Prompt radiation emitted during accelerator operation poses a significant health risk,necessitating a thorough search and securing of hazardous areas prior to initiation.Currently,manual sweep methods are employed.How...Prompt radiation emitted during accelerator operation poses a significant health risk,necessitating a thorough search and securing of hazardous areas prior to initiation.Currently,manual sweep methods are employed.However,the limitations of manual sweeps have become increasingly evident with the implementation of large-scale accelerators.By leveraging advancements in machine vision technology,the automatic identification of stranded personnel in controlled areas through camera imagery presents a viable solution for efficient search and security.Given the criticality of personal safety for stranded individuals,search and security processes must be sufficiently reliable.To ensure comprehensive coverage,180°camera groups were strategically positioned on both sides of the accelerator tunnel to eliminate blind spots within the monitoring range.The YOLOV8 network model was modified to enable the detection of small targets,such as hands and feet,as well as larger targets formed by individuals near the cameras.Furthermore,the system incorporates a pedestrian recognition model that detects human body parts,and an information fusion strategy is used to integrate the detected head,hands,and feet with the identified pedestrians as a cohesive unit.This strategy enhanced the capability of the model to identify pedestrians obstructed by equipment,resulting in a notable improvement in the recall rate.Specifically,recall rates of 0.915 and 0.82were obtained for Datasets 1 and 2,respectively.Although there was a slight decrease in accuracy,it aligned with the intended purpose of the search-and-secure software design.Experimental tests conducted within an accelerator tunnel demonstrated the effectiveness of this approach in achieving reliable recognition outcomes.展开更多
This manuscript presents a research proposal to investigate how hazardous attitudes among general aviation pilots influence pilot performance in aviation accidents. General aviation pilots train to maintain safe flyin...This manuscript presents a research proposal to investigate how hazardous attitudes among general aviation pilots influence pilot performance in aviation accidents. General aviation pilots train to maintain safe flying conditions, but accidents still occur, and human factors figure prominently among the causes of aviation accidents. The levels of hazardous attitudes among pilots may influence the likelihood of engaging in risky flight behaviors that can lead to accidents. This quantitative study aims to determine whether dangerous attitudes impact risk perception in general aviation pilots. The study will focus on two specific hazardous attitudes, “Anti-Authority” and Macho” behaviors. Among the hazardous attitudes identified by the Federal Aviation Administration (FAA), the two attitudes often stand out in accident investigations and pilot narratives. While all hazardous attitudes have inherent dangers, these two attitudes tend to be more frequently cited in accident reports and investigations. Despite rigorous training in safe flying conditions, general aviation accidents still transpire due to human factors. This research hypothesizes that the five attitudes from the hazardous attitude model, particularly Anti-Authority and Macho, significantly shape pilots’ risk perception. The insights from this study would benefit stakeholders, like the Aircraft Owners and Pilots Association (AOPA), Air Safety Institute, and aviation training programs, in creating training modules tailored to reduce such attitudes.展开更多
This paper examines the management of hazardous chemicals in Chinese university laboratories,identifying key challenges and proposing improvements.It reviews current practices and safety measures,highlighting deficien...This paper examines the management of hazardous chemicals in Chinese university laboratories,identifying key challenges and proposing improvements.It reviews current practices and safety measures,highlighting deficiencies such as inadequate safety systems and insufficient awareness among personnel.The study emphasizes the necessity of tailored safety management systems,the integration of digital tracking technologies like Radio Frequency Identification,and enhanced safety training for staff.The proposed recommendations aim to mitigate risks and enhance laboratory safety and efficiency.In conclusion,the paper asserts that a comprehensive approach,encompassing improved management systems,technological advancements,and educational initiatives,is essential for safer chemical handling in academic research environments.展开更多
The coupling effect of heat absorption and release exists in the thermal decomposition of a few chemical materials.However,the impact of the above coupling on thermal hazard assessment is not considered in the literat...The coupling effect of heat absorption and release exists in the thermal decomposition of a few chemical materials.However,the impact of the above coupling on thermal hazard assessment is not considered in the literature studies.In this work,nitroguanidine(NQ)and 1,3,5-trinitro-1,3,5-triazine(RDX)are selected as representative materials to explore the influence of the coupling effect on the thermal hazard assessment of chemical materials.The linear heating experiments of NQ and RDX are carried out by a microcalorimeter and synchronous thermal analyser.The thermal decomposition curves are decoupled by advanced thermokinetics software.The thermal decomposition and kinetic parameters before and after decoupling are calculated.The results of TG experiment show that both NQ and RDX began to lose mass during the endothermic stage.The endothermic melting and exothermic decomposition of NQ and RDX are coupled within this stage.The coupling effect has different degrees of influence on its initial decomposition temperature and safety parameters.Compared with the parameters in the coupling state,the initial decomposition temperature and adiabatic induction period after decoupling decrease.The self-accelerating decomposition temperature increases,and internal thermal runaway time decreases.In the thermal hazard assessment of chemical materials with coupling effects,the calculated parameters after decoupling should be taken as an important safety index。展开更多
This study investigates how the debris cloud structure and hazardous fragment distribution vary with attack angle by simulating a circular cylinder projectile hypervelocity impinging on a thin plate using the finite e...This study investigates how the debris cloud structure and hazardous fragment distribution vary with attack angle by simulating a circular cylinder projectile hypervelocity impinging on a thin plate using the finite element-smoothed particle hydrodynamics(FE-SPH)adaptive method.Based on the comparison and analysis of the experimental and simulation results,the FE-SPH adaptive method was applied to address the hypervelocity yaw impact problem,and the variation law of the debris cloud structure with the attack angle was obtained.The screening criterion of the hazardous fragment at yaw impact is given by analyzing the debris formation obtained by the FE-SPH adaptive method,and the distribution characteristics of hazardous fragments and their relationship with the attack angle are given.Moreover,the velocity space was used to evaluate the distribution range and damage capability of asymmetric hazardous fragments.The maximum velocity angle was extended from fully symmetrical working conditions to asymmetrical cases to describe the asymmetrical debris cloud distribution range.In this range,the energy density was calculated to quantitatively analyze how much damage hazardous fragments inflict on the rear plate.The results showed that the number of hazardous fragments generated by the case near the 35°attack angle was the largest,the distribution range was the smallest,and the energy density was the largest.These results suggest that in this case,debris cloud generated by the impact had the strongest damage to the rear plate.展开更多
Proper waste management models using recent technologies like computer vision,machine learning(ML),and deep learning(DL)are needed to effectively handle the massive quantity of increasing waste.Therefore,waste classif...Proper waste management models using recent technologies like computer vision,machine learning(ML),and deep learning(DL)are needed to effectively handle the massive quantity of increasing waste.Therefore,waste classification becomes a crucial topic which helps to categorize waste into hazardous or non-hazardous ones and thereby assist in the decision making of the waste management process.This study concentrates on the design of hazardous waste detection and classification using ensemble learning(HWDC-EL)technique to reduce toxicity and improve human health.The goal of the HWDC-EL technique is to detect the multiple classes of wastes,particularly hazardous and non-hazardous wastes.The HWDC-EL technique involves the ensemble of three feature extractors using Model Averaging technique namely discrete local binary patterns(DLBP),EfficientNet,and DenseNet121.In addition,the flower pollination algorithm(FPA)based hyperparameter optimizers are used to optimally adjust the parameters involved in the EfficientNet and DenseNet121 models.Moreover,a weighted voting-based ensemble classifier is derived using three machine learning algorithms namely support vector machine(SVM),extreme learning machine(ELM),and gradient boosting tree(GBT).The performance of the HWDC-EL technique is tested using a benchmark Garbage dataset and it obtains a maximum accuracy of 98.85%.展开更多
The hazardous waste produced by coal-fired power plants are large in quantity and variety. It is important for ecological environment protection to properly store hazardous waste in coal-fired power plants. The enviro...The hazardous waste produced by coal-fired power plants are large in quantity and variety. It is important for ecological environment protection to properly store hazardous waste in coal-fired power plants. The environmental management of hazardous waste in coal-fired power plants started late, and there are many problems in the construction and management of their storage facilities. In this paper, taking eight typical coal-fired power plants as examples, the present problems of hazardous waste storage facilities in coal-fired power plants are analyzed, and corresponding countermeasures are put forward to solve the main common problems.展开更多
ldentification work of solid wastes ’ risks is a kind of improvement and amendment for environmental impact assessment document of constructed projectss. ln the research, waste identification is classified as per ent...ldentification work of solid wastes ’ risks is a kind of improvement and amendment for environmental impact assessment document of constructed projectss. ln the research, waste identification is classified as per entrustment source and the characteristics of pol ution accidents are analyzed, with major problems of National Catalogue of Hazardous Wastes and countermeasures proposed.展开更多
Coal is the most abundant fossil fuel in the world. Because of the growth of coal mining, coal-fired power plants and coal-burning industries, the increase of the emission of particulates(coarse, fine or ultrafine)is ...Coal is the most abundant fossil fuel in the world. Because of the growth of coal mining, coal-fired power plants and coal-burning industries, the increase of the emission of particulates(coarse, fine or ultrafine)is of great concern. There is a relationship between increasing human morbidity and mortality and progressive environmental air pollution caused by these types of particles. Thus, the knowledge of the physico-chemical composition and ambient concentrations of coal-derived nanoparticles will improve pollution control strategy. Given the current importance of this area of research, the advanced characterization of this coal combustion-derived nanoparticles/nanominerals as well as hazardous elements is likely to be one of the hottest research fields in coming days. In this review, we try to compile the existing knowledge on coal-derived nanoparticles/nanominerals and discuss the advanced level of characterization techniques for future research. This review also provides some of aspects of health risks associated with exposure to ambient nanoparticles. In addition, the presence of some of the hazardous elements in coal and coal combustion activities is also reviewed.展开更多
This article reviews the most recent advances in the development of flexible substrates used as surface-enhanced Ra-man scattering(SERS)platforms for detecting several hazardous materials(e.g.,explosives,pesticides,dr...This article reviews the most recent advances in the development of flexible substrates used as surface-enhanced Ra-man scattering(SERS)platforms for detecting several hazardous materials(e.g.,explosives,pesticides,drugs,and dyes).Different flexible platforms such as papers/filter papers,fabrics,polymer nanofibers,and cellulose fibers have been investigated over the last few years and their SERS efficacies have been evaluated.We start with an introduction of the importance of hazardous materials trace detection followed by a summary of different SERS methodologies with par-ticular attention on flexible substrates and their advantages over the nanostructures and nanoparticle-based solid/hybrid substrates.The potential of flexible SERS substrates,in conjunction with a simple portable Raman spectrometer,is the power to enable practical/on-field/point of interest applications primarily because of their low-cost and easy sampling.展开更多
Large-scale data emerge in food safety inspection and testing industry with the development of Internet technology in China.This paper was aimed at designing toxic and hazardous substance big data risk analysis algori...Large-scale data emerge in food safety inspection and testing industry with the development of Internet technology in China.This paper was aimed at designing toxic and hazardous substance big data risk analysis algorithm in food safety inspection and testing based on cloud computing^([1]).Cloud computing platform was set up to store the massive extensive data with geographical distribution,dynamic and high complexity from the Internet,and MapReduce^([2]) computational framework in cloud computing was applied to process and compute parallel data.The risk analysis results were obtained by analyzing 1000000 meat products testing data collected from the laboratory management information system based on web.The results show that food safety index IFS < 1,which proves that the food safety state is in good condition.展开更多
Objective:To evaluate the hazardous effects of fried potato chips upon the retina of two developmental stages of the albino rats aged 7 and 14 days from parturition.Methods:Pregnant rats were arranged into two groups:...Objective:To evaluate the hazardous effects of fried potato chips upon the retina of two developmental stages of the albino rats aged 7 and 14 days from parturition.Methods:Pregnant rats were arranged into two groups:control pregnant rats and consequently their delivered newborns until reaching 7 and 14 days old from parturition and fried potato chips group in which pregnant rats at the 6th day of gestation maintained on diet formed of fried potato chips supplied from the market mixed with standard diet at a concentration of 50%per each till 7 and 14 postpartum.Three fold integrated approaches were adopted,namely,histological,ultrastructural and proteomic analysis.Results:Histological examination of the retina of the experimental offsprings revealed many histopathological changes,including massive degeneration,vacuolization and cell loss in the ganglion cell layer,as well as general reduction in retinal size.At the ultrastructural level,the retina of experimental offsprings exhibited number of deformities,including ill differentiated and degenerated nuclear layer,malformed and vacuolated pigment epithelium with vesiculated and fragmented rough endoplasmic reticulum,degenerated outer segment of photoreceptors,as well as swollen choriocapillaris and loss of neuronal cells.Proteomic analysis of retina of the two experimental developmental stages showed variations in the expressed proteins as a result of intoxication which illustrated the adverse toxic effects of fried potato chips upon the retina.Conclusions:It can be concluded that the effect of fried potato chips on the development of retina in rats may be due to the presence of acrylamide or its metabolite.展开更多
Roads are one of the most important infrastructures in any country. One problem on road based transportation networks is accident. Current methods to identify of high potential segments of roads for accidents are base...Roads are one of the most important infrastructures in any country. One problem on road based transportation networks is accident. Current methods to identify of high potential segments of roads for accidents are based on statistical approaches that need statistical data of accident occurrences over an extended period of time so this cannot be applied to newly-built roads. In this research a new approach for road hazardous segment identification (RHSI) is introduced using Geospatial Information System (GIS) and fuzzy reasoning. In this research among all factors that usually play critical roles in the occurrence of traffic accidents, environmental factors and roadway design are considered. Using incomplete data the consideration of uncertainty is herein investigated using fuzzy reasoning. This method is performed in part of Iran's transit roads (Kohin-Loshan) for less expensive means of analyzing the risks and road safety in Iran. Comparing the results of this approach with existing statistical methods shows advantages when data are uncertain and incomplete, specially for recently built transportation roadways where statistical data are limited. Results show in some instances accident locations are somewhat displaced from the segments of highest risk and in few sites hazardous segments are not determined using traditional statistical methods.展开更多
The achievement progresses of investigation and studies on marine hazardous geology are summarized and presentsd in the late 20 century in China. The importance, research value and present-day studies of marine hazard...The achievement progresses of investigation and studies on marine hazardous geology are summarized and presentsd in the late 20 century in China. The importance, research value and present-day studies of marine hazardous geology, a newly developing branch of geoscience, are well expatiated. Several often confused concepts and theories are explained and redefined here. The comment on the means of investigations, assessment of marine hazardous geology, as well as its evolution, innovation, existing questions and future tasks are also introduced and presented. The concepts of 'hazard geology', geohazard', 'map of marine hazard geology', 'integrated evaluaton on seafloor stablity' are respectively discussed, including their definition, research objects, methods and contents. The types and classification of marine hazardous geology, principles and methods of marine hazardous geology map compilation, the assessment methods and models of marine hazardous geology environment and seafloor stability and so on are also discussed.展开更多
As industrialization accelerates and the amount of hazardous waste generated gradually increases,the means of disposal of hazardous waste is of increasing concern.In this paper,a 40 t/d counter-fow rotary kiln inciner...As industrialization accelerates and the amount of hazardous waste generated gradually increases,the means of disposal of hazardous waste is of increasing concern.In this paper,a 40 t/d counter-fow rotary kiln incineration system owned by a Jiangsu environmental protection company was researched.The software Aspen Plus was used to build the mixed pyrolysis model and the software Fluent was used to build the computational fuid dynamics model of the incineration system.The infuence of the calorifc value of the hazardous waste,the operating temperature and the air supply on the operational efectiveness of the incineration system were analyzed by varying the simulation conditions.The results show that the SO_(x)and NO_(x)content of the product is lower when the operating temperature is above 800℃.The incineration system could only operate above 800℃when the calorifc value of the hazardous waste is not less than 1500 kcal/kg.The incineration system operated best at a primary air velocity of 1.5 m/s.The simulation results in this paper serve as a guide for the operation of counter-fow rotary kiln incineration systems.展开更多
The analyses of different sulfur forms, the trace elements in pyrites using electron microprobe and the trace elements in coal using INAA (instrumental neutron activation analysis) of the Late Paleozoic coals from the...The analyses of different sulfur forms, the trace elements in pyrites using electron microprobe and the trace elements in coal using INAA (instrumental neutron activation analysis) of the Late Paleozoic coals from the Taozao coalfield in Shandong Province, China, conclude that most sulfur (>75 %) in high-sulfur coal of Taiyuan Formation occurred as pyrite, in which many hazardous elements co-existed and their concentrations varied with their geological origin. The concentrations of hazardous elements in high-sulfur coals from Taiyuan Formation, composing mainly of Cu, As, U, Pb, Mo and Co, are much higher than those in the low-sulfur coals from Shanxi Formation and Shihezi Formation, because the influence of seawater during and after coal accumulation in Taiyuan Formation is stronger than those in Shanxi and Shihezi formations. Moreover, the element As is related to Fe, and both elements exist mainly in the form of pyrite. The element U is richer in the coal influenced by seawater. In addition, the coal affected by the magmatism contains more U, too. When high-sulfur coals are processed with heavy media washing to remove sulfur and minerals, the majority of hazardous elements will also be removed from the coals.展开更多
This article describes the investigation of hazardous waste (HW) in the Three Gorges Area of Chongqing region, which indicates that by May 2002, the dumped HW therein amounted to 14 600 t and was mainly distributed in...This article describes the investigation of hazardous waste (HW) in the Three Gorges Area of Chongqing region, which indicates that by May 2002, the dumped HW therein amounted to 14 600 t and was mainly distributed in five districts and counties with 11 000 t in Fuling, 1 650 t in Fengdu, 950 t in Wanzhou; 630 t in Wushan and 430 t in Yunyang. The total amount was composed of 9 670 t chromic residue, 2 310 t waste oil and residue, 410 t waste (false) fertilizer, 28 t waste chemical medicine, 26 t waste materials and 2 200 t other things including acid residue, waste asbestos, fluorine silicate, pigment, additive, waste acid, alkali, nitric acid, vitriol, lead mud, storage battery, calcium carbide, potassium cyanide, polluted soil, discard dynamite, waste packing barrel of cyanides, etc. In all of the HW, 578 t can be treated by chemical neutralization and stabilization technology such as redox, chemical precipitation, acid and alkali neutralization, etc., and the rest is temporarily untreatble and should be removed and piled at a temporary storage site above the 177 m water level of the dam with an aim to be transported to a future disposal site for innocuous treatment.展开更多
Studied the content and distribution of 18 environmental hazardous trace elementsin the lignite, fatty coal, anthracite and its burnt products by combustion simulatingexpriment in the one-dismensinal boiler.The transf...Studied the content and distribution of 18 environmental hazardous trace elementsin the lignite, fatty coal, anthracite and its burnt products by combustion simulatingexpriment in the one-dismensinal boiler.The transformations and concentration of 18 traceelements during different coal combustion were discussed.The results show that there aresome content distribution of 18 hazardous trace elements in every burnt product, but thelaw of concentration and dispersion of every trace element during different coal combustionis very different.Experiment results indicate that the transformation and concentrationof trace elements during coal combustion are related to the element contents and occur-rencesof trace elements in raw coal, but are also affected by some man-made factorssuch as the combustion method of boiler, combustion temperature and atmosphere, thetype of precipitators and so on.展开更多
A puff model for the dispersion of material from fugitive hazardous emissions is presented. For vertical diffusion the model is based on general techniques for solving time dependent advection-diffusion equation: the ...A puff model for the dispersion of material from fugitive hazardous emissions is presented. For vertical diffusion the model is based on general techniques for solving time dependent advection-diffusion equation: the ADMM (Advection Diffusion Multilayer Method) and GILTT (Generalized Integral Laplace Transform Technique) techniques. Both approaches accept wind and eddy diffusion coefficients with any restriction in their height functions. Comparisons between values predicted by the models against experimental ground-level concentrations (from Copenhagen data set) are shown. The preliminary results confirm the applicability of the approaches proposed and are promising for future work.展开更多
Newly acquired high-resolution shallow seismic profiles(7069 km in length) in the coastal and offshore areas of Zhejiang Province, East China Sea, China, have revealed eight marine hazardous geological features: shall...Newly acquired high-resolution shallow seismic profiles(7069 km in length) in the coastal and offshore areas of Zhejiang Province, East China Sea, China, have revealed eight marine hazardous geological features: shallow gas, sand ridges, erosion ditches, scarps, irregular bedrock features, underwater shoals, buried paleo-channels, and submarine deltas. Based on the seismic profiles, we have constructed a marine geological map of these hazardous features. Shallow gas accumulations are common and occur mainly in two separate nearshore regions that cover 4613 and 3382 km^2 respectively. There are also scattered shallow gas accumulations in the offshore area, typically accompanied by paleo-channels that occur mainly in the middle of the study area. Sand ridges, erosion ditches, scarps, and irregular bedrock features are found mainly in the northeast of the study area in association with each other. In the southeastern part of the study area, the sand ridges have a linear form and trend NW–SE, representing the western part of the linear sand ridges in the East China Sea. The maximum slope gradient is 1?, which suggests that this area is prone to landslides. These hazardous marine geological features are important to marine and engineering activities in this region.展开更多
文摘Prompt radiation emitted during accelerator operation poses a significant health risk,necessitating a thorough search and securing of hazardous areas prior to initiation.Currently,manual sweep methods are employed.However,the limitations of manual sweeps have become increasingly evident with the implementation of large-scale accelerators.By leveraging advancements in machine vision technology,the automatic identification of stranded personnel in controlled areas through camera imagery presents a viable solution for efficient search and security.Given the criticality of personal safety for stranded individuals,search and security processes must be sufficiently reliable.To ensure comprehensive coverage,180°camera groups were strategically positioned on both sides of the accelerator tunnel to eliminate blind spots within the monitoring range.The YOLOV8 network model was modified to enable the detection of small targets,such as hands and feet,as well as larger targets formed by individuals near the cameras.Furthermore,the system incorporates a pedestrian recognition model that detects human body parts,and an information fusion strategy is used to integrate the detected head,hands,and feet with the identified pedestrians as a cohesive unit.This strategy enhanced the capability of the model to identify pedestrians obstructed by equipment,resulting in a notable improvement in the recall rate.Specifically,recall rates of 0.915 and 0.82were obtained for Datasets 1 and 2,respectively.Although there was a slight decrease in accuracy,it aligned with the intended purpose of the search-and-secure software design.Experimental tests conducted within an accelerator tunnel demonstrated the effectiveness of this approach in achieving reliable recognition outcomes.
文摘This manuscript presents a research proposal to investigate how hazardous attitudes among general aviation pilots influence pilot performance in aviation accidents. General aviation pilots train to maintain safe flying conditions, but accidents still occur, and human factors figure prominently among the causes of aviation accidents. The levels of hazardous attitudes among pilots may influence the likelihood of engaging in risky flight behaviors that can lead to accidents. This quantitative study aims to determine whether dangerous attitudes impact risk perception in general aviation pilots. The study will focus on two specific hazardous attitudes, “Anti-Authority” and Macho” behaviors. Among the hazardous attitudes identified by the Federal Aviation Administration (FAA), the two attitudes often stand out in accident investigations and pilot narratives. While all hazardous attitudes have inherent dangers, these two attitudes tend to be more frequently cited in accident reports and investigations. Despite rigorous training in safe flying conditions, general aviation accidents still transpire due to human factors. This research hypothesizes that the five attitudes from the hazardous attitude model, particularly Anti-Authority and Macho, significantly shape pilots’ risk perception. The insights from this study would benefit stakeholders, like the Aircraft Owners and Pilots Association (AOPA), Air Safety Institute, and aviation training programs, in creating training modules tailored to reduce such attitudes.
文摘This paper examines the management of hazardous chemicals in Chinese university laboratories,identifying key challenges and proposing improvements.It reviews current practices and safety measures,highlighting deficiencies such as inadequate safety systems and insufficient awareness among personnel.The study emphasizes the necessity of tailored safety management systems,the integration of digital tracking technologies like Radio Frequency Identification,and enhanced safety training for staff.The proposed recommendations aim to mitigate risks and enhance laboratory safety and efficiency.In conclusion,the paper asserts that a comprehensive approach,encompassing improved management systems,technological advancements,and educational initiatives,is essential for safer chemical handling in academic research environments.
基金the project of the Open Research Fund Program of Science and Technology on Aerospace Chemical Power Laboratory(Grant No.STACPL320221B04)Key Laboratory of Explosion Science and Technology(Beijing Institute of Technology)The project number is ZDKT21-01.
文摘The coupling effect of heat absorption and release exists in the thermal decomposition of a few chemical materials.However,the impact of the above coupling on thermal hazard assessment is not considered in the literature studies.In this work,nitroguanidine(NQ)and 1,3,5-trinitro-1,3,5-triazine(RDX)are selected as representative materials to explore the influence of the coupling effect on the thermal hazard assessment of chemical materials.The linear heating experiments of NQ and RDX are carried out by a microcalorimeter and synchronous thermal analyser.The thermal decomposition curves are decoupled by advanced thermokinetics software.The thermal decomposition and kinetic parameters before and after decoupling are calculated.The results of TG experiment show that both NQ and RDX began to lose mass during the endothermic stage.The endothermic melting and exothermic decomposition of NQ and RDX are coupled within this stage.The coupling effect has different degrees of influence on its initial decomposition temperature and safety parameters.Compared with the parameters in the coupling state,the initial decomposition temperature and adiabatic induction period after decoupling decrease.The self-accelerating decomposition temperature increases,and internal thermal runaway time decreases.In the thermal hazard assessment of chemical materials with coupling effects,the calculated parameters after decoupling should be taken as an important safety index。
基金supported by the National Natural Science Foundation of China(Grant No.11872118,11627901)。
文摘This study investigates how the debris cloud structure and hazardous fragment distribution vary with attack angle by simulating a circular cylinder projectile hypervelocity impinging on a thin plate using the finite element-smoothed particle hydrodynamics(FE-SPH)adaptive method.Based on the comparison and analysis of the experimental and simulation results,the FE-SPH adaptive method was applied to address the hypervelocity yaw impact problem,and the variation law of the debris cloud structure with the attack angle was obtained.The screening criterion of the hazardous fragment at yaw impact is given by analyzing the debris formation obtained by the FE-SPH adaptive method,and the distribution characteristics of hazardous fragments and their relationship with the attack angle are given.Moreover,the velocity space was used to evaluate the distribution range and damage capability of asymmetric hazardous fragments.The maximum velocity angle was extended from fully symmetrical working conditions to asymmetrical cases to describe the asymmetrical debris cloud distribution range.In this range,the energy density was calculated to quantitatively analyze how much damage hazardous fragments inflict on the rear plate.The results showed that the number of hazardous fragments generated by the case near the 35°attack angle was the largest,the distribution range was the smallest,and the energy density was the largest.These results suggest that in this case,debris cloud generated by the impact had the strongest damage to the rear plate.
基金the Deanship of Scientific Research at King Khalid University for funding this work underGrant Number(RGP 2/209/42)PrincessNourah bint Abdulrahman University Researchers Supporting Project Number(PNURSP2022R136)Princess Nourah bint Abdulrahman University,Riyadh,Saudi Arabia.The authors would like to thank the Deanship of Scientific Research at Umm Al-Qura University for supporting this work by Grant Code:(22UQU4210118DSR27).
文摘Proper waste management models using recent technologies like computer vision,machine learning(ML),and deep learning(DL)are needed to effectively handle the massive quantity of increasing waste.Therefore,waste classification becomes a crucial topic which helps to categorize waste into hazardous or non-hazardous ones and thereby assist in the decision making of the waste management process.This study concentrates on the design of hazardous waste detection and classification using ensemble learning(HWDC-EL)technique to reduce toxicity and improve human health.The goal of the HWDC-EL technique is to detect the multiple classes of wastes,particularly hazardous and non-hazardous wastes.The HWDC-EL technique involves the ensemble of three feature extractors using Model Averaging technique namely discrete local binary patterns(DLBP),EfficientNet,and DenseNet121.In addition,the flower pollination algorithm(FPA)based hyperparameter optimizers are used to optimally adjust the parameters involved in the EfficientNet and DenseNet121 models.Moreover,a weighted voting-based ensemble classifier is derived using three machine learning algorithms namely support vector machine(SVM),extreme learning machine(ELM),and gradient boosting tree(GBT).The performance of the HWDC-EL technique is tested using a benchmark Garbage dataset and it obtains a maximum accuracy of 98.85%.
文摘The hazardous waste produced by coal-fired power plants are large in quantity and variety. It is important for ecological environment protection to properly store hazardous waste in coal-fired power plants. The environmental management of hazardous waste in coal-fired power plants started late, and there are many problems in the construction and management of their storage facilities. In this paper, taking eight typical coal-fired power plants as examples, the present problems of hazardous waste storage facilities in coal-fired power plants are analyzed, and corresponding countermeasures are put forward to solve the main common problems.
文摘ldentification work of solid wastes ’ risks is a kind of improvement and amendment for environmental impact assessment document of constructed projectss. ln the research, waste identification is classified as per entrustment source and the characteristics of pol ution accidents are analyzed, with major problems of National Catalogue of Hazardous Wastes and countermeasures proposed.
基金partial financial assistance of Ministry of Environment Forest and Climate Change (MoEFCC), Govt. of India (GPP-0325)
文摘Coal is the most abundant fossil fuel in the world. Because of the growth of coal mining, coal-fired power plants and coal-burning industries, the increase of the emission of particulates(coarse, fine or ultrafine)is of great concern. There is a relationship between increasing human morbidity and mortality and progressive environmental air pollution caused by these types of particles. Thus, the knowledge of the physico-chemical composition and ambient concentrations of coal-derived nanoparticles will improve pollution control strategy. Given the current importance of this area of research, the advanced characterization of this coal combustion-derived nanoparticles/nanominerals as well as hazardous elements is likely to be one of the hottest research fields in coming days. In this review, we try to compile the existing knowledge on coal-derived nanoparticles/nanominerals and discuss the advanced level of characterization techniques for future research. This review also provides some of aspects of health risks associated with exposure to ambient nanoparticles. In addition, the presence of some of the hazardous elements in coal and coal combustion activities is also reviewed.
基金financial supports from DRDO,India,for fund-ing[Project#ERIP/ER/1501138/M/01/319/D(R&D)dated 27.02.2017]support through the Institute of Eminence(IoE)project UOH/IOE/RC1/RC1-2016ob-tained vide notification F11/9/2019-U3(A)from the MHRD,India.V.R.Soma thanks DST for support through project#CRG/2019/003714 dated 31 January 2020.
文摘This article reviews the most recent advances in the development of flexible substrates used as surface-enhanced Ra-man scattering(SERS)platforms for detecting several hazardous materials(e.g.,explosives,pesticides,drugs,and dyes).Different flexible platforms such as papers/filter papers,fabrics,polymer nanofibers,and cellulose fibers have been investigated over the last few years and their SERS efficacies have been evaluated.We start with an introduction of the importance of hazardous materials trace detection followed by a summary of different SERS methodologies with par-ticular attention on flexible substrates and their advantages over the nanostructures and nanoparticle-based solid/hybrid substrates.The potential of flexible SERS substrates,in conjunction with a simple portable Raman spectrometer,is the power to enable practical/on-field/point of interest applications primarily because of their low-cost and easy sampling.
文摘Large-scale data emerge in food safety inspection and testing industry with the development of Internet technology in China.This paper was aimed at designing toxic and hazardous substance big data risk analysis algorithm in food safety inspection and testing based on cloud computing^([1]).Cloud computing platform was set up to store the massive extensive data with geographical distribution,dynamic and high complexity from the Internet,and MapReduce^([2]) computational framework in cloud computing was applied to process and compute parallel data.The risk analysis results were obtained by analyzing 1000000 meat products testing data collected from the laboratory management information system based on web.The results show that food safety index IFS < 1,which proves that the food safety state is in good condition.
文摘Objective:To evaluate the hazardous effects of fried potato chips upon the retina of two developmental stages of the albino rats aged 7 and 14 days from parturition.Methods:Pregnant rats were arranged into two groups:control pregnant rats and consequently their delivered newborns until reaching 7 and 14 days old from parturition and fried potato chips group in which pregnant rats at the 6th day of gestation maintained on diet formed of fried potato chips supplied from the market mixed with standard diet at a concentration of 50%per each till 7 and 14 postpartum.Three fold integrated approaches were adopted,namely,histological,ultrastructural and proteomic analysis.Results:Histological examination of the retina of the experimental offsprings revealed many histopathological changes,including massive degeneration,vacuolization and cell loss in the ganglion cell layer,as well as general reduction in retinal size.At the ultrastructural level,the retina of experimental offsprings exhibited number of deformities,including ill differentiated and degenerated nuclear layer,malformed and vacuolated pigment epithelium with vesiculated and fragmented rough endoplasmic reticulum,degenerated outer segment of photoreceptors,as well as swollen choriocapillaris and loss of neuronal cells.Proteomic analysis of retina of the two experimental developmental stages showed variations in the expressed proteins as a result of intoxication which illustrated the adverse toxic effects of fried potato chips upon the retina.Conclusions:It can be concluded that the effect of fried potato chips on the development of retina in rats may be due to the presence of acrylamide or its metabolite.
文摘Roads are one of the most important infrastructures in any country. One problem on road based transportation networks is accident. Current methods to identify of high potential segments of roads for accidents are based on statistical approaches that need statistical data of accident occurrences over an extended period of time so this cannot be applied to newly-built roads. In this research a new approach for road hazardous segment identification (RHSI) is introduced using Geospatial Information System (GIS) and fuzzy reasoning. In this research among all factors that usually play critical roles in the occurrence of traffic accidents, environmental factors and roadway design are considered. Using incomplete data the consideration of uncertainty is herein investigated using fuzzy reasoning. This method is performed in part of Iran's transit roads (Kohin-Loshan) for less expensive means of analyzing the risks and road safety in Iran. Comparing the results of this approach with existing statistical methods shows advantages when data are uncertain and incomplete, specially for recently built transportation roadways where statistical data are limited. Results show in some instances accident locations are somewhat displaced from the segments of highest risk and in few sites hazardous segments are not determined using traditional statistical methods.
文摘The achievement progresses of investigation and studies on marine hazardous geology are summarized and presentsd in the late 20 century in China. The importance, research value and present-day studies of marine hazardous geology, a newly developing branch of geoscience, are well expatiated. Several often confused concepts and theories are explained and redefined here. The comment on the means of investigations, assessment of marine hazardous geology, as well as its evolution, innovation, existing questions and future tasks are also introduced and presented. The concepts of 'hazard geology', geohazard', 'map of marine hazard geology', 'integrated evaluaton on seafloor stablity' are respectively discussed, including their definition, research objects, methods and contents. The types and classification of marine hazardous geology, principles and methods of marine hazardous geology map compilation, the assessment methods and models of marine hazardous geology environment and seafloor stability and so on are also discussed.
基金supported by the National Key R&D Program of China(No.2018YFC1902600)。
文摘As industrialization accelerates and the amount of hazardous waste generated gradually increases,the means of disposal of hazardous waste is of increasing concern.In this paper,a 40 t/d counter-fow rotary kiln incineration system owned by a Jiangsu environmental protection company was researched.The software Aspen Plus was used to build the mixed pyrolysis model and the software Fluent was used to build the computational fuid dynamics model of the incineration system.The infuence of the calorifc value of the hazardous waste,the operating temperature and the air supply on the operational efectiveness of the incineration system were analyzed by varying the simulation conditions.The results show that the SO_(x)and NO_(x)content of the product is lower when the operating temperature is above 800℃.The incineration system could only operate above 800℃when the calorifc value of the hazardous waste is not less than 1500 kcal/kg.The incineration system operated best at a primary air velocity of 1.5 m/s.The simulation results in this paper serve as a guide for the operation of counter-fow rotary kiln incineration systems.
文摘The analyses of different sulfur forms, the trace elements in pyrites using electron microprobe and the trace elements in coal using INAA (instrumental neutron activation analysis) of the Late Paleozoic coals from the Taozao coalfield in Shandong Province, China, conclude that most sulfur (>75 %) in high-sulfur coal of Taiyuan Formation occurred as pyrite, in which many hazardous elements co-existed and their concentrations varied with their geological origin. The concentrations of hazardous elements in high-sulfur coals from Taiyuan Formation, composing mainly of Cu, As, U, Pb, Mo and Co, are much higher than those in the low-sulfur coals from Shanxi Formation and Shihezi Formation, because the influence of seawater during and after coal accumulation in Taiyuan Formation is stronger than those in Shanxi and Shihezi formations. Moreover, the element As is related to Fe, and both elements exist mainly in the form of pyrite. The element U is richer in the coal influenced by seawater. In addition, the coal affected by the magmatism contains more U, too. When high-sulfur coals are processed with heavy media washing to remove sulfur and minerals, the majority of hazardous elements will also be removed from the coals.
文摘This article describes the investigation of hazardous waste (HW) in the Three Gorges Area of Chongqing region, which indicates that by May 2002, the dumped HW therein amounted to 14 600 t and was mainly distributed in five districts and counties with 11 000 t in Fuling, 1 650 t in Fengdu, 950 t in Wanzhou; 630 t in Wushan and 430 t in Yunyang. The total amount was composed of 9 670 t chromic residue, 2 310 t waste oil and residue, 410 t waste (false) fertilizer, 28 t waste chemical medicine, 26 t waste materials and 2 200 t other things including acid residue, waste asbestos, fluorine silicate, pigment, additive, waste acid, alkali, nitric acid, vitriol, lead mud, storage battery, calcium carbide, potassium cyanide, polluted soil, discard dynamite, waste packing barrel of cyanides, etc. In all of the HW, 578 t can be treated by chemical neutralization and stabilization technology such as redox, chemical precipitation, acid and alkali neutralization, etc., and the rest is temporarily untreatble and should be removed and piled at a temporary storage site above the 177 m water level of the dam with an aim to be transported to a future disposal site for innocuous treatment.
基金Supported by the National Natural Science Key Foundation of China(40133010)Natural Science Foundation of China of Anhui University of Science and Technology for ph.D to Research(DG414)
文摘Studied the content and distribution of 18 environmental hazardous trace elementsin the lignite, fatty coal, anthracite and its burnt products by combustion simulatingexpriment in the one-dismensinal boiler.The transformations and concentration of 18 traceelements during different coal combustion were discussed.The results show that there aresome content distribution of 18 hazardous trace elements in every burnt product, but thelaw of concentration and dispersion of every trace element during different coal combustionis very different.Experiment results indicate that the transformation and concentrationof trace elements during coal combustion are related to the element contents and occur-rencesof trace elements in raw coal, but are also affected by some man-made factorssuch as the combustion method of boiler, combustion temperature and atmosphere, thetype of precipitators and so on.
文摘A puff model for the dispersion of material from fugitive hazardous emissions is presented. For vertical diffusion the model is based on general techniques for solving time dependent advection-diffusion equation: the ADMM (Advection Diffusion Multilayer Method) and GILTT (Generalized Integral Laplace Transform Technique) techniques. Both approaches accept wind and eddy diffusion coefficients with any restriction in their height functions. Comparisons between values predicted by the models against experimental ground-level concentrations (from Copenhagen data set) are shown. The preliminary results confirm the applicability of the approaches proposed and are promising for future work.
基金supported by the China-ASEAN maritime cooperation fund (Comparative Study of Holocene Sedimentary Evolution of the Yangtze River Delta and the Red River Delta)the National Natural Science Foundation of China (Nos. 41306063 and 41330964)the China Geology Survey (Nos. GZH201200506 and DD20 160145)
文摘Newly acquired high-resolution shallow seismic profiles(7069 km in length) in the coastal and offshore areas of Zhejiang Province, East China Sea, China, have revealed eight marine hazardous geological features: shallow gas, sand ridges, erosion ditches, scarps, irregular bedrock features, underwater shoals, buried paleo-channels, and submarine deltas. Based on the seismic profiles, we have constructed a marine geological map of these hazardous features. Shallow gas accumulations are common and occur mainly in two separate nearshore regions that cover 4613 and 3382 km^2 respectively. There are also scattered shallow gas accumulations in the offshore area, typically accompanied by paleo-channels that occur mainly in the middle of the study area. Sand ridges, erosion ditches, scarps, and irregular bedrock features are found mainly in the northeast of the study area in association with each other. In the southeastern part of the study area, the sand ridges have a linear form and trend NW–SE, representing the western part of the linear sand ridges in the East China Sea. The maximum slope gradient is 1?, which suggests that this area is prone to landslides. These hazardous marine geological features are important to marine and engineering activities in this region.
