Electric-heat coupling characteristics of a cogeneration system and the operating mode of fixing electricity with heat are the main reasons for wind abandonment during the heating season in the Three North area.To imp...Electric-heat coupling characteristics of a cogeneration system and the operating mode of fixing electricity with heat are the main reasons for wind abandonment during the heating season in the Three North area.To improve the wind-power absorption capacity and operating economy of the system,the structure of the system is improved by adding a heat storage device and an electric boiler.First,aiming at the minimum operating cost of the system,the optimal scheduling model of the cogeneration system,including a heat storage device and electric boiler,is constructed.Second,according to the characteristics of the problem,a cultural gene algorithm program is compiled to simulate the calculation example.Finally,through the system improvement,the comparison between the conditions before and after and the simulation solutions of similar algorithms prove the effectiveness of the proposed scheme.The simulation results show that adding the heat storage device and electric boiler to the scheduling optimization process not only improves the wind power consumption capacity of the cogeneration system but also reduces the operating cost of the system by significantly reducing the coal consumption of the unit and improving the economy of the system operation.The cultural gene algorithm framework has both the global evolution process of the population and the local search for the characteristics of the problem,which has a better optimization effect on the solution.展开更多
An underground heat storage system in a double-film-covered greenhouse and an adjacent greenhouse without the heat storage system were designed on the basis of plant physiology to reduce the energy consumption in gree...An underground heat storage system in a double-film-covered greenhouse and an adjacent greenhouse without the heat storage system were designed on the basis of plant physiology to reduce the energy consumption in greenhouses. The results indicated that the floor temperature was respectively 5.2℃, 4.6℃ and 2.0 ℃ higher than that of the soil in the adjacent reference greenhouse after heat storage in a clear, cloudy and overcast sky in winter. Results showed that the temperature and humidity were feasible for plant growth in the heat saving greenhouse.展开更多
The simultaneous CO_(2) capture and heat storage performances of the modified carbide slag with byproduct of biodiesel were investigated in the process coupled calcium looping and CaO/Ca(OH)2 thermochemical heat stora...The simultaneous CO_(2) capture and heat storage performances of the modified carbide slag with byproduct of biodiesel were investigated in the process coupled calcium looping and CaO/Ca(OH)2 thermochemical heat storage using air as the heat transfer fluid.The modified carbide slag with by-product of biodiesel exhibits superior CO_(2) capture and heat storage capacities in the coupled calcium looping and heat storage cycles.The hydration conversion and heat storage density of the modified carbide slag after 30 heat storage cycles are 0.65 mol·mol^(-1) and 1.14 GJ·t^(-1),respectively,which are 1.6 times as high as those of calcined carbide slag.The negative effect of CO_(2) in air as the heat storage fluid on the heat storage capacity of the modified carbide slag is overcome by introducing CO_(2) capture cycles.In addition,the CO_(2) capture reactivity of the modified carbide slag after the multiple calcium looping cycles is enhanced by the introduction of heat storage cycles.By introducing 10 heat storage cycles after the 10th and 15th CO_(2) capture cycles,the CO_(2) capture capacities of the modified carbide slag are subsequently improved by 32%and 43%,respectively.The porous and loose structure of modified carbide slag reduces the diffusion resistances of CO_(2) and steam in the material in the coupled process.The formed CaCO_(3)in the modified carbide slag as a result of air as the heat transfer fluid in heat storage cycles decomposes to regenerate CaO in calcium looping cycles,which improves heat storage capacity.Therefore,the modified carbide slag with by-product of biodiesel seems promising in the coupled calcium looping and CaO/Ca(OH)_(2) heat storage cycles.展开更多
By using the upper layer data(downloaded from the web of the Scripps Institution of Oceanography),the interannual variability of the heat storage of upper layer(from surface to 400 m depth) and the mixed layer depth i...By using the upper layer data(downloaded from the web of the Scripps Institution of Oceanography),the interannual variability of the heat storage of upper layer(from surface to 400 m depth) and the mixed layer depth in the tropical Pacific Ocean are investigated. The abnormal signal of the warm event comes from the central and west Pacific Ocean, whereas it is regarded that the abnormal signal of the warm event comes from the east Pacific Ocean in the popular viewpoint. From the viewpoint on the evolution of the interannual variability of the mixed layer depth and the heat storage of the whole upper layer, the difference between the two types of El Nino is so small that it can be neglected. During these two El Nino/La Nina events(1972/1973 and 1997/1998), other than the case of the heat storage or for the mixed layer depth, the abnormal signal propagates from the central and west Pacific Ocean to the east usually by the path along the equator whereas the abnormal signal propagates from the east to the west by the path northern to the equator. For the interannual variability, the evolution of the mixed layer depth corresponds to that of the heat storage in the upper layer very well. This is quite different from the evolution of seasonality.展开更多
Owing to its high heat storage capacity and fast heat transfer rate,packed bed latent heat storage(LHS)is considered as a promising method to store thermal energy.In a packed bed,the wall effect can impact the packing...Owing to its high heat storage capacity and fast heat transfer rate,packed bed latent heat storage(LHS)is considered as a promising method to store thermal energy.In a packed bed,the wall effect can impact the packing arrangement of phase change material(PCM)capsules,inducing radial porosity oscillation.In this study,an actual-arrangement-based three-dimensional packed bed LHS model was built to consider the radial porosity oscillation.Its fluid flow and heat transfer were analyzed.With different cylindrical sub-surfaces intercepted along the radial direction in the packed bed,the corresponding relationships between the arrangement of capsules and porosity oscillation were identified.The oscillating distribution of radial porosity led to a non-uniform distribution of heat transfer fluid(HTF)velocity.As a result,radial temperature distributions and liquid fraction distributions of PCMs were further affected.The effects of different dimensionless parameters(e.g.,tube-to-capsule diameter ratio,Reynolds number,and Stefan number)on the radial characteristics of HTF and PCMs were discussed.The results showed that different diameter ratios correspond to different radial porosity distributions.Further,with an increase in diameter ratio,HTF velocity varies significantly in the near wall region while the non-uniformity of HTF velocity in the center region will decrease.The Reynolds and Stefan numbers slightly impact the relative velocity distribution of the HTF-while higher Reynolds numbers can lead to a proportional improvement of velocity,an increase in Stefan number can promote heat storage of the packed bed LHS system.展开更多
Thermochemical heat storage(THS)systems have recently attracted a lot of attention in research and development.In this study,an anodic aluminum oxide(AAO)template,fabricated by a two-step anodization method,was used f...Thermochemical heat storage(THS)systems have recently attracted a lot of attention in research and development.In this study,an anodic aluminum oxide(AAO)template,fabricated by a two-step anodization method,was used for the first time as the matrix material for a THS system.Different salts were studied as thermochemical materials for their suitability in low-grade heat storage application driven by solar energy for an open system.Compositions were prepared by absorbing CaCl2,MgCl2,LiCl,LiNO3 and mixtures of these salts under a vacuum in an AAO matrix.Field Emission Scanning Electron Microscopy was used to examine the morphology of the produced AAO composites.Thermal energy storage capacities of the composites were characterized using a differential scanning calorimeter.Characterization analysis showed that anodized Al plates were suitable matrix materials for THS systems,and composite sorbent prepared with a 1:1 ratio LiCl/LiNO3 salt mixture had the highest energy value among all composites,with an energy density of 468.1 k J·kg-1.展开更多
The latent heat storage(LHS)technique is of crucial importance in chemical energy engineering.Inspired by multi-bifurcated fern leaves,a mimic fern-fractal fin is designed to improve the thermal energy charging effici...The latent heat storage(LHS)technique is of crucial importance in chemical energy engineering.Inspired by multi-bifurcated fern leaves,a mimic fern-fractal fin is designed to improve the thermal energy charging efficiency.This paper develops a transient melting model of a rectangular LHS unit using fern-fractal fins,and their melting behaviors are compared with the conventional fins.Besides,a parametric optimization of fernfractal fins is conducted for maximizing the thermal efficiency based on the response surface method(RSM).The results indicate that the temperature uniformity is more superior and the melting duration is shorter for the fern-fractal LHS unit when compared with the conventional one.Interestingly,the fern-fractal LHS device presents a slower heat storage rate during the initial conduction-dominated and early convection-dominated melting stages,while a prominent melting enhancement is achieved during the later melting stage.The shortest melting time is obtained based on the RSM technique when a fern-fractal fin with length ratio α=0.94 and branch angle θ=54.7°is utilized.Compared with a conventional fin,the averaged heat storage rate increases by 88.3%,and the total melting time is declined by 40.3%for an optimized fern-fractal fin.展开更多
Thermal energy storage is an attractive option for effectiveness since it gives flexibility and reduces energy consumption and costs. New composite materials for storage and transformation of heat of NaCl-Al2O3composi...Thermal energy storage is an attractive option for effectiveness since it gives flexibility and reduces energy consumption and costs. New composite materials for storage and transformation of heat of NaCl-Al2O3composite materials were synthesized by one-step synthesis method. The chemical composition, morphology, structure, and thermal properties were investigated by XRD, EDS, SEM, and DSC. The results show that NaCl can be absorbed by Al2O3particle from 800 to 900 ℃ for Al2O3particle surface is rich active structure. The results also indicate that the leakage of NaCl when the phase change can be prevented by Al2O3particles and the enthalpy of phase change of NaCl-Al2O3material is 362 J/g. The composites have an excellent heat storage capacity. Therefore, this study contributes to one new thought and method to prepare high temperature heat storage material and this material can be applied in future thermal engineering.展开更多
Availability of clean water is going to become one of biggest demands of the country. Even though there arc various technologies available for purification of water harnessing solar energy fits the purpose for future ...Availability of clean water is going to become one of biggest demands of the country. Even though there arc various technologies available for purification of water harnessing solar energy fits the purpose for future problems. Distillation is one of many processes available for water purification, and solar energy is one of several forms of heat energy that can be used to energize this process. In this review a study is made to enhance the productivity of the solar stills by connecting solar still with latent heat storage and solar air heater in series and other factors like improving evaporation rate by maintaining Low depth, more exposure area, heat addition by solar collector and presence of latent heat storage material, which is a paraffin wax as a integral part of still. Latent heat storage is one of the most efficient ways of storing thermal energy. Unlike the sensible heat storage method, the latent heat storage method provides much higher storage density, with a smaller temperature difference between storing and releasing heat. Further augmentation of the yield by scraps, pebble, and sand are added.展开更多
The CaO-based pellets were fabricated using extrusion-spheronization method for calcium looping thermochemical heat storage under the fluidization.The effects of adhesive,biomass-based pore-forming agent,binder and pa...The CaO-based pellets were fabricated using extrusion-spheronization method for calcium looping thermochemical heat storage under the fluidization.The effects of adhesive,biomass-based pore-forming agent,binder and particle size on the heat storage performance and mechanical property of the CaObased pellets were investigated in a bubbling fluidized bed reactor.The addition of 2%(mass)polyvinylpyrrolidone as an adhesive not only helps granulate,but also improves the heat storage capacity of the pellets.All biomass-templated CaO-based pellets display higher heat storage capacity than biomass-free pellets,indicating that the biomass-based pore-forming agent is beneficial for heat storage under the fluidization.Especially,bagasse-templated pellets show the highest heat storage conversion of 0.61 after 10 cycles.Moreover,Al_(2)O_(3)as a binder for the pellets helps obtain high mechanical strength.The CaO-based pellets doped with 10%(mass)bagasse and 5%(mass)Al_(2)O_(3)reach the highest heat storage density of 1621 kJ·kg^(-1) after 30 cycles and the highest crushing strength of 4.98 N.The microstructure of the bagasse-templated pellets appears more porous than that of biomass-free pellets.The bagassetemplated CaO-based pellets doped with Al_(2)O_(3)seem promising for thermochemical heat storage under the fluidization,owing to the enhanced heat storage capacity,excellent mechanical strength,and simplicity of the synthesis procedure.展开更多
Thermochemical heat storage material inorganic hydrate LiOH is selected as a promising candidate material for storing low-temperature heat energy because of its high energy density(1440 kJ/kg)and mild reaction process...Thermochemical heat storage material inorganic hydrate LiOH is selected as a promising candidate material for storing low-temperature heat energy because of its high energy density(1440 kJ/kg)and mild reaction process.However,the low hydration rate of LiOH limits the performance of low temperature thermochemical heat storage system as well as the thermal conductivity.In this study,porous-graphene/LiOH composite thermochemical heat storage materials with strong water sorption property and higher thermal conductivity were synthesized by hydrothermal process.The experimental results show that the hydration rate of the composites was greatly improved.The heat storage density of the composite materials was increased by 47%(from 661 kJ/kg to 974 kJ/kg).By combing the porous graphene,the thermal conductivity of composites with different contents were highly increased by 21.1%to 78.7%,but the increase of heat storage density is opposite to that of thermal conductivity.The development of high-performance materials for thermochemical heat storage should consider the relationship between the heat storage density and thermal conductivity of the material,and the thermal conductivity of the supporter needs to be further improved.展开更多
To solve the severe problem of wind power curtailment in the winter heating period caused by ＂power determined by heat＂ operation constraint of cogeneration units, this paper analyzes thermoelectric load, wind power...To solve the severe problem of wind power curtailment in the winter heating period caused by ＂power determined by heat＂ operation constraint of cogeneration units, this paper analyzes thermoelectric load, wind power output distribution and fluctuation characteristics at different time scales, and finally proposes a two level coordinated control strategy based on electric heat storage and pumped storage. The optimization target of the first level coordinated control is the lowest operation cost and the largest wind power utilization rate. Based on prediction of thermoelectric load and wind power, the operation economy of the system and wind power accommodation level are improved with the cooperation of electric heat storage and pumped storage in regulation capacity. The second level coordinated control stabilizes wind power real time fluctuations by cooperating electric heat storage and pumped storage in control speed. The example results of actual wind farms in Jiuquan, Gansu verifies the feasibility and effectiveness of the proposed coordinated control strategy.展开更多
Solar heating system is widely used recently. Heat storage equipment is the guarantee for steady performance of solar heating system. A design of latent heat storage exchanger with submerged coil was introduced with t...Solar heating system is widely used recently. Heat storage equipment is the guarantee for steady performance of solar heating system. A design of latent heat storage exchanger with submerged coil was introduced with the structure, working principle, and the main advantages. This heat exchanger was integrated into solar heating system as the heat storage equipment. Advantage comparison of the designed heat exchanger in solar heating system with hot water tank was carried out. The analysis results show that the latent heat storage exchanger is superior to hot water tank obviously. The heat exchanger performance parameters and variations of these parameters are got： （1） with the increase of phase change material （PCM） volume ratio, heat storage equipment volume ratio decreases; （2） heat storage efficiency has the same varying tendency with outdoor and air temperature; while the bigger PCM volume ratio is, the weaker the effect of outdoor air temperature on heat storage efficiency is; （3） heat storage capacity and heat storage efficiency increase together; when PCM volume ratio is big, heat storage efficiency is high and the system can begin operating effcienfly and quickly; （4） with the increase of heat storage capacity, life cyde operation cost （LCOC） of system increases gradually in high speed; but with the increase of PCM volume ratio, the difference between the two systems LCOCs becomes smaller and smaller; （5） the reasonable range of PCM volume ratio is 0.5 - 0.7. Temperature characteristic analysis shows that, with the filled PCM, heat storage medium temperature presents several segments at different time, under conditions of different heat storage capacity and different PCM state.展开更多
Solar cookers are a good option in developing countries with high solar potential for environmentally friendly cooking and reduced pressure on forests. However, they are still affected by the intermittency of the sun....Solar cookers are a good option in developing countries with high solar potential for environmentally friendly cooking and reduced pressure on forests. However, they are still affected by the intermittency of the sun. In order to overcome this problem, in this work, a box type solar cooker integrated Jatropha oil as a heat storage material is fabricated and experimented with. The design was examined with a maximum stagnation temperature of 157.7°C. The recorded cooking power vanished between 78.4 and 103.6 W, while thermal efficiency varied from 41.26% to 58.78%. The energy transfer cycle test, including charge and discharge revealed that 91.18% of the heat lost through the cooker could be recovered by the heat storage unit and a large amount is restored to the system during cloudiness or a temperature perturbation.展开更多
Chemical heat storage is a promising technology for improving thermal energy efficiency. In this study, CaCl<sub>2</sub> and H<sub>2</sub>O were selected as a reaction system for utilization of...Chemical heat storage is a promising technology for improving thermal energy efficiency. In this study, CaCl<sub>2</sub> and H<sub>2</sub>O were selected as a reaction system for utilization of low-grade exhaust heat that is cooler than 200<span style="white-space:nowrap;"><span style="white-space:nowrap;">°</span></span>C. Heat discharging and charging were conducted through the CaCl<sub>2</sub> hydration reaction. A silicon carbide honeycomb was adopted to improve heat transfer in the CaCl<sub>2</sub> packed bed. The heat storage, condenser, and evaporator temperature were set at 150<span style="white-space:nowrap;">°</span>C, 30<span style="white-space:nowrap;">°</span>C and 90<span style="white-space:nowrap;">°</span>C respectively. Repeated trials and experiments are time consuming for optimizing design of the equipment. Therefore, in this research, we constructed a simulation that can predict the performance of the device. A numerical simulation model was utilized in preparation for the design of the heat storage module. The consistency of both the simulation and the experimental results was confirmed by comparing them.展开更多
Thermochemical heat storage is a promising technology for improving energy efficiency through the utilization of low-grade waste heat. The formation of a SrCl<sub>2</sub> ammine complex was selected as the...Thermochemical heat storage is a promising technology for improving energy efficiency through the utilization of low-grade waste heat. The formation of a SrCl<sub>2</sub> ammine complex was selected as the reaction system for the purpose of this study. Discharge characteristics were evaluated in a packed bed reactor for both the gas-solid reaction and the liquid-solid reaction. The average power of the gas-solid reaction was influenced by the pressure of the supplied ammonia gas, with greater powers being recorded at higher ammonia pressure. For the liquid-solid reaction, the obtained average power was comparable to that obtained for the gas-solid reaction at 0.2 MPa. Moreover, the lower heat transfer resistance in the reactor was observed, which was likely caused by the presence of liquid ammonia in the system. Finally, the short-term durability of the liquid-solid reaction system was demonstrated over 10 stable charge/discharge cycles.展开更多
The seasonal heat storage tank is the most important component of the SDH （solar district heating） system, which allows significant increase in the share of solar energy in heat supply in comparison with conventiona...The seasonal heat storage tank is the most important component of the SDH （solar district heating） system, which allows significant increase in the share of solar energy in heat supply in comparison with conventional solar systems with short-term accumulation of heat. The adverse impact of their investment sophistication on competitiveness may be compensated by the increased use. For example： Cooperation with heat pump allows to increase the accumulation capacity of the seasonal heat storage tank and causes the direct use of heating energy and accumulation of cooling energy produced by heat pump. In the final stage of the heating period, it can be used to remote cooling supplied buildings. Experimentation on mathematical model is possible to obtain valuable insights about the dynamics of the processes of charging and discharging in the seasonal storage tank and subsequently used in the design, implementation and operation.展开更多
Heat storage properties of phase change materials(PCMs) are essential characteristics that perform a key role in thermal heat energy storage systems.The thermal properties of PCMs can be improved by developing metal f...Heat storage properties of phase change materials(PCMs) are essential characteristics that perform a key role in thermal heat energy storage systems.The thermal properties of PCMs can be improved by developing metal foam/PCM composites.The addition of metal foam in PCMs has a significant effect on the thermal characteristics of PCMs.In this paper,the heat storage properties of two different metal foam/PCM composites were experimentally examined.The behavior of paraffin in metal foam(copper and iron-nickel)/paraffin composites concerning pure paraffin at a constant heat flux of 1000 W/m^(2) in three directions simultaneously(x,y,and z) was studied.Paraffin was infiltrated into copper and iron-nickel foams to develop composite materials which resulted in enhancing the thermal conductivity of the paraffin.A comparative analysis is made on the heat storage properties of paraffin in copper and iron-nickel foams/paraffin composites.Inner temperature distribution during the phase transition process is experimentally evaluated.This comparison indicates that temperature uniformity in copper foam/paraffin composite is better than in iron-nickel foam/paraffin composite and pure paraffin at the same heat flux.Experimental results show that at heat flux of 1000 W/m^(2),the heat storage time for copper foam/paraffin composite is 20.63% of that of iron-nickel foam/paraffin composite.展开更多
The heat storage performance of latent heat storage systems is not good due to the poor thermal conductivity of phase change materials.In this paper,a new type of pointer-shaped fins combining rectangular and triangul...The heat storage performance of latent heat storage systems is not good due to the poor thermal conductivity of phase change materials.In this paper,a new type of pointer-shaped fins combining rectangular and triangular fins has been employed to numerically simulate the melting process in the heat storage tank,and the fin geometry parameter effects on heat storage performance have been studied.The results indicate that compared with the bare tube and the rectangular finned tank,the melting time of the phase change material in the pointer-shaped finned tank is reduced by 64.2%and 15.1%,respectively.The closer the tip of the triangular fin is to the hot wall,the better the heat transfer efficiency.The optimal height of the triangular fin is about 8 mm.Increasing the number of fins from 4 to 6 and from 6 to 8 reduces the melting time by 16.0%and 16.7%respectively.However,increasing the number of fins from 8 to 10 only reduces the melting time by 8.4%.When the fin dimensionless length is increased from 0.3 to 0.5 and from 0.5 to 0.7,the melting time is shortened by 17.5%and 13.0%.But the melting time is only reduced by 2.9%when the dimensionless fin length is increased from 0.7 to 0.9.For optimising the design of the thermal storage system,the results can provide a reference value.展开更多
A dispersion system fluid can convect even if the dispersoid is a solid phase.Therefore,heat exchange performance can be improved while maintaining fluidity using a material with high thermal conductivity as the dispe...A dispersion system fluid can convect even if the dispersoid is a solid phase.Therefore,heat exchange performance can be improved while maintaining fluidity using a material with high thermal conductivity as the dispersoid.This study presents the melting performance evaluation results of a latent heat storage material with a carbon nanotube(CNT)dispersion system with high thermal conductivity,which enhances the thermal conductivity of the latent heat storage material and does not limit free convection.Increasing the thermal conductivity and enhancing the melting convection of the heat storage material result in increased latent heat storage speed.In this study,the thermal conductivity of the latent heat storage material was successfully increased by dispersing CNTs in the material.When 0.1%(in mass)of multi-wall CNT(MWCNT)was dispersed in a paraffin-based latent heat storage material,the shear stress increased by 1.5 times at a shear rate of 500 s^(-1),while taking into account the potential effects of convective inhibition.Therefore,a latent heat storage experiment was conducted in a rectangular heat storage tank using the CNT dispersion composition ratio as a parameter.A rectangular vessel with a heated vertical surface was used for the latent heat storage experiment.The melting speed was determined by comparing the amount of latent heat stored in a CNT-dispersed latent heat storage material and a single-phase latent heat storage material sample.The experimental results show that the time required for the latent heat storage material to completely melt in the heat storage tank was the shortest for the single-phase latent heat storage material sample.However,the fastest melting progress was observed for the sample with 0.02%(in mass)MWCNT content in the melting rate range of up to approximately 40%in the tank.The results indicate that this phenomenon is caused by the difference in the melting rates in the upper part of the tank.The generated data are useful for determining the shape and heat transfer surface arrangement of the latent heat storage tank.展开更多
基金supported by the National Natural Science Foundation of China(61773269)China Scholarship for Overseas Studying(CSC No.202008210181),Department of Education of Liaoning Province of China(LJKZ1110)+1 种基金the Natural Science Foundation of Liaoning Province of China(2019-KF-03-08)the Program for Shenyang High Level Innovative Talents(RC190042).
文摘Electric-heat coupling characteristics of a cogeneration system and the operating mode of fixing electricity with heat are the main reasons for wind abandonment during the heating season in the Three North area.To improve the wind-power absorption capacity and operating economy of the system,the structure of the system is improved by adding a heat storage device and an electric boiler.First,aiming at the minimum operating cost of the system,the optimal scheduling model of the cogeneration system,including a heat storage device and electric boiler,is constructed.Second,according to the characteristics of the problem,a cultural gene algorithm program is compiled to simulate the calculation example.Finally,through the system improvement,the comparison between the conditions before and after and the simulation solutions of similar algorithms prove the effectiveness of the proposed scheme.The simulation results show that adding the heat storage device and electric boiler to the scheduling optimization process not only improves the wind power consumption capacity of the cogeneration system but also reduces the operating cost of the system by significantly reducing the coal consumption of the unit and improving the economy of the system operation.The cultural gene algorithm framework has both the global evolution process of the population and the local search for the characteristics of the problem,which has a better optimization effect on the solution.
基金Project (No. 20050912) supported by the Education Department of Zhejiang Province, China
文摘An underground heat storage system in a double-film-covered greenhouse and an adjacent greenhouse without the heat storage system were designed on the basis of plant physiology to reduce the energy consumption in greenhouses. The results indicated that the floor temperature was respectively 5.2℃, 4.6℃ and 2.0 ℃ higher than that of the soil in the adjacent reference greenhouse after heat storage in a clear, cloudy and overcast sky in winter. Results showed that the temperature and humidity were feasible for plant growth in the heat saving greenhouse.
基金supported by the National Natural Science Foun-dation of China(51876105)the Fundamental Research Funds of Shandong University(2018JC039).
文摘The simultaneous CO_(2) capture and heat storage performances of the modified carbide slag with byproduct of biodiesel were investigated in the process coupled calcium looping and CaO/Ca(OH)2 thermochemical heat storage using air as the heat transfer fluid.The modified carbide slag with by-product of biodiesel exhibits superior CO_(2) capture and heat storage capacities in the coupled calcium looping and heat storage cycles.The hydration conversion and heat storage density of the modified carbide slag after 30 heat storage cycles are 0.65 mol·mol^(-1) and 1.14 GJ·t^(-1),respectively,which are 1.6 times as high as those of calcined carbide slag.The negative effect of CO_(2) in air as the heat storage fluid on the heat storage capacity of the modified carbide slag is overcome by introducing CO_(2) capture cycles.In addition,the CO_(2) capture reactivity of the modified carbide slag after the multiple calcium looping cycles is enhanced by the introduction of heat storage cycles.By introducing 10 heat storage cycles after the 10th and 15th CO_(2) capture cycles,the CO_(2) capture capacities of the modified carbide slag are subsequently improved by 32%and 43%,respectively.The porous and loose structure of modified carbide slag reduces the diffusion resistances of CO_(2) and steam in the material in the coupled process.The formed CaCO_(3)in the modified carbide slag as a result of air as the heat transfer fluid in heat storage cycles decomposes to regenerate CaO in calcium looping cycles,which improves heat storage capacity.Therefore,the modified carbide slag with by-product of biodiesel seems promising in the coupled calcium looping and CaO/Ca(OH)_(2) heat storage cycles.
基金This project is supported by the National Natural Science Foundation of China under contract No.59021 1004,40005007,49975021,and 40376039.
文摘By using the upper layer data(downloaded from the web of the Scripps Institution of Oceanography),the interannual variability of the heat storage of upper layer(from surface to 400 m depth) and the mixed layer depth in the tropical Pacific Ocean are investigated. The abnormal signal of the warm event comes from the central and west Pacific Ocean, whereas it is regarded that the abnormal signal of the warm event comes from the east Pacific Ocean in the popular viewpoint. From the viewpoint on the evolution of the interannual variability of the mixed layer depth and the heat storage of the whole upper layer, the difference between the two types of El Nino is so small that it can be neglected. During these two El Nino/La Nina events(1972/1973 and 1997/1998), other than the case of the heat storage or for the mixed layer depth, the abnormal signal propagates from the central and west Pacific Ocean to the east usually by the path along the equator whereas the abnormal signal propagates from the east to the west by the path northern to the equator. For the interannual variability, the evolution of the mixed layer depth corresponds to that of the heat storage in the upper layer very well. This is quite different from the evolution of seasonality.
基金This work is supported by the Foundation for Innovative Research Groups of the National Natural Science Foundation of China(51521004)the National Natural Science Foundation of China(51906150).
文摘Owing to its high heat storage capacity and fast heat transfer rate,packed bed latent heat storage(LHS)is considered as a promising method to store thermal energy.In a packed bed,the wall effect can impact the packing arrangement of phase change material(PCM)capsules,inducing radial porosity oscillation.In this study,an actual-arrangement-based three-dimensional packed bed LHS model was built to consider the radial porosity oscillation.Its fluid flow and heat transfer were analyzed.With different cylindrical sub-surfaces intercepted along the radial direction in the packed bed,the corresponding relationships between the arrangement of capsules and porosity oscillation were identified.The oscillating distribution of radial porosity led to a non-uniform distribution of heat transfer fluid(HTF)velocity.As a result,radial temperature distributions and liquid fraction distributions of PCMs were further affected.The effects of different dimensionless parameters(e.g.,tube-to-capsule diameter ratio,Reynolds number,and Stefan number)on the radial characteristics of HTF and PCMs were discussed.The results showed that different diameter ratios correspond to different radial porosity distributions.Further,with an increase in diameter ratio,HTF velocity varies significantly in the near wall region while the non-uniformity of HTF velocity in the center region will decrease.The Reynolds and Stefan numbers slightly impact the relative velocity distribution of the HTF-while higher Reynolds numbers can lead to a proportional improvement of velocity,an increase in Stefan number can promote heat storage of the packed bed LHS system.
基金supported by the Scientific and Technological Research Council of Turkey (TUBITAK) (Project No. 315M524)the Scientific Research Projects Coordination Unit of Istanbul University (Project No. 25427)
文摘Thermochemical heat storage(THS)systems have recently attracted a lot of attention in research and development.In this study,an anodic aluminum oxide(AAO)template,fabricated by a two-step anodization method,was used for the first time as the matrix material for a THS system.Different salts were studied as thermochemical materials for their suitability in low-grade heat storage application driven by solar energy for an open system.Compositions were prepared by absorbing CaCl2,MgCl2,LiCl,LiNO3 and mixtures of these salts under a vacuum in an AAO matrix.Field Emission Scanning Electron Microscopy was used to examine the morphology of the produced AAO composites.Thermal energy storage capacities of the composites were characterized using a differential scanning calorimeter.Characterization analysis showed that anodized Al plates were suitable matrix materials for THS systems,and composite sorbent prepared with a 1:1 ratio LiCl/LiNO3 salt mixture had the highest energy value among all composites,with an energy density of 468.1 k J·kg-1.
基金supported by the National Key R&D Program of China(2019YFB1504301)National Natural Science Foundation of China(51725602,51906039)Natural Science Foundation of Jiangsu Province(BK20180405)。
文摘The latent heat storage(LHS)technique is of crucial importance in chemical energy engineering.Inspired by multi-bifurcated fern leaves,a mimic fern-fractal fin is designed to improve the thermal energy charging efficiency.This paper develops a transient melting model of a rectangular LHS unit using fern-fractal fins,and their melting behaviors are compared with the conventional fins.Besides,a parametric optimization of fernfractal fins is conducted for maximizing the thermal efficiency based on the response surface method(RSM).The results indicate that the temperature uniformity is more superior and the melting duration is shorter for the fern-fractal LHS unit when compared with the conventional one.Interestingly,the fern-fractal LHS device presents a slower heat storage rate during the initial conduction-dominated and early convection-dominated melting stages,while a prominent melting enhancement is achieved during the later melting stage.The shortest melting time is obtained based on the RSM technique when a fern-fractal fin with length ratio α=0.94 and branch angle θ=54.7°is utilized.Compared with a conventional fin,the averaged heat storage rate increases by 88.3%,and the total melting time is declined by 40.3%for an optimized fern-fractal fin.
基金Funded by the National Natural Science of China(No.2012BAA05B06)
文摘Thermal energy storage is an attractive option for effectiveness since it gives flexibility and reduces energy consumption and costs. New composite materials for storage and transformation of heat of NaCl-Al2O3composite materials were synthesized by one-step synthesis method. The chemical composition, morphology, structure, and thermal properties were investigated by XRD, EDS, SEM, and DSC. The results show that NaCl can be absorbed by Al2O3particle from 800 to 900 ℃ for Al2O3particle surface is rich active structure. The results also indicate that the leakage of NaCl when the phase change can be prevented by Al2O3particles and the enthalpy of phase change of NaCl-Al2O3material is 362 J/g. The composites have an excellent heat storage capacity. Therefore, this study contributes to one new thought and method to prepare high temperature heat storage material and this material can be applied in future thermal engineering.
文摘Availability of clean water is going to become one of biggest demands of the country. Even though there arc various technologies available for purification of water harnessing solar energy fits the purpose for future problems. Distillation is one of many processes available for water purification, and solar energy is one of several forms of heat energy that can be used to energize this process. In this review a study is made to enhance the productivity of the solar stills by connecting solar still with latent heat storage and solar air heater in series and other factors like improving evaporation rate by maintaining Low depth, more exposure area, heat addition by solar collector and presence of latent heat storage material, which is a paraffin wax as a integral part of still. Latent heat storage is one of the most efficient ways of storing thermal energy. Unlike the sensible heat storage method, the latent heat storage method provides much higher storage density, with a smaller temperature difference between storing and releasing heat. Further augmentation of the yield by scraps, pebble, and sand are added.
基金supported by the National Natural Science Foundation of China(51876105)the Fundamental Research Funds of Shandong University(2018JC039)Major Scientific and Technological Innovation Projects of Key Research&Development Program of Shandong Province(2019JZZY020118).
文摘The CaO-based pellets were fabricated using extrusion-spheronization method for calcium looping thermochemical heat storage under the fluidization.The effects of adhesive,biomass-based pore-forming agent,binder and particle size on the heat storage performance and mechanical property of the CaObased pellets were investigated in a bubbling fluidized bed reactor.The addition of 2%(mass)polyvinylpyrrolidone as an adhesive not only helps granulate,but also improves the heat storage capacity of the pellets.All biomass-templated CaO-based pellets display higher heat storage capacity than biomass-free pellets,indicating that the biomass-based pore-forming agent is beneficial for heat storage under the fluidization.Especially,bagasse-templated pellets show the highest heat storage conversion of 0.61 after 10 cycles.Moreover,Al_(2)O_(3)as a binder for the pellets helps obtain high mechanical strength.The CaO-based pellets doped with 10%(mass)bagasse and 5%(mass)Al_(2)O_(3)reach the highest heat storage density of 1621 kJ·kg^(-1) after 30 cycles and the highest crushing strength of 4.98 N.The microstructure of the bagasse-templated pellets appears more porous than that of biomass-free pellets.The bagassetemplated CaO-based pellets doped with Al_(2)O_(3)seem promising for thermochemical heat storage under the fluidization,owing to the enhanced heat storage capacity,excellent mechanical strength,and simplicity of the synthesis procedure.
基金the Key Area Research and Development Program of Guangdong Province(2019B110209003)Key Research Program of Frontier Sciences,Chinese Academy of Sciences,China(QYZDY-SSW-JSC038)+1 种基金Natural Science Foundation of Guangdong Province(2017A030310185)Science and Technology Project of China Energy Investment Corporation(GJNY-20-121).
文摘Thermochemical heat storage material inorganic hydrate LiOH is selected as a promising candidate material for storing low-temperature heat energy because of its high energy density(1440 kJ/kg)and mild reaction process.However,the low hydration rate of LiOH limits the performance of low temperature thermochemical heat storage system as well as the thermal conductivity.In this study,porous-graphene/LiOH composite thermochemical heat storage materials with strong water sorption property and higher thermal conductivity were synthesized by hydrothermal process.The experimental results show that the hydration rate of the composites was greatly improved.The heat storage density of the composite materials was increased by 47%(from 661 kJ/kg to 974 kJ/kg).By combing the porous graphene,the thermal conductivity of composites with different contents were highly increased by 21.1%to 78.7%,but the increase of heat storage density is opposite to that of thermal conductivity.The development of high-performance materials for thermochemical heat storage should consider the relationship between the heat storage density and thermal conductivity of the material,and the thermal conductivity of the supporter needs to be further improved.
基金National Natural Science Foundation of China(No.61663019)
文摘To solve the severe problem of wind power curtailment in the winter heating period caused by ＂power determined by heat＂ operation constraint of cogeneration units, this paper analyzes thermoelectric load, wind power output distribution and fluctuation characteristics at different time scales, and finally proposes a two level coordinated control strategy based on electric heat storage and pumped storage. The optimization target of the first level coordinated control is the lowest operation cost and the largest wind power utilization rate. Based on prediction of thermoelectric load and wind power, the operation economy of the system and wind power accommodation level are improved with the cooperation of electric heat storage and pumped storage in regulation capacity. The second level coordinated control stabilizes wind power real time fluctuations by cooperating electric heat storage and pumped storage in control speed. The example results of actual wind farms in Jiuquan, Gansu verifies the feasibility and effectiveness of the proposed coordinated control strategy.
基金National Natural Science Foundation of China(No.21106149)
文摘Solar heating system is widely used recently. Heat storage equipment is the guarantee for steady performance of solar heating system. A design of latent heat storage exchanger with submerged coil was introduced with the structure, working principle, and the main advantages. This heat exchanger was integrated into solar heating system as the heat storage equipment. Advantage comparison of the designed heat exchanger in solar heating system with hot water tank was carried out. The analysis results show that the latent heat storage exchanger is superior to hot water tank obviously. The heat exchanger performance parameters and variations of these parameters are got： （1） with the increase of phase change material （PCM） volume ratio, heat storage equipment volume ratio decreases; （2） heat storage efficiency has the same varying tendency with outdoor and air temperature; while the bigger PCM volume ratio is, the weaker the effect of outdoor air temperature on heat storage efficiency is; （3） heat storage capacity and heat storage efficiency increase together; when PCM volume ratio is big, heat storage efficiency is high and the system can begin operating effcienfly and quickly; （4） with the increase of heat storage capacity, life cyde operation cost （LCOC） of system increases gradually in high speed; but with the increase of PCM volume ratio, the difference between the two systems LCOCs becomes smaller and smaller; （5） the reasonable range of PCM volume ratio is 0.5 - 0.7. Temperature characteristic analysis shows that, with the filled PCM, heat storage medium temperature presents several segments at different time, under conditions of different heat storage capacity and different PCM state.
文摘Solar cookers are a good option in developing countries with high solar potential for environmentally friendly cooking and reduced pressure on forests. However, they are still affected by the intermittency of the sun. In order to overcome this problem, in this work, a box type solar cooker integrated Jatropha oil as a heat storage material is fabricated and experimented with. The design was examined with a maximum stagnation temperature of 157.7°C. The recorded cooking power vanished between 78.4 and 103.6 W, while thermal efficiency varied from 41.26% to 58.78%. The energy transfer cycle test, including charge and discharge revealed that 91.18% of the heat lost through the cooker could be recovered by the heat storage unit and a large amount is restored to the system during cloudiness or a temperature perturbation.
文摘Chemical heat storage is a promising technology for improving thermal energy efficiency. In this study, CaCl<sub>2</sub> and H<sub>2</sub>O were selected as a reaction system for utilization of low-grade exhaust heat that is cooler than 200<span style="white-space:nowrap;"><span style="white-space:nowrap;">°</span></span>C. Heat discharging and charging were conducted through the CaCl<sub>2</sub> hydration reaction. A silicon carbide honeycomb was adopted to improve heat transfer in the CaCl<sub>2</sub> packed bed. The heat storage, condenser, and evaporator temperature were set at 150<span style="white-space:nowrap;">°</span>C, 30<span style="white-space:nowrap;">°</span>C and 90<span style="white-space:nowrap;">°</span>C respectively. Repeated trials and experiments are time consuming for optimizing design of the equipment. Therefore, in this research, we constructed a simulation that can predict the performance of the device. A numerical simulation model was utilized in preparation for the design of the heat storage module. The consistency of both the simulation and the experimental results was confirmed by comparing them.
文摘Thermochemical heat storage is a promising technology for improving energy efficiency through the utilization of low-grade waste heat. The formation of a SrCl<sub>2</sub> ammine complex was selected as the reaction system for the purpose of this study. Discharge characteristics were evaluated in a packed bed reactor for both the gas-solid reaction and the liquid-solid reaction. The average power of the gas-solid reaction was influenced by the pressure of the supplied ammonia gas, with greater powers being recorded at higher ammonia pressure. For the liquid-solid reaction, the obtained average power was comparable to that obtained for the gas-solid reaction at 0.2 MPa. Moreover, the lower heat transfer resistance in the reactor was observed, which was likely caused by the presence of liquid ammonia in the system. Finally, the short-term durability of the liquid-solid reaction system was demonstrated over 10 stable charge/discharge cycles.
文摘The seasonal heat storage tank is the most important component of the SDH （solar district heating） system, which allows significant increase in the share of solar energy in heat supply in comparison with conventional solar systems with short-term accumulation of heat. The adverse impact of their investment sophistication on competitiveness may be compensated by the increased use. For example： Cooperation with heat pump allows to increase the accumulation capacity of the seasonal heat storage tank and causes the direct use of heating energy and accumulation of cooling energy produced by heat pump. In the final stage of the heating period, it can be used to remote cooling supplied buildings. Experimentation on mathematical model is possible to obtain valuable insights about the dynamics of the processes of charging and discharging in the seasonal storage tank and subsequently used in the design, implementation and operation.
文摘Heat storage properties of phase change materials(PCMs) are essential characteristics that perform a key role in thermal heat energy storage systems.The thermal properties of PCMs can be improved by developing metal foam/PCM composites.The addition of metal foam in PCMs has a significant effect on the thermal characteristics of PCMs.In this paper,the heat storage properties of two different metal foam/PCM composites were experimentally examined.The behavior of paraffin in metal foam(copper and iron-nickel)/paraffin composites concerning pure paraffin at a constant heat flux of 1000 W/m^(2) in three directions simultaneously(x,y,and z) was studied.Paraffin was infiltrated into copper and iron-nickel foams to develop composite materials which resulted in enhancing the thermal conductivity of the paraffin.A comparative analysis is made on the heat storage properties of paraffin in copper and iron-nickel foams/paraffin composites.Inner temperature distribution during the phase transition process is experimentally evaluated.This comparison indicates that temperature uniformity in copper foam/paraffin composite is better than in iron-nickel foam/paraffin composite and pure paraffin at the same heat flux.Experimental results show that at heat flux of 1000 W/m^(2),the heat storage time for copper foam/paraffin composite is 20.63% of that of iron-nickel foam/paraffin composite.
基金financially supported by the National Natural Science Foundation of China(Grant No.51876147)。
文摘The heat storage performance of latent heat storage systems is not good due to the poor thermal conductivity of phase change materials.In this paper,a new type of pointer-shaped fins combining rectangular and triangular fins has been employed to numerically simulate the melting process in the heat storage tank,and the fin geometry parameter effects on heat storage performance have been studied.The results indicate that compared with the bare tube and the rectangular finned tank,the melting time of the phase change material in the pointer-shaped finned tank is reduced by 64.2%and 15.1%,respectively.The closer the tip of the triangular fin is to the hot wall,the better the heat transfer efficiency.The optimal height of the triangular fin is about 8 mm.Increasing the number of fins from 4 to 6 and from 6 to 8 reduces the melting time by 16.0%and 16.7%respectively.However,increasing the number of fins from 8 to 10 only reduces the melting time by 8.4%.When the fin dimensionless length is increased from 0.3 to 0.5 and from 0.5 to 0.7,the melting time is shortened by 17.5%and 13.0%.But the melting time is only reduced by 2.9%when the dimensionless fin length is increased from 0.7 to 0.9.For optimising the design of the thermal storage system,the results can provide a reference value.
基金supported by JSPS KAKENHI(Grant numbers JP18K03999 and 22K03958)。
文摘A dispersion system fluid can convect even if the dispersoid is a solid phase.Therefore,heat exchange performance can be improved while maintaining fluidity using a material with high thermal conductivity as the dispersoid.This study presents the melting performance evaluation results of a latent heat storage material with a carbon nanotube(CNT)dispersion system with high thermal conductivity,which enhances the thermal conductivity of the latent heat storage material and does not limit free convection.Increasing the thermal conductivity and enhancing the melting convection of the heat storage material result in increased latent heat storage speed.In this study,the thermal conductivity of the latent heat storage material was successfully increased by dispersing CNTs in the material.When 0.1%(in mass)of multi-wall CNT(MWCNT)was dispersed in a paraffin-based latent heat storage material,the shear stress increased by 1.5 times at a shear rate of 500 s^(-1),while taking into account the potential effects of convective inhibition.Therefore,a latent heat storage experiment was conducted in a rectangular heat storage tank using the CNT dispersion composition ratio as a parameter.A rectangular vessel with a heated vertical surface was used for the latent heat storage experiment.The melting speed was determined by comparing the amount of latent heat stored in a CNT-dispersed latent heat storage material and a single-phase latent heat storage material sample.The experimental results show that the time required for the latent heat storage material to completely melt in the heat storage tank was the shortest for the single-phase latent heat storage material sample.However,the fastest melting progress was observed for the sample with 0.02%(in mass)MWCNT content in the melting rate range of up to approximately 40%in the tank.The results indicate that this phenomenon is caused by the difference in the melting rates in the upper part of the tank.The generated data are useful for determining the shape and heat transfer surface arrangement of the latent heat storage tank.
