The title compound, methyl 2-（diphenylamino）-4-phenyl-1,3-thiazole-5-carboxylate, was synthesized and studied by single-crystal X-ray diffraction method. The structure of the product was confirmed by IR, 1H- and 13C...The title compound, methyl 2-（diphenylamino）-4-phenyl-1,3-thiazole-5-carboxylate, was synthesized and studied by single-crystal X-ray diffraction method. The structure of the product was confirmed by IR, 1H- and 13C-NMR spectroscopy and elemental analysis. These experimental studies were supported by quantum mechanical calculations. The structure was solved in monoclinic, space group P21/c with a = 9.573（3）, b = 19.533（7）, c = 9.876（3）, β = 92.35（4）°, V = 1845.2（10）3, T = 85（2） K, Z = 4, R = 0.040 and wR = 0.089 for 6424 observed reflections with I2σ（I）.展开更多
Triphenyltin thiazole-2-carboxylate (1) and triphenyltin 3-pyridinylcarboxylate (2) were synthesized by the reaction of sodium thiazole-2-carboxylate or sodium 3-pyridinylcarboxylate with the triphenyltin chloride and...Triphenyltin thiazole-2-carboxylate (1) and triphenyltin 3-pyridinylcarboxylate (2) were synthesized by the reaction of sodium thiazole-2-carboxylate or sodium 3-pyridinylcarboxylate with the triphenyltin chloride and their crystal structures were determined by single crystal X-ray diffraction analysis. In the structure of 1, the tin atom is five-coordinated in a distorted trigonal bipyramidal structure. Due to the presence of a close intermolecular Sn...S interaction distance of 0.3666 nm, the structure can be described as a weakly-bridged one-dimensional chain compound. In the structure of 2, the tin atom is five-coordinated with bridging 3-pyridinylcarboxylate ligands N atom and resulting structure is one-dimensional chain compound.展开更多
The target compounds were prepared from thioamides with a series of α-halogenated carbonylate compounds.Ethyl thiazole-5-carboxylate,4-(chloromethyl)-2-isopropylthiazole and 2-isopropyl-ethyl thiazole-5-carboxylate w...The target compounds were prepared from thioamides with a series of α-halogenated carbonylate compounds.Ethyl thiazole-5-carboxylate,4-(chloromethyl)-2-isopropylthiazole and 2-isopropyl-ethyl thiazole-5-carboxylate were obtained in yields of 60%,65% and 70% respectively.展开更多
基金supported by Urmia Branch,Islamic Azad University
文摘The title compound, methyl 2-（diphenylamino）-4-phenyl-1,3-thiazole-5-carboxylate, was synthesized and studied by single-crystal X-ray diffraction method. The structure of the product was confirmed by IR, 1H- and 13C-NMR spectroscopy and elemental analysis. These experimental studies were supported by quantum mechanical calculations. The structure was solved in monoclinic, space group P21/c with a = 9.573（3）, b = 19.533（7）, c = 9.876（3）, β = 92.35（4）°, V = 1845.2（10）3, T = 85（2） K, Z = 4, R = 0.040 and wR = 0.089 for 6424 observed reflections with I2σ（I）.
基金ProjectsupportedbytheNaturalScienceFoundationofShandongProvince (No .Z2 0 0 1B0 2 )andtheFoundationofStateKeyLaborato ryofCrystalMaterials,ShandongUniversity
文摘Triphenyltin thiazole-2-carboxylate (1) and triphenyltin 3-pyridinylcarboxylate (2) were synthesized by the reaction of sodium thiazole-2-carboxylate or sodium 3-pyridinylcarboxylate with the triphenyltin chloride and their crystal structures were determined by single crystal X-ray diffraction analysis. In the structure of 1, the tin atom is five-coordinated in a distorted trigonal bipyramidal structure. Due to the presence of a close intermolecular Sn...S interaction distance of 0.3666 nm, the structure can be described as a weakly-bridged one-dimensional chain compound. In the structure of 2, the tin atom is five-coordinated with bridging 3-pyridinylcarboxylate ligands N atom and resulting structure is one-dimensional chain compound.
文摘The target compounds were prepared from thioamides with a series of α-halogenated carbonylate compounds.Ethyl thiazole-5-carboxylate,4-(chloromethyl)-2-isopropylthiazole and 2-isopropyl-ethyl thiazole-5-carboxylate were obtained in yields of 60%,65% and 70% respectively.
