Fourfold benzocyclobutene-functionalized perylene bisimide（PBI 4） has been synthesized and its structure was characterized by FTIR,MS and NMR.PBI 4 can react either with itself,or the appropriate dienophiles to form...Fourfold benzocyclobutene-functionalized perylene bisimide（PBI 4） has been synthesized and its structure was characterized by FTIR,MS and NMR.PBI 4 can react either with itself,or the appropriate dienophiles to form the corresponding products under appropriate temperature.The polymer film obtained from the reaction of PBI 4 with methyl vinyl silicone rubber possessed excellent film forming properties including flatness.The optical properties of PBI 4 and polymer film obtained from the reaction of PBI 4 and methyl vinyl silicone rubber have been determined by UV/vis and fluorescence spectroscopy.展开更多
基金supported by the Science and Technology Development Foundation of China Academy of Engineering Physics (Nos.2012A0302015,2012B0302050 and 2013B0302051)Doctoral Fund of Southwest University of Science and Technology (No.13zx7133)
文摘Fourfold benzocyclobutene-functionalized perylene bisimide（PBI 4） has been synthesized and its structure was characterized by FTIR,MS and NMR.PBI 4 can react either with itself,or the appropriate dienophiles to form the corresponding products under appropriate temperature.The polymer film obtained from the reaction of PBI 4 with methyl vinyl silicone rubber possessed excellent film forming properties including flatness.The optical properties of PBI 4 and polymer film obtained from the reaction of PBI 4 and methyl vinyl silicone rubber have been determined by UV/vis and fluorescence spectroscopy.
