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Tracking gassing behavior in pouch cell by operando on-line electrochemical mass spectrometry
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作者 Haitang Zhang Jianken Chen +10 位作者 Baodan Zhang Xiaohong Wu Zhengang Li Leiyu Chen Junhao Wang Xiaoyu Yu Haiyan Luo Jiyuan Xue Yu-Hao Hong Yu Qiao Shi-Gang Sun 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第9期286-291,共6页
As the rapid development of more powerful and safer lithiumion batteries, the mechanism study of gases evolution is attacking more and more attention in recent years. Especially under overcharge/discharge and/or high-... As the rapid development of more powerful and safer lithiumion batteries, the mechanism study of gases evolution is attacking more and more attention in recent years. Especially under overcharge/discharge and/or high-temperature working condition. 展开更多
关键词 Pouch cell Operando characterization Mass spectrometry Lithium-ion batteries gassing behavior
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基于Gassing模型的锂电池SOC估计与参数辨识
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作者 周苏 胡哲 +1 位作者 王章保 陈凤祥 《电源技术》 CAS CSCD 北大核心 2011年第12期1507-1510,共4页
具有非线性、时变性的Gassing锂电池模型具有以下两大特点:模型考虑了析气现象,使其适用范围拓广到SOC>85%的临界情况;模型考虑了温度的动态变化对系统状态变量的影响。针对该模型,基于相关的试验数据,采用双Kalman滤波算法(DKF),同... 具有非线性、时变性的Gassing锂电池模型具有以下两大特点:模型考虑了析气现象,使其适用范围拓广到SOC>85%的临界情况;模型考虑了温度的动态变化对系统状态变量的影响。针对该模型,基于相关的试验数据,采用双Kalman滤波算法(DKF),同时实现了对模型参数的辨识和对SOC的在线估计。台架试验和实车验证表明,该算法在非临界情况和临界情况下均可以较准确地在线估计SOC(估计误差在4%以内),并且对SOC的初值误差具有较好的鲁棒性。 展开更多
关键词 锂电池gassing模型 参数辨识 SOC估计 双Kalman滤波
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Influence of the gassing materials on the dielectric properties of air 被引量:2
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作者 张含天 厉天威 +4 位作者 罗兵 吴翊 杨飞 孙昊 唐力 《Plasma Science and Technology》 SCIE EI CAS CSCD 2017年第5期68-73,共6页
Influence of the gassing materials, such as PA6, PMMA, and POM on the dielectric properties of air are investigated. In this work, the fundamental electron collision cross section data were carefully selected and vali... Influence of the gassing materials, such as PA6, PMMA, and POM on the dielectric properties of air are investigated. In this work, the fundamental electron collision cross section data were carefully selected and validated. Then the species compositions of the air–organic vapor mixtures were calculated based on the Gibbs free energy minimization. Finally, the Townsend ionization coefficient, the Townsend electron attachment coefficient and the critical reduced electric field strength were derived from the calculated electron energy distribution function by solving the Boltzmann transport equation. The calculation results indicated that H;O with large attachment cross sections has a great impact on the critical reduced electric field strength of the air–organic vapor mixtures. On the other hand, the vaporization of gassing materials can help to increase the dielectric properties of air circuit breakers to some degree. 展开更多
关键词 air circuit breaker gassing materials Boltzmann equation analysis dielectric properties EEDF critical reduced electric field strength electron collision cross section
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Experimental Study of the Influence of Gassing Material on Blow Open Force and Arc Motion
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作者 李兴文 陈德桂 +2 位作者 刘洪武 史宗谦 王建华 《Plasma Science and Technology》 SCIE EI CAS CSCD 2007年第6期657-660,共4页
The study of arc behavior is important to understand the dynamic phenomena concerning the interruption process in a variety of switching devices. This paper is devoted to investigate the influence of gassing material ... The study of arc behavior is important to understand the dynamic phenomena concerning the interruption process in a variety of switching devices. This paper is devoted to investigate the influence of gassing material on blow open force and arc motion. To one double- breaker model, measuring the arc current, voltage and force acting on the moving conductor, the characteristics of the ratio of the emerging blow open force over arc power FB/(ui) could be obtained. With the help of a 2-D optical fiber measurement system, to one arc chamber model, arc motion behavior was measured, too. It is demonstrated that, with the action of gassing material, FB/(ui) will increase 2.5 times, and the arc will enter the splitter plates much easier. 展开更多
关键词 circuit breaker gassing material blow open force arc motion
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基于积分变换的锂电池系统建模 被引量:1
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作者 周苏 王章保 +1 位作者 陈凤祥 胡哲 《电源技术》 CAS CSCD 北大核心 2013年第7期1136-1139,1232,共5页
Gassing锂电池模型考虑了电化学反应的析气和温度影响,描述了锂电池系统的非线性时变特性,使模型的适用范围拓广至SOC>85%的临界情况。通过积分变换,用能量状态W0代替原状态变量开路电压U0,将表征锂电池重要特性的SOC-OCV曲线转换成S... Gassing锂电池模型考虑了电化学反应的析气和温度影响,描述了锂电池系统的非线性时变特性,使模型的适用范围拓广至SOC>85%的临界情况。通过积分变换,用能量状态W0代替原状态变量开路电压U0,将表征锂电池重要特性的SOC-OCV曲线转换成SOC-W0曲线,同时进一步考虑了倍率充放电效应,提出了改进型Gassing模型。仿真结果表明,改进型Gassing模型不仅能适用于SOC-OCV曲线中间区域平坦的磷酸铁锂电池,还进一步提高了模型的仿真精度及SOC计算的合理性和有效性。 展开更多
关键词 改进型gassing模型 积分变换 荷电状态 系统仿真
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锂离子电池系统建模仿真 被引量:2
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作者 杨洋 肖凯旋 周苏 《佳木斯大学学报(自然科学版)》 CAS 2015年第1期54-58,共5页
动力电池测试是动力电池研究的基础,而建立和选择合适准确的电池模型对于电池管理系统开发具有重要意义.为了解决电动汽车仿真时电池模型选取的问题,分别系统的建立了Thevenin模型,Gassing模型以及AVL电池模型,其中,Thevenin模型和AVL... 动力电池测试是动力电池研究的基础,而建立和选择合适准确的电池模型对于电池管理系统开发具有重要意义.为了解决电动汽车仿真时电池模型选取的问题,分别系统的建立了Thevenin模型,Gassing模型以及AVL电池模型,其中,Thevenin模型和AVL电池模型实质上分别为一阶等效电路模型和三阶等效电路模型,而Gassing模型是一种半机理半经验模型.三种模型在非极限工况下,都具有较高的精度,Thevenin模型和AVL电池能够更加准确地描述电池极化环节,AVL电池模型和Gassing模型在剧烈变化工况下误差很小,而Gassing模型能够很好地描述电池在极限工况下的动态特性,且可以反映出温度与内阻的动态变化. 展开更多
关键词 锂离子电池 系统建模 Thevenin模型 gassing模型 AVL电池模型
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便携式烟气监测样气处理系统在燃煤电厂“超低排放”中的应用研究 被引量:6
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作者 宋钊 陈晓婷 李峰 《分析仪器》 CAS 2016年第5期41-47,共7页
在燃煤电厂“超低排放”工况下,便携式SO2分析仪对高湿、低温、低SO2烟气的监测面临很大的挑战,主要是如何有效去除烟气中的水汽,而又不影响低量程SO2的准确分析。Nafion干燥管是唯一气态膜式除湿并保持大多数待测烟气组分不流失的先进... 在燃煤电厂“超低排放”工况下,便携式SO2分析仪对高湿、低温、低SO2烟气的监测面临很大的挑战,主要是如何有效去除烟气中的水汽,而又不影响低量程SO2的准确分析。Nafion干燥管是唯一气态膜式除湿并保持大多数待测烟气组分不流失的先进技术,使烟气处理后的烟气露点突破+(2~4)℃极限、达到0℃露点乃至于-20℃低露点的唯一独特技术,可应用于“超低放”CEMS的样气处理除湿处理。以Nafion管为核心的便携式GASS-35烟气样气处理系统,通过和便携式电化学分析仪及NDIR分析仪的试验室内配合测试研究后,已成功应用于便携式的现场手工监测,可满足“超低排放”条件下高湿度、低量程SO2的准确监测要求,为稳定、准确的现场手工监测高湿度(〉10%V/V)、低烟温(〈50℃且无GGH)、低SO2浓度(〈35mg/Nm3)烟气提供了一种可行的技术方案。 展开更多
关键词 超低排放 Nafion干燥管 便携式电化学分析仪 便携式NDIR分析仪 GASS系统手工监测
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Nafion干燥器GASS处理系统在“超低排放”CEMS中的工程应用研究 被引量:22
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作者 蒋雄杰 李峰 《分析仪器》 CAS 2015年第3期26-33,共8页
燃煤电厂在推广"超低排放"CEMS气态污染物监测系统监测低量程SO2和NOx中,低温、高湿度的烟气条件是极为严峻的挑战。Nafion干燥管独特的气态膜除湿、能保留目标气体的特点,为冷干直抽法CEMS提出了一个样气处理的新方案。Nafio... 燃煤电厂在推广"超低排放"CEMS气态污染物监测系统监测低量程SO2和NOx中,低温、高湿度的烟气条件是极为严峻的挑战。Nafion干燥管独特的气态膜除湿、能保留目标气体的特点,为冷干直抽法CEMS提出了一个样气处理的新方案。Nafion管为核心的GASS样气处理系统,集絮凝过滤、除酸雾、Nafion管干燥和在线酸性气体露点监测为一体,可彻底解决冷干直抽法CEMS中冷凝水析出和低量程SO2易溶于冷凝水的难题,是一种创新的冷干直取法CEMS样气处理技术。通过实验室试验,手持式CEMS应用实验,和嘉兴发电厂8号机组"超低排放"CEMS的应用,证明GASS样气处理系统非常适合在燃煤电厂"超低排放"CEMS中应用。 展开更多
关键词 GASS处理系统 冷干直抽法 CEMS 燃煤电厂 超低排放 Nafion干燥管
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Simulation of the Effects of Several Factors on Arc Plasma Behavior in Low Voltage Circuit Breaker 被引量:7
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作者 李兴文 陈德桂 +1 位作者 汪倩 李志鹏 《Plasma Science and Technology》 SCIE EI CAS CSCD 2005年第5期3069-3072,共4页
Taking into account the properties of the arc plasma and the electromagnetic, heat and radiative phenomena, commercial computational fluid dynamics software PHOENICS has been adapted and modified to develop the three-... Taking into account the properties of the arc plasma and the electromagnetic, heat and radiative phenomena, commercial computational fluid dynamics software PHOENICS has been adapted and modified to develop the three-dimensional magneto-hydrodynamic (MHD) model of arc in a low voltage circuit breaker. The effects of the arc ignition location, venting size and gassing material on arc behavior have been investigated. The analysis of the results show that the arc velocity accelerates with the increase in the distance between arc ignition location and of the venting size, and the existence of the gassing material is beneficial to improving the arc voltage and reducing the arc temperature. 展开更多
关键词 arc model VENTING gassing material
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基于GASS烟气测试系统的SCR喷氨优化调整试验研究 被引量:1
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作者 鲍强 何金亮 +6 位作者 王建阳 金理鹏 卢承政 周健 梁俊杰 顾江峰 张庆文 《锅炉技术》 北大核心 2021年第5期65-71,共7页
基于网格化快速采样自动切换(GASS)烟气测试系统对SCR喷氨优化调整试验测试时间、测量不确定度和准确度进行研究,并利用某1000 MW机组进行实例验证。结果表明:GASS烟气测试系统单工况测试时间为传统方法的1/5~1/10,提高了测试效率,可减... 基于网格化快速采样自动切换(GASS)烟气测试系统对SCR喷氨优化调整试验测试时间、测量不确定度和准确度进行研究,并利用某1000 MW机组进行实例验证。结果表明:GASS烟气测试系统单工况测试时间为传统方法的1/5~1/10,提高了测试效率,可减少试验负荷申请时间。GASS烟气测试系统降低了NO x质量浓度测量不确定度,直接提高了测试准确度和SCR喷氨优化调整效果。 展开更多
关键词 GASS烟气测试系统 SCR 测试时间 不确定度 喷氨优化
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Numerical and experimental analyses of a stirred vessel for a large volumetric flow rate of sparged air 被引量:1
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作者 Andrej Bombac Jernej Pirnar 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2019年第10期2304-2312,共9页
Computational fluid dynamics(CFD)and experimental analyses of some of the basic characteristics of air sparging in a tall stirred vessel equipped with a three-stage impeller are presented.The impeller was assembled fr... Computational fluid dynamics(CFD)and experimental analyses of some of the basic characteristics of air sparging in a tall stirred vessel equipped with a three-stage impeller are presented.The impeller was assembled from a radial ABT impeller as the lower,a turbine 6 PBT45 as the middle and an axial Scaba-type 3SHP1 impeller as the upper.All the impellers were of the same diameter,i.e.,225 mm,while the vessel diameter was 450 mm.The impeller’s rotational speed was 178 r·min-1.The aeration regime was established with an air volumetric flow rate of 28.3 m3·h-1.To the best of our knowledge,this study is the first to consider the very high gassing rate by means of CFD in a tank stirred by three-stage axial/radial impellers.The numerical simulation was performed using the ANSYS Fluent(R17.2,2016)code for solving the governing equations of fluid dynamics in single-and multi-phase systems.While discussing the bubble size distribution,a discrete population balance model(PBM)was used.Adopting CFD,the stirring power and the total void fraction(the total gas holdup)were calculated.The results were in good agreement with the measured values using a laboratory experimental device. 展开更多
关键词 MIXING Stirred vessel AERATION Multiple stirrer High gassing rate Local void fraction
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《输入、交际与第二语言学习者》评介 被引量:1
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作者 覃修桂 《外语教学》 北大核心 2002年第4期94-96,共3页
关键词 《输入、交际与第二语言学习者》 SUSAN M.Gass 信息加工 外语教学
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“超低排放”用非分散红外CEMS的预处理优化应用研究 被引量:4
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作者 毛国明 戴勇 《上海节能》 2017年第4期204-210,共7页
采用非分散红外分析仪(NDIR)的超低排放CEMS系统目前在预处理方面存在的主要问题是烟气含水量高,会导致部分SO2溶解在冷凝水中发生损失,且烟气中的水份会连续的干扰目标气体的红外吸收谱段,造成分析仪漂移。针对这些问题,对超低排放CEM... 采用非分散红外分析仪(NDIR)的超低排放CEMS系统目前在预处理方面存在的主要问题是烟气含水量高,会导致部分SO2溶解在冷凝水中发生损失,且烟气中的水份会连续的干扰目标气体的红外吸收谱段,造成分析仪漂移。针对这些问题,对超低排放CEMS的预处理系统进行了优化改造,采用了以Nafion干燥管气态除湿技术为核心的GASS-6000原位式预处理系统,获得了成功的应用。该应用研究表明,通过Nafion管除湿预处理,烟气露点可以降低到-1 0℃,避免了SO2的溶解损失,同时大大降低了水份对目标气体在红外特征吸收谱段的干扰,因此可确认:NDIR冷干直抽法CEMS符合超低排放监测的要求。 展开更多
关键词 超低排放 非分散红外分析仪 冷干直抽法CEMS 预处理系统 Nafion干燥管 GASS系统
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基于GASS-BPEE交叉训练算法的河道冰情预报组合模型
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作者 李成振 郭学仲 《东北水利水电》 2012年第1期40-44,72,共5页
在文章的河道冰情预报的组合模型中,首先在成因分析的基础上,采用逐步回归算法对预报因子进行有效的筛选,然后采用GASS-BPEE交叉训练算法对冰情要素进行预报。利用该组合模型对凌汛灾害多发的松花江依兰、佳木斯江段开河日期进行了预报... 在文章的河道冰情预报的组合模型中,首先在成因分析的基础上,采用逐步回归算法对预报因子进行有效的筛选,然后采用GASS-BPEE交叉训练算法对冰情要素进行预报。利用该组合模型对凌汛灾害多发的松花江依兰、佳木斯江段开河日期进行了预报,结果表明所建立的河道冰情预报组合模型结构简单、预报精度较高,具有实用价值。 展开更多
关键词 冰情预报 GASS—BPEE算法 交叉训练 开河日期
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ⅡO模式与外语教学
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作者 任仙敏 张发祥 《科技经济市场》 2007年第3期343-,共1页
ⅡO模式集成Krashen的Input理论、Long的交互理论及Swain的Output理论,指出二语习得的五个阶段:感知(apperception)、可理解性输入(comprehended input)、吸收(intake)、整合(integration)及输出(output)。该理论避免过度强调某一学习阶... ⅡO模式集成Krashen的Input理论、Long的交互理论及Swain的Output理论,指出二语习得的五个阶段:感知(apperception)、可理解性输入(comprehended input)、吸收(intake)、整合(integration)及输出(output)。该理论避免过度强调某一学习阶段,而认为每个阶段都有独特的特性。该理论对二语习得的教学有着重要的意义,而且为现代语言学研究和外语教学提供了有益的启示. 展开更多
关键词 Gass IIO模式 SLA
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Verification of Insulation Oil Reclamation by Turbidity and Spetrophotometry Measurements
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作者 Janvier Sylvestre N'cho Issouf Fofana +2 位作者 Abderrahmane Beroual Thomas Aka-Ngnui John Sabau 《Journal of Energy and Power Engineering》 2012年第5期703-712,共10页
Oil reclamation with Fuller's earth is known to have an improved effect on conditioning aged oil. In this paper it is shown that aged oil reclamation effectiveness can be monitored with turbidity and spectrophotometr... Oil reclamation with Fuller's earth is known to have an improved effect on conditioning aged oil. In this paper it is shown that aged oil reclamation effectiveness can be monitored with turbidity and spectrophotometry measurements. These low cost testing techniques offer a useful tool to quantify the effect of Fuller's earth. Experimental investigations performed in laboratory conditions have shown that the quality of properly reclaimed aged oil can compete with that of new oils. Thus, in addition to extending the life cycle of this non-renewable resource, on-line reclamation of liquid might also prevent the premature ageing of paper insulation. Studying the stability of reclaimed service aged oil samples emphasized the important role played by Fuller's earth absorption capability. 展开更多
关键词 Insulating oil RECLAMATION Fuller's earth TURBIDITY SPECTROPHOTOMETER decay product gassing tendency.
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基于BP网络的稀疏信道估计算法的改进 被引量:1
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作者 管建中 孙艳华 张延华 《中国电子科学研究院学报》 2011年第3期284-289,共6页
为了在稀疏信道下有效地降低传统信道估计算法的复杂度,提出了一种基于反向传播(BP,back propagation)网络的正交匹配追踪后接消除(OMPC,orthogonal matching pursuit cancellation)信道估计改进算法。首先通过OMPC算法确定各个非零抽... 为了在稀疏信道下有效地降低传统信道估计算法的复杂度,提出了一种基于反向传播(BP,back propagation)网络的正交匹配追踪后接消除(OMPC,orthogonal matching pursuit cancellation)信道估计改进算法。首先通过OMPC算法确定各个非零抽头的位置,其次设置BP网络的权值与阈值,进一步实现对非零抽头估计值的逼近,最后通过自适应调整来对信道估计的准确度进行修正。通过与基于BP和OMPC信号稀疏分解的比较发现,本方法较好地解决了信号稀疏分解计算量大、收敛速度慢、不能利用信道稀疏特性等难题。 展开更多
关键词 稀疏信道 BP神经网络 OMPC GASS MP
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Nitrous Oxide and Methane Emissions as Affected by Water,Soil and Nitrogen 被引量:41
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作者 XIONG Zheng-Qin XING Guang-Xi ZHU Zhao-Liang 《Pedosphere》 SCIE CAS CSCD 2007年第2期146-155,共10页
Specific management of water regimes, soil and N in China might play an important role in regulating N2O and CH4 emissions in rice fields. Nitrous oxide and methane emissions from alternate non-flooded/flooded paddies... Specific management of water regimes, soil and N in China might play an important role in regulating N2O and CH4 emissions in rice fields. Nitrous oxide and methane emissions from alternate non-flooded/flooded paddies were monitored simultaneously during a 516-day incubation with lysimeter experiments. Two N sources (15N-(NH4)2SO4 and 15N-labeled milk vetch) were applied to two contrasting paddies: one derived from Xiashu loess (Loess) and one from Quaternary red clay (Clay). Both N2O and CH4 emissions were significantly higher in soil Clay than in soil Loess during the flooded period. For both soil, N2O emissions peaked at the transition periods shortly after the beginning of the flooded and non-flooded seasons. Soil type affected N2O emission patterns. In soil Clay, the emission peak during the transition period from non-flooded to flooded conditions was much higher than the peak during the transition period from flooded to non-flooded conditions. In soil Loess, the emission peak during the transition period from flooded to non-flooded conditions was obviously higher than the peak during the transition period from non-flooded to flooded conditions except for milk vetch treatment. Soil type also had a significant effect on CH4 emissions during the flooded season, over which the weighted average flux was 111 mg C m-2 h-1 and 2.2 mg C m-2 h-1 from Clay and Loess, respectively. Results indicated that it was the transition in the water regime that dominated N2O emissions while it was the soil type that dominated CH4 emissions during the flooded season. Anaerobic oxidation of methane possibly existed in soil Loess during the flooded season. 展开更多
关键词 anaerobic oxidation of methane (AOM) dissimilatory nitrate reduction to ammonium (DNRA) greenhouse gasses LYSIMETER paddy soil
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一种创新的冷干直抽法CEMS样气预处理技术的应用研究 被引量:15
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作者 李峰 《分析仪器》 CAS 2013年第2期71-76,共6页
样气预处理系统技术是冷干直抽法CEMS系统的核心和关键技术。在线样气预处理技术的重点和难点是样气的除湿和除尘处理。不同于传统的冷凝除湿,Nafion管除湿具有其独特的特点,是对现有除湿技术的一大补充。而以Nafion管为核心的GASS样气... 样气预处理系统技术是冷干直抽法CEMS系统的核心和关键技术。在线样气预处理技术的重点和难点是样气的除湿和除尘处理。不同于传统的冷凝除湿,Nafion管除湿具有其独特的特点,是对现有除湿技术的一大补充。而以Nafion管为核心的GASS样气预处理系统,则集取样、二次过滤除尘、除酸雾除氨气、Nafion管干燥为一体,是一种创新的冷干直取法CEMS样气预处理技术,可彻底解决冷干直抽法CEMS中冷凝水和铵盐结晶问题。 展开更多
关键词 样气预处理 CEMS Nafion管 GASS系统 除湿 铵盐结晶 除氨 除酸雾
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Supplying System for Drinking Water to Small Rural Communities with Zero Greenhouse Gasses: Sixteen Years of Experiences in Mexico 被引量:1
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作者 Martín Mundo-Molina 《Journal of Water Resource and Protection》 2016年第12期1044-1052,共10页
In Chiapas highlands to southeast of Mexico, the scarcity of water is worrying, according to technical reports of the IPCC the runoff will less between 150 to 250 mm per year in the southeast of Mexico, this situation... In Chiapas highlands to southeast of Mexico, the scarcity of water is worrying, according to technical reports of the IPCC the runoff will less between 150 to 250 mm per year in the southeast of Mexico, this situation will increase the problems of water availability in Chiapas highlands in the future. For actually more of 18,160 small rural indigenous communities (SRIC) in Chiapas there is not drinking water. In order to contribute a given solution to scarcity of drinking water in the SRIC, The Autonomous University of Chiapas (UNACH in its Spanish acronym) and Mexican Institute of Water Technology (IMTA in its Spanish acronym) designed and constructed in 1999 the Rain Water Harvesting (RWH) in Yalentay municipality of Zinacantan in Chiapas, Mexico. The scientific and technical contributions of RWH are: The design guarantee the water quality for a prolonged time of storage avoiding the photosynthesis inside the system;Not emitted greenhouse gasses because it doesn’t need any kind of fossil fuels;Not produces anything kind of damage to the environment;It has to be inexpensive, using in its construction manpower and materials from de region;Store the maximum quantity of water in the minimum space. The RWH has increased the standard of living of the habitants from Yalentay and improving their health conditions. 展开更多
关键词 Climatic Change Rain Water Harsvesting Technology Appropiatte Greenhouse Gasses
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