Based on experiments and first-principles calculations,the microstructures and mechanical properties of as-cast and solution treated Mg-10Gd-4Y-xZn-0.6Zr(x=0,1,2,wt.%)alloys are investigated.The transformation process...Based on experiments and first-principles calculations,the microstructures and mechanical properties of as-cast and solution treated Mg-10Gd-4Y-xZn-0.6Zr(x=0,1,2,wt.%)alloys are investigated.The transformation process of long-period stacking ordered(LPSO)structure during solidification and heat treatment and its effect on the mechanical properties of experimental alloys are discussed.Results reveal that the stacking faults and 18R LPSO phases appear in the as-cast Mg-10Gd-4Y-1Zn-0.6Zr and Mg-10Gd-4Y-2Zn-0.6Zr alloys,respectively.After solution treatment,the stacking faults and 18R LPSO phase transform into 14H LPSO phase.The Enthalpies of formation and reaction energy of 14H and 18R LPSO are calculated based on first-principles.Results show that the alloying ability of 18R is stronger than that of 14H.The reaction energies show that the 14H LPSO phase is more stable than the 18R LPSO.The elastic properties of the 14H and 18R LPSO phases are also evaluated by first-principles calculations,and the results are in good agreement with the experimental results.The precipitation of LPSO phase improves the tensile strength,yield strength and elongation of the alloy.After solution treatment,the Mg-10Gd-4Y-2Zn-0.6Zr alloy has the best mechanical properties,and its ultimate tensile strength and yield strength are 278.7 MPa and 196.4 MPa,respectively.The elongation of Mg-10Gd-4Y-2Zn-0.6Zr reaches 15.1,which is higher than that of Mg-10Gd-4Y0.6Zr alloy.The improving mechanism of elastic modulus by the LPSO phases and the influence on the alloy mechanical properties are also analyzed.展开更多
采用降温往复镦粗-挤压的方法对Mg-12.5Gd-4Y-2Zn-0.5Zr(wt%)合金进行了大塑性变形.总变形道次为5道次,累积应变为6.75,温度由480℃逐道次降低到390℃.利用光学显微镜、扫描电子显微镜和X射线衍射仪研究了合金在不同变形道次下微观组织...采用降温往复镦粗-挤压的方法对Mg-12.5Gd-4Y-2Zn-0.5Zr(wt%)合金进行了大塑性变形.总变形道次为5道次,累积应变为6.75,温度由480℃逐道次降低到390℃.利用光学显微镜、扫描电子显微镜和X射线衍射仪研究了合金在不同变形道次下微观组织的演变规律.结果表明:该方法可以有效细化Mg-12.5Gd-4Y-2Zn-0.5Zr合金晶粒,随变形道次的增加,晶粒细化效果逐渐减弱.5道次变形后得完全再结晶的细小晶粒组织,平均晶粒尺寸由初始态的64.2μm减小到4.4μm.此外,随着变形道次的增加,原始晶粒内的片层状长周期堆垛有序结构(Long Period Stacking Ordered Structure,LPSO结构)逐渐溶解消失,同时,在动态再结晶晶粒界处析出大量细小颗粒状β-Mg5(Gd,Y,Zn)相.另外,原始组织中沿晶界不连续网状分布的块状LPSO相发生剧烈扭折变形,逐渐破碎成小块并均匀地沿挤压方向排列.展开更多
基金supported by the National Key Research and Development Program of China[grant No.2018YFB2001800]National Natural Science Foundation of China[grant No.51871184]Dalian High-level Talents Innovation Support Program[grant No.2021RD06]。
文摘Based on experiments and first-principles calculations,the microstructures and mechanical properties of as-cast and solution treated Mg-10Gd-4Y-xZn-0.6Zr(x=0,1,2,wt.%)alloys are investigated.The transformation process of long-period stacking ordered(LPSO)structure during solidification and heat treatment and its effect on the mechanical properties of experimental alloys are discussed.Results reveal that the stacking faults and 18R LPSO phases appear in the as-cast Mg-10Gd-4Y-1Zn-0.6Zr and Mg-10Gd-4Y-2Zn-0.6Zr alloys,respectively.After solution treatment,the stacking faults and 18R LPSO phase transform into 14H LPSO phase.The Enthalpies of formation and reaction energy of 14H and 18R LPSO are calculated based on first-principles.Results show that the alloying ability of 18R is stronger than that of 14H.The reaction energies show that the 14H LPSO phase is more stable than the 18R LPSO.The elastic properties of the 14H and 18R LPSO phases are also evaluated by first-principles calculations,and the results are in good agreement with the experimental results.The precipitation of LPSO phase improves the tensile strength,yield strength and elongation of the alloy.After solution treatment,the Mg-10Gd-4Y-2Zn-0.6Zr alloy has the best mechanical properties,and its ultimate tensile strength and yield strength are 278.7 MPa and 196.4 MPa,respectively.The elongation of Mg-10Gd-4Y-2Zn-0.6Zr reaches 15.1,which is higher than that of Mg-10Gd-4Y0.6Zr alloy.The improving mechanism of elastic modulus by the LPSO phases and the influence on the alloy mechanical properties are also analyzed.
文摘采用降温往复镦粗-挤压的方法对Mg-12.5Gd-4Y-2Zn-0.5Zr(wt%)合金进行了大塑性变形.总变形道次为5道次,累积应变为6.75,温度由480℃逐道次降低到390℃.利用光学显微镜、扫描电子显微镜和X射线衍射仪研究了合金在不同变形道次下微观组织的演变规律.结果表明:该方法可以有效细化Mg-12.5Gd-4Y-2Zn-0.5Zr合金晶粒,随变形道次的增加,晶粒细化效果逐渐减弱.5道次变形后得完全再结晶的细小晶粒组织,平均晶粒尺寸由初始态的64.2μm减小到4.4μm.此外,随着变形道次的增加,原始晶粒内的片层状长周期堆垛有序结构(Long Period Stacking Ordered Structure,LPSO结构)逐渐溶解消失,同时,在动态再结晶晶粒界处析出大量细小颗粒状β-Mg5(Gd,Y,Zn)相.另外,原始组织中沿晶界不连续网状分布的块状LPSO相发生剧烈扭折变形,逐渐破碎成小块并均匀地沿挤压方向排列.
