Microstructures and inclusions in the Si-Mn-Ti deoxidized steels after cooling in the furnace were investigated. The composition and morphology of the inclusions were analyzed using a field emission scanning electron ...Microstructures and inclusions in the Si-Mn-Ti deoxidized steels after cooling in the furnace were investigated. The composition and morphology of the inclusions were analyzed using a field emission scanning electron microscope （FE-SEM） with energy dispersive X-ray spectrometry （EDS）. The kind and composition of the inclusions calculated from the thermodynamic database were in good agreement with the experimental results. There were two main kinds of inclusions formed in the Si-Mn-Ti deoxidized steels. One kind of inclusion was the manganese titanium oxide （Mn-Ti oxide）. Another kind of inclusion was the MnS inclusion with segregation points containing Ti and N. According to the thermodynamic calculation, those segregation points were TiN precipitates. The formation of intragranular ferrite （IGF） microstructures refined the grain size during the austenite-ferrite transformation. The mechanisms of IGF formation were discussed. Mn-Ti oxide inclusions with Mn-depleted zone （MDZ） were effective to be nucleation sites for IGF formation, because the MDZ increased the austenite-ferrite transformation temperature. TiN had the low misfit ratio with IGF, so the TiN precipitated on the MnS surface also promoted the formation of IGF because of decreasing interfacial energies.展开更多
Metal active gas （ MAG） welding has been carried out on microalloy controlled rolling steel （S355J2W） by two kinds of welding wires with different Ti content. The mechanical tests have been carried out on the weld...Metal active gas （ MAG） welding has been carried out on microalloy controlled rolling steel （S355J2W） by two kinds of welding wires with different Ti content. The mechanical tests have been carried out on the welded joint. The optical microscope and scanning electron microscope （SEM） observations have been performed to investigate the effect of microalloy element Ti on the microstructure of weld metal and impact fracture, respectively. The microstrueture of the MAG multipass weld metal includes the columnar grain zone （CGZ） consisting of primary ferrite （ PF）, ferrite with second phase （FS） and acicularferrite （AF）, and the fine grain zone （FGZ） consisting of polygonal ferrite due to the heat effect of subsequent welding pass. It has been found that the small amount of Ti can significantly increase the impact energy of the weld metal at low temperature and weakly affect tensile strength of welded joint. By adding small amount of Ti, the inclusions have changed from Mn-Si-O inclusions to Ti-bearing inclusions, which causes the Mn-depleted zones（MDZs） much larger and is beneficial to the impact energy by promoting the AF formation, refining the PF and pinning the austenite grain boundary during the subsequent transformation process.展开更多
High grade pipeline steels were prepared using vacuum carbon deoxidization process combined with a final Ti-deoxidation process.The microstructure of the as-cast steels was investigated by using scanning electron micr...High grade pipeline steels were prepared using vacuum carbon deoxidization process combined with a final Ti-deoxidation process.The microstructure of the as-cast steels was investigated by using scanning electron microscopy（SEM）and transmission electron microscopy（TEM）.SEM observation shows that the formation of intragranular ferrite（IGF）structure is induced by fine inclusions.TEM selected area diffraction（SAD）patterns and elemental distribution analysis indicate that these inclusions are mainly Ti2O3 and MnS.It is also found that Ti2O3 may act as nucleus in the formation of MnS during solidification process.Raman spectroscopic analysis demonstrates the presence of another phase,MnTiO3,which could be formed through entrapment of Mn by Ti2O3.It is believed that the formation of Mn-depleted region in the inclusions and thus the formation of MnTiO3 phase will increase the Mn pickup from matrix and promote the formation of IGF during solidification of molten steel.展开更多
Inclusion characteristic and microstructure steel were evaluated with scanning electron of rare earth （RE） elements containing microscopy with energy dispersive spec- troscopy （SEM-EDS）, element-mapping, optical m...Inclusion characteristic and microstructure steel were evaluated with scanning electron of rare earth （RE） elements containing microscopy with energy dispersive spec- troscopy （SEM-EDS）, element-mapping, optical microscopy （OM）, and automated feature analysis （AFA） option equipped with ASPEX PSEM. Factsage was used to calculate the equilibrium inclusion composition. Based on the calculation, an inclu- sion evolution mechanism was proposed. Furthermore, line scanning analysis was used to elucidate the intra-granular acicular ferrite （IAF） nucleation mechanism. The re- sult showed that two different inclusions exist in sample steel： （Mn-A1-Si-Ti-La-Ce-O） ＋MnS complex inclusion and isolated MnS inclusion. Almost all nucleation sites for IAF are complex inclusions, while single MnS inclusion cannot induce IAF. A possible formation mechanism of complex inclusion is proposed based on calculated results using Factsage, which agrees well with experimental results. A Mn-depletion zone （MDZ） which exists adjacent to the （Mn-A1-Si-Ti-La-Ce-O） ＋MnS complex inclusion can account for the IAF formation. However, the low volume fraction （1.49× 10-7） of effective inclusion may result in only 10% （volume fraction） IAF.展开更多
To verify the formation behaviors and mechanisms of intra-granular acicular ferrite（ IAF） grains nucleated by Mg-Al-O in low carbon steel,the steels containing different Mg contents were refined in a vacuum inductio...To verify the formation behaviors and mechanisms of intra-granular acicular ferrite（ IAF） grains nucleated by Mg-Al-O in low carbon steel,the steels containing different Mg contents were refined in a vacuum induction furnace. The effect of Mg addition on the formation of IAF structure in Al-killed low carbon steel was investigated by optical microscope（ OM） and scanning electron microscope with energy dispersive X-ray spectroscope（ SEM-EDX）. It reveals that the IAFs are only detected in Mg-added steels,and the volume fraction of IAF increases with the Mg concentration from 8 × 10^（-6） to 26 × 10^（-6）. It shows that not only the MgO-Al_2O_3-MnS and MgO-Al_2O_3-P_2O_5 particles are the effective nucleation sites for IAF,but also the pure MgO·Al_2O_3 phase can promote the ferrite nucleation. A Mn-depletion zone（ MDZ） is characterized adjacent to the MgO-Al_2O_3-MnS,which is believed to be one of the possible mechanisms to explain the IAF nucleation. The MDZ around the MgO-Al_2O_3-MnS inclusion would be induced by the Mn S precipitation on the inclusion. It seems that the ability of Mg-containing inclusions to induce the nucleation of ferrite might be attributed to a new mechanism,i. e.,the Prich zone formed on a few Mg-Al-O inclusions might be another factor for promoting the IAF formation.展开更多
文摘Microstructures and inclusions in the Si-Mn-Ti deoxidized steels after cooling in the furnace were investigated. The composition and morphology of the inclusions were analyzed using a field emission scanning electron microscope （FE-SEM） with energy dispersive X-ray spectrometry （EDS）. The kind and composition of the inclusions calculated from the thermodynamic database were in good agreement with the experimental results. There were two main kinds of inclusions formed in the Si-Mn-Ti deoxidized steels. One kind of inclusion was the manganese titanium oxide （Mn-Ti oxide）. Another kind of inclusion was the MnS inclusion with segregation points containing Ti and N. According to the thermodynamic calculation, those segregation points were TiN precipitates. The formation of intragranular ferrite （IGF） microstructures refined the grain size during the austenite-ferrite transformation. The mechanisms of IGF formation were discussed. Mn-Ti oxide inclusions with Mn-depleted zone （MDZ） were effective to be nucleation sites for IGF formation, because the MDZ increased the austenite-ferrite transformation temperature. TiN had the low misfit ratio with IGF, so the TiN precipitated on the MnS surface also promoted the formation of IGF because of decreasing interfacial energies.
文摘Metal active gas （ MAG） welding has been carried out on microalloy controlled rolling steel （S355J2W） by two kinds of welding wires with different Ti content. The mechanical tests have been carried out on the welded joint. The optical microscope and scanning electron microscope （SEM） observations have been performed to investigate the effect of microalloy element Ti on the microstructure of weld metal and impact fracture, respectively. The microstrueture of the MAG multipass weld metal includes the columnar grain zone （CGZ） consisting of primary ferrite （ PF）, ferrite with second phase （FS） and acicularferrite （AF）, and the fine grain zone （FGZ） consisting of polygonal ferrite due to the heat effect of subsequent welding pass. It has been found that the small amount of Ti can significantly increase the impact energy of the weld metal at low temperature and weakly affect tensile strength of welded joint. By adding small amount of Ti, the inclusions have changed from Mn-Si-O inclusions to Ti-bearing inclusions, which causes the Mn-depleted zones（MDZs） much larger and is beneficial to the impact energy by promoting the AF formation, refining the PF and pinning the austenite grain boundary during the subsequent transformation process.
基金Item Sponsored by Provincial Natural Science Foundation of Hubei Province of China(2006ABD006)Excellent Young Scientific and Technological Innovation Team Scheme of Hubei Universities of China(T200609)
文摘High grade pipeline steels were prepared using vacuum carbon deoxidization process combined with a final Ti-deoxidation process.The microstructure of the as-cast steels was investigated by using scanning electron microscopy（SEM）and transmission electron microscopy（TEM）.SEM observation shows that the formation of intragranular ferrite（IGF）structure is induced by fine inclusions.TEM selected area diffraction（SAD）patterns and elemental distribution analysis indicate that these inclusions are mainly Ti2O3 and MnS.It is also found that Ti2O3 may act as nucleus in the formation of MnS during solidification process.Raman spectroscopic analysis demonstrates the presence of another phase,MnTiO3,which could be formed through entrapment of Mn by Ti2O3.It is believed that the formation of Mn-depleted region in the inclusions and thus the formation of MnTiO3 phase will increase the Mn pickup from matrix and promote the formation of IGF during solidification of molten steel.
基金supported by the National Natural Science Foundation of China(No.2010CB30806)
文摘Inclusion characteristic and microstructure steel were evaluated with scanning electron of rare earth （RE） elements containing microscopy with energy dispersive spec- troscopy （SEM-EDS）, element-mapping, optical microscopy （OM）, and automated feature analysis （AFA） option equipped with ASPEX PSEM. Factsage was used to calculate the equilibrium inclusion composition. Based on the calculation, an inclu- sion evolution mechanism was proposed. Furthermore, line scanning analysis was used to elucidate the intra-granular acicular ferrite （IAF） nucleation mechanism. The re- sult showed that two different inclusions exist in sample steel： （Mn-A1-Si-Ti-La-Ce-O） ＋MnS complex inclusion and isolated MnS inclusion. Almost all nucleation sites for IAF are complex inclusions, while single MnS inclusion cannot induce IAF. A possible formation mechanism of complex inclusion is proposed based on calculated results using Factsage, which agrees well with experimental results. A Mn-depletion zone （MDZ） which exists adjacent to the （Mn-A1-Si-Ti-La-Ce-O） ＋MnS complex inclusion can account for the IAF formation. However, the low volume fraction （1.49× 10-7） of effective inclusion may result in only 10% （volume fraction） IAF.
基金Item Sponsored by National Natural Science Foundation of China(51374059,51374060)Scientific Research Fund of Liaoning Provincial Education Department of China(2012221013)
文摘To verify the formation behaviors and mechanisms of intra-granular acicular ferrite（ IAF） grains nucleated by Mg-Al-O in low carbon steel,the steels containing different Mg contents were refined in a vacuum induction furnace. The effect of Mg addition on the formation of IAF structure in Al-killed low carbon steel was investigated by optical microscope（ OM） and scanning electron microscope with energy dispersive X-ray spectroscope（ SEM-EDX）. It reveals that the IAFs are only detected in Mg-added steels,and the volume fraction of IAF increases with the Mg concentration from 8 × 10^（-6） to 26 × 10^（-6）. It shows that not only the MgO-Al_2O_3-MnS and MgO-Al_2O_3-P_2O_5 particles are the effective nucleation sites for IAF,but also the pure MgO·Al_2O_3 phase can promote the ferrite nucleation. A Mn-depletion zone（ MDZ） is characterized adjacent to the MgO-Al_2O_3-MnS,which is believed to be one of the possible mechanisms to explain the IAF nucleation. The MDZ around the MgO-Al_2O_3-MnS inclusion would be induced by the Mn S precipitation on the inclusion. It seems that the ability of Mg-containing inclusions to induce the nucleation of ferrite might be attributed to a new mechanism,i. e.,the Prich zone formed on a few Mg-Al-O inclusions might be another factor for promoting the IAF formation.
