Despite the pressing demand for integrated spectrometers,a solution that deliver high-performance while being practically operated is still missing.Furthermore,current integrated spectrometers lack reconfigurability i...Despite the pressing demand for integrated spectrometers,a solution that deliver high-performance while being practically operated is still missing.Furthermore,current integrated spectrometers lack reconfigurability in their performance,which is highly desirable for dynamic working scenarios.This study presents a viable solution by demonstrating a userfriendly,reconfigurable spectrometer on silicon.At the core of this innovative spectrometer is a programmable photonic circuit capable of exhibiting diverse spectral responses,which can be significantly adjusted using on-chip phase shifters.The distinguishing feature of our spectrometer lies in its inverse design approach,facilitating effortless control and efficient manipulation of the programmable circuit.By eliminating the need for intricate configuration,our design reduces power consumption and mitigates control complexity.Additionally,our reconfigurable spectrometer offers two distinct operating conditions.In the Ultra-High-Performance mode,it is activated by multiple phase-shifters and achieves exceptional spectral resolution in the picometer scale while maintaining broad bandwidth.On the other hand,the Ease-of-Use mode further simplifies the control logic and reduces power consumption by actuating a single-phase shifter.Although this mode provides a slightly degraded spectral resolution of approximately 0.3 nm,it prioritizes ease of use and is wellsuited for applications where ultra-fine spectral reconstruction is not a primary requirement.展开更多
Currently,with the advent of high-repetition-rate laser-plasma experiments,the demand for online diagnosis for the X-ray spectrum is increasing because the laser-plasma-generated X-ray spectrum is very important for c...Currently,with the advent of high-repetition-rate laser-plasma experiments,the demand for online diagnosis for the X-ray spectrum is increasing because the laser-plasma-generated X-ray spectrum is very important for characterizing electron dynamics and applications.In this study,scintillators and silicon PIN(P-type–intrinsic-N-type semiconductor)diodes were used to construct a wideband online filter stack spectrometer.The X-ray sensor and filter arrangement was optimized using a genetic algorithm to minimize the condition number of the response matrix.Consequently,the unfolding error was significantly reduced based on numerical experiments.The detector responses were quantitatively calibrated by irradiating the scintillator and PIN diode with various nuclides and comparing the measuredγ-ray peaks.A prototype 15-channel spectrometer was developed by integrating an X-ray detector with front-and back-end electronics.The prototype spectrometer could record X-ray pulse signals at a repetition rate of 1 kHz.Furthermore,an optimized spectrometer was employed to record the real-time spectra of laser-driven bremsstrahlung sources.This optimized spectrometer offers a compact solution for spectrum diagnostics of ultrashort X-ray pulses,exhibiting improved accuracy in terms of spectrum measurements and repetition rates,and could be widely used in next-generation high-repetition-rate high-power laser facilities.展开更多
An innovative monochromator shielding is designed and implemented for the cold neutron spectrometers XINGZHI and BOYA operated by Renmin University of China at China Advanced Research Reactor.Via Monte Carlo simulatio...An innovative monochromator shielding is designed and implemented for the cold neutron spectrometers XINGZHI and BOYA operated by Renmin University of China at China Advanced Research Reactor.Via Monte Carlo simulations and careful mechanical designs,a shielding configuration has been successfully developed to satisfy safety requirements of below 3μSv/h dose rate at its exterior,meanwhile fulfilling space,floor load and nonmagnetic requirements.Composite materials are utilized to form the sandwich-type shielding walls:the inner layer of boron carbide rubber,the middle layer of steel-encased lead and the outer layer of borated polyethylene.Special-shaped liftable shielding blocks are incorporated to facilitate a continuous adjustment of the neutron energy while preventing radiation leakage.Our work has demonstrated that by utilizing composite shielding materials,along with the sandwich structure and liftable shielding blocks,a compact and lightweight shielding solution can be achieved.This enables the realization of advanced neutron scattering instruments that provide expanded space of measurement,larger energy and momentum coverage,and higher flux on the sample.This shielding represents the first of its kind in neutron scattering instruments in China.Following its successful operation,it has been subsequently employed by other neutron instruments across the country.展开更多
A Johann-type X-ray spectrometer was successfully developed at the hard X-ray branch(in-vacuum undulator with a 24-mm periodic length)of the energy material beamline(E-line)at the Shanghai Synchrotron Radiation Facili...A Johann-type X-ray spectrometer was successfully developed at the hard X-ray branch(in-vacuum undulator with a 24-mm periodic length)of the energy material beamline(E-line)at the Shanghai Synchrotron Radiation Facility(SSRF).This spectrometer was utilized to implement X-ray emission spectroscopy(XES),high-energy resolution fluorescence-detected X-ray absorption spectroscopy(HERFD-XAS),and resonant inelastic X-ray scattering.Seven spherically bent crystals were positioned on the respective vertical 500-mm-diameter Rowland circles,adopting an area detector to increase the solid angle to 1.75%of 4πsr,facilitating the study of low-concentrate systems under complex reaction conditions.Operated under the atmosphere pressure,the spectrometer covers the energy region from 3.5 to 18 keV,with the Bragg angle ranging from 73°to 86°during vertical scanning.It offers a promised energy resolution of sub-eV(XES)and super-eV(HERFD-XAS).Generally,these comprehensive core-level spectroscopy methods based on hard X-rays at the E-line with an extremely high photon flux can meet the crucial requirements of a green energy strategy.Moreover,they provide substantial support for scientific advances in fundamental research.展开更多
To detect radioactive substances with low activity levels,an anticoincidence detector and a high-purity germanium(HPGe)detector are typically used simultaneously to suppress Compton scattering background,thereby resul...To detect radioactive substances with low activity levels,an anticoincidence detector and a high-purity germanium(HPGe)detector are typically used simultaneously to suppress Compton scattering background,thereby resulting in an extremely low detection limit and improving the measurement accuracy.However,the complex and expensive hardware required does not facilitate the application or promotion of this method.Thus,a method is proposed in this study to discriminate the digital waveform of pulse signals output using an HPGe detector,whereby Compton scattering background is suppressed and a low minimum detectable activity(MDA)is achieved without using an expensive and complex anticoincidence detector and device.The electric-field-strength and energy-deposition distributions of the detector are simulated to determine the relationship between pulse shape and energy-deposition location,as well as the characteristics of energy-deposition distributions for fulland partial-energy deposition events.This relationship is used to develop a pulse-shape-discrimination algorithm based on an artificial neural network for pulse-feature identification.To accurately determine the relationship between the deposited energy of gamma(γ)rays in the detector and the deposition location,we extract four shape parameters from the pulse signals output by the detector.Machine learning is used to input the four shape parameters into the detector.Subsequently,the pulse signals are identified and classified to discriminate between partial-and full-energy deposition events.Some partial-energy deposition events are removed to suppress Compton scattering.The proposed method effectively decreases the MDA of an HPGeγ-energy dispersive spectrometer.Test results show that the Compton suppression factors for energy spectra obtained from measurements on ^(152)Eu,^(137)Cs,and ^(60)Co radioactive sources are 1.13(344 keV),1.11(662 keV),and 1.08(1332 keV),respectively,and that the corresponding MDAs are 1.4%,5.3%,and 21.6%lower,respectively.展开更多
Synthetic aperture radar(SAR)and wave spectrometers,crucial in microwave remote sensing,play an essential role in monitoring sea surface wind and wave conditions.However,they face inherent limitations in observing sea...Synthetic aperture radar(SAR)and wave spectrometers,crucial in microwave remote sensing,play an essential role in monitoring sea surface wind and wave conditions.However,they face inherent limitations in observing sea surface phenomena.SAR systems,for instance,are hindered by an azimuth cut-off phenomenon in sea surface wind field observation.Wave spectrometers,while unaffected by the azimuth cutoff phenomenon,struggle with low azimuth resolution,impacting the capture of detailed wave and wind field data.This study utilizes SAR and surface wave investigation and monitoring(SWIM)data to initially extract key feature parameters,which are then prioritized using the extreme gradient boosting(XGBoost)algorithm.The research further addresses feature collinearity through a combined analysis of feature importance and correlation,leading to the development of an inversion model for wave and wind parameters based on XGBoost.A comparative analysis of this model with ERA5 reanalysis and buoy data for of significant wave height,mean wave period,wind direction,and wind speed reveals root mean square errors of 0.212 m,0.525 s,27.446°,and 1.092 m/s,compared to 0.314 m,0.888 s,27.698°,and 1.315 m/s from buoy data,respectively.These results demonstrate the model’s effective retrieval of wave and wind parameters.Finally,the model,incorporating altimeter and scatterometer data,is evaluated against SAR/SWIM single and dual payload inversion methods across different wind speeds.This comparison highlights the model’s superior inversion accuracy over other methods.展开更多
The accuracy(repeatability and reproducibility) of the iron content analysis of galvanized coating using an X-ray fluorescence spectrometer with an L-spectrum is not better than that of flame atomic absorption spectro...The accuracy(repeatability and reproducibility) of the iron content analysis of galvanized coating using an X-ray fluorescence spectrometer with an L-spectrum is not better than that of flame atomic absorption spectrometry, sometimes it exceeds the quality control limit.Influences, such as current, voltage, equipment(internal circulating water, 10%CH4+90%Ar, and vacuum) checking, instrument monitoring, sample cleaning, and oper-ators, were investigated by means of 6-sigma and lean operations to improve accuracy.展开更多
Laser-driven proton-induced x-ray emission(laser-PIXE) is a nuclear analysis method based on the compact laser ion accelerator. Due to the transient process of ion acceleration, the laser-PIXE signals are usually spur...Laser-driven proton-induced x-ray emission(laser-PIXE) is a nuclear analysis method based on the compact laser ion accelerator. Due to the transient process of ion acceleration, the laser-PIXE signals are usually spurted within nanoseconds and accompanied by strong electromagnetic pulses(EMP), so traditional multi-channel detectors are no longer applicable.In this work, we designed a reflective elliptical crystal spectrometer for the diagnosis of laser-PIXE. The device can detect the energy range of 1 keV–11 ke V with a high resolution. A calibration experiment was completed on the electrostatic accelerator of Peking University using samples of Al, Ti, Cu, and ceramic artifacts. The detection efficiency of the elliptical crystal spectrometer was obtained in the order of 10-9.展开更多
[Objectives]This study was conducted to establish an uncertainty evaluation method for the determination of ethyl maltol by ultra-high performance liquid chromatograph-mass spectrometer(UPLC-MS).[Methods]A mathematica...[Objectives]This study was conducted to establish an uncertainty evaluation method for the determination of ethyl maltol by ultra-high performance liquid chromatograph-mass spectrometer(UPLC-MS).[Methods]A mathematical model of uncertainty was established by analyzing the method for determining ethyl maltol using UPLC-MS.The sources of uncertainty were analyzed,and the components of uncertainty were calculated to evaluate the expanded uncertainty of the method.[Results]When the content of ethyl maltol in edible vegetable oil was 1657μg/kg,the expanded uncertainty was 22.4μg/kg(K=2,P=95%).[Conclusions]The uncertainty in this evaluation model mainly came from standard solution preparation,sample weighing,dilution of sample to constant volume,standard curve fitting,and repeated measurement.展开更多
A combination of high-field asymmetric waveform ion mobility spectrometry （FAIMS） with mass spectrometer （MS） was analyzed. FAIMS separates ions from the volatile organic compounds in the gas-phase as an ion-filte...A combination of high-field asymmetric waveform ion mobility spectrometry （FAIMS） with mass spectrometer （MS） was analyzed. FAIMS separates ions from the volatile organic compounds in the gas-phase as an ion-filter for MS. The sample ions were created at ambient pressure by ion source, which was equipped with a 10.6 eV UV discharge lamp （A=116.5 nm）. The drift tube of FAIMS is composed of two parallel planar electrodes and the dimension is 10 mm×8 mm×0.5 mm. FAIMS was investigated when driven by the high-filed rectangular asymmetric waveform with the peak-to-peak voltage of 1.36 kV at the frequency of 1 MHz and the duty cycle of 30%. The acetone, the butanone, and their mixture were adopted to characterize the FAIMS-MS. The mass spectra obtained from MS illustrate that there are ion-molecular reactions between the ions and the sample neutral molecular. And the proton transfer behavior in the mixture of the acetone and the butanone is also observed. With the compensation voltage tuned from -30 V to 10 V with a step size of 0.1 V, the ion pre-separation before MS is realized.展开更多
A wide-range and phase-locked Michelson interferometer technique is described. This technique combined with femtosecond laser is used to measure the spectrum of the rare-earth ion Nd：YVO4, which presents very high si...A wide-range and phase-locked Michelson interferometer technique is described. This technique combined with femtosecond laser is used to measure the spectrum of the rare-earth ion Nd：YVO4, which presents very high signal to noise ratio of interferometric intensity output and higher spectral resolution than traditional grating spectrophotometer.展开更多
A simple negative ion mobility spectrometer （IMS） is designed and used to investi- gate the factors that influence the number and efficiency of electrons generated by the needle-ring pulsed corona discharge electron...A simple negative ion mobility spectrometer （IMS） is designed and used to investi- gate the factors that influence the number and efficiency of electrons generated by the needle-ring pulsed corona discharge electron source. Simulation with Ansoft Maxwell 12 is carried out to analyze the electric field distribution within the IMS, and to offer the basis and foundation for analyzing the measurement results. The measurement results of the quantities of electrons show that when the drift electric field strength and the ring inner diameter rise, both the number of ef- fective electrons and the effective electron rate are increased. When the discharge voltage becomes stronger, the number of effective electrons goes up while the effective electron rate goes down. In light of the simulation results, mechanisms underlying the effects of drift electric field strength, ring inner diameter, and discharge voltage on the effective electron number and effective electron rate are discussed. These will make great sense for designing negative ion mode IMS using the needle-ring pulsed corona discharge as the electron source.展开更多
The miniature design technology is an important trend in space exploration.Mass spectrometer is used extensively in the space environment detection.The miniature ion mass spectrometer utilizes a 127° cylindrical ...The miniature design technology is an important trend in space exploration.Mass spectrometer is used extensively in the space environment detection.The miniature ion mass spectrometer utilizes a 127° cylindrical electrostatic analyzer accompanied with a Time of Flight(TOF)unit based on ultrathin carbon foil to measure the energy spectra and composition of space plasma.The Time of Flight technique has been used broadly in space plasma measurement.A new type of miniature method for the ion mass spectrometer is introduced.The total mass of the instrument is1.8 kg and the total power consumption is 2.0 W.The calibration results show that the energy measurement range is 8.71~43550eV,the energy resolution is 1.86%and the ion mass from 1 amu(1 amu= 1.67 × 10^(-27)kg) to 58 amu can be resolved by the miniature mass spectrometer.The miniature ion mass spectrometer also has a potential to be increased in the field of view by an electrostatic deflecting system to extend its application in space plasma detection.The miniature ion mass spectrometer has been selected for pre-study of Chinese Strategic Priority Research Program on Space Science.展开更多
Fine particle of organic aerosol （OA）, mostly arising from pollution, are abundant in Beijing. To achieve a better un- derstanding of the difference in OA in summer and autumn, a high-resolution time-of-flight aeros...Fine particle of organic aerosol （OA）, mostly arising from pollution, are abundant in Beijing. To achieve a better un- derstanding of the difference in OA in summer and autumn, a high-resolution time-of-flight aerosol mass spectrometer （HR- ToF-AMS, Aerodyne Research Inc., USA） was deployed in urban Beijing in August and October 2012. The mean OA mass concentration in autumn was 30 4-30 μg m-3, which was higher than in summer （13 4-6.9 μg m-3）. The elemental anal- ysis found that OA was more aged in summer （oxygen-to-carbon （O/C） ratios were 0.41 and 0.32 for summer and autumn, respectively）. Positive matrix factorization （PMF） analysis identified three and five components in summer and autumn, re- spectively. In summer, an oxygenated OA （OOA）, a cooking-emission-related OA （COA）, and a hydrocarbon-like OA （HOA） were indentified. Meanwhile, the OOA was separated into LV-OOA （low-volatility OOA） and SV-OOA （semi-volatile OOA）; and in autumn, a nitrogen-containing OA （NOA） was also found. The SOA （secondary OA） was always the most important OA component, accounting for 55% of the OA in the two seasons. Back trajectory clustering analysis found that the origin of the air masses was more complex in summer. Southerly air masses in both seasons were associated with the highest OA loading, while northerly air masses were associated with the lowest OA loading. A preliminary study of OA components, especially the POA （primary OA）, in different periods found that the HOA and COA all decreased during the National Day holiday period, and HOA decreased at weekends compared with weekdays.展开更多
A real-time Bonner sphere spectrometer(BSS)has been developed for spectral neutron measurements with the HL-2A Tokamak.To correct and verify the accuracy of the neutron spectrum from the BSS,the BSS system was calibra...A real-time Bonner sphere spectrometer(BSS)has been developed for spectral neutron measurements with the HL-2A Tokamak.To correct and verify the accuracy of the neutron spectrum from the BSS,the BSS system was calibrated using monoenergetic neutron beams in the energy range of 100 keV–5 MeV.The response function of the BSS was corrected based on the calibration results,and the corrected BSS system was verified by unfolding monoenergetic neutron spectra.Fusion neutron spectra on the HL-2A have been obtained from the calibrated BSS system for the first time.展开更多
A real-time double-ring neutron time-of-flight(TOFII) spectrometer system has been proposed to achieve plasma diagnosis on HL-2M tokamak with a relatively high count rate and sufficient energy resolution.The TOFII sys...A real-time double-ring neutron time-of-flight(TOFII) spectrometer system has been proposed to achieve plasma diagnosis on HL-2M tokamak with a relatively high count rate and sufficient energy resolution.The TOFII system is in its development stage,and this work describes its characteristics in terms of design principle,system structure,electronic system design,preliminary tests,and neutron transport simulation.The preliminary test results illustrate that the TOFII system can demonstrate the realtime dynamic spectrum every 10 ms.The results also show that based on the support vector machine method,the n-γ discrimination algorithm achieves the discrimination accuracy of 99.1%with a figure of merit of 1.30,and the intrinsic timing resolution of the system is within 0.3%.The simulated flight time spectrums from 1 to 5 MeV are obtained through the Monte Carlo tool Geant4,which also provide the reasonable results.The TOFII system will then be calibrated on mono-energetic neutron sources for further verification.展开更多
A new neutron-gamma discriminator based on the support vector machine(SVM) method is proposed to improve the performance of the time-of-flight neutron spectrometer. The neutron detector is an EJ-299-33 plastic scintil...A new neutron-gamma discriminator based on the support vector machine(SVM) method is proposed to improve the performance of the time-of-flight neutron spectrometer. The neutron detector is an EJ-299-33 plastic scintillator with pulse-shape discrimination(PSD) property. The SVM algorithm is implemented in field programmable gate array(FPGA) to carry out the real-time sifting of neutrons in neutron-gamma mixed radiation fields. This study compares the ability of the pulse gradient analysis method and the SVM method. The results show that this SVM discriminator can provide a better discrimination accuracy of 99.1%. The accuracy and performance of the SVM discriminator based on FPGA have been evaluated in the experiments. It can get a figure of merit of 1.30.展开更多
The atmospheric aerosol absorption capacity is a critical parameter determining its direct and indirect effects on cli- mate. Accurate measurement is highly desired for the study of the radiative budget of the Earth. ...The atmospheric aerosol absorption capacity is a critical parameter determining its direct and indirect effects on cli- mate. Accurate measurement is highly desired for the study of the radiative budget of the Earth. A multi-wavelength （405 rim, 532 nm, 780 nm） aerosol absorption meter based on photoacoustic spectroscopy （PAS） invovling a single cylin- drical acoustic resonator is developed for measuring the aerosol optical absorption coefficients （OACs）. A sensitivity of 1.3 Mm-l （at 532 nm） is demonstrated. The aerosol absorption meter is successfully tested through measuring the OACs of atmospheric nigrosin and ambient aerosols in the suburbs of Hefei city. The absorption cross section and absorption Angstrom exponent （AAE） for ambient aerosol are determined for characterizing the component of the ambient aerosol.展开更多
For a characteristic c-ray with interlaced overlap peak, and the case where its reliable and credible net count cannot be obtained using the current high-purity germanium(HPGe) multichannel γ-ray spectrum software, t...For a characteristic c-ray with interlaced overlap peak, and the case where its reliable and credible net count cannot be obtained using the current high-purity germanium(HPGe) multichannel γ-ray spectrum software, two new methods are proposed herein to obtain the γ-ray net peak count from the interlaced overlap peak in the HPGe cray spectrometer system, of which one is the symmetric conversion method based on Gaussian distribution and the other is where the energy average value of two close γ-rays is regarded as the γ-ray energy. The experimental results indicate that the two methods mentioned above are reliable and credible. This study is significant for the development of better γ-ray spectrum processing software for measuring complex γ-ray spectra concerning the nuclear reaction cross section, neutron activation analysis, and analysis of transuranium elements, using an HPGe detector.展开更多
The snapshot image mapping spectrometer（IMS） has advantages such as high temporal resolution,high throughput,compact structure and simple reconstructed algorithm.In recent years,it has been utilized in biomedicine,r...The snapshot image mapping spectrometer（IMS） has advantages such as high temporal resolution,high throughput,compact structure and simple reconstructed algorithm.In recent years,it has been utilized in biomedicine,remote sensing,etc.However,the system errors and various factors can cause cross talk,image degradation and spectral distortion in the system.In this research,a theoretical model is presented along with the point response function（PRF） for the IMS,and the influence of the mirror tilt angle error of the image mapper and the prism apex angle error are analyzed based on the model.The results indicate that the tilt angle error causes loss of light throughput and the prism apex angle error causes spectral mixing between adjacent sub-images.The light intensity on the image plane is reduced to 95%when the mirror tilt angle error is increased to ±100 ＂（≈ 0.028°）.The prism apex error should be controlled within the range of 0-36＂（0.01°）to ensure the designed number of spectral bands,and avoid spectral mixing between adjacent images.展开更多
基金supports from following sources:National Key R&D Program of China(grant No.2021YFB2801500)National Natural Science Foundation of China(grant No.62375126,No.62105149 and No.62334001)+1 种基金Natural Science Foundation of Jiangsu Province(grant No.BK20210288)Opening Foundation of Key Laboratory of Laser&Infrared System(Shandong University),Minister of Education Key Lab of Modern Optical Technologies of Education Ministry of China,Soochow University State Key Laboratory of Advanced Optical Communication Systems and Networks,China Specially-appointed Professor Fund of Jiangsu.
文摘Despite the pressing demand for integrated spectrometers,a solution that deliver high-performance while being practically operated is still missing.Furthermore,current integrated spectrometers lack reconfigurability in their performance,which is highly desirable for dynamic working scenarios.This study presents a viable solution by demonstrating a userfriendly,reconfigurable spectrometer on silicon.At the core of this innovative spectrometer is a programmable photonic circuit capable of exhibiting diverse spectral responses,which can be significantly adjusted using on-chip phase shifters.The distinguishing feature of our spectrometer lies in its inverse design approach,facilitating effortless control and efficient manipulation of the programmable circuit.By eliminating the need for intricate configuration,our design reduces power consumption and mitigates control complexity.Additionally,our reconfigurable spectrometer offers two distinct operating conditions.In the Ultra-High-Performance mode,it is activated by multiple phase-shifters and achieves exceptional spectral resolution in the picometer scale while maintaining broad bandwidth.On the other hand,the Ease-of-Use mode further simplifies the control logic and reduces power consumption by actuating a single-phase shifter.Although this mode provides a slightly degraded spectral resolution of approximately 0.3 nm,it prioritizes ease of use and is wellsuited for applications where ultra-fine spectral reconstruction is not a primary requirement.
基金partially supported by the Natural Science Foundation of China(Nos.12004353,11975214,11991071,11905202,12175212,and 12120101005)the Key Laboratory Foundation of the Science and Technology on Plasma Physics Laboratory(Nos.6142A04200103 and 6142A0421010).
文摘Currently,with the advent of high-repetition-rate laser-plasma experiments,the demand for online diagnosis for the X-ray spectrum is increasing because the laser-plasma-generated X-ray spectrum is very important for characterizing electron dynamics and applications.In this study,scintillators and silicon PIN(P-type–intrinsic-N-type semiconductor)diodes were used to construct a wideband online filter stack spectrometer.The X-ray sensor and filter arrangement was optimized using a genetic algorithm to minimize the condition number of the response matrix.Consequently,the unfolding error was significantly reduced based on numerical experiments.The detector responses were quantitatively calibrated by irradiating the scintillator and PIN diode with various nuclides and comparing the measuredγ-ray peaks.A prototype 15-channel spectrometer was developed by integrating an X-ray detector with front-and back-end electronics.The prototype spectrometer could record X-ray pulse signals at a repetition rate of 1 kHz.Furthermore,an optimized spectrometer was employed to record the real-time spectra of laser-driven bremsstrahlung sources.This optimized spectrometer offers a compact solution for spectrum diagnostics of ultrashort X-ray pulses,exhibiting improved accuracy in terms of spectrum measurements and repetition rates,and could be widely used in next-generation high-repetition-rate high-power laser facilities.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.12004426,U2030106,and 12304185)the National Key Scientific Instrument and Equipment Development Project of NSFC(Grant No.11227906)the National Key R&D Program of China(Grant No.2023YFA1406500)。
文摘An innovative monochromator shielding is designed and implemented for the cold neutron spectrometers XINGZHI and BOYA operated by Renmin University of China at China Advanced Research Reactor.Via Monte Carlo simulations and careful mechanical designs,a shielding configuration has been successfully developed to satisfy safety requirements of below 3μSv/h dose rate at its exterior,meanwhile fulfilling space,floor load and nonmagnetic requirements.Composite materials are utilized to form the sandwich-type shielding walls:the inner layer of boron carbide rubber,the middle layer of steel-encased lead and the outer layer of borated polyethylene.Special-shaped liftable shielding blocks are incorporated to facilitate a continuous adjustment of the neutron energy while preventing radiation leakage.Our work has demonstrated that by utilizing composite shielding materials,along with the sandwich structure and liftable shielding blocks,a compact and lightweight shielding solution can be achieved.This enables the realization of advanced neutron scattering instruments that provide expanded space of measurement,larger energy and momentum coverage,and higher flux on the sample.This shielding represents the first of its kind in neutron scattering instruments in China.Following its successful operation,it has been subsequently employed by other neutron instruments across the country.
基金supported by the National Key Research and Development Program of China(Nos.2022YFA1503801,2021YFA1600800)the Photon Science Center for Carbon Neutrality of Chinese Academy of Sciences+2 种基金Shanghai Science and Technology Development Funds(Nos.22YF1454500,23ZR1471400)the CAS Project for Young Scientists in Basic Research(No.YSBR-022)the National Natural Science Foundation of China(No.12305375)。
文摘A Johann-type X-ray spectrometer was successfully developed at the hard X-ray branch(in-vacuum undulator with a 24-mm periodic length)of the energy material beamline(E-line)at the Shanghai Synchrotron Radiation Facility(SSRF).This spectrometer was utilized to implement X-ray emission spectroscopy(XES),high-energy resolution fluorescence-detected X-ray absorption spectroscopy(HERFD-XAS),and resonant inelastic X-ray scattering.Seven spherically bent crystals were positioned on the respective vertical 500-mm-diameter Rowland circles,adopting an area detector to increase the solid angle to 1.75%of 4πsr,facilitating the study of low-concentrate systems under complex reaction conditions.Operated under the atmosphere pressure,the spectrometer covers the energy region from 3.5 to 18 keV,with the Bragg angle ranging from 73°to 86°during vertical scanning.It offers a promised energy resolution of sub-eV(XES)and super-eV(HERFD-XAS).Generally,these comprehensive core-level spectroscopy methods based on hard X-rays at the E-line with an extremely high photon flux can meet the crucial requirements of a green energy strategy.Moreover,they provide substantial support for scientific advances in fundamental research.
基金This work was supported by the National Key R&D Program of China(Nos.2022YFF0709503,2022YFB1902700,2017YFC0602101)the Key Research and Development Program of Sichuan province(No.2023YFG0347)the Key Research and Development Program of Sichuan province(No.2020ZDZX0007).
文摘To detect radioactive substances with low activity levels,an anticoincidence detector and a high-purity germanium(HPGe)detector are typically used simultaneously to suppress Compton scattering background,thereby resulting in an extremely low detection limit and improving the measurement accuracy.However,the complex and expensive hardware required does not facilitate the application or promotion of this method.Thus,a method is proposed in this study to discriminate the digital waveform of pulse signals output using an HPGe detector,whereby Compton scattering background is suppressed and a low minimum detectable activity(MDA)is achieved without using an expensive and complex anticoincidence detector and device.The electric-field-strength and energy-deposition distributions of the detector are simulated to determine the relationship between pulse shape and energy-deposition location,as well as the characteristics of energy-deposition distributions for fulland partial-energy deposition events.This relationship is used to develop a pulse-shape-discrimination algorithm based on an artificial neural network for pulse-feature identification.To accurately determine the relationship between the deposited energy of gamma(γ)rays in the detector and the deposition location,we extract four shape parameters from the pulse signals output by the detector.Machine learning is used to input the four shape parameters into the detector.Subsequently,the pulse signals are identified and classified to discriminate between partial-and full-energy deposition events.Some partial-energy deposition events are removed to suppress Compton scattering.The proposed method effectively decreases the MDA of an HPGeγ-energy dispersive spectrometer.Test results show that the Compton suppression factors for energy spectra obtained from measurements on ^(152)Eu,^(137)Cs,and ^(60)Co radioactive sources are 1.13(344 keV),1.11(662 keV),and 1.08(1332 keV),respectively,and that the corresponding MDAs are 1.4%,5.3%,and 21.6%lower,respectively.
基金The project supported by Key Laboratory of Space Ocean Remote Sensing and Application,Ministry of Natural Resources under contract No.2023CFO016the National Natural Science Foundation of China under contract No.61931025+1 种基金the Innovation Fund Project for Graduate Student of China University of Petroleum(East China)the Fundamental Research Funds for the Central Universities under contract No.23CX04042A.
文摘Synthetic aperture radar(SAR)and wave spectrometers,crucial in microwave remote sensing,play an essential role in monitoring sea surface wind and wave conditions.However,they face inherent limitations in observing sea surface phenomena.SAR systems,for instance,are hindered by an azimuth cut-off phenomenon in sea surface wind field observation.Wave spectrometers,while unaffected by the azimuth cutoff phenomenon,struggle with low azimuth resolution,impacting the capture of detailed wave and wind field data.This study utilizes SAR and surface wave investigation and monitoring(SWIM)data to initially extract key feature parameters,which are then prioritized using the extreme gradient boosting(XGBoost)algorithm.The research further addresses feature collinearity through a combined analysis of feature importance and correlation,leading to the development of an inversion model for wave and wind parameters based on XGBoost.A comparative analysis of this model with ERA5 reanalysis and buoy data for of significant wave height,mean wave period,wind direction,and wind speed reveals root mean square errors of 0.212 m,0.525 s,27.446°,and 1.092 m/s,compared to 0.314 m,0.888 s,27.698°,and 1.315 m/s from buoy data,respectively.These results demonstrate the model’s effective retrieval of wave and wind parameters.Finally,the model,incorporating altimeter and scatterometer data,is evaluated against SAR/SWIM single and dual payload inversion methods across different wind speeds.This comparison highlights the model’s superior inversion accuracy over other methods.
文摘The accuracy(repeatability and reproducibility) of the iron content analysis of galvanized coating using an X-ray fluorescence spectrometer with an L-spectrum is not better than that of flame atomic absorption spectrometry, sometimes it exceeds the quality control limit.Influences, such as current, voltage, equipment(internal circulating water, 10%CH4+90%Ar, and vacuum) checking, instrument monitoring, sample cleaning, and oper-ators, were investigated by means of 6-sigma and lean operations to improve accuracy.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 11975037 and 11921006)the National Grand Instrument Project of China (Grant Nos. 2019YFF01014400 and 2019YFF01014404)。
文摘Laser-driven proton-induced x-ray emission(laser-PIXE) is a nuclear analysis method based on the compact laser ion accelerator. Due to the transient process of ion acceleration, the laser-PIXE signals are usually spurted within nanoseconds and accompanied by strong electromagnetic pulses(EMP), so traditional multi-channel detectors are no longer applicable.In this work, we designed a reflective elliptical crystal spectrometer for the diagnosis of laser-PIXE. The device can detect the energy range of 1 keV–11 ke V with a high resolution. A calibration experiment was completed on the electrostatic accelerator of Peking University using samples of Al, Ti, Cu, and ceramic artifacts. The detection efficiency of the elliptical crystal spectrometer was obtained in the order of 10-9.
文摘[Objectives]This study was conducted to establish an uncertainty evaluation method for the determination of ethyl maltol by ultra-high performance liquid chromatograph-mass spectrometer(UPLC-MS).[Methods]A mathematical model of uncertainty was established by analyzing the method for determining ethyl maltol using UPLC-MS.The sources of uncertainty were analyzed,and the components of uncertainty were calculated to evaluate the expanded uncertainty of the method.[Results]When the content of ethyl maltol in edible vegetable oil was 1657μg/kg,the expanded uncertainty was 22.4μg/kg(K=2,P=95%).[Conclusions]The uncertainty in this evaluation model mainly came from standard solution preparation,sample weighing,dilution of sample to constant volume,standard curve fitting,and repeated measurement.
文摘A combination of high-field asymmetric waveform ion mobility spectrometry （FAIMS） with mass spectrometer （MS） was analyzed. FAIMS separates ions from the volatile organic compounds in the gas-phase as an ion-filter for MS. The sample ions were created at ambient pressure by ion source, which was equipped with a 10.6 eV UV discharge lamp （A=116.5 nm）. The drift tube of FAIMS is composed of two parallel planar electrodes and the dimension is 10 mm×8 mm×0.5 mm. FAIMS was investigated when driven by the high-filed rectangular asymmetric waveform with the peak-to-peak voltage of 1.36 kV at the frequency of 1 MHz and the duty cycle of 30%. The acetone, the butanone, and their mixture were adopted to characterize the FAIMS-MS. The mass spectra obtained from MS illustrate that there are ion-molecular reactions between the ions and the sample neutral molecular. And the proton transfer behavior in the mixture of the acetone and the butanone is also observed. With the compensation voltage tuned from -30 V to 10 V with a step size of 0.1 V, the ion pre-separation before MS is realized.
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China （No.60677051 and No.10774193） and the National Key Basic Research Special Foundation （No.G2010CB923204）.
文摘A wide-range and phase-locked Michelson interferometer technique is described. This technique combined with femtosecond laser is used to measure the spectrum of the rare-earth ion Nd：YVO4, which presents very high signal to noise ratio of interferometric intensity output and higher spectral resolution than traditional grating spectrophotometer.
基金supported by National Natural Science Foundation of China(No.51077062)
文摘A simple negative ion mobility spectrometer （IMS） is designed and used to investi- gate the factors that influence the number and efficiency of electrons generated by the needle-ring pulsed corona discharge electron source. Simulation with Ansoft Maxwell 12 is carried out to analyze the electric field distribution within the IMS, and to offer the basis and foundation for analyzing the measurement results. The measurement results of the quantities of electrons show that when the drift electric field strength and the ring inner diameter rise, both the number of ef- fective electrons and the effective electron rate are increased. When the discharge voltage becomes stronger, the number of effective electrons goes up while the effective electron rate goes down. In light of the simulation results, mechanisms underlying the effects of drift electric field strength, ring inner diameter, and discharge voltage on the effective electron number and effective electron rate are discussed. These will make great sense for designing negative ion mode IMS using the needle-ring pulsed corona discharge as the electron source.
基金Supported by the Strategic Priority Research Program on Space Science,the Chinese Academy of Sciences(XDA04071700,XDA04060202)
文摘The miniature design technology is an important trend in space exploration.Mass spectrometer is used extensively in the space environment detection.The miniature ion mass spectrometer utilizes a 127° cylindrical electrostatic analyzer accompanied with a Time of Flight(TOF)unit based on ultrathin carbon foil to measure the energy spectra and composition of space plasma.The Time of Flight technique has been used broadly in space plasma measurement.A new type of miniature method for the ion mass spectrometer is introduced.The total mass of the instrument is1.8 kg and the total power consumption is 2.0 W.The calibration results show that the energy measurement range is 8.71~43550eV,the energy resolution is 1.86%and the ion mass from 1 amu(1 amu= 1.67 × 10^(-27)kg) to 58 amu can be resolved by the miniature mass spectrometer.The miniature ion mass spectrometer also has a potential to be increased in the field of view by an electrostatic deflecting system to extend its application in space plasma detection.The miniature ion mass spectrometer has been selected for pre-study of Chinese Strategic Priority Research Program on Space Science.
基金supported by the "Strategic Priority Research Program" of the Chinese Academy of Sciences (Grant No. XDA05100100&XDB05020000)the National Natural Science Foundation of China (Grant Nos. 41230642 & 41275139)
文摘Fine particle of organic aerosol （OA）, mostly arising from pollution, are abundant in Beijing. To achieve a better un- derstanding of the difference in OA in summer and autumn, a high-resolution time-of-flight aerosol mass spectrometer （HR- ToF-AMS, Aerodyne Research Inc., USA） was deployed in urban Beijing in August and October 2012. The mean OA mass concentration in autumn was 30 4-30 μg m-3, which was higher than in summer （13 4-6.9 μg m-3）. The elemental anal- ysis found that OA was more aged in summer （oxygen-to-carbon （O/C） ratios were 0.41 and 0.32 for summer and autumn, respectively）. Positive matrix factorization （PMF） analysis identified three and five components in summer and autumn, re- spectively. In summer, an oxygenated OA （OOA）, a cooking-emission-related OA （COA）, and a hydrocarbon-like OA （HOA） were indentified. Meanwhile, the OOA was separated into LV-OOA （low-volatility OOA） and SV-OOA （semi-volatile OOA）; and in autumn, a nitrogen-containing OA （NOA） was also found. The SOA （secondary OA） was always the most important OA component, accounting for 55% of the OA in the two seasons. Back trajectory clustering analysis found that the origin of the air masses was more complex in summer. Southerly air masses in both seasons were associated with the highest OA loading, while northerly air masses were associated with the lowest OA loading. A preliminary study of OA components, especially the POA （primary OA）, in different periods found that the HOA and COA all decreased during the National Day holiday period, and HOA decreased at weekends compared with weekdays.
基金supported by the National Natural Science Foundation of China(Nos.11375195 and 11575184)
文摘A real-time Bonner sphere spectrometer(BSS)has been developed for spectral neutron measurements with the HL-2A Tokamak.To correct and verify the accuracy of the neutron spectrum from the BSS,the BSS system was calibrated using monoenergetic neutron beams in the energy range of 100 keV–5 MeV.The response function of the BSS was corrected based on the calibration results,and the corrected BSS system was verified by unfolding monoenergetic neutron spectra.Fusion neutron spectra on the HL-2A have been obtained from the calibrated BSS system for the first time.
基金partially supported by the National Science and Technology Major Project of Ministry of Science and Technology of China(Nos.2014GB109003 and 2015GB111002)the National Natural Science Foundation of China(Nos.11375195,11575184,11375004,and 11775068)
文摘A real-time double-ring neutron time-of-flight(TOFII) spectrometer system has been proposed to achieve plasma diagnosis on HL-2M tokamak with a relatively high count rate and sufficient energy resolution.The TOFII system is in its development stage,and this work describes its characteristics in terms of design principle,system structure,electronic system design,preliminary tests,and neutron transport simulation.The preliminary test results illustrate that the TOFII system can demonstrate the realtime dynamic spectrum every 10 ms.The results also show that based on the support vector machine method,the n-γ discrimination algorithm achieves the discrimination accuracy of 99.1%with a figure of merit of 1.30,and the intrinsic timing resolution of the system is within 0.3%.The simulated flight time spectrums from 1 to 5 MeV are obtained through the Monte Carlo tool Geant4,which also provide the reasonable results.The TOFII system will then be calibrated on mono-energetic neutron sources for further verification.
基金partially supported by the National Science and Technology Major Project of Ministry of Science and Technology of China (Grant Nos. 2014GB109003 and 2015GB111002)National Natural Science Foundation of China (Grant Nos. 11375195, 11575184, 11375004 and 11775068)
文摘A new neutron-gamma discriminator based on the support vector machine(SVM) method is proposed to improve the performance of the time-of-flight neutron spectrometer. The neutron detector is an EJ-299-33 plastic scintillator with pulse-shape discrimination(PSD) property. The SVM algorithm is implemented in field programmable gate array(FPGA) to carry out the real-time sifting of neutrons in neutron-gamma mixed radiation fields. This study compares the ability of the pulse gradient analysis method and the SVM method. The results show that this SVM discriminator can provide a better discrimination accuracy of 99.1%. The accuracy and performance of the SVM discriminator based on FPGA have been evaluated in the experiments. It can get a figure of merit of 1.30.
基金supported by the Open Research Fund of Key Laboratory of Atmospheric Composition and Optical Radiation,Chinese Academy of Sciencesthe National Natural Science Foundation of China(Grant Nos.41175036 and 41205120)
文摘The atmospheric aerosol absorption capacity is a critical parameter determining its direct and indirect effects on cli- mate. Accurate measurement is highly desired for the study of the radiative budget of the Earth. A multi-wavelength （405 rim, 532 nm, 780 nm） aerosol absorption meter based on photoacoustic spectroscopy （PAS） invovling a single cylin- drical acoustic resonator is developed for measuring the aerosol optical absorption coefficients （OACs）. A sensitivity of 1.3 Mm-l （at 532 nm） is demonstrated. The aerosol absorption meter is successfully tested through measuring the OACs of atmospheric nigrosin and ambient aerosols in the suburbs of Hefei city. The absorption cross section and absorption Angstrom exponent （AAE） for ambient aerosol are determined for characterizing the component of the ambient aerosol.
基金supported by the National Natural Science Foundation of China(Nos.11575090,11605099)the Young Key Teachers Training Program of He’nan Higher Education in China(No.2015GGJS-258)
文摘For a characteristic c-ray with interlaced overlap peak, and the case where its reliable and credible net count cannot be obtained using the current high-purity germanium(HPGe) multichannel γ-ray spectrum software, two new methods are proposed herein to obtain the γ-ray net peak count from the interlaced overlap peak in the HPGe cray spectrometer system, of which one is the symmetric conversion method based on Gaussian distribution and the other is where the energy average value of two close γ-rays is regarded as the γ-ray energy. The experimental results indicate that the two methods mentioned above are reliable and credible. This study is significant for the development of better γ-ray spectrum processing software for measuring complex γ-ray spectra concerning the nuclear reaction cross section, neutron activation analysis, and analysis of transuranium elements, using an HPGe detector.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61635002 and 61307020)the Changjiang Scholars and Innovative Research Team in University(PCSIRT)Program,China
文摘The snapshot image mapping spectrometer（IMS） has advantages such as high temporal resolution,high throughput,compact structure and simple reconstructed algorithm.In recent years,it has been utilized in biomedicine,remote sensing,etc.However,the system errors and various factors can cause cross talk,image degradation and spectral distortion in the system.In this research,a theoretical model is presented along with the point response function（PRF） for the IMS,and the influence of the mirror tilt angle error of the image mapper and the prism apex angle error are analyzed based on the model.The results indicate that the tilt angle error causes loss of light throughput and the prism apex angle error causes spectral mixing between adjacent sub-images.The light intensity on the image plane is reduced to 95%when the mirror tilt angle error is increased to ±100 ＂（≈ 0.028°）.The prism apex error should be controlled within the range of 0-36＂（0.01°）to ensure the designed number of spectral bands,and avoid spectral mixing between adjacent images.
