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Optimization of cement-based grouts using chemical additives 被引量:8
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作者 Mohammad Reza Azadi Ali Taghichian Ali Taheri 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2017年第4期623-637,共15页
Grout injection is used for sealing or strengthening the ground in order to prevent water entrance or any failure after excavation.There are many methods of grouting.Permeation grouting is one of the most common types... Grout injection is used for sealing or strengthening the ground in order to prevent water entrance or any failure after excavation.There are many methods of grouting.Permeation grouting is one of the most common types in which the grout material is injected to the pore spaces of the ground.In grouting operations,the grout quality is important to achieve the best results.There are four main characteristics for a grout mixture including bleeding,setting time,strength,and viscosity.In this paper,we try to build some efficient grouting mixtures with different water to cement ratios considering these characteristics.The ingredients of grout mixtures built in this study are cement,water,bentonite,and some chemical additives such as sodium silicate,sodium carbonate,and triethanolamine(TEA).The grout mixtures are prepared for both of the sealing and strengthening purposes for a structural project.Effect of each abovementioned ingredient is profoundly investigated.Since each ingredient may have positive or negative aspect,an optimization of appropriate amount of each ingredient is determined.The optimization is based on 200 grout mixture samples with different percentages of ingredients.Finally,some of these grout mixtures are chosen for the introduced project.It should be mentioned that grouting operations depend on various factors such as pressure of injection,ground structure and grain size of soils.However,quality of a grout can be helpful to make an injection easier and reasonable.For example,during the injection,a wrong estimated setting time can destroy the injected grout by washing the grout or setting early which prevents grouting.This paper tries to show some tests in easy way to achieve a desirable sample of grout. 展开更多
关键词 PERMEATION GROUTING BLEEDING Setting time chemical additives CEMENT-BASED GROUT
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INFLUENCE OF CHEMICAL ADDITIVES ON GAS HYDRATE FORMATION 被引量:2
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作者 TANG Cuiping and FAN Shuanshi (Center for Gas Hydrate Research, Guangzhou Institute of Energy Conversion, Chinese Academy of Science, Guangzhou 510070, Guangdong, China) 《化工学报》 EI CAS CSCD 北大核心 2003年第z1期37-40,共4页
One surfactant as sodium dodecyl sulfate (SDS) and one synthesized sample as gas hydrate inhibitor are introduced in this paper. Through experiments we prove sodium dodecyl sulfate can accelerate the formation rate of... One surfactant as sodium dodecyl sulfate (SDS) and one synthesized sample as gas hydrate inhibitor are introduced in this paper. Through experiments we prove sodium dodecyl sulfate can accelerate the formation rate of gas hydrate and the synthesized sample can inhibit the formation and growth. 展开更多
关键词 NATURAL gas hydrate chemical additive KINETIC INHIBITOR
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Non-target Screening and Quantitation of Organic Chlorides in Oilfield Chemicals with Comprehensive Two Dimensional Gas Chromatography Coupled with Time of Flight Mass Spectrometry 被引量:1
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作者 Zheng Kewen Guo Rui +5 位作者 Ren Guofa Xia Lingyan Xiong Wei Zhang Jin Chu Xiaodong Yu Zhiqiang 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2017年第4期65-71,共7页
Advanced analytical methodology based on comprehensive two-dimensional gas chromatography-time of flight mass spectrometry(GC×GC-TOFMS) is proposed for investigation of organic chlorides in different oilfield che... Advanced analytical methodology based on comprehensive two-dimensional gas chromatography-time of flight mass spectrometry(GC×GC-TOFMS) is proposed for investigation of organic chlorides in different oilfield chemicals.The target screening was initially carried out on 8 suspected organic chlorides by evaluating the capability of the enhanced separation and reliable identification at a trace concentration. GC×GC-TOFMS allowed for the fast and automated analysis of organic chlorides at a level of 200 μg/L. This method was subsequently applied for non-target screening of organic chlorides in different oilfield chemicals at various locations across China. 22 organic chlorides were identified and verified by comparison with pure standards in the mixed sample. Finally, this method was used to determine the content of the organic chlorides in individual samples. The result showed that the organic chloride levels in 19 of the 39 tested oilfield chemicals were above the threshold limit of 1.0 mg/L. 展开更多
关键词 GC×GC-TOFMS non-target SCREENING oilfield chemicals organic chlorides QUANTITATION
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Mechanism and Optimal Application of Chemical Additives for Accelerating Early Strength of Lime-flyash Stabilized Soils 被引量:3
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作者 姜增国 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2005年第3期110-112,共3页
To accelerate the early strength of lime-flyash stabilized soil for extending its further uses in highway and shortening highway construction time,five kinds of chemical additives were chosen on the basis of mechanism... To accelerate the early strength of lime-flyash stabilized soil for extending its further uses in highway and shortening highway construction time,five kinds of chemical additives were chosen on the basis of mechanism analysis of accelerating early strength in highway as a semi-rigid base material,and a series of experiments about the effect of different kinds of additives and quantity on the early strength of the stabilized soil were tested.The results show that chemical additives can efficiently improve the early strength of lime-flyash stabilized soil both the 7d and 28d,and the optimum quantity for above chemical additive is 1.5%-2.5% approximately.Some suggestions for the practical construction were also proposed. 展开更多
关键词 稳定土壤 化学添加剂 扩展性 高速公路 路面材料
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Vegetable Oil-Based Nanolubricants in Machining:From Physicochemical Properties to Application 被引量:2
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作者 Xiaotian Zhang Changhe Li +9 位作者 Zongming Zhou Bo Liu Yanbin Zhang Min Yang Teng Gao Mingzheng Liu Naiqing Zhang Zafar Said Shubham Sharma Hafiz Muhammad Ali 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2023年第4期4-42,共39页
Cutting fluid is crucial in ensuring surface quality and machining accuracy during machining.However,traditional mineral oil-based cutting fluids no longer meet modern machining’s health and environmental protection ... Cutting fluid is crucial in ensuring surface quality and machining accuracy during machining.However,traditional mineral oil-based cutting fluids no longer meet modern machining’s health and environmental protection require-ments.As a renewable,pollution-free alternative with excellent processing characteristics,vegetable oil has become an inevitable replacement.However,vegetable oil lacks oxidation stability,extreme pressure,and antiwear proper-ties,which are essential for machining requirements.The physicochemical characteristics of vegetable oils and the improved methods’application mechanism are not fully understood.This study aims to investigate the effects of viscosity,surface tension,and molecular structure of vegetable oil on cooling and lubricating properties.The mechanisms of autoxidation and high-temperature oxidation based on the molecular structure of vegetable oil are also discussed.The study further investigates the application mechanism and performance of chemical modification and antioxidant additives.The study shows that the propionic ester of methyl hydroxy-oleate obtained by epoxidation has an initial oxidation temperature of 175℃.The application mechanism and extreme pressure performance of conventional extreme pressure additives and nanoparticle additives were also investigated to solve the problem of insufficient oxidation resistance and extreme pressure performance of nanobiological lubricants.Finally,the study discusses the future prospects of vegetable oil for chemical modification and nanoparticle addition.The study provides theoretical guidance and technical support for the industrial application and scientific research of vegetable oil in the field of lubrication and cooling.It is expected to promote sustainable development in the manufacturing industry. 展开更多
关键词 Cutting fluid Vegetable oil chemical modification ANTIOXIDANT Extreme pressure additive Minimum quality lubrication
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Chemical Structure of Surfactant-Grafted Polyacrylamide Used in Oilfields
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作者 Tingting Jiang Haiyu Wang Baohui Wang 《Open Journal of Applied Sciences》 2014年第9期451-457,共7页
Surfactant-grafted Polyacrylamide (S-PAM) flooding is a new technique used in Daqiang Oil Field in China and also a novel way for improving the recovery efficiency of primary oil layer after polymer flooding. S-PAM fl... Surfactant-grafted Polyacrylamide (S-PAM) flooding is a new technique used in Daqiang Oil Field in China and also a novel way for improving the recovery efficiency of primary oil layer after polymer flooding. S-PAM flooding technology is perfected gradually with the proceeding of multiple polymer surfactant oil displacement tests. Test results showed that the S-PAM used in field was greatly different with conventional ones. Therefore, it is necessary to study the chemical structure of S-PAM. Aiming at making clear the chemical structure of S-PAM, this study characterized the two commonly used S-PAM in oil field through chemical analysis and Fourier infrared spectrometer detection and analyzed the main composition and chemical structure of the two S-PAM. 展开更多
关键词 Surfactant-Grafted POLYACRYLAMIDE chemical Structure oilfield
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Technologies of enhancing oil recovery by chemical flooding in Daqing Oilfield, NE China
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作者 SUN Longde WU Xiaolin +2 位作者 ZHOU Wanfu LI Xuejun HAN Peihui 《Petroleum Exploration and Development》 2018年第4期673-684,共12页
By tracking and analyzing the research and practices of chemical flooding carried out in the Daqing Oilfield, NE China since the 1970 s, the chemical flooding theory, technology adaptability and existing problems were... By tracking and analyzing the research and practices of chemical flooding carried out in the Daqing Oilfield, NE China since the 1970 s, the chemical flooding theory, technology adaptability and existing problems were systematically summarized, and directions and ideas of development in the future were proposed. In enhanced oil recovery by chemical flooding, the Daqing Oilfield developed theories related to compatibility between crude oil and surfactant that may form ultra-low interfacial tensions with low-acidity oil, and a series of surfactant products were developed independently. The key technologies for chemical flooding such as injection parameter optimization and numerical simulation were established. The technologies of separation injection, cleansing and anti-scaling, preparation and injection, and produced liquid processing were developed. The matching technologies of production engineering and surface facilities were formed. Through implementation of chemical flooding, the Daqing Oilfield achieved outstanding performances with enhanced recovery rate of 12% in polymer flooding and with enhanced recovery rate of 18% in ASP flooding. To further enhance the oil recovery of chemical flooding, three aspects need to be studied:(1) fine characterization of reservoirs;(2) smart and efficient recovery enhancement technologies;(3) environment friendly, high-efficiency and smart matching processes. 展开更多
关键词 DAQING oilfield chemical FLOODING surfactant-oil MATCH theory injection parameter optimization engineering support technology enhanced OIL recovery
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Status and Tendency of Liaohe Oilfield Chemical Production
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《China Oil & Gas》 CAS 1999年第2期107-109,共3页
关键词 LH Status and Tendency of Liaohe oilfield chemical Production
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Synergic effect of covalent and chemical sulfur fixation enhancing the immobilization-conversion of polysulfides in lithium-sulfur batteries
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作者 Ruili Gao Qian Zhang +5 位作者 Hui Wang Fanghui Wang Jianwei Ren Xuyun Wang Xianguo Ma Rongfang Wang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第4期1-11,共11页
Lithium-sulfur batteries(LSBs)are promising as the next generation energy storage options.However,their wide applications have been technically challenged by the diffusion losses of polysulfides and polysulfide shuttl... Lithium-sulfur batteries(LSBs)are promising as the next generation energy storage options.However,their wide applications have been technically challenged by the diffusion losses of polysulfides and polysulfide shuttle effect.In this work,the small organic molecules of 2,5-dichloropyrazine(2,5-DCP)were combined with Co-doped carbon(CoA NAC)flakes to achieve the synergic effect of the covalent and chemical sulfur fixation,so as that the immobilization-conversion of polysulfides in LSBs was greatly enhanced.More specifically,the nucleophilic substitution of the 2,5-DCP additive in the electrolyte with polysulfides formed the CAS bonds.Through the further covalent N-Li bonds between the N atoms in 2,5-DCP and polysulfides,sulfur fixation was achieved in the form of solid organosulfur.Meanwhile,the CoA NAC flakes served as the sulfur cathode to chemically anchor the polysulfides.The interaction mechanism between CoA NAC/2,5-DCP and polysulfides was explored by the density functional theory(DFT)calculations and in-situ infrared spectroscopy.The results showed that the optimal“with 2,5-DCP”sample-assembled LSB exhibited an initial discharge specific capacity of 1244 mA h g^(-1)at 0.2C,and a capacity decay rate of 0.053%per cycle was displayed after 800 cycles at 1C.The good cycling stability with a high sulfur-loaded electrode sample suggested that the synergic effect of covalent/chemical sulfur fixation enabled the enhancement of polysulfides immobilization-conversion in LSBs. 展开更多
关键词 Lithium-sulfur battery Covalent sulfur-fixation chemical sulfur-fixation Electrolyte additive Cycling stability
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An overview of chemical enhanced oil recovery and its status in India
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作者 Ganesh Kumar Pothula Rakesh Kumar Vij Achinta Bera 《Petroleum Science》 SCIE EI CAS CSCD 2023年第4期2305-2323,共19页
India is currently producing crude oil from matured fields because of insufficient discoveries of new fields.Therefore,in order to control the energy crisis in India,enhanced oil recovery(EOR)techniques are required t... India is currently producing crude oil from matured fields because of insufficient discoveries of new fields.Therefore,in order to control the energy crisis in India,enhanced oil recovery(EOR)techniques are required to reduce the import of crude from the OPEC(Organization of the Petroleum Exporting Countries).This review mentions chemical EOR techniques(polymers,surfactants,alkali,nanoparticles,and combined alkali-surfactant-polymer flooding)and operations in India.Chemical EOR methods are one of the most efficient methods for oil displacement.The efficiency is enhanced by interfacial tension(IFT)reduction using surfactants and alkali,and mobility control of injected water is done by adding a polymer to increase the volumetric sweep efficiency.This paper also reviews the current trend of chemical EOR,prospects of chemical EOR in Indian oilfields,the development of chemical EOR in India with their challenges raising with economics,and screening criteria for chemical EOR implementation on the field scale.Furthermore,the review gives a brief idea about chemical EOR implementation in Indian oilfields in future prospects to increase the additional oil recovery from existing depleted fields to reduce the import of crude oil.The outcome of this review depicts all chemical EOR operations and recovery rates both at the laboratory scale and field scale around the country.The additional recovery rates are compared from various chemical EOR methods like conventional chemical flooding methods and conventional chemicals combined with nanoparticles on a laboratory scale.The development of chemical EOR in the past few decades and the EOR policy given by the government of India has been mentioned in this review.The analysis provides an idea about enhanced recovery screening and implementation of chemical EOR methods in existing fields will significantly reduce the energy crisis in India. 展开更多
关键词 chemical enhanced oil recovery Surfactant flooding Polymer flooding Indian oilfields Enhanced oil recovery challenges in India Screening criteria
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Layered injection technology for chemical flooding of Class-Ⅲ oil reservoirs in the Daqing Oil Fields complex,Songliao Basin,Northeast China
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作者 Haicheng Li 《Energy Geoscience》 2023年第1期51-58,共8页
The Class-Ⅲ oil reservoirs of Lasaxing oilfield in the Daqing Oil Fields complex have geological oil reserves of 1.86 billion tonnes,an oil recovery of 39%,with remaining reserves accounting for more than 45%of the t... The Class-Ⅲ oil reservoirs of Lasaxing oilfield in the Daqing Oil Fields complex have geological oil reserves of 1.86 billion tonnes,an oil recovery of 39%,with remaining reserves accounting for more than 45%of the total geological reserves of the oilfield.Therefore,they have considerable potential for future oil production.The current layered injection technologies fail to achieve effective control over the low single-layer injection rates since they can only produce low throttle differential pressure under low injection rates(5-20 m^(3)/d).In this study,a symmetrically-structured double-offset-hole injection allocator and a novel throttling component were developed.Their spatial layout was constructed and mechanical parameters were optimized using finite element analysis,which allows for expanding the flow rate range at low injection rates.According to experimental results,the throttle differential pressure increased from 0.2 MPa to 0.8 MPa at an injection rate of 5 m^(3)/d,and the range of the single-layer flow rates expanded from 20-70 m^(3)/d to 5-70 m3/d.The field test results show that the effective production of oil layers with medium and low permeability was achieved and that the ratio of producing oil layer thickness to the total reservoir thickness increased by 9.7%on average.Therefore,this study provides valuable technical support for the effective chemical-flooding-based development of Class-Ⅲ oil reservoirs. 展开更多
关键词 chemical flooding Layered injection technology Low injection rate Lasaxing oilfield Daqing Oil Fields complex Songliao Basin
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稠油化学复合冷采技术研究与应用
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作者 计秉玉 孟霖 +3 位作者 束青林 方吉超 杨书 刘合 《中国工程科学》 CSCD 北大核心 2024年第1期216-224,共9页
我国稠油储量可观,其中60%的是深层稠油,而主流的蒸汽吞吐等热采技术采收率不足20%;稠油资源开发潜力极大,积极探索新的开采方式以提高采收率是石油领域高质量发展的必然选择。本文着重阐述稠油化学复合冷采技术体系构建及其现场应用,... 我国稠油储量可观,其中60%的是深层稠油,而主流的蒸汽吞吐等热采技术采收率不足20%;稠油资源开发潜力极大,积极探索新的开采方式以提高采收率是石油领域高质量发展的必然选择。本文着重阐述稠油化学复合冷采技术体系构建及其现场应用,为中深层稠油的新型绿色低成本接替技术发展提供有效方案。在分析稠油组分的基础上,细致剖析稠油结构致黏机理,包括化学降黏机理、降低启动压力梯度机理、提高驱油效果机理在内的提高采收率机理,以丰富理论认识。面向工程应用亟需,从水溶性降黏剂分子设计与合成、自组装调堵剂研发两方面出发,突破稠油绿色化学驱油体系。基于发展的稠油化学复合冷采技术,完成了3个稠油油田示范工程应用,在提高产油量、控制含水率方面取得了良好成效。进一步梳理了分子采油理论与技术、渗流理论与数值模拟技术等方面的后续发展要点,以为深层稠油的绿色高效开发接替技术研究、稠油化学复合冷采技术推广应用研究等提供启发和参考。 展开更多
关键词 深层稠油 结构致黏机理 化学降黏机理 降黏剂 现场试验
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耐高温泡沫树脂低伤害均匀固砂技术
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作者 匡韶华 吕民 +1 位作者 孙振宇 胡祎 《油田化学》 CAS CSCD 北大核心 2024年第1期53-60,共8页
针对常规泡沫树脂体系耐温性较差和辽河油田疏松砂岩稠油油藏化学固砂储层伤害大与有效期短的问题,以环氧树脂、酚醛树脂、疏水纳米SiO_(2)、硅烷偶联剂等为原料制得纳米改性树脂基液,然后加入固化剂、乳化剂、起泡剂、稳泡剂等添加剂... 针对常规泡沫树脂体系耐温性较差和辽河油田疏松砂岩稠油油藏化学固砂储层伤害大与有效期短的问题,以环氧树脂、酚醛树脂、疏水纳米SiO_(2)、硅烷偶联剂等为原料制得纳米改性树脂基液,然后加入固化剂、乳化剂、起泡剂、稳泡剂等添加剂制得泡沫树脂固砂体系。评价了该体系的固化温度、固砂强度、渗透性能、耐温性能和非均质多层注入性能;研发了配套的泡沫发生器,形成了耐高温泡沫树脂低伤害均匀固砂技术,并在辽河油田进行了现场应用。结果表明,泡沫树脂固砂体系的最优配方为:20%~30%树脂基液+8%~12%酚醛胺类固化剂+0.3%乳化剂OP-10+0.5%起泡剂有机硅表面活性剂+0.1%固体稳泡剂纳米SiO_(2)+0.1%聚合物稳泡剂聚乙二醇+57%~71%清水。该体系的起泡体积约为发泡前的7倍、半衰期大于20 min,可在35℃以上固化,固化后耐温可达280℃,既具有低温固化的特点,又具有耐高温的特点。在不同温度下固化的泡沫树脂固结岩心的抗压强度达到5 MPa以上,固砂强度高,满足疏松砂岩固砂强度的要求。对用0.25~0.42 mm石英砂制得的固结岩心的固砂渗透率达到4.8μm2,优于常规树脂固砂剂(1.9μm~2)。在非均质多油层中可明显防止高渗透层突进,改善固砂剂注入剖面,实现均匀固砂。现场试验取得良好的防砂效果,验证了该技术可实现均匀固砂和低伤害特性。利用泡沫树脂流体特性实现非均质多油层均匀固砂,达到了提高化学固砂效果和防砂有效期的目的。 展开更多
关键词 化学固砂 泡沫树脂 低温固化 耐高温 均匀固砂 泡沫发生器 辽河油田
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陕西地区油田化学品助剂产业发展研究与分析
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作者 王小荣 王乐 +2 位作者 马国艳 王婕 钱芳 《当代化工》 CAS 2024年第1期163-166,共4页
以陕西本土油田企业为基础,采用问卷调查法对企业的油田化学品助剂的现状进行调查分析,重点调查了油田化学品助剂的使用情况、对石油开采的有用程度、环保情况等现状,并总结了普通员工与管理者对油田化学品助剂产业发展的意见与建议。通... 以陕西本土油田企业为基础,采用问卷调查法对企业的油田化学品助剂的现状进行调查分析,重点调查了油田化学品助剂的使用情况、对石油开采的有用程度、环保情况等现状,并总结了普通员工与管理者对油田化学品助剂产业发展的意见与建议。通过SWOT战略分析法研究了油田化学品助剂产业发展的优、劣势以及面临的机遇与威胁。 展开更多
关键词 油田化学品助剂 行业发展现状 调查问卷 SWOT战略分析法
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油田伴生气与CO_(2)驱采气CO_(2)回收技术研究进展
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作者 徐赋海 付广永 +1 位作者 李乐天 王风 《山东化工》 CAS 2024年第6期118-123,共6页
油田伴生气和CO_(2)驱采气的数量巨大,且其中含有较多的CO_(2),合理回收利用其中的CO_(2)是当前油田开发和气体资源利用的重要研究领域。回收其中的CO_(2)不仅响应国家环境保护政策,而且将其合理的资源化以提高经济效益。本文以油田伴... 油田伴生气和CO_(2)驱采气的数量巨大,且其中含有较多的CO_(2),合理回收利用其中的CO_(2)是当前油田开发和气体资源利用的重要研究领域。回收其中的CO_(2)不仅响应国家环境保护政策,而且将其合理的资源化以提高经济效益。本文以油田伴生气、CO_(2)驱采气的CO_(2)回收技术为研究对象,详细介绍了当前五大类分离提纯工艺的基本原理,并对各工艺的特点以及实用性进行了综合对比与分析。另外总结分析了四类复合方法的适用性,得出变压吸附法+化学吸收法适用于较低CO_(2)浓度含量油田伴生气烃类回收和CO_(2)除杂;膜分离+变压吸附法以及膜分离+化学吸收法适用于CO_(2)浓度较高的CO_(2)驱采气的收集;化学吸收法+低温精馏法适用于制作高纯度的CO_(2)产品气。 展开更多
关键词 油田伴生气 天然气 驱采气 化学吸收法 变压吸附法 膜分离法 低温精馏法
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微反应器内环酯类锂电池添加剂合成研究进展
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作者 王婷 王忠东 +4 位作者 项星宇 何呈祥 朱春英 马友光 付涛涛 《化工学报》 EI CSCD 北大核心 2024年第1期95-109,共15页
锂电池电解液添加剂是一类在锂电池中用量不大,但对改善锂电池高低温性能,提高使用寿命和循环次数等方面发挥重要作用的高附加值电子化学品。随着锂电池等下游应用长期向好地发展,添加剂的需求量不断增长,但传统的釜式反应器由于传递性... 锂电池电解液添加剂是一类在锂电池中用量不大,但对改善锂电池高低温性能,提高使用寿命和循环次数等方面发挥重要作用的高附加值电子化学品。随着锂电池等下游应用长期向好地发展,添加剂的需求量不断增长,但传统的釜式反应器由于传递性能不佳导致产品质量稳定性较差且污染严重。微反应器在微米尺度对流体有着高效分散和混合的优势,能显著提高生产效率、降低生产成本,在锂电池添加剂合成方面受到越来越广泛的关注。本文结合微反应器优异的传递性能,系统综述了微反应器在环酯类锂离子电池电解液添加剂合成中的应用进展,并对添加剂的微化工合成领域的研究方向进行了展望。 展开更多
关键词 微反应器 合成 传递 锂电池电解液添加剂 电子化学品
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油田化学剂毒性评价方法探讨
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作者 于璐 贺丽鹏 +4 位作者 刘卫东 刘芳 孔灿 姜晓雅 魏小芳 《油气田环境保护》 CAS 2024年第2期7-13,共7页
油田化学剂的使用贯穿油气勘探和开发的全过程,但目前其对环境产生的影响甚至毒性作用却不甚明晰。为了探究油田化学剂对环境产生的毒性影响,文章参考了大量国内外的生态毒性的评价方法标准,包括以土壤为载体的化学品毒性评价方法、以... 油田化学剂的使用贯穿油气勘探和开发的全过程,但目前其对环境产生的影响甚至毒性作用却不甚明晰。为了探究油田化学剂对环境产生的毒性影响,文章参考了大量国内外的生态毒性的评价方法标准,包括以土壤为载体的化学品毒性评价方法、以水为载体的化学品毒性评价方法和以高等动物为载体的化学品毒性评价方法。此外,根据油田化学剂本身的独特性质及对其进行毒性评价的限制因素,通过对比与借鉴,得出在众多毒性评价方法中微生物法是最具潜力的油田化学剂毒性评价方法,并提出几点针对油田化学剂的生态毒性评价的思考,为今后油田化学剂在环境中的毒性评价方法和体系的完善提供参考。 展开更多
关键词 油田化学剂 生物毒性评价 环境毒理学
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Synergistic effects of chemical additives and mature compost on reducing H_2S emission during kitchen waste composting
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作者 Yongdi Liu Haihou Wang +9 位作者 Hao Zhang Yueyue Tao Rui Chen Sheng Hang Xiaoyan Ding Meidi Cheng Guochun Ding Yuquan Wei Ting Xu Ji Li 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2024年第5期84-92,共9页
Additives could improve composting performance and reduce gaseous emission,but few studies have explored the synergistic of additives on H_(2)S emission and compost maturity.This research aims to make an investigation... Additives could improve composting performance and reduce gaseous emission,but few studies have explored the synergistic of additives on H_(2)S emission and compost maturity.This research aims to make an investigation about the effects of chemical additives and mature compost on H_(2)S emission and compost maturity of kitchen waste composting.The results showed that additives increased the germination index value and H_(2)S emission reduction over 15 days and the treatment with both chemical additives and mature compost achieved highest germination index value and H_(2)S emission reduction(85%).Except for the treatment with only chemical additives,the total sulfur content increased during the kitchen waste composting.The proportion of effective sulfur was higher with the addition of chemical additives,compared with other groups.The relative abundance of H_(2)S-formation bacterial(Desulfovibrio)was reduced and the relative abundance of bacterial(Pseudomonas and Paracoccus),which could convert sulfur-containing substances and H_(2)S to sulfate was improved with additives.In the composting process with both chemical additives and mature compost,the relative abundance of Desulfovibrio was lowest,while the relative abundance of Pseudomonas and Paracoccus was highest.Taken together,the chemical additives and mature compost achieved H_(2)S emission reduction by regulating the dynamics of microbial community. 展开更多
关键词 Kitchen waste composting Sulfur conversion chemical additives Mature compost Microbial community
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PLA/EC共混制备自降解暂堵剂及性能评价
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作者 李金涛 于洪江 +2 位作者 雷亮 黄鹤云 崔彦琦 《化工技术与开发》 CAS 2024年第3期8-12,共5页
以聚乳酸为主剂,将其与乙基纤维素、腰果酚NSF3、纳米碳酸钙进行熔融共混改性,制备了新型自降解暂堵剂。通过扫描电镜分析和热重分析测试,对暂堵剂的结构进行表征,考察了自降解暂堵剂体系的降解性能、配伍性能、砂床封堵性能、储层保护... 以聚乳酸为主剂,将其与乙基纤维素、腰果酚NSF3、纳米碳酸钙进行熔融共混改性,制备了新型自降解暂堵剂。通过扫描电镜分析和热重分析测试,对暂堵剂的结构进行表征,考察了自降解暂堵剂体系的降解性能、配伍性能、砂床封堵性能、储层保护性能等指标。结果表明,当聚乳酸和乙基纤维素的比例为4∶6时,暂堵剂具有较好的降解性能和热稳定性。90℃、pH=9的条件下,5d的降解率小于30%,15d的降解率大于90%,满足水平钻井作业要求。温度达到223℃时,质量损失仅为0.35%。在钻井液中加入质量分数为3%的暂堵剂后,在0.69MPa压力下,30min侵入石英砂床的深度小于5cm,能起到良好的封堵作用。此外,该暂堵剂与钻井液的配伍性良好,具有降滤失作用,且解堵后不同岩心的渗透率恢复值均在85%以上,具有较好的储层保护性能。 展开更多
关键词 油田化学品 储层保护 自降解 共混 砂床封堵
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XJ-21菌株在胍胶压裂液体系中破胶驱油的复合性能
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作者 翟怀建 董景锋 +3 位作者 张凤娟 尹剑宇 孙秀鹏 赵静 《精细化工》 EI CAS CSCD 北大核心 2024年第4期911-919,共9页
在储层压裂改造过程中,胍胶压裂液体系低温破胶难,储层改造效果差,是新疆油田油藏开发亟待解决的关键技术难题。针对这一技术难题,将微生物强化采油技术应用于压裂液体系中,从新疆油田吉7井区烧房沟组采集到油泥,通过对样品中微生物的... 在储层压裂改造过程中,胍胶压裂液体系低温破胶难,储层改造效果差,是新疆油田油藏开发亟待解决的关键技术难题。针对这一技术难题,将微生物强化采油技术应用于压裂液体系中,从新疆油田吉7井区烧房沟组采集到油泥,通过对样品中微生物的富集培养及分离,筛选得到一株能够高产生物表面活性剂的菌株,将其命名为XJ-21。结合菌落形态观察、革兰氏染色及16S rRNA序列分析结果,XJ-21菌株被鉴定为枯草芽孢杆菌(Bacillussubitlis)。FTIR分析确定XJ-21代谢产物中的生物表面活性剂与环脂肽类结构一致。XJ-21菌株与外源ZW-027菌株复配后,复配体系对油藏环境条件具有广泛适应性,不仅在温度为35~55℃的范围内可以产生物酶使胍胶冻胶破胶,还可在50℃下降低样品所在区块的原油黏度,降黏率可达95.45%。在水驱后,使用复配体系驱油与仅用水驱技术相比可以提高10.14%的驱油率。 展开更多
关键词 压裂液 胍胶 微生物强化采油 稠油降黏 表面活性剂 油田化学品
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