The Tongling area is one of the 7 ore-cluster areas in the Middle-Lower Yangtze metallogenic belt, East China, and has tectonically undergone a long-term geologic history from the late Paleozoic continental rifting, t...The Tongling area is one of the 7 ore-cluster areas in the Middle-Lower Yangtze metallogenic belt, East China, and has tectonically undergone a long-term geologic history from the late Paleozoic continental rifting, through the Middle Triassic continent-continent collision to the Jurassic-Cretaceous intracontinental tectono-magmatic activation. The Carboniferous sedimentary-exhalative processes in the area produced widespread massive sulfides with ages of 303-321 Ma, which partly formed massive pyrite-Cu deposits, but mostly provided significant sulfur and metals to the skarn Cu mineralization associated with the Yanshanian felsic intrusions.To understand the Carboniferous submarine hydrothermal system, an area of about 1046 km^2 was chosen to carry out the geological fluid mapping. Associated with massive sulfide formation, footwall sequences 948 m to 1146 m thick, composed of the Lower Silurian-Upper Devonian sandstone, siltstone and thin-layered shale, were widely altered. This hydrothermal alteration is interpreted to reflect largescale hydrothermal fluid flow associated with the late Paleozoic crustal rifting and subsidence. Three hydrothermal alteration types, i.e., deep-level semiconformable siliclfication （S1）, fracture-controlled quartz-sericite-pyrite alteration （S2-3）, and upper-level sub-discordant quartz-sericite-chlorite alteration （D3）, were developed to form distinct zones in the mapped area. About 50-m thick semiconformable silicification zones are located at -1-km depth below massive sulfides and developed between an impermeable shale caprock （S1） and the underlying Ordovician unaltered limestone. Comparisons with modern geothermal systems suggest that the alteration zones record a sub-seafioor aquifer with the most productive hydrothermal fluid flow. Fracture-controlled quartz-sericite-pyrite alteration formed transgressive zones, which downward crosscut the semiconformable alteration zones, and upwards grade into sub-discordant alteration zones that enveloped no economic stringer- stockwork zones beneath massive sulfides. This transgressive zone likely marks an upfiow path of high- flux fluids from the hydrothermal aquifer. Lateral zonation of the sub-discordant alteration zones and their relationship to overlying massive sulfide lenses suggest lateral flows and diffusive discharging of the hydrothermal fluids in a permeable sandstone sequence. Three large-sized, 14 middle-small massive sulfide deposits, and 40 massive sulfide sites have been mapped in detail. They show regional strata- bound characters and two major styles, i.e., the layered sheet plus strata-bound stringer-style and the mound-style. Associated exhalite and chemical sedimentary rock suites include （1） anhydrite-barite, （2） jasper-chert, （3） Mg-rich mudstone-pyrite shale, （4） barite lens, （5） siderite-Fe-bearing dolomite, and （6） Mn-rich shale-mudstone, which usually comprise three sulfide-exhalite cyclic units in the area.The spatial distribution of these alteration zones （minerals） and associated massive sulfdes and exhalites, and regional variation in δ^34S of hydrothermal pyrite and in δ^18O-δ^34C of hanging wall carbonates, suggest three WNW-extending domains of fluid flow, controlled by the basement faults and syn-depositional faults. Each fluid domain appears to have at least two upflow zones, with estimated even spacing of about 5-8 km in the mapped area. The repeated appearance of sulfide-sulfate or sulfide-carbonate rhythmic units in the area suggests episodically venting of fluids through the upfiow conduits by breaking the overlying seals of the hydrothermal aquifer.展开更多
Micromotion is the daily tiny vibration of the earth</span><span style="font-family:Verdana;">’</span><span style="font-family:Verdana;">s surface. Micromotional exploratio...Micromotion is the daily tiny vibration of the earth</span><span style="font-family:Verdana;">’</span><span style="font-family:Verdana;">s surface. Micromotional exploration can use the surface wave information of micro motion to study the shallow structure of underground media. In this study, we collected microtremor data at 68 stations in the Middle-Lower Yangtze Metallogenic Belt (MLYMB) and determined the resonant frequency and obtained the distribution of sedimentary thickness in this area by using H/V spectral ratio. According to the results of H/V, the sedimentary layer in the basin is thick, and the predominant frequency of the basin is 0.05</span><span style="font-family:""> </span><span style="font-family:Verdana;">-</span><span style="font-family:""> </span><span style="font-family:Verdana;">0.1</span><span style="font-family:""> </span><span style="font-family:Verdana;">Hz. There are no obvious lateral changes in the impedance interface between bedrock and sedimentary layer in this area. The basement of Tongling, Anqing and Luzhou mining areas and their adjacent areas is Kongling-Dongling type basement, which is composed of a set of metamorphic core complex. The predominant frequency is 0.05</span><span style="font-family:""> </span><span style="font-family:Verdana;">-</span><span style="font-family:""> </span><span style="font-family:Verdana;">0.1</span><span style="font-family:""> </span><span style="font-family:Verdana;">Hz. The sedimentary thickness gradually thinned from 3800</span><span style="font-family:""> </span><span style="font-family:Verdana;">m in the west to 2100</span><span style="font-family:""> </span><span style="font-family:Verdana;">m in the East. Moreover, this article used SPAC (spatial autocorrelation) method to obtain the S-wave velocity structure of the mining area near Luzong. The SPAC method reveals that the depth of the interface between the loose sediments and the volcanic rocks is about 600 m in the study area near the Luzhou mining area in the Middle-Lower Yangtze Metallogenic Belt, and the average depth of the interface between the volcanic rock section and the intrusive complex section is about 1000</span><span style="font-family:""> </span><span style="font-family:Verdana;">m. The thickness of the intrusive rock is more than 2500</span><span style="font-family:""> </span><span style="font-family:Verdana;">m. Tourmaline is developed in the interior of the intrusive rock, which may have better exploration value.展开更多
The Tongshankou Cu-Mo deposit, located in southeast Hubei province, is a typical skarn–porphyry type ore deposit closely related to the Tongshankou granodiorite porphyry, characterized by a high Sr/Y ratio.Detailed i...The Tongshankou Cu-Mo deposit, located in southeast Hubei province, is a typical skarn–porphyry type ore deposit closely related to the Tongshankou granodiorite porphyry, characterized by a high Sr/Y ratio.Detailed in situ analyses of the trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry were performed.Scarcely any inherited zircons were observed, and the analyzed zircons yielded highly concordant results with a weighted mean 206Pb/238 U age of 143.5 ± 0.45 Ma（n=20, mean square weighted deviation was 0.75）, which was interpreted to represent the crystallization age of the Tongshankou granodiorite porphyry.The chondrite-normalized rare-earth element pattern was characterized by a slope that steeply rises from the light-group rare-earth elements（LREE） to the heavy-group rare-earth elements（HREE） with a positive Ce-anomaly and inconspicuous Eu-anomaly, which was coincident with the pattern of the zircons from the Chuquicamata West porphyry, Chile.The analyzed zircons also had relatively low 176Hf/177 Hf ratios of 0.282526–0.282604.Assuming t=143 Ma, the corresponding calculated initial Hf isotope compositions（εHf（t）） ranged from-5.6 to-2.9.The results of the in situ analysis of trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry suggest that a deep-seated process involving a thickened-crust/enriched-mantle interaction may play an important role in the generation of high Sr/Y-ratio magma and potentially in the generation of porphyry Cu-Mo systems.展开更多
The Magushan skarn Cu-Mo deposit is a representative example of the skarn mineralization occurring within the Xuancheng ore district of the Middle-Lower Yangtze River Metallogenic Belt of eastern China.The precise age...The Magushan skarn Cu-Mo deposit is a representative example of the skarn mineralization occurring within the Xuancheng ore district of the Middle-Lower Yangtze River Metallogenic Belt of eastern China.The precise age of an ore deposit is important for understanding the timing of mineralization relative to other geological events in a region and to fully place the formation of a mineral deposit within the geological context of other processes that occur within the study area.Here,we present new molybdenite Re-Os and titanite and andradite garnet U-Pb ages for the Magushan deposit and use these data to outline possible approaches for identifying genetic relationships in geologically complex areas.The spatial and paragenetic relationships between the intrusions,alteration,and mineralization within the study area indicates that the formation of the Magushan deposit is genetically associated with the porphyritic granodiorite.However,this is not always the case,as some areas contain complexly zoned plutons with multiple phases of intrusion or mineralization may be distal from or may not have any clear spatial relationship to a pluton.This means that it may not be possible to determine whether the mineralization formed as a result of single or multiple magmatic/hydrothermal events.As such,the approaches presented in this study provide an approach that allows the identification of any geochronological relationships between mineralization and intrusive events in areas more complex than the study area.Previously published zircon U-Pb data for the mineralization-related porphyritic granodiorite in this area yielded an age of 134.2±1.2 Ma(MSWD=1.4)whereas the Re-Os dating of molybdenite from the study area yielded an isochron age of 137.7±2.5 Ma(MSWD=0.43).The timing of the mineralizing event in the study area was further examined by the dating of magmatic accessory titanite and skarn-related andradite garnet,yielding U-Pb ages of 136.3±2.5 Ma(MSWD=3.2)and 135.9±2.7 Ma(MSWD=2.5),respectively.The dating of magmatic and hydrothermal activity within the Magushan area yields ages around 136 Ma,strongly suggesting that the mineralization in this area formed as a result of the emplacement of the intrusion.The dates presented in this study also provide the first indication of the timing of mineralization within the Xuancheng district.providing evidence of a close genetic relationship between the formation of the mineralization within the Xuancheng district and the Early Cretaceous magmatism that occurred in this area.This in turn suggests that other Early Cretaceous intrusive rocks within this region are likely to be associated with mineralization and should be considered highly prospective for future mineral exploration.This study also indicates that the dating of garnet and titanite can also provide reliable geochronological data and evidence of the timing of mineralization and magmatism,respectively,in areas lacking other dateable minerals(e.g.,molybdenite)or where the relationship between mineralization and magmatism is unclear,for example in areas with multiple stages of magmatism,with complexly zoned plutons,and with distal skarn mineralization.展开更多
The Middle-Lower Yangtze River Metallogenic Belt(MLYB)is known to contain abundant copper and iron porphyry-skarn deposits,with an increasing number of tungsten deposits and scheelite in Fe-Cu deposits being discovere...The Middle-Lower Yangtze River Metallogenic Belt(MLYB)is known to contain abundant copper and iron porphyry-skarn deposits,with an increasing number of tungsten deposits and scheelite in Fe-Cu deposits being discovered in the MLYB during recent decades.The ore genesis of the newly-discovered tungsten mineralization in the MLYB is poorly understood.We investigate four sets of scheelite samples from tungsten,iron and copper deposits,using CL imaging and LA-ICP-MS techniques to reveal internal zonation patterns and trace element compositions.The REE distribution patterns of four studied deposits show varying degrees of LREE enrichment with negative Eu anomalies.The oxygen fugacity of ore-forming fluid increased in Donggushan,while the oxygen fugacity of ore-forming fluid decreased in Ruanjiawan,Guilinzheng and Gaojiabang.The scheelites from the Donggushan,Ruanjiawan,Guilinzheng and Gaojiabang deposits show enrichment in LREEs and HFSE,with Nb/La ratios ranging from 1.217 to 52.455,indicating that the four tungsten deposits are enriched in the volatile fluorine.A plot of(La/Lu)N versus Mo/δEu can be used to distinguish quartz vein type,porphyry and skarn tungsten deposits.This study demonstrates that scheelite grains can be used to infer tungsten mineralization and are effective in identifying magmatic types of tungsten deposits in prospective mining sites.展开更多
The newly discovered Yangchongli gold deposit is a unique independent gold deposit in the Tongling ore-cluster region controlled by the tectonic alteration firstly discovered in the Lower Yangtze Metallogenic Belt （L...The newly discovered Yangchongli gold deposit is a unique independent gold deposit in the Tongling ore-cluster region controlled by the tectonic alteration firstly discovered in the Lower Yangtze Metallogenic Belt （LYMB）. The host magmatic rocks mainly consist of monzodiorite and K-feldspar granite. The LA-ICP-MS U-Pb zircons dating yielded weighted mean 206pb/23SU ages of 140.7 ± 1.8 Ma and 126.4 ±1.2 Ma for the monzodiorite and K-feldspar granite, respectively. Monzodiorites are enriched in Sr, Ba, Rb, and depleted in Y, Yb with high Sr/Y and La/Yb ratios, similar to the geochemical features of adakite, considered as products of differentiation of mafic magmas originating from lithospheric mantle melt/fluids caused by metasomatism during paleo-Pacific Plate subduction in the Mesozic. In contrast, the compositions of K-feldspar granites are A-type granites, indicating an extensional tectonic background. Gold ores hosted in the fracture zone occurred as quartz vein within cataclastic rock. Sulfur and lead isotopes from pyrites show crust-mantle mixing characteristics. Metal components from strata also took part in the gold mineralization, and resulted from two episodes of magmatism that were probably related to tectonic transition from a compressive to an extensional setting between 140-126 Ma, which led to the Mesozoic large-scale polymetallic mineralization events in eastern China.展开更多
The newly discovered Paodaoling porphyry Au deposit from the Guichi region, Lower Yangtze River Metallogenic Belt （LYRB）, contains 〉35 tons of Au at an average grade of -1.7 g/t. It is a porphyry ＇Au-only＇ deposi...The newly discovered Paodaoling porphyry Au deposit from the Guichi region, Lower Yangtze River Metallogenic Belt （LYRB）, contains 〉35 tons of Au at an average grade of -1.7 g/t. It is a porphyry ＇Au-only＇ deposit, as revealed by current exploration in the depths, mostly above -400 m, which is quite uncommon among coeval porphyry mineralization along the LYRB. Additionally, there are also Cu-Au bearing porphyries and barren alkaline granitoids in the Paodaoling district. Zircon LA-ICP-MS U-Pb dating of the Cu-Au-bearing porphyries yield an age of 141-140 Ma, falling within the main magmatic stage of the LYRB, whereas the barren granites give an age of 125-120 Ma, coeval with the regional A- type granites. The Cu-Au-bearing porphyries are LILE-, LREE-enriched and HFSE-depleted, typical of arc magmatic affinities. The barren granites are HFSE-enriched, with lower LREE/HREE ratios and pronounced negative Eu anomalies. The Cu-Au-bearing porphyries in the Paodaoling district have high oxygen fugacities and high water content. Pyrite sulfur isotopes of the Paodaoling gold deposit indicate a magmatic-sedimentary mixed source for the ore-forming fluids. Based on the alteration and poly-metal zonation of the deepest exploration drill hole from the Paodaoling Au deposit, we propose that Cu ore bodies could lie at depth beneath the current Au ore bodies. The magmatism and associated Cu-Au mineralization of the Paodaoling district are likely to have formed in a subduction setting, during slab rollback of the paleo-Pacific plate.展开更多
Studies of the Pb, Sr and Nd isotopic composition of Mesozoic intrusive rocks indicate that the basement of the copper-gold metallogenic belt of the middle and lower reaches of the Yangtze River has “two-layer struct...Studies of the Pb, Sr and Nd isotopic composition of Mesozoic intrusive rocks indicate that the basement of the copper-gold metallogenic belt of the middle and lower reaches of the Yangtze River has “two-layer structure” and partly has “multi-layered structure”, and is inhomogeneous and shows the distinct feature of E-W provincialism. The calculated model lead ages (t1) are mostly greater than 2600 Ma, and the model neodymium ages (TDM) vary from 953 to 2276 Ma and concentrate in two time intervals: 1800–2000 Ma and 1200–1600 Ma. It is concluded that the basement of the MBYR is composed of the Late Archaeozoic to Middle Proterozoic metamorphic series and that the crust was initiated in the Archaean and continued to grow in the Early and Middle Proterozoic, and the proportion of new crust formed by mantle differentiation during the Late Proterozoic is low.展开更多
In this study,we compiled and analyzed 69310 P-wave travel-time data from 6639 earthquake events.These events(M≥2.0)occurred from 1980 s to June 2019 and were recorded at 319 seismic stations(Chinese Earthquake Netwo...In this study,we compiled and analyzed 69310 P-wave travel-time data from 6639 earthquake events.These events(M≥2.0)occurred from 1980 s to June 2019 and were recorded at 319 seismic stations(Chinese Earthquake Networks Center)in the study area.We adopted the double-difference seismic tomographic method(tomo DD)to invert the 3-D P-wave velocity structure and constrain the crust-upper mantle architecture of the Middle and Lower Reaches of the Yangtze River Metallogenic Belt(MLYB).A 1-D initial model extracted from wide-angle seismic profiles was used in the seismic tomography,which greatly reduced the inversion residual.Our results indicate that reliable velocity structure of th e uppermost mantle can be obtained when Pn is involved in the tomography.Our results show that:(1)the pattern of the uppermost mantle velocity structure corresponds well with the geological partitioning:a nearly E-W-trending low-velocity zone is present beneath the Dabie Orogen,in contrast to the mainly NE-trending low-velocity anomalies beneath the Jiangnan Orogen.They suggest the presence of thickened lower crust beneath the orogens in the study area.In contrast,the Yangtze and Cathaysia blocks are characterized by relatively high-velocity anomalies;(2)both the ultra-high-pressure(UHP)metamorphic rocks in the Dabie Orogen and the low-pressure metamorphic rocks in the Zhangbaling dome are characterized by high-velocity anomalies.The upper crust in the Dabie Orogen is characterized by a low-velocity belt,sandwiched between two high velocity zones in a horizontal direction,with discontinuous low-velocity layers in the middle crust.The keel of the Dabie Orogen is mainly preserved beneath its northern section.We infer that the lower crustal delamination may have mainly occurred in the southern Dabie Orogen,which caused the mantle upwelling responsible for the formation of the granitic magmas emplaced in the middle crust as the low-velocity layers observed there.Continuous deep-level compression likely squeezed the granitic magma upward to intrude the upper crustal UHP metamorphic rocks,forming the'sandwich'velocity structure there;(3)high-velocity updoming is widespread in the crust-mantle transition zone beneath the MLYB.From the Anqing-Guichi ore field northeastward to the Luzong,Tongling,Ningwu and Ningzhen orefields,high-velocity anomalies in the crust-mantle transition zone increase rapidly in size and are widely distributed.The updoming also exists in the crust-mantle transition zone beneath the Jiurui and Edongnan orefields,but the high-velocity anomalies are mainly stellate distributed.The updoming high-velocity zone beneath the MLYB generally extends from the crust-mantle transition zone to the middle crust,different from the velocity structure in the upper crust.The upper crust beneath the Early Cretaceous extension-related Luzong and Ningwu volcanic basins is characterized by high velocity zones,in contrast to the low velocity anomalies beneath the Late Jurassic to Early Cretaceous compression-related Tongling ore field.The MLYB may have undergone a compressive-to-extensional transition during the Yanshanian(Jurassic-Cretaceous)period,during which extensive magmatism occurred.The near mantle-crustal boundary updoming was likely caused by asthenospheric underplating at the base of the lower crust.The magmas may have ascended through major crustal faults,undergoing AFC(assimilation and fractional crystallization)processes,became emplaced in the fault-bounded basins or Paleozoic sequences,eventually forming the many Cu-Fe polymetallic deposits there.展开更多
The Nanling-Xuancheng ore region of Anhui Province is located in the Middle-Lower Yangtze River metallogenic belt.Insufficient exploration and research have been carried out in this newly defined ore district,although...The Nanling-Xuancheng ore region of Anhui Province is located in the Middle-Lower Yangtze River metallogenic belt.Insufficient exploration and research have been carried out in this newly defined ore district,although the Chating large porphyry Cu-Au deposit and a few middle-sized skarntype Cu polymetallic deposits have been discovered.In this study,we carried out high-resolution seismic reflection,magnetotelluric,gravity,and magnetic investigations,and constructed the 3 D geological structure of the uppermost crust in a depth range of 0-5 km using a comprehensive inversion of the new data constrained by previous deep-drilling data.We hence proposed some new insights to understand the mineralization processes of this district.A system of alternating ridges and valleys is suggested as the major structure pattern,composed of“two-layer structure”of the basins and“three-layer structure”of anticlines.Moreover,a conjugated fault system and its distribution features are revealed in our models,including the Jiangnan fault,Zhouwang fault,and Kunshan thrust nappe.The Jiangnan and Kunshan faults are suggested to have controlled the diagenesis and metallogenesis.Two deep concealed plutons located in Chating and Magushan are found,forming the Mesozoic diorite-felsic intrusions.These intrusions are believed to be the causes of hydrothermal deposits such as the Chating deposit and the Magushan deposit.展开更多
The Middle-Lower Yangtze River Metallogenic Belt(MLYMB) is an important mineral resource region in China.High-resolution crustal models can provide crucial constraints to understand the ore-forming processes and geody...The Middle-Lower Yangtze River Metallogenic Belt(MLYMB) is an important mineral resource region in China.High-resolution crustal models can provide crucial constraints to understand the ore-forming processes and geodynamic setting in this region. Using ambient seismic noise from 107 permanent and 82 portable stations in the MLYMB and the adjacent area,we present a new high-resolution 3D S-wave velocity model of this region. We first extract 5–50 s Rayleigh wave phase velocity dispersion data by calculating ambient noise cross-correlation functions(CFs) and then use the surface wave direct inversion method to invert the mixed path travel times for the 3D S-wave velocity structure. Checkerboard tests show that the horizontal resolution of the 3D S-wave velocity model is approximately 0.5°–1.0° and that the vertical resolution decreases with increasing noise and depth. Our high-resolution 3D S-wave velocity model reveals:(1) AV-shaped high-velocity zone(HVZ) is located in the lower crust and the uppermost mantle in the study region. The western branch of the HVZ passes through the Jianghan Basin,the Qinling-Dabie orogenic belt and the Nanxiang Basin. The eastern branch, which almost completely covers the main body of the MLYMB, is located near the Tanlu Fault. The low-velocity anomalies between the western and eastern branches are located in the area of the Qinling-Dabie orogenic belt.(2) High-velocity uplifts(HVUs) are common in the crust of the MLYMB,especially in the areas near the Tanlu Fault, the Changjiang Fault and the Yangxin-Changzhou Fault. The intensities of the HVUs gradually weaken from west to east. The V-shaped HVZ in the lower crust and uppermost mantle and the HVUs in the middle and lower crust likely represent cooled mantle intrusive rocks. During the Yanshanian period, fault systems formed in the MLYMB due to the convergence between the South China Plate and the North China Plate, the multiple-direction drifting of the PaleoPacific Plate and its subduction beneath the Eurasian Plate. The dehydration of the cold oceanic crust led to partial melting in the upper mantle. Temperature differences caused strong convection of the upper mantle material that underplated the lower crust and rose to near the surface along the deep fault systems. After mixing with the crustal materials, mineralization processes, such as assimilation and fractional crystallization, occurred in the MLYMB.展开更多
文摘The Tongling area is one of the 7 ore-cluster areas in the Middle-Lower Yangtze metallogenic belt, East China, and has tectonically undergone a long-term geologic history from the late Paleozoic continental rifting, through the Middle Triassic continent-continent collision to the Jurassic-Cretaceous intracontinental tectono-magmatic activation. The Carboniferous sedimentary-exhalative processes in the area produced widespread massive sulfides with ages of 303-321 Ma, which partly formed massive pyrite-Cu deposits, but mostly provided significant sulfur and metals to the skarn Cu mineralization associated with the Yanshanian felsic intrusions.To understand the Carboniferous submarine hydrothermal system, an area of about 1046 km^2 was chosen to carry out the geological fluid mapping. Associated with massive sulfide formation, footwall sequences 948 m to 1146 m thick, composed of the Lower Silurian-Upper Devonian sandstone, siltstone and thin-layered shale, were widely altered. This hydrothermal alteration is interpreted to reflect largescale hydrothermal fluid flow associated with the late Paleozoic crustal rifting and subsidence. Three hydrothermal alteration types, i.e., deep-level semiconformable siliclfication （S1）, fracture-controlled quartz-sericite-pyrite alteration （S2-3）, and upper-level sub-discordant quartz-sericite-chlorite alteration （D3）, were developed to form distinct zones in the mapped area. About 50-m thick semiconformable silicification zones are located at -1-km depth below massive sulfides and developed between an impermeable shale caprock （S1） and the underlying Ordovician unaltered limestone. Comparisons with modern geothermal systems suggest that the alteration zones record a sub-seafioor aquifer with the most productive hydrothermal fluid flow. Fracture-controlled quartz-sericite-pyrite alteration formed transgressive zones, which downward crosscut the semiconformable alteration zones, and upwards grade into sub-discordant alteration zones that enveloped no economic stringer- stockwork zones beneath massive sulfides. This transgressive zone likely marks an upfiow path of high- flux fluids from the hydrothermal aquifer. Lateral zonation of the sub-discordant alteration zones and their relationship to overlying massive sulfide lenses suggest lateral flows and diffusive discharging of the hydrothermal fluids in a permeable sandstone sequence. Three large-sized, 14 middle-small massive sulfide deposits, and 40 massive sulfide sites have been mapped in detail. They show regional strata- bound characters and two major styles, i.e., the layered sheet plus strata-bound stringer-style and the mound-style. Associated exhalite and chemical sedimentary rock suites include （1） anhydrite-barite, （2） jasper-chert, （3） Mg-rich mudstone-pyrite shale, （4） barite lens, （5） siderite-Fe-bearing dolomite, and （6） Mn-rich shale-mudstone, which usually comprise three sulfide-exhalite cyclic units in the area.The spatial distribution of these alteration zones （minerals） and associated massive sulfdes and exhalites, and regional variation in δ^34S of hydrothermal pyrite and in δ^18O-δ^34C of hanging wall carbonates, suggest three WNW-extending domains of fluid flow, controlled by the basement faults and syn-depositional faults. Each fluid domain appears to have at least two upflow zones, with estimated even spacing of about 5-8 km in the mapped area. The repeated appearance of sulfide-sulfate or sulfide-carbonate rhythmic units in the area suggests episodically venting of fluids through the upfiow conduits by breaking the overlying seals of the hydrothermal aquifer.
文摘Micromotion is the daily tiny vibration of the earth</span><span style="font-family:Verdana;">’</span><span style="font-family:Verdana;">s surface. Micromotional exploration can use the surface wave information of micro motion to study the shallow structure of underground media. In this study, we collected microtremor data at 68 stations in the Middle-Lower Yangtze Metallogenic Belt (MLYMB) and determined the resonant frequency and obtained the distribution of sedimentary thickness in this area by using H/V spectral ratio. According to the results of H/V, the sedimentary layer in the basin is thick, and the predominant frequency of the basin is 0.05</span><span style="font-family:""> </span><span style="font-family:Verdana;">-</span><span style="font-family:""> </span><span style="font-family:Verdana;">0.1</span><span style="font-family:""> </span><span style="font-family:Verdana;">Hz. There are no obvious lateral changes in the impedance interface between bedrock and sedimentary layer in this area. The basement of Tongling, Anqing and Luzhou mining areas and their adjacent areas is Kongling-Dongling type basement, which is composed of a set of metamorphic core complex. The predominant frequency is 0.05</span><span style="font-family:""> </span><span style="font-family:Verdana;">-</span><span style="font-family:""> </span><span style="font-family:Verdana;">0.1</span><span style="font-family:""> </span><span style="font-family:Verdana;">Hz. The sedimentary thickness gradually thinned from 3800</span><span style="font-family:""> </span><span style="font-family:Verdana;">m in the west to 2100</span><span style="font-family:""> </span><span style="font-family:Verdana;">m in the East. Moreover, this article used SPAC (spatial autocorrelation) method to obtain the S-wave velocity structure of the mining area near Luzong. The SPAC method reveals that the depth of the interface between the loose sediments and the volcanic rocks is about 600 m in the study area near the Luzhou mining area in the Middle-Lower Yangtze Metallogenic Belt, and the average depth of the interface between the volcanic rock section and the intrusive complex section is about 1000</span><span style="font-family:""> </span><span style="font-family:Verdana;">m. The thickness of the intrusive rock is more than 2500</span><span style="font-family:""> </span><span style="font-family:Verdana;">m. Tourmaline is developed in the interior of the intrusive rock, which may have better exploration value.
基金supported by geological survey projects of the China Geological Survey (1212011120863, 12120114039401, 12120114005901 and 12120115029401)
文摘The Tongshankou Cu-Mo deposit, located in southeast Hubei province, is a typical skarn–porphyry type ore deposit closely related to the Tongshankou granodiorite porphyry, characterized by a high Sr/Y ratio.Detailed in situ analyses of the trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry were performed.Scarcely any inherited zircons were observed, and the analyzed zircons yielded highly concordant results with a weighted mean 206Pb/238 U age of 143.5 ± 0.45 Ma（n=20, mean square weighted deviation was 0.75）, which was interpreted to represent the crystallization age of the Tongshankou granodiorite porphyry.The chondrite-normalized rare-earth element pattern was characterized by a slope that steeply rises from the light-group rare-earth elements（LREE） to the heavy-group rare-earth elements（HREE） with a positive Ce-anomaly and inconspicuous Eu-anomaly, which was coincident with the pattern of the zircons from the Chuquicamata West porphyry, Chile.The analyzed zircons also had relatively low 176Hf/177 Hf ratios of 0.282526–0.282604.Assuming t=143 Ma, the corresponding calculated initial Hf isotope compositions（εHf（t）） ranged from-5.6 to-2.9.The results of the in situ analysis of trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry suggest that a deep-seated process involving a thickened-crust/enriched-mantle interaction may play an important role in the generation of high Sr/Y-ratio magma and potentially in the generation of porphyry Cu-Mo systems.
基金financially supported by funds from the National Key R&D Program of China(Grant Nos.2016YFC0600209,2016YFC0600206)the National Natural Science Foundation of China(Grant No.41820104007)+1 种基金the Scientific and Technological Program of Land and Resources of Anhui province(Grant No.2016-K-4)the China Scholarship Council(Grant No.201906690036)。
文摘The Magushan skarn Cu-Mo deposit is a representative example of the skarn mineralization occurring within the Xuancheng ore district of the Middle-Lower Yangtze River Metallogenic Belt of eastern China.The precise age of an ore deposit is important for understanding the timing of mineralization relative to other geological events in a region and to fully place the formation of a mineral deposit within the geological context of other processes that occur within the study area.Here,we present new molybdenite Re-Os and titanite and andradite garnet U-Pb ages for the Magushan deposit and use these data to outline possible approaches for identifying genetic relationships in geologically complex areas.The spatial and paragenetic relationships between the intrusions,alteration,and mineralization within the study area indicates that the formation of the Magushan deposit is genetically associated with the porphyritic granodiorite.However,this is not always the case,as some areas contain complexly zoned plutons with multiple phases of intrusion or mineralization may be distal from or may not have any clear spatial relationship to a pluton.This means that it may not be possible to determine whether the mineralization formed as a result of single or multiple magmatic/hydrothermal events.As such,the approaches presented in this study provide an approach that allows the identification of any geochronological relationships between mineralization and intrusive events in areas more complex than the study area.Previously published zircon U-Pb data for the mineralization-related porphyritic granodiorite in this area yielded an age of 134.2±1.2 Ma(MSWD=1.4)whereas the Re-Os dating of molybdenite from the study area yielded an isochron age of 137.7±2.5 Ma(MSWD=0.43).The timing of the mineralizing event in the study area was further examined by the dating of magmatic accessory titanite and skarn-related andradite garnet,yielding U-Pb ages of 136.3±2.5 Ma(MSWD=3.2)and 135.9±2.7 Ma(MSWD=2.5),respectively.The dating of magmatic and hydrothermal activity within the Magushan area yields ages around 136 Ma,strongly suggesting that the mineralization in this area formed as a result of the emplacement of the intrusion.The dates presented in this study also provide the first indication of the timing of mineralization within the Xuancheng district.providing evidence of a close genetic relationship between the formation of the mineralization within the Xuancheng district and the Early Cretaceous magmatism that occurred in this area.This in turn suggests that other Early Cretaceous intrusive rocks within this region are likely to be associated with mineralization and should be considered highly prospective for future mineral exploration.This study also indicates that the dating of garnet and titanite can also provide reliable geochronological data and evidence of the timing of mineralization and magmatism,respectively,in areas lacking other dateable minerals(e.g.,molybdenite)or where the relationship between mineralization and magmatism is unclear,for example in areas with multiple stages of magmatism,with complexly zoned plutons,and with distal skarn mineralization.
基金funded by grants from the National Key Research and Development Program(2016YFC0600206)the National Natural Science Foundation of China(41872081)+1 种基金the Doctoral initial funding project of Anhui Jianzhu University(2019QDZ33)the Anhui Province Science and Technology Plan Project for Housing Urban-rural Construction(2020-YF35)。
文摘The Middle-Lower Yangtze River Metallogenic Belt(MLYB)is known to contain abundant copper and iron porphyry-skarn deposits,with an increasing number of tungsten deposits and scheelite in Fe-Cu deposits being discovered in the MLYB during recent decades.The ore genesis of the newly-discovered tungsten mineralization in the MLYB is poorly understood.We investigate four sets of scheelite samples from tungsten,iron and copper deposits,using CL imaging and LA-ICP-MS techniques to reveal internal zonation patterns and trace element compositions.The REE distribution patterns of four studied deposits show varying degrees of LREE enrichment with negative Eu anomalies.The oxygen fugacity of ore-forming fluid increased in Donggushan,while the oxygen fugacity of ore-forming fluid decreased in Ruanjiawan,Guilinzheng and Gaojiabang.The scheelites from the Donggushan,Ruanjiawan,Guilinzheng and Gaojiabang deposits show enrichment in LREEs and HFSE,with Nb/La ratios ranging from 1.217 to 52.455,indicating that the four tungsten deposits are enriched in the volatile fluorine.A plot of(La/Lu)N versus Mo/δEu can be used to distinguish quartz vein type,porphyry and skarn tungsten deposits.This study demonstrates that scheelite grains can be used to infer tungsten mineralization and are effective in identifying magmatic types of tungsten deposits in prospective mining sites.
基金supported by the DREAM project of MOST China (No.2016YFC0600404)the Natural Science Foundation of China (Grant Nos.41372087, 41673040)the Project of Geological Science and Technology of Anhui Province (2015-K-01)
文摘The newly discovered Yangchongli gold deposit is a unique independent gold deposit in the Tongling ore-cluster region controlled by the tectonic alteration firstly discovered in the Lower Yangtze Metallogenic Belt （LYMB）. The host magmatic rocks mainly consist of monzodiorite and K-feldspar granite. The LA-ICP-MS U-Pb zircons dating yielded weighted mean 206pb/23SU ages of 140.7 ± 1.8 Ma and 126.4 ±1.2 Ma for the monzodiorite and K-feldspar granite, respectively. Monzodiorites are enriched in Sr, Ba, Rb, and depleted in Y, Yb with high Sr/Y and La/Yb ratios, similar to the geochemical features of adakite, considered as products of differentiation of mafic magmas originating from lithospheric mantle melt/fluids caused by metasomatism during paleo-Pacific Plate subduction in the Mesozic. In contrast, the compositions of K-feldspar granites are A-type granites, indicating an extensional tectonic background. Gold ores hosted in the fracture zone occurred as quartz vein within cataclastic rock. Sulfur and lead isotopes from pyrites show crust-mantle mixing characteristics. Metal components from strata also took part in the gold mineralization, and resulted from two episodes of magmatism that were probably related to tectonic transition from a compressive to an extensional setting between 140-126 Ma, which led to the Mesozoic large-scale polymetallic mineralization events in eastern China.
基金supported by the National Key R&D Program of China(No.2016YFC0600404)the National Natural Science Foundation of China(Grant Nos.41673040 and 41611540339)the Project of National Land Resource Science and Technology of Anhui Province(2014-K-4)
文摘The newly discovered Paodaoling porphyry Au deposit from the Guichi region, Lower Yangtze River Metallogenic Belt （LYRB）, contains 〉35 tons of Au at an average grade of -1.7 g/t. It is a porphyry ＇Au-only＇ deposit, as revealed by current exploration in the depths, mostly above -400 m, which is quite uncommon among coeval porphyry mineralization along the LYRB. Additionally, there are also Cu-Au bearing porphyries and barren alkaline granitoids in the Paodaoling district. Zircon LA-ICP-MS U-Pb dating of the Cu-Au-bearing porphyries yield an age of 141-140 Ma, falling within the main magmatic stage of the LYRB, whereas the barren granites give an age of 125-120 Ma, coeval with the regional A- type granites. The Cu-Au-bearing porphyries are LILE-, LREE-enriched and HFSE-depleted, typical of arc magmatic affinities. The barren granites are HFSE-enriched, with lower LREE/HREE ratios and pronounced negative Eu anomalies. The Cu-Au-bearing porphyries in the Paodaoling district have high oxygen fugacities and high water content. Pyrite sulfur isotopes of the Paodaoling gold deposit indicate a magmatic-sedimentary mixed source for the ore-forming fluids. Based on the alteration and poly-metal zonation of the deepest exploration drill hole from the Paodaoling Au deposit, we propose that Cu ore bodies could lie at depth beneath the current Au ore bodies. The magmatism and associated Cu-Au mineralization of the Paodaoling district are likely to have formed in a subduction setting, during slab rollback of the paleo-Pacific plate.
基金This study was supported by the National Natural Science Foundation of China grant 49802007.
文摘Studies of the Pb, Sr and Nd isotopic composition of Mesozoic intrusive rocks indicate that the basement of the copper-gold metallogenic belt of the middle and lower reaches of the Yangtze River has “two-layer structure” and partly has “multi-layered structure”, and is inhomogeneous and shows the distinct feature of E-W provincialism. The calculated model lead ages (t1) are mostly greater than 2600 Ma, and the model neodymium ages (TDM) vary from 953 to 2276 Ma and concentrate in two time intervals: 1800–2000 Ma and 1200–1600 Ma. It is concluded that the basement of the MBYR is composed of the Late Archaeozoic to Middle Proterozoic metamorphic series and that the crust was initiated in the Archaean and continued to grow in the Early and Middle Proterozoic, and the proportion of new crust formed by mantle differentiation during the Late Proterozoic is low.
基金funded by grants from the Key Project of the National Natural Science Foundation of China(No.41630320)the National Key Research and Development Program of China(No.2016YFC0600200)the Hefei Postdoctoral Science Foundation。
文摘In this study,we compiled and analyzed 69310 P-wave travel-time data from 6639 earthquake events.These events(M≥2.0)occurred from 1980 s to June 2019 and were recorded at 319 seismic stations(Chinese Earthquake Networks Center)in the study area.We adopted the double-difference seismic tomographic method(tomo DD)to invert the 3-D P-wave velocity structure and constrain the crust-upper mantle architecture of the Middle and Lower Reaches of the Yangtze River Metallogenic Belt(MLYB).A 1-D initial model extracted from wide-angle seismic profiles was used in the seismic tomography,which greatly reduced the inversion residual.Our results indicate that reliable velocity structure of th e uppermost mantle can be obtained when Pn is involved in the tomography.Our results show that:(1)the pattern of the uppermost mantle velocity structure corresponds well with the geological partitioning:a nearly E-W-trending low-velocity zone is present beneath the Dabie Orogen,in contrast to the mainly NE-trending low-velocity anomalies beneath the Jiangnan Orogen.They suggest the presence of thickened lower crust beneath the orogens in the study area.In contrast,the Yangtze and Cathaysia blocks are characterized by relatively high-velocity anomalies;(2)both the ultra-high-pressure(UHP)metamorphic rocks in the Dabie Orogen and the low-pressure metamorphic rocks in the Zhangbaling dome are characterized by high-velocity anomalies.The upper crust in the Dabie Orogen is characterized by a low-velocity belt,sandwiched between two high velocity zones in a horizontal direction,with discontinuous low-velocity layers in the middle crust.The keel of the Dabie Orogen is mainly preserved beneath its northern section.We infer that the lower crustal delamination may have mainly occurred in the southern Dabie Orogen,which caused the mantle upwelling responsible for the formation of the granitic magmas emplaced in the middle crust as the low-velocity layers observed there.Continuous deep-level compression likely squeezed the granitic magma upward to intrude the upper crustal UHP metamorphic rocks,forming the'sandwich'velocity structure there;(3)high-velocity updoming is widespread in the crust-mantle transition zone beneath the MLYB.From the Anqing-Guichi ore field northeastward to the Luzong,Tongling,Ningwu and Ningzhen orefields,high-velocity anomalies in the crust-mantle transition zone increase rapidly in size and are widely distributed.The updoming also exists in the crust-mantle transition zone beneath the Jiurui and Edongnan orefields,but the high-velocity anomalies are mainly stellate distributed.The updoming high-velocity zone beneath the MLYB generally extends from the crust-mantle transition zone to the middle crust,different from the velocity structure in the upper crust.The upper crust beneath the Early Cretaceous extension-related Luzong and Ningwu volcanic basins is characterized by high velocity zones,in contrast to the low velocity anomalies beneath the Late Jurassic to Early Cretaceous compression-related Tongling ore field.The MLYB may have undergone a compressive-to-extensional transition during the Yanshanian(Jurassic-Cretaceous)period,during which extensive magmatism occurred.The near mantle-crustal boundary updoming was likely caused by asthenospheric underplating at the base of the lower crust.The magmas may have ascended through major crustal faults,undergoing AFC(assimilation and fractional crystallization)processes,became emplaced in the fault-bounded basins or Paleozoic sequences,eventually forming the many Cu-Fe polymetallic deposits there.
基金supported by the National Key R&D Program Project of China(No.2016YFC0600209)。
文摘The Nanling-Xuancheng ore region of Anhui Province is located in the Middle-Lower Yangtze River metallogenic belt.Insufficient exploration and research have been carried out in this newly defined ore district,although the Chating large porphyry Cu-Au deposit and a few middle-sized skarntype Cu polymetallic deposits have been discovered.In this study,we carried out high-resolution seismic reflection,magnetotelluric,gravity,and magnetic investigations,and constructed the 3 D geological structure of the uppermost crust in a depth range of 0-5 km using a comprehensive inversion of the new data constrained by previous deep-drilling data.We hence proposed some new insights to understand the mineralization processes of this district.A system of alternating ridges and valleys is suggested as the major structure pattern,composed of“two-layer structure”of the basins and“three-layer structure”of anticlines.Moreover,a conjugated fault system and its distribution features are revealed in our models,including the Jiangnan fault,Zhouwang fault,and Kunshan thrust nappe.The Jiangnan and Kunshan faults are suggested to have controlled the diagenesis and metallogenesis.Two deep concealed plutons located in Chating and Magushan are found,forming the Mesozoic diorite-felsic intrusions.These intrusions are believed to be the causes of hydrothermal deposits such as the Chating deposit and the Magushan deposit.
基金supported by the Land Resources Survey Project of the China Geological Survey Bureau (Grant No. DD20179354)the National Natural Science Foundation of China (Grant Nos. 41790464 & 41674061)
文摘The Middle-Lower Yangtze River Metallogenic Belt(MLYMB) is an important mineral resource region in China.High-resolution crustal models can provide crucial constraints to understand the ore-forming processes and geodynamic setting in this region. Using ambient seismic noise from 107 permanent and 82 portable stations in the MLYMB and the adjacent area,we present a new high-resolution 3D S-wave velocity model of this region. We first extract 5–50 s Rayleigh wave phase velocity dispersion data by calculating ambient noise cross-correlation functions(CFs) and then use the surface wave direct inversion method to invert the mixed path travel times for the 3D S-wave velocity structure. Checkerboard tests show that the horizontal resolution of the 3D S-wave velocity model is approximately 0.5°–1.0° and that the vertical resolution decreases with increasing noise and depth. Our high-resolution 3D S-wave velocity model reveals:(1) AV-shaped high-velocity zone(HVZ) is located in the lower crust and the uppermost mantle in the study region. The western branch of the HVZ passes through the Jianghan Basin,the Qinling-Dabie orogenic belt and the Nanxiang Basin. The eastern branch, which almost completely covers the main body of the MLYMB, is located near the Tanlu Fault. The low-velocity anomalies between the western and eastern branches are located in the area of the Qinling-Dabie orogenic belt.(2) High-velocity uplifts(HVUs) are common in the crust of the MLYMB,especially in the areas near the Tanlu Fault, the Changjiang Fault and the Yangxin-Changzhou Fault. The intensities of the HVUs gradually weaken from west to east. The V-shaped HVZ in the lower crust and uppermost mantle and the HVUs in the middle and lower crust likely represent cooled mantle intrusive rocks. During the Yanshanian period, fault systems formed in the MLYMB due to the convergence between the South China Plate and the North China Plate, the multiple-direction drifting of the PaleoPacific Plate and its subduction beneath the Eurasian Plate. The dehydration of the cold oceanic crust led to partial melting in the upper mantle. Temperature differences caused strong convection of the upper mantle material that underplated the lower crust and rose to near the surface along the deep fault systems. After mixing with the crustal materials, mineralization processes, such as assimilation and fractional crystallization, occurred in the MLYMB.
