A resolution method based on Gaussian-like distribution for overlapped linear sweep polarographic peaks was proposed to simultaneously detect the polymetallic components, such as Zn（Ⅱ） and Co（Ⅱ）, coexisting in t...A resolution method based on Gaussian-like distribution for overlapped linear sweep polarographic peaks was proposed to simultaneously detect the polymetallic components, such as Zn（Ⅱ） and Co（Ⅱ）, coexisting in the leaching solution of zinc hydrometallurgy. A Gaussian-like distribution was constructed as the sub-model of overlapped peaks by analyzing the characteristics of linear sweep polarographic curve. Then, the abscissas of each peak and trough were pinpointed through multi-resolution wavelet decomposition, the curve and its derivative curves were fitted by using nonlinear weighted least squares （NWLS）. Finally, overlapped peaks were resolved into independent sub-peaks based on fitted reconstruction parameters. The experimental results show that the relative error of half-wave potential pinpointed by multi-resolution wavelet decomposition is less than 1% and the accuracy of Ip fitted by NWLS is higher than 96%. The proposed resolution method is effective for overlapped linear sweep polarographic peaks of Zn（Ⅱ） and Co（Ⅱ）.展开更多
The gradient descent(GD)method is used to fit the measured data(i.e.,the laser grain-size distribution of the sediments)with a sum of four weighted lognormal functions.The method is calibrated by a series of ideal num...The gradient descent(GD)method is used to fit the measured data(i.e.,the laser grain-size distribution of the sediments)with a sum of four weighted lognormal functions.The method is calibrated by a series of ideal numerical experiments.The numerical results indicate that the GD method not only is easy to operate but also could effectively optimize the parameters of the fitting function with the error decreasing steadily.The method is applied to numerical partitioning of laser grain-size components of a series of Garzêloess samples and three bottom sedimentary samples of submarine turbidity currents modeled in an open channel laboratory flume.The overall fitting results are satisfactory.As a new approach of data fitting,the GD method could also be adapted to solve other optimization problems.展开更多
基金Project(2012BAF03B05)supported by the National Key Technology R&D Program of ChinaProject(61025015)supported by the National Natural Science Foundation for Distinguished Young Scholars of China+1 种基金Project(61273185)supported by the National Natural Science Foundation of ChinaProject(2012CK4018)supported by the Science and Technology Project of Hunan Province,China
文摘A resolution method based on Gaussian-like distribution for overlapped linear sweep polarographic peaks was proposed to simultaneously detect the polymetallic components, such as Zn（Ⅱ） and Co（Ⅱ）, coexisting in the leaching solution of zinc hydrometallurgy. A Gaussian-like distribution was constructed as the sub-model of overlapped peaks by analyzing the characteristics of linear sweep polarographic curve. Then, the abscissas of each peak and trough were pinpointed through multi-resolution wavelet decomposition, the curve and its derivative curves were fitted by using nonlinear weighted least squares （NWLS）. Finally, overlapped peaks were resolved into independent sub-peaks based on fitted reconstruction parameters. The experimental results show that the relative error of half-wave potential pinpointed by multi-resolution wavelet decomposition is less than 1% and the accuracy of Ip fitted by NWLS is higher than 96%. The proposed resolution method is effective for overlapped linear sweep polarographic peaks of Zn（Ⅱ） and Co（Ⅱ）.
基金supported by the National Natural Science Foundation of China(Grant Nos.41072176,41371496)the National Science and Technology Supporting Program of China(Grant No.2013BAK05B04)the Fundamental Research Funds for the Central Universities(Grant No.201261006)
文摘The gradient descent(GD)method is used to fit the measured data(i.e.,the laser grain-size distribution of the sediments)with a sum of four weighted lognormal functions.The method is calibrated by a series of ideal numerical experiments.The numerical results indicate that the GD method not only is easy to operate but also could effectively optimize the parameters of the fitting function with the error decreasing steadily.The method is applied to numerical partitioning of laser grain-size components of a series of Garzêloess samples and three bottom sedimentary samples of submarine turbidity currents modeled in an open channel laboratory flume.The overall fitting results are satisfactory.As a new approach of data fitting,the GD method could also be adapted to solve other optimization problems.
