Ferritic/martensitic(F/M)steel is widely used as a structural material in thermal and nuclear power plants.However,it is susceptible to intergranular damage,which is a critical issue,under service conditions.In this s...Ferritic/martensitic(F/M)steel is widely used as a structural material in thermal and nuclear power plants.However,it is susceptible to intergranular damage,which is a critical issue,under service conditions.In this study,to improve the resistance to intergranular damage of F/M steel,a thermomechanical process(TMP)was employed to achieve a grain boundary engineering(GBE)microstructure in F/M steel P92.The TMP,including cold-rolling thickness reduction of 6%,9%,and 12%,followed by austenitization at 1323 K for 40 min and tempering at 1053 K for 45 min,was applied to the as-received(AR)P92 steel.The prior austenite grain(PAG)size,prior austenite grain boundary character distribution(GBCD),and connectivity of prior austenite grain boundaries(PAGBs)were investigated.Compared to the AR specimen,the PAG size did not change significantly.The fraction of coincident site lattice boundaries(CSLBs,3≤Σ≤29)and Σ3^(n) boundaries along PAGBs decreased with increasing reduction ratio because the recrystallization fraction increased with increasing reduction ratio.The PAGB connectivity of the 6%deformed specimen slightly deteriorated compared with that of the AR specimen.Moreover,potentiodynamic polarization studies revealed that the intergranular damage resistance of the studied steel could be improved by increasing the fraction of CSLBs along the PAGBs,indicating that the TMP,which involves low deformation,could enhance the intergranular damage resistance.展开更多
Microstructure and mechanical properties of GN9 Ferritic/Martensitic steel for sodium-cooled fast reactors have been investigated through orthogonal design and analysis.Scanning electron microscopy(SEM),transmission e...Microstructure and mechanical properties of GN9 Ferritic/Martensitic steel for sodium-cooled fast reactors have been investigated through orthogonal design and analysis.Scanning electron microscopy(SEM),transmission electron microscopy(TEM),differential scanning calorimeter(DSC),tensile and impact tests were used to evaluate the heat treatment parameters on yield strength,elongation and ductile-to-brittle transition temperature(DBTT).The results indicate that the microstructures of GN9 steel after orthogonal heat treatments consist of tempered martensite,M23C6,MX carbides and MX carbonitrides.The average prior austenite grains increase and the lath width decreases with the austenitizing temperature increasing from 1000°C to 1080°C.Tempering temperature is the most important factor that influences the dislocation evolution,yield strength and elongation compared with austenitizing tempera-ture and cooling methods.Austenitizing temperature,tempering temperature and cooling methods show interactive effects on DBTT.Carbide morphology and distribution,which is influenced by austenitizing and tempering tempera-tures,is the critical microstructural factor that influences the Charpy impact energy and DBTT.Based on the orthogo-nal design and microstructural analysis,the optimal heat treatment of GN9 steel is austenitizing at 1000°C for 0.5 h followed by air cooling and tempering at 760°C for 1.5 h.展开更多
This review summarizes the strengthening mechanisms of reduced activation ferritic/martensitic(RAFM)steels.High-angle grain boundaries,subgrain boundaries,nano-sized M_(23)C_(6),and MX carbide precipitates effectively...This review summarizes the strengthening mechanisms of reduced activation ferritic/martensitic(RAFM)steels.High-angle grain boundaries,subgrain boundaries,nano-sized M_(23)C_(6),and MX carbide precipitates effectively hinder dislocation motion and increase high-temperature strength.M23C6 carbides are easily coarsened under high temperatures,thereby weakening their ability to block dislocations.Creep properties are improved through the reduction of M23C6 carbides.Thus,the loss of strength must be compensated by other strengthening mechanisms.This review also outlines the recent progress in the development of RAFM steels.Oxide dispersion-strengthened steels prevent M23C6 precipitation by reducing C content to increase creep life and introduce a high density of nano-sized oxide precipitates to offset the reduced strength.Severe plastic deformation methods can substantially refine subgrains and MX carbides in the steel.The thermal deformation strengthening of RAFM steels mainly relies on thermo-mechanical treatment to increase the MX carbide and subgrain boundaries.This procedure increases the creep life of TMT(thermo-mechanical treatment)9Cr-1W-0.06Ta steel by~20 times compared with those of F82H and Eurofer 97 steels under 550℃/260 MPa.展开更多
Recent accomplishment by the SWIP for the reduced activation ferritic/martensitic steel CLF-1 development has been reviewed. It＇s found that CLF- 1 steel has better room temperature tensile properties than Eurofer97 ...Recent accomplishment by the SWIP for the reduced activation ferritic/martensitic steel CLF-1 development has been reviewed. It＇s found that CLF- 1 steel has better room temperature tensile properties than Eurofer97 steel and has a fully martensitic microstructure.展开更多
Studies of synergetic irradiation effects and liquid lead-bismuth eutectic(LBE) corrosion/embrittlement effects on ferritic/martensitic(F/M) steels are of great importance for developing high power spallation neutron ...Studies of synergetic irradiation effects and liquid lead-bismuth eutectic(LBE) corrosion/embrittlement effects on ferritic/martensitic(F/M) steels are of great importance for developing high power spallation neutron targets(>1 M W) such as the European Spallation Source(ESS) and Accelerator Driven System(ADS) facilities that can be used for transmuting long-lifetime radioactive wastes. Liquid LBE(45Pb-55Bi,in terms of mass fraction) has been selected as the candidate target material in high power spallation neutron targets due to its favourable thermal,physical & chemical properties,and to its high spallation neutron yield. 9Cr F/M steels such as T91(9Cr1M oVNb,in terms of mass fraction) have been chosen as the structural material for the targets due to their good mechanical properties and good resistance to irradiation induced swelling in fission neutron irradiation environments. For developing high power spallation neutron targets,behaviors of F/M steels in spallation neutron target irradiation environments and LBE corrosion/embrittlement effects have been extensively studied. However,many open questions have not been answered. The aim of this paper is to describe the present research situation on this topic. The obtained experimental data about LBE embrittlement effects on F/M steels is summarized and the influence of different parameters involved is analyzed to understand the influence effect on LBE embrittlement effect of F/M s.展开更多
Reduced activation ferritic/martensitic steels (RAFM) are important candidate materials for future nuclear fusion reactors because of their high thermal conductivity, low thermal expansion rate and high resistance to ...Reduced activation ferritic/martensitic steels (RAFM) are important candidate materials for future nuclear fusion reactors because of their high thermal conductivity, low thermal expansion rate and high resistance to void swelling. The influence of the accumulation of high concentration of helium via the（n, a）nuclear reaction on microstructures and macro-properties of the steels is an important issue limiting the service lifetime of the materials.展开更多
In this study,the microstructures and mechanical properties of 9%Cr reduced activation ferritic/martensitic（RAFM） steel friction stir welded joints were investigated.When a W-Re tool is used,the recommended welding ...In this study,the microstructures and mechanical properties of 9%Cr reduced activation ferritic/martensitic（RAFM） steel friction stir welded joints were investigated.When a W-Re tool is used,the recommended welding parameters are 300 rpm rotational speed,60 mm/min welding speed and10 kn axial force.In stir zone（SZ）,austenite dynamic recrystallization induced by plastic deformation and the high cooling rates lead to an obvious refinement of prior austenite grains and martensite laths.The microstructure in SZ contains lath martensite with high dislocation density,a lot of nano-sized MX and M3C phase particles,but almost no M23C6 precipitates.In thermal mechanically affect zone（TMAZ）and heat affect zone（HAZ）,refinement of prior austenite and martensitic laths and partial dissolution of M（23）C6 precipitates are obtained at relatively low rotational speed.However,with the increase of heat input,coarsening of martensitic laths,prior austenite grains,and complete dissolution of M23C6 precipitates are achieved.Impact toughness of SZ at-20℃ is slightly lower than that of base material（BM）,and exhibits a decreasing trend with the increase of rotational speed.展开更多
12Cr ferritic/martensitic steels with 0, 0.1 wt%, 0.2 wt% and 0.3 wt% theoretical yttrium(Y) additions were fabricated by vacuum inducting melting and casting method. Solubilities of Y in the 12Cr steels are0.027, 0.0...12Cr ferritic/martensitic steels with 0, 0.1 wt%, 0.2 wt% and 0.3 wt% theoretical yttrium(Y) additions were fabricated by vacuum inducting melting and casting method. Solubilities of Y in the 12Cr steels are0.027, 0.078 and 0.17 for 12Cr-0.1 Y, 12Cr-0.2 Y and 12Cr-0.3 Y, respectively. Phase transformations and microstructure characteristics under different heat-treatment schedules were investigated. The starting temperature of ferrite-to-austenite transformation A^(c1) are maintained about 850℃, but the finishing temperature of ferrite-to-austenite transformation A^(c3) are about 950, 970, 980 and 1000℃ for 12Cr-0 Y,12Cr-0.1 Y, 12Cr-0.2 Y and 12Cr-0.3 Y, respectively, which indicates that A^(c3) increases gradually with the addition of Y. Martensite accompanied with a few δ-ferrite is the dominant structure in all the steels. The amount of δ-ferrite shows a strong dependence with the Y content and austenitizing temperature. Area fraction of δ-ferrite increases with the content of Y, which is the ferrite favouring element. The minimum amount of δ-ferrite are achieved at 950℃ for 12Cr-0 Y, 12Cr-0.1 Y, 12Cr-0.2 Y and 1000℃ for 12Cr-0.3 Y.Besides, more carbides precipitate along the martensite laths and grain boundaries in the Y-bearing steel due to the redistribution of carbon between austenite and ferrite resulting from the ferrite favouring element of Y.展开更多
A high Si reduced activation ferritic/martensitic(RAFM) steel for nuclear structure application is successfully designed by using Calphad method. The main designed chemical composition is C 0.18–0.22%, Cr10.0–10.5%,...A high Si reduced activation ferritic/martensitic(RAFM) steel for nuclear structure application is successfully designed by using Calphad method. The main designed chemical composition is C 0.18–0.22%, Cr10.0–10.5%, W 1.0–1.5%, Si 1.0–1.3%, V+Ta 0.30–0.45%, and Fe in balance. High Si design brings excellent corrosion resistance, while low activation is advantageous in the nuclear waste processing. The experimental results indicate that the newly designed high Si RAFM steel had full martensitic structure and uniformly distributed fine second phase particles, and exhibited excellent mechanical properties and corrosion resistance. Compared to the P91 steel, this new RAFM steel designed by Calphad method is expected to be a promising candidate used in nuclear power generation, which also provides a new and effective approach to the development of RAFM steel for nuclear application.展开更多
Ferritic/martensitic steels with Cr of 9%-12% （in mass percent） are favourable candidates for fuel cladding tube and in-core components of supercritical water-cooled reactor. 9Cr-3WVTiTaN low activation ferritic/mar...Ferritic/martensitic steels with Cr of 9%-12% （in mass percent） are favourable candidates for fuel cladding tube and in-core components of supercritical water-cooled reactor. 9Cr-3WVTiTaN low activation ferritic/martensitic steel, designated as China Nuclear Steel- I （CNS- I ）, was patterned after T91 steel （modified 9Cr-lMo） for the reactor. The idea of low activation material and microalloy technology was introduced into the design of the steel. The hardening, tempering and transformation behaviour of CNS- I steel was investigated. The steel has advantages in tensile properties at elevated temperature relative to zircaloy that has been widely used as cladding material for conventional light water reactors. CNS- I steel exhibits tensile properties and impact toughness comparable to T91 steel which exhibits availability in the present fission reactors and fast breeder reactor but includes undesired radioactive elements such as molybdenum and niobium.展开更多
The hot deformation behavior and workability of a new reduced activation ferritic/martensitic steel named SIMP steel for accelerator-driven system were studied. The flow curve and its microstructure were studied at 90...The hot deformation behavior and workability of a new reduced activation ferritic/martensitic steel named SIMP steel for accelerator-driven system were studied. The flow curve and its microstructure were studied at 900-1200 ℃ and strain rate range of 0.001-10 s^-1. The results showed that the deformation behavior of the SIMP steel during hot compression could be manifested by the Zener-Hollomon parameter in an exponent-type equation. Based on the obtained constitutive equation, the calculated flow stresses were in agreement with the experimentally measured ones, and the average activity energies Qdrv and QHw for the initiation of dynamic recrystallization and the peak strain were calculated to be 476.1 kJ/mol and 462.7 kJ/mol, respectively. Furthermore, based on the processing maps and microstructure evolution, the optimum processing condition for the SIMP steel was determined to be 1050-1200 ℃/0.001-0.1s^-1.展开更多
The oxidation behavior of two Ferritic/Martensitic(F/M)steels including novel SIMP steel and commercial P91 steel were investigated by exposure to flowing deaerated supercritical water(SCW)at 700℃for up to 1000 h.The...The oxidation behavior of two Ferritic/Martensitic(F/M)steels including novel SIMP steel and commercial P91 steel were investigated by exposure to flowing deaerated supercritical water(SCW)at 700℃for up to 1000 h.The kinetic weight gain curves follow parabolic and near-cubic rate equations for SIMP and P91 steels,respectively.X-Ray Diffraction analysis showed the presence of magnetite and a spinel phase in flowing SCW for both steels.The morphology and structure of the oxide scales formed on these two steels were analyzed.The relationship between the microstructure and oxidation behavior and the reason that SIMP steel showed better oxidation resistance than P91 steel were discussed.展开更多
Precipitates in an 11% Cr ferritic/martensitic steel containing Nd with tempering and creep conditions were investigated using transmission electron microscope with energy-dispersive X-ray spectroscopy. The precipitat...Precipitates in an 11% Cr ferritic/martensitic steel containing Nd with tempering and creep conditions were investigated using transmission electron microscope with energy-dispersive X-ray spectroscopy. The precipitates in the steel with a tempering condition were identified to be Cr-rich M23C6 carbide, Nb-rich/V-rich/Ta–Nb-rich MX carbides, Nbrich MX carbonitride, and Fe-rich M5C2 carbide. Nd-rich carbonitride, which is not known to have been reported previously in steels, was also detected in the steel after tempering. Most of the Nb-rich MX precipitates were dissolved, whereas the amount of Ta-rich MX precipitates was increased significantly in the steel after a creep test at 600 °C at an applied stress of180 MPa for 1,100 h. No Fe2 W Laves phase has been detected in the steel after tempering.（Fe, Cr）2W Laves phase with a relatively large size was observed in the steel after the creep test.展开更多
Helium ion irradiation at 350℃was performed to study equilibrium segregation and radiation-induced segregation(RIS)of Cr at grain boundaries in reduced activation ferritic/martensitic steels.Cr concentration at grain...Helium ion irradiation at 350℃was performed to study equilibrium segregation and radiation-induced segregation(RIS)of Cr at grain boundaries in reduced activation ferritic/martensitic steels.Cr concentration at grain boundary was measured by scanning transmission electron microscopy with an energy-dispersive spectrometer.The measured Cr concentration at grain boundaries in heat treated zone was 11.7 and 12.8 wt.%in irradiated zone,respectively,which matched well to the calculated results from Mclean and modified Perk model.Equilibrium segregation and RIS of Cr mechanisms were theoretically analysed.The analysis indicates that as temperature rises,equilibrium Cr segregation decreases monotoni-cally,while RIS of Cr has a bell-shape profile,which increases first and then decreases.It is also shown that at low and high temperatures,equilibrium segregation of Cr is higher than that of RIS;at intermediate temperatures,equilibrium Cr segregation is lower than RIS.展开更多
The corrosion behaviors of CNS-I and modified CNS-II were evaluated by exposing to superciritical water （SCW） at 550℃ and 25 MPa with a dissolved oxygen concentration of 200× 10 ^-9 for up to 1 000 h. Detailed...The corrosion behaviors of CNS-I and modified CNS-II were evaluated by exposing to superciritical water （SCW） at 550℃ and 25 MPa with a dissolved oxygen concentration of 200× 10 ^-9 for up to 1 000 h. Detailed corrosion results of these two alloys were provided, including the growth rate of the oxide scales, microstructure of the oxide scales, distribution of phases and alloying elements. The mass gains of CNS-I and modified CNS-II were 609.73 mg/dm2 and 459.42 mg/dm2 , respectively, after exposing to SCW for 1 000 h. A duplex oxide scale with an outer porous magnetite layer and an inner relatively dense magnetite/spinel-mixed layer was identified on CNS-I and modified CNS-II after the test. The oxide scales were rather porous at the beginning of the test but the porosity decreased with increase of the exposure duration. It was found that Fe was enriched in the outer oxide layer, Cr was enriched in the inner oxide layer and O existed at a very high concnetration in the whole oxide scale. Other alloying elements such as Mo, W, Mn were depleted from the outer oxide layer and showed slightly enrichment in the inner oxide layer. The distributution of Ni was different from other elements, it was enriched in the interface bewteen the base metal and the oxide scale and depleted in the outer and inner oxide layers.展开更多
For dissimilar metal welds(DMWs)involving nickel-based weld metal(WM)and ferritic heat resistant steel base metal(BM)in power plants,there must be an interface between WM and BM,and this interface suffers mechanical a...For dissimilar metal welds(DMWs)involving nickel-based weld metal(WM)and ferritic heat resistant steel base metal(BM)in power plants,there must be an interface between WM and BM,and this interface suffers mechanical and microstructure mismatches and is often the rupture location of premature failure.In this study,a new form of WM/BM interface form,namely double Y-type interface was designed for the DMWs.Creep behaviors and life of DMWs containing double Y-type interface and conventional I-type interface were compared by finite element analysis and creep tests,and creep failure mechanisms were investigated by stress-strain analysis and microstructure characterization.By applying double Y-type interface instead of conventional I-type interface,failure location of DMW could be shifted from the WM/ferritic heat-affected zone(HAZ)interface into the ferritic HAZ or even the ferritic BM,and the failure mode change improved the creep life of DMW.The interface premature failure of I-type interface DMW was related to the coupling effect of microstructure degradation,stress and strain concentrations,and oxide notch on the WM/HAZ interface.The creep failure of double Y-type interface DMW was the result of Type IV fracture due to the creep voids and micro-cracks on fine-grain boundaries in HAZ,which was a result of the matrix softening of HAZ and lack of precipitate pinning at fine-grain boundaries.The double Y-type interface form separated the stress and strain concentrations in DMW from the WM/HAZ interface,preventing the trigger effect of oxide notch on interface failure and inhibiting the interfacial microstructure cracking.It is a novel scheme to prolong creep life and enhance reliability of DMW,by means of optimizing the interface form,decoupling the damage factors from WM/HAZ interface,and then changing the failure mechanism and shifting the failure location.展开更多
Advanced oxide metallurgy technique was adopted to produce 100-kg Y-bearing 12Cr ferritic/martensitic steel via vacuum induction melting and casting route. Subsequently, nine specimens at top, middle and bottom region...Advanced oxide metallurgy technique was adopted to produce 100-kg Y-bearing 12Cr ferritic/martensitic steel via vacuum induction melting and casting route. Subsequently, nine specimens at top, middle and bottom regions of the sheet were char-acterized to evaluate the homogeneity of chemical composition, microstructure and mechanical properties. The small vibra-tion of hardness (200–220 HBW), ultimate tensile strength (672–678 MPa), yield strength (468–480 MPa), total elongation (26.2%–30.5%) and Charpy energy at room temperature (98–133 J) and at ??40 ℃ (12–40 J) demonstrated that mechanical properties’ homogeneity of Y-bearing steel was acceptable although slight Y segregation and inhomogeneous microstructure occurred at the bottom. Furthermore, the effect of Y content on microstructure characteristics and mechanical properties was explained and the comparison of failure mechanism for the dual-phase steel between tensile test (i.e., quasi-static loading) and Charpy test (i.e., dynamic loading) was discussed in detail.展开更多
Taking Pd_(2)MnTi as a representative example,we systematically investigate and theoretically reveal the electronic structure evolution during martensitic phase transition in all-d-metal Heusler compounds.The calculat...Taking Pd_(2)MnTi as a representative example,we systematically investigate and theoretically reveal the electronic structure evolution during martensitic phase transition in all-d-metal Heusler compounds.The calculation and theoretical analysis suggest that Pd_(2)MnTi is not stable in cubic structure and prone to transform to lowsymmetric tetragonal structure.By tetragonal deformation,the shrinkage of lattice parameters and the decrease of symmetry promote the electron accumulation between Pd and its first nearest neighboring Ti atom,resulting in the increasing covalent hybridization.The occurrence of pseudogap in density of states of tetragonal Pd_(2)MnTi near the Fermi level also verifies the enhancement of covalent bond.Comparatively,the stronger interatomic bond in tetragonal Pd_(2)MnTi,i.e.,covalent bond here,would strengthen interatomic coupling and consequently lower the energy of the material.By the martensitic phase transition,more stable states in energy are achieved.Thus,based on the analysis of electronic structure evolution,the nature of martensitic phase transition is a process wherein symmetry breaking weakens the original weak chemical bonds in high-symmetric parent phase and induces the strong chemical bond to lower the energy of the materials and to achieve a more stable state.This study could help to deepen the understanding of martensitic phase transition and the exploration of novel materials for potential technical applications.展开更多
The thermal-elastic martensitic transformation from high-temperature Ni_(2)In-type hexagonal structure to low-temperature TiNiSi-type orthorhombic structure has been widely studied in MnMX(M=Ni or Co,and X=Ge or Si)al...The thermal-elastic martensitic transformation from high-temperature Ni_(2)In-type hexagonal structure to low-temperature TiNiSi-type orthorhombic structure has been widely studied in MnMX(M=Ni or Co,and X=Ge or Si)alloys.However,the answer to how the orthorhombic martensite nucleates and grows within the hexagonal parent is still unclear.In this work,the hexagonal-orthorhombic martensitic transformation in a Co and Ge co-substituted MnNiSi is investigated.One can find some orthorhombic laths embedded in the hexagonal parent at a temperature above the martensitic transformation start temperature(M_(s)).With the the sample cooing to M_(s),the laths turn broader,indicating that the martensitic transformation starts from these pre-existing orthorhombic laths.Microstructure observation suggests that these pre-existing orthorhombic laths do not originate from the hexagonal-orthorhombic martensitic transformation because of the difference between atomic occupations of doping elements in the hexagonal parent and those in the preexisting orthorhombic laths.The phenomenological crystallographic theory and experimental investigations prove that the pre-existing orthorhombic lath and generated orthorhombic martensite have the same crystallography relationship to the hexagonal parent.Therefore,the orthorhombic martensite can take these pre-existing laths as embryos and grow up.This work implies that the martensitic transformation in MnNiSi_(1-x)(CoNiGe)_(x) alloy is initiated by orthorhombic embryos.展开更多
Controlling the content of athermal martensite and retained austenite is important to improving the mechanical properties of high-strength steels,but a mechanism for the accurate description of martensitic transformat...Controlling the content of athermal martensite and retained austenite is important to improving the mechanical properties of high-strength steels,but a mechanism for the accurate description of martensitic transformation during the cooling process must be addressed.At present,frequently used semi-empirical kinetics models suffer from huge errors at the beginning of transformation,and most of them fail to exhibit the sigmoidal shape characteristic of transformation curves.To describe the martensitic transformation process accurately,based on the Magee model,we introduced the changes in the nucleation activation energy of martensite with temperature,which led to the varying nucleation rates of this model during martensitic transformation.According to the calculation results,the relative error of the modified model for the martensitic transformation kinetics curves of Fe-C-X(X = Ni,Cr,Mn,Si) alloys reached 9.5% compared with those measured via the thermal expansion method.The relative error was approximately reduced by two-thirds compared with that of the Magee model.The incorporation of nucleation activation energy into the kinetics model contributes to the improvement of its precision.展开更多
基金supported by the National Natural Science Foundation of China(Nos.12175231 and 11805131),Anhui Natural Science Foundation of China(No.2108085J05)Projects of International Cooperation and Exchanges NSFC(No.51111140389)the Collaborative Innovation Program of the Hefei Science Center,CAS(Nos.2021HSC-CIP020 and 2022HSCCIP009).
文摘Ferritic/martensitic(F/M)steel is widely used as a structural material in thermal and nuclear power plants.However,it is susceptible to intergranular damage,which is a critical issue,under service conditions.In this study,to improve the resistance to intergranular damage of F/M steel,a thermomechanical process(TMP)was employed to achieve a grain boundary engineering(GBE)microstructure in F/M steel P92.The TMP,including cold-rolling thickness reduction of 6%,9%,and 12%,followed by austenitization at 1323 K for 40 min and tempering at 1053 K for 45 min,was applied to the as-received(AR)P92 steel.The prior austenite grain(PAG)size,prior austenite grain boundary character distribution(GBCD),and connectivity of prior austenite grain boundaries(PAGBs)were investigated.Compared to the AR specimen,the PAG size did not change significantly.The fraction of coincident site lattice boundaries(CSLBs,3≤Σ≤29)and Σ3^(n) boundaries along PAGBs decreased with increasing reduction ratio because the recrystallization fraction increased with increasing reduction ratio.The PAGB connectivity of the 6%deformed specimen slightly deteriorated compared with that of the AR specimen.Moreover,potentiodynamic polarization studies revealed that the intergranular damage resistance of the studied steel could be improved by increasing the fraction of CSLBs along the PAGBs,indicating that the TMP,which involves low deformation,could enhance the intergranular damage resistance.
基金Supported by Natural Science Foundation Guidance Plan of Liaoning Province of China(Grant No.2019-ZD-0362)CAS Key Laboratory of Nuclear Materials and Safety Assessment,Institute of Metal Research,Chinese Academy of Sciences(Grant No.2021NMSAKF02).
文摘Microstructure and mechanical properties of GN9 Ferritic/Martensitic steel for sodium-cooled fast reactors have been investigated through orthogonal design and analysis.Scanning electron microscopy(SEM),transmission electron microscopy(TEM),differential scanning calorimeter(DSC),tensile and impact tests were used to evaluate the heat treatment parameters on yield strength,elongation and ductile-to-brittle transition temperature(DBTT).The results indicate that the microstructures of GN9 steel after orthogonal heat treatments consist of tempered martensite,M23C6,MX carbides and MX carbonitrides.The average prior austenite grains increase and the lath width decreases with the austenitizing temperature increasing from 1000°C to 1080°C.Tempering temperature is the most important factor that influences the dislocation evolution,yield strength and elongation compared with austenitizing tempera-ture and cooling methods.Austenitizing temperature,tempering temperature and cooling methods show interactive effects on DBTT.Carbide morphology and distribution,which is influenced by austenitizing and tempering tempera-tures,is the critical microstructural factor that influences the Charpy impact energy and DBTT.Based on the orthogo-nal design and microstructural analysis,the optimal heat treatment of GN9 steel is austenitizing at 1000°C for 0.5 h followed by air cooling and tempering at 760°C for 1.5 h.
基金the National Key Research and Development Program of China(No.2016YFB 0300600)the National Natural Science Foundation of China(NSFC)(No.51922026)+1 种基金the Fundamental Research Funds for the Central Universities(Nos.N2002013,N2002005,N2007011)the 111 Project(No.B20029).
文摘This review summarizes the strengthening mechanisms of reduced activation ferritic/martensitic(RAFM)steels.High-angle grain boundaries,subgrain boundaries,nano-sized M_(23)C_(6),and MX carbide precipitates effectively hinder dislocation motion and increase high-temperature strength.M23C6 carbides are easily coarsened under high temperatures,thereby weakening their ability to block dislocations.Creep properties are improved through the reduction of M23C6 carbides.Thus,the loss of strength must be compensated by other strengthening mechanisms.This review also outlines the recent progress in the development of RAFM steels.Oxide dispersion-strengthened steels prevent M23C6 precipitation by reducing C content to increase creep life and introduce a high density of nano-sized oxide precipitates to offset the reduced strength.Severe plastic deformation methods can substantially refine subgrains and MX carbides in the steel.The thermal deformation strengthening of RAFM steels mainly relies on thermo-mechanical treatment to increase the MX carbide and subgrain boundaries.This procedure increases the creep life of TMT(thermo-mechanical treatment)9Cr-1W-0.06Ta steel by~20 times compared with those of F82H and Eurofer 97 steels under 550℃/260 MPa.
文摘Recent accomplishment by the SWIP for the reduced activation ferritic/martensitic steel CLF-1 development has been reviewed. It＇s found that CLF- 1 steel has better room temperature tensile properties than Eurofer97 steel and has a fully martensitic microstructure.
基金Funded by the National Natural Science Foundation of China(No.91226203)
文摘Studies of synergetic irradiation effects and liquid lead-bismuth eutectic(LBE) corrosion/embrittlement effects on ferritic/martensitic(F/M) steels are of great importance for developing high power spallation neutron targets(>1 M W) such as the European Spallation Source(ESS) and Accelerator Driven System(ADS) facilities that can be used for transmuting long-lifetime radioactive wastes. Liquid LBE(45Pb-55Bi,in terms of mass fraction) has been selected as the candidate target material in high power spallation neutron targets due to its favourable thermal,physical & chemical properties,and to its high spallation neutron yield. 9Cr F/M steels such as T91(9Cr1M oVNb,in terms of mass fraction) have been chosen as the structural material for the targets due to their good mechanical properties and good resistance to irradiation induced swelling in fission neutron irradiation environments. For developing high power spallation neutron targets,behaviors of F/M steels in spallation neutron target irradiation environments and LBE corrosion/embrittlement effects have been extensively studied. However,many open questions have not been answered. The aim of this paper is to describe the present research situation on this topic. The obtained experimental data about LBE embrittlement effects on F/M steels is summarized and the influence of different parameters involved is analyzed to understand the influence effect on LBE embrittlement effect of F/M s.
文摘Reduced activation ferritic/martensitic steels (RAFM) are important candidate materials for future nuclear fusion reactors because of their high thermal conductivity, low thermal expansion rate and high resistance to void swelling. The influence of the accumulation of high concentration of helium via the（n, a）nuclear reaction on microstructures and macro-properties of the steels is an important issue limiting the service lifetime of the materials.
基金financially supported by the National Natural Science Foundation of China (Grant Nos.51325401 and U1660201)the National Magnetic Confinement Fusion Energy Research Project (Grant No.2015GB119001)
文摘In this study,the microstructures and mechanical properties of 9%Cr reduced activation ferritic/martensitic（RAFM） steel friction stir welded joints were investigated.When a W-Re tool is used,the recommended welding parameters are 300 rpm rotational speed,60 mm/min welding speed and10 kn axial force.In stir zone（SZ）,austenite dynamic recrystallization induced by plastic deformation and the high cooling rates lead to an obvious refinement of prior austenite grains and martensite laths.The microstructure in SZ contains lath martensite with high dislocation density,a lot of nano-sized MX and M3C phase particles,but almost no M23C6 precipitates.In thermal mechanically affect zone（TMAZ）and heat affect zone（HAZ）,refinement of prior austenite and martensitic laths and partial dissolution of M（23）C6 precipitates are obtained at relatively low rotational speed.However,with the increase of heat input,coarsening of martensitic laths,prior austenite grains,and complete dissolution of M23C6 precipitates are achieved.Impact toughness of SZ at-20℃ is slightly lower than that of base material（BM）,and exhibits a decreasing trend with the increase of rotational speed.
基金Project supported by the National Key Research and Development Program of China(2017YFB0702400)
文摘12Cr ferritic/martensitic steels with 0, 0.1 wt%, 0.2 wt% and 0.3 wt% theoretical yttrium(Y) additions were fabricated by vacuum inducting melting and casting method. Solubilities of Y in the 12Cr steels are0.027, 0.078 and 0.17 for 12Cr-0.1 Y, 12Cr-0.2 Y and 12Cr-0.3 Y, respectively. Phase transformations and microstructure characteristics under different heat-treatment schedules were investigated. The starting temperature of ferrite-to-austenite transformation A^(c1) are maintained about 850℃, but the finishing temperature of ferrite-to-austenite transformation A^(c3) are about 950, 970, 980 and 1000℃ for 12Cr-0 Y,12Cr-0.1 Y, 12Cr-0.2 Y and 12Cr-0.3 Y, respectively, which indicates that A^(c3) increases gradually with the addition of Y. Martensite accompanied with a few δ-ferrite is the dominant structure in all the steels. The amount of δ-ferrite shows a strong dependence with the Y content and austenitizing temperature. Area fraction of δ-ferrite increases with the content of Y, which is the ferrite favouring element. The minimum amount of δ-ferrite are achieved at 950℃ for 12Cr-0 Y, 12Cr-0.1 Y, 12Cr-0.2 Y and 1000℃ for 12Cr-0.3 Y.Besides, more carbides precipitate along the martensite laths and grain boundaries in the Y-bearing steel due to the redistribution of carbon between austenite and ferrite resulting from the ferrite favouring element of Y.
基金supported by "Excellent Scholar Funding" with the title of "R&D on advanced structural steels in new nuclear energy system" initialed by Institute for Materials Research, Chinese Academy (grant number: Y7A7A111A1)
文摘A high Si reduced activation ferritic/martensitic(RAFM) steel for nuclear structure application is successfully designed by using Calphad method. The main designed chemical composition is C 0.18–0.22%, Cr10.0–10.5%, W 1.0–1.5%, Si 1.0–1.3%, V+Ta 0.30–0.45%, and Fe in balance. High Si design brings excellent corrosion resistance, while low activation is advantageous in the nuclear waste processing. The experimental results indicate that the newly designed high Si RAFM steel had full martensitic structure and uniformly distributed fine second phase particles, and exhibited excellent mechanical properties and corrosion resistance. Compared to the P91 steel, this new RAFM steel designed by Calphad method is expected to be a promising candidate used in nuclear power generation, which also provides a new and effective approach to the development of RAFM steel for nuclear application.
基金Item Sponsored by National Basic Research Program(973 Program) of China (2007CB209800)
文摘Ferritic/martensitic steels with Cr of 9%-12% （in mass percent） are favourable candidates for fuel cladding tube and in-core components of supercritical water-cooled reactor. 9Cr-3WVTiTaN low activation ferritic/martensitic steel, designated as China Nuclear Steel- I （CNS- I ）, was patterned after T91 steel （modified 9Cr-lMo） for the reactor. The idea of low activation material and microalloy technology was introduced into the design of the steel. The hardening, tempering and transformation behaviour of CNS- I steel was investigated. The steel has advantages in tensile properties at elevated temperature relative to zircaloy that has been widely used as cladding material for conventional light water reactors. CNS- I steel exhibits tensile properties and impact toughness comparable to T91 steel which exhibits availability in the present fission reactors and fast breeder reactor but includes undesired radioactive elements such as molybdenum and niobium.
基金financially supported by the National Natural Science Foundation of China (No. 51874368)the Project of CAS Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences (No. 2018NMSAKF03)
文摘The hot deformation behavior and workability of a new reduced activation ferritic/martensitic steel named SIMP steel for accelerator-driven system were studied. The flow curve and its microstructure were studied at 900-1200 ℃ and strain rate range of 0.001-10 s^-1. The results showed that the deformation behavior of the SIMP steel during hot compression could be manifested by the Zener-Hollomon parameter in an exponent-type equation. Based on the obtained constitutive equation, the calculated flow stresses were in agreement with the experimentally measured ones, and the average activity energies Qdrv and QHw for the initiation of dynamic recrystallization and the peak strain were calculated to be 476.1 kJ/mol and 462.7 kJ/mol, respectively. Furthermore, based on the processing maps and microstructure evolution, the optimum processing condition for the SIMP steel was determined to be 1050-1200 ℃/0.001-0.1s^-1.
基金financially supported by the project 2018NMSAKF03 of CAS Key Laboratory of Nuclear Materials and Safety Assessment,Institute of Metal Research,Chinese Academy of SciencesKey fund from National Natural Science Foundation of China(No.U1832206)+1 种基金the National Key Research and Development Program of China(No.20180771-T-605)“Excellent Scholar Funding”initialed by Institute for Materials Research,Chinese Academy of Science(IMR-CAS)(No.JY7A7A111A1)。
文摘The oxidation behavior of two Ferritic/Martensitic(F/M)steels including novel SIMP steel and commercial P91 steel were investigated by exposure to flowing deaerated supercritical water(SCW)at 700℃for up to 1000 h.The kinetic weight gain curves follow parabolic and near-cubic rate equations for SIMP and P91 steels,respectively.X-Ray Diffraction analysis showed the presence of magnetite and a spinel phase in flowing SCW for both steels.The morphology and structure of the oxide scales formed on these two steels were analyzed.The relationship between the microstructure and oxidation behavior and the reason that SIMP steel showed better oxidation resistance than P91 steel were discussed.
基金financially supported by Key Program of National Natural Science Foundation of China (No. 51034011)ITER-National Magnetic Confinement Fusion Program (No.2011GB113001)National Science and Technology Major Project (No.2011ZX06004-009)
文摘Precipitates in an 11% Cr ferritic/martensitic steel containing Nd with tempering and creep conditions were investigated using transmission electron microscope with energy-dispersive X-ray spectroscopy. The precipitates in the steel with a tempering condition were identified to be Cr-rich M23C6 carbide, Nb-rich/V-rich/Ta–Nb-rich MX carbides, Nbrich MX carbonitride, and Fe-rich M5C2 carbide. Nd-rich carbonitride, which is not known to have been reported previously in steels, was also detected in the steel after tempering. Most of the Nb-rich MX precipitates were dissolved, whereas the amount of Ta-rich MX precipitates was increased significantly in the steel after a creep test at 600 °C at an applied stress of180 MPa for 1,100 h. No Fe2 W Laves phase has been detected in the steel after tempering.（Fe, Cr）2W Laves phase with a relatively large size was observed in the steel after the creep test.
文摘Helium ion irradiation at 350℃was performed to study equilibrium segregation and radiation-induced segregation(RIS)of Cr at grain boundaries in reduced activation ferritic/martensitic steels.Cr concentration at grain boundary was measured by scanning transmission electron microscopy with an energy-dispersive spectrometer.The measured Cr concentration at grain boundaries in heat treated zone was 11.7 and 12.8 wt.%in irradiated zone,respectively,which matched well to the calculated results from Mclean and modified Perk model.Equilibrium segregation and RIS of Cr mechanisms were theoretically analysed.The analysis indicates that as temperature rises,equilibrium Cr segregation decreases monotoni-cally,while RIS of Cr has a bell-shape profile,which increases first and then decreases.It is also shown that at low and high temperatures,equilibrium segregation of Cr is higher than that of RIS;at intermediate temperatures,equilibrium Cr segregation is lower than RIS.
基金Item Sponsored by National Basic Research Program of China(2007CB209800)
文摘The corrosion behaviors of CNS-I and modified CNS-II were evaluated by exposing to superciritical water （SCW） at 550℃ and 25 MPa with a dissolved oxygen concentration of 200× 10 ^-9 for up to 1 000 h. Detailed corrosion results of these two alloys were provided, including the growth rate of the oxide scales, microstructure of the oxide scales, distribution of phases and alloying elements. The mass gains of CNS-I and modified CNS-II were 609.73 mg/dm2 and 459.42 mg/dm2 , respectively, after exposing to SCW for 1 000 h. A duplex oxide scale with an outer porous magnetite layer and an inner relatively dense magnetite/spinel-mixed layer was identified on CNS-I and modified CNS-II after the test. The oxide scales were rather porous at the beginning of the test but the porosity decreased with increase of the exposure duration. It was found that Fe was enriched in the outer oxide layer, Cr was enriched in the inner oxide layer and O existed at a very high concnetration in the whole oxide scale. Other alloying elements such as Mo, W, Mn were depleted from the outer oxide layer and showed slightly enrichment in the inner oxide layer. The distributution of Ni was different from other elements, it was enriched in the interface bewteen the base metal and the oxide scale and depleted in the outer and inner oxide layers.
基金Supported by Youth Elite Project of CNNC and Modular HTGR Super-critical Power Generation Technology Collaborative Project between CNNC and Tsinghua University Project of China(Grant No.ZHJTIZYFGWD20201).
文摘For dissimilar metal welds(DMWs)involving nickel-based weld metal(WM)and ferritic heat resistant steel base metal(BM)in power plants,there must be an interface between WM and BM,and this interface suffers mechanical and microstructure mismatches and is often the rupture location of premature failure.In this study,a new form of WM/BM interface form,namely double Y-type interface was designed for the DMWs.Creep behaviors and life of DMWs containing double Y-type interface and conventional I-type interface were compared by finite element analysis and creep tests,and creep failure mechanisms were investigated by stress-strain analysis and microstructure characterization.By applying double Y-type interface instead of conventional I-type interface,failure location of DMW could be shifted from the WM/ferritic heat-affected zone(HAZ)interface into the ferritic HAZ or even the ferritic BM,and the failure mode change improved the creep life of DMW.The interface premature failure of I-type interface DMW was related to the coupling effect of microstructure degradation,stress and strain concentrations,and oxide notch on the WM/HAZ interface.The creep failure of double Y-type interface DMW was the result of Type IV fracture due to the creep voids and micro-cracks on fine-grain boundaries in HAZ,which was a result of the matrix softening of HAZ and lack of precipitate pinning at fine-grain boundaries.The double Y-type interface form separated the stress and strain concentrations in DMW from the WM/HAZ interface,preventing the trigger effect of oxide notch on interface failure and inhibiting the interfacial microstructure cracking.It is a novel scheme to prolong creep life and enhance reliability of DMW,by means of optimizing the interface form,decoupling the damage factors from WM/HAZ interface,and then changing the failure mechanism and shifting the failure location.
基金This work was supported by the National Key Research and Development Program of China(2017YFB0702400).
文摘Advanced oxide metallurgy technique was adopted to produce 100-kg Y-bearing 12Cr ferritic/martensitic steel via vacuum induction melting and casting route. Subsequently, nine specimens at top, middle and bottom regions of the sheet were char-acterized to evaluate the homogeneity of chemical composition, microstructure and mechanical properties. The small vibra-tion of hardness (200–220 HBW), ultimate tensile strength (672–678 MPa), yield strength (468–480 MPa), total elongation (26.2%–30.5%) and Charpy energy at room temperature (98–133 J) and at ??40 ℃ (12–40 J) demonstrated that mechanical properties’ homogeneity of Y-bearing steel was acceptable although slight Y segregation and inhomogeneous microstructure occurred at the bottom. Furthermore, the effect of Y content on microstructure characteristics and mechanical properties was explained and the comparison of failure mechanism for the dual-phase steel between tensile test (i.e., quasi-static loading) and Charpy test (i.e., dynamic loading) was discussed in detail.
基金supported by the special fund for introduced talent to initiate scientific research in Nanjing Tech Universitythe National Natural Science Foundation of China(Grant Nos.52088101 and 52325201)the National Key Research and Development Program of China(Grant No.2023YFA1607400)。
文摘Taking Pd_(2)MnTi as a representative example,we systematically investigate and theoretically reveal the electronic structure evolution during martensitic phase transition in all-d-metal Heusler compounds.The calculation and theoretical analysis suggest that Pd_(2)MnTi is not stable in cubic structure and prone to transform to lowsymmetric tetragonal structure.By tetragonal deformation,the shrinkage of lattice parameters and the decrease of symmetry promote the electron accumulation between Pd and its first nearest neighboring Ti atom,resulting in the increasing covalent hybridization.The occurrence of pseudogap in density of states of tetragonal Pd_(2)MnTi near the Fermi level also verifies the enhancement of covalent bond.Comparatively,the stronger interatomic bond in tetragonal Pd_(2)MnTi,i.e.,covalent bond here,would strengthen interatomic coupling and consequently lower the energy of the material.By the martensitic phase transition,more stable states in energy are achieved.Thus,based on the analysis of electronic structure evolution,the nature of martensitic phase transition is a process wherein symmetry breaking weakens the original weak chemical bonds in high-symmetric parent phase and induces the strong chemical bond to lower the energy of the materials and to achieve a more stable state.This study could help to deepen the understanding of martensitic phase transition and the exploration of novel materials for potential technical applications.
基金Project supported by the National Natural Science Foundation of China (Grant No.11974184)。
文摘The thermal-elastic martensitic transformation from high-temperature Ni_(2)In-type hexagonal structure to low-temperature TiNiSi-type orthorhombic structure has been widely studied in MnMX(M=Ni or Co,and X=Ge or Si)alloys.However,the answer to how the orthorhombic martensite nucleates and grows within the hexagonal parent is still unclear.In this work,the hexagonal-orthorhombic martensitic transformation in a Co and Ge co-substituted MnNiSi is investigated.One can find some orthorhombic laths embedded in the hexagonal parent at a temperature above the martensitic transformation start temperature(M_(s)).With the the sample cooing to M_(s),the laths turn broader,indicating that the martensitic transformation starts from these pre-existing orthorhombic laths.Microstructure observation suggests that these pre-existing orthorhombic laths do not originate from the hexagonal-orthorhombic martensitic transformation because of the difference between atomic occupations of doping elements in the hexagonal parent and those in the preexisting orthorhombic laths.The phenomenological crystallographic theory and experimental investigations prove that the pre-existing orthorhombic lath and generated orthorhombic martensite have the same crystallography relationship to the hexagonal parent.Therefore,the orthorhombic martensite can take these pre-existing laths as embryos and grow up.This work implies that the martensitic transformation in MnNiSi_(1-x)(CoNiGe)_(x) alloy is initiated by orthorhombic embryos.
基金financially supported by the National Natural Science Foundation of China(No.U2102212)the Shanghai Rising-Star Program(No.21QA1403200)。
文摘Controlling the content of athermal martensite and retained austenite is important to improving the mechanical properties of high-strength steels,but a mechanism for the accurate description of martensitic transformation during the cooling process must be addressed.At present,frequently used semi-empirical kinetics models suffer from huge errors at the beginning of transformation,and most of them fail to exhibit the sigmoidal shape characteristic of transformation curves.To describe the martensitic transformation process accurately,based on the Magee model,we introduced the changes in the nucleation activation energy of martensite with temperature,which led to the varying nucleation rates of this model during martensitic transformation.According to the calculation results,the relative error of the modified model for the martensitic transformation kinetics curves of Fe-C-X(X = Ni,Cr,Mn,Si) alloys reached 9.5% compared with those measured via the thermal expansion method.The relative error was approximately reduced by two-thirds compared with that of the Magee model.The incorporation of nucleation activation energy into the kinetics model contributes to the improvement of its precision.
