Fluoride mediated nano-sized ZSM-5(ZSM-5-F) with a high Si/Al ratio of 181 was fabricated using a seed-induction method and evaluated the catalysis of the methanol to propylene(MTP) reaction. High propylene selectivit...Fluoride mediated nano-sized ZSM-5(ZSM-5-F) with a high Si/Al ratio of 181 was fabricated using a seed-induction method and evaluated the catalysis of the methanol to propylene(MTP) reaction. High propylene selectivity(45%) was similar to ZSM-5-OH synthesized via a hydroxide route. However, ZSM-5-F showed much longer lifetime(305 h) compared with ZSM-5-OH(157 h) in spite of similar crystal size and aluminum content. Characterization by NH_3-TPD, Py-IR, OH-IR, SEM, TG-DTA, XRD and ~1H MAS NMR techniques indicated that the enhanced catalytic performance of ZSM-5-F is attributed to the fewer structural defects in the form of internal silanol groups and silanol nests.展开更多
Effects of high magnetic field on modification of Al-6%Si hypoeutectic alloy, Al-12.6%Si eutectic alloy and Al-18%Si hypereutectic alloy were studied. For the Al-6%Si alloy, it is found that the sample modified by Na-...Effects of high magnetic field on modification of Al-6%Si hypoeutectic alloy, Al-12.6%Si eutectic alloy and Al-18%Si hypereutectic alloy were studied. For the Al-6%Si alloy, it is found that the sample modified by Na-salt does not lose efficacy after remelting under high magnetic field. For the Al-12.6%Si alloy, if the sample modified by Na-salt is kept at the temperature of modification reaction, high magnetic field can postpone the effective time of the modification. For Al-18%Si alloy modified by P-salt, the primary Si in solidified structure concentrates at the edge of the sample and eutectic Si appears in the center of the sample under the condition without high magnetic field, while the primary Si distributes evenly in the sample when the high magnetic field is imposed. It is thought that the high magnetic field restrains the convection of the melt.展开更多
Aiming to meet the challenge of the shape complexity and high plasticity demanded for the upper connective plate(UCP) in motorcycle, a high plasticity Al Si alloy named HGZL 02 was developed by optimizing the chemical...Aiming to meet the challenge of the shape complexity and high plasticity demanded for the upper connective plate(UCP) in motorcycle, a high plasticity Al Si alloy named HGZL 02 was developed by optimizing the chemical composition and casting process. Premium UCP castings were obtained by using optimized casting process. Results show that fine and dense microstructure are obtained in the UCP castings. An average of 224 MPa in ultimate tensile strength, 149 MPa in yield strength and 13.2% in elongation are achieved for T6 heat treated UPS castings.展开更多
The influence of zirconium on the resistance to high temperature softening of 6082 Al-Mg-Si alloys has been researched. The softening process of 6082 alloys with Zr and without Zr, isothermally conditioned at 250°...The influence of zirconium on the resistance to high temperature softening of 6082 Al-Mg-Si alloys has been researched. The softening process of 6082 alloys with Zr and without Zr, isothermally conditioned at 250°C, has been investigated. The results show the inclusion of Zr inhibits the decrease of HB in hardness(HB) compared with the alloys without Zr. This is due to the Zr and Al forming coherent dispersoid-A!3Zr, and Al3Zr particles within an Al matrix, which effectively restricts grain boundary movement. A study is also carried out to investigate the changes in resistivity, which occurs during the ageing of alloys containing Zr, compared to those without Zr. It is found that in both cases there is an initial rapid rise in resistivity followed by a slower rise in resistivity as ageing proceeds. The value of resistivity is lower for 6082 alloys with Zr compared with 6082 alloys without Zr; this is explained in terms of the role of Zr in the 6082 alloys.展开更多
The CrN and Cr-Al-Si-N films were deposited on Si wafer and SUS 304 substrates by a hybrid coating system with high power impulse magnetron sputtering (HIPIMS) and a DC pulse sputtering using Cr and AlSi targets under...The CrN and Cr-Al-Si-N films were deposited on Si wafer and SUS 304 substrates by a hybrid coating system with high power impulse magnetron sputtering (HIPIMS) and a DC pulse sputtering using Cr and AlSi targets under N2/Ar atmosphere.By varying the sputtering current of the AlSi target in the range of 0-2.5 A,both the Al and Si contents in the films increased gradually from 0 to 19.1% and 11.1% (mole fraction),respectively.The influences of the AlSi cathode DC pulse current on the microstructure,phase constituents,mechanical properties,and oxidation behaviors of the Cr-Al-Si-N films were investigated systematically.The results indicate that the as-deposited Cr-Al-Si-N films possess the typical nanocomposite structure,namely the face centered cubic (Cr,Al)N nano-crystallites are embedded in the amorphous Si3N4 matrix.With increasing the Al and Si contents,the hardness of the film first increases from 20.8 GPa for the CrN film to the peak value of 29.4 GPa for the Cr0.23Al0.14Si0.07 N film,and then decreases gradually.In the meanwhile,the Cr0.23Al0.14Si0.07N film also possesses excellent high-temperature oxidation resistance that is much better than that of the CrN film at 900 or 1000 °C.展开更多
The fatigue behavior of press hardened Al-Si coated high strength steel has been investigated,and the fatigue strength turns out to be about 1 000 MPa.Surface morphology of fractured and non-fractured specimen has bee...The fatigue behavior of press hardened Al-Si coated high strength steel has been investigated,and the fatigue strength turns out to be about 1 000 MPa.Surface morphology of fractured and non-fractured specimen has been observed,and the coating shows significant influence on the fatigue behavior.The difference of elastic modulus between coating and substrate led to the main cracks perpendicular to the loading direction.The coating close to fracture exfoliated thinly,while the coating far away from the fracture kept integrated.Though the specimen was polished to obtain high surface quality,3 types of cracks occurred during the fatigue test.What’s more,inclusion particles were proved to play a crucial role in causing these cracks.展开更多
The microstructure of hypoeutectic Al-9.21wt.%Si alloy solidified under 5.5 GPa was studied.The results show that the solidifi cation microstructure is refi ned.The primary α phase is the extended solid solution.The ...The microstructure of hypoeutectic Al-9.21wt.%Si alloy solidified under 5.5 GPa was studied.The results show that the solidifi cation microstructure is refi ned.The primary α phase is the extended solid solution.The solid solubility of Si in α phase is up to 8.26wt.%.The growth mode of the α phase is cellular,and this cellular growth mechanism is interpreted in terms of the decrease of the diffusivity and the extended solid solution under high pressure.By calculation,it can be known that the the diffusivity of solute in the liquid under normal pressure is as high as two hundred times that under high pressure.The microhardness of the hypoeutectic Al-Si alloy solidif ied under high pressure is higher than that of solidifi ed under normal pressure.After annealing,Si precipitates from the solid solution,the microhardness of the alloy decrease,but,still higher than that of solidif ied under normal pressure.展开更多
文摘Fluoride mediated nano-sized ZSM-5(ZSM-5-F) with a high Si/Al ratio of 181 was fabricated using a seed-induction method and evaluated the catalysis of the methanol to propylene(MTP) reaction. High propylene selectivity(45%) was similar to ZSM-5-OH synthesized via a hydroxide route. However, ZSM-5-F showed much longer lifetime(305 h) compared with ZSM-5-OH(157 h) in spite of similar crystal size and aluminum content. Characterization by NH_3-TPD, Py-IR, OH-IR, SEM, TG-DTA, XRD and ~1H MAS NMR techniques indicated that the enhanced catalytic performance of ZSM-5-F is attributed to the fewer structural defects in the form of internal silanol groups and silanol nests.
文摘Effects of high magnetic field on modification of Al-6%Si hypoeutectic alloy, Al-12.6%Si eutectic alloy and Al-18%Si hypereutectic alloy were studied. For the Al-6%Si alloy, it is found that the sample modified by Na-salt does not lose efficacy after remelting under high magnetic field. For the Al-12.6%Si alloy, if the sample modified by Na-salt is kept at the temperature of modification reaction, high magnetic field can postpone the effective time of the modification. For Al-18%Si alloy modified by P-salt, the primary Si in solidified structure concentrates at the edge of the sample and eutectic Si appears in the center of the sample under the condition without high magnetic field, while the primary Si distributes evenly in the sample when the high magnetic field is imposed. It is thought that the high magnetic field restrains the convection of the melt.
文摘Aiming to meet the challenge of the shape complexity and high plasticity demanded for the upper connective plate(UCP) in motorcycle, a high plasticity Al Si alloy named HGZL 02 was developed by optimizing the chemical composition and casting process. Premium UCP castings were obtained by using optimized casting process. Results show that fine and dense microstructure are obtained in the UCP castings. An average of 224 MPa in ultimate tensile strength, 149 MPa in yield strength and 13.2% in elongation are achieved for T6 heat treated UPS castings.
基金the Scientificand Technical Commission Fund of Shanghai
文摘The influence of zirconium on the resistance to high temperature softening of 6082 Al-Mg-Si alloys has been researched. The softening process of 6082 alloys with Zr and without Zr, isothermally conditioned at 250°C, has been investigated. The results show the inclusion of Zr inhibits the decrease of HB in hardness(HB) compared with the alloys without Zr. This is due to the Zr and Al forming coherent dispersoid-A!3Zr, and Al3Zr particles within an Al matrix, which effectively restricts grain boundary movement. A study is also carried out to investigate the changes in resistivity, which occurs during the ageing of alloys containing Zr, compared to those without Zr. It is found that in both cases there is an initial rapid rise in resistivity followed by a slower rise in resistivity as ageing proceeds. The value of resistivity is lower for 6082 alloys with Zr compared with 6082 alloys without Zr; this is explained in terms of the role of Zr in the 6082 alloys.
基金supported by a 2-Year Research Grant of Pusan National University,Korea
文摘The CrN and Cr-Al-Si-N films were deposited on Si wafer and SUS 304 substrates by a hybrid coating system with high power impulse magnetron sputtering (HIPIMS) and a DC pulse sputtering using Cr and AlSi targets under N2/Ar atmosphere.By varying the sputtering current of the AlSi target in the range of 0-2.5 A,both the Al and Si contents in the films increased gradually from 0 to 19.1% and 11.1% (mole fraction),respectively.The influences of the AlSi cathode DC pulse current on the microstructure,phase constituents,mechanical properties,and oxidation behaviors of the Cr-Al-Si-N films were investigated systematically.The results indicate that the as-deposited Cr-Al-Si-N films possess the typical nanocomposite structure,namely the face centered cubic (Cr,Al)N nano-crystallites are embedded in the amorphous Si3N4 matrix.With increasing the Al and Si contents,the hardness of the film first increases from 20.8 GPa for the CrN film to the peak value of 29.4 GPa for the Cr0.23Al0.14Si0.07 N film,and then decreases gradually.In the meanwhile,the Cr0.23Al0.14Si0.07N film also possesses excellent high-temperature oxidation resistance that is much better than that of the CrN film at 900 or 1000 °C.
基金National Natural Science Foundation of China （No. 51275185, No. 51405171） National Basic Research Program of China （No. 2010CB630802-3）+1 种基金 Graduate Innovation and Entrepreneurship Fund of Huazhong University of Science and Technology （No. 0109070112） Fundamental Research Funds for the Central Universities （No. 0118110621）
文摘The fatigue behavior of press hardened Al-Si coated high strength steel has been investigated,and the fatigue strength turns out to be about 1 000 MPa.Surface morphology of fractured and non-fractured specimen has been observed,and the coating shows significant influence on the fatigue behavior.The difference of elastic modulus between coating and substrate led to the main cracks perpendicular to the loading direction.The coating close to fracture exfoliated thinly,while the coating far away from the fracture kept integrated.Though the specimen was polished to obtain high surface quality,3 types of cracks occurred during the fatigue test.What’s more,inclusion particles were proved to play a crucial role in causing these cracks.
基金supported by the National Natural Science Foundation of China(grant No.59571040)
文摘The microstructure of hypoeutectic Al-9.21wt.%Si alloy solidified under 5.5 GPa was studied.The results show that the solidifi cation microstructure is refi ned.The primary α phase is the extended solid solution.The solid solubility of Si in α phase is up to 8.26wt.%.The growth mode of the α phase is cellular,and this cellular growth mechanism is interpreted in terms of the decrease of the diffusivity and the extended solid solution under high pressure.By calculation,it can be known that the the diffusivity of solute in the liquid under normal pressure is as high as two hundred times that under high pressure.The microhardness of the hypoeutectic Al-Si alloy solidif ied under high pressure is higher than that of solidifi ed under normal pressure.After annealing,Si precipitates from the solid solution,the microhardness of the alloy decrease,but,still higher than that of solidif ied under normal pressure.
