The one-pot aza-Diels-Alder reaction of substituted aromatic amines, ethyl glyoxylate and benzyl vinylcarbamate or N- benzyloxycarbonyl 2-pyrroline was conducted in hexafluoroisopropanol, providing the desired 1,2,3,4...The one-pot aza-Diels-Alder reaction of substituted aromatic amines, ethyl glyoxylate and benzyl vinylcarbamate or N- benzyloxycarbonyl 2-pyrroline was conducted in hexafluoroisopropanol, providing the desired 1,2,3,4-tetrahydroquinline derivatives in moderate yields.展开更多
Ten novel analogues of flubendiamide containing a hexafluoroisopropanol moiety were designed and synthe- sized. Their insecticidal activities against armyworm （Pseudaletia separata Walker） were examined and compared...Ten novel analogues of flubendiamide containing a hexafluoroisopropanol moiety were designed and synthe- sized. Their insecticidal activities against armyworm （Pseudaletia separata Walker） were examined and compared with the commercial product flubendiamide. Compound 7b showed nearly the same insecticidal activity as fluben- diamide against armyworm.展开更多
A facile, efficient and novel approach to access 2-substituted-N1-carbethoxy-2,3-dihydro-4（1H）-quinazolinones was developed by condensation of substituted N-carbethoxyanthranilamide with alkyl, aromatic or heteroaro...A facile, efficient and novel approach to access 2-substituted-N1-carbethoxy-2,3-dihydro-4（1H）-quinazolinones was developed by condensation of substituted N-carbethoxyanthranilamide with alkyl, aromatic or heteroaromatic aldehydes in the refluxing 2,2,2- trifluoroethanol or hexafluoroisopropanol using p-toluenesulfonic acid as catalyst.展开更多
基金the National Natural Science Foundation of China(No.30672540)NSF of Beijing(No.7072048)for financial support.
文摘The one-pot aza-Diels-Alder reaction of substituted aromatic amines, ethyl glyoxylate and benzyl vinylcarbamate or N- benzyloxycarbonyl 2-pyrroline was conducted in hexafluoroisopropanol, providing the desired 1,2,3,4-tetrahydroquinline derivatives in moderate yields.
文摘Ten novel analogues of flubendiamide containing a hexafluoroisopropanol moiety were designed and synthe- sized. Their insecticidal activities against armyworm （Pseudaletia separata Walker） were examined and compared with the commercial product flubendiamide. Compound 7b showed nearly the same insecticidal activity as fluben- diamide against armyworm.
基金We are grateful to the National Natural Science Foundation of China(No.30672540)the Natural Science Foundation of Beijing(No.7072048)for financial support.
文摘A facile, efficient and novel approach to access 2-substituted-N1-carbethoxy-2,3-dihydro-4（1H）-quinazolinones was developed by condensation of substituted N-carbethoxyanthranilamide with alkyl, aromatic or heteroaromatic aldehydes in the refluxing 2,2,2- trifluoroethanol or hexafluoroisopropanol using p-toluenesulfonic acid as catalyst.
