degradation rate,controlled swelling,and hydrophilic characteristics which are favorable for bone-tissue engineering.The tensile strength improved from(386±15)to(693±15)kPa due to the increased stiffness of SA/CH scaffolds upon addition of gelatin.The enhanced protein adsorption and in vitro bioactivity(forming an apatite layer)confirmed the ability of the SA/CH/GE scaffold to offer higher cellular adhesion and a bone-like environment to cells during the process of tissue regeneration.In vitro biological evaluation including the MTT assay,confocal microscopy analysis,and alizarin red S assay showed a significant increase in cell attachment,cell viability,and cell proliferation,which further improved biomineralization over the scaffold surface.In addition,SA/CH containing 15%gelatin designated as SA/CH/GE15 showed superior performance to the other fabricated 3D structures,demonstrating its potential for use in bone-tissue engineering. 展开更多
关键词 SCAFFOLD Biomaterial Sodium alginate CHITOSAN GELATIN 3D printing Tissue engineering
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Ionization Engineering of Hydrogels Enables Highly Efficient Salt‑Impeded Solar Evaporation and Night‑Time Electricity Harvesting
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作者 Nan He Haonan Wang +3 位作者 Haotian Zhang Bo Jiang Dawei Tang Lin Li 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第1期131-146,共16页
Interfacial solar evaporation holds immense potential for brine desalination with low carbon footprints and high energy utilization.Hydrogels,as a tunable material platform from the molecular level to the macroscopic ... Interfacial solar evaporation holds immense potential for brine desalination with low carbon footprints and high energy utilization.Hydrogels,as a tunable material platform from the molecular level to the macroscopic scale,have been considered the most promising candidate for solar evaporation.However,the simultaneous achievement of high evaporation efficiency and satisfactory tolerance to salt ions in brine remains a challenging scientific bottleneck,restricting the widespread application.Herein,we report ionization engineering,which endows polymer chains of hydrogels with electronegativity for impeding salt ions and activating water molecules,fundamentally overcoming the hydrogel salt-impeded challenge and dramatically expediting water evaporating in brine.The sodium dodecyl benzene sulfonate-modified carbon black is chosen as the solar absorbers.The hydrogel reaches a ground-breaking evaporation rate of 2.9 kg m−2 h−1 in 20 wt%brine with 95.6%efficiency under one sun irradiation,surpassing most of the reported literature.More notably,such a hydrogel-based evaporator enables extracting clean water from oversaturated salt solutions and maintains durability under different high-strength deformation or a 15-day continuous operation.Meantime,on the basis of the cation selectivity induced by the electronegativity,we first propose an all-day system that evaporates during the day and generates salinity-gradient electricity using waste-evaporated brine at night,anticipating pioneer a new opportunity for all-day resource-generating systems in fields of freshwater and electricity. 展开更多
关键词 Solar evaporation Hydrogel evaporators Salt impeding Ionization engineering Cyclic vapor-electricity generation
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d-d Orbital coupling induced by crystal-phase engineering assists acetonitrile electroreduction to ethylamine
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作者 Honggang Huang Yao Chen +7 位作者 Hui Fu Cun Chen Hanjun Li Zhe Zhang Feili Lai Shuxing Bai Nan Zhang Tianxi Liu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期216-225,I0006,共11页
The d-d orbital coupling induced by crystal-phase engineering can effectively adjust the electronic structure of electrocatalysts,thus showing significant catalytic performance,while it has been rarely explored in ele... The d-d orbital coupling induced by crystal-phase engineering can effectively adjust the electronic structure of electrocatalysts,thus showing significant catalytic performance,while it has been rarely explored in electrochemical acetonitrile reduction reaction(ARR)to date.Herein,we successfully realize the structural transformation of Pd Cu metallic aerogels(MAs)from face-centered cubic(FCC)to body-centered cubic(BCC)through annealing treatment.Specifically,the BCC Pd Cu MAs exhibit excellent ARR performance with high ethylamine selectivity of 90.91%,Faradaic efficiency of 88.60%,yield rate of 316.0 mmol h^(-1)g^(-1)_(Pd+Cu)and long-term stability for consecutive electrolysis within 20 h at-0.55 V vs.reversible hydrogen electrode,outperforming than those of FCC Pd Cu MAs.Under the membrane electrode assembly system,BCC Pd Cu MAs also demonstrate excellent ethylamine yield rate of 389.5 mmol h^(-1)g^(-1)_(Pd+Cu).Density functional theory calculation reveals that the d-d orbital coupling in BCC Pd Cu MAs results in an evident correlation effect for the interaction of Pd and Cu sites,which boosts up the Cu sites electronic activities to enhance ARR performance.Our work opens a new route to develop efficient ARR electrocatalysts from the perspective of crystalline structure transformation. 展开更多
关键词 d-d Orbital coupling Crystal-phase engineering Metallic aerogels Acetonitrile electroreduction reaction ETHYLAMINE
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The design and engineering strategies of metal tellurides for advanced metal-ion batteries
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作者 Wenmiao Zhao Xiaoyuan Shi +3 位作者 Bo Liu Hiroshi Ueno Ting Deng Weitao Zheng 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期579-598,I0013,共21页
Owning various crystal structures and high theoretical capacity,metal tellurides are emerging as promising electrode materials for high-performance metal-ion batteries(MBs).Since metal telluride-based MBs are quite ne... Owning various crystal structures and high theoretical capacity,metal tellurides are emerging as promising electrode materials for high-performance metal-ion batteries(MBs).Since metal telluride-based MBs are quite new,fundamental issues raise regarding the energy storage mechanism and other aspects affecting electrochemical performance.Severe volume expansion,low intrinsic conductivity and slow ion diffusion kinetics jeopardize the performance of metal tellurides,so that rational design and engineering are crucial to circumvent these disadvantages.Herein,this review provides an in-depth discussion of recent investigations and progresses of metal tellurides,beginning with a critical discussion on the energy storage mechanisms of metal tellurides in various MBs.In the following,recent design and engineering strategies of metal tellurides,including morphology engineering,compositing,defect engineering and heterostructure construction,for high-performance MBs are summarized.The primary focus is to present a comprehensive understanding of the structural evolution based on the mechanism and corresponding effects of dimension control,composition,electron configuration and structural complexity on the electrochemical performance.In closing,outlooks and prospects for future development of metal tellurides are proposed.This work also highlights the promising directions of design and engineering strategies of metal tellurides with high performance and low cost. 展开更多
关键词 Metal tellurides Metal-ion battery Energy storage mechanism Material design and engineering
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From VIB‑to VB‑Group Transition Metal Disulfides:Structure Engineering Modulation for Superior Electromagnetic Wave Absorption
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作者 Junye Cheng Yongheng Jin +10 位作者 Jinghan Zhao Qi Jing Bailong Gu Jialiang Wei Shenghui Yi Mingming Li Wanli Nie Qinghua Qin Deqing Zhang Guangping Zheng Renchao Che 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第2期218-257,共40页
The laminated transition metal disulfides(TMDs),which are well known as typical two-dimensional(2D)semiconductive materials,possess a unique layered structure,leading to their wide-spread applications in various field... The laminated transition metal disulfides(TMDs),which are well known as typical two-dimensional(2D)semiconductive materials,possess a unique layered structure,leading to their wide-spread applications in various fields,such as catalysis,energy storage,sensing,etc.In recent years,a lot of research work on TMDs based functional materials in the fields of electromagnetic wave absorption(EMA)has been carried out.Therefore,it is of great significance to elaborate the influence of TMDs on EMA in time to speed up the application.In this review,recent advances in the development of electromagnetic wave(EMW)absorbers based on TMDs,ranging from the VIB group to the VB group are summarized.Their compositions,microstructures,electronic properties,and synthesis methods are presented in detail.Particularly,the modulation of structure engineering from the aspects of heterostructures,defects,morphologies and phases are systematically summarized,focusing on optimizing impedance matching and increasing dielectric and magnetic losses in the EMA materials with tunable EMW absorption performance.Milestones as well as the challenges are also identified to guide the design of new TMDs based dielectric EMA materials with high performance. 展开更多
关键词 Transition metal disulfides Electromagnetic wave absorption Impedance matching Structure engineering modulation
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Phase-engineering modulation of Mn-based oxide cathode for constructing super-stable sodium storage
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作者 Quanqing Zhao Ruru Wang +5 位作者 Ming Gao Bolin Liu Jianfeng Jia Haishun Wu Youqi Zhu Chuanbao Cao 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第1期421-427,I0010,共8页
The Mn-based oxide cathode with enriched crystal phase structure and component diversity can provide the excellent chemistry structure for Na-ion batteries.Nevertheless,the broad application prospect is obstructed by ... The Mn-based oxide cathode with enriched crystal phase structure and component diversity can provide the excellent chemistry structure for Na-ion batteries.Nevertheless,the broad application prospect is obstructed by the sluggish Na^(+)kinetics and the phase transitions upon cycling.Herein,we establish the thermodynamically stable phase diagram of various Mn-based oxide composites precisely controlled by sodium content tailoring strategy coupling with co-doping and solid-state reaction.The chemical environment of the P2/P'3 and P2/P3 biphasic composites indicate that the charge compensation mechanism stems from the cooperative contribution of anions and cations.Benefiting from the no phase transition to scavenge the structure strain,P2/P'3 electrode can deliver long cycling stability(capacity retention of 73.8%after 1000 cycles at 10 C)and outstanding rate properties(the discharge capacity of 84.08 mA h g^(-1)at 20 C)than P2/P3 electrode.Furthermore,the DFT calculation demonstrates that the introducing novel P'3 phase can significantly regulate the Na^(+)reaction dynamics and modify the local electron configuration of Mn.The effective phase engineering can provide a reference for designing other high-performance electrode materials for Na-ion batteries. 展开更多
关键词 Sodium ion battery Oxide cathode Phase engineering Phase diagram Na~+kinetic
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