Single-ion conductors based on covalent organic frameworks(COFs)have garnered attention as a potential alternative to currently prevalent inorganic ion conductors owing to their structural uniqueness and chemical vers...Single-ion conductors based on covalent organic frameworks(COFs)have garnered attention as a potential alternative to currently prevalent inorganic ion conductors owing to their structural uniqueness and chemical versatility.However,the sluggish Li+conduction has hindered their practical applications.Here,we present a class of solvent-free COF single-ion conductors(Li-COF@P)based on weak ion-dipole interaction as opposed to traditional strong ion-ion interaction.The ion(Li+from the COF)-dipole(oxygen from poly(ethylene glycol)diacrylate embedded in the COF pores)interaction in the Li-COF@P promotes ion dissociation and Li+migration via directional ionic channels.Driven by this single-ion transport behavior,the Li-COF@P enables reversible Li plating/stripping on Li-metal electrodes and stable cycling performance(88.3%after 2000 cycles)in organic batteries(Li metal anode||5,5’-dimethyl-2,2’-bis-p-benzoquinone(Me2BBQ)cathode)under ambient operating conditions,highlighting the electrochemical viability of the Li-COF@P for all-solid-state organic batteries.展开更多
High-temperature superconducting(HTS)rare-earth Ba_(2)Cu_(3)O_(7-x)(REBCO)coated conductors(CCs)have significant potential in high-current and high-field applications.However,owing to the weak interface strength of th...High-temperature superconducting(HTS)rare-earth Ba_(2)Cu_(3)O_(7-x)(REBCO)coated conductors(CCs)have significant potential in high-current and high-field applications.However,owing to the weak interface strength of the laminated composite REBCO CCs,the damage induced by the thermal mismatch stress under a combination of epoxy impregnation,cooling,and quenching can cause premature degradation of the critical current.In this study,a three-dimensional(3D)electromagnetic-thermal-mechanical model based on the H-formulation and cohesive zone model(CZM)is developed to study the critical current degradation characteristics in an epoxy-impregnated REBCO CC caused by the damage during a quench.The temperature variation,critical current degradation of the REBCO CC,and its degradation onset temperature calculated by the numerical model are in agreement with the experimental data taken from the literature.The delamination of the REBCO CC predicted by the numerical model is consistent with the experimental result.The numerical results also indicate that the shear stress is the main contributor to the damage propagation inside the REBCO CC.The premature degradation of the critical current during a quench is closely related to the interface shear strength inside the REBCO CC.Finally,the effects of the coefficient of thermal expansion(CTE)of the epoxy resin,thickness of the substrate,and substrate material on the critical current degradation characteristics of the epoxy-impregnated REBCO CC during a quench are also discussed.These results help us understand the relationship between the current-carrying degradation and damage in the HTS applications.展开更多
A solid-state electrolyte(SSE),which is a solid ionic conductor and electroninsulating material,is known to play a crucial role in adapting a lithium metal anode to a high-capacity cathode in a solid-state battery.Amo...A solid-state electrolyte(SSE),which is a solid ionic conductor and electroninsulating material,is known to play a crucial role in adapting a lithium metal anode to a high-capacity cathode in a solid-state battery.Among the various SSEs,the single Li-ion conductor has advantages in terms of enhancing the ion conductivity,eliminating interfacial side reactions,and broadening the electrochemical window.Covalent organic frameworks(COFs)are optimal platforms for achieving single Li-ion conduction behavior because of wellordered one-dimensional channels and precise chemical modification features.Herein,we study in depth three types of Li-carboxylate COFs(denoted LiOOC-COFn,n=1,2,and 3)as single Li-ion conducting SSEs.Benefiting from well-ordered directional ion channels,the single Li-ion conductor LiOOC-COF3 shows an exceptional ion conductivity of 1.36×10^(-5) S cm^(-1) at room temperature and a high transference number of 0.91.Moreover,it shows excellent electrochemical performance with long-term cycling,high-capacity output,and no dendrites in the quasi-solid-state organic battery,with the organic small molecule cyclohexanehexone(C_(6)O_(6))as the cathode and the Li metal as the anode,and enables effectively avoiding dissolution of the organic electrode by the liquid electrolyte.展开更多
Electrosynthesis of ammonia from the reduction of nitrogen is still confronted with the limited supply of gas reactant in dynamics as well as high activation barrier in thermodynamics.Unfortunately,despite tremendous ...Electrosynthesis of ammonia from the reduction of nitrogen is still confronted with the limited supply of gas reactant in dynamics as well as high activation barrier in thermodynamics.Unfortunately,despite tremendous efforts devoted to electrocatalysts themselves,they still fail to tackle the above two challenges simultaneously.Herein,we employ a heterogeneous catalyst adlayer-composed of crown ethers associated with Li^(+)ions-to achieve the dual promotion of dynamics and thermodynamics for ambient ammonia synthesis.Dynamically,the bound Li^(+)ions interact with the strong quadrupole moment of nitrogen,and trigger considerable reactant flux toward the catalyst.Thermodynamically,Li^(+)associated with the oxygen of crown ether achieves a higher density of states at the Fermi level for the catalyst,enabling effortless electron transfer from the catalysts to nitrogen and thus greatly reducing the activation barrier.As expected,the proof-of-concept system achieves an ammonia yield rate of 168.5μg h^(-1)mg^(-1)and a Faradaic efficiency of 75.3%at-0.3 V vs.RHE.This system-level approach opens up pathways for tackling the two key challenges that have limited the field of ammonia synthesis.展开更多
Serious ice accumulating,pile-up and ice jamming occur around the conductor array of offshore jacket platforms during the winter every year in Bohai Sea,which could cause grave threats to the stability of platform str...Serious ice accumulating,pile-up and ice jamming occur around the conductor array of offshore jacket platforms during the winter every year in Bohai Sea,which could cause grave threats to the stability of platform structure,the safety of people and equipment,and even severer calamity.Therefore,the process of ice accumulation and ice jamming in the jacket platform area needs more concern.This study focuses on ice accumulation and jamming behaviors in the jacket platform conductor area by using a coupled two-dimensional hydro-ice dynamics model.A series of cases are conducted with different flow conditions,such as flow velocity,drifting direction and oscillatory flow.Through the simulation,the ice pile-up process is described and changes in ice-jamming thickness,ice pile-up location and ice pile-up volume are investigated.The differences in ice pile-up in the steady flow and oscillatory flow are analyzed.This study proposes a new approach to simulate the ice jamming process in the jacket platform conductor area,providing a reference for ice management on the platform.展开更多
Turbulence is expected to play a relevant role in the so-called conductor gallop phenomena,namely,the high-amplitude,low-frequency oscillation of overhead power lines due to the formation of ice structures and the ens...Turbulence is expected to play a relevant role in the so-called conductor gallop phenomena,namely,the high-amplitude,low-frequency oscillation of overhead power lines due to the formation of ice structures and the ensu-ing effect that wind can have on these.In this work,the galloping time history of a wire with distorted(fixed in time)shape due to the formation of ice is analyzed numerically in the frame of afluid-solid coupling method for different wind speeds and levels of turbulence.The results show that the turbulence intensity has a moderate effect on the increase of the conductor’s aerodynamic lift and drag coefficients due to ice accretion;nevertheless,the corresponding changes in the torsion coefficient are very significant and complicated.A high turbulence intensity can affect the torsion coefficient in a certain range of attack angles and increase the torsion angle of the conductor.Through comparison of the galloping phenomena for different wind velocities,it is found that the related amplitude grows significantly with an increase of the wind speed.For a relatively large wind speed,the galloping amplitude is more sensitive to the turbulence intensity.Moreover,the larger the turbulence intensity,the larger the conductor’s vertical and horizontal galloping amplitudes after icing.The torsion angle also increases with an increase in the wind speed and turbulence intensity.展开更多
A novel expandable conductor was designed and applied in deep-water drilling to improve the vertical and lateral bearing capacity with a significant reduction of conductor jetting depth and soaking time. The vertical ...A novel expandable conductor was designed and applied in deep-water drilling to improve the vertical and lateral bearing capacity with a significant reduction of conductor jetting depth and soaking time. The vertical and lateral bearing capability of expandable conductors was depicted based on the ultimate subgrade reaction method and pile foundation bearing theory. The load-bearing characteristics of a laboratory-scale expandable conductor were analyzed through laboratory experiments. The serial simulation experiments are accomplished to study the bearing characteristics(vertical ultimate bearing capacity, lateral soil pressure, and lateral displacement) during the conductor soaking process. The laboratory experimental results show that the larger the length and thickness of expandable materials are,the higher the bearing capacity of the wellhead will be. During the conductor soaking process, the soil pressure around the three expandable conductors increases faster, strings representing a stronger squeezing effect and resulting in higher vertical bearing capacity. Furthermore, the lateral displacement of novel expandable conductor is smaller than that of the conventional conductor. All the advantages mentioned above contributed to the reduction of conductor’s jetting depth and soaking time. Lastly, the application workflow of a novel expandable deep-water drilling conductor was established and the autonomous expandable conductor was successfully applied in the South China Sea with a significant reduction of conductor’s jetting depth and soaking time. According to the soil properties and designed installation depth of the surface conductor, the arrangement of expandable materials should be designed reasonably to meet the safety condition and reduce the construction cost of the subsea wellhead.展开更多
Severe lithium(Li)dendrite growth caused by the uneven overpotential deposition is a formidable challenge for high energy density Li metal batteries(LMBs).Herein,we investigate a synergetic interfacial kinetic to regu...Severe lithium(Li)dendrite growth caused by the uneven overpotential deposition is a formidable challenge for high energy density Li metal batteries(LMBs).Herein,we investigate a synergetic interfacial kinetic to regulate Li deposition behavior and stabilize Li metal anode.Through constructing Li alloying matrix with a bi-functional silver(Ag)-Li_(3)N blended interface,fast Li^(+)conductivity and high Li affinity can be achieved simultaneously,resulting in both decreased Li nucleation and mass transfercontrolled overpotentials.Beyond these properties,a more important feature is demonstrated herein;that is,the inward diffusion depth of the Li adatoms inside of the Ag site can be restricted by the Li^(+)solvation structure in a highly coordinating environment.The latter feature can ensure the durability of the operational Ag sites,thereby elongating the Li protection ability of the Ag-Li_(3)N interface greatly.This work provides a deep insight into the synergetic effect of functional alloying structure and Li^(+)solvation mediated interfacial kinetic on Li metal protection.展开更多
A floating conductor exhibits a bipolar corona phenomenon with microscopic discharge characteristics that are still unclear.In this study,a plasma simulation model of the bipolar corona with 108 chemical reaction equa...A floating conductor exhibits a bipolar corona phenomenon with microscopic discharge characteristics that are still unclear.In this study,a plasma simulation model of the bipolar corona with 108 chemical reaction equations is established by combining hydrodynamics and plasma chemical reactions.The evolution characteristics of electrons,positive ions,negative ions and neutral particles,as well as the distribution characteristics of space charges are analyzed,and the evolutionary flow of microscopic particles is summarized.The results indicate that the positive end of the bipolar corona initiates discharge before the negative end,but the plasma chemistry at the negative end is more vigorous.The electron generation rate can reach 1240 mol(m^(3) s)^(-1),and the dissipation rate can reach 34 mol(m^(3) s)^(-1).The positive ion swarm is dominated by O_(4)^(+),and the maximum generation rate can reach 440 mol((m^(3) s)^(-1).The negative ion swarm is mainly O_(2) and O_(4).The O_(2) content is approximately 1.5-3 times that of O_(4),and the maximum reaction rate can reach 51 mol(m^(3) s)^(-1).The final destination of neutral particles is an accumulation in the form of O_(3) and NO,and the amount of O3 produced is approximately 4-6 times that of NO.The positive end of the bipolar corona is dominated by positive space charges,which continue to develop and spread outwards in the form of a pulse wave.The negative end exhibits a space charge distribution structure of concentrated positive charges and diffused negative charges.The validity of the microscopic simulation analysis is verified by the macroscopic discharge phenomenon.展开更多
In the harsh environment,the structural health of the anti-vibration hammer,which suffers from the coupled effects of corrosion and fatigue damage,is significantly reduced.As part of the conductor structure,the anti-v...In the harsh environment,the structural health of the anti-vibration hammer,which suffers from the coupled effects of corrosion and fatigue damage,is significantly reduced.As part of the conductor structure,the anti-vibration hammer is rigidly attached to the conductor,effectively suppressing conductor vibration.The conductor’s breeze vibration law and natural modal frequency are altered damage to the anti-vibration hammer structure.Through built a vibration experiment platform to simulate multiple faults such as anti-vibration hammer head drop off and position slippage,which to obtained the vibration acceleration signal of the conductor.The acceleration vibration signal is processed and analyzed in the time and frequency domains.The results are used to derive the breeze vibration law of the conductor under multiple faults and propose an anti-vibration hammer damage online monitoring technology.The results show that the vibration acceleration value and vibration intensity of the conductor are significantly increased after the anti-vibration hammer damage.The natural frequency increases for each order,with an absolute change ranging from 0.15 to 6.49 Hz.The anti-vibration hammer slipped due to a loose connection,the 1st natural frequency increases from 8.18 to 16.62 Hz.Therefore,in engineering applications,there can be no contact to determine the anti-vibration hammer damage situation by monitoring the modal natural frequency of the conductor.This is even a tiny damage that cannot be seen.This method will prevent the further expansion of the damage that can cause accidents.展开更多
基金supported by the Basic Science Research Program (No.RS-2024-00344021) through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT and future Planningthe financial support from the National Natural Science Foundation of China (52103277)+2 种基金the Program for Science & Technology Innovation Talents in Universities of Henan Province (23HASTIT015)Natural Science Foundation of Henan Province (242300421073)supported by the Technology Innovation Program (20010960) funded by the Ministry of Trade, Industry & Energy (MOTIE, Korea)
文摘Single-ion conductors based on covalent organic frameworks(COFs)have garnered attention as a potential alternative to currently prevalent inorganic ion conductors owing to their structural uniqueness and chemical versatility.However,the sluggish Li+conduction has hindered their practical applications.Here,we present a class of solvent-free COF single-ion conductors(Li-COF@P)based on weak ion-dipole interaction as opposed to traditional strong ion-ion interaction.The ion(Li+from the COF)-dipole(oxygen from poly(ethylene glycol)diacrylate embedded in the COF pores)interaction in the Li-COF@P promotes ion dissociation and Li+migration via directional ionic channels.Driven by this single-ion transport behavior,the Li-COF@P enables reversible Li plating/stripping on Li-metal electrodes and stable cycling performance(88.3%after 2000 cycles)in organic batteries(Li metal anode||5,5’-dimethyl-2,2’-bis-p-benzoquinone(Me2BBQ)cathode)under ambient operating conditions,highlighting the electrochemical viability of the Li-COF@P for all-solid-state organic batteries.
基金Project supported by the National Natural Science Foundation of China(Nos.12302278,U2241267,12172155,and 11932008)the Fundamental Research Funds for the Central Universities of China(No.lzujbky-2022-48)the Natural Science Foundation of Gansu Province of China(No.24JRRA473)。
文摘High-temperature superconducting(HTS)rare-earth Ba_(2)Cu_(3)O_(7-x)(REBCO)coated conductors(CCs)have significant potential in high-current and high-field applications.However,owing to the weak interface strength of the laminated composite REBCO CCs,the damage induced by the thermal mismatch stress under a combination of epoxy impregnation,cooling,and quenching can cause premature degradation of the critical current.In this study,a three-dimensional(3D)electromagnetic-thermal-mechanical model based on the H-formulation and cohesive zone model(CZM)is developed to study the critical current degradation characteristics in an epoxy-impregnated REBCO CC caused by the damage during a quench.The temperature variation,critical current degradation of the REBCO CC,and its degradation onset temperature calculated by the numerical model are in agreement with the experimental data taken from the literature.The delamination of the REBCO CC predicted by the numerical model is consistent with the experimental result.The numerical results also indicate that the shear stress is the main contributor to the damage propagation inside the REBCO CC.The premature degradation of the critical current during a quench is closely related to the interface shear strength inside the REBCO CC.Finally,the effects of the coefficient of thermal expansion(CTE)of the epoxy resin,thickness of the substrate,and substrate material on the critical current degradation characteristics of the epoxy-impregnated REBCO CC during a quench are also discussed.These results help us understand the relationship between the current-carrying degradation and damage in the HTS applications.
基金National Natural Science Foundation of China,Grant/Award Number:52064049Key National Natural Science Foundation of Yunnan Province,Grant/Award Numbers:2018FA028,2019FY003023+1 种基金International Joint Research Center for Advanced Energy Materials of Yunnan Province,Grant/Award Number:202003AE140001Key Laboratory of Solid State Ions for Green Energy of Yunnan University,Grant/Award Number:2019。
文摘A solid-state electrolyte(SSE),which is a solid ionic conductor and electroninsulating material,is known to play a crucial role in adapting a lithium metal anode to a high-capacity cathode in a solid-state battery.Among the various SSEs,the single Li-ion conductor has advantages in terms of enhancing the ion conductivity,eliminating interfacial side reactions,and broadening the electrochemical window.Covalent organic frameworks(COFs)are optimal platforms for achieving single Li-ion conduction behavior because of wellordered one-dimensional channels and precise chemical modification features.Herein,we study in depth three types of Li-carboxylate COFs(denoted LiOOC-COFn,n=1,2,and 3)as single Li-ion conducting SSEs.Benefiting from well-ordered directional ion channels,the single Li-ion conductor LiOOC-COF3 shows an exceptional ion conductivity of 1.36×10^(-5) S cm^(-1) at room temperature and a high transference number of 0.91.Moreover,it shows excellent electrochemical performance with long-term cycling,high-capacity output,and no dendrites in the quasi-solid-state organic battery,with the organic small molecule cyclohexanehexone(C_(6)O_(6))as the cathode and the Li metal as the anode,and enables effectively avoiding dissolution of the organic electrode by the liquid electrolyte.
基金supported by the National Natural Science Foundation of China(U21A20332,52103226,52202275,52203314,and 12204253)the Distinguished Young Scholars Fund of Jiangsu Province(BK20220061)the Fellowship of China Postdoctoral Science Foundation(2021M702382)。
文摘Electrosynthesis of ammonia from the reduction of nitrogen is still confronted with the limited supply of gas reactant in dynamics as well as high activation barrier in thermodynamics.Unfortunately,despite tremendous efforts devoted to electrocatalysts themselves,they still fail to tackle the above two challenges simultaneously.Herein,we employ a heterogeneous catalyst adlayer-composed of crown ethers associated with Li^(+)ions-to achieve the dual promotion of dynamics and thermodynamics for ambient ammonia synthesis.Dynamically,the bound Li^(+)ions interact with the strong quadrupole moment of nitrogen,and trigger considerable reactant flux toward the catalyst.Thermodynamically,Li^(+)associated with the oxygen of crown ether achieves a higher density of states at the Fermi level for the catalyst,enabling effortless electron transfer from the catalysts to nitrogen and thus greatly reducing the activation barrier.As expected,the proof-of-concept system achieves an ammonia yield rate of 168.5μg h^(-1)mg^(-1)and a Faradaic efficiency of 75.3%at-0.3 V vs.RHE.This system-level approach opens up pathways for tackling the two key challenges that have limited the field of ammonia synthesis.
基金jointly supported by the National Key R&D Program of China (Grant No.2021YFB2600700)the Central PublicInterest Scientific Institution Basal Research Fund of China (Grant Nos.Y221007 and Y223005)。
文摘Serious ice accumulating,pile-up and ice jamming occur around the conductor array of offshore jacket platforms during the winter every year in Bohai Sea,which could cause grave threats to the stability of platform structure,the safety of people and equipment,and even severer calamity.Therefore,the process of ice accumulation and ice jamming in the jacket platform area needs more concern.This study focuses on ice accumulation and jamming behaviors in the jacket platform conductor area by using a coupled two-dimensional hydro-ice dynamics model.A series of cases are conducted with different flow conditions,such as flow velocity,drifting direction and oscillatory flow.Through the simulation,the ice pile-up process is described and changes in ice-jamming thickness,ice pile-up location and ice pile-up volume are investigated.The differences in ice pile-up in the steady flow and oscillatory flow are analyzed.This study proposes a new approach to simulate the ice jamming process in the jacket platform conductor area,providing a reference for ice management on the platform.
基金This work was supported in part by the National Natural Science Foundation of China[Grant No.51867013].
文摘Turbulence is expected to play a relevant role in the so-called conductor gallop phenomena,namely,the high-amplitude,low-frequency oscillation of overhead power lines due to the formation of ice structures and the ensu-ing effect that wind can have on these.In this work,the galloping time history of a wire with distorted(fixed in time)shape due to the formation of ice is analyzed numerically in the frame of afluid-solid coupling method for different wind speeds and levels of turbulence.The results show that the turbulence intensity has a moderate effect on the increase of the conductor’s aerodynamic lift and drag coefficients due to ice accretion;nevertheless,the corresponding changes in the torsion coefficient are very significant and complicated.A high turbulence intensity can affect the torsion coefficient in a certain range of attack angles and increase the torsion angle of the conductor.Through comparison of the galloping phenomena for different wind velocities,it is found that the related amplitude grows significantly with an increase of the wind speed.For a relatively large wind speed,the galloping amplitude is more sensitive to the turbulence intensity.Moreover,the larger the turbulence intensity,the larger the conductor’s vertical and horizontal galloping amplitudes after icing.The torsion angle also increases with an increase in the wind speed and turbulence intensity.
基金financially supported by the National Natural Science Foundation of China (Grant Nos.51434009 and 51221003)。
文摘A novel expandable conductor was designed and applied in deep-water drilling to improve the vertical and lateral bearing capacity with a significant reduction of conductor jetting depth and soaking time. The vertical and lateral bearing capability of expandable conductors was depicted based on the ultimate subgrade reaction method and pile foundation bearing theory. The load-bearing characteristics of a laboratory-scale expandable conductor were analyzed through laboratory experiments. The serial simulation experiments are accomplished to study the bearing characteristics(vertical ultimate bearing capacity, lateral soil pressure, and lateral displacement) during the conductor soaking process. The laboratory experimental results show that the larger the length and thickness of expandable materials are,the higher the bearing capacity of the wellhead will be. During the conductor soaking process, the soil pressure around the three expandable conductors increases faster, strings representing a stronger squeezing effect and resulting in higher vertical bearing capacity. Furthermore, the lateral displacement of novel expandable conductor is smaller than that of the conventional conductor. All the advantages mentioned above contributed to the reduction of conductor’s jetting depth and soaking time. Lastly, the application workflow of a novel expandable deep-water drilling conductor was established and the autonomous expandable conductor was successfully applied in the South China Sea with a significant reduction of conductor’s jetting depth and soaking time. According to the soil properties and designed installation depth of the surface conductor, the arrangement of expandable materials should be designed reasonably to meet the safety condition and reduce the construction cost of the subsea wellhead.
基金supported by the 21C Innovation Laboratory,Contemporary Amperex Technology Ltd by project No.21C-OP-202004,the Ningbo S&T Innovation 2025 Major Special Program(Grant No.2018B10061,2018B10087,2019B10044,and 2020Z101)the National Key R&D Program of China(Grant No.2018YFB0905400).
文摘Severe lithium(Li)dendrite growth caused by the uneven overpotential deposition is a formidable challenge for high energy density Li metal batteries(LMBs).Herein,we investigate a synergetic interfacial kinetic to regulate Li deposition behavior and stabilize Li metal anode.Through constructing Li alloying matrix with a bi-functional silver(Ag)-Li_(3)N blended interface,fast Li^(+)conductivity and high Li affinity can be achieved simultaneously,resulting in both decreased Li nucleation and mass transfercontrolled overpotentials.Beyond these properties,a more important feature is demonstrated herein;that is,the inward diffusion depth of the Li adatoms inside of the Ag site can be restricted by the Li^(+)solvation structure in a highly coordinating environment.The latter feature can ensure the durability of the operational Ag sites,thereby elongating the Li protection ability of the Ag-Li_(3)N interface greatly.This work provides a deep insight into the synergetic effect of functional alloying structure and Li^(+)solvation mediated interfacial kinetic on Li metal protection.
基金supported by the Aeronautical Science Foundation of China(No.201944057001)the National Key Research and Development Program of China(No.2017YFC1501506).
文摘A floating conductor exhibits a bipolar corona phenomenon with microscopic discharge characteristics that are still unclear.In this study,a plasma simulation model of the bipolar corona with 108 chemical reaction equations is established by combining hydrodynamics and plasma chemical reactions.The evolution characteristics of electrons,positive ions,negative ions and neutral particles,as well as the distribution characteristics of space charges are analyzed,and the evolutionary flow of microscopic particles is summarized.The results indicate that the positive end of the bipolar corona initiates discharge before the negative end,but the plasma chemistry at the negative end is more vigorous.The electron generation rate can reach 1240 mol(m^(3) s)^(-1),and the dissipation rate can reach 34 mol(m^(3) s)^(-1).The positive ion swarm is dominated by O_(4)^(+),and the maximum generation rate can reach 440 mol((m^(3) s)^(-1).The negative ion swarm is mainly O_(2) and O_(4).The O_(2) content is approximately 1.5-3 times that of O_(4),and the maximum reaction rate can reach 51 mol(m^(3) s)^(-1).The final destination of neutral particles is an accumulation in the form of O_(3) and NO,and the amount of O3 produced is approximately 4-6 times that of NO.The positive end of the bipolar corona is dominated by positive space charges,which continue to develop and spread outwards in the form of a pulse wave.The negative end exhibits a space charge distribution structure of concentrated positive charges and diffused negative charges.The validity of the microscopic simulation analysis is verified by the macroscopic discharge phenomenon.
基金supported by the National Natural Science Foundation of China(No.52007138)the Natural Science Basis Research Plan in Shaanxi Province of China(No.2022JQ-568)the Key Research and Development Program of Shaanxi Province(No.2023-YBGY-069).
文摘In the harsh environment,the structural health of the anti-vibration hammer,which suffers from the coupled effects of corrosion and fatigue damage,is significantly reduced.As part of the conductor structure,the anti-vibration hammer is rigidly attached to the conductor,effectively suppressing conductor vibration.The conductor’s breeze vibration law and natural modal frequency are altered damage to the anti-vibration hammer structure.Through built a vibration experiment platform to simulate multiple faults such as anti-vibration hammer head drop off and position slippage,which to obtained the vibration acceleration signal of the conductor.The acceleration vibration signal is processed and analyzed in the time and frequency domains.The results are used to derive the breeze vibration law of the conductor under multiple faults and propose an anti-vibration hammer damage online monitoring technology.The results show that the vibration acceleration value and vibration intensity of the conductor are significantly increased after the anti-vibration hammer damage.The natural frequency increases for each order,with an absolute change ranging from 0.15 to 6.49 Hz.The anti-vibration hammer slipped due to a loose connection,the 1st natural frequency increases from 8.18 to 16.62 Hz.Therefore,in engineering applications,there can be no contact to determine the anti-vibration hammer damage situation by monitoring the modal natural frequency of the conductor.This is even a tiny damage that cannot be seen.This method will prevent the further expansion of the damage that can cause accidents.
