The magnetic aftereffect （MAE） and the positron lifetime were measured at room temperature on the Fe73.5Cu1 Nb3Si13.5 B9 alloy in as-cast and after annealing at temperature Ta in the range from 450 to 750℃ It was f...The magnetic aftereffect （MAE） and the positron lifetime were measured at room temperature on the Fe73.5Cu1 Nb3Si13.5 B9 alloy in as-cast and after annealing at temperature Ta in the range from 450 to 750℃ It was found that both the MAE and the positron lifetime decrease with increasing Ta when T≤600℃. While Ta≥650℃, MAE is essentially suppressed, and two positron lifetimes appear.展开更多
Introduction In this study,a high-time-resolution electronic module with a high channel density and low power consumption was designed for the measurement of the multi-detector array positron annihilation lifetimes.Th...Introduction In this study,a high-time-resolution electronic module with a high channel density and low power consumption was designed for the measurement of the multi-detector array positron annihilation lifetimes.This electronic module consisted of 32 input channels,and each channel provided a high sampling rate up to 5.12 GSPS based on a Domino Ring Sampler 4(DRS4)chip.Compared to the high-speed flash analog-digital converter(FADC),DRS4 chip has a higher channel density with an affordable lower price and power consumption.Methods The developed electronic module was also capable of real-time data analysis for directly extracting the time information of input signals at the data acquisition site,thereby significantly decreasing the data rate.The digital constant fraction discriminator(DCFD)algorithm was implemented in the field programmable gate array(FPGA)for performing the time pick-up.Results The coincidence time resolution of the electronic module was measured,and the test results revealed a value of 26 ps.A prototypical 16-pixel detector module of the multi-detector system was evaluated using this electronic module,and the coincidence time resolution of the prototypical module was 411.84 ps.Conclusions The electronic module was confirmed to satisfy the severe requirements of the multi-array-detector positron annihilation lifetime measurement system.It was also suitable for other high-time-resolution,high-channel-density,costeffective,and low-power-consumption applications.展开更多
To realize efficient atmospheric CO_(2) chemisorption and activation,abundant Ti^(3+) sites and oxygen vacancies in TiO_(2) ultrathin layers were designed.Positron annihilation lifetime spectroscopy and theoretical ca...To realize efficient atmospheric CO_(2) chemisorption and activation,abundant Ti^(3+) sites and oxygen vacancies in TiO_(2) ultrathin layers were designed.Positron annihilation lifetime spectroscopy and theoretical calculations first unveil each oxygen vacancy is associated with the formation of two Ti^(3+)sites,giving a Ti^(3+)-V_(o)-Ti^(3+) configuration.The Ti^(3+)-V_(o)-Ti^(3+) sites could bond with CO_(2) molecules to form a stable configuration,which converted the endoergic chemisorption step to an exoergic process,verified by in-situ Fourier-transform infrared spectra and theoretical calculations.Also,the adjacent Ti^(3+)sites not only favor CO_(2) activation into COOH*via forming a stable Ti^(3+)–C–O–Ti^(3+) configuration,but also facilitate the rate-limiting COOH^(*)scission to CO^(*)by reducing the energy barrier from 0.75 to 0.45 e V.Thus,the Ti^(3+)-V_(o)-TiO_(2) ultrathinlayers could directly capture and photofix atmospheric CO_(2) into near-unity CO,with the corresponding CO_(2)-to-CO conversion ratio of ca.20.2%.展开更多
Void swelling,which induces the degradation of the original properties of nuclear materials under high-energy particleirradiation,is an important problem.The incubation period,a transient stage before the steady void ...Void swelling,which induces the degradation of the original properties of nuclear materials under high-energy particleirradiation,is an important problem.The incubation period,a transient stage before the steady void growth,determines the duration of service of nuclear materials.Several experimental studies have been performed on void observations by transmission electron microscopy(TEM),which,however,has a resolution limit for the size of defect clusters.Positron annihilation lifetime spectroscopy(PALS)enables the detection of small vacancy clusters,single vacancies,dislocations and precipitates.The use of these two methods provides complementary information toward detecting defect information in the incubation period.Here,defect structures during the incubation period in austenitic stainless steels,by means of PALS and TEM are reviewed.The role of alloying elements into determining the period is explained.Furthermore,the existing problems and research directions in this field are presented.展开更多
文摘The magnetic aftereffect （MAE） and the positron lifetime were measured at room temperature on the Fe73.5Cu1 Nb3Si13.5 B9 alloy in as-cast and after annealing at temperature Ta in the range from 450 to 750℃ It was found that both the MAE and the positron lifetime decrease with increasing Ta when T≤600℃. While Ta≥650℃, MAE is essentially suppressed, and two positron lifetimes appear.
基金the National Natural Science Foundation of China(Grant Nos.11475206,11675191 and 11475197).
文摘Introduction In this study,a high-time-resolution electronic module with a high channel density and low power consumption was designed for the measurement of the multi-detector array positron annihilation lifetimes.This electronic module consisted of 32 input channels,and each channel provided a high sampling rate up to 5.12 GSPS based on a Domino Ring Sampler 4(DRS4)chip.Compared to the high-speed flash analog-digital converter(FADC),DRS4 chip has a higher channel density with an affordable lower price and power consumption.Methods The developed electronic module was also capable of real-time data analysis for directly extracting the time information of input signals at the data acquisition site,thereby significantly decreasing the data rate.The digital constant fraction discriminator(DCFD)algorithm was implemented in the field programmable gate array(FPGA)for performing the time pick-up.Results The coincidence time resolution of the electronic module was measured,and the test results revealed a value of 26 ps.A prototypical 16-pixel detector module of the multi-detector system was evaluated using this electronic module,and the coincidence time resolution of the prototypical module was 411.84 ps.Conclusions The electronic module was confirmed to satisfy the severe requirements of the multi-array-detector positron annihilation lifetime measurement system.It was also suitable for other high-time-resolution,high-channel-density,costeffective,and low-power-consumption applications.
基金This work was supported by the National Key R&D Program of China(2019YFA0210004,2017YFA0207301,2017YFA0303500)the National Natural Science Foundation of China(21975242,U2032212,21890754,21805267,21703222,11975225)+7 种基金the Strategic Priority Research Program of Chinese Academy of Sciences(XDB36000000)Youth Innovation Promotion Association of CAS(CX2340007003)Key Research Program of Frontier Sciences of CAS(QYZDY-SSW-SLH011)Major Program of Development Foundation of Hefei Center for Physical Science and Technology(2020HSC-CIP003)Users with Excellence Program of Hefei Science Center CAS(2020HSCUE001)The University Synergy Innovation Program of Anhui Province(GXXT-2020-001)the Fok Ying-Tong Education Foundation(161012)Supercomputing USTC and National Supercomputing Center in Shenzhen are acknowledged for computational support.
文摘To realize efficient atmospheric CO_(2) chemisorption and activation,abundant Ti^(3+) sites and oxygen vacancies in TiO_(2) ultrathin layers were designed.Positron annihilation lifetime spectroscopy and theoretical calculations first unveil each oxygen vacancy is associated with the formation of two Ti^(3+)sites,giving a Ti^(3+)-V_(o)-Ti^(3+) configuration.The Ti^(3+)-V_(o)-Ti^(3+) sites could bond with CO_(2) molecules to form a stable configuration,which converted the endoergic chemisorption step to an exoergic process,verified by in-situ Fourier-transform infrared spectra and theoretical calculations.Also,the adjacent Ti^(3+)sites not only favor CO_(2) activation into COOH*via forming a stable Ti^(3+)–C–O–Ti^(3+) configuration,but also facilitate the rate-limiting COOH^(*)scission to CO^(*)by reducing the energy barrier from 0.75 to 0.45 e V.Thus,the Ti^(3+)-V_(o)-TiO_(2) ultrathinlayers could directly capture and photofix atmospheric CO_(2) into near-unity CO,with the corresponding CO_(2)-to-CO conversion ratio of ca.20.2%.
文摘Void swelling,which induces the degradation of the original properties of nuclear materials under high-energy particleirradiation,is an important problem.The incubation period,a transient stage before the steady void growth,determines the duration of service of nuclear materials.Several experimental studies have been performed on void observations by transmission electron microscopy(TEM),which,however,has a resolution limit for the size of defect clusters.Positron annihilation lifetime spectroscopy(PALS)enables the detection of small vacancy clusters,single vacancies,dislocations and precipitates.The use of these two methods provides complementary information toward detecting defect information in the incubation period.Here,defect structures during the incubation period in austenitic stainless steels,by means of PALS and TEM are reviewed.The role of alloying elements into determining the period is explained.Furthermore,the existing problems and research directions in this field are presented.
