A high-current vacuum arc （HCVA） with the consideration of anode vapor is modeled and simulated. First, from the HCVA column model, the heat flux density to the anode is obtained, which is put into the anode activit...A high-current vacuum arc （HCVA） with the consideration of anode vapor is modeled and simulated. First, from the HCVA column model, the heat flux density to the anode is obtained, which is put into the anode activity model, and the parameter distributions （such as the vapor temperature and velocity） of anode vapor are obtained from the simulation results of the anode activity model. Then, by iterating and calculating the HCVA column model and anode activity model, the interaction between the HCVA column and the anode vapor is simulated and analyzed. In the simulation, the distribution of the axial magnetic field （AMF） generated by the electrode system is calculated by software ANSYS. The simulation results show that the influence of anode vapor on the parameter distributions in the arc column is significant. The simulation results are also compared with the vacuum arc photograph.展开更多
The gradual advances of offshore oil and gas exploitation and the development tendency of equipment integration have prompted the design of a new type of the high-current composite umbilical to meet development needs....The gradual advances of offshore oil and gas exploitation and the development tendency of equipment integration have prompted the design of a new type of the high-current composite umbilical to meet development needs.In order to study the mechanical behavior of the high-current composite umbilical(HCCU)and provide design suggestions,a theoretical analysis framework of the tension-torsion coupled behavior of the spirally wound structure is proposed,which focuses more on the radial mechanical behavior.Then,by considering the mechanical and thermal conditions during the operation of HCCU,a semi-analytical method of the tension and torsion stiffness of the high-current composite umbilical considering the temperature effect is established.Furthermore,a practical case of HCCU is given,and the thermal effect on the radial and axial mechanical behaviors are analyzed.It is found that the thermal effect has a significant influence on the radial stiffness,and shows non-linear variation characteristics.Finally,the sensitivity analysis is carried out to study the influence of the design parameter on the stiffness of tension and torsion.The results indicated that the equivalent radial stiffness and helical angle have obvious effect on the tension-torsion coupled stiffness,which can provide reasonable reference for the design of HCCU.展开更多
The present paper reports the rapid surface alloying induced by the bombardment of high-current pulsed electron beam. Two kinds of substrate materials were examined to show this effect. The first sample was a pure Al ...The present paper reports the rapid surface alloying induced by the bombardment of high-current pulsed electron beam. Two kinds of substrate materials were examined to show this effect. The first sample was a pure Al metal pre-coated with fine carbon powders prior to the bombardment, and the second alloy is the D2-Crl2MolVl mould steel pre-coated with Cr, Ti, and TiN powders. The surface elements diffuse about several micrometers into the substrate materials only after several bombardments. Tribological behaviors of these samples were characterized and significant improvement in wear resistance was found. Finally, a TEM analysis reveals the presence of stress waves generated by coupled thermal and stress fields, which was considered as the main cause of the enhanced properties.展开更多
One should pay attention to quite a lot of factors when the emittance of high-current ion beam is measured. The background subtraction and threshold setting,the measuring method of pulsed beam emittance,as well as the...One should pay attention to quite a lot of factors when the emittance of high-current ion beam is measured. The background subtraction and threshold setting,the measuring method of pulsed beam emittance,as well as the error sources in the emittance measurements and its elimination or correction are discussed based on the experience during the R&D of three emittance measurement units for high-current ion beams at Peking University.展开更多
The high-current pulsed electron beam(HCPEB) treatment with current density 6 J/cm^2 was applied on AZ91 Mg alloy to improve its corrosion resistance. Results showed that the net-like Mg_(17)Al_(12) disappeared on the...The high-current pulsed electron beam(HCPEB) treatment with current density 6 J/cm^2 was applied on AZ91 Mg alloy to improve its corrosion resistance. Results showed that the net-like Mg_(17)Al_(12) disappeared on the surface of AZ91 Mg alloy after irradiation by HCPEB, which was instead of supersaturated Al element on the surface. Nevertheless, the application of HCPEB also led to the formation of crater-like and groove-like structures as well as micro-cracks on the surface of AZ91 Mg alloy. After HCPEB treatment by 3, 5 and 10 pulses, the AZ91 Mg alloy exhibited better corrosion resistance.However, the increasing amount of micro-cracks reduced the anti-corrosive properties of AZ91 Mg alloy as the pulse increased to 20 and 30.展开更多
Ti–Al surface alloy was fabricated using a cyclic pulsed liquid-phase mixing of predeposited 100 nm Al film with a-Ti substrate by low-energy high-current electron beam. Electron probe micro-analysis（EPMA）,grazing ...Ti–Al surface alloy was fabricated using a cyclic pulsed liquid-phase mixing of predeposited 100 nm Al film with a-Ti substrate by low-energy high-current electron beam. Electron probe micro-analysis（EPMA）,grazing incidence X-ray diffraction analysis（GIXRD）,transmission electron microscopy（TEM）, and nanoindentation were used to investigate the characterization of Ti–Al surface alloy. The experimental results show that the thickness of alloy layer is ＊3 lm, and the content of Al in the ＊1 lm thickness surface layer is ＊60 at%. The tetragonal TiAl and TiAl2intermetallics were synthesized at the top surface, which have nanocrystalline structure.The main phase formed in the ＊2.5 lm thick surface is TiAl, and there are few TiAl2and Ti3Al phase for the alloy.Dislocation is enhanced in the alloyed layer. The nanohardness of Ti–Al surface alloy increased significantly compared with a-Ti substrate due to the nanostructure and enhanced dislocation. Since the e-beam remelted repeatedly, the Ti–Al surface alloy mixed sufficiently with Ti substrate. Moreover, there is no obvious boundary between the alloyed layer and substrate.展开更多
In this paper, we present an experimental investigation of deformation twinning in polycrystalline aluminum exposed to high-current pulsed electron beam (HCPEB) irradiation. The residual tensile stress with about 10 2...In this paper, we present an experimental investigation of deformation twinning in polycrystalline aluminum exposed to high-current pulsed electron beam (HCPEB) irradiation. The residual tensile stress with about 10 2 MPa was introduced in the irradiated surface layer. The feature characteristic irradiated with various numbers of pulses was investigated. The formation of a large number of twin bands on the surface irradiated with multiple pulses was determined. The experimental observations indicated that the deformation twinning was indeed triggered during HCPEB irradiation. It is suggested that high value of stress and strain rate induced by rapid heating and cooling due to HCPEB irradiation may cause the shifting of whole atomic planes simultaneously. Additionally, some slipping systems may be suppressed due to the geometric confinement by thinned size of surface layer, which can promote the initiation of deformation twinning.展开更多
Energy recovery linacs are promising for achieving high average current with superior beam quality.The key component for accelerating such high-current beams is the superconducting radio-frequency cavity.The design of...Energy recovery linacs are promising for achieving high average current with superior beam quality.The key component for accelerating such high-current beams is the superconducting radio-frequency cavity.The design of a 1.3 GHz five-cell high-current superconducting cavity has been carried out under cooperation between Peking University and the Argonne National Laboratory.The radio-frequency properties,damping of the higher order modes,multipacting and mechanical features of this cavity have been discussed and the final design is presented.展开更多
N-type Si(111) wafers have been processed by high-current pulsed electron beam(HCPEB) treatment with an increasing number of irradiation(1, 10 and 20pulses). The results of this work show that a highly porous nanostru...N-type Si(111) wafers have been processed by high-current pulsed electron beam(HCPEB) treatment with an increasing number of irradiation(1, 10 and 20pulses). The results of this work show that a highly porous nanostructure was formed after irradiation. Moreover, the high-density Si nanocrystals(Si-ncs) about 3 nm were distributed on the surface of Si wafers and exhibited3.02 e V Photoluminescence(PL) emission in blue band.The PL intensity increases with the increase in the Si-ncs' density in accordance with the quantum confinement model, which can be ascribed to the different pulse time of HCPEB treatment. The possible formation mechanisms of micropores and Si-ncs are discussed.展开更多
The Advanced Photon Source （APS） at Argonne National Laboratory is considering the development of a superconducting linac-based fourth-generation hard X-ray source to meet future scientific needs of the hard X-ray u...The Advanced Photon Source （APS） at Argonne National Laboratory is considering the development of a superconducting linac-based fourth-generation hard X-ray source to meet future scientific needs of the hard X-ray user community. This work specifically focuses on the design of an optimized 5-cell superconducting radio-frequency structure well suited for a high-energy, high-beam-current energy recovery linac. The cavity design parameters are based on the APS storage ring nominal 7 GeV and 100 mA beam operation. A high-current 5-cell cw superconducting cavity operating at 1.4 GHz has been designed. In order to achieve a high current, the accelerating cavity shape has been optimized and large end-cell beam pipes have been adopted. The beam break-up threshold of the cavity has been estimated using the code TDBBU, which predicts a high threshold beam current for a 7 GeV energy recovery linac model. A copper prototype cavity has been fabricated that uses half-cell modules, initially assembled by clamping the cells together.展开更多
利用可再生能源发电,并通过低温电解水技术生产氢气,被认为是一种环保且可持续的制氢途径,是未来氢能发展的重要方向之一.采用该方法生产的氢气因其环保特性而被称为“绿氢”.然而,目前绿氢高昂的生产成本限制了电解水制氢技术的大规模...利用可再生能源发电,并通过低温电解水技术生产氢气,被认为是一种环保且可持续的制氢途径,是未来氢能发展的重要方向之一.采用该方法生产的氢气因其环保特性而被称为“绿氢”.然而,目前绿氢高昂的生产成本限制了电解水制氢技术的大规模应用.因此,开发先进的非贵金属催化剂和电催化体系以降低电解水制氢成本具有重要意义.界面工程是一种提升非贵金属催化剂电解水性能的有效策略,但目前对其催化活性位点的识别及活性提升机制的研究仍然不足.本文采用简单的水热及低温磷化法制备了具有丰富异质界面的Ni_(2)P/CoP/FeP_(4)/IF催化剂,并研究了其在电解水过程中的催化活性位点及这些位点在提升催化能力方面的协同作用.采用扫描电镜(SEM)证明了Ni_(2)P/CoP/FeP_(4)/IF催化剂呈现纳米线网络结构,这种结构不仅有利于增加催化剂的电化学活性位点和加速反应动力学,而且促进了连续产生的气泡从活性位点逃逸,从而提高了催化剂的机械稳定性.电化学研究结果表明,所制备Ni_(2)P/CoP/FeP_(4)/IF催化剂在1.0 mol L^(‒1)KOH溶液中表现出较好的析氧反应(OER)和析氢反应(HER)活性,分别仅需218和127 mV的过电位,即可达到100 mA cm^(‒2)的电流密度.将Ni_(2)P/CoP/FeP_(4)/IF分别作为阴极和阳极构建双电极电解槽,该装置产生100和500 mA cm^(‒2)的电流密度分别仅需1.68和2.05 V的电压,这一性能优于大多数已报道的自支撑过渡金属磷化物催化剂.多步计时电位测试结果进一步证实了Ni_(2)P/CoP/FeP_(4)/IF作为阳极和阴极材料在水分解过程中具有较好的长期耐久性.X射线光电子能谱和差分电荷分析表明,电子从富电子的FeP_(4)向缺电子的Ni_(2)P和CoP转移,这促使Ni_(2)P和CoP上的电子积累和FeP_(4)上的空穴积累,有利于优化反应中间体的吸附和脱附自由能,提升OER和HER催化性能.结合X射线衍射、扫描电镜、透射电镜、X射线光电子能谱和原位拉曼光谱结果发现,催化剂重构后形成的特定(氧)氢氧化物结构,是OER反应真正的关键活性位点.原位拉曼光谱进一步证实了异质界面促进了OER过程中Ni_(2)P/CoP/FeP_(4)/IF的快速重构.此外,利用密度泛函理论分析了催化剂的HER反应机理.计算结果表明,H2O优先吸附在Fe位点并发生水解,随后产生的H*吸附在Ni位点上并发生解吸,从而促进了催化剂中Fe和Ni活性位点的高效利用.同时,CoP的引入提高了Ni_(2)P/CoP/FeP_(4)/IF催化剂的水吸附和解离能力,进一步提升了其HER活性.综上所述,本文通过简单的水热及低温磷化法制备了具有丰富异质界面的Ni_(2)P/CoP/FeP_(4)/IF过渡金属磷化物纳米线网络催化剂,并将其用于碱性水分解.通过多种表征技术及理论计算结果分析,识别了电解水过程中的关键催化活性位点,即催化剂重构后形成的特定(氧)氢氧化物结构,并揭示了其在OER和HER反应中的催化机制.本研究可为高性能碱性电解水催化剂的理性设计和开发提供参考.展开更多
基金supported by National Natural Science Foundation of China (No. 50907045)
文摘A high-current vacuum arc （HCVA） with the consideration of anode vapor is modeled and simulated. First, from the HCVA column model, the heat flux density to the anode is obtained, which is put into the anode activity model, and the parameter distributions （such as the vapor temperature and velocity） of anode vapor are obtained from the simulation results of the anode activity model. Then, by iterating and calculating the HCVA column model and anode activity model, the interaction between the HCVA column and the anode vapor is simulated and analyzed. In the simulation, the distribution of the axial magnetic field （AMF） generated by the electrode system is calculated by software ANSYS. The simulation results show that the influence of anode vapor on the parameter distributions in the arc column is significant. The simulation results are also compared with the vacuum arc photograph.
基金financially supported by the National Key R&D Program of China(Grant No.2021YFA1003501)the National Natural Science Foundation of China(Grant Nos.U1906233 and 52001088)+1 种基金the Key R&D Program of Shandong Province(Grant No.2019JZZY010801)the Fundamental Research Funds for the Central Universities(Grant Nos.DUT20ZD213 and DUT20LAB308)。
文摘The gradual advances of offshore oil and gas exploitation and the development tendency of equipment integration have prompted the design of a new type of the high-current composite umbilical to meet development needs.In order to study the mechanical behavior of the high-current composite umbilical(HCCU)and provide design suggestions,a theoretical analysis framework of the tension-torsion coupled behavior of the spirally wound structure is proposed,which focuses more on the radial mechanical behavior.Then,by considering the mechanical and thermal conditions during the operation of HCCU,a semi-analytical method of the tension and torsion stiffness of the high-current composite umbilical considering the temperature effect is established.Furthermore,a practical case of HCCU is given,and the thermal effect on the radial and axial mechanical behaviors are analyzed.It is found that the thermal effect has a significant influence on the radial stiffness,and shows non-linear variation characteristics.Finally,the sensitivity analysis is carried out to study the influence of the design parameter on the stiffness of tension and torsion.The results indicated that the equivalent radial stiffness and helical angle have obvious effect on the tension-torsion coupled stiffness,which can provide reasonable reference for the design of HCCU.
文摘The present paper reports the rapid surface alloying induced by the bombardment of high-current pulsed electron beam. Two kinds of substrate materials were examined to show this effect. The first sample was a pure Al metal pre-coated with fine carbon powders prior to the bombardment, and the second alloy is the D2-Crl2MolVl mould steel pre-coated with Cr, Ti, and TiN powders. The surface elements diffuse about several micrometers into the substrate materials only after several bombardments. Tribological behaviors of these samples were characterized and significant improvement in wear resistance was found. Finally, a TEM analysis reveals the presence of stress waves generated by coupled thermal and stress fields, which was considered as the main cause of the enhanced properties.
文摘One should pay attention to quite a lot of factors when the emittance of high-current ion beam is measured. The background subtraction and threshold setting,the measuring method of pulsed beam emittance,as well as the error sources in the emittance measurements and its elimination or correction are discussed based on the experience during the R&D of three emittance measurement units for high-current ion beams at Peking University.
基金the finacial support from the National Natural Science Foundation of China(Nos.51771128 and 51771129)the Projects of International Cooperation in Shanxi(No.201703D421039)the Natural Science Foundation of Shanxi(No.201601D011034)
文摘The high-current pulsed electron beam(HCPEB) treatment with current density 6 J/cm^2 was applied on AZ91 Mg alloy to improve its corrosion resistance. Results showed that the net-like Mg_(17)Al_(12) disappeared on the surface of AZ91 Mg alloy after irradiation by HCPEB, which was instead of supersaturated Al element on the surface. Nevertheless, the application of HCPEB also led to the formation of crater-like and groove-like structures as well as micro-cracks on the surface of AZ91 Mg alloy. After HCPEB treatment by 3, 5 and 10 pulses, the AZ91 Mg alloy exhibited better corrosion resistance.However, the increasing amount of micro-cracks reduced the anti-corrosive properties of AZ91 Mg alloy as the pulse increased to 20 and 30.
基金financially supported by the National Natural Science Foundation of China and the Russian Foundation for Basic Research (No. 11011120081)Large Scientific Facilities of the National Natural Science Foundation of China and of the Chinese Academy of Sciences (No. 11079012)the National Natural Science Foundation of China (No. 10875021)
文摘Ti–Al surface alloy was fabricated using a cyclic pulsed liquid-phase mixing of predeposited 100 nm Al film with a-Ti substrate by low-energy high-current electron beam. Electron probe micro-analysis（EPMA）,grazing incidence X-ray diffraction analysis（GIXRD）,transmission electron microscopy（TEM）, and nanoindentation were used to investigate the characterization of Ti–Al surface alloy. The experimental results show that the thickness of alloy layer is ＊3 lm, and the content of Al in the ＊1 lm thickness surface layer is ＊60 at%. The tetragonal TiAl and TiAl2intermetallics were synthesized at the top surface, which have nanocrystalline structure.The main phase formed in the ＊2.5 lm thick surface is TiAl, and there are few TiAl2and Ti3Al phase for the alloy.Dislocation is enhanced in the alloyed layer. The nanohardness of Ti–Al surface alloy increased significantly compared with a-Ti substrate due to the nanostructure and enhanced dislocation. Since the e-beam remelted repeatedly, the Ti–Al surface alloy mixed sufficiently with Ti substrate. Moreover, there is no obvious boundary between the alloyed layer and substrate.
基金supported by the National Natural Science Foundation of China (U1233111, 50671042)Open Foundation of Key Laboratory of Materials Modification by Laser, Ion and Electron Beams, Ministry of Education, Dalian University of Technology (DP1051102)
文摘In this paper, we present an experimental investigation of deformation twinning in polycrystalline aluminum exposed to high-current pulsed electron beam (HCPEB) irradiation. The residual tensile stress with about 10 2 MPa was introduced in the irradiated surface layer. The feature characteristic irradiated with various numbers of pulses was investigated. The formation of a large number of twin bands on the surface irradiated with multiple pulses was determined. The experimental observations indicated that the deformation twinning was indeed triggered during HCPEB irradiation. It is suggested that high value of stress and strain rate induced by rapid heating and cooling due to HCPEB irradiation may cause the shifting of whole atomic planes simultaneously. Additionally, some slipping systems may be suppressed due to the geometric confinement by thinned size of surface layer, which can promote the initiation of deformation twinning.
基金Supported by National High Technology Research and Development Program 863 (2009AA03Z206)
文摘Energy recovery linacs are promising for achieving high average current with superior beam quality.The key component for accelerating such high-current beams is the superconducting radio-frequency cavity.The design of a 1.3 GHz five-cell high-current superconducting cavity has been carried out under cooperation between Peking University and the Argonne National Laboratory.The radio-frequency properties,damping of the higher order modes,multipacting and mechanical features of this cavity have been discussed and the final design is presented.
基金supported by the National Natural Science Foundation of China(50671042)the Ph.D.Innovation Programs Foundation of Jiangsu Province(CXZZ12_0671)
文摘N-type Si(111) wafers have been processed by high-current pulsed electron beam(HCPEB) treatment with an increasing number of irradiation(1, 10 and 20pulses). The results of this work show that a highly porous nanostructure was formed after irradiation. Moreover, the high-density Si nanocrystals(Si-ncs) about 3 nm were distributed on the surface of Si wafers and exhibited3.02 e V Photoluminescence(PL) emission in blue band.The PL intensity increases with the increase in the Si-ncs' density in accordance with the quantum confinement model, which can be ascribed to the different pulse time of HCPEB treatment. The possible formation mechanisms of micropores and Si-ncs are discussed.
基金Supported by the U.S. Department of Energy,Office of Science,Office of Basic Energy Sciences,DE-AC02-06CH11357)
文摘The Advanced Photon Source （APS） at Argonne National Laboratory is considering the development of a superconducting linac-based fourth-generation hard X-ray source to meet future scientific needs of the hard X-ray user community. This work specifically focuses on the design of an optimized 5-cell superconducting radio-frequency structure well suited for a high-energy, high-beam-current energy recovery linac. The cavity design parameters are based on the APS storage ring nominal 7 GeV and 100 mA beam operation. A high-current 5-cell cw superconducting cavity operating at 1.4 GHz has been designed. In order to achieve a high current, the accelerating cavity shape has been optimized and large end-cell beam pipes have been adopted. The beam break-up threshold of the cavity has been estimated using the code TDBBU, which predicts a high threshold beam current for a 7 GeV energy recovery linac model. A copper prototype cavity has been fabricated that uses half-cell modules, initially assembled by clamping the cells together.
文摘利用可再生能源发电,并通过低温电解水技术生产氢气,被认为是一种环保且可持续的制氢途径,是未来氢能发展的重要方向之一.采用该方法生产的氢气因其环保特性而被称为“绿氢”.然而,目前绿氢高昂的生产成本限制了电解水制氢技术的大规模应用.因此,开发先进的非贵金属催化剂和电催化体系以降低电解水制氢成本具有重要意义.界面工程是一种提升非贵金属催化剂电解水性能的有效策略,但目前对其催化活性位点的识别及活性提升机制的研究仍然不足.本文采用简单的水热及低温磷化法制备了具有丰富异质界面的Ni_(2)P/CoP/FeP_(4)/IF催化剂,并研究了其在电解水过程中的催化活性位点及这些位点在提升催化能力方面的协同作用.采用扫描电镜(SEM)证明了Ni_(2)P/CoP/FeP_(4)/IF催化剂呈现纳米线网络结构,这种结构不仅有利于增加催化剂的电化学活性位点和加速反应动力学,而且促进了连续产生的气泡从活性位点逃逸,从而提高了催化剂的机械稳定性.电化学研究结果表明,所制备Ni_(2)P/CoP/FeP_(4)/IF催化剂在1.0 mol L^(‒1)KOH溶液中表现出较好的析氧反应(OER)和析氢反应(HER)活性,分别仅需218和127 mV的过电位,即可达到100 mA cm^(‒2)的电流密度.将Ni_(2)P/CoP/FeP_(4)/IF分别作为阴极和阳极构建双电极电解槽,该装置产生100和500 mA cm^(‒2)的电流密度分别仅需1.68和2.05 V的电压,这一性能优于大多数已报道的自支撑过渡金属磷化物催化剂.多步计时电位测试结果进一步证实了Ni_(2)P/CoP/FeP_(4)/IF作为阳极和阴极材料在水分解过程中具有较好的长期耐久性.X射线光电子能谱和差分电荷分析表明,电子从富电子的FeP_(4)向缺电子的Ni_(2)P和CoP转移,这促使Ni_(2)P和CoP上的电子积累和FeP_(4)上的空穴积累,有利于优化反应中间体的吸附和脱附自由能,提升OER和HER催化性能.结合X射线衍射、扫描电镜、透射电镜、X射线光电子能谱和原位拉曼光谱结果发现,催化剂重构后形成的特定(氧)氢氧化物结构,是OER反应真正的关键活性位点.原位拉曼光谱进一步证实了异质界面促进了OER过程中Ni_(2)P/CoP/FeP_(4)/IF的快速重构.此外,利用密度泛函理论分析了催化剂的HER反应机理.计算结果表明,H2O优先吸附在Fe位点并发生水解,随后产生的H*吸附在Ni位点上并发生解吸,从而促进了催化剂中Fe和Ni活性位点的高效利用.同时,CoP的引入提高了Ni_(2)P/CoP/FeP_(4)/IF催化剂的水吸附和解离能力,进一步提升了其HER活性.综上所述,本文通过简单的水热及低温磷化法制备了具有丰富异质界面的Ni_(2)P/CoP/FeP_(4)/IF过渡金属磷化物纳米线网络催化剂,并将其用于碱性水分解.通过多种表征技术及理论计算结果分析,识别了电解水过程中的关键催化活性位点,即催化剂重构后形成的特定(氧)氢氧化物结构,并揭示了其在OER和HER反应中的催化机制.本研究可为高性能碱性电解水催化剂的理性设计和开发提供参考.
