Coarse-grained subaqueous fans are vital oil and gas exploration targets in the Bohai Bay basin,China.The insufficient understanding of their sedimentary processes,depositional patterns,and controlling factors restric...Coarse-grained subaqueous fans are vital oil and gas exploration targets in the Bohai Bay basin,China.The insufficient understanding of their sedimentary processes,depositional patterns,and controlling factors restricts efficient exploration and development.Coarse-grained subaqueous fans in the Yong′an area,Dongying Depression,are investigated in this study.These fans include nearshore subaqueous fans,and sublacustrine fans,and their sedimentary processes,depositional patterns and distribution characteristics are mainly controlled by tectonic activity and paleogeomorphology.Nearshore subaqueous fans developed near the boundary fault during the early–middle deposition stage due to strong tectonic activity and large topographic subsidence.Early sublacustrine fans developed at the front of the nearshore subaqueous fans in the area where the topography changed from gentle to steep along the source direction.While the topography was gentle,sublacustrine fans did not develop.During the late weak tectonic activity stage,late sublacustrine fans developed with multiple stages superimposed.Frequent fault activity and related earthquakes steepened the basin margin,and the boundary fault slopes were 25.9°–34°.During the early–middle deposition stage,hyperpycnal flows triggered by outburst floods developed.During the late deposition stage,with weak tectonic activity,seasonal floods triggered hyperpycnal flows,and hybrid event beds developed distally.展开更多
The rare earth elements(REE)geochemistry and the isotope(δ^(13)C,δ^(18)O)composition of manganese ores of the Chiatura(Georgia)deposit were studied.One of the major features of all types of manganese ores is negativ...The rare earth elements(REE)geochemistry and the isotope(δ^(13)C,δ^(18)O)composition of manganese ores of the Chiatura(Georgia)deposit were studied.One of the major features of all types of manganese ores is negative cerium(Ce/Ce*_(PAAS))anomaly and the absence of europium(Eu/Eu*_(PAAS))anomaly.Oxide oolitic manganese ores were formed in oxic shallow marine environments.The content and distribution of REEs(in particular Ce and Eu)in these ores are connected mainly with ferrous oxides.The performed C-and O-isotope research in Mn-carbonates(oolitic and massive)has indicated that carbonate ores were formed by the participation of isotopic ally light CO_(2)which is a result of the oxidation of organic matter in the sediment strata by reducing environments of early diagenesis(and,partially,catagenesis)zone.Obtained negative cerium anomalies in the studied carbonate ores reflect the specific REE patterns in pore waters of sediments of earlier isdiagenesis zone of the Oligocene Chiatura's basin.The deficiency of cerium in this zone remains debatable and requires further study.Formation of manganese carbonates took place multistage by the input of incisional solutions of different chemistry into sea bottom waters and sediments.The absence of europium anomaly indicates about lack of hydrothermal solution input.展开更多
Tonle Sap sedimentary basin was considered a favorable geological condition for hydrocarbon accumulation in the onshore Cambodia. Two exposure outcrops in Battambang province, called Somlout and Takream, were selected...Tonle Sap sedimentary basin was considered a favorable geological condition for hydrocarbon accumulation in the onshore Cambodia. Two exposure outcrops in Battambang province, called Somlout and Takream, were selected to represent sediments in this basin. The sedimentology and geochemistry studies provide insights into the depositional environment of sediments using field investigation, lithological, sedimentological, paleontological, and geochemical analysis. The redox condition, water column, and depositional setting were analyzed by plotting the ratio of V vs. Cr, Uauthigenic vs. V/Cr, Sr vs. Ba, Ca vs. (Fe + Ca), and Fe<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> vs. Al<sub>2</sub>O<sub>3</sub>/(Al<sub>2</sub>O<sub>3</sub> + Fe<sub>2</sub>O<sub>3</sub>) diagram. Moreover, these diagrams can be used to predict depositional conditions as well. Based on the results, Somlout and Takream comprise calcareous shale and limestone facies. The geochemical analysis showed that Somlout calcareous shale samples were deposited in the dysoxic freshwater of the lake setting during the regression, while Somlout limestones and Takream were deposited in high salinity seawater, oxic condition of shallow-marine water. In addition, Somlout limestones consist of fragmental fusulinid foraminifera, bivalve shelve, and bryozoan, which suggest a barrier environment. Meanwhile, Teakream consists of fine-grained calcareous shale, and lime-mudstone, which are presented to form in the quiet marine setting of the lagoon environment. Therefore, the Tonle Sap basin sediments were deposited in the Somlout area’s barrier and lake environment, and the lagoon environment for Takream.展开更多
A systematic analysis of southwestern Ordos Basin's sedimentary characteristics,internal architectural element association styles and depositional model was illustrated through core statistics,well logging data an...A systematic analysis of southwestern Ordos Basin's sedimentary characteristics,internal architectural element association styles and depositional model was illustrated through core statistics,well logging data and outcrop observations in Chang 8 oil-bearing group.This analysis indicates that shallow water delta sediments dominated by a fluvial system is the primary sedimentary system of the Chang 8 oil-bearing group of the Yanchang Formation in southwestern Ordos Basin.Four microfacies with fine grain sizes are identified: distributary channels,sheet sandstone,mouth bar and interdistributary fines.According to the sandbody's spatial distribution and internal architecture,two types of sandbody architectural element associations are identified: amalgamated distributary channels and thin-layer lobate sandstone.In this sedimentary system,net-like distributary channels at the delta with a narrow ribbon shape compose the skeleton of the sandbody that extends further into the delta front and shades into contiguous lobate distribution sheet sandstone in the distal delta front.The mouth bar is largely absent in this system.By analyzing the palaeogeomorphology,the palaeostructure background,sedimentary characteristics,sedimentary facies types and spatial distribution of sedimentary facies during the Chang 8 period,a distinctive depositional model of the Chang 8 shallow water fluvial-dominated delta was established,which primarily consists of straight multi-phase amalgamated distributary channels in the delta plain,net-like distributary channels frequently diverting and converging in the proximal delta front,sheet sandstones with dispersing contiguous lobate shapes in the distal delta front,and prodelta or shallow lake mudstones.展开更多
The capacity fade of spinel lithium manganese oxide in lithium-ion batteries is a bottleneck challenge for the large-scale application.The traditional opinion is that Mn(Ⅱ) ions in the anode are reduced to the metall...The capacity fade of spinel lithium manganese oxide in lithium-ion batteries is a bottleneck challenge for the large-scale application.The traditional opinion is that Mn(Ⅱ) ions in the anode are reduced to the metallic manganese that helps for catalyzing electrolyte decomposition.This could poison and damage the solid electrolyte interface(SEI) film,leading to the the capacity fade in Li-ion batteries.We propose a new mechanism that Mn(Ⅱ) deposites at the anode hinders and/or blocks the intercalation/de-intercalation of lithium ions,which leads to the capacity fade in Li-ion batteries.Based on the new mechanism assumption,a kind of new structure with core-shell characteristic is designed to inhabit manganese ion dissolution,thus improving electrochemical cycle performance of the cell.By the way,this mechanism hypothesis is also supported by the results of these experiments.The LiMn_(2-x)Ti_xO_4 shell layer enhances cathode resistance to corrosion attack and effectively suppresses dissolution of Mn,then improves battery cycle performance with LiMn_2O_4 cathode,even at high rate and elevated temperature.展开更多
The Zunyi manganese deposits, which formed during the Middle to Late Permian period and are located in northern Guizhou and adjacent areas, are the core area of a series of large-medium scale manganese enrichment mine...The Zunyi manganese deposits, which formed during the Middle to Late Permian period and are located in northern Guizhou and adjacent areas, are the core area of a series of large-medium scale manganese enrichment minerogenesis in the southern margin and interior of the Yangtze platform, Southern China. This study reports the universal enrichment of rare earth elements(REEs) in Zunyi manganese deposits and examines the enrichment characteristics, metallogenic environment and genesis of REEs. The manganese ore bodies present stratiform or stratoid in shape, hosted in the silicon–mud–limestones of the Late Permian Maokou Formation. The manganese ores generally present lamellar, massive, banded and brecciated structures, and mainly consist of rhodochrosite, ropperite, tetalite, capillitite, as well as contains paragenetic gangue minerals including pyrite, chalcopyrite, rutile, barite, tuffaceous clay rock, etc. The manganese ores have higher ΣREE contents range from 158 to 1138.9 ppm(average 509.54 ppm). In addition, the ΣREE contents of tuffaceous clay rock in ore beds vary from 1032.2 to 1824.5 ppm(average 1396.42 ppm). The REEs from manganese deposits are characterized by La, Ce, Nd and Y enriched, and existing in the form of independent minerals(e.g., monazite and xenotime), indicating Zunyi manganese deposits enriched in light rare earth elements(LREE). The Ceanom ratios(average-0.13) and lithofacies and paleogeography characteristics indicate that Zunyi manganese deposits were formed in a weak oxidation-reduction environment. The(La/Yb)ch, Y/Ho,(La/Nd)N,(Dy/Yb)N, Ce/Ce* and Eu/Eu* values of samples from the Zunyi manganese deposits are 5.53–56.92, 18–39, 1.42–3.15, 0.55–2.20, 0.21–1.76 and 0.48–0.86, respectively, indicating a hydrothermal origin for the manganese mineralization and REEs enrichment. The δ13 CV-PDB(-0.54 to-18.1‰) and δ18 OSMOW(21.6 to 26.0‰) characteristics of manganese ores reveal a mixed source of magmatic and organic matter. Moreover, the manganese ore, tuffaceous clay rock and Emeishan basalt have extremely similar REE fractionation characteristic, suggesting REEs enrichment and manganese mineralization have been mainly origin from hydrothermal fluids.展开更多
The Dounan manganese deposit is a typical large-scale marine sedimentary manganese deposit of the Middle Triassic in China. The metallogenic environment and change process directly dictate the migration, enrichment, a...The Dounan manganese deposit is a typical large-scale marine sedimentary manganese deposit of the Middle Triassic in China. The metallogenic environment and change process directly dictate the migration, enrichment, and precipitation of Mn. To better understand its metallogenetic environment, a detailed study was undertaken involving field observation, mineralogical and geochemical and M?ssbauer spectroscopic analyses. The major findings are as follows:(1) Lithofacies paleogeography, sedimentary structural characteristics, and geochemical indexes indicate that the deposits were formed in an epicontinental marine sedimentary basin environment of normal salinity;(2) there were three ore phases including Mn oxides, Mn carbonates, and mixed Mn ores. The ore minerals found were braunite, manganite, Ca-rhodochrosite, manganocalcite, and kutnahorite. Petrographic and mineralogical information indicates that the metallogenic environment was a weakly alkaline and weakly oxidized to weakly reduced environment, and the mineralization occurred near the redox interface;(3) the V/(V + Ni)ratios, δCe and Fe^(2+)/Fe^(3+) found in profiles of Baigu and Gake ore sections show that the redox conditions of the ore-forming environment were continuously changing; and(4) three Fe species, α-Fe_2O_3, para-Fe^(3+), and para-Fe^(2+),were found in hematite and clay mineral samples using M?ssbauer spectrum analysis. The presence and distribution of these Fe species indicate that the deposit was formed in a typical sedimentary environment during the mineralization process. In summary, our study showed that redox was a key factor controlling the mineralization of the Dounan manganese deposit. Our results have led us to the conclusion that transgression and regression caused fluctuations in sea level, which in turn caused the change of the redox environment. M?ssbauer spectroscopy is an effective tool for studying the redox conditions of the paleoenvironment in which sedimentary manganese deposits were formed.展开更多
In order to study the characteristics of sea-floor exhalative sedimentary and magmatic hydrothermal superimposition on the Bainiuchang polymetallic deposit, the REE compositions of the granites, host-rocks and ores ha...In order to study the characteristics of sea-floor exhalative sedimentary and magmatic hydrothermal superimposition on the Bainiuchang polymetallic deposit, the REE compositions of the granites, host-rocks and ores have been systematically analyzed by ICP-MS. As viewed from their REE compositions, the granites show obvious negative Eu anomalies and weak negative Ce anomalies. According to their REE characteristics, the host-rocks were derived partly from sea-floor exhalative sediments. In terms of their REE compositions, the ores can be divided into two groups: one group, of which the samples were collected from the Baiyang segment relatively far away from the Bozhushan granite batholith, possesses positive Eu anomalies or no Eu anomaly and negative Ce anomalies, indicating that ore-forming hydrothermal fluid was relatively reductive and its temperature was higher than 250 ℃. Furthermore, the coinstantaneous presence of positive Eu anomalies and negative Ce anomalies indicate that the convective mixing of a little amount of seawater with hydrothermal fluid had happened while ores were precipitated on ancient sea floor. The other group, of which the samples were mainly collected from the Chuanxindong and Duimenshan segments near the Bozhushan granite batholith, has similar chondrite-monalized REE distribution patterns to those of the magmatic rocks. But as a whole, the REE characteristics of both groups change gradually starting from the Bozhushan granite batholith. Based on the REE characteristics of the granites, host-rocks and ores, it is suggested that the ore-forming metals seem to have come from several different sources.展开更多
The Wuchuan-Sihui-Shaoguan(WSS)exhalative sedimentary pyrite belt in the southwestern part of the Qinzhou-Hangzhou(Qin-Hang)belt is the most important sulfur industry base in China.However,a wide range of metallogenet...The Wuchuan-Sihui-Shaoguan(WSS)exhalative sedimentary pyrite belt in the southwestern part of the Qinzhou-Hangzhou(Qin-Hang)belt is the most important sulfur industry base in China.However,a wide range of metallogenetic ages spanning from Ediacaran to Devonian has been reported in the literature.This age range does not support the idea that the typical character of"coeval mineralization"in an exhalative sedimentary mineralization belt in China and worldwide.Therefore,the precise determination of mineralization ages of representative deposits is necessary to provide guides for exploration and metallogenetic models.The Dajiangping pyrite deposit is a typical example of this kind of deposits and is also the largest deposit with a proven reserve of 210 Mt.This deposit was thought to have formed in Ediacaran or Devonian.In this study,2-3 layers of 10-25 cm thick 2M1-type microcrystalline muscovite slate abruptly embedded in the No.Ⅳmassive orebody of the deposit has been identified to be low-grade metamorphic K-bentonite.A Concordia zircon LA-ICP-MS U-Pb age of 432.5±1.3 Ma(mean standard weighted deviation of concordance and equivalence=1.2;N=11)has been yielded for the low-grade metamorphic K-bentonite.This age is distinctly different from the Rb-Sr isochron age of630.1±7.3 Ma for siliceous rock at the top of the No.Ⅲbanded orebody and the Re-Os isochron age of 389±62 Ma for pyrites from a laminated orebody.Instead,it is close to the intercept age(429 Ma)of the youngest detrital zircons from sandstone interlayers of the No.Ⅲbanded orebody.The Concordia age is also coincident with those of the Late Caledonian(400-460 Ma)magmatism-metamorphism events which are widely distributed in Cathaysia Block.Particularly,it agrees well with that of the Early Silurian extensional volcanism(434-444 Ma)which have been revealed in the Dabaoshan,Siqian-Hekou,and Nanjing volcanic basins in northern Guangdong Province and southern Jiangxi Province.Hence,the dating result in this study confirms that the sedimentary time of the ore-host Daganshan Formation is Early Silurian,and implies that the mineralization age of the Dajiangping pyrite deposit should also be Early Silurian.In combination with the Early Silurian age of Shezui pyrite deposit and the Dabaoshan volcanic basin along the WSS pyrite belt,it could be inferred that the WSS pyrite belt provides a record of the northern expanding of Qinzhou-Fangcheng trough in Early Silurian and that the exhalative pyrite mineralization was triggered by the postcollisional extension of the margin of Cathaysia Block after the intracontinental collision between Cathaysia Block and Yangtze Block during Late Caledonian stage.展开更多
The Lannigou deposit is a large-sized sedimentary rock-hosted disseminated gold (SRHDG) deposit located in the Youjiang Basin. It is hosted by the Middle Triassic turbidite. Wall rock alterations, including silicifica...The Lannigou deposit is a large-sized sedimentary rock-hosted disseminated gold (SRHDG) deposit located in the Youjiang Basin. It is hosted by the Middle Triassic turbidite. Wall rock alterations, including silicification, pyritization, arsenopyritization, carbonatization and argillization, commonly occur along fractures. PGE study demonstrates that either Permian basalts or Triassic ultrabasic intrusives are unlikely to be the main source of gold mineralization. Coupled with the lack of other magmatic activity in the vicinity of the mining area, an amagmatic origin is proposed. Organic matter compositions and GC-MS analysis of the ores and host rocks show that the organics in the ores and the host rocks have a common source; the organic matter in the ores was mainly indigenous. The positive correlation between S2 and Au contents, along with the common occurrence of organic inclusions, suggest involvement of organic matter in the ore-forming process in terms of promoting Au leaching from the source rocks, making colloidal Au migration possible, as well as hydrocarbon reduction of sulphate. Geological and geochemical characteristics of the Lannigou deposit suggest that it was formed through circulation of meteoric water and probably less importantly organic bearing formation water driven by high geothermal gradient caused by late Yanshanian extension, which leached Au from the source bed, and then migrated as Au-bisulfides and colloidal Au, culminating in deposition by reduction-adsorption and surface complexation of gold onto the growth surface of arsenian pyrite.展开更多
1 Introduction Sareke glutenite-type copper deposit is the large size copper deposit discovered in recent years,and it is located Sarekebayi intracontinental pull-apart basin in the western margin of the Tarim basin.C...1 Introduction Sareke glutenite-type copper deposit is the large size copper deposit discovered in recent years,and it is located Sarekebayi intracontinental pull-apart basin in the western margin of the Tarim basin.Conglomerate展开更多
Sinian is one of the main periods of the formation of manganese deposits in China. Sinian manganesedeposits are mainly hosted in carbon-rich black shale and siliceous shale formed during the Sinian interglacial period...Sinian is one of the main periods of the formation of manganese deposits in China. Sinian manganesedeposits are mainly hosted in carbon-rich black shale and siliceous shale formed during the Sinian interglacial period. The composition of manganese ore is simple. The main ore mineral is manganiferous carbonates. The grade of manganese ore is about 16-25%, with Mn/Fe】5 and P/Mn=0.006-0.14. Based on the tectonic setting and geological and geochemical characteristics of manganese deposits, this paper discusses the process of migration and concentration of manganese and ore-forming conditions of Sinian manganese deposits in China.展开更多
Nanocluster formation of a metallic platinum (Pt) coating, on manganese oxide inorganic membranes impregnated with multiwall carbon nanotubes (K-OMS-2/MWCNTs), applied by reactive spray deposition technology (RSDT) is...Nanocluster formation of a metallic platinum (Pt) coating, on manganese oxide inorganic membranes impregnated with multiwall carbon nanotubes (K-OMS-2/MWCNTs), applied by reactive spray deposition technology (RSDT) is discussed. RSDT applies thin films of Pt nanoclusters on the substrate;the thickness of the film can be easily controlled. The K-OMS-2/MWCNTs fibers were enclosed by the thin film of Pt. X-ray diffraction (XRD), scanning electron microscopy/X-ray energy dispersive spectroscopy (SEM/XEDS), focus ion beam/scanning electron microscopy (FIB/SEM), transmission electron microscopy (TEM), and X-ray 3D micro-tomography (MicroXCT) which have been used to characterize the resultant Pt/K-OMS-2/MWCNTs membrane. The non-destructive characterization technique (MicroXCT) resolves the Pt layer on the upper layer of the composite membrane and also shows that the membrane is composed of sheets superimposed into stacks. The nanostructured coating on the composite membrane material has been evaluated for carbon monoxide (CO) oxidation. The functionalized Pt/K-OMS-2/MWCNTs membranes show excellent conversion (100%) of CO to CO2 at a lower temperature 200℃ compared to the uncoated K-OMS-2/MWCNTs. Moreover, the Pt/K-OMS-2/MWCNTs membranes show outstanding stability, of more than 4 days, for CO oxidation at 200℃.展开更多
Some high quality manganese ore deposits of Cbina are found to be polygenetic compound ore deposits which are the products of diwa mineralization. Liancheng manganese ore district, Fujian, is a typical example. Simila...Some high quality manganese ore deposits of Cbina are found to be polygenetic compound ore deposits which are the products of diwa mineralization. Liancheng manganese ore district, Fujian, is a typical example. Similar deposits can be found in East GuangdongWest Fujian and Hunan. The genesis of some ore deposits in Southeast Yunnan, for example,those in Deunan and Beixian,maybe related to diwa mineralization.Geological conditions of the mineralization of some high grade manganese ore deposits have been analysized and comPared with other comparatively poor manganese ore deposits.The genesis and perspective of higb quality mamganese ore deposits is discussed based on diwa theory.It is pointed out that South-East China diwa region,the South tip of South-North diwa region and some parts ofYunnan-Guizhou diwa region are more prospective for the reconnaissance geologicaI survey and exploration of high grade polygenetic compound weathering manganese and rhodochrosite-alabandite ore deposits in Cbina.展开更多
The largest Mesozoic northward transgression in Qangtang Basin of Qinghai-Xizang (Tibet) Plateau occurred during the Buqu Stage, Middle Jurassic. Mainly filled with carbonate rocks, the whole basin is composed of tran...The largest Mesozoic northward transgression in Qangtang Basin of Qinghai-Xizang (Tibet) Plateau occurred during the Buqu Stage, Middle Jurassic. Mainly filled with carbonate rocks, the whole basin is composed of transgression-regression sedimentary cycle. Field outcrops and indoor analysis revealed 8 types of sedimentary facies markers in this region. 4 types of sedimentary facies have been recognized: platform facies, platform marginal facies, foreslope facies and basin facies. Influenced by the northern Lazhuglung-Jinshajiang suture zone, central uplift region and southern Bangongco-Nujiang suture zone, these facies belts extended east-west. The sedimentary model was established based on observed depositional features. From their biological features and sedimentary characteristics, it is suggested that the paleoclimate was warm and humid at that time. The Buqu Formation is a promising target for oil and gas exploration in Shuanghu-Duoyong area in future.展开更多
Granular calcite is an authigenic mineral in fine-grained sedimentary rocks.Core observation,thin section observation,cathodoluminescence analysis,fluid inclusion analysis,scanning electron microscope(SEM),and isotopi...Granular calcite is an authigenic mineral in fine-grained sedimentary rocks.Core observation,thin section observation,cathodoluminescence analysis,fluid inclusion analysis,scanning electron microscope(SEM),and isotopic composition analysis were combined to clarify the genesis of granular calcite in the lacustrine fine-grained sedimentary rocks of the Permian Lucaogou Formation in the Jimusar Sag,Junggar Basin.It is found that the granular calcite is distributed with laminated characteristics in fine-grained sedimentary rocks in tuffite zones(or the transitional zone between tuffite and micritic dolomite).Granular calcite has obvious cathodoluminesence band,and it can be divided into three stages.Stage-Ⅰ calcite,with non-luminesence,high content of Sr element,inclusions containing Cos,and homogenization temperature higher than 170℃,was directly formed from the volcanic-hydrothermal deposition.Stage-Ⅱ calcite,with bright yellow luminescence,high contents of Fe,Mn and Mg,enrichment of light rare earth elements(LREEs),and high homogenization temperature,was formed by recrystallization of calcareous edges from exhalative hydrothermal deposition.Stage-IlI calcite,with dark orange luminescence band,high contents of Mg,P,V and other elements,no obvious fractionation among LREEs,and low homogenization temperature,was originated from diagenetic transformation during burial.The granular calcite appears regularly in the vertical direction and its formation temperature decreases from the center to the margin of particles,providing direct evidences for volcanic-hydrothermal events during the deposition of the Lucaogou Formation.The volcanic-hydrothermal event was conducive to the enrichment of organic matters in fine-grained sedimentary rocks of the Lucaogrou Formation,and positive to the development of high-quality source rocks.The volcanic-hydrothermal sediments might generate intergranular pores/fractures during the evolution,creating conditions for the self-generation and self-storage of shale oil.展开更多
基金supported by the National Science Foundation of China(Grant Nos.41972099,4217020246)the National Science and Technology Major of China(Grant Nos.2017ZX05009-002,2017ZX05072-002)。
文摘Coarse-grained subaqueous fans are vital oil and gas exploration targets in the Bohai Bay basin,China.The insufficient understanding of their sedimentary processes,depositional patterns,and controlling factors restricts efficient exploration and development.Coarse-grained subaqueous fans in the Yong′an area,Dongying Depression,are investigated in this study.These fans include nearshore subaqueous fans,and sublacustrine fans,and their sedimentary processes,depositional patterns and distribution characteristics are mainly controlled by tectonic activity and paleogeomorphology.Nearshore subaqueous fans developed near the boundary fault during the early–middle deposition stage due to strong tectonic activity and large topographic subsidence.Early sublacustrine fans developed at the front of the nearshore subaqueous fans in the area where the topography changed from gentle to steep along the source direction.While the topography was gentle,sublacustrine fans did not develop.During the late weak tectonic activity stage,late sublacustrine fans developed with multiple stages superimposed.Frequent fault activity and related earthquakes steepened the basin margin,and the boundary fault slopes were 25.9°–34°.During the early–middle deposition stage,hyperpycnal flows triggered by outburst floods developed.During the late deposition stage,with weak tectonic activity,seasonal floods triggered hyperpycnal flows,and hybrid event beds developed distally.
基金accomplished in accordance with the Research Program of the Geological Institute of the Russian Academy of Sciences。
文摘The rare earth elements(REE)geochemistry and the isotope(δ^(13)C,δ^(18)O)composition of manganese ores of the Chiatura(Georgia)deposit were studied.One of the major features of all types of manganese ores is negative cerium(Ce/Ce*_(PAAS))anomaly and the absence of europium(Eu/Eu*_(PAAS))anomaly.Oxide oolitic manganese ores were formed in oxic shallow marine environments.The content and distribution of REEs(in particular Ce and Eu)in these ores are connected mainly with ferrous oxides.The performed C-and O-isotope research in Mn-carbonates(oolitic and massive)has indicated that carbonate ores were formed by the participation of isotopic ally light CO_(2)which is a result of the oxidation of organic matter in the sediment strata by reducing environments of early diagenesis(and,partially,catagenesis)zone.Obtained negative cerium anomalies in the studied carbonate ores reflect the specific REE patterns in pore waters of sediments of earlier isdiagenesis zone of the Oligocene Chiatura's basin.The deficiency of cerium in this zone remains debatable and requires further study.Formation of manganese carbonates took place multistage by the input of incisional solutions of different chemistry into sea bottom waters and sediments.The absence of europium anomaly indicates about lack of hydrothermal solution input.
文摘Tonle Sap sedimentary basin was considered a favorable geological condition for hydrocarbon accumulation in the onshore Cambodia. Two exposure outcrops in Battambang province, called Somlout and Takream, were selected to represent sediments in this basin. The sedimentology and geochemistry studies provide insights into the depositional environment of sediments using field investigation, lithological, sedimentological, paleontological, and geochemical analysis. The redox condition, water column, and depositional setting were analyzed by plotting the ratio of V vs. Cr, Uauthigenic vs. V/Cr, Sr vs. Ba, Ca vs. (Fe + Ca), and Fe<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> vs. Al<sub>2</sub>O<sub>3</sub>/(Al<sub>2</sub>O<sub>3</sub> + Fe<sub>2</sub>O<sub>3</sub>) diagram. Moreover, these diagrams can be used to predict depositional conditions as well. Based on the results, Somlout and Takream comprise calcareous shale and limestone facies. The geochemical analysis showed that Somlout calcareous shale samples were deposited in the dysoxic freshwater of the lake setting during the regression, while Somlout limestones and Takream were deposited in high salinity seawater, oxic condition of shallow-marine water. In addition, Somlout limestones consist of fragmental fusulinid foraminifera, bivalve shelve, and bryozoan, which suggest a barrier environment. Meanwhile, Teakream consists of fine-grained calcareous shale, and lime-mudstone, which are presented to form in the quiet marine setting of the lagoon environment. Therefore, the Tonle Sap basin sediments were deposited in the Somlout area’s barrier and lake environment, and the lagoon environment for Takream.
基金Project(SQ2013CB021013)supported by the National Key Basic Research Program of ChinaProject(41002045)supported by the National Natural Science Foundation of China
文摘A systematic analysis of southwestern Ordos Basin's sedimentary characteristics,internal architectural element association styles and depositional model was illustrated through core statistics,well logging data and outcrop observations in Chang 8 oil-bearing group.This analysis indicates that shallow water delta sediments dominated by a fluvial system is the primary sedimentary system of the Chang 8 oil-bearing group of the Yanchang Formation in southwestern Ordos Basin.Four microfacies with fine grain sizes are identified: distributary channels,sheet sandstone,mouth bar and interdistributary fines.According to the sandbody's spatial distribution and internal architecture,two types of sandbody architectural element associations are identified: amalgamated distributary channels and thin-layer lobate sandstone.In this sedimentary system,net-like distributary channels at the delta with a narrow ribbon shape compose the skeleton of the sandbody that extends further into the delta front and shades into contiguous lobate distribution sheet sandstone in the distal delta front.The mouth bar is largely absent in this system.By analyzing the palaeogeomorphology,the palaeostructure background,sedimentary characteristics,sedimentary facies types and spatial distribution of sedimentary facies during the Chang 8 period,a distinctive depositional model of the Chang 8 shallow water fluvial-dominated delta was established,which primarily consists of straight multi-phase amalgamated distributary channels in the delta plain,net-like distributary channels frequently diverting and converging in the proximal delta front,sheet sandstones with dispersing contiguous lobate shapes in the distal delta front,and prodelta or shallow lake mudstones.
基金Funded by the National Natural Science Foundation of China(Nos.21561016,21661015)Jiangxi Provincial Science&Technology Program(Nos.20133BBE50010,20142BDH80020,and 20161BBE50052)Science&Technology Program of Jiangxi Provincial Education Bureau(No.GJJ150775)
文摘The capacity fade of spinel lithium manganese oxide in lithium-ion batteries is a bottleneck challenge for the large-scale application.The traditional opinion is that Mn(Ⅱ) ions in the anode are reduced to the metallic manganese that helps for catalyzing electrolyte decomposition.This could poison and damage the solid electrolyte interface(SEI) film,leading to the the capacity fade in Li-ion batteries.We propose a new mechanism that Mn(Ⅱ) deposites at the anode hinders and/or blocks the intercalation/de-intercalation of lithium ions,which leads to the capacity fade in Li-ion batteries.Based on the new mechanism assumption,a kind of new structure with core-shell characteristic is designed to inhabit manganese ion dissolution,thus improving electrochemical cycle performance of the cell.By the way,this mechanism hypothesis is also supported by the results of these experiments.The LiMn_(2-x)Ti_xO_4 shell layer enhances cathode resistance to corrosion attack and effectively suppresses dissolution of Mn,then improves battery cycle performance with LiMn_2O_4 cathode,even at high rate and elevated temperature.
基金financially supported by the project of the graduate scientific research fund of Guizhou Province(No.KYJJ2017009)the National Natural Science Foundation of China(No.U1812402)+1 种基金the project of the scientific and technological innovation team of sedimentary deposits in Guizhou Province(No.20185613)the Project of Talent Base in Guizhou Province(No.RCJD2018-21).
文摘The Zunyi manganese deposits, which formed during the Middle to Late Permian period and are located in northern Guizhou and adjacent areas, are the core area of a series of large-medium scale manganese enrichment minerogenesis in the southern margin and interior of the Yangtze platform, Southern China. This study reports the universal enrichment of rare earth elements(REEs) in Zunyi manganese deposits and examines the enrichment characteristics, metallogenic environment and genesis of REEs. The manganese ore bodies present stratiform or stratoid in shape, hosted in the silicon–mud–limestones of the Late Permian Maokou Formation. The manganese ores generally present lamellar, massive, banded and brecciated structures, and mainly consist of rhodochrosite, ropperite, tetalite, capillitite, as well as contains paragenetic gangue minerals including pyrite, chalcopyrite, rutile, barite, tuffaceous clay rock, etc. The manganese ores have higher ΣREE contents range from 158 to 1138.9 ppm(average 509.54 ppm). In addition, the ΣREE contents of tuffaceous clay rock in ore beds vary from 1032.2 to 1824.5 ppm(average 1396.42 ppm). The REEs from manganese deposits are characterized by La, Ce, Nd and Y enriched, and existing in the form of independent minerals(e.g., monazite and xenotime), indicating Zunyi manganese deposits enriched in light rare earth elements(LREE). The Ceanom ratios(average-0.13) and lithofacies and paleogeography characteristics indicate that Zunyi manganese deposits were formed in a weak oxidation-reduction environment. The(La/Yb)ch, Y/Ho,(La/Nd)N,(Dy/Yb)N, Ce/Ce* and Eu/Eu* values of samples from the Zunyi manganese deposits are 5.53–56.92, 18–39, 1.42–3.15, 0.55–2.20, 0.21–1.76 and 0.48–0.86, respectively, indicating a hydrothermal origin for the manganese mineralization and REEs enrichment. The δ13 CV-PDB(-0.54 to-18.1‰) and δ18 OSMOW(21.6 to 26.0‰) characteristics of manganese ores reveal a mixed source of magmatic and organic matter. Moreover, the manganese ore, tuffaceous clay rock and Emeishan basalt have extremely similar REE fractionation characteristic, suggesting REEs enrichment and manganese mineralization have been mainly origin from hydrothermal fluids.
基金supported by the Natural Science Foundation of China(NSFC No.41376080)the 12th Five-Year Plan project of the State Key Laboratory of Ore-deposit Geochemistry,Chinese Academy of Sciences(SKLODG-ZY125-08)
文摘The Dounan manganese deposit is a typical large-scale marine sedimentary manganese deposit of the Middle Triassic in China. The metallogenic environment and change process directly dictate the migration, enrichment, and precipitation of Mn. To better understand its metallogenetic environment, a detailed study was undertaken involving field observation, mineralogical and geochemical and M?ssbauer spectroscopic analyses. The major findings are as follows:(1) Lithofacies paleogeography, sedimentary structural characteristics, and geochemical indexes indicate that the deposits were formed in an epicontinental marine sedimentary basin environment of normal salinity;(2) there were three ore phases including Mn oxides, Mn carbonates, and mixed Mn ores. The ore minerals found were braunite, manganite, Ca-rhodochrosite, manganocalcite, and kutnahorite. Petrographic and mineralogical information indicates that the metallogenic environment was a weakly alkaline and weakly oxidized to weakly reduced environment, and the mineralization occurred near the redox interface;(3) the V/(V + Ni)ratios, δCe and Fe^(2+)/Fe^(3+) found in profiles of Baigu and Gake ore sections show that the redox conditions of the ore-forming environment were continuously changing; and(4) three Fe species, α-Fe_2O_3, para-Fe^(3+), and para-Fe^(2+),were found in hematite and clay mineral samples using M?ssbauer spectrum analysis. The presence and distribution of these Fe species indicate that the deposit was formed in a typical sedimentary environment during the mineralization process. In summary, our study showed that redox was a key factor controlling the mineralization of the Dounan manganese deposit. Our results have led us to the conclusion that transgression and regression caused fluctuations in sea level, which in turn caused the change of the redox environment. M?ssbauer spectroscopy is an effective tool for studying the redox conditions of the paleoenvironment in which sedimentary manganese deposits were formed.
基金This research project was financially supported jointly by the Key Research Project （No. KZCX3-SW-125） of CAS and the National Natural Science Foundation of China （No. 40172037）.
文摘In order to study the characteristics of sea-floor exhalative sedimentary and magmatic hydrothermal superimposition on the Bainiuchang polymetallic deposit, the REE compositions of the granites, host-rocks and ores have been systematically analyzed by ICP-MS. As viewed from their REE compositions, the granites show obvious negative Eu anomalies and weak negative Ce anomalies. According to their REE characteristics, the host-rocks were derived partly from sea-floor exhalative sediments. In terms of their REE compositions, the ores can be divided into two groups: one group, of which the samples were collected from the Baiyang segment relatively far away from the Bozhushan granite batholith, possesses positive Eu anomalies or no Eu anomaly and negative Ce anomalies, indicating that ore-forming hydrothermal fluid was relatively reductive and its temperature was higher than 250 ℃. Furthermore, the coinstantaneous presence of positive Eu anomalies and negative Ce anomalies indicate that the convective mixing of a little amount of seawater with hydrothermal fluid had happened while ores were precipitated on ancient sea floor. The other group, of which the samples were mainly collected from the Chuanxindong and Duimenshan segments near the Bozhushan granite batholith, has similar chondrite-monalized REE distribution patterns to those of the magmatic rocks. But as a whole, the REE characteristics of both groups change gradually starting from the Bozhushan granite batholith. Based on the REE characteristics of the granites, host-rocks and ores, it is suggested that the ore-forming metals seem to have come from several different sources.
基金supported by the National Natural Science Foundation of China(Grant Nos.41873058 and 41462001)the Natural Science and Technology Foundation of Guizhou Province,China(Grant No.JZ[2015]2009)。
文摘The Wuchuan-Sihui-Shaoguan(WSS)exhalative sedimentary pyrite belt in the southwestern part of the Qinzhou-Hangzhou(Qin-Hang)belt is the most important sulfur industry base in China.However,a wide range of metallogenetic ages spanning from Ediacaran to Devonian has been reported in the literature.This age range does not support the idea that the typical character of"coeval mineralization"in an exhalative sedimentary mineralization belt in China and worldwide.Therefore,the precise determination of mineralization ages of representative deposits is necessary to provide guides for exploration and metallogenetic models.The Dajiangping pyrite deposit is a typical example of this kind of deposits and is also the largest deposit with a proven reserve of 210 Mt.This deposit was thought to have formed in Ediacaran or Devonian.In this study,2-3 layers of 10-25 cm thick 2M1-type microcrystalline muscovite slate abruptly embedded in the No.Ⅳmassive orebody of the deposit has been identified to be low-grade metamorphic K-bentonite.A Concordia zircon LA-ICP-MS U-Pb age of 432.5±1.3 Ma(mean standard weighted deviation of concordance and equivalence=1.2;N=11)has been yielded for the low-grade metamorphic K-bentonite.This age is distinctly different from the Rb-Sr isochron age of630.1±7.3 Ma for siliceous rock at the top of the No.Ⅲbanded orebody and the Re-Os isochron age of 389±62 Ma for pyrites from a laminated orebody.Instead,it is close to the intercept age(429 Ma)of the youngest detrital zircons from sandstone interlayers of the No.Ⅲbanded orebody.The Concordia age is also coincident with those of the Late Caledonian(400-460 Ma)magmatism-metamorphism events which are widely distributed in Cathaysia Block.Particularly,it agrees well with that of the Early Silurian extensional volcanism(434-444 Ma)which have been revealed in the Dabaoshan,Siqian-Hekou,and Nanjing volcanic basins in northern Guangdong Province and southern Jiangxi Province.Hence,the dating result in this study confirms that the sedimentary time of the ore-host Daganshan Formation is Early Silurian,and implies that the mineralization age of the Dajiangping pyrite deposit should also be Early Silurian.In combination with the Early Silurian age of Shezui pyrite deposit and the Dabaoshan volcanic basin along the WSS pyrite belt,it could be inferred that the WSS pyrite belt provides a record of the northern expanding of Qinzhou-Fangcheng trough in Early Silurian and that the exhalative pyrite mineralization was triggered by the postcollisional extension of the margin of Cathaysia Block after the intracontinental collision between Cathaysia Block and Yangtze Block during Late Caledonian stage.
文摘The Lannigou deposit is a large-sized sedimentary rock-hosted disseminated gold (SRHDG) deposit located in the Youjiang Basin. It is hosted by the Middle Triassic turbidite. Wall rock alterations, including silicification, pyritization, arsenopyritization, carbonatization and argillization, commonly occur along fractures. PGE study demonstrates that either Permian basalts or Triassic ultrabasic intrusives are unlikely to be the main source of gold mineralization. Coupled with the lack of other magmatic activity in the vicinity of the mining area, an amagmatic origin is proposed. Organic matter compositions and GC-MS analysis of the ores and host rocks show that the organics in the ores and the host rocks have a common source; the organic matter in the ores was mainly indigenous. The positive correlation between S2 and Au contents, along with the common occurrence of organic inclusions, suggest involvement of organic matter in the ore-forming process in terms of promoting Au leaching from the source rocks, making colloidal Au migration possible, as well as hydrocarbon reduction of sulphate. Geological and geochemical characteristics of the Lannigou deposit suggest that it was formed through circulation of meteoric water and probably less importantly organic bearing formation water driven by high geothermal gradient caused by late Yanshanian extension, which leached Au from the source bed, and then migrated as Au-bisulfides and colloidal Au, culminating in deposition by reduction-adsorption and surface complexation of gold onto the growth surface of arsenian pyrite.
基金supported by the metallogenic regularities and prediction of glutenite type Cu-Pb-Zn deposit in Tarim west margin(201511016-1)the special mapping techniques and its application demonstration in Sareke overall-exploration area in Xinjiang(12120114081501)
文摘1 Introduction Sareke glutenite-type copper deposit is the large size copper deposit discovered in recent years,and it is located Sarekebayi intracontinental pull-apart basin in the western margin of the Tarim basin.Conglomerate
基金This research is supported by the National Natural Science Foundation of China （No. 40672061） ； ＇National Science Support Plan Program＇ （2006BAB01A06） ； ＇National Basic Research Program of China＇ （No.2007CB411304 No. 2001 CB409806）.
文摘Sinian is one of the main periods of the formation of manganese deposits in China. Sinian manganesedeposits are mainly hosted in carbon-rich black shale and siliceous shale formed during the Sinian interglacial period. The composition of manganese ore is simple. The main ore mineral is manganiferous carbonates. The grade of manganese ore is about 16-25%, with Mn/Fe】5 and P/Mn=0.006-0.14. Based on the tectonic setting and geological and geochemical characteristics of manganese deposits, this paper discusses the process of migration and concentration of manganese and ore-forming conditions of Sinian manganese deposits in China.
文摘Nanocluster formation of a metallic platinum (Pt) coating, on manganese oxide inorganic membranes impregnated with multiwall carbon nanotubes (K-OMS-2/MWCNTs), applied by reactive spray deposition technology (RSDT) is discussed. RSDT applies thin films of Pt nanoclusters on the substrate;the thickness of the film can be easily controlled. The K-OMS-2/MWCNTs fibers were enclosed by the thin film of Pt. X-ray diffraction (XRD), scanning electron microscopy/X-ray energy dispersive spectroscopy (SEM/XEDS), focus ion beam/scanning electron microscopy (FIB/SEM), transmission electron microscopy (TEM), and X-ray 3D micro-tomography (MicroXCT) which have been used to characterize the resultant Pt/K-OMS-2/MWCNTs membrane. The non-destructive characterization technique (MicroXCT) resolves the Pt layer on the upper layer of the composite membrane and also shows that the membrane is composed of sheets superimposed into stacks. The nanostructured coating on the composite membrane material has been evaluated for carbon monoxide (CO) oxidation. The functionalized Pt/K-OMS-2/MWCNTs membranes show excellent conversion (100%) of CO to CO2 at a lower temperature 200℃ compared to the uncoated K-OMS-2/MWCNTs. Moreover, the Pt/K-OMS-2/MWCNTs membranes show outstanding stability, of more than 4 days, for CO oxidation at 200℃.
文摘Some high quality manganese ore deposits of Cbina are found to be polygenetic compound ore deposits which are the products of diwa mineralization. Liancheng manganese ore district, Fujian, is a typical example. Similar deposits can be found in East GuangdongWest Fujian and Hunan. The genesis of some ore deposits in Southeast Yunnan, for example,those in Deunan and Beixian,maybe related to diwa mineralization.Geological conditions of the mineralization of some high grade manganese ore deposits have been analysized and comPared with other comparatively poor manganese ore deposits.The genesis and perspective of higb quality mamganese ore deposits is discussed based on diwa theory.It is pointed out that South-East China diwa region,the South tip of South-North diwa region and some parts ofYunnan-Guizhou diwa region are more prospective for the reconnaissance geologicaI survey and exploration of high grade polygenetic compound weathering manganese and rhodochrosite-alabandite ore deposits in Cbina.
基金Sponsored by National Ninth Five Year Plan Science and Technology Project (970204-01-01).
文摘The largest Mesozoic northward transgression in Qangtang Basin of Qinghai-Xizang (Tibet) Plateau occurred during the Buqu Stage, Middle Jurassic. Mainly filled with carbonate rocks, the whole basin is composed of transgression-regression sedimentary cycle. Field outcrops and indoor analysis revealed 8 types of sedimentary facies markers in this region. 4 types of sedimentary facies have been recognized: platform facies, platform marginal facies, foreslope facies and basin facies. Influenced by the northern Lazhuglung-Jinshajiang suture zone, central uplift region and southern Bangongco-Nujiang suture zone, these facies belts extended east-west. The sedimentary model was established based on observed depositional features. From their biological features and sedimentary characteristics, it is suggested that the paleoclimate was warm and humid at that time. The Buqu Formation is a promising target for oil and gas exploration in Shuanghu-Duoyong area in future.
基金Supported by the National Natural Science Foundation Project of China(42072161)College Basic Research Funding Project(22CX07008A).
文摘Granular calcite is an authigenic mineral in fine-grained sedimentary rocks.Core observation,thin section observation,cathodoluminescence analysis,fluid inclusion analysis,scanning electron microscope(SEM),and isotopic composition analysis were combined to clarify the genesis of granular calcite in the lacustrine fine-grained sedimentary rocks of the Permian Lucaogou Formation in the Jimusar Sag,Junggar Basin.It is found that the granular calcite is distributed with laminated characteristics in fine-grained sedimentary rocks in tuffite zones(or the transitional zone between tuffite and micritic dolomite).Granular calcite has obvious cathodoluminesence band,and it can be divided into three stages.Stage-Ⅰ calcite,with non-luminesence,high content of Sr element,inclusions containing Cos,and homogenization temperature higher than 170℃,was directly formed from the volcanic-hydrothermal deposition.Stage-Ⅱ calcite,with bright yellow luminescence,high contents of Fe,Mn and Mg,enrichment of light rare earth elements(LREEs),and high homogenization temperature,was formed by recrystallization of calcareous edges from exhalative hydrothermal deposition.Stage-IlI calcite,with dark orange luminescence band,high contents of Mg,P,V and other elements,no obvious fractionation among LREEs,and low homogenization temperature,was originated from diagenetic transformation during burial.The granular calcite appears regularly in the vertical direction and its formation temperature decreases from the center to the margin of particles,providing direct evidences for volcanic-hydrothermal events during the deposition of the Lucaogou Formation.The volcanic-hydrothermal event was conducive to the enrichment of organic matters in fine-grained sedimentary rocks of the Lucaogrou Formation,and positive to the development of high-quality source rocks.The volcanic-hydrothermal sediments might generate intergranular pores/fractures during the evolution,creating conditions for the self-generation and self-storage of shale oil.
