Commercial hydrocarbon reservoirs have been discovered in shallow-water areas of the Scotian Basin, Eastern Canada. However, knowledge about the structure and hydrocarbon accumulation characteristics of the basin is s...Commercial hydrocarbon reservoirs have been discovered in shallow-water areas of the Scotian Basin, Eastern Canada. However, knowledge about the structure and hydrocarbon accumulation characteristics of the basin is still insufficient, which constrains the oil and gas exploration in deep-water areas. Based on comprehensive data of magnetic anomalies, seismic survey, and drilling, this study determines the structure characteristics of the Scotian Basin and its hydrocarbon accumulation conditions in deep waters and evaluates the deep-water hydrocarbon exploration potential. The transform faults and basement structures in the northern basin control the sedimentary framework showing thick strata in east and thin strata in west of the basin. The bowl-shaped depression formed by thermal subsidence during the transitional phase and the confined environment (micro basins) caused by salt tectonics provide favorable conditions for the development of source rocks during the depression stage (also referred to as the depression period sequence) of the basin. The progradation of large shelf-margin deltas during the drift phase and steep continental slope provide favorable conditions for the deposition of slope-floor fans on continental margins of the basin. Moreover, the source-reservoir assemblage comprising the source rocks within the depression stage and the turbidite sandstones on the continental margin in the deep waters may form large deep-water turbidite sandstone reservoirs. This study will provide a valuable reference for the deep-water hydrocarbon exploration in the Scotian Basin.展开更多
Based on the oil and gas exploration practice in the Songliao Basin,combined with the latest exploration and development data such as seismic,well logging and geochemistry,the basic geological conditions,oil and gas t...Based on the oil and gas exploration practice in the Songliao Basin,combined with the latest exploration and development data such as seismic,well logging and geochemistry,the basic geological conditions,oil and gas types and distribution characteristics,reservoir-forming dynamics,source-reservoir relationship and hydrocarbon accumulation model of the whole petroleum system in shallow and medium strata in the northern part of Songliao Basin are systematically studied.The shallow-medium strata in northern Songliao Basin have the conditions for the formation of whole petroleum system,with sufficient oil and gas sources,diverse reservoir types and well-developed transport system,forming a whole petroleum system centered on the source rocks of the Cretaceous Qingshankou Formation.Different types of oil and gas resources in the whole petroleum system are correlated with each other in terms of depositional system,lithologic association and physical property changes,and they,to a certain extent,have created the spatial framework with orderly symbiosis of shallow-medium conventional oil reservoirs,tight oil reservoirs and shale oil reservoirs in northern Songliao Basin.Vertically,the resources are endowed as conventional oil above source,shale oil/tight oil within source,and tight oil below source.Horizontally,conventional oil,tight oil,interlayer-type shale oil,and pure shale-type shale oil are developed in an orderly way,from the margin of the basin to the center of the depression.Three hydrocarbon accumulation models are recognized for the whole petroleum system in northern Songliao Basin,namely,buoyancy-driven charging of conventional oil above source,retention of shale oil within source,and pressure differential-driven charging of tight oil below source.展开更多
Using the data of drilling, logging, core, experiments and production, the heterogeneity and differential hydrocarbon accumulation model of deep reservoirs in Cretaceous Qingshuihe Formation(K1q) in the western sectio...Using the data of drilling, logging, core, experiments and production, the heterogeneity and differential hydrocarbon accumulation model of deep reservoirs in Cretaceous Qingshuihe Formation(K1q) in the western section of the foreland thrust belt in southern Junggar Basin are investigated. The target reservoirs are characterized by superimposition of conglomerates, sandy conglomerates and sandstones, with high content of plastic clasts. The reservoir space is mainly composed of intergranular pores. The reservoirs are overall tight, and the sandy conglomerate has the best physical properties. The coupling of short deep burial period with low paleotemperature gradient and formation overpressure led to the relatively weak diagenetic strength of the reservoirs. Specifically, the sandy conglomerates show relatively low carbonate cementation, low compaction rate and high dissolution porosity. The special stress-strain mechanism of the anticline makes the reservoirs at the top of the anticline turning point more reformed by fractures than those at the limbs, and the formation overpressure makes the fractures in open state. Moreover, the sandy conglomerates have the highest oil saturation. Typical anticline reservoirs are developed in deep part of the thrust belt, but characterized by "big trap with small reservoir". Significantly, the sandy conglomerates at the top of anticline turning point have better quality, lower in-situ stress and higher structural position than those at the limbs,with the internal hydrocarbons most enriched, making them high-yield oil/gas layers. The exponential decline of fractures makes hydrocarbon accumulation difficult in the reservoirs at the limbs. Nonetheless, plane hydrocarbon distribution is more extensive at the gentle limb than the steep limb.展开更多
The fluid evolution and reservoir formation model of the ultra-deep gas reservoirs in the Permian Qixia Formation of the northwestern Sichuan Basin are investigated by using thin section,cathodoluminescence,inclusion ...The fluid evolution and reservoir formation model of the ultra-deep gas reservoirs in the Permian Qixia Formation of the northwestern Sichuan Basin are investigated by using thin section,cathodoluminescence,inclusion temperature and U-Pb isotopic dating,combined with gas source identification plates and reservoir formation evolution profiles established based on burial history,thermal history,reservoir formation history and diagenetic evolution sequence.The fluid evolution of the marine ultra-deep gas reservoirs in the Qixia Formation has undergone two stages of dolomitization and one phase of hydrothermal action,two stages of oil and gas charging and two stages of associated burial dissolution.The diagenetic fluids include ancient seawater,atmospheric freshwater,deep hydrothermal fluid and hydrocarbon fluids.The two stages of hydrocarbon charging happened in the Late Triassic and Late Jurassic–Early Cretaceous respectively,and the Middle to Late Cretaceous is the period when the crude oil cracked massively into gas.The gas reservoirs in deep marine Permian strata of northwest Sichuan feature multiple source rocks,composite transportation,differential accumulation and late finalization.The natural gas in the Permian is mainly cracked gas from Permian marine mixed hydrocarbon source rocks,with cracked gas from crude oil in the deeper Sinian strata in local parts.The scale development of paleo-hydrocarbon reservoirs and the stable and good preservation conditions are the keys to the forming large-scale gas reservoirs.展开更多
Based on the practice of oil and gas exploration and the analysis of shallow lithologic reservoirs,combined with the allocation relationship and enrichment law of oil and gas accumulation factors,main controlling fact...Based on the practice of oil and gas exploration and the analysis of shallow lithologic reservoirs,combined with the allocation relationship and enrichment law of oil and gas accumulation factors,main controlling factors and models of hydrocarbon accumulation of large lithologic reservoirs in shallow strata around the Bozhong sag are summarized,and favorable exploration areas are proposed.The coupling of the four factors of“ridge-fault-sand-zone”is crucial for the hydrocarbon enrichment in the shallow lithologic reservoirs.The convergence intensity of deep convergence ridges is the basis for shallow oil and gas enrichment,the activity intensity of large fault cutting ridges and the thickness of cap rocks control the vertical migration ability of oil and gas,the coupling degree of large sand bodies and fault cutting ridges control large-scale oil and gas filling,the fault sealing ability of structural stress concentration zones affects the enrichment degree of lithologic oil and gas reservoirs.Three enrichment models including uplift convergence type,steep slope sand convergence type and depression uplift convergence type are established through the case study of lithologic reservoirs in shallow strata around the Bozhong sag.展开更多
With continuous hydrocarbon exploration extending to deeper basins,the deepest industrial oil accumulation was discovered below 8,200 m,revealing a new exploration field.Hence,the extent to which oil exploration can b...With continuous hydrocarbon exploration extending to deeper basins,the deepest industrial oil accumulation was discovered below 8,200 m,revealing a new exploration field.Hence,the extent to which oil exploration can be extended,and the prediction of the depth limit of oil accumulation(DLOA),are issues that have attracted significant attention in petroleum geology.Since it is difficult to characterize the evolution of the physical properties of the marine carbonate reservoir with burial depth,and the deepest drilling still cannot reach the DLOA.Hence,the DLOA cannot be predicted by directly establishing the relationship between the ratio of drilling to the dry layer and the depth.In this study,by establishing the relationships between the porosity and the depth and dry layer ratio of the carbonate reservoir,the relationships between the depth and dry layer ratio were obtained collectively.The depth corresponding to a dry layer ratio of 100%is the DLOA.Based on this,a quantitative prediction model for the DLOA was finally built.The results indicate that the porosity of the carbonate reservoir,Lower Ordovician in Tazhong area of Tarim Basin,tends to decrease with burial depth,and manifests as an overall low porosity reservoir in deep layer.The critical porosity of the DLOA was 1.8%,which is the critical geological condition corresponding to a 100%dry layer ratio encountered in the reservoir.The depth of the DLOA was 9,000 m.This study provides a new method for DLOA prediction that is beneficial for a deeper understanding of oil accumulation,and is of great importance for scientific guidance on deep oil drilling.展开更多
The Ediacaran–Ordovician strata within three major marine basins(Tarim,Sichuan,and Ordos)in China are analyzed.Based on previous studies focusing on the characteristics of the Neoproterozoic–Cambrian strata within t...The Ediacaran–Ordovician strata within three major marine basins(Tarim,Sichuan,and Ordos)in China are analyzed.Based on previous studies focusing on the characteristics of the Neoproterozoic–Cambrian strata within the three major basins(East Siberian,Oman,and Officer in Australia)overseas,the carbonate–evaporite assemblages in the target interval are divided into three types:intercalated carbonate and gypsum salt,interbedded carbonate and gypsum salt,and coexisted carbonate,gypsum salt and clastic rock.Moreover,the concept and definition of the carbonate-evaporite assemblage are clarified.The results indicate that the oil and gas in the carbonate-evaporite assemblage are originated from two types of source rocks:shale and argillaceous carbonate,and confirmed the capability of gypsum salt in the saline environment to drive the source rock hydrocarbon generation.The dolomite reservoirs are classified in two types:gypseous dolomite flat,and grain shoalµbial mound.This study clarifies that the penecontemporaneous or epigenic leaching of atmospheric fresh water mainly controlled the large-scale development of reservoirs.Afterwards,burial dissolution transformed and reworked the reservoirs.The hydrocarbon accumulation in carbonate-evaporite assemblage can be categorized into eight sub-models under three models(sub-evaporite hydrocarbon accumulation,supra-evaporite hydrocarbon accumulation,and inter-evaporite hydrocarbon accumulation).As a result,the Cambrian strata in the Tazhong Uplift North Slope,Maigaiti Slope and Mazatag Front Uplift Zone of the Tarim Basin,the Cambrian strata in the eastern-southern area of the Sichuan Basin,and the inter-evaporite Ma-4 Member of Ordovician in the Ordos Basin,China,are defined as favorable targets for future exploration.展开更多
Based on the analysis of the fluid inclusion homogenization temperature and apatite fission track on the northern slope zone of the Bongor Basin in Chad,this paper studied the time and stages of hydrocarbon accumulati...Based on the analysis of the fluid inclusion homogenization temperature and apatite fission track on the northern slope zone of the Bongor Basin in Chad,this paper studied the time and stages of hydrocarbon accumulation in the study area.The results show that:(1)The brine inclusions of the samples from the Kubla and Prosopis formations in the Lower Cretaceous coexisting with the hydrocarbon generally present two sets of peak ranges of homogenization temperature,with the peak ranges of low temperature and high temperature being 75–105℃ and 115–135℃,respectively;(2)The samples from the Kubla and Prosopis formations have experienced five tectonic evolution stages,i.e.,rapid subsidence in the Early Cretaceous,tectonic inversion in the Late Cretaceous,small subsidence in the Paleogene,uplift at the turn of the Paleogene and Neogene,and subsidence since the Miocene,in which the denudation thickness of the Late Cretaceous and after the turn of the Paleogene and Neogene are~1.8 km and~0.5 km,respectively.The cumulative denudation thickness of the two periods is about 2.3 km;(3)Using the brine inclusion homogenization temperature coexisting with the hydrocarbon as the capture temperature of the hydrocarbon,and combining with the apatite fission track thermal history modeling,the result shows that the Kubla and Prosopis formations in the Lower Cretaceous on the northern slope of the Bongor Basin have the same hydrocarbon accumulation time and stages,both of which have undergone two stages of hydrocarbon charging at 80–95 Ma and 65–80 Ma.The first stage of charging corresponds to the initial migration of hydrocarbon at the end of the Early Cretaceous rapid sedimentation,while the second stage of charging is in the stage of intense tectonic inversion in the Late Cretaceous.展开更多
According to the latest drilling and the analysis of the burial history,source rock evolution history and hydrocarbon accumulation history,the sub-source hydrocarbon accumulation characteristics of the Permian reservo...According to the latest drilling and the analysis of the burial history,source rock evolution history and hydrocarbon accumulation history,the sub-source hydrocarbon accumulation characteristics of the Permian reservoirs in the Jinan Sag,eastern Junggar Basin,are clarified,and the hydrocarbon accumulation model of these reservoirs is established.The results are obtained in four aspects.First,the main body of the thick salified lake basin source rocks in the Lucaogou Formation has reached the mature stage with abundant resource base.Large-scale reservoirs are developed in the Jingjingzigou,Wutonggou and Lucaogou formations.Vertically,there are multiple sets of good regional seals,the source-reservoir-caprock assemblage is good,and there are three reservoir-forming assemblages:sub-source,intra-source and above-source.Second,dissolution,hydrocarbon charging and pore-preserving effect,and presence of chlorite film effectively increase the sub-source pore space.Oil charging is earlier than the time when the reservoir becomes densified,which improves the efficiency of hydrocarbon accumulation.Third,buoyancy and source-reservoir pressure difference together constitute the driving force of oil charging,and the micro-faults within the formation give the advantage of"source-reservoir lateral docking"under the source rock.Microfractures can be critical channels for efficient seepage and continuous charging of oil in different periods.Fourth,the Jingjingzigou Formation experienced three periods of oil accumulation in the Middle-Late Permian,Middle-Late Jurassic and Late Neogene,with the characteristics of long-distance migration and accumulation in early stage,mixed charging and accumulation in middle stage and short-distance migration and high-position accumulation in late stage.The discovery and theoretical understanding of the Permian reservoirs in the Jinan Sag reveal that the thrust belt has good conditions for forming large reservoirs,and it is promising for exploration.The study results are of guidance and reference significance for oil and gas exploration in the Jinan Sag and other geologically similar areas.展开更多
The geologic conditions of superimposed basins in China are very complicated. This is mainly shown by multi-phase structural evolution,multiple sets of source-reservoir-cap rock combinations,multiple stages of hydroca...The geologic conditions of superimposed basins in China are very complicated. This is mainly shown by multi-phase structural evolution,multiple sets of source-reservoir-cap rock combinations,multiple stages of hydrocarbon generation and expulsion from source rocks,multi-cycle hydrocarbon enrichment and accumulation,and multi-phase reservoir adjustment and reconstruction. The enrichment,accumulation and distribution of hydrocarbon is mainly controlled by the source rock kitchen,paleoanticline,regional cap rock and intensity of tectonic movement. In this paper,the T-BCMS model has been developed to predict favorable areas of hydrocarbon accumulation in complicated superimposed basins according to time and spatial relationships among five key factors. The five factors include unconformity surface representing tectonic balancing(B) ,regional cap rock representing hydrocarbon protection(C) ,paleo-anticline representing hydrocarbon migration and accumulation(M) ,source rock kitchen representing hydrocarbon generation and expulsion(S) and geological time(T) . There are three necessary conditions to form favorable areas of hydrocarbon accumulation. First,four key factors BCMS should be strictly in the order of BCMS from top to bottom. Second,superimposition of four key factors BCMS in the same area is the most favorable for hydrocarbon accumulation. Third,vertically ordered combination and superimposition in the same area of BCMS should occur at the same geological time. The model has been used to predict the most favorable exploration areas in Ordovician in the Tarim Basin in the main hydrocarbon accumulation periods. The result shows that 95% of the discovered Ordovician hydrocarbon reservoirs are located in the predicted areas,which indicates the feasibility and reliability of the key factor matching T-BCMS model for hydrocarbon accumulation and enrichment.展开更多
By conducting experimental analyses, including thermal pyrolysis, micro-/nano-CT, argon-ion polishing field emission scanning electron microscopy (FE-SEM), confocal laser scanning microscopy (CLSM), and two-dimensiona...By conducting experimental analyses, including thermal pyrolysis, micro-/nano-CT, argon-ion polishing field emission scanning electron microscopy (FE-SEM), confocal laser scanning microscopy (CLSM), and two-dimensional nuclear magnetic resonance (2D NMR), the Gulong shale oil in the Songliao Basin was investigated with respect to formation model, pore structure and accumulation mechanism. First, in the Gulong shale, there are a large number of pico-algae, nano-algae and dinoflagellates, which were formed in brackish water environment and constituted the hydrogen-rich oil source materials of shale. Second, most of the oil-generating materials of the Qingshankou Formation shale exist in the form of organo-clay complex. During organic matter thermal evolution, clay minerals had double effects of suppression and catalytic hydrogenation, which expanded shale oil window and increased light hydrocarbon yield. Third, the formation of storage space in the Gulong Shale was related to dissolution and hydrocarbon generation. With the diagenesis, micro-/nano-pores increased, pore diameter decreased and more bedding fractures appeared, which jointly gave rise to the unique reservoir with dual media (i.e. nano-scale pores and micro-scale bedding fractures) in the Gulong shale. Fourth, the micro-/nano-scale oil storage unit in the Gulong shale exhibits independent oil/gas occurrence phase, and shows that all-size pores contain oils, which occur in condensate state in micropores or in oil-gas two phase (or liquid) state in macropores/mesopores. The understanding about Gulong shale oil formation and accumulation mechanism has theoretical and practical significance for advancing continental shale oil exploration in China.展开更多
Based on outcrop,seismic and drilling data,the main regional unconformities in the Sichuan Basin and their controls on hydrocarbon accumulation were systematically studied.Three findings are obtained.First,six regiona...Based on outcrop,seismic and drilling data,the main regional unconformities in the Sichuan Basin and their controls on hydrocarbon accumulation were systematically studied.Three findings are obtained.First,six regional stratigraphic unconformities are mainly developed in the Sichuan Basin,from the bottom up which are between pre-Sinian and Sinian,between Sinian and Cambrian,between pre-Permian and Permian,between middle and upper Permian,between middle and upper Triassic,and between Triassic and Jurassic.Especially,16 of 21l conventional(and tight)gas fields discovered are believed to have formed in relation to regional unconformities.Second,regional unconformity mainly controls hydrocarbon accumulation from five aspects:(1)The porosity and permeability of reservoirs under the unconformity are improved through weathering crust karstification to form large-scale karst reservoirs;(2)Good source-reservoir-caprock assemblage can form near the unconformity,which provides a basis for forming large gas field;(3)Regional unconformity may lead to stratigraphic pinch-out and rugged ancient landform,giving rise to a large area of stratigraphic and lithologic trap groups;(4)Regional unconformity provides a dominant channel for lateral migration of oil and gas;and(5)Regional unconformity is conducive to large-scale accumulation of oil and gas.Third,the areas related to regional unconformities are the exploration focus of large gas fields in the Sichuan Basin.The pre-Sinian is found with source rocks,reservoir rocks and other favorable conditions for the formation of large gas fields,and presents a large exploration potential.Thus,it is expected to be an important strategic replacement.展开更多
By using the latest geological,seismic,drilling and logging data,this article studies the basic conditions for the formation of the total petroleum system and the orderly coexisting characteristics and accumulation mo...By using the latest geological,seismic,drilling and logging data,this article studies the basic conditions for the formation of the total petroleum system and the orderly coexisting characteristics and accumulation models of conventional&unconventional reservoirs in the Lower Permian Fengcheng Formation in the Junggar Basin.Controlled by thermal evolution,hydrocarbon generation and expulsion process of the high-quality source rocks in alkaline lake as well as the characteristics of multi-type reservoirs(conglomerate,sandstone,dolomite and shale),conventional structure-lithologic reservoirs and tight oil and shale oil reservoirs controlled by source-reservoir structure have been formed.On the plane,mature conventional reservoirs,medium-high mature tight oil,and medium-high mature shale oil reservoirs coexist orderly from the slope area around Mahu sag to the sag.Based on the orderly coexisting characteristics of conventional and unconventional reservoirs in the Fengcheng Formation,it is clear that oil and gas in the Fengcheng Formation accumulate continuously over a large area in three accumulation models:integrated source-reservoir,source-reservoir in close contact,and separated source-reservoir model.The three accumulation models differ in relationship between source-reservoir structure,reservoir lithology and spatial distribution,hydrocarbon migration,oil and gas type.It is pointed out that the conventional&unconventional oil and gas should be explored and developed as a whole to achieve an overall breakthrough of the total petroleum system.This study is expected to enrich the geological theory of oil and gas enrichment in continental basins and to provide an analogy for exploration and research in other hydrocarbon-rich sags.展开更多
The knowledge of the existence,distribution and fate of polycyclic aromatic hydrocarbons(PAHs)and substituted polycyclic aromatic hydrocarbons(SPAHs)in wastewater treatment plants(WWTPs)was vital for reducing their co...The knowledge of the existence,distribution and fate of polycyclic aromatic hydrocarbons(PAHs)and substituted polycyclic aromatic hydrocarbons(SPAHs)in wastewater treatment plants(WWTPs)was vital for reducing their concentrations entering the aquatic environment.The concentrations of 13 SPAHs and 16 PAHs were all determined in a WWTP with styrene butadiene rubber(SBR)in partnership with the moving bed biofilm reactor(MBBR)process.SPAHs presented a higher concentration lever than PAHs in nearly all samples.The total removal efficiencies of PAHs and SPAHs ranged from 64.0%to 71.36%and 78.4%to 79.7%,respectively.The total yearly loads of PAHs(43.0 kg)and SPAHs(73.0 kg)were mainly reduced by the primary and SBR/MBBR biological treatment stages.The tertiary treatment stage had a minor contribution to target compounds removal.According to a synthesis and improvement fate model,we found that the dominant processes changed as the chemical octanol water partition coefficient(K_(ow))increased.But the seasonal variations of experimental removal efficiencies were more obvious than that of predicted data.In the primary sedimentation tank,dissolution in the aqueous phase and sorption to sludge/particulate matter were controlling processes for the removal of PAHs and SPAHs.The sorption to sludge and biodegradation were the principal removal mechanisms during the SBR/MBBR biological treatment process.The contribution of volatilization to removal was always insignificant.Furthermore,the basic physicochemical properties and operating parameters influenced the fate of PAHs and SPAHs in the WWTP.展开更多
The complexity of diagenesis and hydrocarbon accumulation in the deep reservoirs in southern Junggar Basin restricts hydrocarbon exploration in the lower reservoir assemblage. The lithofacies and diagenesis of reservo...The complexity of diagenesis and hydrocarbon accumulation in the deep reservoirs in southern Junggar Basin restricts hydrocarbon exploration in the lower reservoir assemblage. The lithofacies and diagenesis of reservoirs in the Cretaceous Qingshuihe Formation in the Gaoquan structure of the Sikeshu Sag, southern Junggar Basin were analyzed. On this basis, the thermal history was calibrated using calcite in-situ U-Pb dating and fluid inclusion analysis to depict the hydrocarbon accumulation process in the Gaoquan structure. The results show that the Qingshuihe reservoir experienced two phases of calcite cementation and three phases of hydrocarbon charging. The calcite cements are dated to be (122.1±6.4) Ma, (14.4±1.0) Ma - (14.2±0.3) Ma. The hydrocarbon charging events occurred at around 14.2-30.0 Ma (low-mature oil), 14.2 Ma (mature oil), and 2 Ma (high-mature gas). The latter two phases of hydrocarbon charging contributed dominantly to the formation of reservoir. Due to the S-N compressive thrust activity during the late Himalayan period since 2 Ma, the traps in the Gaoquan structure were reshaped, especially the effective traps which developed in the main reservoir-forming period were decreased significantly in scale, resulting in weak hydrocarbon shows in the middle-lower part of the structure. This indicates that the effective traps in key reservoir-forming period controlled hydrocarbon enrichment and distribution in the lower reservoir assemblage. Calcite U-Pb dating combined with fluid inclusion analysis can help effectively describe the complex diagenesis and hydrocarbon accumulation process in the central-west part of the basin.展开更多
Based on the seismic and drilling data, casting thin sections, geochemical analysis of oil and rock samples, and hydrocarbon generation history simulation, the hydrocarbon accumulation characteristics and exploration ...Based on the seismic and drilling data, casting thin sections, geochemical analysis of oil and rock samples, and hydrocarbon generation history simulation, the hydrocarbon accumulation characteristics and exploration direction of Termit superimposed marine–continental rift basin are discussed. The Termit basin is superimposed with two-phase rifts(Early Cretaceous and Paleogene). The subsidence curves from two wells on the Trakes slope in the east of the basin show high subsidence rate in the Late Cretaceous, which is believed to be high deposition rate influenced by transgression. However, a weak rift may also be developed. The depositional sequences in the Termit basin were controlled by the Late Cretaceous marine transgression cycle and the Paleogene lacustrine transgression cycle, giving rise to two types of superimposed marine–continental “source-sink” deposits. The marine and continental mixed source rocks developed universally in the whole basinduring the marine transgression period, and are overlaid by the Paleogene Sokor 1 reservoir rocks and Sokor 2 caprocks developed during the lacustrine transgression period, forming the unique superimposed marine–continental basin in WCARS. The early low geothermal gradient in the Termit basin resulted in the late hydrocarbon generated by the source rock of Upper Cretaceous Yogou in Paleogene. Mature source rock of Upper Cretaceous Donga developed in the Trakes slope, so that the double-source-supply hydrocarbon and accumulation models are proposed for the Trakes slope in which formed the oil fields. Due to virtue of the newly proposed hydrocarbon accumulation model and the exploration activities in recent years in the Termit superimposed marine–continental rift basin, an additional effective exploration area of about 2500 km2has been confirmed in the east of the basin. It is believed that potential domains such as Sokor 1, Donga and Upper Cretaceous lithologic traps in the southeast of the basin are key expected targets for exploration and frontier evaluation in future.展开更多
The gas-water distribution and production heterogeneity of tight gas reservoirs have been summarized from experimental and geological observations, but the charging and accumulation mechanisms have not been examined q...The gas-water distribution and production heterogeneity of tight gas reservoirs have been summarized from experimental and geological observations, but the charging and accumulation mechanisms have not been examined quantitatively by mathematical model. The tight gas charging and accumulation mechanisms were revealed from a combination of physical simulation of nuclear magnetic resonance coupling displacement, numerical simulation considering material and mechanical equilibria, as well as actual geological observation. The results show that gas migrates into tight rocks to preferentially form a gas saturation stabilization zone near the source-reservoir interface. When the gas source is insufficient, gas saturation reduction zone and uncharged zone are formed in sequence from the source-reservoir interface. The better the source rock conditions with more gas expulsion volume and higher overpressure, the thicker the gas saturation stabilization and reduction zones, and the higher the overall gas saturation. When the source rock conditions are limited, the better the tight reservoir conditions with higher porosity and permeability as well as larger pore throat, the thinner the gas saturation stabilization and reduction zones, but the gas saturation is high. The sweet spot of tight gas is developed in the high-quality reservoir near the source rock, which often corresponds to the gas saturation stabilization zone. The numerical simulation results by mathematical model agree well with the physical simulation results by nuclear magnetic resonance coupling displacement, and reasonably explain the gas-water distribution and production pattern of deep reservoirs in the Xujiaweizi fault depression of the Songliao Basin and tight gas reservoirs in the Linxing-Huangfu area of the Ordos Basin.展开更多
Through the analysis of the faults and their internal structure in Zhu I Depression,it is found that the internal structure of the late fault is obviously segmented vertically.It develops unitary structure(simple faul...Through the analysis of the faults and their internal structure in Zhu I Depression,it is found that the internal structure of the late fault is obviously segmented vertically.It develops unitary structure(simple fault plane)in shallow layers,binary structure(induced fracture zone in hanging wall and sliding fracture zone in footwall)in middle,layers and ternary structure(induced fracture zone in hanging wall and sliding fracture zone in middle,and induced fracture zone in footwall)in deep layers.Because the induced fracture zone is a high porosity and permeability zone,and the sliding fracture zone is a low porosity and ultra-low permeability zone,the late fault in middle layers has the character of"transporting while sealing".The late fault can transport hydrocarbon by its induced fracture zone in the side of the hanging wall and seal hydrocarbon by its sliding fracture zone in the side of the footwall.In deep layers,the late fault has the character of"dual-transportation",induced fracture zones in both sides of hanging wall and footwall can transport hydrocarbon.The early fault that only developed in the deep layers is presumed to be unitary structure,which plays a completely sealing role in the process of hydrocarbon migration and accumulation due to inactivity during the hydrocarbon filling period.Controlled by hydrocarbon source,early/late faults,sand bodies and traps,two reservoir-forming models of"inverted L"and"stereo-spiral"can be proposed in middle layers,while two reservoir-forming models of"cross fault"and"lateral fault sealing"are developed in the deep layers of Zhu I Depression.展开更多
Transfer zones are structural areas of faults interactions where fault motion or displacement can be transferred from one fault to another, regional strain maintains laterally constant. Transfer zones are widely devel...Transfer zones are structural areas of faults interactions where fault motion or displacement can be transferred from one fault to another, regional strain maintains laterally constant. Transfer zones are widely developed in rift basins and have significance on hydrocarbon accumulation. In this review article, we attempt to summarize recent advances on the types, distance-displacement curves, evolutionary stages and controlling factors of transfer zones in rift basins and their effects on sedimentary systems, reservoir properties, trap formation and hydrocarbon migration. The formation of transfer zones is genetically related to the segmented growth of normal faults. Depending on the degree of interaction between these normal faults, transfer zones in rift basins could be divided into two types: soft-linked and hard-linked, which are further subdivided into transfer slope, oblique anticline, horst and transfer fault based on the combination patterns of normal faults. In general, the development of transfer zones experiences several stages including isolated normal faulting, transfer slope forming, complicating and breaking. During the interaction and growth of segmented normal faults, stress-strain and spatial array of faults, pre-existing basement structures, and mechanical conditions of rocks have a great influence on the location and development processes of transfer zones. A transfer zone is commonly considered as a pathway for conveying sediments from provenance to basin, and it hence exerts an essential control on the distribution of sandbodies. In addition, transfer zone is the area where stresses are concentrated, which facilitates the formation of various types of structural traps, and it is also a favorable conduit for hydrocarbon migration. Consequently, there exists great hydrocarbon potentials in transfer zones to which more attention should be given.展开更多
The Xixiangchi Group in eastern Sichuan Basin has great potential for natural gas exploration.However,there is a lack of in-depth studies of the hydrocarbon sources and the formation and evolution of gas reservoirs in...The Xixiangchi Group in eastern Sichuan Basin has great potential for natural gas exploration.However,there is a lack of in-depth studies of the hydrocarbon sources and the formation and evolution of gas reservoirs in this Group.Systematic investigation about the gas reservoir in Pingqiao anticline was consequently carried out in terms of characteristics of reservoir bitumen,the geochemical characteristics of natural gas,diagenetic minerals,and fluid inclusions.Based on this,combined with the reconstruction of the burial history,thermal evolution history and uplifting history of strata,and analysis of the regional tectonic settings,the hydrocarbon sources were identified and the formation and evolutionary processes of the gas reservoirs in Xixiangchi Group was revealed in this study.It was shown that the gas reservoirs have mixed gas sources from the shale source rocks in the Lower Cambrian Qiongzhusi Formation and in the Upper Ordovician Wufeng Formation-Lower Silurian Longmaxi Formation,and experienced several evolutionary stages,including the paleo-oil reservoir stage from the Late Siliurian to the Middle Permian,the paleo-gas reservoir stage from the Late Permian to the Early Cretaceous,and the superimposed accumulation and mixed-source gas reservoir stage since the Late Cretaceous.The mixed-source gas reservoir is formed by the adjustment of the Xixiangchi Group paleo-gas reservoirs and depressurization of the overpressure Wufeng-Longmaxi shale gas reservoirs and the charging of gas into the Xixiangchi Group reservoir of the Pingqiao anticline since the Late Cretaceous,which show obvious superimposed accumulation characteristics.There are different accumulation patterns in different geological periods.The accumulation pattern of the“old source-young reservoir”(i.e.hydrocarbons generated from older source rocks accumulating in younger reservoirs)dominates before the Late Cretaceous,and that of“juxtaposed young source-old reservoir”(i.e.hydrocarbons generated from younger source rocks accumulating in juxtaposed older reservoirs)dominates after the Early Cretaceous.Moreover,faults acted as critical vertical pathways for hydrocarbon migration during the evolution of the Xixiangchi Group gas reservoirs.This model provides new insights and theoretical basis for evaluation and mapping of the Xixiangchi Group play fairway in eastern Sichuan Basin.展开更多
基金supported by the National Science and Technology Major Project of China(2016ZX05033)the Project of SINOPEC Science and Technology Department(P19021-2)the Basic Prospective Research Project of SINOPEC(P22214-2).
文摘Commercial hydrocarbon reservoirs have been discovered in shallow-water areas of the Scotian Basin, Eastern Canada. However, knowledge about the structure and hydrocarbon accumulation characteristics of the basin is still insufficient, which constrains the oil and gas exploration in deep-water areas. Based on comprehensive data of magnetic anomalies, seismic survey, and drilling, this study determines the structure characteristics of the Scotian Basin and its hydrocarbon accumulation conditions in deep waters and evaluates the deep-water hydrocarbon exploration potential. The transform faults and basement structures in the northern basin control the sedimentary framework showing thick strata in east and thin strata in west of the basin. The bowl-shaped depression formed by thermal subsidence during the transitional phase and the confined environment (micro basins) caused by salt tectonics provide favorable conditions for the development of source rocks during the depression stage (also referred to as the depression period sequence) of the basin. The progradation of large shelf-margin deltas during the drift phase and steep continental slope provide favorable conditions for the deposition of slope-floor fans on continental margins of the basin. Moreover, the source-reservoir assemblage comprising the source rocks within the depression stage and the turbidite sandstones on the continental margin in the deep waters may form large deep-water turbidite sandstone reservoirs. This study will provide a valuable reference for the deep-water hydrocarbon exploration in the Scotian Basin.
基金Supported by the PetroChina Major Science and Technology Project (2016E0201,2021ZZ10,2021DJ0101)。
文摘Based on the oil and gas exploration practice in the Songliao Basin,combined with the latest exploration and development data such as seismic,well logging and geochemistry,the basic geological conditions,oil and gas types and distribution characteristics,reservoir-forming dynamics,source-reservoir relationship and hydrocarbon accumulation model of the whole petroleum system in shallow and medium strata in the northern part of Songliao Basin are systematically studied.The shallow-medium strata in northern Songliao Basin have the conditions for the formation of whole petroleum system,with sufficient oil and gas sources,diverse reservoir types and well-developed transport system,forming a whole petroleum system centered on the source rocks of the Cretaceous Qingshankou Formation.Different types of oil and gas resources in the whole petroleum system are correlated with each other in terms of depositional system,lithologic association and physical property changes,and they,to a certain extent,have created the spatial framework with orderly symbiosis of shallow-medium conventional oil reservoirs,tight oil reservoirs and shale oil reservoirs in northern Songliao Basin.Vertically,the resources are endowed as conventional oil above source,shale oil/tight oil within source,and tight oil below source.Horizontally,conventional oil,tight oil,interlayer-type shale oil,and pure shale-type shale oil are developed in an orderly way,from the margin of the basin to the center of the depression.Three hydrocarbon accumulation models are recognized for the whole petroleum system in northern Songliao Basin,namely,buoyancy-driven charging of conventional oil above source,retention of shale oil within source,and pressure differential-driven charging of tight oil below source.
基金Supported by the National Natural Science Foundation of China (41902118)Natural Science Foundation of Xinjiang Uygur Autonomous Region (2022D01B141)+1 种基金Natural Science Foundation of Heilongjiang Province (LH2021D003)Heilongjiang Postdoctoral Fund (No.LBH-Z20045)。
文摘Using the data of drilling, logging, core, experiments and production, the heterogeneity and differential hydrocarbon accumulation model of deep reservoirs in Cretaceous Qingshuihe Formation(K1q) in the western section of the foreland thrust belt in southern Junggar Basin are investigated. The target reservoirs are characterized by superimposition of conglomerates, sandy conglomerates and sandstones, with high content of plastic clasts. The reservoir space is mainly composed of intergranular pores. The reservoirs are overall tight, and the sandy conglomerate has the best physical properties. The coupling of short deep burial period with low paleotemperature gradient and formation overpressure led to the relatively weak diagenetic strength of the reservoirs. Specifically, the sandy conglomerates show relatively low carbonate cementation, low compaction rate and high dissolution porosity. The special stress-strain mechanism of the anticline makes the reservoirs at the top of the anticline turning point more reformed by fractures than those at the limbs, and the formation overpressure makes the fractures in open state. Moreover, the sandy conglomerates have the highest oil saturation. Typical anticline reservoirs are developed in deep part of the thrust belt, but characterized by "big trap with small reservoir". Significantly, the sandy conglomerates at the top of anticline turning point have better quality, lower in-situ stress and higher structural position than those at the limbs,with the internal hydrocarbons most enriched, making them high-yield oil/gas layers. The exponential decline of fractures makes hydrocarbon accumulation difficult in the reservoirs at the limbs. Nonetheless, plane hydrocarbon distribution is more extensive at the gentle limb than the steep limb.
基金Supported by the Special Project of National Key R&D Plan(2017YFC0603106).
文摘The fluid evolution and reservoir formation model of the ultra-deep gas reservoirs in the Permian Qixia Formation of the northwestern Sichuan Basin are investigated by using thin section,cathodoluminescence,inclusion temperature and U-Pb isotopic dating,combined with gas source identification plates and reservoir formation evolution profiles established based on burial history,thermal history,reservoir formation history and diagenetic evolution sequence.The fluid evolution of the marine ultra-deep gas reservoirs in the Qixia Formation has undergone two stages of dolomitization and one phase of hydrothermal action,two stages of oil and gas charging and two stages of associated burial dissolution.The diagenetic fluids include ancient seawater,atmospheric freshwater,deep hydrothermal fluid and hydrocarbon fluids.The two stages of hydrocarbon charging happened in the Late Triassic and Late Jurassic–Early Cretaceous respectively,and the Middle to Late Cretaceous is the period when the crude oil cracked massively into gas.The gas reservoirs in deep marine Permian strata of northwest Sichuan feature multiple source rocks,composite transportation,differential accumulation and late finalization.The natural gas in the Permian is mainly cracked gas from Permian marine mixed hydrocarbon source rocks,with cracked gas from crude oil in the deeper Sinian strata in local parts.The scale development of paleo-hydrocarbon reservoirs and the stable and good preservation conditions are the keys to the forming large-scale gas reservoirs.
基金Supported by the China National Science and Technology Major Project(2011ZX05023-006-002,2016ZX05024-003).
文摘Based on the practice of oil and gas exploration and the analysis of shallow lithologic reservoirs,combined with the allocation relationship and enrichment law of oil and gas accumulation factors,main controlling factors and models of hydrocarbon accumulation of large lithologic reservoirs in shallow strata around the Bozhong sag are summarized,and favorable exploration areas are proposed.The coupling of the four factors of“ridge-fault-sand-zone”is crucial for the hydrocarbon enrichment in the shallow lithologic reservoirs.The convergence intensity of deep convergence ridges is the basis for shallow oil and gas enrichment,the activity intensity of large fault cutting ridges and the thickness of cap rocks control the vertical migration ability of oil and gas,the coupling degree of large sand bodies and fault cutting ridges control large-scale oil and gas filling,the fault sealing ability of structural stress concentration zones affects the enrichment degree of lithologic oil and gas reservoirs.Three enrichment models including uplift convergence type,steep slope sand convergence type and depression uplift convergence type are established through the case study of lithologic reservoirs in shallow strata around the Bozhong sag.
基金This work was supported by the Beijing Nova Program[Z211100002121136]Open Fund Project of State Key Laboratory of Lithospheric Evolution[SKL-K202103]+1 种基金Joint Funds of National Natural Science Foundation of China[U19B6003-02]the National Natural Science Foundation of China[42302149].We would like to thank Prof.Zhu Rixiang from the Institute of Geology and Geophysics,Chinese Academy of Sciences.
文摘With continuous hydrocarbon exploration extending to deeper basins,the deepest industrial oil accumulation was discovered below 8,200 m,revealing a new exploration field.Hence,the extent to which oil exploration can be extended,and the prediction of the depth limit of oil accumulation(DLOA),are issues that have attracted significant attention in petroleum geology.Since it is difficult to characterize the evolution of the physical properties of the marine carbonate reservoir with burial depth,and the deepest drilling still cannot reach the DLOA.Hence,the DLOA cannot be predicted by directly establishing the relationship between the ratio of drilling to the dry layer and the depth.In this study,by establishing the relationships between the porosity and the depth and dry layer ratio of the carbonate reservoir,the relationships between the depth and dry layer ratio were obtained collectively.The depth corresponding to a dry layer ratio of 100%is the DLOA.Based on this,a quantitative prediction model for the DLOA was finally built.The results indicate that the porosity of the carbonate reservoir,Lower Ordovician in Tazhong area of Tarim Basin,tends to decrease with burial depth,and manifests as an overall low porosity reservoir in deep layer.The critical porosity of the DLOA was 1.8%,which is the critical geological condition corresponding to a 100%dry layer ratio encountered in the reservoir.The depth of the DLOA was 9,000 m.This study provides a new method for DLOA prediction that is beneficial for a deeper understanding of oil accumulation,and is of great importance for scientific guidance on deep oil drilling.
基金Supported by the National Natural Science Foundation of China(U22B6002)National Project for Oil and Gas Technology(2016ZX05-004)CNPC Science and Technology Project(2023ZZ02).
文摘The Ediacaran–Ordovician strata within three major marine basins(Tarim,Sichuan,and Ordos)in China are analyzed.Based on previous studies focusing on the characteristics of the Neoproterozoic–Cambrian strata within the three major basins(East Siberian,Oman,and Officer in Australia)overseas,the carbonate–evaporite assemblages in the target interval are divided into three types:intercalated carbonate and gypsum salt,interbedded carbonate and gypsum salt,and coexisted carbonate,gypsum salt and clastic rock.Moreover,the concept and definition of the carbonate-evaporite assemblage are clarified.The results indicate that the oil and gas in the carbonate-evaporite assemblage are originated from two types of source rocks:shale and argillaceous carbonate,and confirmed the capability of gypsum salt in the saline environment to drive the source rock hydrocarbon generation.The dolomite reservoirs are classified in two types:gypseous dolomite flat,and grain shoalµbial mound.This study clarifies that the penecontemporaneous or epigenic leaching of atmospheric fresh water mainly controlled the large-scale development of reservoirs.Afterwards,burial dissolution transformed and reworked the reservoirs.The hydrocarbon accumulation in carbonate-evaporite assemblage can be categorized into eight sub-models under three models(sub-evaporite hydrocarbon accumulation,supra-evaporite hydrocarbon accumulation,and inter-evaporite hydrocarbon accumulation).As a result,the Cambrian strata in the Tazhong Uplift North Slope,Maigaiti Slope and Mazatag Front Uplift Zone of the Tarim Basin,the Cambrian strata in the eastern-southern area of the Sichuan Basin,and the inter-evaporite Ma-4 Member of Ordovician in the Ordos Basin,China,are defined as favorable targets for future exploration.
基金Supported by the PetroChina Science and Technology Project(2023ZZ0703)National Natural Science Foundation of China(42072229,41102131).
文摘Based on the analysis of the fluid inclusion homogenization temperature and apatite fission track on the northern slope zone of the Bongor Basin in Chad,this paper studied the time and stages of hydrocarbon accumulation in the study area.The results show that:(1)The brine inclusions of the samples from the Kubla and Prosopis formations in the Lower Cretaceous coexisting with the hydrocarbon generally present two sets of peak ranges of homogenization temperature,with the peak ranges of low temperature and high temperature being 75–105℃ and 115–135℃,respectively;(2)The samples from the Kubla and Prosopis formations have experienced five tectonic evolution stages,i.e.,rapid subsidence in the Early Cretaceous,tectonic inversion in the Late Cretaceous,small subsidence in the Paleogene,uplift at the turn of the Paleogene and Neogene,and subsidence since the Miocene,in which the denudation thickness of the Late Cretaceous and after the turn of the Paleogene and Neogene are~1.8 km and~0.5 km,respectively.The cumulative denudation thickness of the two periods is about 2.3 km;(3)Using the brine inclusion homogenization temperature coexisting with the hydrocarbon as the capture temperature of the hydrocarbon,and combining with the apatite fission track thermal history modeling,the result shows that the Kubla and Prosopis formations in the Lower Cretaceous on the northern slope of the Bongor Basin have the same hydrocarbon accumulation time and stages,both of which have undergone two stages of hydrocarbon charging at 80–95 Ma and 65–80 Ma.The first stage of charging corresponds to the initial migration of hydrocarbon at the end of the Early Cretaceous rapid sedimentation,while the second stage of charging is in the stage of intense tectonic inversion in the Late Cretaceous.
基金Supported by the PetroChina Oil&Gas and New Energy Company Project(2022KT0405)PetroChina Science and Technology Major Project(2021DJ0605)Basic and Prospective Science and Technology Project of Petrochina Science and Technology Management Department(2021DJ0404).
文摘According to the latest drilling and the analysis of the burial history,source rock evolution history and hydrocarbon accumulation history,the sub-source hydrocarbon accumulation characteristics of the Permian reservoirs in the Jinan Sag,eastern Junggar Basin,are clarified,and the hydrocarbon accumulation model of these reservoirs is established.The results are obtained in four aspects.First,the main body of the thick salified lake basin source rocks in the Lucaogou Formation has reached the mature stage with abundant resource base.Large-scale reservoirs are developed in the Jingjingzigou,Wutonggou and Lucaogou formations.Vertically,there are multiple sets of good regional seals,the source-reservoir-caprock assemblage is good,and there are three reservoir-forming assemblages:sub-source,intra-source and above-source.Second,dissolution,hydrocarbon charging and pore-preserving effect,and presence of chlorite film effectively increase the sub-source pore space.Oil charging is earlier than the time when the reservoir becomes densified,which improves the efficiency of hydrocarbon accumulation.Third,buoyancy and source-reservoir pressure difference together constitute the driving force of oil charging,and the micro-faults within the formation give the advantage of"source-reservoir lateral docking"under the source rock.Microfractures can be critical channels for efficient seepage and continuous charging of oil in different periods.Fourth,the Jingjingzigou Formation experienced three periods of oil accumulation in the Middle-Late Permian,Middle-Late Jurassic and Late Neogene,with the characteristics of long-distance migration and accumulation in early stage,mixed charging and accumulation in middle stage and short-distance migration and high-position accumulation in late stage.The discovery and theoretical understanding of the Permian reservoirs in the Jinan Sag reveal that the thrust belt has good conditions for forming large reservoirs,and it is promising for exploration.The study results are of guidance and reference significance for oil and gas exploration in the Jinan Sag and other geologically similar areas.
基金supported by the National Basic Research Program (2006CB202308)
文摘The geologic conditions of superimposed basins in China are very complicated. This is mainly shown by multi-phase structural evolution,multiple sets of source-reservoir-cap rock combinations,multiple stages of hydrocarbon generation and expulsion from source rocks,multi-cycle hydrocarbon enrichment and accumulation,and multi-phase reservoir adjustment and reconstruction. The enrichment,accumulation and distribution of hydrocarbon is mainly controlled by the source rock kitchen,paleoanticline,regional cap rock and intensity of tectonic movement. In this paper,the T-BCMS model has been developed to predict favorable areas of hydrocarbon accumulation in complicated superimposed basins according to time and spatial relationships among five key factors. The five factors include unconformity surface representing tectonic balancing(B) ,regional cap rock representing hydrocarbon protection(C) ,paleo-anticline representing hydrocarbon migration and accumulation(M) ,source rock kitchen representing hydrocarbon generation and expulsion(S) and geological time(T) . There are three necessary conditions to form favorable areas of hydrocarbon accumulation. First,four key factors BCMS should be strictly in the order of BCMS from top to bottom. Second,superimposition of four key factors BCMS in the same area is the most favorable for hydrocarbon accumulation. Third,vertically ordered combination and superimposition in the same area of BCMS should occur at the same geological time. The model has been used to predict the most favorable exploration areas in Ordovician in the Tarim Basin in the main hydrocarbon accumulation periods. The result shows that 95% of the discovered Ordovician hydrocarbon reservoirs are located in the predicted areas,which indicates the feasibility and reliability of the key factor matching T-BCMS model for hydrocarbon accumulation and enrichment.
基金Supported by the Central Guiding Local Science and Technology Development Special Project(ZY20B13)。
文摘By conducting experimental analyses, including thermal pyrolysis, micro-/nano-CT, argon-ion polishing field emission scanning electron microscopy (FE-SEM), confocal laser scanning microscopy (CLSM), and two-dimensional nuclear magnetic resonance (2D NMR), the Gulong shale oil in the Songliao Basin was investigated with respect to formation model, pore structure and accumulation mechanism. First, in the Gulong shale, there are a large number of pico-algae, nano-algae and dinoflagellates, which were formed in brackish water environment and constituted the hydrogen-rich oil source materials of shale. Second, most of the oil-generating materials of the Qingshankou Formation shale exist in the form of organo-clay complex. During organic matter thermal evolution, clay minerals had double effects of suppression and catalytic hydrogenation, which expanded shale oil window and increased light hydrocarbon yield. Third, the formation of storage space in the Gulong Shale was related to dissolution and hydrocarbon generation. With the diagenesis, micro-/nano-pores increased, pore diameter decreased and more bedding fractures appeared, which jointly gave rise to the unique reservoir with dual media (i.e. nano-scale pores and micro-scale bedding fractures) in the Gulong shale. Fourth, the micro-/nano-scale oil storage unit in the Gulong shale exhibits independent oil/gas occurrence phase, and shows that all-size pores contain oils, which occur in condensate state in micropores or in oil-gas two phase (or liquid) state in macropores/mesopores. The understanding about Gulong shale oil formation and accumulation mechanism has theoretical and practical significance for advancing continental shale oil exploration in China.
基金Supported by the National Natural Science Foundation Project of China(U22B6002)Prospective Basic Technology Research Project of PetroChina(2021DJ0605).
文摘Based on outcrop,seismic and drilling data,the main regional unconformities in the Sichuan Basin and their controls on hydrocarbon accumulation were systematically studied.Three findings are obtained.First,six regional stratigraphic unconformities are mainly developed in the Sichuan Basin,from the bottom up which are between pre-Sinian and Sinian,between Sinian and Cambrian,between pre-Permian and Permian,between middle and upper Permian,between middle and upper Triassic,and between Triassic and Jurassic.Especially,16 of 21l conventional(and tight)gas fields discovered are believed to have formed in relation to regional unconformities.Second,regional unconformity mainly controls hydrocarbon accumulation from five aspects:(1)The porosity and permeability of reservoirs under the unconformity are improved through weathering crust karstification to form large-scale karst reservoirs;(2)Good source-reservoir-caprock assemblage can form near the unconformity,which provides a basis for forming large gas field;(3)Regional unconformity may lead to stratigraphic pinch-out and rugged ancient landform,giving rise to a large area of stratigraphic and lithologic trap groups;(4)Regional unconformity provides a dominant channel for lateral migration of oil and gas;and(5)Regional unconformity is conducive to large-scale accumulation of oil and gas.Third,the areas related to regional unconformities are the exploration focus of large gas fields in the Sichuan Basin.The pre-Sinian is found with source rocks,reservoir rocks and other favorable conditions for the formation of large gas fields,and presents a large exploration potential.Thus,it is expected to be an important strategic replacement.
基金Supported by the China National Science and Technology Major Project(2017ZX05001-004,2016ZX05046-006)Petrochina Science and Technology Major Project(2019E-2601,2019E-2602)。
文摘By using the latest geological,seismic,drilling and logging data,this article studies the basic conditions for the formation of the total petroleum system and the orderly coexisting characteristics and accumulation models of conventional&unconventional reservoirs in the Lower Permian Fengcheng Formation in the Junggar Basin.Controlled by thermal evolution,hydrocarbon generation and expulsion process of the high-quality source rocks in alkaline lake as well as the characteristics of multi-type reservoirs(conglomerate,sandstone,dolomite and shale),conventional structure-lithologic reservoirs and tight oil and shale oil reservoirs controlled by source-reservoir structure have been formed.On the plane,mature conventional reservoirs,medium-high mature tight oil,and medium-high mature shale oil reservoirs coexist orderly from the slope area around Mahu sag to the sag.Based on the orderly coexisting characteristics of conventional and unconventional reservoirs in the Fengcheng Formation,it is clear that oil and gas in the Fengcheng Formation accumulate continuously over a large area in three accumulation models:integrated source-reservoir,source-reservoir in close contact,and separated source-reservoir model.The three accumulation models differ in relationship between source-reservoir structure,reservoir lithology and spatial distribution,hydrocarbon migration,oil and gas type.It is pointed out that the conventional&unconventional oil and gas should be explored and developed as a whole to achieve an overall breakthrough of the total petroleum system.This study is expected to enrich the geological theory of oil and gas enrichment in continental basins and to provide an analogy for exploration and research in other hydrocarbon-rich sags.
基金This work was supported by the National Natural Science Foundation of China(No.51979255).
文摘The knowledge of the existence,distribution and fate of polycyclic aromatic hydrocarbons(PAHs)and substituted polycyclic aromatic hydrocarbons(SPAHs)in wastewater treatment plants(WWTPs)was vital for reducing their concentrations entering the aquatic environment.The concentrations of 13 SPAHs and 16 PAHs were all determined in a WWTP with styrene butadiene rubber(SBR)in partnership with the moving bed biofilm reactor(MBBR)process.SPAHs presented a higher concentration lever than PAHs in nearly all samples.The total removal efficiencies of PAHs and SPAHs ranged from 64.0%to 71.36%and 78.4%to 79.7%,respectively.The total yearly loads of PAHs(43.0 kg)and SPAHs(73.0 kg)were mainly reduced by the primary and SBR/MBBR biological treatment stages.The tertiary treatment stage had a minor contribution to target compounds removal.According to a synthesis and improvement fate model,we found that the dominant processes changed as the chemical octanol water partition coefficient(K_(ow))increased.But the seasonal variations of experimental removal efficiencies were more obvious than that of predicted data.In the primary sedimentation tank,dissolution in the aqueous phase and sorption to sludge/particulate matter were controlling processes for the removal of PAHs and SPAHs.The sorption to sludge and biodegradation were the principal removal mechanisms during the SBR/MBBR biological treatment process.The contribution of volatilization to removal was always insignificant.Furthermore,the basic physicochemical properties and operating parameters influenced the fate of PAHs and SPAHs in the WWTP.
基金Supported by PetroChina Science and Technology Development Project(2023ZZ0206,2021DJ0303,2021DJ0105,2021DJ0203)National Natural ScienceFoundation of China(U22B6002).
文摘The complexity of diagenesis and hydrocarbon accumulation in the deep reservoirs in southern Junggar Basin restricts hydrocarbon exploration in the lower reservoir assemblage. The lithofacies and diagenesis of reservoirs in the Cretaceous Qingshuihe Formation in the Gaoquan structure of the Sikeshu Sag, southern Junggar Basin were analyzed. On this basis, the thermal history was calibrated using calcite in-situ U-Pb dating and fluid inclusion analysis to depict the hydrocarbon accumulation process in the Gaoquan structure. The results show that the Qingshuihe reservoir experienced two phases of calcite cementation and three phases of hydrocarbon charging. The calcite cements are dated to be (122.1±6.4) Ma, (14.4±1.0) Ma - (14.2±0.3) Ma. The hydrocarbon charging events occurred at around 14.2-30.0 Ma (low-mature oil), 14.2 Ma (mature oil), and 2 Ma (high-mature gas). The latter two phases of hydrocarbon charging contributed dominantly to the formation of reservoir. Due to the S-N compressive thrust activity during the late Himalayan period since 2 Ma, the traps in the Gaoquan structure were reshaped, especially the effective traps which developed in the main reservoir-forming period were decreased significantly in scale, resulting in weak hydrocarbon shows in the middle-lower part of the structure. This indicates that the effective traps in key reservoir-forming period controlled hydrocarbon enrichment and distribution in the lower reservoir assemblage. Calcite U-Pb dating combined with fluid inclusion analysis can help effectively describe the complex diagenesis and hydrocarbon accumulation process in the central-west part of the basin.
基金Supported by CNPC Scientific Research and Technology Development Project (2021DJ3103)CNODC Overseas Rresearch and Development Support Project (2023-YF-01-04)。
文摘Based on the seismic and drilling data, casting thin sections, geochemical analysis of oil and rock samples, and hydrocarbon generation history simulation, the hydrocarbon accumulation characteristics and exploration direction of Termit superimposed marine–continental rift basin are discussed. The Termit basin is superimposed with two-phase rifts(Early Cretaceous and Paleogene). The subsidence curves from two wells on the Trakes slope in the east of the basin show high subsidence rate in the Late Cretaceous, which is believed to be high deposition rate influenced by transgression. However, a weak rift may also be developed. The depositional sequences in the Termit basin were controlled by the Late Cretaceous marine transgression cycle and the Paleogene lacustrine transgression cycle, giving rise to two types of superimposed marine–continental “source-sink” deposits. The marine and continental mixed source rocks developed universally in the whole basinduring the marine transgression period, and are overlaid by the Paleogene Sokor 1 reservoir rocks and Sokor 2 caprocks developed during the lacustrine transgression period, forming the unique superimposed marine–continental basin in WCARS. The early low geothermal gradient in the Termit basin resulted in the late hydrocarbon generated by the source rock of Upper Cretaceous Yogou in Paleogene. Mature source rock of Upper Cretaceous Donga developed in the Trakes slope, so that the double-source-supply hydrocarbon and accumulation models are proposed for the Trakes slope in which formed the oil fields. Due to virtue of the newly proposed hydrocarbon accumulation model and the exploration activities in recent years in the Termit superimposed marine–continental rift basin, an additional effective exploration area of about 2500 km2has been confirmed in the east of the basin. It is believed that potential domains such as Sokor 1, Donga and Upper Cretaceous lithologic traps in the southeast of the basin are key expected targets for exploration and frontier evaluation in future.
基金Supported by the National Natural Science Foundation of China(42302183,42272156,41922015)Sanya City Science and Technology Innovation Project(2022KJCX51).
文摘The gas-water distribution and production heterogeneity of tight gas reservoirs have been summarized from experimental and geological observations, but the charging and accumulation mechanisms have not been examined quantitatively by mathematical model. The tight gas charging and accumulation mechanisms were revealed from a combination of physical simulation of nuclear magnetic resonance coupling displacement, numerical simulation considering material and mechanical equilibria, as well as actual geological observation. The results show that gas migrates into tight rocks to preferentially form a gas saturation stabilization zone near the source-reservoir interface. When the gas source is insufficient, gas saturation reduction zone and uncharged zone are formed in sequence from the source-reservoir interface. The better the source rock conditions with more gas expulsion volume and higher overpressure, the thicker the gas saturation stabilization and reduction zones, and the higher the overall gas saturation. When the source rock conditions are limited, the better the tight reservoir conditions with higher porosity and permeability as well as larger pore throat, the thinner the gas saturation stabilization and reduction zones, but the gas saturation is high. The sweet spot of tight gas is developed in the high-quality reservoir near the source rock, which often corresponds to the gas saturation stabilization zone. The numerical simulation results by mathematical model agree well with the physical simulation results by nuclear magnetic resonance coupling displacement, and reasonably explain the gas-water distribution and production pattern of deep reservoirs in the Xujiaweizi fault depression of the Songliao Basin and tight gas reservoirs in the Linxing-Huangfu area of the Ordos Basin.
基金The National Science and Technology Major Project of the Ministry of Science and Technology of China under contract No.2016ZX05024-002
文摘Through the analysis of the faults and their internal structure in Zhu I Depression,it is found that the internal structure of the late fault is obviously segmented vertically.It develops unitary structure(simple fault plane)in shallow layers,binary structure(induced fracture zone in hanging wall and sliding fracture zone in footwall)in middle,layers and ternary structure(induced fracture zone in hanging wall and sliding fracture zone in middle,and induced fracture zone in footwall)in deep layers.Because the induced fracture zone is a high porosity and permeability zone,and the sliding fracture zone is a low porosity and ultra-low permeability zone,the late fault in middle layers has the character of"transporting while sealing".The late fault can transport hydrocarbon by its induced fracture zone in the side of the hanging wall and seal hydrocarbon by its sliding fracture zone in the side of the footwall.In deep layers,the late fault has the character of"dual-transportation",induced fracture zones in both sides of hanging wall and footwall can transport hydrocarbon.The early fault that only developed in the deep layers is presumed to be unitary structure,which plays a completely sealing role in the process of hydrocarbon migration and accumulation due to inactivity during the hydrocarbon filling period.Controlled by hydrocarbon source,early/late faults,sand bodies and traps,two reservoir-forming models of"inverted L"and"stereo-spiral"can be proposed in middle layers,while two reservoir-forming models of"cross fault"and"lateral fault sealing"are developed in the deep layers of Zhu I Depression.
基金funded by the National Natural Science Foundation of China(No.42072149).
文摘Transfer zones are structural areas of faults interactions where fault motion or displacement can be transferred from one fault to another, regional strain maintains laterally constant. Transfer zones are widely developed in rift basins and have significance on hydrocarbon accumulation. In this review article, we attempt to summarize recent advances on the types, distance-displacement curves, evolutionary stages and controlling factors of transfer zones in rift basins and their effects on sedimentary systems, reservoir properties, trap formation and hydrocarbon migration. The formation of transfer zones is genetically related to the segmented growth of normal faults. Depending on the degree of interaction between these normal faults, transfer zones in rift basins could be divided into two types: soft-linked and hard-linked, which are further subdivided into transfer slope, oblique anticline, horst and transfer fault based on the combination patterns of normal faults. In general, the development of transfer zones experiences several stages including isolated normal faulting, transfer slope forming, complicating and breaking. During the interaction and growth of segmented normal faults, stress-strain and spatial array of faults, pre-existing basement structures, and mechanical conditions of rocks have a great influence on the location and development processes of transfer zones. A transfer zone is commonly considered as a pathway for conveying sediments from provenance to basin, and it hence exerts an essential control on the distribution of sandbodies. In addition, transfer zone is the area where stresses are concentrated, which facilitates the formation of various types of structural traps, and it is also a favorable conduit for hydrocarbon migration. Consequently, there exists great hydrocarbon potentials in transfer zones to which more attention should be given.
基金supported by the National Key R&D Program of China grant(2017YFC0603105).
文摘The Xixiangchi Group in eastern Sichuan Basin has great potential for natural gas exploration.However,there is a lack of in-depth studies of the hydrocarbon sources and the formation and evolution of gas reservoirs in this Group.Systematic investigation about the gas reservoir in Pingqiao anticline was consequently carried out in terms of characteristics of reservoir bitumen,the geochemical characteristics of natural gas,diagenetic minerals,and fluid inclusions.Based on this,combined with the reconstruction of the burial history,thermal evolution history and uplifting history of strata,and analysis of the regional tectonic settings,the hydrocarbon sources were identified and the formation and evolutionary processes of the gas reservoirs in Xixiangchi Group was revealed in this study.It was shown that the gas reservoirs have mixed gas sources from the shale source rocks in the Lower Cambrian Qiongzhusi Formation and in the Upper Ordovician Wufeng Formation-Lower Silurian Longmaxi Formation,and experienced several evolutionary stages,including the paleo-oil reservoir stage from the Late Siliurian to the Middle Permian,the paleo-gas reservoir stage from the Late Permian to the Early Cretaceous,and the superimposed accumulation and mixed-source gas reservoir stage since the Late Cretaceous.The mixed-source gas reservoir is formed by the adjustment of the Xixiangchi Group paleo-gas reservoirs and depressurization of the overpressure Wufeng-Longmaxi shale gas reservoirs and the charging of gas into the Xixiangchi Group reservoir of the Pingqiao anticline since the Late Cretaceous,which show obvious superimposed accumulation characteristics.There are different accumulation patterns in different geological periods.The accumulation pattern of the“old source-young reservoir”(i.e.hydrocarbons generated from older source rocks accumulating in younger reservoirs)dominates before the Late Cretaceous,and that of“juxtaposed young source-old reservoir”(i.e.hydrocarbons generated from younger source rocks accumulating in juxtaposed older reservoirs)dominates after the Early Cretaceous.Moreover,faults acted as critical vertical pathways for hydrocarbon migration during the evolution of the Xixiangchi Group gas reservoirs.This model provides new insights and theoretical basis for evaluation and mapping of the Xixiangchi Group play fairway in eastern Sichuan Basin.
