The vertical distribution and migration of Cu,Zn,Pb,and Cd in two forest soil profiles near an industrial emission source were investigated using a high resolution sampling method together with reference element Ti.On...The vertical distribution and migration of Cu,Zn,Pb,and Cd in two forest soil profiles near an industrial emission source were investigated using a high resolution sampling method together with reference element Ti.One-meter soil profile was sectioned horizontally at 2 cm intervals in the first 40 cm,5 cm intervals in the next 40 cm,and 10 cm intervals in the last 20 cm.The migration distance and rate of heavy metals in the soil profiles were calculated according to their relative concentrations in the profiles,as calibrated by the reference element Ti.The enrichment of heavy metals appeared in the uppermost layer of the forest soil,and the soil heavy metal concentrations decreased down the profile until reaching their background values.The calculated average migration rates of Cd,Cu,Pb,and Zn were 0.70,0.33,0.37,and 0.76 cm year-1,respectively,which were comparable to other methods.A simulation model was proposed,which could well describe the distribution of Cu,Zn,Pb,and Cd in natural forest soils.展开更多
In this paper,the pricing of a Credit Default Swap(CDS)contract with multiple counterparties is considered.The pricing model takes into account the credit rating migration risk of the reference.It is a new model estab...In this paper,the pricing of a Credit Default Swap(CDS)contract with multiple counterparties is considered.The pricing model takes into account the credit rating migration risk of the reference.It is a new model established under the reduced form framework,where the intensity rates are assumed to have structural styles.We derive from it a non-linear partial differential equation system where both positive and negative correlations of counterparties and the references are considered via a single factor model.Then,an ADI(Alternating Direction Implicit)difference method is used to solve the partial differential equations by iteration.From the numerical results,the comparison of multi-counterparty CDS contract and the standard one are analyzed respectively.Moreover,the impact of default parameters on value of the contracts are discussed.展开更多
[Objective] The deliver amount and deliver rate of heavy metal elements during smoking were studied, which could provide a reference for reducing the damage of cigarette products. [Method] Two pretreatment methodsof m...[Objective] The deliver amount and deliver rate of heavy metal elements during smoking were studied, which could provide a reference for reducing the damage of cigarette products. [Method] Two pretreatment methodsof microwave di- gestion and acid extraction were used to process the ash content, the total particu- late matter of mainstream smoke （TPM） and cigarette filter. Detection results of heavy metal elements were compared by the two methods. [Result] The microwave digestion method was better than acid solution extraction method on analysis of TPM, but presented disadvantages on analysis of ash and filter. Meanwhile, the migration amount and rate were studied and resultsshowed that most heavy metal elements were escaped along with sidestream smoke between 66.89% and 95.48%, and almost all Hg escaped through sidestream smoke. Other heavy metal elements, except Hg, were separately found in ash, TPM and filter. Cr, Ni, As and Se were mostly residual in ash, followed by TPM, and filter had the least, while Cd and Pb were just in the reverse order. Normally, 5% or less heavy metal elements were transferred to TPM, only a small part of which could reach 5%-10%. [Conclusion] Most of the heavy metal elements are taken by sidestream smoke, ash and filter, while the migration amounts to mainstream smoke are extremely low.展开更多
An important challenge facing K-ion batteries lies in exploring earth-abundant and safe cathode materials that can provide high capacity with high migration rate of K ions.Here,we propose a simple and efficient method...An important challenge facing K-ion batteries lies in exploring earth-abundant and safe cathode materials that can provide high capacity with high migration rate of K ions.Here,we propose a simple and efficient method for searching potential K cathode materials with first principles calculations.Our screening is based on combinations of weight capacity,K ion occupation ratio,volume change per K,and valence limit.With this screening method we predicted a series of potential K ions cathodes with favorable electrochemical performance,such as K_(2)VPO_(4)CO_(3)-like structures with 1 D diffusion channels,3 D channel structures K_(2)CoSiO_(4),layered materials KCoO_(2),KCrO_(2),KVF_(4) and K_(5)V_(3)F_(14),and others.These potential cathodes have small volume changes,suitable voltage,and high capacity,with small diffusion barriers.They may be useful in K-ion batteries with high energy density and rate performance.展开更多
This research examines the shifts in age profiles among migrants in China,utilizing microdata derived from four national censuses and two 1%population sample surveys conducted since 1990.Our findings indicate:(1)there...This research examines the shifts in age profiles among migrants in China,utilizing microdata derived from four national censuses and two 1%population sample surveys conducted since 1990.Our findings indicate:(1)there has been a surge in age-specific migration intensity across all age groups over the past two decades;(2)the age profiles of the flow floating population differ from both the entire and the residual migrant populations;and(3)the age profiles of China’s flow floating population exhibit a blend of Asian and Western patterns-a prevalence among individuals in their early 20s,typical of Asian patterns,and a broad range of ages post-peak,indicative of Western patterns.Consequently,we propose that future population projections prioritize the flow floating population over the traditionally employed entire floating population.Furthermore,recognizing heterogeneity is critical for accurately understanding migrants in China,necessitating a comprehensive migration policy that safeguards the rights and welfare of these individuals.展开更多
A pricing model for a corporate bond with rating migration risk is established in this article. With the technology of utility-indifference valuation under the Markov-modulated framework, we analyze the price of a mul...A pricing model for a corporate bond with rating migration risk is established in this article. With the technology of utility-indifference valuation under the Markov-modulated framework, we analyze the price of a multi-rating bond and obtain closed formulae in a three-rating case. Based on the pricing formulae, the impacts of the parameters on the indifference price are analyzed and some reasonable financial explanations are provided as well.展开更多
Monte Carlo （MC） simulations, including multiple physical and chemical mechanisms, were performed to investigate the microstructure evolution of a conducting metal filament in a typical oxide-electrolyte-based ReRAM...Monte Carlo （MC） simulations, including multiple physical and chemical mechanisms, were performed to investigate the microstructure evolution of a conducting metal filament in a typical oxide-electrolyte-based ReRAM. It has been revealed that the growth direction and geometry of the conductive filament are controlled by the ion migration rate in the electrolyte layer during the formation procedure. When the migration rate is rela- tive high, the filament is shown to grow from cathode to anode. When the migration rate is low, the growth direction is expected to start from the anode. Simulated conductive filament （CF） geometries and I-V characteristics are also illustrated and analyzed. A good agreement between the simulation results and experiment data is obtained.展开更多
Radionuclide fallout during nuclear accidents on the land may impair the atmosphere, contaminate farmland soils and crops, and can even reach the groundwater. Previous research focused on the field distribution of dep...Radionuclide fallout during nuclear accidents on the land may impair the atmosphere, contaminate farmland soils and crops, and can even reach the groundwater. Previous research focused on the field distribution of deposited radionuclides in farmland soils, but details of the amounts of radionuclides in the plough layer and the changes in their proportional distribution in the soil profile with time are still inadequate. In this study, a lysimeter experiment was conducted to determine the vertical migration of 137Cs and 60Co in brown and aeolian sandy soils, collected from the farmlands adjoining Shidaowan Nuclear Power Plant(NPP) in eastern China, and to identify the factors influencing their migration depths in soil. At the end of the experiment(800 d), >96% of added 137Cs and 60Co were retained in the top 0–20 cm soil layer of both soils;very little 137Cs or 60Co initially migrated to 20–30 cm, but their amounts at this depth increased with time. The migration depth of 137Cs was greater in the aeolian sandy soil than in the brown soil during 0–577 d, but at the end of the experiment, 137Cs migrated to the same depth(25 cm) in both soils. Three phases on the vertical migration rate(v) of 60Co in the aeolian sandy soil can be identified: an initial rapid movement(0–355 d, v = 219 ± 17 mm year-1), followed by a steady movement(355–577 d, v = 150 ± 24 mm year-1) and a very slow movement(577–800 d, v = 107 ± 7 mm year-1). In contrast, its migration rate in the brown soil(v = 133 ± 17 mm year-1) was steady throughout the 800-d experimental period. The migration of both 137Cs and 60Co in the two soils appears to be regulated by soil clay and silt fractions that provide most of the soil surface area, soil organic carbon(SOC), and soil pH, which were manifested by the solid-liquid distribution coefficient of 137Cs and 60Co. The results of this study suggest that most 137Cs and 60Co remained within the top layer(0–20 cm depth) of farmland soils following a simulated NPP accident, and little reached the subsurface(20–30 cm depth). Fixation of radionuclides onto clay minerals may limit their migration in soil, but some could be laterally distributed by soil erosion and taken up by crops, and migrate into groundwater in a high water table level area after several decades.Remediation measures, therefore, should focus on reducing their impact on the farmland soils, crops, and water.展开更多
基金the National Natural Science Foundation of China (No40625001)the Knowledge Innovation Pro-gram of the Chinese Academy of Sciences (NoKZCX2-YW-409)the Jiangsu Provincial Natural Science Foundation of China (NoBK2004167)
文摘The vertical distribution and migration of Cu,Zn,Pb,and Cd in two forest soil profiles near an industrial emission source were investigated using a high resolution sampling method together with reference element Ti.One-meter soil profile was sectioned horizontally at 2 cm intervals in the first 40 cm,5 cm intervals in the next 40 cm,and 10 cm intervals in the last 20 cm.The migration distance and rate of heavy metals in the soil profiles were calculated according to their relative concentrations in the profiles,as calibrated by the reference element Ti.The enrichment of heavy metals appeared in the uppermost layer of the forest soil,and the soil heavy metal concentrations decreased down the profile until reaching their background values.The calculated average migration rates of Cd,Cu,Pb,and Zn were 0.70,0.33,0.37,and 0.76 cm year-1,respectively,which were comparable to other methods.A simulation model was proposed,which could well describe the distribution of Cu,Zn,Pb,and Cd in natural forest soils.
基金Supported by the National Natural Science Foundation of China(11671301,12071349).
文摘In this paper,the pricing of a Credit Default Swap(CDS)contract with multiple counterparties is considered.The pricing model takes into account the credit rating migration risk of the reference.It is a new model established under the reduced form framework,where the intensity rates are assumed to have structural styles.We derive from it a non-linear partial differential equation system where both positive and negative correlations of counterparties and the references are considered via a single factor model.Then,an ADI(Alternating Direction Implicit)difference method is used to solve the partial differential equations by iteration.From the numerical results,the comparison of multi-counterparty CDS contract and the standard one are analyzed respectively.Moreover,the impact of default parameters on value of the contracts are discussed.
文摘[Objective] The deliver amount and deliver rate of heavy metal elements during smoking were studied, which could provide a reference for reducing the damage of cigarette products. [Method] Two pretreatment methodsof microwave di- gestion and acid extraction were used to process the ash content, the total particu- late matter of mainstream smoke （TPM） and cigarette filter. Detection results of heavy metal elements were compared by the two methods. [Result] The microwave digestion method was better than acid solution extraction method on analysis of TPM, but presented disadvantages on analysis of ash and filter. Meanwhile, the migration amount and rate were studied and resultsshowed that most heavy metal elements were escaped along with sidestream smoke between 66.89% and 95.48%, and almost all Hg escaped through sidestream smoke. Other heavy metal elements, except Hg, were separately found in ash, TPM and filter. Cr, Ni, As and Se were mostly residual in ash, followed by TPM, and filter had the least, while Cd and Pb were just in the reverse order. Normally, 5% or less heavy metal elements were transferred to TPM, only a small part of which could reach 5%-10%. [Conclusion] Most of the heavy metal elements are taken by sidestream smoke, ash and filter, while the migration amounts to mainstream smoke are extremely low.
基金supported by the National Key R&D Program of China(Grant No.2016YFA0200400)the National Natural Science Foundation of China(Grant No.11504123 and No.51627805)。
文摘An important challenge facing K-ion batteries lies in exploring earth-abundant and safe cathode materials that can provide high capacity with high migration rate of K ions.Here,we propose a simple and efficient method for searching potential K cathode materials with first principles calculations.Our screening is based on combinations of weight capacity,K ion occupation ratio,volume change per K,and valence limit.With this screening method we predicted a series of potential K ions cathodes with favorable electrochemical performance,such as K_(2)VPO_(4)CO_(3)-like structures with 1 D diffusion channels,3 D channel structures K_(2)CoSiO_(4),layered materials KCoO_(2),KCrO_(2),KVF_(4) and K_(5)V_(3)F_(14),and others.These potential cathodes have small volume changes,suitable voltage,and high capacity,with small diffusion barriers.They may be useful in K-ion batteries with high energy density and rate performance.
基金Funding was provided by National Planning Office of Philosophy and Social Science(Grant no.19BRK039).
文摘This research examines the shifts in age profiles among migrants in China,utilizing microdata derived from four national censuses and two 1%population sample surveys conducted since 1990.Our findings indicate:(1)there has been a surge in age-specific migration intensity across all age groups over the past two decades;(2)the age profiles of the flow floating population differ from both the entire and the residual migrant populations;and(3)the age profiles of China’s flow floating population exhibit a blend of Asian and Western patterns-a prevalence among individuals in their early 20s,typical of Asian patterns,and a broad range of ages post-peak,indicative of Western patterns.Consequently,we propose that future population projections prioritize the flow floating population over the traditionally employed entire floating population.Furthermore,recognizing heterogeneity is critical for accurately understanding migrants in China,necessitating a comprehensive migration policy that safeguards the rights and welfare of these individuals.
基金Acknowledgements This work was supported by the National Natural Science Foundation of China （Grant No. 11271287）.
文摘A pricing model for a corporate bond with rating migration risk is established in this article. With the technology of utility-indifference valuation under the Markov-modulated framework, we analyze the price of a multi-rating bond and obtain closed formulae in a three-rating case. Based on the pricing formulae, the impacts of the parameters on the indifference price are analyzed and some reasonable financial explanations are provided as well.
基金Project supported by the Ministry of Science and Technology of China(Nos.2010CB934200,2011CBA00602,2009CB930803,2011CB921804,2011AA010401,2011AA010402,XDA06020102)the National Natural Science Foundation of China(Nos.61221004,61274091,60825403,61106119,61106082,61306117)
文摘Monte Carlo （MC） simulations, including multiple physical and chemical mechanisms, were performed to investigate the microstructure evolution of a conducting metal filament in a typical oxide-electrolyte-based ReRAM. It has been revealed that the growth direction and geometry of the conductive filament are controlled by the ion migration rate in the electrolyte layer during the formation procedure. When the migration rate is rela- tive high, the filament is shown to grow from cathode to anode. When the migration rate is low, the growth direction is expected to start from the anode. Simulated conductive filament （CF） geometries and I-V characteristics are also illustrated and analyzed. A good agreement between the simulation results and experiment data is obtained.
基金the IAEA Project (No. 18176)the National Science and Technology Major Projects of China (No. 2013ZX06002001) that supported this workpart of the project supported by the National Key Research and Development Program of China (No. 2017YFC0505402)。
文摘Radionuclide fallout during nuclear accidents on the land may impair the atmosphere, contaminate farmland soils and crops, and can even reach the groundwater. Previous research focused on the field distribution of deposited radionuclides in farmland soils, but details of the amounts of radionuclides in the plough layer and the changes in their proportional distribution in the soil profile with time are still inadequate. In this study, a lysimeter experiment was conducted to determine the vertical migration of 137Cs and 60Co in brown and aeolian sandy soils, collected from the farmlands adjoining Shidaowan Nuclear Power Plant(NPP) in eastern China, and to identify the factors influencing their migration depths in soil. At the end of the experiment(800 d), >96% of added 137Cs and 60Co were retained in the top 0–20 cm soil layer of both soils;very little 137Cs or 60Co initially migrated to 20–30 cm, but their amounts at this depth increased with time. The migration depth of 137Cs was greater in the aeolian sandy soil than in the brown soil during 0–577 d, but at the end of the experiment, 137Cs migrated to the same depth(25 cm) in both soils. Three phases on the vertical migration rate(v) of 60Co in the aeolian sandy soil can be identified: an initial rapid movement(0–355 d, v = 219 ± 17 mm year-1), followed by a steady movement(355–577 d, v = 150 ± 24 mm year-1) and a very slow movement(577–800 d, v = 107 ± 7 mm year-1). In contrast, its migration rate in the brown soil(v = 133 ± 17 mm year-1) was steady throughout the 800-d experimental period. The migration of both 137Cs and 60Co in the two soils appears to be regulated by soil clay and silt fractions that provide most of the soil surface area, soil organic carbon(SOC), and soil pH, which were manifested by the solid-liquid distribution coefficient of 137Cs and 60Co. The results of this study suggest that most 137Cs and 60Co remained within the top layer(0–20 cm depth) of farmland soils following a simulated NPP accident, and little reached the subsurface(20–30 cm depth). Fixation of radionuclides onto clay minerals may limit their migration in soil, but some could be laterally distributed by soil erosion and taken up by crops, and migrate into groundwater in a high water table level area after several decades.Remediation measures, therefore, should focus on reducing their impact on the farmland soils, crops, and water.
