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Seismic response of a mid-story isolated structure considering SSI in mountainous areas under long-period earthquakes 被引量:1
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作者 Wan Feng Qin Shengwu +7 位作者 Liu Dewen Zhao Tiange Zheng Yanping Shan Hang Li Zhiang Peng Fusong Xu Jingran Lei Min 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2024年第1期151-161,共11页
At present,there is not much research on mid-story isolated structures in mountainous areas.In this study,a model of a mid-story isolated structure considering soil-structure interaction(SSI)in mountainous areas is es... At present,there is not much research on mid-story isolated structures in mountainous areas.In this study,a model of a mid-story isolated structure considering soil-structure interaction(SSI)in mountainous areas is established along with a model that does not consider SSI.Eight long-period earthquake waves and two ordinary earthquake waves are selected as inputs for the dynamic time history analysis of the structure.The results show that the seismic response of a mid-story isolated structure considering SSI in mountainous areas can be amplified when compared with a structure that does not consider SSI.The structure response under long-period earthquakes is larger than that of ordinary earthquakes.The structure response under far-field harmonic-like earthquakes is larger than that of near-fault pulse-type earthquakes.The structure response under near-fault pulse-type earthquakes is larger than that of far-field non-harmonic earthquakes.When subjected to long-period earthquakes,the displacement of the isolated bearings exceeded the limit value,which led to instability and overturning of the structure.The structure with dampers in the isolated story could adequately control the nonlinear response of the structure,effectively reduce the displacement of the isolated bearings,and provide a convenient,efficient and economic method not only for new construction but also to retrofit existing structures. 展开更多
关键词 SSI in mountainous areas long-period earthquakes mid-story isolated structure structural dynamic analysis
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Study on the Influence of Aspect Ratio on the Seismic Response and Overturning Resistance of a New Staggered Story Isolated Structure
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作者 Tiange Zhao Dewen Liu 《World Journal of Engineering and Technology》 2024年第3期617-634,共18页
The aspect ratio of the structure has a significant impact on the overall stability of the ultra high-rise building. A large aspect ratio of the structure increases the risk of overturning and reduces the lateral stif... The aspect ratio of the structure has a significant impact on the overall stability of the ultra high-rise building. A large aspect ratio of the structure increases the risk of overturning and reduces the lateral stiffness of the structure, leading to significant tensile and compressive stresses in the isolated bearings. To study the effect of aspect ratio on the seismic response and overturning resistance of a new staggered story isolated structure, three models with different aspect ratios were established. Nonlinear time-history analysis of the three models was conducted using ETABS finite element software. The results indicate that the overturning moment and overturning resistance moment of the superstructure in the new staggered story isolated structure increase with an increasing aspect ratio. However, the increase in the overturning moment of the superstructure is much greater than the increase in the overturning resistance moment, resulting in a decrease in the overturning resistance ratio of the superstructure with an increasing aspect ratio. The overturning moment and overturning resistance moment of the substructure in the new staggered story isolated structure decrease with an increasing aspect ratio. However, the decrease in the overturning moment of the substructure is greater than the decrease in the overturning resistance moment, leading to an increase in the overturning resistance ratio of the substructure with an increasing aspect ratio. The decrease in the overturning resistance ratio of the superstructure in the new staggered story isolated structure is much greater than the increase in the overturning resistance ratio of the substructure. Therefore, as the aspect ratio of the overall structure increases, the overturning resistance ratio of the superstructure and the entire structure decreases. 展开更多
关键词 Aspect Ratio A New Staggered Story isolated structure Seismic Response Overturning Resistance Ratio isolated Bearing
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Optimal design and effectiveness evaluation for inerter-based devices on mitigating seismic responses of base isolated structures 被引量:3
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作者 Li Yafeng Li Shouying Chen Zhengqing 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2021年第4期1021-1032,共12页
The optimal design and effectiveness of three control systems,tuned viscous mass damper(TVMD),tuned inerter damper(TID)and tuned mass damper(TMD),on mitigating the seismic responses of base isolated structures,were sy... The optimal design and effectiveness of three control systems,tuned viscous mass damper(TVMD),tuned inerter damper(TID)and tuned mass damper(TMD),on mitigating the seismic responses of base isolated structures,were systematically studied.First,the seismic responses of the base isolated structure with each control system under white noise excitation were obtained.Then,the structural parameter optimizations of the TVMD,TID and TMD were conducted by using three different objectives.The results show that the three control systems were all effective in minimizing the root mean square value of seismic responses,including the base shear of the BIS,the absolute acceleration of structural SDOF,and the relative displacement between the base isolation floor and the foundation.Finally,considering the superstructure as a structural MDOF,a series of time history analyses were performed to investigate the effectiveness and activation sensitivity of the three control systems under far field and near fault seismic excitations.The results show that the effectiveness of TID and TMD with optimized parameters on mitigating the seismic responses of base isolated structures increased as the mass ratio increases,and the effectiveness of TID was always better than TMD with the same mass ratio.The TVMD with a lower mass ratio was more efficient in reducing the seismic response than the TID and TMD.Furthermore,the TVMD,when compared with TMD and TID,had better activation sensitivity and a smaller stroke. 展开更多
关键词 base isolated structure inerter optimal design seismic response vibration control
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Shaking Table Model Test of Isolated Structure on Soft Site and Analysis on Its Isolation Efficiency 被引量:3
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作者 Yu Xu Zhuang Haiyang Zhu Chao 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2017年第2期169-176,共8页
Adopting a soft site model built on soft interlayer soil foundation,a shaking table test for soft interlayer soil-isolated structure interaction is conducted to investigate the seismic response of isolated structure o... Adopting a soft site model built on soft interlayer soil foundation,a shaking table test for soft interlayer soil-isolated structure interaction is conducted to investigate the seismic response of isolated structure on soft site,and analyze its isolation effect.Test results show that the test can reflect the earthquake response characteristics of isolated structure on soft site.It is on soft site that the dynamic characteristics of isolated structure,acceleration magnification factor(AMF)of isolated structure and isolation efficiency of the isolation layer differ from those on rigid foundation with an soil-structure interaction(SSI)effect,represented by the reduction in fundamental vibration frequency of isolated structure and the increase of damping ratio with changes of the SSI effect.SSI can either increase or decrease AMF of isolated structure on soft site,depending on the characteristics of earthquake motion input.Furthermore,the isolation efficiency of isolation layer on soft site is decreased with the SSI effect,which is related to the peak ground acceleration(PGA)and the characteristics of earthquake motion input. 展开更多
关键词 isolated structure shaking table model test soil-structure interaction(SSI) seismic response isolation efficiency
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Dynamic Interaction of Soil-Isolated Structure:A Systematic Review 被引量:3
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作者 YU Xu WU Xiaofei +1 位作者 ZHU Mingxuan ZHUANG Haiyang 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2020年第1期40-53,共14页
Isolation technique of ground structure is a hot topic in the field of earthquake engineering and structure dynamics.Since soil-isolated structure dynamic interaction study is of great significance to enhance seismic ... Isolation technique of ground structure is a hot topic in the field of earthquake engineering and structure dynamics.Since soil-isolated structure dynamic interaction study is of great significance to enhance seismic performance of isolated structures and revision of relevant isolation specifications,research on dynamic interaction of soil-isolated structure has attracted more and more attention.Based on the basic theory of soil-structure dynamic interaction,we summarize and analyze the research status quo of soil-isolated structure dynamic interaction by means of theoretical analysis,numerical simulation,model test,prototype observation and seismic performance.After reviewing the results of previous research,we reveal that some key issues,which can be used to uncover dynamic interaction mechanism and seismic response characteristics of soil-isolated structures interaction system,should not be neglected.Based on the concept of seismic performance design and the latest research of soil-isolated structure dynamic interaction,we predict the future development of soil-isolated structure dynamic interaction by elastoplastic time history analysis method,seismic performance level and practical analysis method based on energy. 展开更多
关键词 isolated structure earthquake resistance soil-structure interaction
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The height-width ratio limited value for rubber bearing isolated structure computed by uniform design method 被引量:7
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作者 王铁英 王焕定 +1 位作者 张永山 刘文光 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2007年第1期36-40,共5页
Rubber isolation is the most mature control technology in practical application, and is widely used by short rigid buildings. However, many high isolation buildings have been built around the world in recent years, wh... Rubber isolation is the most mature control technology in practical application, and is widely used by short rigid buildings. However, many high isolation buildings have been built around the world in recent years, which do not follow the existing criterions and codes. Many researchers began to research the special problems caused by larger height-width ratio isolation structures. The overturning effect of high height-width ratio structures with rubber bearing is firstly studied. Considering the main factors, such as the height-width ratio of structures, type of site, the designed basic acceleration of ground motion and the decouple factor in horizon, computing experiment is defined with the Uniform Design Method, which is also known as designing isolation structure. The forces of the bearing under edge of structures based on the position of the rubber bearing are calculated. The result indicates that the rubber bearings will lose its functionality under very high tension and compressing force of earthquake motion in horizon and vertical, when the height-width ratio is over a certain value. Thus, based on the calculation result of isolation structures defined in the uniform design method, regression analysis is conducted, and also the rubber edge force regression formula are gotten, which has higher correlation and smaller standard deviation. This formula can be used to roughly calculate whether the pull force occurs at the edge of the building. By the edge bearings of isolation structure minimum force formula, the height-width ratio limited value of the isolation structure is deducted when rubber bearing has minimum force of zero. 展开更多
关键词 isolation structures the uniform design method regression analysis height-width ratio limited value
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Seismic Response Analysis of Steel Structure Isolation System Under Long-Period Seismic Motion
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作者 Long Yu Mei Sheng +1 位作者 Huan Feng Jianan Hu 《Journal of Architectural Research and Development》 2024年第3期147-155,共9页
To analyze the seismic response of steel structure isolation systems under long-period seismic motion,a 9-story steel frame building was selected as the subject.Five steel structure finite element models were establis... To analyze the seismic response of steel structure isolation systems under long-period seismic motion,a 9-story steel frame building was selected as the subject.Five steel structure finite element models were established using SAP2000.Response spectrum analysis was conducted on the seismic motion to determine if it adhered to the characteristics of long-period seismic motion.Modal analysis of each structural model revealed that the isolation structure significantly prolonged the structural natural vibration period and enhanced seismic performance.Base reactions and floor displacements of various structures notably increased under long-period seismic motion compared to regular seismic activity.Placing isolation bearings in the lower part of the structure proved more effective under long-period seismic motion.In seismic design engineering,it is essential to consider the impact of long-period seismic motion on structures and the potential failure of isolation bearings. 展开更多
关键词 Long-period seismic motion Steel structure Mid-story isolation structure Isolation bearing Seismic performance
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Isolated structures in two-dimensional optical superlattice 被引量:1
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作者 Xin-Hao Zou Bao-Guo Yang +2 位作者 Xia Xu Peng-Ju Tang Xiao-Ji Zhou 《Frontiers of physics》 SCIE CSCD 2017年第5期135-141,共7页
Overlaying commensurate optical lattices with various configurations called superlattices can lead to exotic lattice topologies and, in turn, a discovery of novel physics. In this study, by overlapping the maxima of l... Overlaying commensurate optical lattices with various configurations called superlattices can lead to exotic lattice topologies and, in turn, a discovery of novel physics. In this study, by overlapping the maxima of lattices, a new isolated structure is created, while the interference of minima can generate various "sublattice" patterns. Three different kinds of primitive lattices are used to demonstrate isolated square, triangular, and hexagonal "sublattice" structures in a two-dimensional optical superlattice, the patterns of which can be manipulated dynamically by tuning the polarization, frequency, and intensity of laser beams. In addition, we propose the method of altering the relative phase to adjust the tunneling amplitudes in "sublattices'. Our configurations provide unique opportunities to study particle entanglement in "lattices" formed by intersecting wells and to implement special quantum logic gates in exotic lattice geometries. 展开更多
关键词 optical superlattice isolated structures exotic lattice geometries quantum logic gates
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Application of an efficient stochastic calculation method on the seismic analysis of an isolated structure
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作者 Wei GUO Zhiwu YU 《Frontiers of Structural and Civil Engineering》 SCIE EI 2012年第4期379-384,共6页
An isolated structure often possesses distinct non-proportional damping characteristics.However,traditional seismic calculation theory and methods are derived based on the assumption that damping is proportional.Based... An isolated structure often possesses distinct non-proportional damping characteristics.However,traditional seismic calculation theory and methods are derived based on the assumption that damping is proportional.Based on this drawback,a new,more efficient stochastic calculation method,an improvement on the pseudo-excitation method,is introduced.This method is then applied to the seismic analysis of an isolated structure.By comparing it with the forced decoupling,matrix inversion and iteration methods,it is shown that the presented method can produce accurate results while increasing the efficiency of the stochastic analysis.Moreover,the calculation process of the seismic response of an isolated structure is convergent.Based on the results of the example presented in this paper,the given method is applicable to the seismic analysis of an isolated structure and can be utilized in practice. 展开更多
关键词 isolated structure stochastic response non-proportional damping EFFICIENT ACCURATE pseudo-excitation method
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Dynamic Analysis for Structures Isolated with Dampers 被引量:1
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作者 Gu Peiying and Gao Ming M. Sc, Engineer, Material and Structure Department, Nanjing Hydraulic Research Institute, Nanjing 210024 Professor, Material and Structure Department, Nanjing Hydraulic Research Institute, Nanjing 210024 《China Ocean Engineering》 SCIE EI 1996年第3期269-280,共12页
In this paper, mathematical models and dynamic analyses for both SDOF and MDOF structures isolated with dampers are established and performed, and a comprehensive computation method is provided. The shock absorbing ef... In this paper, mathematical models and dynamic analyses for both SDOF and MDOF structures isolated with dampers are established and performed, and a comprehensive computation method is provided. The shock absorbing effect is illustrated through an example of a two DOF damper-isolated system excited by sinusoidal waves and actual ground acceleration input recorded in earthquakes. It is shown that most of the responses of the structure with dampers reduce greatly near the resonant zone, but acceleration is enlarged in the lower or higher frequency zone; among various parameters, the influence of frictional coefficient n is the most significant, that of damping ratio of the dampers , is the second, and that of stiffness coefficient of the dampers k, is the slightest. 展开更多
关键词 shock absorbing structure isolated with dampers shock absorbing effect dynamic analysis parametric analysis
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A bio-inspired spider-like structure isolator for low-frequency vibration 被引量:2
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作者 Guangdong SUI Shuai HOU +5 位作者 Xiaofan ZHANG Xiaobiao SHAN Chengwei HOU Henan SONG Weijie HOU Jianming LI 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2023年第8期1263-1286,共24页
This paper proposes a quasi-zero stiffness(QZS)isolator composed of a curved beam(as spider foot)and a linear spring(as spider muscle)inspired by the precise capturing ability of spiders in vibrating environments.The ... This paper proposes a quasi-zero stiffness(QZS)isolator composed of a curved beam(as spider foot)and a linear spring(as spider muscle)inspired by the precise capturing ability of spiders in vibrating environments.The curved beam is simplified as an inclined horizontal spring,and a static analysis is carried out to explore the effects of different structural parameters on the stiffness performance of the QZS isolator.The finite element simulation analysis verifies that the QZS isolator can significantly reduce the first-order natural frequency under the load in the QZS region.The harmonic balance method(HBM)is used to explore the effects of the excitation amplitude,damping ratio,and stiffness coefficient on the system’s amplitude-frequency response and transmissibility performance,and the accuracy of the analytical results is verified by the fourth-order Runge-Kutta integral method(RK-4).The experimental data of the QZS isolator prototype are fitted to a ninth-degree polynomial,and the RK-4 can theoretically predict the experimental results.The experimental results show that the QZS isolator has a lower initial isolation frequency and a wider isolation frequency bandwidth than the equivalent linear isolator.The frequency sweep test of prototypes with different harmonic excitation amplitudes shows that the initial isolation frequency of the QZS isolator is 3 Hz,and it can isolate 90%of the excitation signal at 7 Hz.The proposed biomimetic spider-like QZS isolator has high application prospects and can provide a reference for optimizing low-frequency or ultra-low-frequency isolators. 展开更多
关键词 bionic isolation structure curved beam nonlinear stiffness quasi-zero stiffness(QzS) low-frequency vibration isolator
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STRUCTURE OF NERVOSIN D ISOLATED FROM ISODOM NERVOSUS
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作者 Mei Juan XU Xin En HUANG Pei Yuan CHENG Jin XIANG Mai TANG a Nanjing Institute of Materia Medica,Nanjing 210009 b Jiangsu Institute of Cancer Research,Nanjing 210009 c Sanitary School of Fujian Province,Fujian 350000 《Chinese Chemical Letters》 SCIE CAS CSCD 1993年第9期783-784,共2页
On the basis of spectral analysis combined with preparation of derivatives,nervosin D was identified as ent-12,6β,7β,112,15β-pentahydro- xy-72,20-epoxykaur-16-ene.
关键词 PPM structure OF NERVOSIN D isolated FROM ISODOM NERVOSUS
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High-Throughput Growth of Hexagonal Boron Nitride Film Using Porous-Structure Isolation Layer
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作者 Ruitao Jia Fangzhu Qing Xuesong Li 《Journal of Materials Science and Chemical Engineering》 CAS 2023年第3期45-51,共7页
Chemical vapor deposition is considered as the most hopeful method for the synthesis of large-area high-quality hexagonal boron nitride on the substrate of catalytic metal. However, the size the hexagonal boron nitrid... Chemical vapor deposition is considered as the most hopeful method for the synthesis of large-area high-quality hexagonal boron nitride on the substrate of catalytic metal. However, the size the hexagonal boron nitride films are limited to the size of growth chamber, which indicates a lower production efficiency. In this paper, the utilization efficiency of growth chamber is highly improved by alternately stacking multiple pieces of Cu foils and carbon fiber surface felt with porous structure. Uniform and continuous hexagonal boron nitride films are prepared on Cu foils through chemical vapor deposition utilizing ammonia borane as the precursor. This work develops a simple and practicable method for high-throughput preparation of hexagonal boron nitride films, which could contribute to the industrial application of hexagonal boron nitride. . 展开更多
关键词 Hexagonal Boron Nitride Chemical Vapor Deposition Porous structure Isolation Layer High Throughput
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A Novel Radiation Tolerant SOI Isolation Structure
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作者 赵洪辰 海潮和 +2 位作者 韩郑生 钱鹤 司红 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2005年第7期1291-1294,共4页
A novel radiation tolerant SOI isolation structure,consisting of thin SiO2/polysilicon/field SiO2 multilayers,is proposed. A device with this structure does not show obvious changes in subthreshold characteristics and... A novel radiation tolerant SOI isolation structure,consisting of thin SiO2/polysilicon/field SiO2 multilayers,is proposed. A device with this structure does not show obvious changes in subthreshold characteristics and leakage current,indicating a superior radiation tolerance to traditional LOCOS. 展开更多
关键词 isolation structure radiation tolerance SOI
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A new isolation device using shape memory alloy and its application for long-span structures 被引量:3
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作者 Ding Youliang Chen Xin +1 位作者 Li Aiqun Zuo Xiaobao 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2011年第2期239-252,共14页
The key points to consider in determining the effectiveness of using structural isolation with shape memory alloys (SMA) are the constitutive model, the SMA isolation device and the analysis method. In this paper, a... The key points to consider in determining the effectiveness of using structural isolation with shape memory alloys (SMA) are the constitutive model, the SMA isolation device and the analysis method. In this paper, a simplified constitutive model based on the classic theory of plasticity is proposed to simulate the behavior of the superelasticity of the SMA, in which the martensite volume fraction is considered as one of the state variables. Comparisons between simulation results and experimental results are made and indicate that the proposed constitutive model yields stress-strain curves that are in good agreement with the experimental ones. Thus, the proposed model can correctly simulate the yield mechanism and energy dissipation capacity of the SMA. Next, in order to make full use of the superelasticity of SMA, a new SMA isolator composed of pre-tensioned SMA bars is presented. Then, a finite element analytical model is established to simulate the behavior of the SMA isolator according to its configuration and simplified constitutive model. Finally, a simplified design method for long-span structures installed with SMA isolators is proposed, which is further used to investigate the isolation effects of a space grid structure. Results show that the SMA isolator can reduce the seismic responses of the structure effectively, which indicates the effectiveness of the proposed SMA isolation method. 展开更多
关键词 shape memory alloy super-elasticity constitutive model seismic response structural isolation space gridstructure
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ISOLATION AND STRUCTURE ELUCIDATION OF A NOVEL STEROL FROM THE SOUTH CHINA SEA SPONGE DYSIDEA SP. 被引量:3
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作者 Yong Li ZHONG Jing Yu SU Long Mei ZENG Department of Chemistry,Zhongshan University,Guangzhou,510275 Wei SHEN Qi Wen WANG State Key Laboratory of Bioorganic and Natural Products Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Science,Shanghai,200032 《Chinese Chemical Letters》 SCIE CAS CSCD 1992年第12期981-982,共2页
A novel and unusual sterol with unsaturation in the△^(5(14)) position,5α-cholesta-8(14),24(25)-diene-3β,6α-diol 1,was isolated from the South China Ses sponge Dysidea sp.The structure and relative stereochemistry ... A novel and unusual sterol with unsaturation in the△^(5(14)) position,5α-cholesta-8(14),24(25)-diene-3β,6α-diol 1,was isolated from the South China Ses sponge Dysidea sp.The structure and relative stereochemistry of 1 was established by spectral analysis and comparison to the spectral data of known sterols. 展开更多
关键词 ISOLATION AND structure ELUCIDATION OF A NOVEL STEROL FROM THE SOUTH CHINA SEA SPONGE DYSIDEA SP 二七 SEA
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ISOLATION AND STRUCTURES OF FOUR CYCLODIPEPTIDES 被引量:2
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作者 Jing Yu SU Yong Li ZHONG +2 位作者 Long Mei ZENG Wei SHEN Qi Wen WANG 《Chinese Chemical Letters》 SCIE CAS CSCD 1993年第2期139-140,共2页
Three novel interesting polychlorinated cyclodipeptides,designated dyssmide A(1),B(2),C(3)and a known compound,2,3-dihydrodyeamide C(4)were isolated from the sponge Dysidea sp.Their structures were elucidated by spect... Three novel interesting polychlorinated cyclodipeptides,designated dyssmide A(1),B(2),C(3)and a known compound,2,3-dihydrodyeamide C(4)were isolated from the sponge Dysidea sp.Their structures were elucidated by spectroscopic methods. 展开更多
关键词 CCI IR ISOLATION AND structureS OF FOUR CYCLODIPEPTIDES
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Seismic Response Analysis of Structure with Cooperation of Laminated Rubber Bearing and Wind-Resistant Support 被引量:2
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作者 吴应雄 王兆樑 +1 位作者 林树枝 林婷婷 《Journal of Donghua University(English Edition)》 EI CAS 2014年第4期411-417,共7页
The purpose is to study the seismic reduction effect of an isolated structure,with wind-resistant bearings( WRBs) setting on its isolation layer to withstand great wind load,and the working mechanism of the WRB. In th... The purpose is to study the seismic reduction effect of an isolated structure,with wind-resistant bearings( WRBs) setting on its isolation layer to withstand great wind load,and the working mechanism of the WRB. In this paper,two isolation models with /without WRBs,taking an actual engineering as the background,are established in the finite element software ETABS. The one with WRBs has horizontal damping coefficient less than 0. 40 while the other between 0. 40 and 0. 53. WRBs are simulated by Plastic 1element and the collaborative work between them and isolation layer is described by a mechanical model. Time history analysis is conducted on the models to compare their responses under earthquake excitations. Results show that the one with WRBs,but less lead-rubber bearings( LRBs),has better damping effect than the other,although they both can meet wind requirements. It is also shown that under normal conditions and small earthquakes,WRBs function well and the isolation layer will not yield; under moderate earthquakes,WRBs will yield and be destroyed to stop functioning but without affecting the damping effect of the upper structure.Additionally, the total yield shear force provided by LRBs is proposed to be close to the standard value of wind load. 展开更多
关键词 isolation structure wind-resistant bearings(WRBs) cooperation working seismic response
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K2SbB3O8: A Novel Boroantimonate)with Isolated [B3O8]^7- Groups 被引量:3
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作者 沈耀国 赵三根 罗军华 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2016年第8期1269-1276,共8页
A new boroantimonate K2SbB3O8 has been synthesized by high-temperature solidstate reactions, and its crystals have been obtained by the flux method. The crystal structure has been determined from single-crystal X-ray ... A new boroantimonate K2SbB3O8 has been synthesized by high-temperature solidstate reactions, and its crystals have been obtained by the flux method. The crystal structure has been determined from single-crystal X-ray diffraction analysis. The compound crystallizes in the monoclinic space group P21/c with a = 5.8890(2), b = 11.0512(4), c = 10.8951(4)A, β =103.200(4)°, V = 690.32(4) A^3, Z = 4, F(000) = 672, ρc = 3.467 g/cm^3, Mr = 360.38 and μ = 5.215mm^-1. Its structure feature is a three-dimensional framework composed of SbO6 octahedra and isolated [B3O8]^7- groups with K+ cations residing in the one-dimensional tunnels along the a-axis.Interestingly, the isolated [B3O8]^7- groups are distinct from the known [B3O8]^7- groups, which always connect to each other. The UV-vis-NIR absorption, thermal stability and infrared spectrum are also discussed in this paper. 展开更多
关键词 borate crystal structure isolated group infrared spectrum
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ISOLATION AND STRUCTURE DETERMINATION OF XF-1,A NEW ANTHRACYCLINE ANTIBIOTIC
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作者 Xu Guang YAN Jian Bo WU a.Institute of Medicinal Biotechnology,Chinese Academy of Medical Sciences,Beijing 100050Shao Zhao WANG b.Institute of Microbiology,Fuzhou 350007 《Chinese Chemical Letters》 SCIE CAS CSCD 1993年第9期787-790,共4页
A new Mutactimycin group antibiotic(XF-1)was isolated from the mycelium of Streptomyces sp.80-115 and its structure has been determined on the basis of its spectroscopical and chemical properties. XF-1 showed active a... A new Mutactimycin group antibiotic(XF-1)was isolated from the mycelium of Streptomyces sp.80-115 and its structure has been determined on the basis of its spectroscopical and chemical properties. XF-1 showed active against some Gram positive bacteria. 展开更多
关键词 ISOLATION AND structure DETERMINATION OF XF-1 A NEW ANTHRACYCLINE ANTIBIOTIC OH FIGURE
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