As a cornerstone of the national economy,the iron and steel industry generates a significant amount of sintering dust containing both valuable lead resources and deleterious elements.Flotation is a promising technique...As a cornerstone of the national economy,the iron and steel industry generates a significant amount of sintering dust containing both valuable lead resources and deleterious elements.Flotation is a promising technique for lead recovery from sintering dust,but efficient separation from Fe_(2)O_(3) is still challenging.This study investigated the cooperative effect of sodium lauryl sulfate(SLS,C_(12)H_(25)SO_(4)Na)and sodium pyrophosphate(SPP,Na_(4)P_(2)O_(7))on the selective flotation of lead oxide minerals(PbOHCl and PbSO_(4))from hematite(Fe_(2)O_(3)).Optimal flotation conditions were first identified,resulting in high recovery of lead oxide minerals while inhibiting Fe_(2)O_(3) flotation.Zeta potential measurements,Fourier transform infrared spectroscopy(FT-IR)analysis,adsorption capacity analysis,and X-ray photoelectron spectroscopy(XPS)studies offer insights into the adsorption behaviors of the reagents on mineral surfaces,revealing strong adsorption of SLS on PbOHCl and PbSO_(4) surfaces and remarkable adsorption of SPP on Fe_(2)O_(3).The proposed model of reagent adsorption on mineral surfaces illustrates the selective adsorption behavior,highlighting the pivotal role of reagent adsorption in the separation process.These findings contribute to the efficient and environmentally friendly utilization of iron ore sintering dust for lead recovery,paving the way for sustainable resource management in the iron and steel industry.展开更多
Lauryl betaine(LB)as an amphoteric surfactant carries both positive and negative charges and should be able to generate stable foam through electrostatic interaction with nanoparticles and co-surfactants.However,no pr...Lauryl betaine(LB)as an amphoteric surfactant carries both positive and negative charges and should be able to generate stable foam through electrostatic interaction with nanoparticles and co-surfactants.However,no previous attempts have been made to investigate the influence of nanoparticles and other co-surfactants on the stability and apparent viscosity of LBstabilized foam.In this study,a thorough investigation on the influence of silicon dioxide(SiO2)nanoparticles,alpha olefin sulfonate(AOS)and sodium dodecyl sulfate(SDS),on foam stability and apparent viscosity was carried out.The experiments were conducted with the 2D Hele-Shaw cell at high foam qualities(80%-98%).Influence of AOS on the interaction between the LB foam and oil was also investigated.Results showed that the SiO2-LB foam apparent viscosity decreased with increasing surfactant concentration from 0.1 wt%to 0.3 wt%.0.1 wt%SiO2 was the optimum concentration and increased the 0.1 wt%LB foam stability by 108.65%at 96%foam quality.In the presence of co-surfactants,the most stable foam,with the highest apparent viscosity,was generated by AOS/LB solution at a ratio of 9:1.The emulsified crude oil did not imbibe into AOS-LB foam lamellae.Instead,oil was redirected into the plateau borders where the accumulated oil drops delayed the rate of film thinning,bubble coalescence and coarsening.展开更多
This paper aims at synthesizing a detergent with graphene oxide(GO)and lauryl betaine(LB),where the GO will have a better performance with the modification of LB.First,the complexus of GO and LB and the complexus of G...This paper aims at synthesizing a detergent with graphene oxide(GO)and lauryl betaine(LB),where the GO will have a better performance with the modification of LB.First,the complexus of GO and LB and the complexus of GO,KH550(Amino functional silane),and LB were synthesized to obtain two products,GO⁃LB and GO⁃KH550⁃LB.Then,the abilities and safety of the products were evaluated by characterization,contact angle measurement,measurement of KRAFFT Point,foaming test,emulsion ability test,decontamination capacity test,skin irritation test,and skin allergy test.Results of the experiment showed that GO⁃LB was superior to GO⁃KH550⁃LB in wetting ability and foaming stability,while GO⁃KH550⁃LB outperformed in emulsifying capacity.Besides,good abilities of removing mussels,seaweed,and protein were proved.According to the result of the irritation test of the materials to skin,they were both at the light irritation level,and the irritation of the GO⁃LB was slightly lower than that of GO⁃KH550⁃LB.Neither GO⁃LB nor GO⁃KH550⁃LB had allergic effect.Therefore,it can be concluded that as a surface active agent,graphene oxide/lauryl betaine was effective as a new detergent,which had low irritation and insignificant allergic phenomena on the human body over a long term of use.展开更多
The guinea pigs were dermally exposed to nickel (Ni), sodium lauryl sulphate (SLS) and in their combination for 7 and 14 days. The exposure to Ni and SLS produced changes in enzymes and lipid peroxidation in kidney. T...The guinea pigs were dermally exposed to nickel (Ni), sodium lauryl sulphate (SLS) and in their combination for 7 and 14 days. The exposure to Ni and SLS produced changes in enzymes and lipid peroxidation in kidney. The exposure to Ni or SLS depicted slight changes while combined exposure to Ni plus SLS exhibited more degenerative changes in kidney. The result of the study suggests that industrial workers and/or populations exposed simultaneously to Ni and SLS produces more damage to kidney.展开更多
The effeclt of condensed tannins from Leucaena leucocephala （Lam.） and sodium lauryl sulfate （SLS） addition to basal diets of corn silage on nematode eggs and protozoa interaction in the rumen within Thai native x...The effeclt of condensed tannins from Leucaena leucocephala （Lam.） and sodium lauryl sulfate （SLS） addition to basal diets of corn silage on nematode eggs and protozoa interaction in the rumen within Thai native x Anglo-Nubian male goats was studied. Goats （n = 24 male; BW = 30 ＋ 2） were randomly considered toward treatment position into randomized complete block design （RCBD）. The treatments were： 1） Basal （B; 1.0-1.2 kg/head/day, corn silage）, 2） B ＋ SLS 8 g/head/day） 3） B ＋ 40g Leucaena/head/day （1.0% condensed tannins）, and 4） B ＋ 40g Leucaena/head/day （1.0% condensed tannins） with SLS 4 g/head/day）. These studies indicate that the action of 1.0% condensed tannins by Leucaena with 8 g SLS has the effect of increasing C3 （P 〈 0.05）. The opposite effect was observed for C2 which decreased （P 〈 0.05）. Both intestinal nematode eggs and protozoa in the rumen were reduced highly significantly （P 〈 0.01）. Bacteria population was raised （P 〈 0.01）. Nevertheless, all of these treatments did not affect intake, productive performances and blood urea nitrogen.展开更多
Spin-lattice relaxation time, spin-spin relaxation time and two-dimensional nuclear Overhauser enhancement spectroscopy (2D NOESY) experiments of polyoxyethylene lauryl ether (Brij-35) micelles in aqueous solutions at...Spin-lattice relaxation time, spin-spin relaxation time and two-dimensional nuclear Overhauser enhancement spectroscopy (2D NOESY) experiments of polyoxyethylene lauryl ether (Brij-35) micelles in aqueous solutions at a concentration of 100 times the critical micellar concentration (cmc) give direct evidence that the hydrophilic polyoxyethylene chains, staying in the exterior of the micellar core, are coiled, bent and aligned around the micellar core with a certain number of water molecules included. This hydrophilic layer is in contact with the solvent, water, keeping the micellar solution stable. 1H NMR relaxation time measurements show that the first oxyethylene group next to the alkyl chain participates in the formation of the surface area of the micellar core. The motion of the hydrophilic polyoxyethylene chains is less restricted as compared with the hydrophobic alkyl chains.展开更多
Poly（n-alkyl acrylate） with long side groups,namely,poly（lauryl acrylate）（PLA） was synthesized by reversible addition-fragmentation chain transfer（RAFT） polymerization,and the trithioester terminal groups were...Poly（n-alkyl acrylate） with long side groups,namely,poly（lauryl acrylate）（PLA） was synthesized by reversible addition-fragmentation chain transfer（RAFT） polymerization,and the trithioester terminal groups were converted to thiol by reducing reaction.Grafting of the obtained polymer onto nano-silica modified with 3-（methacryloxy）propyl-trimethoxysilane（SiO2-MPS） was conducted by thiol-ene ‘click chemistry＇.PLA was characterized by proton nuclear magnetic resonance（1H NMR） and gel permeation chromatography（GPC）.Fourier transform infrared（FTIR） spectrometry and thermogravimetric analysis（TGA） were used to demonstrate the grafting reaction,and the grafted hairy nano-silica（SiO2-g-PLA） was viewed under a transmission electron microscope（TEM）.According to TGA,grafting ratio and grafting density of SiO2-g-PLA are 30.27％ and 0.013 chain/nm2,respectively.The static water contact angle of SiO2-g-PLA is （80.10±2.97）°,which ensures its hydrophobicity.Dispersion experiment was carried out to confirm its dispersibility in mixed solvents,indicating its potential application in coatings or composites.展开更多
基金supported by the National Natural Science Foundation of China(Nos.52004335 and 52204298)the National Natural Science Foundation of Hunan Province,China(No.2023JJ20071)the Science and Technology Innovation Program of Hunan Province,China(No.2023RC3067).
文摘As a cornerstone of the national economy,the iron and steel industry generates a significant amount of sintering dust containing both valuable lead resources and deleterious elements.Flotation is a promising technique for lead recovery from sintering dust,but efficient separation from Fe_(2)O_(3) is still challenging.This study investigated the cooperative effect of sodium lauryl sulfate(SLS,C_(12)H_(25)SO_(4)Na)and sodium pyrophosphate(SPP,Na_(4)P_(2)O_(7))on the selective flotation of lead oxide minerals(PbOHCl and PbSO_(4))from hematite(Fe_(2)O_(3)).Optimal flotation conditions were first identified,resulting in high recovery of lead oxide minerals while inhibiting Fe_(2)O_(3) flotation.Zeta potential measurements,Fourier transform infrared spectroscopy(FT-IR)analysis,adsorption capacity analysis,and X-ray photoelectron spectroscopy(XPS)studies offer insights into the adsorption behaviors of the reagents on mineral surfaces,revealing strong adsorption of SLS on PbOHCl and PbSO_(4) surfaces and remarkable adsorption of SPP on Fe_(2)O_(3).The proposed model of reagent adsorption on mineral surfaces illustrates the selective adsorption behavior,highlighting the pivotal role of reagent adsorption in the separation process.These findings contribute to the efficient and environmentally friendly utilization of iron ore sintering dust for lead recovery,paving the way for sustainable resource management in the iron and steel industry.
文摘Lauryl betaine(LB)as an amphoteric surfactant carries both positive and negative charges and should be able to generate stable foam through electrostatic interaction with nanoparticles and co-surfactants.However,no previous attempts have been made to investigate the influence of nanoparticles and other co-surfactants on the stability and apparent viscosity of LBstabilized foam.In this study,a thorough investigation on the influence of silicon dioxide(SiO2)nanoparticles,alpha olefin sulfonate(AOS)and sodium dodecyl sulfate(SDS),on foam stability and apparent viscosity was carried out.The experiments were conducted with the 2D Hele-Shaw cell at high foam qualities(80%-98%).Influence of AOS on the interaction between the LB foam and oil was also investigated.Results showed that the SiO2-LB foam apparent viscosity decreased with increasing surfactant concentration from 0.1 wt%to 0.3 wt%.0.1 wt%SiO2 was the optimum concentration and increased the 0.1 wt%LB foam stability by 108.65%at 96%foam quality.In the presence of co-surfactants,the most stable foam,with the highest apparent viscosity,was generated by AOS/LB solution at a ratio of 9:1.The emulsified crude oil did not imbibe into AOS-LB foam lamellae.Instead,oil was redirected into the plateau borders where the accumulated oil drops delayed the rate of film thinning,bubble coalescence and coarsening.
基金Sponsored by the Outstanding Academic Leaders Foundation of Harbin(Grant No.2013RFXXJ042)the Planning Project for Space Application(Grant No.01-1-08).
文摘This paper aims at synthesizing a detergent with graphene oxide(GO)and lauryl betaine(LB),where the GO will have a better performance with the modification of LB.First,the complexus of GO and LB and the complexus of GO,KH550(Amino functional silane),and LB were synthesized to obtain two products,GO⁃LB and GO⁃KH550⁃LB.Then,the abilities and safety of the products were evaluated by characterization,contact angle measurement,measurement of KRAFFT Point,foaming test,emulsion ability test,decontamination capacity test,skin irritation test,and skin allergy test.Results of the experiment showed that GO⁃LB was superior to GO⁃KH550⁃LB in wetting ability and foaming stability,while GO⁃KH550⁃LB outperformed in emulsifying capacity.Besides,good abilities of removing mussels,seaweed,and protein were proved.According to the result of the irritation test of the materials to skin,they were both at the light irritation level,and the irritation of the GO⁃LB was slightly lower than that of GO⁃KH550⁃LB.Neither GO⁃LB nor GO⁃KH550⁃LB had allergic effect.Therefore,it can be concluded that as a surface active agent,graphene oxide/lauryl betaine was effective as a new detergent,which had low irritation and insignificant allergic phenomena on the human body over a long term of use.
文摘The guinea pigs were dermally exposed to nickel (Ni), sodium lauryl sulphate (SLS) and in their combination for 7 and 14 days. The exposure to Ni and SLS produced changes in enzymes and lipid peroxidation in kidney. The exposure to Ni or SLS depicted slight changes while combined exposure to Ni plus SLS exhibited more degenerative changes in kidney. The result of the study suggests that industrial workers and/or populations exposed simultaneously to Ni and SLS produces more damage to kidney.
文摘The effeclt of condensed tannins from Leucaena leucocephala （Lam.） and sodium lauryl sulfate （SLS） addition to basal diets of corn silage on nematode eggs and protozoa interaction in the rumen within Thai native x Anglo-Nubian male goats was studied. Goats （n = 24 male; BW = 30 ＋ 2） were randomly considered toward treatment position into randomized complete block design （RCBD）. The treatments were： 1） Basal （B; 1.0-1.2 kg/head/day, corn silage）, 2） B ＋ SLS 8 g/head/day） 3） B ＋ 40g Leucaena/head/day （1.0% condensed tannins）, and 4） B ＋ 40g Leucaena/head/day （1.0% condensed tannins） with SLS 4 g/head/day）. These studies indicate that the action of 1.0% condensed tannins by Leucaena with 8 g SLS has the effect of increasing C3 （P 〈 0.05）. The opposite effect was observed for C2 which decreased （P 〈 0.05）. Both intestinal nematode eggs and protozoa in the rumen were reduced highly significantly （P 〈 0.01）. Bacteria population was raised （P 〈 0.01）. Nevertheless, all of these treatments did not affect intake, productive performances and blood urea nitrogen.
基金This work was supported by the National Key Basic Research Development Program "Fundamental Studies of the Extensively Enhanced Petroleum Recovery" (Grant No. G199022504) .
文摘Spin-lattice relaxation time, spin-spin relaxation time and two-dimensional nuclear Overhauser enhancement spectroscopy (2D NOESY) experiments of polyoxyethylene lauryl ether (Brij-35) micelles in aqueous solutions at a concentration of 100 times the critical micellar concentration (cmc) give direct evidence that the hydrophilic polyoxyethylene chains, staying in the exterior of the micellar core, are coiled, bent and aligned around the micellar core with a certain number of water molecules included. This hydrophilic layer is in contact with the solvent, water, keeping the micellar solution stable. 1H NMR relaxation time measurements show that the first oxyethylene group next to the alkyl chain participates in the formation of the surface area of the micellar core. The motion of the hydrophilic polyoxyethylene chains is less restricted as compared with the hydrophobic alkyl chains.
基金Supported by the National Natural Science Foundation of China（No.51273146 and 51103061）.
文摘Poly（n-alkyl acrylate） with long side groups,namely,poly（lauryl acrylate）（PLA） was synthesized by reversible addition-fragmentation chain transfer（RAFT） polymerization,and the trithioester terminal groups were converted to thiol by reducing reaction.Grafting of the obtained polymer onto nano-silica modified with 3-（methacryloxy）propyl-trimethoxysilane（SiO2-MPS） was conducted by thiol-ene ‘click chemistry＇.PLA was characterized by proton nuclear magnetic resonance（1H NMR） and gel permeation chromatography（GPC）.Fourier transform infrared（FTIR） spectrometry and thermogravimetric analysis（TGA） were used to demonstrate the grafting reaction,and the grafted hairy nano-silica（SiO2-g-PLA） was viewed under a transmission electron microscope（TEM）.According to TGA,grafting ratio and grafting density of SiO2-g-PLA are 30.27％ and 0.013 chain/nm2,respectively.The static water contact angle of SiO2-g-PLA is （80.10±2.97）°,which ensures its hydrophobicity.Dispersion experiment was carried out to confirm its dispersibility in mixed solvents,indicating its potential application in coatings or composites.
