Sharing the advantages of high optical power,high efficiency and design flexibility in a compact size,quantum cascade lasers(QCLs)are excellent mid-to-far infrared laser sources for gas sensing,infrared spectroscopic,...Sharing the advantages of high optical power,high efficiency and design flexibility in a compact size,quantum cascade lasers(QCLs)are excellent mid-to-far infrared laser sources for gas sensing,infrared spectroscopic,medical diagnosis,and defense applications.Metalorganic chemical vapor deposition(MOCVD)is an important technology for growing high quality semiconductor materials,and has achieved great success in the semiconductor industry due to its advantages of high efficiency,short maintenance cycles,and high stability and repeatability.The utilization of MOCVD for the growth of QCL materials holds a significant meaning for promoting the large batch production and industrial application of QCL devices.This review summarizes the recent progress of QCLs grown by MOCVD.Material quality and the structure design together determine the device performance.Research progress on the performance improvement of MOCVD-grown QCLs based on the optimization of material quality and active region structure are mainly reviewed.展开更多
For mode selection in a quantum cascade laser(QCL),we demonstrate an anti-symmetric sampled grating(ASG).The wavelength of the-1-th mode of this laser has been blue-shifted more than 75 nm(~10 cm^(-1))compared with th...For mode selection in a quantum cascade laser(QCL),we demonstrate an anti-symmetric sampled grating(ASG).The wavelength of the-1-th mode of this laser has been blue-shifted more than 75 nm(~10 cm^(-1))compared with that of an ordinary sampled grating laser with an emission wavelength of approximately 8.6μm,when the periodicities within both the base grating and the sample grating are kept constant.Under this condition,an improvement in the continuous tuning capability of the QCL array is ensured.The ASG structure is fabricated in holographic exposure and optical photolithography,thereby enhancing its flexibility,repeatability,and cost-effectiveness.The wavelength modulation capability of the two channels of the grating is insensitive to the variations in channel size,assuming that the overall waveguide width remains constant.The output wavelength can be tailored freely within a certain range by adjusting the width of the ridge and the material of the cladding layer.展开更多
Arson presents a challenging crime scene for fire investigators worldwide. Key to the investigation of suspected arson cases is the analysis of fire debris for the presence of accelerants or ignitable liquids. This st...Arson presents a challenging crime scene for fire investigators worldwide. Key to the investigation of suspected arson cases is the analysis of fire debris for the presence of accelerants or ignitable liquids. This study has investigated the application and method development of vapor phase mid-Infrared (mid-IR) spectroscopy using a field portable quantum cascade laser (QCL) based system for the detection and identification of accelerant residues such as gasoline, diesel, and ethanol in fire debris. A searchable spectral library of various ignitable fluids and fuel components measured in the vapor phase was constructed that allowed for real-time identification of accelerants present in samples using software developed in-house. Measurement of vapors collected from paper material that had been doused with an accelerant followed by controlled burning and then extinguished with water showed that positive identification could be achieved for gasoline, diesel, and ethanol. This vapor phase mid-IR QCL method is rapid, easy to use, and has the sensitivity and discrimination capability that make it well suited for non-destructive crime scene sample analysis. Sampling and measurement can be performed in minutes with this 7.5 kg instrument. This vibrational spectroscopic method required no time-consuming sample pretreatment or complicated solvent extraction procedure. The results of this initial feasibility study demonstrate that this portable fire debris analyzer would greatly benefit arson investigators performing analysis on-site.展开更多
Robust quantum cascade laser(QCL)enduring high temperature continuous-wave(CW)operation is of critical importance for some applications.We report on the realization of lattice-matched InGaAs/InAlAs/InP QCL materials g...Robust quantum cascade laser(QCL)enduring high temperature continuous-wave(CW)operation is of critical importance for some applications.We report on the realization of lattice-matched InGaAs/InAlAs/InP QCL materials grown by metal-organic chemical vapor deposition(MOCVD).High interface quality structures designed for light emission at 8.5μm are achieved by optimizing and precise controlling of growth conditions.A CW output power of 1.04 W at 288 K was obtained from a 4 mm-long and 10μm-wide coated laser.Corresponding maximum wall-plug efficiency and threshold current density were 7.1%and 1.18 kA/cm2,respectively.The device can operate in CW mode up to 408 K with an output power of 160 mW.展开更多
In this work,we demonstrated high-power quantum cascade laser(QCL)arrays lasing at λ~5μm by employing an optimized coupled-ridge waveguide(CRW)structure.Five-element QCL arrays were simulated and fabricated through ...In this work,we demonstrated high-power quantum cascade laser(QCL)arrays lasing at λ~5μm by employing an optimized coupled-ridge waveguide(CRW)structure.Five-element QCL arrays were simulated and fabricated through a two-step etching method to extend the CRW structure to a mid-wave infrared regime.A lateral far-field with the main peak near a diffraction-limited intensity curve of about 10°was observed by properly designing a geometric shape of the ridges and interspaces.By introducing a buried 2nd-order distributed feedback(DFB)grating,substrate emission with a radiation power above 1 W at 25℃ is achieved.Single longitudinal mode operation is obtained by changing the temperature of the heatsink with a good linear wavelength tuning coefficient of -0.2 cm^(-1)/K.展开更多
We demonstrate a broad gain,continuous-wave(CW)operation InP-based quantum cascade laser(QCL)emitting at 11.8μm with a modified dual-upper-state(DAU)and diagonal transition active region design.A 3 mm cavity length,1...We demonstrate a broad gain,continuous-wave(CW)operation InP-based quantum cascade laser(QCL)emitting at 11.8μm with a modified dual-upper-state(DAU)and diagonal transition active region design.A 3 mm cavity length,16.5μm average ridge wide QCL with high-reflection(HR)coatings demonstrates a maximum peak power of 1.07 W at 283 K and CW output power of 60 m W at 293 K.The device also shows a broad and dual-frequency lasing spectrum in pulsed mode and a maximum average power of 258.6 mW at 283 K.Moreover,the full width at half maximum(FWHM)of the electroluminescent spectrum measured at subthreshold current is 2.37μm,which indicates a broad gain spectrum of the materials.The tuning range of 1.38μm is obtained by a grating-coupled external cavity(EC)Littrow configuration,which is beneficial for gas detection.展开更多
A multimode interference(MMI)structure is designed to simplify the fabrication of quantum cascade laser(QCL)phase-locked arrays.The MMI geometry is optimized with a sufficient output channel distance to accommodate co...A multimode interference(MMI)structure is designed to simplify the fabrication of quantum cascade laser(QCL)phase-locked arrays.The MMI geometry is optimized with a sufficient output channel distance to accommodate conventional photolithography and wet etching process by which power amplifier array is fabricated without using the complicated two-step etching-regrowth or dry etching technique.The far-field pattern with periodically modulated peaks reveals that the beams from the arrays are phase-locked.Furthermore,the frequency tuning performance of the MMI-based phase-locked arrays is studied using the Littrow-configuration external cavity structure.A wavelength tuning range of more than 60 cm^(−1) is demonstrated,which will eventually realize the high power,frequency tunable,large-scale phase-locked arrays,and their application in spectroscopy.展开更多
The pulse generation from active mode-locking terahertz quantum cascade laser is studied by Maxwell-Bloch equations.It is shown that longer dephasing time will lead to multiple pulses generation from the laser.The dep...The pulse generation from active mode-locking terahertz quantum cascade laser is studied by Maxwell-Bloch equations.It is shown that longer dephasing time will lead to multiple pulses generation from the laser.The dependence of output field on modulation length and radio-frequency parameters is obtained.In order to achieve short pulse generation,the DC bias should close to threshold value and modulation length should be shorter than 0.256 mm.The output pulse is unstable and the envelope shows many oscillations in the presence of spatial hole burning,resulting destabilization of mode-locking.展开更多
Dynamic states in mutual-coupled mid-infrared quantum cascade lasers(QCLs) were numerically investigated in the parameter space of injection strength and detuning frequency based on the Lang-Kobayashi equations model....Dynamic states in mutual-coupled mid-infrared quantum cascade lasers(QCLs) were numerically investigated in the parameter space of injection strength and detuning frequency based on the Lang-Kobayashi equations model. Three types of period-one states were found, with different periods of injection time delay τ_(inj), 2τ_(inj), and reciprocal of the detuning frequency. Besides, square-wave, quasi-period, pulse-burst and chaotic oscillations were also observed. It is concluded that external-cavity periodic dynamics and optical modes beating are the mainly periodic dynamics. The interaction of the two periodic dynamics and the high-frequency dynamics stimulated by strong injection induces the dynamic states evolution.This work helps to understand the dynamic behaviors in QCLs and shows a new way to mid-infrared wide-band chaotic laser.展开更多
An external cavity quantum cascade laser(QCL)array with a wide tuning range and high output power is presented.The coherent QCL array combined with a diffraction grating and gold mirror is tuned in the Littrow configu...An external cavity quantum cascade laser(QCL)array with a wide tuning range and high output power is presented.The coherent QCL array combined with a diffraction grating and gold mirror is tuned in the Littrow configuration.Taking advantage of the single-lobed fundamental supermode far-field pattern,the tuning capability of 30.6 cm^(-1)is achieved with a fixed injected current of 3.5 A at room temperature.Single-mode emission can be observed in the entire process.The maximum single-mode output power of the external cavity setup is as high as 25 mW and is essential in real applications.展开更多
<div style="text-align:justify;"> In this paper, we report a single-mode Fabry-Pérot long wave infrared quantum cascade lasers based on the double phonon resonance active region design. For room t...<div style="text-align:justify;"> In this paper, we report a single-mode Fabry-Pérot long wave infrared quantum cascade lasers based on the double phonon resonance active region design. For room temperature CW operation, the wafer with 35 stages was processed into buried heterostructure lasers. For a 4 mm long and 13 μm wide laser with high-reflectivity (HR) coating on the rear facet, continuous wave output power of 43 mW at 288 K and 5 mW at 303 K is obtained with threshold current densities of 2.17 and 2.7 kA/cm2. The lasing wavelength is around 10.5 μm. Single mode emission was observed for this particular device over the whole investigated current and temperature range. </div>展开更多
A 7.8-μm surface emitting second-order distributed feedback quantum cascade laser(DFB QCL) structure with metallized surface grating is studied.The modal property of this structure is described by utilizing coupled-m...A 7.8-μm surface emitting second-order distributed feedback quantum cascade laser(DFB QCL) structure with metallized surface grating is studied.The modal property of this structure is described by utilizing coupled-mode theory where the coupling coefficients are derived from exact Floquet-Bloch solutions of infinite periodic structure.Based on this theory,the influence of waveguide structure and grating topography as well as device length on the laser performance is numerically investigated.The optimized surface emitting second-order DFB QCL structure design exhibits a high surface outcoupling efficiency of 22% and a low threshold gain of 10 cm 1.Using a π phase-shift in the centre of the grating,a high-quality single-lobe far-field radiation pattern is obtained.展开更多
亚热带蔬菜地是氧化亚氮(N_2O)的重要排放源,本研究首次采用基于闭路量子级联激光吸收光谱仪的涡动相关(QCLAS-EC)法观测亚热带蔬菜地秋冬季非施肥阶段的N_2O排放通量,以评估QCLAS-EC法测量亚热带蔬菜地N_2O通量的适用性。结果表明,QCLA...亚热带蔬菜地是氧化亚氮(N_2O)的重要排放源,本研究首次采用基于闭路量子级联激光吸收光谱仪的涡动相关(QCLAS-EC)法观测亚热带蔬菜地秋冬季非施肥阶段的N_2O排放通量,以评估QCLAS-EC法测量亚热带蔬菜地N_2O通量的适用性。结果表明,QCLAS-EC观测系统在野外条件下能长期稳定运行,可观测到N_2O排放的季节变化趋势,其检测限为18.5μg N m^(-2) h^(-1)(95%置信水平),试验期间获得的97.5%的N_2O通量大于此检测限,表明QCLAS-EC观测系统可有效并准确测量亚热带蔬菜地的N_2O排放通量,仪器本身的灵敏度不是通量检测的限制因素。展开更多
In this paper, we report a single-mode Fabry-Pérot long wave infrared quantum cascade lasers based on the double phonon resonance active region design. For room temperature CW operation, the wafer with 35 stages ...In this paper, we report a single-mode Fabry-Pérot long wave infrared quantum cascade lasers based on the double phonon resonance active region design. For room temperature CW operation, the wafer with 35 stages was processed into buried heterostructure lasers. For a 4 mm long and 13 μm wide laser with high-reflectivity (HR) coating on the rear facet, continuous wave output power of 43 mW at 288 K and 5 mW at 303 K is obtained with threshold current densities of 2.17 and 2.7 kA/cm2. The lasing wavelength is around 10.5 μm. Single mode emission was observed for this particular device over the whole investigated current and temperature range.展开更多
For non-invasive measurement of blood glucose levels, a measurement system based on mid-infrared, attenuated-total-reflection spectroscopy equipped with hollow optical fibers, a trapezoidal multi-reflection prism, and...For non-invasive measurement of blood glucose levels, a measurement system based on mid-infrared, attenuated-total-reflection spectroscopy equipped with hollow optical fibers, a trapezoidal multi-reflection prism, and two fixed-wavelength quantum cascade lasers emitting different wavelengths is proposed. From the absorption spectra of lip mucosa measured by Fourier-transform infrared spectrometry, two wavelengths, 1152 cm-1 for absorption by glucose and 1186 cm-1 for the background, were chosen. To reduce measurement errors, the power distribution on the prism surface was investigated, and it was found that some high-intensity spots appear on the prism surface due to the coherency of the laser beam. This inhomogeneous power distribution causes measurement errors for slight movements of the lip mucosa. To homogenize the intensity distribution on the prism, a lens to excite higher modes in the fiber was introduced, and the incident angle was changed to suppress interference due to back-reflected light. These improvements increased the measurement stability, and in-vivo experiments demonstrated that the measured optical absorption correlates well with blood glucose levels.展开更多
We present the detection of hydrogen sulfide(H_(2)S)in a quantum cascade laser(QCL)based gas sensing system employing direct laser absorption spectroscopy.The sensitivity is obtained to be 3.61×10^(−6) cm^(−1)Hz^...We present the detection of hydrogen sulfide(H_(2)S)in a quantum cascade laser(QCL)based gas sensing system employing direct laser absorption spectroscopy.The sensitivity is obtained to be 3.61×10^(−6) cm^(−1)Hz^(−1/2) and the H_(2)S broadening coefficient in N2 is analyzed by fitting to the plot of the Lorentzian half width at the half maximum as a function of N_(2) pressure is 0.1124±0.0031 cm^(−1)·atm^(−1).A simulation based on data from the HITRAN database shows broad agreement with the experimentally obtained spectrum.展开更多
We demonstrate continuous-wave(cw)operation of terahertz(THz)quantum cascade lasers emitting at 3.2 THz based on bound-to-continuum active region and semi-insulating surface-plasmon waveguide design.Optical power of 6...We demonstrate continuous-wave(cw)operation of terahertz(THz)quantum cascade lasers emitting at 3.2 THz based on bound-to-continuum active region and semi-insulating surface-plasmon waveguide design.Optical power of 62 mW with a threshold current density of 285 A/cm^(2)is obtained at 10 K from a 130-μm-wide and 1.5-mm-long laser in cw operation.Maximum cw operation temperature is up to 60 K.In pulsed mode,peak optical power more than 100 mW at 10 K and 2.1 mW at 85 K are observed from a 230-μm-wide and 2-mm-long device.展开更多
A strain-compensated InP-based quantum cascade laser(QCL) structure emitting at 4.6 μm is demonstrated,based on a two-phonon resonant design and grown by solid-source molecular beam epitaxy(MBE).By optimizing the gro...A strain-compensated InP-based quantum cascade laser(QCL) structure emitting at 4.6 μm is demonstrated,based on a two-phonon resonant design and grown by solid-source molecular beam epitaxy(MBE).By optimizing the growth parameters,a very high quality heterostructure with the lowest threshold current densities ever reported for QCLs was fabricated.Threshold current densities as low as 0.47 kA/cm^2 in pulsed operation and 0.56 kA/cm^2 in continuous-wave(cw) operation at 293 K were achieved for this state-of-the-art QCL.A minimum power consumption of 3.65 W was measured for the QCL,uncooled,with a high-reflectivity(HR) coating on its rear facet.展开更多
We demonstrate continuous-wave(CW) high power-efficiency terahertz quantum cascade laser based on semiinsulating surface-plasmon waveguide with epitaxial-side down(Epi-down) mounting process.The performance of the dev...We demonstrate continuous-wave(CW) high power-efficiency terahertz quantum cascade laser based on semiinsulating surface-plasmon waveguide with epitaxial-side down(Epi-down) mounting process.The performance of the device is analyzed in detail.The laser emits at a frequency of ~3.27 THz and has a maximum CW operating temperature of ~ 70 K.The peak output powers are 177 mW in pulsed mode and 149 mW in CW mode at 10 K for 130-μm-wide Epi-down mounted lasers.The record wall-plug efficiencies in direct measurement are 2.26% and 2.05% in pulsed and CW mode,respectively.展开更多
基金supported by National Key Research and Development Program of China (Grant No.2021YFB3201900)National Natural Science Foundation of China (Grant Nos.61991430,62235016)+1 种基金Youth Innovation Promotion Association of CAS (Grant Nos.2022112,Y2022046)Key projects of the Chinese Academy of Sciences (Grant No.XDB43000000)。
文摘Sharing the advantages of high optical power,high efficiency and design flexibility in a compact size,quantum cascade lasers(QCLs)are excellent mid-to-far infrared laser sources for gas sensing,infrared spectroscopic,medical diagnosis,and defense applications.Metalorganic chemical vapor deposition(MOCVD)is an important technology for growing high quality semiconductor materials,and has achieved great success in the semiconductor industry due to its advantages of high efficiency,short maintenance cycles,and high stability and repeatability.The utilization of MOCVD for the growth of QCL materials holds a significant meaning for promoting the large batch production and industrial application of QCL devices.This review summarizes the recent progress of QCLs grown by MOCVD.Material quality and the structure design together determine the device performance.Research progress on the performance improvement of MOCVD-grown QCLs based on the optimization of material quality and active region structure are mainly reviewed.
基金Project supported by the National Basic Research Program of China (Grant No. 2021YFB3201900)in part by the National Natural Science Foundation of China (Grant Nos. 61991430, 61774146, 61790583,61627822, and 61774150)in part by the Key Projects of the Chinese Academy of Sciences (Grant Nos. 2018147, YJKYYQ20190002, QYZDJ-SSW-JSC027,XDB43000000)
文摘For mode selection in a quantum cascade laser(QCL),we demonstrate an anti-symmetric sampled grating(ASG).The wavelength of the-1-th mode of this laser has been blue-shifted more than 75 nm(~10 cm^(-1))compared with that of an ordinary sampled grating laser with an emission wavelength of approximately 8.6μm,when the periodicities within both the base grating and the sample grating are kept constant.Under this condition,an improvement in the continuous tuning capability of the QCL array is ensured.The ASG structure is fabricated in holographic exposure and optical photolithography,thereby enhancing its flexibility,repeatability,and cost-effectiveness.The wavelength modulation capability of the two channels of the grating is insensitive to the variations in channel size,assuming that the overall waveguide width remains constant.The output wavelength can be tailored freely within a certain range by adjusting the width of the ridge and the material of the cladding layer.
文摘Arson presents a challenging crime scene for fire investigators worldwide. Key to the investigation of suspected arson cases is the analysis of fire debris for the presence of accelerants or ignitable liquids. This study has investigated the application and method development of vapor phase mid-Infrared (mid-IR) spectroscopy using a field portable quantum cascade laser (QCL) based system for the detection and identification of accelerant residues such as gasoline, diesel, and ethanol in fire debris. A searchable spectral library of various ignitable fluids and fuel components measured in the vapor phase was constructed that allowed for real-time identification of accelerants present in samples using software developed in-house. Measurement of vapors collected from paper material that had been doused with an accelerant followed by controlled burning and then extinguished with water showed that positive identification could be achieved for gasoline, diesel, and ethanol. This vapor phase mid-IR QCL method is rapid, easy to use, and has the sensitivity and discrimination capability that make it well suited for non-destructive crime scene sample analysis. Sampling and measurement can be performed in minutes with this 7.5 kg instrument. This vibrational spectroscopic method required no time-consuming sample pretreatment or complicated solvent extraction procedure. The results of this initial feasibility study demonstrate that this portable fire debris analyzer would greatly benefit arson investigators performing analysis on-site.
基金The authors would thank Ping Liang and Ying Hu for their help with device fabrication.This work was supported by the National Key Research and Development Program of China(Grant No.2020YFB0408401)in part by the National Natural Science Foundation of China(Grant Nos.61991430,61774146,61790583,61734006,61835011,61674144,61774150,61805168)+1 种基金in part by Beijing Municipal Science&Technology Commission(Grant No.Z201100004020006)in part by the Key Projects of the Chinese Academy of Sciences(Grant Nos.2018147,YJKYYQ20190002,QYZDJ-SSW-JSC027,XDB43000000,ZDKYYQ20200006).
文摘Robust quantum cascade laser(QCL)enduring high temperature continuous-wave(CW)operation is of critical importance for some applications.We report on the realization of lattice-matched InGaAs/InAlAs/InP QCL materials grown by metal-organic chemical vapor deposition(MOCVD).High interface quality structures designed for light emission at 8.5μm are achieved by optimizing and precise controlling of growth conditions.A CW output power of 1.04 W at 288 K was obtained from a 4 mm-long and 10μm-wide coated laser.Corresponding maximum wall-plug efficiency and threshold current density were 7.1%and 1.18 kA/cm2,respectively.The device can operate in CW mode up to 408 K with an output power of 160 mW.
基金supported by National Basic Research Program of China(Grant Nos.2018YFA0209103,2018YFB2200504)in part by National Natural Science Foundation of China(Grant Nos.61991430,61774146,61790583,61734006,61835011,61674144,61774150,61805168)+1 种基金in part by Beijing Municipal Science&Technology Commission(Grant No.Z201100004020006)in part by the Key projects of the Chinese Academy of Sciences(Grant No.2018147,Grant No.YJKYYQ20190002,Grant No.QYZDJ-SSW-JSC027,Grant No.XDB43000000,Grant No.ZDKYYQ20200006).
文摘In this work,we demonstrated high-power quantum cascade laser(QCL)arrays lasing at λ~5μm by employing an optimized coupled-ridge waveguide(CRW)structure.Five-element QCL arrays were simulated and fabricated through a two-step etching method to extend the CRW structure to a mid-wave infrared regime.A lateral far-field with the main peak near a diffraction-limited intensity curve of about 10°was observed by properly designing a geometric shape of the ridges and interspaces.By introducing a buried 2nd-order distributed feedback(DFB)grating,substrate emission with a radiation power above 1 W at 25℃ is achieved.Single longitudinal mode operation is obtained by changing the temperature of the heatsink with a good linear wavelength tuning coefficient of -0.2 cm^(-1)/K.
基金Project supported by the National Basic Research Program of China(Grant No.2018YFA0209103)the National Natural Science Foundation of China(Grant Nos.61991430,61774146,61790583,61734006,61835011,61674144,61774150,and 61805168)+1 种基金Beijing Municipal Science&Technology Commission,China(Grant No.Z201100004020006)the Key Projects of the Chinese Academy of Sciences(Grant Nos.2018147,YJKYYQ20190002,QYZDJ-SSWJSC027,XDB43000000,and ZDKYYQ20200006)。
文摘We demonstrate a broad gain,continuous-wave(CW)operation InP-based quantum cascade laser(QCL)emitting at 11.8μm with a modified dual-upper-state(DAU)and diagonal transition active region design.A 3 mm cavity length,16.5μm average ridge wide QCL with high-reflection(HR)coatings demonstrates a maximum peak power of 1.07 W at 283 K and CW output power of 60 m W at 293 K.The device also shows a broad and dual-frequency lasing spectrum in pulsed mode and a maximum average power of 258.6 mW at 283 K.Moreover,the full width at half maximum(FWHM)of the electroluminescent spectrum measured at subthreshold current is 2.37μm,which indicates a broad gain spectrum of the materials.The tuning range of 1.38μm is obtained by a grating-coupled external cavity(EC)Littrow configuration,which is beneficial for gas detection.
基金supported by the National Basic Research Program of China(Grant Nos.2018YFA0209103 and 2018YFB2200504)the National Natural Science Foundation of China(Grant Nos.61991430,61774146,61790583,61674144,61774150,and 61805168)+1 种基金the Beijing Municipal Science&Technology Commission,China(Grant No.Z201100004020006)the Key Projects of the Chinese Academy of Sciences(Grant Nos.2018147,YJKYYQ20190002,QYZDJ-SSW-JSC027,and XDB43000000).
文摘A multimode interference(MMI)structure is designed to simplify the fabrication of quantum cascade laser(QCL)phase-locked arrays.The MMI geometry is optimized with a sufficient output channel distance to accommodate conventional photolithography and wet etching process by which power amplifier array is fabricated without using the complicated two-step etching-regrowth or dry etching technique.The far-field pattern with periodically modulated peaks reveals that the beams from the arrays are phase-locked.Furthermore,the frequency tuning performance of the MMI-based phase-locked arrays is studied using the Littrow-configuration external cavity structure.A wavelength tuning range of more than 60 cm^(−1) is demonstrated,which will eventually realize the high power,frequency tunable,large-scale phase-locked arrays,and their application in spectroscopy.
基金Project supported by the National Key Research and Development Program of China(Grant No.2017YFF0106302)the National Natural Science Foundation of China(Grant Nos.61975225 and 61927813)Shanghai International Cooperation Project,China(Grant No.18590780100).
文摘The pulse generation from active mode-locking terahertz quantum cascade laser is studied by Maxwell-Bloch equations.It is shown that longer dephasing time will lead to multiple pulses generation from the laser.The dependence of output field on modulation length and radio-frequency parameters is obtained.In order to achieve short pulse generation,the DC bias should close to threshold value and modulation length should be shorter than 0.256 mm.The output pulse is unstable and the envelope shows many oscillations in the presence of spatial hole burning,resulting destabilization of mode-locking.
基金Project supported by the National Key Research and Development Program of China (Grant No. 2019YFB1803500)the National Natural Science Foundation of China (Grant No. 61805168)+4 种基金the Natural Science Foundation of Shanxi Province, China (Grant Nos. 201801D221183 and 20210302123185)International Cooperation of Key Research and Development Program of Shanxi Province (Grant No. 201903D421012)Research Project Supported by Shanxi Scholarship Council of China (Grant No. 2021-032)Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi (Grant No. 2019L0133)Fund for Shanxi “1331 Project” Key Innovative Research Team。
文摘Dynamic states in mutual-coupled mid-infrared quantum cascade lasers(QCLs) were numerically investigated in the parameter space of injection strength and detuning frequency based on the Lang-Kobayashi equations model. Three types of period-one states were found, with different periods of injection time delay τ_(inj), 2τ_(inj), and reciprocal of the detuning frequency. Besides, square-wave, quasi-period, pulse-burst and chaotic oscillations were also observed. It is concluded that external-cavity periodic dynamics and optical modes beating are the mainly periodic dynamics. The interaction of the two periodic dynamics and the high-frequency dynamics stimulated by strong injection induces the dynamic states evolution.This work helps to understand the dynamic behaviors in QCLs and shows a new way to mid-infrared wide-band chaotic laser.
基金Supported by the National Basic Research Program of China under Grant No 2013CB632801the National Key Research and Development Program of China under Grant No 2016YFB0402303+2 种基金the National Natural Science Foundation of China under Grant Nos 61435014,61627822,61574136,61306058 and 61404131the Key Projects of Chinese Academy of Sciences under Grant No ZDRW-XH-2016-4the Beijing Natural Science Foundation under Grant No 4162060
文摘An external cavity quantum cascade laser(QCL)array with a wide tuning range and high output power is presented.The coherent QCL array combined with a diffraction grating and gold mirror is tuned in the Littrow configuration.Taking advantage of the single-lobed fundamental supermode far-field pattern,the tuning capability of 30.6 cm^(-1)is achieved with a fixed injected current of 3.5 A at room temperature.Single-mode emission can be observed in the entire process.The maximum single-mode output power of the external cavity setup is as high as 25 mW and is essential in real applications.
文摘<div style="text-align:justify;"> In this paper, we report a single-mode Fabry-Pérot long wave infrared quantum cascade lasers based on the double phonon resonance active region design. For room temperature CW operation, the wafer with 35 stages was processed into buried heterostructure lasers. For a 4 mm long and 13 μm wide laser with high-reflectivity (HR) coating on the rear facet, continuous wave output power of 43 mW at 288 K and 5 mW at 303 K is obtained with threshold current densities of 2.17 and 2.7 kA/cm2. The lasing wavelength is around 10.5 μm. Single mode emission was observed for this particular device over the whole investigated current and temperature range. </div>
基金Project supported by the National Science Fund for Distinguished Young Scholars of China (Grant No. 60525406)the National Natural Science Foundation of China (Grant Nos. 60736031,60806018,and 60906026)+1 种基金the National Basic Research Program of China (Grant No. 2006CB604903)the National High Technology Research and Development Program of China (Grant Nos. 2007AA03Z446 and 2009AA03Z403)
文摘A 7.8-μm surface emitting second-order distributed feedback quantum cascade laser(DFB QCL) structure with metallized surface grating is studied.The modal property of this structure is described by utilizing coupled-mode theory where the coupling coefficients are derived from exact Floquet-Bloch solutions of infinite periodic structure.Based on this theory,the influence of waveguide structure and grating topography as well as device length on the laser performance is numerically investigated.The optimized surface emitting second-order DFB QCL structure design exhibits a high surface outcoupling efficiency of 22% and a low threshold gain of 10 cm 1.Using a π phase-shift in the centre of the grating,a high-quality single-lobe far-field radiation pattern is obtained.
基金supported from the Ministry of Science and Technology of China[grant number 2012CB417106]the Chinese Academy of Sciences[grant number XDA05020100]+1 种基金the German Science Foundation[contract number BU1173/12-1]the National Natural Science Foundation of China[grant numbers41405137 and 41321064]
文摘亚热带蔬菜地是氧化亚氮(N_2O)的重要排放源,本研究首次采用基于闭路量子级联激光吸收光谱仪的涡动相关(QCLAS-EC)法观测亚热带蔬菜地秋冬季非施肥阶段的N_2O排放通量,以评估QCLAS-EC法测量亚热带蔬菜地N_2O通量的适用性。结果表明,QCLAS-EC观测系统在野外条件下能长期稳定运行,可观测到N_2O排放的季节变化趋势,其检测限为18.5μg N m^(-2) h^(-1)(95%置信水平),试验期间获得的97.5%的N_2O通量大于此检测限,表明QCLAS-EC观测系统可有效并准确测量亚热带蔬菜地的N_2O排放通量,仪器本身的灵敏度不是通量检测的限制因素。
文摘In this paper, we report a single-mode Fabry-Pérot long wave infrared quantum cascade lasers based on the double phonon resonance active region design. For room temperature CW operation, the wafer with 35 stages was processed into buried heterostructure lasers. For a 4 mm long and 13 μm wide laser with high-reflectivity (HR) coating on the rear facet, continuous wave output power of 43 mW at 288 K and 5 mW at 303 K is obtained with threshold current densities of 2.17 and 2.7 kA/cm2. The lasing wavelength is around 10.5 μm. Single mode emission was observed for this particular device over the whole investigated current and temperature range.
文摘For non-invasive measurement of blood glucose levels, a measurement system based on mid-infrared, attenuated-total-reflection spectroscopy equipped with hollow optical fibers, a trapezoidal multi-reflection prism, and two fixed-wavelength quantum cascade lasers emitting different wavelengths is proposed. From the absorption spectra of lip mucosa measured by Fourier-transform infrared spectrometry, two wavelengths, 1152 cm-1 for absorption by glucose and 1186 cm-1 for the background, were chosen. To reduce measurement errors, the power distribution on the prism surface was investigated, and it was found that some high-intensity spots appear on the prism surface due to the coherency of the laser beam. This inhomogeneous power distribution causes measurement errors for slight movements of the lip mucosa. To homogenize the intensity distribution on the prism, a lens to excite higher modes in the fiber was introduced, and the incident angle was changed to suppress interference due to back-reflected light. These improvements increased the measurement stability, and in-vivo experiments demonstrated that the measured optical absorption correlates well with blood glucose levels.
基金by the National Natural Science Foundation of China under Grant Nos 60850006 and 61077057the International S&T Cooperation Program of China under Grant Nos 2007DFC00040 and 2009DFB10440.
文摘We present the detection of hydrogen sulfide(H_(2)S)in a quantum cascade laser(QCL)based gas sensing system employing direct laser absorption spectroscopy.The sensitivity is obtained to be 3.61×10^(−6) cm^(−1)Hz^(−1/2) and the H_(2)S broadening coefficient in N2 is analyzed by fitting to the plot of the Lorentzian half width at the half maximum as a function of N_(2) pressure is 0.1124±0.0031 cm^(−1)·atm^(−1).A simulation based on data from the HITRAN database shows broad agreement with the experimentally obtained spectrum.
基金Supported in part by the 100 Talents Program of Chinese Academy of Sciences under Grant No 1731110000012the National Natural Science Foundation of China under Grant Nos 60736031,60806018 and 60906026the Special-funded Program on National Key Scientific Instruments and Equipment Development under Grant No 2011YQ13001802-4.
文摘We demonstrate continuous-wave(cw)operation of terahertz(THz)quantum cascade lasers emitting at 3.2 THz based on bound-to-continuum active region and semi-insulating surface-plasmon waveguide design.Optical power of 62 mW with a threshold current density of 285 A/cm^(2)is obtained at 10 K from a 130-μm-wide and 1.5-mm-long laser in cw operation.Maximum cw operation temperature is up to 60 K.In pulsed mode,peak optical power more than 100 mW at 10 K and 2.1 mW at 85 K are observed from a 230-μm-wide and 2-mm-long device.
基金supported by the National Basic Research Program of China(Grant Nos.2013CB632801 and 2013CB632803)the National Natural Science Foundation of China(Grant Nos.61306058,61274094,and 61435014)the Beijing Natural Science Foundation(Grant No.4144086)
文摘A strain-compensated InP-based quantum cascade laser(QCL) structure emitting at 4.6 μm is demonstrated,based on a two-phonon resonant design and grown by solid-source molecular beam epitaxy(MBE).By optimizing the growth parameters,a very high quality heterostructure with the lowest threshold current densities ever reported for QCLs was fabricated.Threshold current densities as low as 0.47 kA/cm^2 in pulsed operation and 0.56 kA/cm^2 in continuous-wave(cw) operation at 293 K were achieved for this state-of-the-art QCL.A minimum power consumption of 3.65 W was measured for the QCL,uncooled,with a high-reflectivity(HR) coating on its rear facet.
基金supported by the National Basic Research Program of China(Grant Nos.2014CB339803 and 2013CB632801)the Special-funded Program on National Key Scientific Instruments and Equipment Development,China(Grant No.2011YQ13001802-04)the National Natural Science Foundation of China(Grant No.61376051)
文摘We demonstrate continuous-wave(CW) high power-efficiency terahertz quantum cascade laser based on semiinsulating surface-plasmon waveguide with epitaxial-side down(Epi-down) mounting process.The performance of the device is analyzed in detail.The laser emits at a frequency of ~3.27 THz and has a maximum CW operating temperature of ~ 70 K.The peak output powers are 177 mW in pulsed mode and 149 mW in CW mode at 10 K for 130-μm-wide Epi-down mounted lasers.The record wall-plug efficiencies in direct measurement are 2.26% and 2.05% in pulsed and CW mode,respectively.
