It is necessary to understand all the prerequisites, which result in gas hydrate formation for safe design and control of a variety of processes in petroleum industry. Thermodynamic hydrate inhibitors (THIs) are norma...It is necessary to understand all the prerequisites, which result in gas hydrate formation for safe design and control of a variety of processes in petroleum industry. Thermodynamic hydrate inhibitors (THIs) are normally used to preclude gas hydrate formation by shifting hydrate stability region to lower temperatures and higher pressures. Sometimes, it is difficult to avoid hydrate formation and hydrates will form anyway. In this situation, kinetic hydrate inhibitors (KHIs) can be used to postpone formation of gas hydrates by retarding hydrate nucleation and growth rate. In this study, two kinetic parameters including natural gas hydrate formation induction time and the rate of gas consumption were experimentally investigated in the presence of monoethylene glycol (MEG), L-tyrosine, and polyvinylpyrrolidone (PVP) at various concentrations in aqueous solutions. Since hydrate formation is a stochastic phenomenon, the repeatability of each kinetic parameter was evaluated several times and the average values for the hydrate formation induction times and the rates of gas consumption are reported. The results indicate that from the view point of hydrate formation induction time, 2 wt% PVP and 20 wt% MEG aqueous solutions have the highest values and are the best choices. It is also interpreted from the results that from the view point of the rate of gas consumption, 20 wt% MEG aqueous solution yields the lowest value and is the best choice. Finally, it is concluded that the combination of PVP and MEG in an aqueous solution has a simultaneous synergistic impact on natural gas hydrate formation induction time and the rate of gas consumption. Furthermore, a semi-empirical model based on chemical kinetic theory is applied to evaluate the hydrate formation induction time data. A good agreement between the experimental and calculated hydrate formation induction time data is observed.展开更多
We study the stability of an interface between two fluids of different densities flowing parallel to each other in the presence of a transverse magnetic field. A simple theory based on fully developed flow approximati...We study the stability of an interface between two fluids of different densities flowing parallel to each other in the presence of a transverse magnetic field. A simple theory based on fully developed flow approximations is used to de-rive the dispersion relation for the growth rate of KHI. We replace the effect of boundary layer with Beavers and Joseph slip condition. The dispersion relation is derived using suitable boundary and surface conditions and results are discussed graphically. The magnetic field is found to be stabilizing and the influence of the various parameters of the problem on the interface stability is thoroughly analyzed. These are favorable to control the surface instabilities in many practical applications discussed in this paper.展开更多
Kelvin-Helmholtz instability (KHI) appears in stratified two-fluid flow at surface. When the relative velocity is higher than the critical relative velocity, the growth of waves occurs. It is found that magnetic field...Kelvin-Helmholtz instability (KHI) appears in stratified two-fluid flow at surface. When the relative velocity is higher than the critical relative velocity, the growth of waves occurs. It is found that magnetic field has a stabilization effect whereas the buoyancy force has a destabilization effect on the KHI in the presence of sharp inter-face. The RT instability increases with wave number and flow shear, and acts much like a KHI when destabilizing effect of sheared flow dominates. It is shown that both of ablation velocity and magnetic field have stabilization effect on RT instability in the presence of continued interface. In this paper, we study the effect of magnetic field on Kelvin-Helmholtz instability (KHI) in a Couple-stress fluid layer above by a porous layer and below by a rigid surface. A simple theory based on fully developed flow approximations is used to derive the dispersion relation for the growth rate of KHI. We replace the effect of boundary layer with Beavers and Joseph slip condition at the rigid surface. The dispersion relation is derived using suitable boundary and surface conditions and results are discussed graphically. The stabilization effect of magnetic field takes place for whole waveband and becomes more significant for the short wavelength. The growth rate decreases as the density scale length increases. The stabilization effect of magnetic field is more significant for the short density scale length.展开更多
The surface instability of Kelvin-Helmholtz type bounded above by a porous layer and below by a rigid surface is investigated using linear stability analysis. Here we adopt the theory based on electrohydrodynamic as w...The surface instability of Kelvin-Helmholtz type bounded above by a porous layer and below by a rigid surface is investigated using linear stability analysis. Here we adopt the theory based on electrohydrodynamic as well as Stokes and lubrication approximations. We replace the effect of boundary layer with Beavers and Joseph slip condition. Here we have studied the combined effect of electric and magnetic fields on Kelvin-Helmholtz instability (KHI) in a fluid layer bounded above by a porous layer and below by a rigid surface. The dispersion relation is obtained using suitable boundary and surface conditions and results are depicted graphically. Also the ratio Gm is numerically computed for different values of We and M given in the Table 1. From this it is clear that the combined effect of electric and magnetic fields with porous layer are more effective than the effect of compressibility in reducing the growth rate of RTI. Also, these results shows that with a proper choice of magnetic field it is possible to control the growth rate of Electrohydrody-namic KHI (EKHI) and hence can be restored the symmetry of IFE target.展开更多
文摘It is necessary to understand all the prerequisites, which result in gas hydrate formation for safe design and control of a variety of processes in petroleum industry. Thermodynamic hydrate inhibitors (THIs) are normally used to preclude gas hydrate formation by shifting hydrate stability region to lower temperatures and higher pressures. Sometimes, it is difficult to avoid hydrate formation and hydrates will form anyway. In this situation, kinetic hydrate inhibitors (KHIs) can be used to postpone formation of gas hydrates by retarding hydrate nucleation and growth rate. In this study, two kinetic parameters including natural gas hydrate formation induction time and the rate of gas consumption were experimentally investigated in the presence of monoethylene glycol (MEG), L-tyrosine, and polyvinylpyrrolidone (PVP) at various concentrations in aqueous solutions. Since hydrate formation is a stochastic phenomenon, the repeatability of each kinetic parameter was evaluated several times and the average values for the hydrate formation induction times and the rates of gas consumption are reported. The results indicate that from the view point of hydrate formation induction time, 2 wt% PVP and 20 wt% MEG aqueous solutions have the highest values and are the best choices. It is also interpreted from the results that from the view point of the rate of gas consumption, 20 wt% MEG aqueous solution yields the lowest value and is the best choice. Finally, it is concluded that the combination of PVP and MEG in an aqueous solution has a simultaneous synergistic impact on natural gas hydrate formation induction time and the rate of gas consumption. Furthermore, a semi-empirical model based on chemical kinetic theory is applied to evaluate the hydrate formation induction time data. A good agreement between the experimental and calculated hydrate formation induction time data is observed.
文摘We study the stability of an interface between two fluids of different densities flowing parallel to each other in the presence of a transverse magnetic field. A simple theory based on fully developed flow approximations is used to de-rive the dispersion relation for the growth rate of KHI. We replace the effect of boundary layer with Beavers and Joseph slip condition. The dispersion relation is derived using suitable boundary and surface conditions and results are discussed graphically. The magnetic field is found to be stabilizing and the influence of the various parameters of the problem on the interface stability is thoroughly analyzed. These are favorable to control the surface instabilities in many practical applications discussed in this paper.
文摘Kelvin-Helmholtz instability (KHI) appears in stratified two-fluid flow at surface. When the relative velocity is higher than the critical relative velocity, the growth of waves occurs. It is found that magnetic field has a stabilization effect whereas the buoyancy force has a destabilization effect on the KHI in the presence of sharp inter-face. The RT instability increases with wave number and flow shear, and acts much like a KHI when destabilizing effect of sheared flow dominates. It is shown that both of ablation velocity and magnetic field have stabilization effect on RT instability in the presence of continued interface. In this paper, we study the effect of magnetic field on Kelvin-Helmholtz instability (KHI) in a Couple-stress fluid layer above by a porous layer and below by a rigid surface. A simple theory based on fully developed flow approximations is used to derive the dispersion relation for the growth rate of KHI. We replace the effect of boundary layer with Beavers and Joseph slip condition at the rigid surface. The dispersion relation is derived using suitable boundary and surface conditions and results are discussed graphically. The stabilization effect of magnetic field takes place for whole waveband and becomes more significant for the short wavelength. The growth rate decreases as the density scale length increases. The stabilization effect of magnetic field is more significant for the short density scale length.
文摘The surface instability of Kelvin-Helmholtz type bounded above by a porous layer and below by a rigid surface is investigated using linear stability analysis. Here we adopt the theory based on electrohydrodynamic as well as Stokes and lubrication approximations. We replace the effect of boundary layer with Beavers and Joseph slip condition. Here we have studied the combined effect of electric and magnetic fields on Kelvin-Helmholtz instability (KHI) in a fluid layer bounded above by a porous layer and below by a rigid surface. The dispersion relation is obtained using suitable boundary and surface conditions and results are depicted graphically. Also the ratio Gm is numerically computed for different values of We and M given in the Table 1. From this it is clear that the combined effect of electric and magnetic fields with porous layer are more effective than the effect of compressibility in reducing the growth rate of RTI. Also, these results shows that with a proper choice of magnetic field it is possible to control the growth rate of Electrohydrody-namic KHI (EKHI) and hence can be restored the symmetry of IFE target.
