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Phase Equilibria of Salt-water Systems Containing Magnesium and Borate Ions
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作者 HAN Xunian GUO Yafei +1 位作者 WANG Shiqiang DENG Tianlong 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2014年第S1期331-332,共2页
1 Introduction A salt lake is a naturally occurring complex body of water and salt interaction.More than 700 salt lakes are widely distributed in the area of the Qinghai-Tibet Plateau.Most of the salt lakes are famous... 1 Introduction A salt lake is a naturally occurring complex body of water and salt interaction.More than 700 salt lakes are widely distributed in the area of the Qinghai-Tibet Plateau.Most of the salt lakes are famous for their abundance of lithium,potassium,magnesium,and boron resources.It is 展开更多
关键词 salt-water system phase equilibrium MAGNESIUM BORATE
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Salt-Water Transport in Unsaturated Soils Under Crop Planting: Dynamics and Numerical Simulation 被引量:7
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作者 XU Li-Gang YANG Jing-Song +1 位作者 ZHANG Qi LIU Guang-Ming 《Pedosphere》 SCIE CAS CSCD 2005年第5期634-640,共7页
A laboratory salt-water dynamics experiment using unsaturated soils in packed silt loam and clay soil columns withdifferent soil texture profiles and groundwater levels under crops were conducted to study the changes ... A laboratory salt-water dynamics experiment using unsaturated soils in packed silt loam and clay soil columns withdifferent soil texture profiles and groundwater levels under crops were conducted to study the changes of salt-waterdynamics induced by water uptake of crops and to propose the theoretical basis for the regulation and control of salt-water dynamics as well as to predict salinity levels. The HYDRUS 1D model was applied to simulate the one-dimensionalmovement of water and salt transport in the soil columns. The results showed that the salts mainly accumulated in theplow layer in the soil columns under crops. Soil water and salt both moved towards the plow layer due to soil waterabsorption by the crop root system. The salt contents in the column with lower groundwater were mostly greater thanthose with high groundwater. The water contents in the soil columns increased from top to the bottom due to plant rootwater uptake. The changes in groundwater level had little influence on water content of the root zone in the soil columnswith crop planting. Comparison between the simulated and the determined values showed that model simulation resultswere ideal, so it is practicable to do numerical simulation of soil salt and water transport by the HYDRUS 1D model.Furthermore, if the actual movement of salt and water in fields is to be described in detail, much work needs to be done.The most important thing is to refine the parameters and select precise boundary conditions. 展开更多
关键词 crop planting numerical simulation salt accumulation salt-water dynamics
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Salt-Water Dynamics in Soils: II. Effect of Precipitation on Salt-Water Dynamics 被引量:6
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作者 YOUWEN-RUI MENGFAN-HUA 《Pedosphere》 SCIE CAS CSCD 1992年第4期289-306,共18页
Through a simulation test carried out with soil columns (61.8 cm in diameter), the effect of precipitation on salt-water dynamics in soils was studied by in-situ monitoring of salt-water dynamics using soil salinity s... Through a simulation test carried out with soil columns (61.8 cm in diameter), the effect of precipitation on salt-water dynamics in soils was studied by in-situ monitoring of salt-water dynamics using soil salinity sensors and tensiometers. The results show that in the profile of whole silty loam soil, the surface runoff volume due to precipitation and the salt-leaching role of infiltrated precipitation increased with the depth of ground water; and in the profile with an intercalated bed of clay or with a thick upper layer of clay, the amount of surface runoff was greater but the salt-leaching role of precipitation was smaller than those in the profile of whole silty loam soil. In case of soil water being supplemented by precipitation, the evaporation of groundwater in the soil columns reduced, resulting in a great decline of salt accumulation from soil profile to surface soil. The effect of precipitation on the water regime of soil profile was performed via both water infiltration and water pressure transfer. The direct infiltration depth of precipitation was less than 1 m in general, but water pressure transfer could go up to groundwater surface directly. 展开更多
关键词 groundwater evaporation precipitation infiltration salt-water dynamics salt-leaching surface runoff
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Salt-Water Dynamics in Highly Salinized Topsoil of Salt-Affected Soil During Water Infiltration 被引量:4
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作者 WANGXUE-FENG YOUWEN-RUI 《Pedosphere》 SCIE CAS CSCD 1991年第4期315-323,共9页
Continuous monitoring of salt and water movement in the soil profile of highly salinized topsoil under steadystate infiltration was conducted.It gives that salt and water dynamics during convection-diffusion period ca... Continuous monitoring of salt and water movement in the soil profile of highly salinized topsoil under steadystate infiltration was conducted.It gives that salt and water dynamics during convection-diffusion period can be divided into three stages:1.formation of a salt peak,2.the salt peak moving downwards till the appearance of the summit of the salt peak,3.the salt peak moving further downwards with the peak value decreasing.Results show that the maximum salt peak appears at the same depth if soil texture and outflow condition are the same.Factors affecting salt and water movement and ion components in the outflow solution underinfiltration are discussed. 展开更多
关键词 INFILTRATION SALINE salt peak salt-water dynamics
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Environmental evolution in the salt-water intrusion area south of Laizhou Bay since late Pleistocene 被引量:4
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作者 ZHANG Zulu LIU Enfeng +1 位作者 ZHANG Yan XIN Liangjie 《Journal of Geographical Sciences》 SCIE CSCD 2008年第1期37-45,共9页
The south coastal plain of Laizhou Bay is one of the typical salt-water intrusion areas in China, the occurrence and development of which was closely related with the palaeoenvironment evolution. Systematic analyses o... The south coastal plain of Laizhou Bay is one of the typical salt-water intrusion areas in China, the occurrence and development of which was closely related with the palaeoenvironment evolution. Systematic analyses of pollen, foraminifera and grain size composition based on ^14C and luminescence dating from two sediment cores were performed for the purpose of understanding the salt-water intrusion in the coastal plain of Laizhou Bay from the perspective of environmental evolution since late Pleistocene. It could be classified into seven evolution stages since 120 kaBP: 120-85 kaBP was a transition period from cold to warm; 85-76 kaBP was a period with warm and wet climate having swamp lakes developed in the lower reaches of the Weihe River, south coastal plain of Laizhou Bay; 76-50 kaBP was characterized by grassland vegetation and coarse sediments in terrestrial environment, which was the early stage of Dali Ice-Age; 50-24 kaBP was a period with alternate sea deposition in the south coastal plain of Laizhou Bay; 24-10 kaBP was the late stage of Dali Ice-Age with coldest period of Quaternary, the south coastal plain of Laizhou Bay was dry grassland and loess deposition environment; 10-4 kaBP was another warm and wet climate period, sea level was high and regressed at 4 kaBP; and has been the modern sedimentary environment since 4 kaBP. Among the three warm stages, including 85-76 kaBP, 50-24 kaBP and 10-4 kaBP, corresponded to late Yangkou, Guangrao and Kenli seawater transgression respectively. The duration of the latter one in south coastal plain of Laizhou Bay was longer than that in west coast of Bohai Sea and east coast of Laizhou Bay. The three periods of seawater transgression formed the foundation of salt-water intrusion in this area. 展开更多
关键词 environmental evolution salt-water intrusion late Pleistocene south coastal plain of Laizhou Bay China
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Salt-Water Dynamics in Soils: Ⅰ. Salt-Water Dynamics in Unsaturated Soils Under Stable Evaporation Condition 被引量:3
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作者 YOUWEN-RUI MENGFAN-HUA 《Pedosphere》 SCIE CAS CSCD 1992年第3期219-235,共17页
A long term simulation test on salt-water dynamics in unsaturated soils with different groundwater depths and soil texture profiles under stable evaporation condition was conducted.Salinity sensors and tensiometers we... A long term simulation test on salt-water dynamics in unsaturated soils with different groundwater depths and soil texture profiles under stable evaporation condition was conducted.Salinity sensors and tensiometers were used to monitor salt and water variation in soils.The experiment revealed that in the process of fresh groundwater moving upwards by capillary rise in the column,the salts in subsoil were brought upwards and accumulated in the surface soil,and consequently the salinization of surface soil took place.The rate of salt accumulation is determined mainly by the volume of capillary water flow and the conditions of salts contained in the soil profile.Water flux in soils decreased obviously when groundwater depths fell below 1.5m.When there was an interbedded clay layer 30cm in thickness in the silty loam soil profile or a clay layer 100cm in thickness at the top layer,the water flux was 3-5 times less than in the soil profile of homogeneous silty loam soil.Therefore,the rate of salt accumulation was decreased and the effect of variation of groundwater depth on the water flux in soils was weakened comparatively.If there was precipitation or irrigation supplying water to the soil,the groundwater could rarely take a direct part in the process of salt accumulation in surface soil,especially,in soil profiles with an interbedded stratum or a clayey surface soil layer. 展开更多
关键词 evaporation condition salt accumulation salt-water dynamics
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Salt-Water Dynamics in Soils:Ⅲ.Effect of Crop Planting 被引量:3
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作者 YOUWEN-RUI MENGFAN-HUA 《Pedosphere》 SCIE CAS CSCD 1993年第1期7-22,共16页
Through a simulation test conducted with soil columns (61.8cm in diameter) in field condition,effect of crop planting upon the regulation of salt-water dynamics in soils was studied by monitoring of salt-water dynamic... Through a simulation test conducted with soil columns (61.8cm in diameter) in field condition,effect of crop planting upon the regulation of salt-water dynamics in soils was studied by monitoring of salt-water dynamics in situ,using soil salinity sensors and tensiometers.The results indicated that the amount of water absorbed by crops from the soil was generally larger than the decrement of water consumption from soil surface evaporation reduced by the crop covering the soil surface and improving the soil structure,therefore,under the conditions of crop growing and non-irrigation,water content in soil profile was less than that without crop growing,and the gradient of negative pressure of soil water in soil profile especially in the root zone was enlarged,thus causing the water flowing from subsoils into root zone and increasing the groundwater moving upwards into soil layer via capillary rise,so that the groundwater evaporation increased.Consequently,under the condition of crop growing,the salt was mainly accumulated towards the root zone rather than to the top soil.the accumulating rate of salt in groundwater via capillary rise of soil water to subsoils was increased thereby. 展开更多
关键词 groundwater evaporation salt-water dynamics water regime
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Na^(+),K^(+)//CO_(3)^(2-),SO_(4)^(2-)-H_(2)O四元水盐体系相平衡综合实验设计
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作者 杨小俊 于雪松 +2 位作者 龚美玲 王雪茹 闫志国 《实验室研究与探索》 CAS 北大核心 2024年第5期192-195,229,共5页
针对相平衡理论知识抽象难懂,相律、相图等内容难教难学的问题,设计了四元水盐体系相平衡综合实验。采用等温溶解平衡法研究了353~373 K下交互四元体系Na^(+),K^(+)//CO_(3)^(2-),SO_(4)^(2-)-H_(2)O的固液相平衡,并绘制出等温干基相图... 针对相平衡理论知识抽象难懂,相律、相图等内容难教难学的问题,设计了四元水盐体系相平衡综合实验。采用等温溶解平衡法研究了353~373 K下交互四元体系Na^(+),K^(+)//CO_(3)^(2-),SO_(4)^(2-)-H_(2)O的固液相平衡,并绘制出等温干基相图和对应水图,确定硫酸钠相区随着温度的增加而上移。依据相图指导碱灰溶解-蒸发结晶工艺设计,解决了高CO_(3)^(2-)浓度下结晶参数的优化问题,实现Na2SO4在高温下溶解,随后降温结晶析出的循环回收过程。该实验将相平衡数据的测量、相图的绘制、相图的分析融合一体,有利于增强学生用相平衡基本理论解决工程问题的能力,实现对理论知识的融会贯通,激发其科研兴趣和探索精神。 展开更多
关键词 综合实验 相平衡 水盐体系 结晶
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水汽系统积盐问题分析及处理
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作者 文慧峰 张兆 +1 位作者 韩涛 位承君 《热力发电》 CAS CSCD 北大核心 2024年第3期161-166,共6页
尿素水解制氨技术已广泛应用于火电机组脱硝还原剂的制备。然而,若出现尿素质量不合格,尿素水解器发生泄漏以及水解器疏水回用至凝汽器的情况,会对热力系统造成巨大危害。对某燃煤机组尿素水解器泄漏致水汽系统严重积盐及过热器爆管进... 尿素水解制氨技术已广泛应用于火电机组脱硝还原剂的制备。然而,若出现尿素质量不合格,尿素水解器发生泄漏以及水解器疏水回用至凝汽器的情况,会对热力系统造成巨大危害。对某燃煤机组尿素水解器泄漏致水汽系统严重积盐及过热器爆管进行了分析,并提出了补充处理方案。实施后机组各项水汽指标均达到《火力发电机组及蒸汽动力设备水汽质量》(GB/T 12145—2016)要求,为水汽系统积盐的原因分析及处理提供了解决方案。 展开更多
关键词 尿素水解器 泄漏 汽轮机 水汽系统 积盐 水冲洗
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四元体系(NaB_(5)O_(8)+KB_(5)O_(8)+RbB_(5)O_(8)+H_(2)O)288.15 K固液相平衡与相图研究 被引量:1
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作者 陈燕 王佳悦 +3 位作者 王丹阳 郭亚飞 王士强 邓天龙 《地球学报》 CAS CSCD 北大核心 2024年第5期807-813,共7页
我国东台吉乃尔盐湖卤水中锂钾硼含量显著,水盐体系相平衡与相图为盐湖矿物的分离提取提供了理论基础。本文对四元体系(NaB_(5)O_(8)+KB_(5)O_(8)+RbB_(5)O_(8)+H_(2)O)在288.15 K时的相平衡与相图采用等温溶解平衡法研究,实验得出溶解... 我国东台吉乃尔盐湖卤水中锂钾硼含量显著,水盐体系相平衡与相图为盐湖矿物的分离提取提供了理论基础。本文对四元体系(NaB_(5)O_(8)+KB_(5)O_(8)+RbB_(5)O_(8)+H_(2)O)在288.15 K时的相平衡与相图采用等温溶解平衡法研究,实验得出溶解度以及平衡液相的密度和折光率这两个主要物化性质,分析且鉴定出存在的盐湖矿物种类。研究发现:288.15 K时,该体系稳定相图中的共饱点(NaB_(5)O_(8)·5H_(2)O+KB_(5)O_(8)·4H_(2)O+RbB_(5)O_(8)·4H_(2)O)的液相组成为w(NaB_(5)O_(8))=9.02%、w(KB_(5)O_(8))=0.47%、w(RbB_(5)O_(8))=0.21%,且3种盐类矿物(NaB_(5)O_(8)·5H_(2)O、KB_(5)O_(8)·4H_(2)O、RbB_(5)O_(8)·4H_(2)O)的体系没有固溶体或复盐生成。三个矿物中RbB_(5)O_(8)·4H_(2)O的结晶区面积最大,溶解度最小。液相的折光率和密度均随Z(NaB_(5)O_(8))的增加呈规律性变化,密度和折光率均采用经验公式进行相对误差计算,所得计算值与实验值吻合较好。 展开更多
关键词 水盐体系 固液相平衡与相图 盐类矿物 溶解度 五硼酸盐
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光卤石原矿品位对其冷分解结晶氯化钾过程影响浅析 被引量:1
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作者 郭凯花 范雨薪 +3 位作者 杨静 赵文立 贾原媛 王彦飞 《无机盐工业》 CAS CSCD 北大核心 2024年第8期9-18,共10页
光卤石冷分解结晶是国内生产氯化钾的主要工艺,但随着光卤石原矿品位的下降,原有技术生产的氯化钾产品出现了粒度变小、易聚结、纯度差且收率低等问题,已成为困扰氯化钾行业发展的难题。对比了不同地区钾盐原矿品质,结合Na^(+)、K^(+)、... 光卤石冷分解结晶是国内生产氯化钾的主要工艺,但随着光卤石原矿品位的下降,原有技术生产的氯化钾产品出现了粒度变小、易聚结、纯度差且收率低等问题,已成为困扰氯化钾行业发展的难题。对比了不同地区钾盐原矿品质,结合Na^(+)、K^(+)、Mg^(2+)∥Cl^(-)-H_(2)O四元体系及其子体系的热力学相平衡规律,概述了原矿品质对分解结晶过程析盐规律的影响,从分解-结晶耦合过程动力学角度,总结了不同品位光卤石冷分解结晶制备氯化钾过程的产品粒度及形貌调控关键因素及其作用机理。结合产品现行标准,提出低钠光卤石、含钠光卤石和高钠光卤石的新分类方法和对应的工艺选择策略,并对不同品位光卤石原矿的冷分解结晶新工艺进行展望,以期为行业健康发展提供理论指导与参考。 展开更多
关键词 光卤石 氯化钾 冷分解结晶 水盐体系相平衡 粒度及粒度分布
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Polyoxometalates-Modulated Hydrophilic-Hydrophobic Composite Interfacial Material for Efficient Solar Water Evaporation and Salt Harvesting in High-Salinity Brine
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作者 Sihang Cheng Cuimei Liu +3 位作者 Yingqi Li Huaqiao Tan Yonghui Wang Yangguang Li 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第3期219-227,共9页
Solar vapor generation(SVC)represents a promising technique for seawater desalination to alleviate the global water crisis and energy shortage.One of its main bottleneck problems is that the evaporation efficiency and... Solar vapor generation(SVC)represents a promising technique for seawater desalination to alleviate the global water crisis and energy shortage.One of its main bottleneck problems is that the evaporation efficiency and stability are limited by salt crystallization under high-salinity brines.Herein,we demonstrate that the 3D porous melamine-foam(MF)wrapped by a type of self-assembling composite materials based on reduced polyoxometalates(i.e.heteropoly blue,HPB),oleic acid(OA),and polypyrrole(PPy)(labeled with MF@HPB-PPy_(n)-OA)can serve as efficient and stable SVC material at high salinity.Structural characterizations of MF@HPB-PPy_(n)-OA indicate that both hydrophilic region of HPBs and hydrophobic region of OA co-exist on the surface of composite materials,optimizing the hydrophilic and hydrophobic interfaces of the SVC materials,and fully exerting its functionality for ultrahigh water-evaporation and anti-salt fouling.The optimal MF@HPB-PPy_(10)-OA operates continuously and stably for over 100 h in 10wt%brine.Furthermore,MF@HPB-PPy_(10)-OA accomplishes complete salt-water separation of 10wt%brine with 3.3kgm^(-2)h^(-1)under 1-sun irradiation,yielding salt harvesting efficiency of 96.5%,which belongs to the record high of high-salinity systems reported so far and is close to achieving zero liquid discharge.Moreover,the low cost of MF@HPB-PPy_(10)-OA(2.56$m^(-2))suggests its potential application in the practical SVC technique. 展开更多
关键词 heteropoly blue(HPB) hydrophilic-hydrophobic interface polyoxometalates(POM) salt-water separation solar vapor generation(SVG)
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滴灌水盐氮调控对棉田水肥盐运移及棉花产量的影响
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作者 张紫淇 杨丽莉 +1 位作者 何新林 李小龙 《干旱区研究》 CSCD 北大核心 2024年第5期876-893,共18页
为明析覆膜滴灌条件下水盐氮调控对土壤水盐养分运移变化、棉花生长指标及产量的影响,通过两年三因素全组合大田试验,设置灌水量三水平(W1:2700 m^(3)·hm^(-2)、W2:3600 m^(3)·hm^(-2)和W3:4500 m^(3)·hm^(-2))、含盐量... 为明析覆膜滴灌条件下水盐氮调控对土壤水盐养分运移变化、棉花生长指标及产量的影响,通过两年三因素全组合大田试验,设置灌水量三水平(W1:2700 m^(3)·hm^(-2)、W2:3600 m^(3)·hm^(-2)和W3:4500 m^(3)·hm^(-2))、含盐量三水平(S1:3 dS·m^(-1)、S2:6 dS·m^(-1)和S3:9 dS·m^(-1))、施氮量三水平(F1:105 kg·hm^(-2)、F2:210 kg·hm^(-2)和F3:315 kg·hm^(-2)),研究了不同水盐氮组合对土壤水分、盐分、氮素分布及植株生长、产量的影响。结果表明:土壤水分主要聚集在30~40 cm土层,不同土层深度的含水率基本呈先增大后减小的变化趋势;蕾期和花铃期的S3F3W1和S2F3W1比S1F3W1的0~40 cm土层平均含水率增大1.3%~21.8%;同一灌溉量下S1F3组合的平均含水率比S1F2和S1F1增大1.39%~13.83%。土壤盐分生育期内呈现先减少后增加的变化趋势;S1土壤盐分随施氮量的增大而先增大后减小,S2、S3土壤盐分随施氮量的增加而减少。W2、W3处理中,氮素在40~60 cm土层中缓慢积聚;S1处理的氮素含量明显高于S2、S3。土壤水分、盐分、氮素含量交互影响,在适宜的土壤水分、氮素条件下,较低的土壤含盐量,能使植株更好地利用养分,利于植株的生长进而促进产量的形成。为获得较高的经济效益,低、中盐土壤推荐灌溉量为3600 m^(3)·hm^(-2),施氮量为210 kg·hm^(-2);高盐土壤推荐灌溉量为4500 m^(3)·hm^(-2),施氮量为315 kg·hm^(-2)。研究为探索干旱区多年膜下滴灌棉花农田生态系统水盐养分运移机制及水肥高效利用提供科学的理论依据。 展开更多
关键词 膜下滴灌 棉花 水盐养分运移 灌溉制度优化
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酚酞基聚醚醚酮/聚乙烯亚胺复合超滤膜的制备与性能研究
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作者 于云武 吴岩 +2 位作者 谢春阳 韩至立 孙小巍 《沈阳建筑大学学报(自然科学版)》 CAS 北大核心 2024年第5期952-960,共9页
目的 制备纯水通量较高的复合超滤膜,实现染料废水的高效快速分离。方法 采用相分离转化法,以丙酮为非溶剂,酚酞基聚醚醚酮和聚乙烯亚胺为研究对象,在室温条件下,开发出一种性能较好的酚酞基聚醚醚酮/聚乙烯亚胺复合超滤膜;分析酚酞基... 目的 制备纯水通量较高的复合超滤膜,实现染料废水的高效快速分离。方法 采用相分离转化法,以丙酮为非溶剂,酚酞基聚醚醚酮和聚乙烯亚胺为研究对象,在室温条件下,开发出一种性能较好的酚酞基聚醚醚酮/聚乙烯亚胺复合超滤膜;分析酚酞基聚醚醚酮(PEEK-WC)质量分数、聚乙烯亚胺(PEI)添加量、改性反应时间等工艺因素对复合超滤膜性能的影响。结果 随着反应沉积时间的增加,复合超滤膜的水通量呈上升趋势;随着聚乙烯亚胺质量分数增加,复合超滤膜的水通量不断增加;复合超滤膜的最优制备条件为PEI与PEEK-WC的质量比为20%,PEEK-WC与NMP的质量比为15%,反应时间为12 h。结论 酚酞基聚醚醚酮/聚乙烯亚胺复合超滤膜具有良好的截留效果和抗细菌污染性。 展开更多
关键词 超滤膜 高纯水通量 染料截留 盐染体系
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水盐体系相图与盐湖资源开发利用研究
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作者 马经黎 《化工管理》 2024年第16期109-112,共4页
当前,水盐体系相图的研究和盐湖资源的开发利用都是与水资源和盐类相关的重要课题。水盐体系相图能够帮助人们深入理解水和盐之间的相互作用以及它们的溶解特性,从而对水资源的管理和利用提供指导和参考。盐湖资源作为一种重要的天然资... 当前,水盐体系相图的研究和盐湖资源的开发利用都是与水资源和盐类相关的重要课题。水盐体系相图能够帮助人们深入理解水和盐之间的相互作用以及它们的溶解特性,从而对水资源的管理和利用提供指导和参考。盐湖资源作为一种重要的天然资源,具有丰富的盐类储量,对化学工业、能源和农业等领域的发展具有重要的意义。基于此,文章简单讨论水盐体系相图以及对盐湖资源开发利用的作用,深入探讨盐湖资源开发利用要点,以供参考。 展开更多
关键词 水盐体系相图 盐湖资源开发 资源提取
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超大城市供水系统韧性评估与应用实践——以上海受咸潮入侵影响为例
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作者 顾晨 《净水技术》 CAS 2024年第5期1-9,共9页
供水系统韧性作为韧性城市建设的关键一环,近年来正面临着前所未有的挑战。文中探讨了供水系统韧性的评估方法,分析了当前供水系统韧性研究实践的现状及其存在的问题。通过事前、事中和事后不同阶段的定性和定量相结合的方式,识别解析... 供水系统韧性作为韧性城市建设的关键一环,近年来正面临着前所未有的挑战。文中探讨了供水系统韧性的评估方法,分析了当前供水系统韧性研究实践的现状及其存在的问题。通过事前、事中和事后不同阶段的定性和定量相结合的方式,识别解析了超大城市供水系统的韧性影响因素,创新构建了上海供水系统韧性评估体系。此外,以2022年上海受咸潮入侵影响为例,进行了详尽的供水系统韧性综合评价。结果表明,上海供水系统在咸潮期间的整体韧性介于“可控”与“健康”。文章对于供水系统的韧性评估与应用实践可为其他城市提供更完备的借鉴和策略参考。 展开更多
关键词 超大城市 供水系统 韧性 评估 咸潮入侵
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基于五元体系Na^(+),K^(+),Mg^(2+)// Cl^(-),SO_(4)^(2-)-H_(2)O相图的硫酸钾生产工艺研究及应用
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作者 盖晓宏 黎国亮 《化工矿物与加工》 CAS 2024年第11期53-59,共7页
国内外采用硫酸镁转化法生产硫酸钾的工艺一般为两段转化法,其主要理论依据是25℃K^(+),Mg^(2+)//Cl^(-),SO_(4)^(2-)-H_(2)O体系相图。对于硫酸盐型盐湖或利用硫酸盐和氯化钾转化法生产硫酸钾的生产企业,生产原料中会不可避免地存在较... 国内外采用硫酸镁转化法生产硫酸钾的工艺一般为两段转化法,其主要理论依据是25℃K^(+),Mg^(2+)//Cl^(-),SO_(4)^(2-)-H_(2)O体系相图。对于硫酸盐型盐湖或利用硫酸盐和氯化钾转化法生产硫酸钾的生产企业,生产原料中会不可避免地存在较多的可溶性杂质,物料为五元体系属性。通常,硫酸钾生产的3个工艺过程(光卤石分解、钾混盐转化、硫酸钾合成),需运用K^(+),Mg^(2+)//Cl^(-)-H_(2)O或K^(+),Mg^(2+),Na^(+)//Cl^(-)-H_(2)O三元、四元简单体系相图和K^(+),Mg^(2+)//Cl^(-),SO_(4)^(2-)-H_(2)O交互四元体系相图指导生产;由于五元体系引入了较多的氯化钠,导致工艺过程与相图存在较大偏差。本文以罗布泊盐湖卤水为研究对象,通过构建五元介稳体系相图,探讨了相图分析的理论依据和相关控制参数。结果表明:Na^(+),K^(+),Mg^(2+)//Cl^(-),SO_(4)^(2-)-H_(2)O五元体系介稳相图可以解释成矿机理,反映生产过程,并确定钾混盐转化温度控制在28℃较为适宜;通过计算还可获得工艺参数,具有便利、统一的优点。 展开更多
关键词 水盐体系法 二段转化 五元相图 硫酸钾 氯化钾 相图 硫酸镁
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醇-水混合溶剂中水盐体系相平衡研究进展
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作者 周婷婷 乔丹 《山东化工》 CAS 2023年第2期106-108,共3页
水盐体系相平衡的研究是无机盐化工的理论基础,对于盐湖资源的开发和利用有着非常重要的意义。概述了甲醇-水、乙醇-水、多元醇-水混合溶剂体系中的相平衡研究,总结了各混合溶剂体系的特点和研究进展。
关键词 混合溶剂 水盐体系 相平衡
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河北滨海盐碱地浅层轻度咸水资源冬小麦灌溉安全利用研究 被引量:2
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作者 高会 赵亮 +2 位作者 刘斌 付同刚 刘金铜 《中国生态农业学报(中英文)》 CAS CSCD 北大核心 2023年第7期1102-1109,共8页
河北滨海盐碱耕地缺少灌溉水资源,该区具有丰富的浅层微/轻度咸水资源,冬小麦生长关键期适当进行微/轻度咸水灌溉能够缓解该区农田灌溉危机。本文以河北省滨海盐碱地为研究对象,选择沧州市南大港产业园区马营村为试验基地,开展浅层轻度... 河北滨海盐碱耕地缺少灌溉水资源,该区具有丰富的浅层微/轻度咸水资源,冬小麦生长关键期适当进行微/轻度咸水灌溉能够缓解该区农田灌溉危机。本文以河北省滨海盐碱地为研究对象,选择沧州市南大港产业园区马营村为试验基地,开展浅层轻度咸水冬小麦农田灌溉试验,分析咸水灌溉对冬小麦产量和土壤盐分含量变化的影响。结果表明:1)河北滨海盐碱地浅层轻度咸水(6 g∙L^(-1))在冬小麦拔节—抽穗期进行一次600 m^(3)∙hm^(-2)的灌溉,产量能够达到旱作冬小麦的1.5倍以上,增产效果明显。2)基于暗管排水排盐工程、在雨季保持多年平均降雨量条件下,2016—2018年雨季后试验地土壤平均含盐量分别为2.86 g∙kg^(-1)、1.60 g∙kg^(-1)和1.38 g∙kg^(-1),呈现逐年降低的趋势。由此得出:河北滨海盐碱地浅层咸水资源在冬小麦灌溉方面能够实现安全利用。在此基础上,以河北滨海沧州市为例分析浅层咸水资源利用前景,从水资源量上,1~5 g∙L^(-1)的浅层微/轻度咸水资源可以满足冬小麦农田因地下水压采限采造成的至少1.7×10^(8)m^(3)灌溉水量亏缺,从耕地资源方面,扩大一年两熟种植面积,增加冬小麦种植面积约131000 hm2。研究结果可为河北滨海盐碱地咸水资源安全利用、土壤健康和粮食安全提供科学依据。 展开更多
关键词 滨海盐碱地 冬小麦 咸水灌溉 土壤盐分 作物产量 暗管排盐
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盐湖化工方向水盐体系相图课程教学内容的改进 被引量:1
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作者 成怀刚 宋慧平 +2 位作者 赵静 程芳琴 崔香梅 《化工高等教育》 2023年第5期12-16,98,共6页
水盐体系相图课程主要聚焦于卤水相图原理及其在相分离过程中的应用,是盐湖化工方向本科生和研究生的基础课程之一,也是面向盐湖产业基地人才培养的支撑课程。近年来,水盐体系相图逐渐显现出多元化应用的特征,学科交叉的持续深入也对水... 水盐体系相图课程主要聚焦于卤水相图原理及其在相分离过程中的应用,是盐湖化工方向本科生和研究生的基础课程之一,也是面向盐湖产业基地人才培养的支撑课程。近年来,水盐体系相图逐渐显现出多元化应用的特征,学科交叉的持续深入也对水盐体系相图教材和教学内容提出了新要求。据此,文章梳理了水盐体系相图教材的发展历程和教学内容设置情况,阐述了讲授相图研究前沿内容和非传统相图应用案例的必要性,并提出应紧跟实际应用需求的变化,拓展讲解相图的科研热点和应用技术。 展开更多
关键词 水盐体系 相图 教材 盐湖化工
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