The technology for spraying a sintering bed and thus improving sinter quality indicators while reducing the emission of flue gas pollutants has recently become an important research topic.The impacts on sinter quality...The technology for spraying a sintering bed and thus improving sinter quality indicators while reducing the emission of flue gas pollutants has recently become an important research topic.The impacts on sinter quality and emissions when spraying the sintering surface with different amounts and flow rates of steam were investigated in this study.The sinter quality indicators were most effectively improved by spraying 180 g of steam flow continuously at a rate of 0.02 m^(3)/min for 15 min after ignition for 8 min.The optimal effect on emission reduction was obtained by spraying 90 g of steam flow continuously at a rate of 0.01 m^(3)/min for 15 min after ignition for 8 min.展开更多
Supercritical carbon dioxide(S-CO_(2))Brayton power cycle power generation technology,has attracted more and more scholars'attention in recent years because of its advantages of high efficiency and flexibility.Com...Supercritical carbon dioxide(S-CO_(2))Brayton power cycle power generation technology,has attracted more and more scholars'attention in recent years because of its advantages of high efficiency and flexibility.Compared with conventional steam boilers,S-CO_(2) has different heat transfer characteristics,it is easy to cause the temperature of the cooling wall of the boiler to rise,which leads to higher combustion gas temperature in the furnace,higher NOX generation concentration.The adoption of flue gas recirculation has a significance impact on the combustion process of pulverized coal in the boiler,and it is the most effective ways to reduce the emission of NOX and the combustion temperature in the boiler.This paper takes 1000MW S-CO_(2) T-type coal-fired boiler as the research target to investigate the combustion and NOX generation characteristics of S-CO_(2) coal-fired boilers under flue gas recirculation condition,the influence of recirculated flue gas distribution along the furnace height on the characteristics of NOX formation and the combustion of pulverized coal.The results show that the recirculated flue gas distribution has the great impact on the concentration of NOX at the boiler outlet.When the bottom recirculation flue gas rate is gradually increased,the average temperature of the lower boiler decreases and the average temperature of the upper boiler increases slightly;The concentration of NOx at the furnace outlet increases.展开更多
In order to investigate the factual air pollutant emissions from Henan’s power sector in 2010, SO2, NOx and PM emissions from 24 generating sets from 15 coal-fired power plants have been measured. It is shown that SO...In order to investigate the factual air pollutant emissions from Henan’s power sector in 2010, SO2, NOx and PM emissions from 24 generating sets from 15 coal-fired power plants have been measured. It is shown that SO2 emission values from 22 of 24 generating sets conform to the requirements, which is causing by the high performance of the flue gas desulfurization system. Much higher NOx emissions indicate that the construction of flue gas denitrition systems is necessary. PM emissions varied from 2.3 kg to 299.9 kg per hour. Total sulfur, moisture, ash and volatile content, and net caloric value of coals were investigated to elucidate the relationship between coals and air pollutant emissions.展开更多
HTAC (High Temperature Air Combustion) technology needs high temperature air and low oxygen atmosphere to complete its unique combustion and achieve extra low NOx production. In order to apply HTAC technology to forge...HTAC (High Temperature Air Combustion) technology needs high temperature air and low oxygen atmosphere to complete its unique combustion and achieve extra low NOx production. In order to apply HTAC technology to forge furnace and meet the NOx emission standard, exhaust gas regeneration technology in combination with no-fuel-switch and U-shape air circulation methods was applied on forge furnace. The results show that extra low NOx emission (NOx 2.9× 10-5, in volume fraction) could be obtained, the NOx emission meets the standards of Japan and US, HTAC mechanism is discussed finally.展开更多
In most of the world’s building material industries,the control of flue gas pollutants mainly focuses on a single pollutant.However,given the large capacity and high contribution of China’s building materials indust...In most of the world’s building material industries,the control of flue gas pollutants mainly focuses on a single pollutant.However,given the large capacity and high contribution of China’s building materials industry to global air pollution,the need to develop multipollutant emission reduction technology is urgent.Recently,China has focused on reducing the emissions of flue gas pollutants in the building materials industry,established many key research and development projects,and gradually implemented more stringent pollutant emission limits.This project focuses on the most recent advances in flue gas emission control technology in China’s building materials industry,including denitration,dust removal,desulfurization,synergistic multi-pollutant emission reduction,and the construction of pilot research and demonstration projects for pollutant removal in several building material industries.On this basis,revised pollutant limits in flue gas emitted in China’s building material industry are proposed.展开更多
Pyrolysis of biomass followed by combustion of pyrolytic vapors to replace fossil fuels is an economic low-carbon solution.However,the polycyclic aromatic hydrocarbons and N-containing species in biomass pyrolysis vap...Pyrolysis of biomass followed by combustion of pyrolytic vapors to replace fossil fuels is an economic low-carbon solution.However,the polycyclic aromatic hydrocarbons and N-containing species in biomass pyrolysis vapors result in the soot and NO emissions.The flue gas recirculation(FGR)technology,having the potential to reduce the soot and NO emissions,was introduced to the biomass pyrolysis-combustion system.In addition,it was numerically studied by simulating the biomass pyrolysis vapors based co-flow diffusion flames with CO_(2)addition.Both the experimental and simulated results showed that the FGR had significant suppression effects on the soot formation.When the FGR ratio(i.e.,CO_(2)addition ratio)increased from 0%to 15%,the experimental and simulated soot volume fraction respectively decreased by 32%and 21%,which verified the models used in this study.The decrease in OH concentration caused by the CO_(2)addition was responsible for the decrease in the decomposition rate of A2(A2+OH=A2–+H_(2)O).Hence,more benzo(ghi)fluoranthene(BGHIF)was generated through A1C_(2)H–+A2→BGHIF+H_(2)+H,leading to the increase in inception rate.The decrease in benzo(a)pyrene(BAPYR)concentration was the major factor in the decrease in soot condensation rate.Moreover,the decrease in the C_(2)H_(2) and OH concentrations was responsible for the decrease in the HACA surface growth rate.Furthermore,the simulated results showed that the NO concentration decreased by 0.4%when the content of CO_(2)was increased by 1 vol.%.The decrease in OH concentration suppressed the NO formation via decreasing reaction rates of N+OH=NO+H and HNO+OH=NO+H_(2)O and enhanced the NO consumption via increasing reaction rate of HO_(2)+NO=NO_(2)+OH.展开更多
Selective catalytic reduction(SCR) denitration may increase the emission of NH4+and NH3.The removal and transformation characteristics of ammonium sulfate aerosols and ammonia slip during the wet flue gas desulfurizat...Selective catalytic reduction(SCR) denitration may increase the emission of NH4+and NH3.The removal and transformation characteristics of ammonium sulfate aerosols and ammonia slip during the wet flue gas desulfurization(WFGD) process, as well as the effect of desulfurization parameters, were investigated in an experimental system equipped with a simulated SCR flue gas generation system and a limestone-based WFGD system.The results indicate that the ammonium sulfate aerosols and ammonia slip in the flue gas from SCR can be partly removed by slurry scrubbing, while the entrainment and evaporation of desulfurization slurry with accumulated NH4+will generate new ammoniumcontaining particles and gaseous ammonia.The ammonium-containing particles formed by desulfurization are not only derived from the entrainment of slurry droplets, but also from the re-condensation of gaseous ammonia generated by slurry evaporation.Therefore,even if the concentration of NH4+in the desulfurization slurry is quite low, a high level of NH4+was still contained in the fine particles at the outlet of the scrubber.When the accumulated NH4+in the desulfurization slurry was high enough, the WFGD system promoted the conversion of NH3 to NH4+and increased the additional emission of primary NH4+aerosols.With the decline of the liquid/gas ratio and flue gas temperature, the removal efficiency of ammonia sulfate aerosols increased, and the NH4+emitted from entrainment and evaporation of the desulfurization slurry decreased.In addition, the volatile ammonia concentration after the WFGD system was reduced with the decrease of the NH4+concentration and p H values of the slurry.展开更多
The flue gas pollutants deep-removal technology(DRT) focusing on PM2.5removal is the prime method of further reducing pollutants emission from coal-fired power plants. In view of the four key technological challenges ...The flue gas pollutants deep-removal technology(DRT) focusing on PM2.5removal is the prime method of further reducing pollutants emission from coal-fired power plants. In view of the four key technological challenges in developing the DRT, studies were conducted on a series of purification technologies and the DRT was developed and successfully applied in 660 MW and 1000 MW coal-fired units. This paper analyzes the application results of the demonstration project, and proposes a roadmap for the follow-up researches and optimizations.展开更多
文摘The technology for spraying a sintering bed and thus improving sinter quality indicators while reducing the emission of flue gas pollutants has recently become an important research topic.The impacts on sinter quality and emissions when spraying the sintering surface with different amounts and flow rates of steam were investigated in this study.The sinter quality indicators were most effectively improved by spraying 180 g of steam flow continuously at a rate of 0.02 m^(3)/min for 15 min after ignition for 8 min.The optimal effect on emission reduction was obtained by spraying 90 g of steam flow continuously at a rate of 0.01 m^(3)/min for 15 min after ignition for 8 min.
基金This paper is supported by the National Key R&D Program of China(2017YFB0601805).
文摘Supercritical carbon dioxide(S-CO_(2))Brayton power cycle power generation technology,has attracted more and more scholars'attention in recent years because of its advantages of high efficiency and flexibility.Compared with conventional steam boilers,S-CO_(2) has different heat transfer characteristics,it is easy to cause the temperature of the cooling wall of the boiler to rise,which leads to higher combustion gas temperature in the furnace,higher NOX generation concentration.The adoption of flue gas recirculation has a significance impact on the combustion process of pulverized coal in the boiler,and it is the most effective ways to reduce the emission of NOX and the combustion temperature in the boiler.This paper takes 1000MW S-CO_(2) T-type coal-fired boiler as the research target to investigate the combustion and NOX generation characteristics of S-CO_(2) coal-fired boilers under flue gas recirculation condition,the influence of recirculated flue gas distribution along the furnace height on the characteristics of NOX formation and the combustion of pulverized coal.The results show that the recirculated flue gas distribution has the great impact on the concentration of NOX at the boiler outlet.When the bottom recirculation flue gas rate is gradually increased,the average temperature of the lower boiler decreases and the average temperature of the upper boiler increases slightly;The concentration of NOx at the furnace outlet increases.
文摘In order to investigate the factual air pollutant emissions from Henan’s power sector in 2010, SO2, NOx and PM emissions from 24 generating sets from 15 coal-fired power plants have been measured. It is shown that SO2 emission values from 22 of 24 generating sets conform to the requirements, which is causing by the high performance of the flue gas desulfurization system. Much higher NOx emissions indicate that the construction of flue gas denitrition systems is necessary. PM emissions varied from 2.3 kg to 299.9 kg per hour. Total sulfur, moisture, ash and volatile content, and net caloric value of coals were investigated to elucidate the relationship between coals and air pollutant emissions.
文摘HTAC (High Temperature Air Combustion) technology needs high temperature air and low oxygen atmosphere to complete its unique combustion and achieve extra low NOx production. In order to apply HTAC technology to forge furnace and meet the NOx emission standard, exhaust gas regeneration technology in combination with no-fuel-switch and U-shape air circulation methods was applied on forge furnace. The results show that extra low NOx emission (NOx 2.9× 10-5, in volume fraction) could be obtained, the NOx emission meets the standards of Japan and US, HTAC mechanism is discussed finally.
基金supported by the National Key Research and Development Program of China(No.2017YFC0210700)。
文摘In most of the world’s building material industries,the control of flue gas pollutants mainly focuses on a single pollutant.However,given the large capacity and high contribution of China’s building materials industry to global air pollution,the need to develop multipollutant emission reduction technology is urgent.Recently,China has focused on reducing the emissions of flue gas pollutants in the building materials industry,established many key research and development projects,and gradually implemented more stringent pollutant emission limits.This project focuses on the most recent advances in flue gas emission control technology in China’s building materials industry,including denitration,dust removal,desulfurization,synergistic multi-pollutant emission reduction,and the construction of pilot research and demonstration projects for pollutant removal in several building material industries.On this basis,revised pollutant limits in flue gas emitted in China’s building material industry are proposed.
基金supported by the National Natural Science Foundation of China(Grant Nos.52276185,52276189,and 51976057)the Science and Technology Innovation Program of Hunan Province(Grant No.2020RC5008)the Fundamental Research Funds for the Central Universities(Grant No.2020DF01)。
文摘Pyrolysis of biomass followed by combustion of pyrolytic vapors to replace fossil fuels is an economic low-carbon solution.However,the polycyclic aromatic hydrocarbons and N-containing species in biomass pyrolysis vapors result in the soot and NO emissions.The flue gas recirculation(FGR)technology,having the potential to reduce the soot and NO emissions,was introduced to the biomass pyrolysis-combustion system.In addition,it was numerically studied by simulating the biomass pyrolysis vapors based co-flow diffusion flames with CO_(2)addition.Both the experimental and simulated results showed that the FGR had significant suppression effects on the soot formation.When the FGR ratio(i.e.,CO_(2)addition ratio)increased from 0%to 15%,the experimental and simulated soot volume fraction respectively decreased by 32%and 21%,which verified the models used in this study.The decrease in OH concentration caused by the CO_(2)addition was responsible for the decrease in the decomposition rate of A2(A2+OH=A2–+H_(2)O).Hence,more benzo(ghi)fluoranthene(BGHIF)was generated through A1C_(2)H–+A2→BGHIF+H_(2)+H,leading to the increase in inception rate.The decrease in benzo(a)pyrene(BAPYR)concentration was the major factor in the decrease in soot condensation rate.Moreover,the decrease in the C_(2)H_(2) and OH concentrations was responsible for the decrease in the HACA surface growth rate.Furthermore,the simulated results showed that the NO concentration decreased by 0.4%when the content of CO_(2)was increased by 1 vol.%.The decrease in OH concentration suppressed the NO formation via decreasing reaction rates of N+OH=NO+H and HNO+OH=NO+H_(2)O and enhanced the NO consumption via increasing reaction rate of HO_(2)+NO=NO_(2)+OH.
基金supported by the National Natural Science Foundation of China(Nos.51576039 and 51576039).
文摘Selective catalytic reduction(SCR) denitration may increase the emission of NH4+and NH3.The removal and transformation characteristics of ammonium sulfate aerosols and ammonia slip during the wet flue gas desulfurization(WFGD) process, as well as the effect of desulfurization parameters, were investigated in an experimental system equipped with a simulated SCR flue gas generation system and a limestone-based WFGD system.The results indicate that the ammonium sulfate aerosols and ammonia slip in the flue gas from SCR can be partly removed by slurry scrubbing, while the entrainment and evaporation of desulfurization slurry with accumulated NH4+will generate new ammoniumcontaining particles and gaseous ammonia.The ammonium-containing particles formed by desulfurization are not only derived from the entrainment of slurry droplets, but also from the re-condensation of gaseous ammonia generated by slurry evaporation.Therefore,even if the concentration of NH4+in the desulfurization slurry is quite low, a high level of NH4+was still contained in the fine particles at the outlet of the scrubber.When the accumulated NH4+in the desulfurization slurry was high enough, the WFGD system promoted the conversion of NH3 to NH4+and increased the additional emission of primary NH4+aerosols.With the decline of the liquid/gas ratio and flue gas temperature, the removal efficiency of ammonia sulfate aerosols increased, and the NH4+emitted from entrainment and evaporation of the desulfurization slurry decreased.In addition, the volatile ammonia concentration after the WFGD system was reduced with the decrease of the NH4+concentration and p H values of the slurry.
文摘The flue gas pollutants deep-removal technology(DRT) focusing on PM2.5removal is the prime method of further reducing pollutants emission from coal-fired power plants. In view of the four key technological challenges in developing the DRT, studies were conducted on a series of purification technologies and the DRT was developed and successfully applied in 660 MW and 1000 MW coal-fired units. This paper analyzes the application results of the demonstration project, and proposes a roadmap for the follow-up researches and optimizations.
