The simple equation relating the activity coefficient of each solute in mixed electrolyte solution to its value in binary solutions under isopiestic equilibrium was tested by comparison with the experimental data for ...The simple equation relating the activity coefficient of each solute in mixed electrolyte solution to its value in binary solutions under isopiestic equilibrium was tested by comparison with the experimental data for the 18 electrolyte solutions consisting of 1：1, 1：2, and 1：3 electrolytes. The isopiestic measurements were made on the quaternary system BaCl2-NH4Br-NaI-H2O and its ternary subsystems NaI-NH4Br-H2O, NaI-BaCl2-H2O, and NH4Br-BaCl2-H2O at 298.15K. The results were used to test the applicability of the Zdanovskii＇s rule to the mixed electrolyte solutions which contain no common ions, and the agreement is excellent. The activity coefficients of the solutes in the above quaternary and ternary systems calculated from the above-mentioned simple equation are in good agreement with the Pitzer＇s equation.展开更多
The isothermal dissolution equilibrium method has been used to investigate the solid and liquid equilibria of quatemary system Li2SO4-Na2SO4-K2SO4-H2O at 288 K. The phase diagram and water diagram were plotted accordi...The isothermal dissolution equilibrium method has been used to investigate the solid and liquid equilibria of quatemary system Li2SO4-Na2SO4-K2SO4-H2O at 288 K. The phase diagram and water diagram were plotted according to the experiment results. It was found that LizSO4-Na2SO4-K2SO4-H2O quaternary system contains four double salts at 288 K. There are six invariant points, twelve univariant curves and seven areas of crystallization： Li2SO4·H2O, Na2SO4·10H2O, K2SO4,LiESO4·3Na2SO4-12H2O, Li2SO4K2SO4, Na2SO4·3K2SO4, 2Li2SO4·Na2SO4- K2SO4. Using the equilibrium solubility data of the quaternary system at 288 K, the solubility product（lnKsp） of solid phase 2LiESO4-Na2SO4.KESO4, which is not reported was acquired. Based on the chemical model of Pitzer＇s electrolyte solution theory, the solubilities for the quaternary system Li2SO4-Na2SO4-K2SO4-H2O at 288 K were calculated with corresponding parameters. Compared the results of experimental measurement with those of calculation, it was shown that the calculated values had a good agreement with the experimental ones.展开更多
Component solubility in HCl-LiCl-MgCl2-H2O system of high ionic strength at 20℃ was predicted by using the Pitzer＇s ion-interaction model. The results indicated that the model supplied a very good prediction of the ...Component solubility in HCl-LiCl-MgCl2-H2O system of high ionic strength at 20℃ was predicted by using the Pitzer＇s ion-interaction model. The results indicated that the model supplied a very good prediction of the component solubility of the system mentioned above. The values of parameters of β^0, β^1 and C^＊ of HCl, LiCl and MgCl2 were obtained from optimization of literature data, while those of θMN and ψMNX were calculated from a least-squares optimization procedure to couple activity coefficient with solubility data. According to the ion-interaction model, no additional parameters need to be determined for more complex systems. The study provided theoretical basis for the manufacture process, which was proposed by Gao and employed to extract LiCl and MgCl2·6H2O from salt lake brine.展开更多
基金the National-Natural Science Foundation of China （No.20476059, No.20276037） and 863 Hi-Technology Research and Development Program of China （2004 AA616040）.
文摘The simple equation relating the activity coefficient of each solute in mixed electrolyte solution to its value in binary solutions under isopiestic equilibrium was tested by comparison with the experimental data for the 18 electrolyte solutions consisting of 1：1, 1：2, and 1：3 electrolytes. The isopiestic measurements were made on the quaternary system BaCl2-NH4Br-NaI-H2O and its ternary subsystems NaI-NH4Br-H2O, NaI-BaCl2-H2O, and NH4Br-BaCl2-H2O at 298.15K. The results were used to test the applicability of the Zdanovskii＇s rule to the mixed electrolyte solutions which contain no common ions, and the agreement is excellent. The activity coefficients of the solutes in the above quaternary and ternary systems calculated from the above-mentioned simple equation are in good agreement with the Pitzer＇s equation.
基金Supported by the National Natural Science Foundation of China（Nos.U1407108, 41373062） and the Scientific Research and Innovation Team in Universities of Sichuan Provincial Department of Education, China（No. 15TD0009）.
文摘The isothermal dissolution equilibrium method has been used to investigate the solid and liquid equilibria of quatemary system Li2SO4-Na2SO4-K2SO4-H2O at 288 K. The phase diagram and water diagram were plotted according to the experiment results. It was found that LizSO4-Na2SO4-K2SO4-H2O quaternary system contains four double salts at 288 K. There are six invariant points, twelve univariant curves and seven areas of crystallization： Li2SO4·H2O, Na2SO4·10H2O, K2SO4,LiESO4·3Na2SO4-12H2O, Li2SO4K2SO4, Na2SO4·3K2SO4, 2Li2SO4·Na2SO4- K2SO4. Using the equilibrium solubility data of the quaternary system at 288 K, the solubility product（lnKsp） of solid phase 2LiESO4-Na2SO4.KESO4, which is not reported was acquired. Based on the chemical model of Pitzer＇s electrolyte solution theory, the solubilities for the quaternary system Li2SO4-Na2SO4-K2SO4-H2O at 288 K were calculated with corresponding parameters. Compared the results of experimental measurement with those of calculation, it was shown that the calculated values had a good agreement with the experimental ones.
文摘Component solubility in HCl-LiCl-MgCl2-H2O system of high ionic strength at 20℃ was predicted by using the Pitzer＇s ion-interaction model. The results indicated that the model supplied a very good prediction of the component solubility of the system mentioned above. The values of parameters of β^0, β^1 and C^＊ of HCl, LiCl and MgCl2 were obtained from optimization of literature data, while those of θMN and ψMNX were calculated from a least-squares optimization procedure to couple activity coefficient with solubility data. According to the ion-interaction model, no additional parameters need to be determined for more complex systems. The study provided theoretical basis for the manufacture process, which was proposed by Gao and employed to extract LiCl and MgCl2·6H2O from salt lake brine.
