The discarded feathers / ethylene vinyl acetate copolymer( EVA) thermoplastic composite materials was obtained with discarded feathers as reinforced material and EVA powders as matrix material by hot pressing method. ...The discarded feathers / ethylene vinyl acetate copolymer( EVA) thermoplastic composite materials was obtained with discarded feathers as reinforced material and EVA powders as matrix material by hot pressing method. Sound absorption properties were studied by changing mass ratio of discarded feathers and EVA,thickness of composite materials,hot pressing pressure and hot pressing temperature. It was found that the sound absorption properties of composite materials were good when the mass ratio of discarded feathers and EVA was 1: 1,thickness of composite materials was 30 mm,hot pressing pressure was 8 MPa,and hot pressing temperature was 80 ℃. Under the optimum conditions,the effect of composite density on sound absorption property was analyzed. In a certain range,the sound absorption property was enhanced with the decrease of the composite density.When the composite density was 0. 1g /cm^3, the maximum absorption coefficient was 0.96. Finally,the capillary theory was used to calculate the maximum sound absorption coefficient of discarded feathers / EVA thermoplastic composite materials. The good agreements of experimental results and calculated results proved the validity of the theoretical models.展开更多
Carbon nanotube (CNT) has remarkable piezoresistive properties,which makes its extremely sensitive to the mechanical force. In this study,the CNT yarn with the strength of 90 MPa and the strain sensing gage factor of ...Carbon nanotube (CNT) has remarkable piezoresistive properties,which makes its extremely sensitive to the mechanical force. In this study,the CNT yarn with the strength of 90 MPa and the strain sensing gage factor of 1.75 was selected and embedded into the ethylene vinyl acetate (EVA) elastomer as a sensing material.By measuring the electric resistance changing under the stretching,bending,longitudinally and transversely compressing of the CNT embedded EVA, the resistance changing curves and their linear correlations were obtained and analyzed. The result shows that the gage factor under the tensile test is the highest( 2.51),which is higher than the original value of CNT yarn (1.75). The gage factors of the CNT yarn embedded into EVA elastomer under bending and longitudinal and transverse compression are 2.29,1.55 and 0.79,respectively.展开更多
Polyamide 6 (PA6) was employed as a charring agent of intumescent flame retardant (IFR) to improve the flame retardancy of ethylene-vinyl acetate copolymer (EVA). Different processing procedures were used to regulate ...Polyamide 6 (PA6) was employed as a charring agent of intumescent flame retardant (IFR) to improve the flame retardancy of ethylene-vinyl acetate copolymer (EVA). Different processing procedures were used to regulate the localization of IFR in the EVA matrix. Localizations in which IFR was dispersed in the PA6phase or in the EVA phase were prepared. The effect of the localization of IFR on the flame retardancy of EVA was investigated. The limited oxygen index (LOI), vertical burning (UL 94) and cone calorimeter test (CCT)showed that the localization of IFR in the EVA matrix exhibited a remarkable influence on the flame retardancy.Compared with EVA/IFR, a weak improvement in the flame retardancy was observed in the EVA/PA6/IFR blend withthe localization of IFR in the PA6 phase. When IFR was regulated from the PA6 phase to the EVA matrix,a remarkable increase in the flame retardancy was exhibited. The LOI was increased from 27.8%to 32.7%, and the UL 94 vertical rating was increased from V-2 to V-0. Moreover, an approximately 41.36%decrease in the peak heat release rate was exhibited. A continuous and compact intumescent charring layer that formed in the blends with the localization of IFR in the EVA matrix should be responsible for its excellent flame retardancy.展开更多
The increasing demand for new packages with increased shelf life properties has stimulated the increase of research in the active packaging sector. The use of antimicrobial agents requires an in-depth study of their p...The increasing demand for new packages with increased shelf life properties has stimulated the increase of research in the active packaging sector. The use of antimicrobial agents requires an in-depth study of their properties to avoid loss of efficiency of the polymer processing. In this context, the objective of this work was to evaluate the preparation of an 18% ethylene vinyl acetate copolymer (EVA) nanocomposite and zinc oxide (ZnO) as microbicidal nanoparticle, prepared in a monosulfon extruder. The nanoparticle was modified with octadecylamine and EVA 18 nanocomposite films were prepared and compared to the systems containing modified nanoparticle. These new materials were characterized by thermogravimetric analysis (TGA), Differential Scanning Calorimetry (DSC), X-Ray Diffraction (XRD), Dynamic Mechanical Analysis (DMA), Time Domain Nuclear Magnetic Resonance (NMR) to investigate the effect of zinc oxide nanoparticles on thermal properties, EVA crystallinity and antimicrobial effect. The TGA showed a tendency of increase of the thermal stability in different proportions of ZnO. DSC results did not show significant changes in thermal parameters. The XRD analysis showed an increase in the degree of crystallinity of the nanocomposites in relation to the EVA matrix and change in the crystallinity with the increase of ZnO percentages. DMA analysis indicates change in structural organization through the variation of storage modulus, loss, and tan delta. Time domain NMR data corroborate with XRD data through the change in molecular mobility.展开更多
The effects of magnesium oxide （MgO） on the flame retardant performance of intumescent systems based on ammonium polyphosphate （APP） and pentaerythritol （PER） in ethylene vinyl acetate copolymer （EVA） were stu...The effects of magnesium oxide （MgO） on the flame retardant performance of intumescent systems based on ammonium polyphosphate （APP） and pentaerythritol （PER） in ethylene vinyl acetate copolymer （EVA） were studied. The results showed that MgO affects both the quality and quantity of residual char. There is an optimal value for the loading amount of MgO. More or less MgO loading may cause the formation of defective char layers and worsen the flame retardancy of EVA. According to the results of limiting oxygen index （LOI）, vertical flammability test （UL94 rating） and cone calorimetry （CONE）, the best flame retardancy with a strong and well intumescent char is obtained from the sample with 1 wt% of MgO, which has the highest LOI value of 27.9, UL94 rating of V-0 and the lowest peak heat release rate of 242 kW·m-2.展开更多
In recent building practice,rapid construction is one of the principal requisites.Furthermore,in designing concrete structures,compressive strength is the most significant of all parameters.While 3-d and 7-d compressi...In recent building practice,rapid construction is one of the principal requisites.Furthermore,in designing concrete structures,compressive strength is the most significant of all parameters.While 3-d and 7-d compressive strength reflects the strengths at early phases,the ultimate strength is paramount.An effort has been made in this study to develop mathematical models for predicting compressive strength of concrete incorporating ethylene vinyl acetate(EVA)at the later phases.Kolmogorov-Smirnov(KS)goodness-of-fit test was used to examine distribution of the data.The compressive strength of EVA-modified concrete was studied by incorporating various concentrations of EVA as an admixture and by testing at ages of 28,56,90,120,210,and 365 d.An accelerated compressive strength at 3.5 hours was considered as a reference strength on the basis of which all the specified strengths were predicted by means of linear regression fit.Based on the results of KS goodness-of-fit test,it was concluded that KS test statistics value(D)in each case was lower than the critical value 0.521 for a significance level of 0.05,which demonstrated that the data was normally distributed.Based on the results of compressive strength test,it was concluded that the strength of EVA-modified specimens increased at all ages and the optimum dosage of EVA was achieved at 16%concentration.Furthermore,it was concluded that predicted compressive strength values lies within a 6%difference from the actual strength values for all the mixes,which indicates the practicability of the regression equations.This research work may help in understanding the role of EVA as a viable material in polymer-based cement composites.展开更多
文摘The discarded feathers / ethylene vinyl acetate copolymer( EVA) thermoplastic composite materials was obtained with discarded feathers as reinforced material and EVA powders as matrix material by hot pressing method. Sound absorption properties were studied by changing mass ratio of discarded feathers and EVA,thickness of composite materials,hot pressing pressure and hot pressing temperature. It was found that the sound absorption properties of composite materials were good when the mass ratio of discarded feathers and EVA was 1: 1,thickness of composite materials was 30 mm,hot pressing pressure was 8 MPa,and hot pressing temperature was 80 ℃. Under the optimum conditions,the effect of composite density on sound absorption property was analyzed. In a certain range,the sound absorption property was enhanced with the decrease of the composite density.When the composite density was 0. 1g /cm^3, the maximum absorption coefficient was 0.96. Finally,the capillary theory was used to calculate the maximum sound absorption coefficient of discarded feathers / EVA thermoplastic composite materials. The good agreements of experimental results and calculated results proved the validity of the theoretical models.
基金National Natural Science Foundations of China(Nos.51303025,51503120)Shanghai Science and Technology Committee,China(No.14YF1409600)+2 种基金Shanghai Municipal Education Commission,China(No.ZZgcd14016)Fundamental Research Funds for the Central Universities,ChinaDonghua University Distinguished Young Professor Program,China
文摘Carbon nanotube (CNT) has remarkable piezoresistive properties,which makes its extremely sensitive to the mechanical force. In this study,the CNT yarn with the strength of 90 MPa and the strain sensing gage factor of 1.75 was selected and embedded into the ethylene vinyl acetate (EVA) elastomer as a sensing material.By measuring the electric resistance changing under the stretching,bending,longitudinally and transversely compressing of the CNT embedded EVA, the resistance changing curves and their linear correlations were obtained and analyzed. The result shows that the gage factor under the tensile test is the highest( 2.51),which is higher than the original value of CNT yarn (1.75). The gage factors of the CNT yarn embedded into EVA elastomer under bending and longitudinal and transverse compression are 2.29,1.55 and 0.79,respectively.
基金the National Natural Science Foundation of China (No.51673059)the Science and Technology Planning Project of Henan Province (No. 212102210636)the Opening Project of Jiangxi Province Key Laboratory of Polymer Micro/Nano Manufacturing and Devices (East China University of Technology)。
文摘Polyamide 6 (PA6) was employed as a charring agent of intumescent flame retardant (IFR) to improve the flame retardancy of ethylene-vinyl acetate copolymer (EVA). Different processing procedures were used to regulate the localization of IFR in the EVA matrix. Localizations in which IFR was dispersed in the PA6phase or in the EVA phase were prepared. The effect of the localization of IFR on the flame retardancy of EVA was investigated. The limited oxygen index (LOI), vertical burning (UL 94) and cone calorimeter test (CCT)showed that the localization of IFR in the EVA matrix exhibited a remarkable influence on the flame retardancy.Compared with EVA/IFR, a weak improvement in the flame retardancy was observed in the EVA/PA6/IFR blend withthe localization of IFR in the PA6 phase. When IFR was regulated from the PA6 phase to the EVA matrix,a remarkable increase in the flame retardancy was exhibited. The LOI was increased from 27.8%to 32.7%, and the UL 94 vertical rating was increased from V-2 to V-0. Moreover, an approximately 41.36%decrease in the peak heat release rate was exhibited. A continuous and compact intumescent charring layer that formed in the blends with the localization of IFR in the EVA matrix should be responsible for its excellent flame retardancy.
文摘The increasing demand for new packages with increased shelf life properties has stimulated the increase of research in the active packaging sector. The use of antimicrobial agents requires an in-depth study of their properties to avoid loss of efficiency of the polymer processing. In this context, the objective of this work was to evaluate the preparation of an 18% ethylene vinyl acetate copolymer (EVA) nanocomposite and zinc oxide (ZnO) as microbicidal nanoparticle, prepared in a monosulfon extruder. The nanoparticle was modified with octadecylamine and EVA 18 nanocomposite films were prepared and compared to the systems containing modified nanoparticle. These new materials were characterized by thermogravimetric analysis (TGA), Differential Scanning Calorimetry (DSC), X-Ray Diffraction (XRD), Dynamic Mechanical Analysis (DMA), Time Domain Nuclear Magnetic Resonance (NMR) to investigate the effect of zinc oxide nanoparticles on thermal properties, EVA crystallinity and antimicrobial effect. The TGA showed a tendency of increase of the thermal stability in different proportions of ZnO. DSC results did not show significant changes in thermal parameters. The XRD analysis showed an increase in the degree of crystallinity of the nanocomposites in relation to the EVA matrix and change in the crystallinity with the increase of ZnO percentages. DMA analysis indicates change in structural organization through the variation of storage modulus, loss, and tan delta. Time domain NMR data corroborate with XRD data through the change in molecular mobility.
基金financially supported by the National Natural Science Foundation of China(No.51203136)the Scientific Special Fund of Zhejiang Province(No.2013C01074)
文摘The effects of magnesium oxide （MgO） on the flame retardant performance of intumescent systems based on ammonium polyphosphate （APP） and pentaerythritol （PER） in ethylene vinyl acetate copolymer （EVA） were studied. The results showed that MgO affects both the quality and quantity of residual char. There is an optimal value for the loading amount of MgO. More or less MgO loading may cause the formation of defective char layers and worsen the flame retardancy of EVA. According to the results of limiting oxygen index （LOI）, vertical flammability test （UL94 rating） and cone calorimetry （CONE）, the best flame retardancy with a strong and well intumescent char is obtained from the sample with 1 wt% of MgO, which has the highest LOI value of 27.9, UL94 rating of V-0 and the lowest peak heat release rate of 242 kW·m-2.
文摘In recent building practice,rapid construction is one of the principal requisites.Furthermore,in designing concrete structures,compressive strength is the most significant of all parameters.While 3-d and 7-d compressive strength reflects the strengths at early phases,the ultimate strength is paramount.An effort has been made in this study to develop mathematical models for predicting compressive strength of concrete incorporating ethylene vinyl acetate(EVA)at the later phases.Kolmogorov-Smirnov(KS)goodness-of-fit test was used to examine distribution of the data.The compressive strength of EVA-modified concrete was studied by incorporating various concentrations of EVA as an admixture and by testing at ages of 28,56,90,120,210,and 365 d.An accelerated compressive strength at 3.5 hours was considered as a reference strength on the basis of which all the specified strengths were predicted by means of linear regression fit.Based on the results of KS goodness-of-fit test,it was concluded that KS test statistics value(D)in each case was lower than the critical value 0.521 for a significance level of 0.05,which demonstrated that the data was normally distributed.Based on the results of compressive strength test,it was concluded that the strength of EVA-modified specimens increased at all ages and the optimum dosage of EVA was achieved at 16%concentration.Furthermore,it was concluded that predicted compressive strength values lies within a 6%difference from the actual strength values for all the mixes,which indicates the practicability of the regression equations.This research work may help in understanding the role of EVA as a viable material in polymer-based cement composites.
