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Photooxidation of hydrochlorofluocarbons and hydrofluorocarbons initiated by OH radicals 被引量:2
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作者 Zhong Jinxian Mu Yujing Yang Wenxiang(Research Center for Eco-Environmental Sciences Chinese Academy of Sciences, Beijing 100085, China)Chen Dazhou(Chinese Center for Certified Reference Materials, Beijing 100013, China) 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 1996年第2期228-234,共7页
PhotooxidationofhydrochlorofluocarbonsandhydrofluorocarbonsinitiatedbyOHradicals¥ZhongJinxian;MuYujing;YangW... PhotooxidationofhydrochlorofluocarbonsandhydrofluorocarbonsinitiatedbyOHradicals¥ZhongJinxian;MuYujing;YangWenxiang(ResearchC... 展开更多
关键词 HYDROCHLOROFLUOROCARBONS hydrofluorocarbons PHOTOOXIDATION OH RADICALS FTIR.
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The estimated schedule and mitigation potential for hydrofluorocarbonsphase-down in China 被引量:3
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作者 LI Yi-Xi ZHANG Zhao-Yang +3 位作者 AN Min-De GAO Ding YI Li-Ying HU Jian-Xin 《Advances in Climate Change Research》 SCIE CSCD 2019年第3期174-180,共7页
As the major producer and consumer of hydrofluorocarbons (HFCs), China is obligated to phase-down HFCs to mitigate global warming if China ratifies the Kigali Amendment (KA) to the Montreal Protocol. Based on historic... As the major producer and consumer of hydrofluorocarbons (HFCs), China is obligated to phase-down HFCs to mitigate global warming if China ratifies the Kigali Amendment (KA) to the Montreal Protocol. Based on historical HFCs consumption in each sector, here we estimated historical HFCs emissions with a bottom-up method, and projected the consumption baseline and schedule for HFCs phase-down in China under the KA and the corresponding potential for emission reduction. Results showed that China's HFCs consumption and emissions in 2017 were 164,000 t (311 Mt C 2_eq) and 108 Mt C02-eq, respectively. HFCs consumption baseline was projected to be (724 ± 18) Mt C 2-eq in 2024, and China should take measures to phase-down HFCs by 2029, at the latest, to meet the requirements of the KA. HFCs consumption in 2050 under KA would reach the level of 2012 2013. Cumulative reduced consumption was estimated at 10.8 (10.1 11.6) Gt C 02-eq, and cumulative reduced emissions were estimated at 5.38 (4.90 5.64) Gt C 02-eq by 2050. 展开更多
关键词 hydrofluorocarbons(HFCs) Kigali Amendment Consumption baseline Mitigation potential
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Contribution of Hydrofluorocarbons (HFCs) and Hydrofluoro-Olefins (HFOs) Atmospheric Breakdown Products to Acidification (“Acid Rain”) in the EU at Present and in the Future
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作者 Andy Lindley Archie McCulloch Tim Vink 《Open Journal of Air Pollution》 2019年第4期81-95,共15页
While hydrogen fluoride (HF) and hydrogen chloride (HCl) are not considered main air-pollutants in the EU, they have the potential to contribute to acidification. Hydrofluorocarbons (HFCs), hydrofluoro-olefins (HFOs) ... While hydrogen fluoride (HF) and hydrogen chloride (HCl) are not considered main air-pollutants in the EU, they have the potential to contribute to acidification. Hydrofluorocarbons (HFCs), hydrofluoro-olefins (HFOs) and hydrochlorofluoro-olefins (HCFOs) are used as refrigerants and for other applications. They break down in the atmosphere to produce HF and HCl (for HCFOs) and some of these fluorocarbons also break down to produce trifluoroacetic acid (TFA). For the emissions of these fluorocarbons in the EU, a worst-case scenario estimates their theoretical potential contribution to acidification and compares it to the acidification potential for the main air pollutants contributing to acidification, which are nitrous oxides (NOx), sulphur oxides (mainly SO2), and ammonia (NH3). The Acidification Potential from these fluorocarbons in 2016 is estimated at 2, NOx, NH3, and it can be concluded that this is insignificant in the context of the main acidification air-pollutants. Assuming that the EU targets for emissions of SO2, NOx and NH3 by 2030 are achieved, the Acidification Potential from HFCs, HFOs and HCFOs in 2030 is also estimated at 2, NOx, NH3 and will remain insignificant. 展开更多
关键词 hydrofluorocarbons Hydrofluoro-Olefins ACIDIFICATION Hydrogen Fluoride
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