The well-developed coal electricity generation and coal chemical industries have led to huge carbon dioxide(CO_(2))emissions in the northeastern Ordos Basin.The geological storage of CO_(2) in saline aquifers is an ef...The well-developed coal electricity generation and coal chemical industries have led to huge carbon dioxide(CO_(2))emissions in the northeastern Ordos Basin.The geological storage of CO_(2) in saline aquifers is an effective backup way to achieve carbon neutrality.In this case,the potential of saline aquifers for CO_(2) storage serves as a critical basis for subsequent geological storage project.This study calculated the technical control capacities of CO_(2) of the saline aquifers in the fifth member of the Shiqianfeng Formation(the Qian-5 member)based on the statistical analysis of the logging and the drilling and core data from more than 200 wells in the northeastern Ordos Basin,as well as the sedimentary facies,formation lithology,and saline aquifer development patterns of the Qian-5 member.The results show that(1)the reservoirs of saline aquifers in the Qian-5 member,which comprise distributary channel sand bodies of deltaic plains,feature low porosities and permeabilities;(2)The study area hosts three NNE-directed saline aquifer zones,where saline aquifers generally have a single-layer thickness of 3‒8 m and a cumulative thickness of 8‒24 m;(3)The saline aquifers of the Qian-5 member have a total technical control capacity of CO_(2) of 119.25×10^(6) t.With the largest scale and the highest technical control capacity(accounting for 61%of the total technical control capacity),the Jinjie-Yulin saline aquifer zone is an important prospect area for the geological storage of CO_(2) in the saline aquifers of the Qian-5 member in the study area.展开更多
The metal-organic framework(MOF)derived Ni–Co–C–N composite alloys(NiCCZ)were“embedded”inside the carbon cloth(CC)strands as opposed to the popular idea of growing them upward to realize ultrastable energy storag...The metal-organic framework(MOF)derived Ni–Co–C–N composite alloys(NiCCZ)were“embedded”inside the carbon cloth(CC)strands as opposed to the popular idea of growing them upward to realize ultrastable energy storage and conversion application.The NiCCZ was then oxygen functionalized,facilitating the next step of stoichiometric sulfur anion diffusion during hydrothermal sulfurization,generating a flower-like metal hydroxysulfide structure(NiCCZOS)with strong partial implantation inside CC.Thus obtained NiCCZOS shows an excellent capacity when tested as a supercapacitor electrode in a three-electrode configuration.Moreover,when paired with the biomass-derived nitrogen-rich activated carbon,the asymmetric supercapacitor device shows almost 100%capacity retention even after 45,000 charge–discharge cycles with remarkable energy density(59.4 Wh kg^(-1)/263.8μWh cm^(–2))owing to a uniquely designed cathode.Furthermore,the same electrode performed as an excellent bifunctional water-splitting electrocatalyst with an overpotential of 271 mV for oxygen evolution reaction(OER)and 168.4 mV for hydrogen evolution reaction(HER)at 10 mA cm−2 current density along with 30 h of unhinged chronopotentiometric stability performance for both HER and OER.Hence,a unique metal chalcogenide composite electrode/substrate configuration has been proposed as a highly stable electrode material for flexible energy storage and conversion applications.展开更多
Tree plantation and forest restoration are the major strategies for enhancing terrestrial carbon sequestration and mitigating climate change.The Grain for Green Project in China has positively impacted global carbon s...Tree plantation and forest restoration are the major strategies for enhancing terrestrial carbon sequestration and mitigating climate change.The Grain for Green Project in China has positively impacted global carbon sequestration and the trend towards fragmentation of plantation forests.Limited studies have been conducted on changes in plantation biomass and stand structure caused by fragmentation,and the effect of fragmentation on the carbon storage of plantation forests remains unclear.This study evaluated the differences between carbon storage and stand structure in black locust forests in fragmented and continuous landscape in the Ansai District,China and discussed the effects of ecological significance of four landscape indices on carbon storage and tree density.We used structural equation modelling to explore the direct and indirect effects of fragmentation,edge,abiotic factors,and stand structure on above-ground carbon storage.Diameter at breast height(DBH)in fragmented forests was 53.3%thicker,tree density was 40.9%lower,and carbon storage was 49.8%higher than those in continuous forests;for all given DBH>10 cm,the trees in fragmented forests were shorter than those in continuous forests.The patch area had a negative impact on carbon storage,i.e.,the higher the degree of fragmentation,the lower the density of the tree;and fragmentation and distance to edge(DTE)directly increased canopy coverage.However,canopy coverage directly decreased carbon storage,and fragmentation directly increased carbon storage and tree density.In non-commercial forests,fragmentation reduces the carbon storage potential of plantation,and the influence of patch area,edge,and patchy connection on plantation should be considered when follow-up trees are planted and for the plantation management.Thus,expanding the area of plantation patches,repairing the edges of complex-shaped patches,enhancing the connectivity of similar patches,and applying nutrients to plantation forests at regular intervals are recommended in fragmented areas of the Loess Plateau.展开更多
This research investigates the ecological importance,changes,and status of mangrove wetlands along China’s coastline.Visual interpretation,geological surveys,and ISO clustering unsupervised classification methods are...This research investigates the ecological importance,changes,and status of mangrove wetlands along China’s coastline.Visual interpretation,geological surveys,and ISO clustering unsupervised classification methods are employed to interpret mangrove distribution from remote sensing images from 2021,utilizing ArcGIS software platform.Furthermore,the carbon storage capacity of mangrove wetlands is quantified using the carbon storage module of InVEST model.Results show that the mangrove wetlands in China covered an area of 278.85 km2 in 2021,predominantly distributed in Hainan,Guangxi,Guangdong,Fujian,Zhejiang,Taiwan,Hong Kong,and Macao.The total carbon storage is assessed at 2.11×10^(6) t,with specific regional data provided.Trends since the 1950s reveal periods of increase,decrease,sharp decrease,and slight-steady increases in mangrove areas in China.An important finding is the predominant replacement of natural coastlines adjacent to mangrove wetlands by artificial ones,highlighting the need for creating suitable spaces for mangrove restoration.This study is poised to guide future mangroverelated investigations and conservation strategies.展开更多
MgH_(2) is considered one of the most promising hydrogen storage materials because of its safety,high efficiency,high hydrogen storage quantity and low cost characteristics.But some shortcomings are still existed:high...MgH_(2) is considered one of the most promising hydrogen storage materials because of its safety,high efficiency,high hydrogen storage quantity and low cost characteristics.But some shortcomings are still existed:high operating temperature and poor hydrogen absorption dynamics,which limit its application.Porous Ni_(3)ZnC_(0.7)/Ni loaded carbon nanotubes microspheres(NZC/Ni@CNT)is prepared by facile filtration and calcination method.Then the different amount of NZC/Ni@CNT(2.5,5.0 and 7.5 wt%)is added to the MgH_(2) by ball milling.Among the three samples with different amount of NZC/Ni@CNT(2.5,5.0 and 7.5 wt%),the MgH_(2)-5 wt%NZC/Ni@CNT composite exhibits the best hydrogen storage performances.After testing,the MgH_(2)-5 wt%NZC/Ni@CNT begins to release hydrogen at around 110℃ and hydrogen absorption capacity reaches 2.34 wt%H_(2) at 80℃ within 60 min.Moreover,the composite can release about 5.36 wt%H_(2) at 300℃.In addition,hydrogen absorption and desorption activation energies of the MgH_(2)-5 wt%NZC/Ni@CNT composite are reduced to 37.28 and 84.22 KJ/mol H_(2),respectively.The in situ generated Mg_(2)NiH_(4)/Mg_(2)Ni can serve as a"hydrogen pump"that plays the main role in providing more activation sites and hydrogen diffusion channels which promotes H_(2) dissociation during hydrogen absorption process.In addition,the evenly dispersed Zn and MgZn2 in Mg and MgH_(2) could provide sites for Mg/MgH_(2) nucleation and hydrogen diffusion channel.This attempt clearly proved that the bimetallic carbide Ni_(3)ZnC_(0.7) is a effective additive for the hydrogen storage performances modification of MgH_(2),and the facile synthesis of the Ni_(3)ZnC_(0.7)/Ni@CNT can provide directions of better designing high performance carbide catalysts for improving MgH_(2).展开更多
Regional sustainable development necessitates a holistic understanding of spatiotemporal variations in ecosystem carbon storage(ECS),particularly in ecologically sensitive areas with arid and semi-arid climate.In this...Regional sustainable development necessitates a holistic understanding of spatiotemporal variations in ecosystem carbon storage(ECS),particularly in ecologically sensitive areas with arid and semi-arid climate.In this study,we calculated the ECS in the Ningxia Section of Yellow River Basin,China from 1985 to 2020 using the Integrated Valuation of Ecosystem Services and Tradeoffs(InVEST)model based on land use data.We further predicted the spatial distribution of ECS in 2050 under four land use scenarios:natural development scenario(NDS),ecological protection scenario(EPS),cultivated land protection scenario(CPS),and urban development scenario(UDS)using the patch-generating land use simulation(PLUS)model,and quantified the influences of natural and human factors on the spatial differentiation of ECS using the geographical detector(Geodetector).Results showed that the total ECS of the study area initially increased from 1985 until reaching a peak at 402.36×10^(6) t in 2010,followed by a decreasing trend to 2050.The spatial distribution of ECS was characterized by high values in the eastern and southern parts of the study area,and low values in the western and northern parts.Between 1985 and 2020,land use changes occurred mainly through the expansion of cultivated land,woodland,and construction land at the expense of unused land.The total ECS in 2050 under different land use scenarios(ranked as EPS>CPS>NDS>UDS)would be lower than that in 2020.Nighttime light was the largest contributor to the spatial differentiation of ECS,with soil type and annual mean temperature being the major natural driving factors.Findings of this study could provide guidance on the ecological construction and high-quality development in arid and semi-arid areas.展开更多
Global climate change is a common challenge facing mankind,which has evolved from a scientific issue into a global economic and political issue of universal concern to the international community(IPCC,2007).Global sur...Global climate change is a common challenge facing mankind,which has evolved from a scientific issue into a global economic and political issue of universal concern to the international community(IPCC,2007).Global surface temperature was 1.1°C higher in 2011–2020 than that in 1850–1900,and has increased faster since 1970 than in any other 50-year period over at least the last 2000 years(IPCC,2023).展开更多
The global energy transition is a widespread phenomenon that requires international exchange of experiences and mutual learning.Germany’s success in its first phase of energy transition can be attributed to its adopt...The global energy transition is a widespread phenomenon that requires international exchange of experiences and mutual learning.Germany’s success in its first phase of energy transition can be attributed to its adoption of smart energy technology and implementation of electricity futures and spot marketization,which enabled the achievement of multiple energy spatial–temporal complementarities and overall grid balance through energy conversion and reconversion technologies.While China can draw from Germany’s experience to inform its own energy transition efforts,its 11-fold higher annual electricity consumption requires a distinct approach.We recommend a clean energy system based on smart sector coupling(ENSYSCO)as a suitable pathway for achieving sustainable energy in China,given that renewable energy is expected to guarantee 85%of China’s energy production by 2060,requiring significant future electricity storage capacity.Nonetheless,renewable energy storage remains a significant challenge.We propose four large-scale underground energy storage methods based on ENSYSCO to address this challenge,while considering China’s national conditions.These proposals have culminated in pilot projects for large-scale underground energy storage in China,which we believe is a necessary choice for achieving carbon neutrality in China and enabling efficient and safe grid integration of renewable energy within the framework of ENSYSCO.展开更多
New energy sources that reduce the volume of harmful gases such as SO_(x)and NO_(x)released into the atmosphere are in constant development.Natural gas,primarily made up of methane,is being widely used as one reliable...New energy sources that reduce the volume of harmful gases such as SO_(x)and NO_(x)released into the atmosphere are in constant development.Natural gas,primarily made up of methane,is being widely used as one reliable energy source for heating and electricity generation due to its high combustion value.Currently,natural gas accounts for a large portion of electricity generation and chemical feedstock in manufacturing plastics and other commercially important organic chemicals.In the near future,natural gas will be widely used as a fuel for vehicles.Therefore,a practical storage device for its storage and transportation is very beneficial to the deployment of natural gas as an energy source for new technologies.In this tutorial review,biomaterials-based carbon monoliths(CMs),one kind of carbonaceous material,was reviewed as an adsorbent for natural gas(methane)adsorption and storage.展开更多
Thinning is a widely used forest management tool but systematic research has not been carried out to verify its eff ects on carbon storage and plant diversity at the ecosystem level.In this study,the eff ect of thinni...Thinning is a widely used forest management tool but systematic research has not been carried out to verify its eff ects on carbon storage and plant diversity at the ecosystem level.In this study,the eff ect of thinning was assessed across seven thinning intensities(0,10,15,20,25,30 and 35%)in a low-quality secondary forest in NE China over a ten-year period.Thinning aff ected the carbon storage of trees,and shrub,herb,and soil layers(P<0.05).It fi rst increased and then decreased as thinning intensity increased,reaching its maximum at 30%thinning.Carbon storage of the soil accounted for more than 64%of the total carbon stored in the ecosystem.It was highest in the upper 20-cm soil layer.Thinning increased tree species diversity while decreasing shrub and herb diversities(P<0.05).Redundancy analysis and a correlation heat map showed that carbon storage of tree and shrub layers was positively correlated with tree diversity but negatively with herb diversity,indicating that the increase in tree diversity increased the carbon storage of natural forest ecosystems.Although thinning decreased shrub and herb diversities,it increased the carbon storage of the overall ecosystem and tree species diversity of secondary forest.Maximum carbon storage and the highest tree diversity were observed at a thinning intensity of 30%.This study provides evidence for the ecological management of natural and secondary forests and improvement of ecosystem carbon sinks and biodiversity.展开更多
The development history of carbon capture,utilization and storage for enhanced oil recovery(CCUS-EOR)in China is comprehensively reviewed,which consists of three stages:research and exploration,field test and industri...The development history of carbon capture,utilization and storage for enhanced oil recovery(CCUS-EOR)in China is comprehensively reviewed,which consists of three stages:research and exploration,field test and industrial application.The breakthrough understanding of CO_(2) flooding mechanism and field practice in recent years and the corresponding supporting technical achievements of CCUS-EOR project are systematically described.The future development prospects are also pointed out.After nearly 60 years of exploration,the theory of CO_(2) flooding and storage suitable for continental sedimentary reservoirs in China has been innovatively developed.It is suggested that C7–C15 are also important components affecting miscibility of CO_(2) and crude oil.The mechanism of rapid recovery of formation energy by CO_(2) and significant improvement of block productivity and recovery factor has been verified in field tests.The CCUS-EOR reservoir engineering design technology for continental sedimentary reservoir is established.The technology of reservoir engineering parameter design and well spacing optimization has been developed,which focuses on maintaining miscibility to improve oil displacement efficiency and uniform displacement to improve sweep efficiency.The technology of CO_(2) capture,injection and production process,whole-system anticorrosion,storage monitoring and other whole-process supporting technologies have been initially formed.In order to realize the efficient utilization and permanent storage of CO_(2),it is necessary to take the oil reservoir in the oil-water transition zone into consideration,realize the large-scale CO_(2) flooding and storage in the area from single reservoir to the overall structural control system.The oil reservoir in the oil-water transition zone is developed by stable gravity flooding of injecting CO_(2) from structural highs.The research on the storage technology such as the conversion of residual oil and CO_(2) into methane needs to be carried out.展开更多
Potassium-ion batteries(PIBs)are potential“Beyond Li-ion Batteries”candidates for their resource advantage and low standard electrode potential.To date,the research on PIBs is in its early stages,the most urgent tas...Potassium-ion batteries(PIBs)are potential“Beyond Li-ion Batteries”candidates for their resource advantage and low standard electrode potential.To date,the research on PIBs is in its early stages,the most urgent task is to develop high-performance electrode materials and reveal their potassium storage mechanism.For PIBs anode materials,carbon with tunable microstructure,excellent electrochemical activity,nontoxicity and low price is considered as one of the most promising anode materials for commercialization.Although some breakthrough works have emerged,the overall electrochemical performance of the reported carbon anode is still far away from practical application.Herein,we carry out a comprehensive overview of PIBs carbon anode in terms of three aspects of rational design of structure,performance evaluation criteria and characterization of potassium storage mechanism.First,the regulation mechanism of key structural features of carbon anode on its potassium storage performance and the representative structural regulation strategies are introduced.Then,in view of the undefined performance evaluation criteria of PIBs carbon anode,a reference principle for evaluating the potassium storage performance of carbon anode is proposed.Finally,the advanced characterization techniques for the potassium storage mechanism of carbon anode are summarize.This review aims to provide guidance for the development of practical PIBs anode.展开更多
Molecular dynamics method was used to establish composite wall/inorganic nanopores of three pore sizes, three shale oil systems, five CO_(2)-cosolvent systems, and pure CO_(2) system. The process of CO_(2)-cosolvent d...Molecular dynamics method was used to establish composite wall/inorganic nanopores of three pore sizes, three shale oil systems, five CO_(2)-cosolvent systems, and pure CO_(2) system. The process of CO_(2)-cosolvent displacement of crude oil in shale nanopores and carbon storage was simulated and the influencing factors of displacement and storage were analyzed. It is shown that the attraction of the quartz wall to shale oil increases with the degree of hydroxylation. The higher the degree of quartz hydroxylation, the more difficult it is to extract the polar components of shale oil. Nanopore size also has a great impact on shale oil displacement efficiency. The larger the pore size, the higher the shale oil displacement efficiency. The closer the cosolvent molecules are to the polarity of the shale oil, the higher the mutual solubility of CO_(2) and shale oil. The more the non-polar components of shale oil, the lower the mutual solubility of CO_(2) and shale oil with highly polar cosolvent. Ethyl acetate is more effective in stripping relatively high polar shale oil, while dimethyl ether is more effective in stripping relatively low polar shale oil. Kerogen is highly adsorptive, especially to CO_(2). The CO_(2) inside the kerogen is not easy to diffuse and leak, thus allowing for a stable carbon storage. The highest CO_(2) storage rate is observed when dimethyl ether is used as a cosolvent, and the best storage stability is observed when ethyl acetate is used as a cosolvent.展开更多
Hard carbon(HC)is considered a promising anode material for sodium-ion batteries due to its relatively low price and high specific capacity.However,HC still suffers from unclear reaction mechanisms and unsatisfactory ...Hard carbon(HC)is considered a promising anode material for sodium-ion batteries due to its relatively low price and high specific capacity.However,HC still suffers from unclear reaction mechanisms and unsatisfactory cycling stability.The study of mechano-electrochemical coupling behavior by in-situ measurement techniques is expected to understand the sodium storage and degradation mechanisms.In this paper,the strain and stress evolution of HC anodes at different sodiation/desodiation depths and cycles are investigated by combining electrochemical methods,digital image correlation,and theoretical equations.The observation by monitoring the in-situ strain evolution during the redox process supports the“adsorption-intercalation/filling”mechanism in reduction and the“de-filling/de-intercalation-deso rption”mechanism in oxidation.Further studies have demonstrated that the strain and stress of the electrode show periodic changes accompanied by a continuous accumulation of residual stress during cycles,explaining the capacity degradation mechanism of HC from a mechanical perspective.In addition,when the higher current density is applied,the electrodes experience greater strain and stress associated with the Na+insertion rate.This work clarifies the Na-storage mechanism and the mechano-electrochemical coupling mechanism of HC anodes by in-situ strain measurement,which helps optimize and design the anode materials of sodium-ion batteries from the perspective of interface microstructure and multi-field coupling,such as in situ integrated interface structure design.展开更多
The Joule-Thomson effect is one of the important thermodynamic properties in the system relevant to gas switching reforming with carbon capture and storage(CCS). In this work, a set of apparatus was set up to determin...The Joule-Thomson effect is one of the important thermodynamic properties in the system relevant to gas switching reforming with carbon capture and storage(CCS). In this work, a set of apparatus was set up to determine the Joule-Thomson effect of binary mixtures(CO_(2)+ H_(2)). The accuracy of the apparatus was verified by comparing with the experimental data of carbon dioxide. The Joule-Thomson coefficients(μ_(JT)) for(CO_(2)+ H_(2)) binary mixtures with mole fractions of carbon dioxide(x_(CO_(2))= 0.1, 0.26, 0.5,0.86, 0.94) along six isotherms at various pressures were measured. Five equations of state EOSs(PR,SRK, PR, BWR and GERG-2008 equation) were used to calculate the μ_(JT)for both pure systems and binary systems, among which the GERG-2008 predicted best with a wide range of pressure and temperature.Moreover, the Joule-Thomson inversion curves(JTIC) were calculated with five equations of state. A comparison was made between experimental data and predicted data for the inversion curve of CO_(2). The investigated EOSs show a similar prediction of the low-temperature branch of the JTIC for both pure and binary systems, except for the BWRS equation of state. Among all the equations, SRK has the most similar result to GERG-2008 for predicting JTIC.展开更多
Continuous accumulation and emission into the atmosphere of anthropogenic carbon dioxide(CO_(2)),a major greenhouse gas,has been recognized as a primary contributor to climate change associated with the global warming...Continuous accumulation and emission into the atmosphere of anthropogenic carbon dioxide(CO_(2)),a major greenhouse gas,has been recognized as a primary contributor to climate change associated with the global warming and acidification of oceans.This has led to drastic changes in the natural ecosystem,and hence an unhealthy ecological environment for human society.Thus,the effective mitigation of the ever increasing CO_(2)emission has been recognized as the most important global challenge.To achieve zero carbon footprint,novel materials and approaches are required for potentially reducing the CO_(2)release,while our current fossil-fuel-based energy must be replaced by renewable energy free from emissions.In this paper,porous carbons with hierarchical pore structures are promising for CO_(2)adsorption and electrochemical CO_(2)reduction owing to their high specific surface area,excellent catalytic performance,low cost and long-term stability.Since efficient gas-phased(electro)catalysis involves the access of reactants to active sites at the gas-liquid-solid triple phase,the hierarchical porous carbon materials possess multiple advantages for various CO_(2)-related applications with enhanced volumetric and gravimetric activities(e.g.,CO_(2)uptake and current density)for practical operations.Recent studies have demonstrated that porous carbon materials exhibited notable activities as CO_(2)adsorbents and provided facile conducting pathways and mass diffusion channels for efficient electrochemical CO_(2)reduction even under the high current operation conditions.Herein,we summarize recent advances in porous carbon materials for CO_(2)capture,storage,and electrochemical conversion.Prospectives and challenges on the rational design of porous carbon materials for scalable and practical CO_(2)capture and conversion are also discussed.展开更多
Urban tree inventory is a great tool for gathering data that can be used by different end users. This study attempted to chart the species diversity in planted areas and measure their tree diameter at breast height to...Urban tree inventory is a great tool for gathering data that can be used by different end users. This study attempted to chart the species diversity in planted areas and measure their tree diameter at breast height to screen them for the carbon storage potential. A total of 2860 trees belonging to 36 species were recorded in the planted vegetation in parks and avenue plantation. The dominant species were Azadirachta indicia (25.5%), Conocarpus erectus (19.2%), Ficus spp. (15.5%), Tabebuia rosea (9.2%), Peitophorum pterocarpum (9.0%) and the remaining represents (21.6%) of the tree identified in this study. It was found that the highest contribution of carbon sequestration (CO<sub>2</sub> equivalent) is dominated by the Ficus spp. (30.3%) with a total of 3399.3 tCO<sub>2</sub>eq, followed by Azadirachta indicia (25.4%) with a total of 2845.2 tCO<sub>2</sub>eq and Conocarpus erectus (20.4%) with a total of 2286 tCO<sub>2</sub>eq. The entire area has the capability to sequester around 11,213.3 tCO<sub>2</sub>eq and on average of 3.9 ± 0.1 tCO<sub>2</sub>eq. In accordance with the findings, it is imperative for the preservation of a sustainable environment to have vegetation that has the capacity to store carbon. The study suggests, there is potential to increase carbon sequestration in urban cities through plantation programs on existing and new land uses and along roads.展开更多
Based on more than 20-year operation of gas storages with complex geological conditions and a series of research findings, the pressure-bearing dynamics mechanism of geological body is revealed. With the discovery of ...Based on more than 20-year operation of gas storages with complex geological conditions and a series of research findings, the pressure-bearing dynamics mechanism of geological body is revealed. With the discovery of gas-water flowing law of multi-cycle relative permeability hysteresis and differential utilization in zones, the extreme utilization theory targeting at the maximum amount of stored gas, maximum injection-production capacity and maximum efficiency in space utilization is proposed to support the three-in-one evaluation method of the maximum pressure-bearing capacity of geological body, maximum well production capacity and maximum peak shaving capacity of storage space. This study realizes the full potential of gas storage(storage capacity) at maximum pressure, maximum formation-wellbore coordinate production, optimum well spacing density match with finite-time unsteady flow, and peaking shaving capacity at minimum pressure, achieving perfect balance between security and capacity. Operation in gas storages, such as Hutubi in Xinjiang, Xiangguosi in Xinan, and Shuang6 in Liaohe, proves that extreme utilization theory has promoted high quality development of gas storages in China.展开更多
To accelerate the achievement of China’s carbon neutrality goal and to study the factors affecting the geologic CO_(2)storage in the Ordos Basin,China’s National Key R&D Programs propose to select the Chang 6 oi...To accelerate the achievement of China’s carbon neutrality goal and to study the factors affecting the geologic CO_(2)storage in the Ordos Basin,China’s National Key R&D Programs propose to select the Chang 6 oil reservoir of the Yanchang Formation in the Ordos Basin as the target reservoir to conduct the geologic carbon capture and storage(CCS)of 100000 t per year.By applying the basic theories of disciplines such as seepage mechanics,multiphase fluid mechanics,and computational fluid mechanics and quantifying the amounts of CO_(2)captured in gas and dissolved forms,this study investigated the effects of seven factors that influence the CO_(2)storage capacity of reservoirs,namely reservoir porosity,horizontal permeability,temperature,formation stress,the ratio of vertical to horizontal permeability,capillary pressure,and residual gas saturation.The results show that the sensitivity of the factors affecting the gas capture capacity of CO_(2)decreases in the order of formation stress,temperature,residual gas saturation,horizontal permeability,and porosity.Meanwhile,the sensitivity of the factors affecting the dissolution capture capacity of CO_(2)decreases in the order of formation stress,residual gas saturation,temperature,horizontal permeability,and porosity.The sensitivity of the influencing factors can serve as the basis for carrying out a reasonable assessment of sites for future CO_(2)storage areas and for optimizing the design of existing CO_(2)storage areas.The sensitivity analysis of the influencing factors will provide basic data and technical support for implementing geologic CO_(2)storage and will assist in improving geologic CO_(2)storage technologies to achieve China’s carbon neutralization goal.展开更多
基金funded by the Top 10 key scientific and technological projects of CHN Energy in 2021 entitled Research and Demonstration of Technology for Carbon Dioxide Capture and Energy Recycling Utilization(GJNYKJ[2021]No.128,No.:GJNY-21-51)the Carbon Neutrality College(Yulin)Northwest University project entitled Design and research of large-scale CCUS cluster construction in Yulin area,Shaanxi Province(YL2022-38-01).
文摘The well-developed coal electricity generation and coal chemical industries have led to huge carbon dioxide(CO_(2))emissions in the northeastern Ordos Basin.The geological storage of CO_(2) in saline aquifers is an effective backup way to achieve carbon neutrality.In this case,the potential of saline aquifers for CO_(2) storage serves as a critical basis for subsequent geological storage project.This study calculated the technical control capacities of CO_(2) of the saline aquifers in the fifth member of the Shiqianfeng Formation(the Qian-5 member)based on the statistical analysis of the logging and the drilling and core data from more than 200 wells in the northeastern Ordos Basin,as well as the sedimentary facies,formation lithology,and saline aquifer development patterns of the Qian-5 member.The results show that(1)the reservoirs of saline aquifers in the Qian-5 member,which comprise distributary channel sand bodies of deltaic plains,feature low porosities and permeabilities;(2)The study area hosts three NNE-directed saline aquifer zones,where saline aquifers generally have a single-layer thickness of 3‒8 m and a cumulative thickness of 8‒24 m;(3)The saline aquifers of the Qian-5 member have a total technical control capacity of CO_(2) of 119.25×10^(6) t.With the largest scale and the highest technical control capacity(accounting for 61%of the total technical control capacity),the Jinjie-Yulin saline aquifer zone is an important prospect area for the geological storage of CO_(2) in the saline aquifers of the Qian-5 member in the study area.
基金supported by the Basic Science Research Program through the National Research Foundation of Korea(NRF)grant funded by the Korean government(MSIT)(2021R1A4A2000934).
文摘The metal-organic framework(MOF)derived Ni–Co–C–N composite alloys(NiCCZ)were“embedded”inside the carbon cloth(CC)strands as opposed to the popular idea of growing them upward to realize ultrastable energy storage and conversion application.The NiCCZ was then oxygen functionalized,facilitating the next step of stoichiometric sulfur anion diffusion during hydrothermal sulfurization,generating a flower-like metal hydroxysulfide structure(NiCCZOS)with strong partial implantation inside CC.Thus obtained NiCCZOS shows an excellent capacity when tested as a supercapacitor electrode in a three-electrode configuration.Moreover,when paired with the biomass-derived nitrogen-rich activated carbon,the asymmetric supercapacitor device shows almost 100%capacity retention even after 45,000 charge–discharge cycles with remarkable energy density(59.4 Wh kg^(-1)/263.8μWh cm^(–2))owing to a uniquely designed cathode.Furthermore,the same electrode performed as an excellent bifunctional water-splitting electrocatalyst with an overpotential of 271 mV for oxygen evolution reaction(OER)and 168.4 mV for hydrogen evolution reaction(HER)at 10 mA cm−2 current density along with 30 h of unhinged chronopotentiometric stability performance for both HER and OER.Hence,a unique metal chalcogenide composite electrode/substrate configuration has been proposed as a highly stable electrode material for flexible energy storage and conversion applications.
基金supported by the National Natural Science Foundation of China(32201429)the College of Landscape Architecture and Art,Northwest A&F University,China.
文摘Tree plantation and forest restoration are the major strategies for enhancing terrestrial carbon sequestration and mitigating climate change.The Grain for Green Project in China has positively impacted global carbon sequestration and the trend towards fragmentation of plantation forests.Limited studies have been conducted on changes in plantation biomass and stand structure caused by fragmentation,and the effect of fragmentation on the carbon storage of plantation forests remains unclear.This study evaluated the differences between carbon storage and stand structure in black locust forests in fragmented and continuous landscape in the Ansai District,China and discussed the effects of ecological significance of four landscape indices on carbon storage and tree density.We used structural equation modelling to explore the direct and indirect effects of fragmentation,edge,abiotic factors,and stand structure on above-ground carbon storage.Diameter at breast height(DBH)in fragmented forests was 53.3%thicker,tree density was 40.9%lower,and carbon storage was 49.8%higher than those in continuous forests;for all given DBH>10 cm,the trees in fragmented forests were shorter than those in continuous forests.The patch area had a negative impact on carbon storage,i.e.,the higher the degree of fragmentation,the lower the density of the tree;and fragmentation and distance to edge(DTE)directly increased canopy coverage.However,canopy coverage directly decreased carbon storage,and fragmentation directly increased carbon storage and tree density.In non-commercial forests,fragmentation reduces the carbon storage potential of plantation,and the influence of patch area,edge,and patchy connection on plantation should be considered when follow-up trees are planted and for the plantation management.Thus,expanding the area of plantation patches,repairing the edges of complex-shaped patches,enhancing the connectivity of similar patches,and applying nutrients to plantation forests at regular intervals are recommended in fragmented areas of the Loess Plateau.
基金supported by China Geological Survey(DD20211301).
文摘This research investigates the ecological importance,changes,and status of mangrove wetlands along China’s coastline.Visual interpretation,geological surveys,and ISO clustering unsupervised classification methods are employed to interpret mangrove distribution from remote sensing images from 2021,utilizing ArcGIS software platform.Furthermore,the carbon storage capacity of mangrove wetlands is quantified using the carbon storage module of InVEST model.Results show that the mangrove wetlands in China covered an area of 278.85 km2 in 2021,predominantly distributed in Hainan,Guangxi,Guangdong,Fujian,Zhejiang,Taiwan,Hong Kong,and Macao.The total carbon storage is assessed at 2.11×10^(6) t,with specific regional data provided.Trends since the 1950s reveal periods of increase,decrease,sharp decrease,and slight-steady increases in mangrove areas in China.An important finding is the predominant replacement of natural coastlines adjacent to mangrove wetlands by artificial ones,highlighting the need for creating suitable spaces for mangrove restoration.This study is poised to guide future mangroverelated investigations and conservation strategies.
基金supported by research programs of National Natural Science Foundation of China(52101274,51731002)Natural Science Foundation of Shandong Province(No.ZR2020QE011)Youth Top Talent Foundation of Yantai University(2219008).
文摘MgH_(2) is considered one of the most promising hydrogen storage materials because of its safety,high efficiency,high hydrogen storage quantity and low cost characteristics.But some shortcomings are still existed:high operating temperature and poor hydrogen absorption dynamics,which limit its application.Porous Ni_(3)ZnC_(0.7)/Ni loaded carbon nanotubes microspheres(NZC/Ni@CNT)is prepared by facile filtration and calcination method.Then the different amount of NZC/Ni@CNT(2.5,5.0 and 7.5 wt%)is added to the MgH_(2) by ball milling.Among the three samples with different amount of NZC/Ni@CNT(2.5,5.0 and 7.5 wt%),the MgH_(2)-5 wt%NZC/Ni@CNT composite exhibits the best hydrogen storage performances.After testing,the MgH_(2)-5 wt%NZC/Ni@CNT begins to release hydrogen at around 110℃ and hydrogen absorption capacity reaches 2.34 wt%H_(2) at 80℃ within 60 min.Moreover,the composite can release about 5.36 wt%H_(2) at 300℃.In addition,hydrogen absorption and desorption activation energies of the MgH_(2)-5 wt%NZC/Ni@CNT composite are reduced to 37.28 and 84.22 KJ/mol H_(2),respectively.The in situ generated Mg_(2)NiH_(4)/Mg_(2)Ni can serve as a"hydrogen pump"that plays the main role in providing more activation sites and hydrogen diffusion channels which promotes H_(2) dissociation during hydrogen absorption process.In addition,the evenly dispersed Zn and MgZn2 in Mg and MgH_(2) could provide sites for Mg/MgH_(2) nucleation and hydrogen diffusion channel.This attempt clearly proved that the bimetallic carbide Ni_(3)ZnC_(0.7) is a effective additive for the hydrogen storage performances modification of MgH_(2),and the facile synthesis of the Ni_(3)ZnC_(0.7)/Ni@CNT can provide directions of better designing high performance carbide catalysts for improving MgH_(2).
基金supported by the Innovation Projects for Overseas Returnees of Ningxia Hui Autonomous Region-Study on Multi-Scenario Land Use Optimization and Carbon Storage in the Ningxia Section of Yellow River Basin(202303)the National Natural Science Foundation of China(42067022,41761066)the Natural Science Foundation of Ningxia Hui Autonomous Region,China(2022AAC03024)。
文摘Regional sustainable development necessitates a holistic understanding of spatiotemporal variations in ecosystem carbon storage(ECS),particularly in ecologically sensitive areas with arid and semi-arid climate.In this study,we calculated the ECS in the Ningxia Section of Yellow River Basin,China from 1985 to 2020 using the Integrated Valuation of Ecosystem Services and Tradeoffs(InVEST)model based on land use data.We further predicted the spatial distribution of ECS in 2050 under four land use scenarios:natural development scenario(NDS),ecological protection scenario(EPS),cultivated land protection scenario(CPS),and urban development scenario(UDS)using the patch-generating land use simulation(PLUS)model,and quantified the influences of natural and human factors on the spatial differentiation of ECS using the geographical detector(Geodetector).Results showed that the total ECS of the study area initially increased from 1985 until reaching a peak at 402.36×10^(6) t in 2010,followed by a decreasing trend to 2050.The spatial distribution of ECS was characterized by high values in the eastern and southern parts of the study area,and low values in the western and northern parts.Between 1985 and 2020,land use changes occurred mainly through the expansion of cultivated land,woodland,and construction land at the expense of unused land.The total ECS in 2050 under different land use scenarios(ranked as EPS>CPS>NDS>UDS)would be lower than that in 2020.Nighttime light was the largest contributor to the spatial differentiation of ECS,with soil type and annual mean temperature being the major natural driving factors.Findings of this study could provide guidance on the ecological construction and high-quality development in arid and semi-arid areas.
文摘Global climate change is a common challenge facing mankind,which has evolved from a scientific issue into a global economic and political issue of universal concern to the international community(IPCC,2007).Global surface temperature was 1.1°C higher in 2011–2020 than that in 1850–1900,and has increased faster since 1970 than in any other 50-year period over at least the last 2000 years(IPCC,2023).
基金Henan Institute for Chinese Development Strategy of Engineering&Technology(No.2022HENZDA02)the Science&Technology Department of Sichuan Province(No.2021YFH0010)。
文摘The global energy transition is a widespread phenomenon that requires international exchange of experiences and mutual learning.Germany’s success in its first phase of energy transition can be attributed to its adoption of smart energy technology and implementation of electricity futures and spot marketization,which enabled the achievement of multiple energy spatial–temporal complementarities and overall grid balance through energy conversion and reconversion technologies.While China can draw from Germany’s experience to inform its own energy transition efforts,its 11-fold higher annual electricity consumption requires a distinct approach.We recommend a clean energy system based on smart sector coupling(ENSYSCO)as a suitable pathway for achieving sustainable energy in China,given that renewable energy is expected to guarantee 85%of China’s energy production by 2060,requiring significant future electricity storage capacity.Nonetheless,renewable energy storage remains a significant challenge.We propose four large-scale underground energy storage methods based on ENSYSCO to address this challenge,while considering China’s national conditions.These proposals have culminated in pilot projects for large-scale underground energy storage in China,which we believe is a necessary choice for achieving carbon neutrality in China and enabling efficient and safe grid integration of renewable energy within the framework of ENSYSCO.
基金Acknowledgment is made to the Donors of the American Chemical Society Petroleum Research Fund for support of this research.
文摘New energy sources that reduce the volume of harmful gases such as SO_(x)and NO_(x)released into the atmosphere are in constant development.Natural gas,primarily made up of methane,is being widely used as one reliable energy source for heating and electricity generation due to its high combustion value.Currently,natural gas accounts for a large portion of electricity generation and chemical feedstock in manufacturing plastics and other commercially important organic chemicals.In the near future,natural gas will be widely used as a fuel for vehicles.Therefore,a practical storage device for its storage and transportation is very beneficial to the deployment of natural gas as an energy source for new technologies.In this tutorial review,biomaterials-based carbon monoliths(CMs),one kind of carbonaceous material,was reviewed as an adsorbent for natural gas(methane)adsorption and storage.
基金This work was supported by the National Natural Science Foundation of China(Grant No.51863005,51462006,51102230,51671062,51871065,and 51971068)the Guangxi Natural Science Foundation(No.2018GXNSFDA281051,2014GXNSFAA118401,and 2020GXNSFGA297004)+2 种基金the Science Research and Technology Development Program of Guangxi(AD17195073,AA19182014 and AA17202030-1)the Guangxi Bagui Scholar Foundation,the Guangxi Collabora-tive Innovation Centre of Structure and Property for New Energy and Materials,the Guangxi Advanced Functional Materials Foundation and Application Talents Small Highlands,Chinesisch-Deutsche Kooperationsgruppe(GZ1528)the Innovation Project of GUET Graduate Education(2019YCXS114 and 2018YJCX88).
文摘We deviseda functional form stable compositephase-change materials(PCMs)toachieve a three-dimensional(3D)interconnectedporous carbon aerogel structure for encapsulating polyethyleneglycol(PEG).Anovelhomogeneity reinforced carbonaerogel witha well-interconnected porous structure was constructed bycombining a flexible carbonresource from biomass guar gum with hard-brittle carbonfrom polyimide,to overcome severeshrinkage andpoor mechanical performance of traditionalcarbon aerogel.Thesupportingcarbon aerogel-encapsulated PEG produced thenovel composite PCMswithgood structure stability andcomprehensive energy storage performance.Theresults showed thatthecomposite PCMsdisplayed awell-defined 3Dinterconnected structure,and theirenergy storage capacities were 171.5 and169.5 J/g,which changed onlyslightlyafter 100 thermalcycles,andthe compositescould maintainthe equilibrium temperature at50.0−58.1℃ for about 760.3 s.The thermal conductivityofthe compositescould reach0.62 W m^(−1) K^(−1),which effectively enhanced the thermalresponse rate.And thecomposite PCMs exhibited good leakage-proof performance andexcellent light–thermal conversion.The compressive strengthof thecomposite PCMscan improveupto 1.602 MPa.Results indicatethatthisstrategy canbe efficiently usedtodevelop novel composite PCMswithimproved comprehensive thermalperformance and high light–thermal conversion.
基金supported by the Applied Technology Research and Development program of Heilongjiang Province(GA19C006)the Innovation Foundation for Doctoral Program of Forestry Engineering of Northeast Forestry University(LYGC202112).
文摘Thinning is a widely used forest management tool but systematic research has not been carried out to verify its eff ects on carbon storage and plant diversity at the ecosystem level.In this study,the eff ect of thinning was assessed across seven thinning intensities(0,10,15,20,25,30 and 35%)in a low-quality secondary forest in NE China over a ten-year period.Thinning aff ected the carbon storage of trees,and shrub,herb,and soil layers(P<0.05).It fi rst increased and then decreased as thinning intensity increased,reaching its maximum at 30%thinning.Carbon storage of the soil accounted for more than 64%of the total carbon stored in the ecosystem.It was highest in the upper 20-cm soil layer.Thinning increased tree species diversity while decreasing shrub and herb diversities(P<0.05).Redundancy analysis and a correlation heat map showed that carbon storage of tree and shrub layers was positively correlated with tree diversity but negatively with herb diversity,indicating that the increase in tree diversity increased the carbon storage of natural forest ecosystems.Although thinning decreased shrub and herb diversities,it increased the carbon storage of the overall ecosystem and tree species diversity of secondary forest.Maximum carbon storage and the highest tree diversity were observed at a thinning intensity of 30%.This study provides evidence for the ecological management of natural and secondary forests and improvement of ecosystem carbon sinks and biodiversity.
基金Supported by the China National Science and Technology Major Project(2016ZX05016).
文摘The development history of carbon capture,utilization and storage for enhanced oil recovery(CCUS-EOR)in China is comprehensively reviewed,which consists of three stages:research and exploration,field test and industrial application.The breakthrough understanding of CO_(2) flooding mechanism and field practice in recent years and the corresponding supporting technical achievements of CCUS-EOR project are systematically described.The future development prospects are also pointed out.After nearly 60 years of exploration,the theory of CO_(2) flooding and storage suitable for continental sedimentary reservoirs in China has been innovatively developed.It is suggested that C7–C15 are also important components affecting miscibility of CO_(2) and crude oil.The mechanism of rapid recovery of formation energy by CO_(2) and significant improvement of block productivity and recovery factor has been verified in field tests.The CCUS-EOR reservoir engineering design technology for continental sedimentary reservoir is established.The technology of reservoir engineering parameter design and well spacing optimization has been developed,which focuses on maintaining miscibility to improve oil displacement efficiency and uniform displacement to improve sweep efficiency.The technology of CO_(2) capture,injection and production process,whole-system anticorrosion,storage monitoring and other whole-process supporting technologies have been initially formed.In order to realize the efficient utilization and permanent storage of CO_(2),it is necessary to take the oil reservoir in the oil-water transition zone into consideration,realize the large-scale CO_(2) flooding and storage in the area from single reservoir to the overall structural control system.The oil reservoir in the oil-water transition zone is developed by stable gravity flooding of injecting CO_(2) from structural highs.The research on the storage technology such as the conversion of residual oil and CO_(2) into methane needs to be carried out.
基金supported financially by the National Key Research and Development Program of China (Grants No. 2017YFA0206301)the National Natural Science Foundation of China (Grants No. 51631001 and 51631001)the China-Germany Collaboration Project (Grants No. M-0199)
文摘Potassium-ion batteries(PIBs)are potential“Beyond Li-ion Batteries”candidates for their resource advantage and low standard electrode potential.To date,the research on PIBs is in its early stages,the most urgent task is to develop high-performance electrode materials and reveal their potassium storage mechanism.For PIBs anode materials,carbon with tunable microstructure,excellent electrochemical activity,nontoxicity and low price is considered as one of the most promising anode materials for commercialization.Although some breakthrough works have emerged,the overall electrochemical performance of the reported carbon anode is still far away from practical application.Herein,we carry out a comprehensive overview of PIBs carbon anode in terms of three aspects of rational design of structure,performance evaluation criteria and characterization of potassium storage mechanism.First,the regulation mechanism of key structural features of carbon anode on its potassium storage performance and the representative structural regulation strategies are introduced.Then,in view of the undefined performance evaluation criteria of PIBs carbon anode,a reference principle for evaluating the potassium storage performance of carbon anode is proposed.Finally,the advanced characterization techniques for the potassium storage mechanism of carbon anode are summarize.This review aims to provide guidance for the development of practical PIBs anode.
基金Supported by National Natural Science Foundation of China(52304021,52204031)Natural Science Foundation of Sichuan Province(2022NSFSC0205)National Science and Technology Major Project of China(2017ZX05049006-010).
文摘Molecular dynamics method was used to establish composite wall/inorganic nanopores of three pore sizes, three shale oil systems, five CO_(2)-cosolvent systems, and pure CO_(2) system. The process of CO_(2)-cosolvent displacement of crude oil in shale nanopores and carbon storage was simulated and the influencing factors of displacement and storage were analyzed. It is shown that the attraction of the quartz wall to shale oil increases with the degree of hydroxylation. The higher the degree of quartz hydroxylation, the more difficult it is to extract the polar components of shale oil. Nanopore size also has a great impact on shale oil displacement efficiency. The larger the pore size, the higher the shale oil displacement efficiency. The closer the cosolvent molecules are to the polarity of the shale oil, the higher the mutual solubility of CO_(2) and shale oil. The more the non-polar components of shale oil, the lower the mutual solubility of CO_(2) and shale oil with highly polar cosolvent. Ethyl acetate is more effective in stripping relatively high polar shale oil, while dimethyl ether is more effective in stripping relatively low polar shale oil. Kerogen is highly adsorptive, especially to CO_(2). The CO_(2) inside the kerogen is not easy to diffuse and leak, thus allowing for a stable carbon storage. The highest CO_(2) storage rate is observed when dimethyl ether is used as a cosolvent, and the best storage stability is observed when ethyl acetate is used as a cosolvent.
基金supported by the National Natural Science Foundation of China(Grant No.11902283)the Natural Science Foundation of Hunan Province(Grant No.2019JJ50578)+1 种基金the Scientific Research Foundation of Hunan Provincial Education Department(Grant No.21B0126)the Science and Technology Innovation Program of Hunan Province(Grant No.2022RC1078)。
文摘Hard carbon(HC)is considered a promising anode material for sodium-ion batteries due to its relatively low price and high specific capacity.However,HC still suffers from unclear reaction mechanisms and unsatisfactory cycling stability.The study of mechano-electrochemical coupling behavior by in-situ measurement techniques is expected to understand the sodium storage and degradation mechanisms.In this paper,the strain and stress evolution of HC anodes at different sodiation/desodiation depths and cycles are investigated by combining electrochemical methods,digital image correlation,and theoretical equations.The observation by monitoring the in-situ strain evolution during the redox process supports the“adsorption-intercalation/filling”mechanism in reduction and the“de-filling/de-intercalation-deso rption”mechanism in oxidation.Further studies have demonstrated that the strain and stress of the electrode show periodic changes accompanied by a continuous accumulation of residual stress during cycles,explaining the capacity degradation mechanism of HC from a mechanical perspective.In addition,when the higher current density is applied,the electrodes experience greater strain and stress associated with the Na+insertion rate.This work clarifies the Na-storage mechanism and the mechano-electrochemical coupling mechanism of HC anodes by in-situ strain measurement,which helps optimize and design the anode materials of sodium-ion batteries from the perspective of interface microstructure and multi-field coupling,such as in situ integrated interface structure design.
基金supported by the National Natural Science Foundation of China (21878056)Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology (2019Z002)。
文摘The Joule-Thomson effect is one of the important thermodynamic properties in the system relevant to gas switching reforming with carbon capture and storage(CCS). In this work, a set of apparatus was set up to determine the Joule-Thomson effect of binary mixtures(CO_(2)+ H_(2)). The accuracy of the apparatus was verified by comparing with the experimental data of carbon dioxide. The Joule-Thomson coefficients(μ_(JT)) for(CO_(2)+ H_(2)) binary mixtures with mole fractions of carbon dioxide(x_(CO_(2))= 0.1, 0.26, 0.5,0.86, 0.94) along six isotherms at various pressures were measured. Five equations of state EOSs(PR,SRK, PR, BWR and GERG-2008 equation) were used to calculate the μ_(JT)for both pure systems and binary systems, among which the GERG-2008 predicted best with a wide range of pressure and temperature.Moreover, the Joule-Thomson inversion curves(JTIC) were calculated with five equations of state. A comparison was made between experimental data and predicted data for the inversion curve of CO_(2). The investigated EOSs show a similar prediction of the low-temperature branch of the JTIC for both pure and binary systems, except for the BWRS equation of state. Among all the equations, SRK has the most similar result to GERG-2008 for predicting JTIC.
基金he Australian Research Council for financial support(ARC,DE190100965,FL190100126 and CE230100032).
文摘Continuous accumulation and emission into the atmosphere of anthropogenic carbon dioxide(CO_(2)),a major greenhouse gas,has been recognized as a primary contributor to climate change associated with the global warming and acidification of oceans.This has led to drastic changes in the natural ecosystem,and hence an unhealthy ecological environment for human society.Thus,the effective mitigation of the ever increasing CO_(2)emission has been recognized as the most important global challenge.To achieve zero carbon footprint,novel materials and approaches are required for potentially reducing the CO_(2)release,while our current fossil-fuel-based energy must be replaced by renewable energy free from emissions.In this paper,porous carbons with hierarchical pore structures are promising for CO_(2)adsorption and electrochemical CO_(2)reduction owing to their high specific surface area,excellent catalytic performance,low cost and long-term stability.Since efficient gas-phased(electro)catalysis involves the access of reactants to active sites at the gas-liquid-solid triple phase,the hierarchical porous carbon materials possess multiple advantages for various CO_(2)-related applications with enhanced volumetric and gravimetric activities(e.g.,CO_(2)uptake and current density)for practical operations.Recent studies have demonstrated that porous carbon materials exhibited notable activities as CO_(2)adsorbents and provided facile conducting pathways and mass diffusion channels for efficient electrochemical CO_(2)reduction even under the high current operation conditions.Herein,we summarize recent advances in porous carbon materials for CO_(2)capture,storage,and electrochemical conversion.Prospectives and challenges on the rational design of porous carbon materials for scalable and practical CO_(2)capture and conversion are also discussed.
文摘Urban tree inventory is a great tool for gathering data that can be used by different end users. This study attempted to chart the species diversity in planted areas and measure their tree diameter at breast height to screen them for the carbon storage potential. A total of 2860 trees belonging to 36 species were recorded in the planted vegetation in parks and avenue plantation. The dominant species were Azadirachta indicia (25.5%), Conocarpus erectus (19.2%), Ficus spp. (15.5%), Tabebuia rosea (9.2%), Peitophorum pterocarpum (9.0%) and the remaining represents (21.6%) of the tree identified in this study. It was found that the highest contribution of carbon sequestration (CO<sub>2</sub> equivalent) is dominated by the Ficus spp. (30.3%) with a total of 3399.3 tCO<sub>2</sub>eq, followed by Azadirachta indicia (25.4%) with a total of 2845.2 tCO<sub>2</sub>eq and Conocarpus erectus (20.4%) with a total of 2286 tCO<sub>2</sub>eq. The entire area has the capability to sequester around 11,213.3 tCO<sub>2</sub>eq and on average of 3.9 ± 0.1 tCO<sub>2</sub>eq. In accordance with the findings, it is imperative for the preservation of a sustainable environment to have vegetation that has the capacity to store carbon. The study suggests, there is potential to increase carbon sequestration in urban cities through plantation programs on existing and new land uses and along roads.
基金Supported by the PetroChina Scientific Research and Technology Development Project (2022DJ83)。
文摘Based on more than 20-year operation of gas storages with complex geological conditions and a series of research findings, the pressure-bearing dynamics mechanism of geological body is revealed. With the discovery of gas-water flowing law of multi-cycle relative permeability hysteresis and differential utilization in zones, the extreme utilization theory targeting at the maximum amount of stored gas, maximum injection-production capacity and maximum efficiency in space utilization is proposed to support the three-in-one evaluation method of the maximum pressure-bearing capacity of geological body, maximum well production capacity and maximum peak shaving capacity of storage space. This study realizes the full potential of gas storage(storage capacity) at maximum pressure, maximum formation-wellbore coordinate production, optimum well spacing density match with finite-time unsteady flow, and peaking shaving capacity at minimum pressure, achieving perfect balance between security and capacity. Operation in gas storages, such as Hutubi in Xinjiang, Xiangguosi in Xinan, and Shuang6 in Liaohe, proves that extreme utilization theory has promoted high quality development of gas storages in China.
基金jointly supported by the National Key R&D Program of China (2018YFB0605503)the National Natural Science Foundation of China (51804112)+2 种基金the National Key R&D Program of China (2018YFC0807801)the Open Foundation of Key Laboratory of Coal Exploration and Comprehensive Utilization of Ministry of Natural Resources (KF2021-5)the Natural Science Foundation of Hunan Province of China (2018JJ3169).
文摘To accelerate the achievement of China’s carbon neutrality goal and to study the factors affecting the geologic CO_(2)storage in the Ordos Basin,China’s National Key R&D Programs propose to select the Chang 6 oil reservoir of the Yanchang Formation in the Ordos Basin as the target reservoir to conduct the geologic carbon capture and storage(CCS)of 100000 t per year.By applying the basic theories of disciplines such as seepage mechanics,multiphase fluid mechanics,and computational fluid mechanics and quantifying the amounts of CO_(2)captured in gas and dissolved forms,this study investigated the effects of seven factors that influence the CO_(2)storage capacity of reservoirs,namely reservoir porosity,horizontal permeability,temperature,formation stress,the ratio of vertical to horizontal permeability,capillary pressure,and residual gas saturation.The results show that the sensitivity of the factors affecting the gas capture capacity of CO_(2)decreases in the order of formation stress,temperature,residual gas saturation,horizontal permeability,and porosity.Meanwhile,the sensitivity of the factors affecting the dissolution capture capacity of CO_(2)decreases in the order of formation stress,residual gas saturation,temperature,horizontal permeability,and porosity.The sensitivity of the influencing factors can serve as the basis for carrying out a reasonable assessment of sites for future CO_(2)storage areas and for optimizing the design of existing CO_(2)storage areas.The sensitivity analysis of the influencing factors will provide basic data and technical support for implementing geologic CO_(2)storage and will assist in improving geologic CO_(2)storage technologies to achieve China’s carbon neutralization goal.
