TiAlN solar selective absorbing coatings which were deposited on 304L stainless steel using cathodic arc evaporation method were annealed under non-vacuum at different temperatures with different times. The optical pr...TiAlN solar selective absorbing coatings which were deposited on 304L stainless steel using cathodic arc evaporation method were annealed under non-vacuum at different temperatures with different times. The optical properties (absorptance and emittance) of the coatings were measured by a spectrophotometer. It was found that, after being annealed for 2 hours at different temperatures, the absorptance of the coatings reached the highest value of 0.92 at 700 ℃ while the emittance got the lowest value of 0.38 at 800 ℃. When the coatings were annealed at 600 ℃ for 24 hours, the optical properties changed to 0.92/0.44 (absorptance/emittance). By measuring the structure, morphology, elements and surface roughness of the coatings, it was found that both the elemental composition and the surface roughness of the coatings changed as a result of annealing, and these changes caused the change of the optical properties of the coatings.展开更多
A new solar selective absorbing coating of Mo/NiAlN/NiAlON/SiO_2 multilayer was prepared on stainless steel(SS) substrates by magnetron sputtering for solar thermal power applications. The optical constants and thickn...A new solar selective absorbing coating of Mo/NiAlN/NiAlON/SiO_2 multilayer was prepared on stainless steel(SS) substrates by magnetron sputtering for solar thermal power applications. The optical constants and thickness of individual layers were simulated using the Scout software based on the experimentally measured reflectance and transmittance spectra of individual layers. The coating of Mo/NiAlN/NiAlON/SiO_2 with an ideal solar absorptance(α) of 0.945 in the solar spectrum range was designed via the optical constants of each layer in the Scout software. The Mo/NiAlN/NiAlON/SiO_2 coating was deposited via the optimized layer thickness. A good spectral selectivity with absorptance(α=0.936) and emittance(ε=0.09, T=80 ℃) was obtained. This method, which incorporates the optical simulation with the related experiments, provides a convenient approach to obtain the ideal solar selective absorbing coatings.展开更多
Solar selective absorbing coatings(SSACs)are required to have not only excellent optical property but also outstanding thermal stability for high temperature applications.The optical properties of Mo/ZrSiN/ZrSiON/SiO_...Solar selective absorbing coatings(SSACs)are required to have not only excellent optical property but also outstanding thermal stability for high temperature applications.The optical properties of Mo/ZrSiN/ZrSiON/SiO_(2) SSAC had been optimized successfully before.Herein,we are focusing on the evaluation and mechanism of thermal stability of this multilayer coating for its potential applications in concentrated solar power(CSP)systems.Fortunately,the coating exhibits excellent thermal stability after aging at 400℃ for 1500 h in vacuum.At aging temperature of 500℃ for 1000 h or 600℃ for 300 h in vacuum,the slight inter-diffusion between Mo layer and stainless steel(SS)substrate occurs.At higher aging temperature of 700℃ for 100 h in vacuum,the serious inter-diffusion between Mo layer and SS substrate leads to invalidation of the coating,which has been evidenced by Rutherford backscattering spectrometry(RBS)and X-ray diffraction(XRD)technologies.Additionally,this coating also has an outstanding thermal stability after aging at 400℃for 300 h in air.A heating-cooling cycling(HCC)treatment evidences the good thermal stability of this coating working in cold environment(60℃).The results reveal that this coating can be a promising candidate not only for CSP system in high temperatures but also for usage in cold environment.展开更多
Based on the cermet double layer structure, Nb-NbN multi-layer films for solar selective coatings were deposited by direct current reactive magnetron sputtering. The Nb/Nb-NbN/Al2O3 trilayered structure was deposited ...Based on the cermet double layer structure, Nb-NbN multi-layer films for solar selective coatings were deposited by direct current reactive magnetron sputtering. The Nb/Nb-NbN/Al2O3 trilayered structure was deposited on a stainless steel (SS) substrate by using a single niobium target. The expected components were adjusted by changing the gas flowing ratios of Ar: N2. The Al2O3 antireflective layer on the top of the film was produced by r. f. magnetron sputtering using Al2O3 ceramic target. A solar absorptivity of 0.94 and a normal emissivity of 0.16 at room temperature have been achieved for the coating. Thermal vacuum aging to the samples was carried out at 350 and 500 ℃ for 1 h. The results show a good thermal stability. Microstructure and its dependence on temperature of the Nb, NbN and Nb-NbN single layers were investigated, respectively.展开更多
Solar selective absorbing coatings directly harvest solar energy in the form of heat.The higher temperatures are required to drive higher power-cycle efficiencies in favor of lower costs of energy.According to differe...Solar selective absorbing coatings directly harvest solar energy in the form of heat.The higher temperatures are required to drive higher power-cycle efficiencies in favor of lower costs of energy.According to different dielectrics,high temperature coatings can mainly be divided to double cermet solar selective coatings,transition metal nitride multilayer coatings and transition metal oxide multilayer coatings.This paper assesses the photothermal conversion efficiency and thermal stability,and discusses the challenges and strategies of improving both thermal and optical properties.Double cermet layers can stabilize nanocrystalline structures by alloying,while transition metal nitride/oxide layers generally choose the reliable materials with superior mechanical properties and thermal stability.The purpose of this review is to get the optimized systems,and propose further research directions at higher temperature,such as all-ceramic absorbing coatings.展开更多
The thermal emittance of Cr film, as an IR reflector, was investigated for the use in SSAC. The Cr thin films with different thicknesses were deposited on silicon wafers, optical quartz and stainless steel substrates ...The thermal emittance of Cr film, as an IR reflector, was investigated for the use in SSAC. The Cr thin films with different thicknesses were deposited on silicon wafers, optical quartz and stainless steel substrates by cathodic arc ion plating technology as a metallic IR reflector layer in SSAC. The thickness of Cr thin films was optimized to achieve the minimum thermal emittance. The effects of structural, microstructural, optical, surface and cross-sectional morphological properties of Cr thin films were investigated on the emittance. An optimal thickness about 450 nm of the Cr thin film for the lowest total thermal emittance of 0.05 was obtained. The experimental results suggested that the Cr metallic thin film with optimal thickness could be used as an effective infrared reflector for the development of SSAC structure.展开更多
A new method of preparing CuO solar selective absorbing coating for medium temperature is presented.After pretreatment,brass was overlaid with CuO by chemical plating.The effects of reactant concentration,reaction tem...A new method of preparing CuO solar selective absorbing coating for medium temperature is presented.After pretreatment,brass was overlaid with CuO by chemical plating.The effects of reactant concentration,reaction tem-perature and reaction time on the absorptivity of CuO coating were investigated.The optimized condition of preparing CuO coating was obtained.The CuO coating was analyzed with X-ray photoelectron spectroscopy(XPS)and scanning electron microscopy(SEM).In order to prolong the period of use,the CuO coating was protected by TiO2.The experi-ment shows that the TiO2/CuO coating is more heat-resistant,acid-resistant,and wear resistant than CuO coating,without losing absorptivity markedly.The TiO2 coating can reduce emissivity and protect the CuO coating.展开更多
Copper zinc tin sulfide(CZTS)thin film was synthesized on soda lime glass substrate by using spin coating method.The synthesized CZTS thin film showed maximum absorption coefficient of 0.193×104 cm-1 and maximum ...Copper zinc tin sulfide(CZTS)thin film was synthesized on soda lime glass substrate by using spin coating method.The synthesized CZTS thin film showed maximum absorption coefficient of 0.193×104 cm-1 and maximum extinction coefficient of 0.011.The direct optical band gap,Urbach energy and steepness parameter of the synthesized CZTS thin film were 1.52 eV,0.52 eV and 0.05 respectively.The CZTS thin film was found to be polycrystalline tetragonal in nature.The scanning electron microscopy(SEM)revealed that the texture structure was formed for the CZTS thin film.展开更多
High entropy alloys(HEAs),which is at the expense of high cost compared to traditional alloy,should not be confined to the mechanical properties,but should be employed to devise a novel combination with unique functio...High entropy alloys(HEAs),which is at the expense of high cost compared to traditional alloy,should not be confined to the mechanical properties,but should be employed to devise a novel combination with unique functional and mechanical performances.In this work,high entropy alloy nitride(HEAN)is utilized as a novel double absorption layer to improve solar absorption in the high temperature solar selective absorbing coatings(SSACs).Our primary motivation is to lower thermal emittance(ε)and enhance solar absorptance(a).In order to realize this goal,coating design(CODE)software is employed to design and optimize the proposed HEAN based SSACs using appropriate dielectric function model.The ultimate as-deposited coating shows good optical properties with a high a value of 0.965 and a lowεvalue of 0.086(at 82C).The estimate of thermal stability tests indicates that HEAN based SSACs has the ability to resist instability in high working temperature,which keeps good optical properties(a¼0.925,ε¼0.070)after annealing at 600C for 10 h.展开更多
A series of selective solar absorber coatings of Cr-Cr2O3 were deposited in different content on stainless steel by plasma spraying.The samples were annealed at different temperatures.The optical performance(both the ...A series of selective solar absorber coatings of Cr-Cr2O3 were deposited in different content on stainless steel by plasma spraying.The samples were annealed at different temperatures.The optical performance(both the solar absorptance and the thermal emittance)were studied by spectrophotometry.The surface morphology,the structure and the surface roughness were investigated by scanning electron microscopy(SEM),X-ray diffraction(XRD),and roughmeter respectively.The results show that,as the content of Cr increased,the solar absorptance(α)decreased greatly,from 0.91 to 0.84.Meanwhile,the thermal emittance(ε) decreased more greatly,from 0.86 to about 0.64.The ratio between the solar absorptance and the thermal emittance increased from 1.06 to 1.31.Annealing had a great impact on the optical performance.Annealing temperature is an important element.But its influence was a little complex.To pure Cr coating,annealing at 500℃ was a perfect chosen,where the ratio between the solar absorptance and the thermal emittance was highest of 1.46.展开更多
Parabolic trough solar collector systems are the most advanced concentrating solar power technology for large-scale power generation purposes. The current work reviews various selective coating materials and their cha...Parabolic trough solar collector systems are the most advanced concentrating solar power technology for large-scale power generation purposes. The current work reviews various selective coating materials and their characteristics for different designs in concentrating solar power. Solar selective absorbing coatings collect solar radiation and convert it to heat. To promote higher efficiency and lower energy costs at higher temperatures requires, this study aims to analyse the fundamental chemistry and thermal stability of some key coatings currently being used and even under investigation to find reasons for differences, information gaps and potential for improvement in results. In recent years, several novel and useful solar absorber coatings have been developed. However, qualification test methods such as corrosion resistance, thermal stability testing and prediction of service life, which have essential technical value for large-scale solar absorbers, are lacking. Coatings are used to enhance the performance of reflectors and absorbers in terms of quality, efficiency, maintenance and cost. Differentiated coatings are required as there are no uniformly perfect materials in various applications, working conditions and material variations. Much more knowledge of the physical and chemical properties and durability of the coatings is required, which will help prevent failures that could not be discovered previously.展开更多
Thermodynamics analysis was carried out for solar thermal receivers with different selective coatings.The relation between the energy conversion efficiency of a medium-high temperature solar thermal system,the spectra...Thermodynamics analysis was carried out for solar thermal receivers with different selective coatings.The relation between the energy conversion efficiency of a medium-high temperature solar thermal system,the spectral properties of selective coating and the operating temperature of the receiver were discussed.Furthermore,the relation between the optimum operating temperatures,the exergy efficiencies and the incident solar flux were analyzed for the traditional concentrating system and concentrating beam splitting system,respectively.According to the analysis results for the thermal receiver with blackbody surface and selective coatings,the optimum cutoff wavelength was obtained for the ideal selective coating.An analysis method for the optimum operating temperature calculation was developed for thermal receivers with selective coating.The optimum operating temperature for an actual selective coating was analyzed on the basis of the proposed theory.展开更多
基金Funded by the "863" Hi-Tech Project of China(No.2009AA05Z440)
文摘TiAlN solar selective absorbing coatings which were deposited on 304L stainless steel using cathodic arc evaporation method were annealed under non-vacuum at different temperatures with different times. The optical properties (absorptance and emittance) of the coatings were measured by a spectrophotometer. It was found that, after being annealed for 2 hours at different temperatures, the absorptance of the coatings reached the highest value of 0.92 at 700 ℃ while the emittance got the lowest value of 0.38 at 800 ℃. When the coatings were annealed at 600 ℃ for 24 hours, the optical properties changed to 0.92/0.44 (absorptance/emittance). By measuring the structure, morphology, elements and surface roughness of the coatings, it was found that both the elemental composition and the surface roughness of the coatings changed as a result of annealing, and these changes caused the change of the optical properties of the coatings.
基金National Natural Science Foundation of China (No.51172012 and No.51472017)State Key Lab of Advance Metals and Materials (2014-ZD03)Foundation of Beijing Municipal Science & Technology Commission
文摘A new solar selective absorbing coating of Mo/NiAlN/NiAlON/SiO_2 multilayer was prepared on stainless steel(SS) substrates by magnetron sputtering for solar thermal power applications. The optical constants and thickness of individual layers were simulated using the Scout software based on the experimentally measured reflectance and transmittance spectra of individual layers. The coating of Mo/NiAlN/NiAlON/SiO_2 with an ideal solar absorptance(α) of 0.945 in the solar spectrum range was designed via the optical constants of each layer in the Scout software. The Mo/NiAlN/NiAlON/SiO_2 coating was deposited via the optimized layer thickness. A good spectral selectivity with absorptance(α=0.936) and emittance(ε=0.09, T=80 ℃) was obtained. This method, which incorporates the optical simulation with the related experiments, provides a convenient approach to obtain the ideal solar selective absorbing coatings.
基金the financial support by the National Natural Science Foundation of China(NSFC)(Nos.51732001,U1832219 and 51972013)Beijing Natural Science Foundation(No.2182035)the Fundamental Research Funds for the Central Universities.
文摘Solar selective absorbing coatings(SSACs)are required to have not only excellent optical property but also outstanding thermal stability for high temperature applications.The optical properties of Mo/ZrSiN/ZrSiON/SiO_(2) SSAC had been optimized successfully before.Herein,we are focusing on the evaluation and mechanism of thermal stability of this multilayer coating for its potential applications in concentrated solar power(CSP)systems.Fortunately,the coating exhibits excellent thermal stability after aging at 400℃ for 1500 h in vacuum.At aging temperature of 500℃ for 1000 h or 600℃ for 300 h in vacuum,the slight inter-diffusion between Mo layer and stainless steel(SS)substrate occurs.At higher aging temperature of 700℃ for 100 h in vacuum,the serious inter-diffusion between Mo layer and SS substrate leads to invalidation of the coating,which has been evidenced by Rutherford backscattering spectrometry(RBS)and X-ray diffraction(XRD)technologies.Additionally,this coating also has an outstanding thermal stability after aging at 400℃for 300 h in air.A heating-cooling cycling(HCC)treatment evidences the good thermal stability of this coating working in cold environment(60℃).The results reveal that this coating can be a promising candidate not only for CSP system in high temperatures but also for usage in cold environment.
基金This work was financially supported by the National Natural Science Foundation of China (NSFC) (No.50471004), Program for New Century Excellent Talents in University (NCET) and Foundation from Engineering Research Institute, Peking University(ERIPKU)(No.204031).
文摘Based on the cermet double layer structure, Nb-NbN multi-layer films for solar selective coatings were deposited by direct current reactive magnetron sputtering. The Nb/Nb-NbN/Al2O3 trilayered structure was deposited on a stainless steel (SS) substrate by using a single niobium target. The expected components were adjusted by changing the gas flowing ratios of Ar: N2. The Al2O3 antireflective layer on the top of the film was produced by r. f. magnetron sputtering using Al2O3 ceramic target. A solar absorptivity of 0.94 and a normal emissivity of 0.16 at room temperature have been achieved for the coating. Thermal vacuum aging to the samples was carried out at 350 and 500 ℃ for 1 h. The results show a good thermal stability. Microstructure and its dependence on temperature of the Nb, NbN and Nb-NbN single layers were investigated, respectively.
基金supported by National Natural Science Foundation of China(Grant no.51801178).
文摘Solar selective absorbing coatings directly harvest solar energy in the form of heat.The higher temperatures are required to drive higher power-cycle efficiencies in favor of lower costs of energy.According to different dielectrics,high temperature coatings can mainly be divided to double cermet solar selective coatings,transition metal nitride multilayer coatings and transition metal oxide multilayer coatings.This paper assesses the photothermal conversion efficiency and thermal stability,and discusses the challenges and strategies of improving both thermal and optical properties.Double cermet layers can stabilize nanocrystalline structures by alloying,while transition metal nitride/oxide layers generally choose the reliable materials with superior mechanical properties and thermal stability.The purpose of this review is to get the optimized systems,and propose further research directions at higher temperature,such as all-ceramic absorbing coatings.
基金Funded by the National Natural Science Foundation of China(No.51402208)the Project by State Key Laboratory of Advanced Technology for Materials Synthesis and Processing(Wuhan University of Technology)(No.2016-KF-11)
文摘The thermal emittance of Cr film, as an IR reflector, was investigated for the use in SSAC. The Cr thin films with different thicknesses were deposited on silicon wafers, optical quartz and stainless steel substrates by cathodic arc ion plating technology as a metallic IR reflector layer in SSAC. The thickness of Cr thin films was optimized to achieve the minimum thermal emittance. The effects of structural, microstructural, optical, surface and cross-sectional morphological properties of Cr thin films were investigated on the emittance. An optimal thickness about 450 nm of the Cr thin film for the lowest total thermal emittance of 0.05 was obtained. The experimental results suggested that the Cr metallic thin film with optimal thickness could be used as an effective infrared reflector for the development of SSAC structure.
基金supported by the Analysis Centre of Tianjin University.
文摘A new method of preparing CuO solar selective absorbing coating for medium temperature is presented.After pretreatment,brass was overlaid with CuO by chemical plating.The effects of reactant concentration,reaction tem-perature and reaction time on the absorptivity of CuO coating were investigated.The optimized condition of preparing CuO coating was obtained.The CuO coating was analyzed with X-ray photoelectron spectroscopy(XPS)and scanning electron microscopy(SEM).In order to prolong the period of use,the CuO coating was protected by TiO2.The experi-ment shows that the TiO2/CuO coating is more heat-resistant,acid-resistant,and wear resistant than CuO coating,without losing absorptivity markedly.The TiO2 coating can reduce emissivity and protect the CuO coating.
文摘Copper zinc tin sulfide(CZTS)thin film was synthesized on soda lime glass substrate by using spin coating method.The synthesized CZTS thin film showed maximum absorption coefficient of 0.193×104 cm-1 and maximum extinction coefficient of 0.011.The direct optical band gap,Urbach energy and steepness parameter of the synthesized CZTS thin film were 1.52 eV,0.52 eV and 0.05 respectively.The CZTS thin film was found to be polycrystalline tetragonal in nature.The scanning electron microscopy(SEM)revealed that the texture structure was formed for the CZTS thin film.
基金supported by the Youth Innovation Promotion Association CAS(2018455)the regional key projects of science and technology service network program of Chinese Academy of Sciences(KFJ-STS-QYZD-139)+1 种基金the National Natural Science Foundation of China(No.51402315)the Key Research&Development Program in Gansu(18YF1GA125)and Scientific Research Project of Colleges and Universities in Gansu Province(No.2018D-03).The characterization results were supported by Beijing Zhongkebaice Technology Service Co.,Ltd.
文摘High entropy alloys(HEAs),which is at the expense of high cost compared to traditional alloy,should not be confined to the mechanical properties,but should be employed to devise a novel combination with unique functional and mechanical performances.In this work,high entropy alloy nitride(HEAN)is utilized as a novel double absorption layer to improve solar absorption in the high temperature solar selective absorbing coatings(SSACs).Our primary motivation is to lower thermal emittance(ε)and enhance solar absorptance(a).In order to realize this goal,coating design(CODE)software is employed to design and optimize the proposed HEAN based SSACs using appropriate dielectric function model.The ultimate as-deposited coating shows good optical properties with a high a value of 0.965 and a lowεvalue of 0.086(at 82C).The estimate of thermal stability tests indicates that HEAN based SSACs has the ability to resist instability in high working temperature,which keeps good optical properties(a¼0.925,ε¼0.070)after annealing at 600C for 10 h.
文摘A series of selective solar absorber coatings of Cr-Cr2O3 were deposited in different content on stainless steel by plasma spraying.The samples were annealed at different temperatures.The optical performance(both the solar absorptance and the thermal emittance)were studied by spectrophotometry.The surface morphology,the structure and the surface roughness were investigated by scanning electron microscopy(SEM),X-ray diffraction(XRD),and roughmeter respectively.The results show that,as the content of Cr increased,the solar absorptance(α)decreased greatly,from 0.91 to 0.84.Meanwhile,the thermal emittance(ε) decreased more greatly,from 0.86 to about 0.64.The ratio between the solar absorptance and the thermal emittance increased from 1.06 to 1.31.Annealing had a great impact on the optical performance.Annealing temperature is an important element.But its influence was a little complex.To pure Cr coating,annealing at 500℃ was a perfect chosen,where the ratio between the solar absorptance and the thermal emittance was highest of 1.46.
基金supported by the Stipendium Hungaricum Programby the Doctoral School of Mechanical Engineering,Hungarian University of Agriculture and Life Sciences,Godollo,Hungary。
文摘Parabolic trough solar collector systems are the most advanced concentrating solar power technology for large-scale power generation purposes. The current work reviews various selective coating materials and their characteristics for different designs in concentrating solar power. Solar selective absorbing coatings collect solar radiation and convert it to heat. To promote higher efficiency and lower energy costs at higher temperatures requires, this study aims to analyse the fundamental chemistry and thermal stability of some key coatings currently being used and even under investigation to find reasons for differences, information gaps and potential for improvement in results. In recent years, several novel and useful solar absorber coatings have been developed. However, qualification test methods such as corrosion resistance, thermal stability testing and prediction of service life, which have essential technical value for large-scale solar absorbers, are lacking. Coatings are used to enhance the performance of reflectors and absorbers in terms of quality, efficiency, maintenance and cost. Differentiated coatings are required as there are no uniformly perfect materials in various applications, working conditions and material variations. Much more knowledge of the physical and chemical properties and durability of the coatings is required, which will help prevent failures that could not be discovered previously.
基金supported by the National Basic Research Program of China("973" Project)(Grant No.2010CB227305)
文摘Thermodynamics analysis was carried out for solar thermal receivers with different selective coatings.The relation between the energy conversion efficiency of a medium-high temperature solar thermal system,the spectral properties of selective coating and the operating temperature of the receiver were discussed.Furthermore,the relation between the optimum operating temperatures,the exergy efficiencies and the incident solar flux were analyzed for the traditional concentrating system and concentrating beam splitting system,respectively.According to the analysis results for the thermal receiver with blackbody surface and selective coatings,the optimum cutoff wavelength was obtained for the ideal selective coating.An analysis method for the optimum operating temperature calculation was developed for thermal receivers with selective coating.The optimum operating temperature for an actual selective coating was analyzed on the basis of the proposed theory.
