The mechanical properties of regenerated W-alloys relating to the chemical purity and size of reclamation powders of 93W-Ni-Fe-Co(Mn)alloy chips,the structure of main constituents of the powders,as well as microstruet...The mechanical properties of regenerated W-alloys relating to the chemical purity and size of reclamation powders of 93W-Ni-Fe-Co(Mn)alloy chips,the structure of main constituents of the powders,as well as microstrueture and fractograph of regenerated W-alloys made by the reclamation powders,composition of W particle and binder phase,content,structure and distribution of main impurity elements have been studied by means of optical microscope, SEM,XRES.XRD,TEM,AES and chemical analysis.The feasibility of oxidation-reduc- tion process for reclamation and the possibility of praetical application of regenerated W-al- loys have been discussed.展开更多
The high-temperature mechanical properties of 95W-3.5Ni-1.5Fe and 95W-4.5Ni-0.5Co alloys were investigated in the temperature range of room temperature to1100℃. The yield strength and tensile strengths declined gradu...The high-temperature mechanical properties of 95W-3.5Ni-1.5Fe and 95W-4.5Ni-0.5Co alloys were investigated in the temperature range of room temperature to1100℃. The yield strength and tensile strengths declined gradually, and the ductility of both alloys increased as the testing temperature was increased to 300℃. All the three properties reached a plateau at temperatures between 300 and 500℃ in the case of 95W-3.5Ni-l.5Fe and at temperatures between 350 and 700℃ in the case of 95W-4.5Ni-0.5Co. Thereafter, the ductility as well as yield and tensile strengths decreased considerably.展开更多
Ultrafine grain tungsten heavy alloys (WHAs) were successfully produced from the nano-crystalline powders using spark plasma sintering.The present study mainly discussed the effects of sintering temperature on the den...Ultrafine grain tungsten heavy alloys (WHAs) were successfully produced from the nano-crystalline powders using spark plasma sintering.The present study mainly discussed the effects of sintering temperature on the density,microstructure and mechanical properties of the alloys.The relative density of 98.12% was obtained at 1 050 ℃,and the tungsten grain size is about 871 nm.At 1 000 ℃-1 200 ℃,the mechanical properties of the alloys tend to first rise and then goes down.After SPS,the alloy exhibits improved hardness (84.3 HRA at 1 050 ℃) and bending strength (987.16 MPa at 1 100 ℃),due to the ultrafine-grained microstructure.The fracture mode after bending tests is mainly characterized as intergranular or intragranular fracture of W grains,interfacial debonding of W grains-binding phase and ductile tearing of binding phase.The EDS analysis reveals a certain proportion of solid solution between W and Ni-Fe binding phase.The good mechanical properties of the alloys can be attributed to grain refinement and solid solution strengthening.展开更多
Against protection requirements for high-speed fragments on the ground weapons,we carried out the research work of crushing mechanism at different impact speeds ofφ8.7 mm spherical tungsten alloy,the penetration to 6...Against protection requirements for high-speed fragments on the ground weapons,we carried out the research work of crushing mechanism at different impact speeds ofφ8.7 mm spherical tungsten alloy,the penetration to 603 armor steel was completed by 20 mm ballistic gun,and the ANSYS/LS-DYNA software was used to complete the numerical calculation of the penetration.We find that there are different crushing mechanisms of spherical tungsten alloy with different speeds and low speed,the crushing mechanism of fragment is mainly controlled by overall plastic deformation,shearing stripping,and squeezing at a high pressure and a high speed.The crushing mechanism will have a spallation phenomenon in addition to the crushing mechanism under high pressure.展开更多
Pure tungsten, oxide dispersion strengthened tungsten and carbide dispersion strengthened tungsten were fabricated by high-energy ball milling and spark plasma sintering process. In order to evaluate the properties of...Pure tungsten, oxide dispersion strengthened tungsten and carbide dispersion strengthened tungsten were fabricated by high-energy ball milling and spark plasma sintering process. In order to evaluate the properties of the tungsten alloys under transient high heat flues, four tungsten samples with different grain sizes were tested by high-intensity pulsed ion beam with a heat flux as high as 160 MW/（m^2·s^-1/2）. Compared with the commercial tungsten, the surface modification of the oxide dispersion strengthened tungsten by high-intensity pulsed ion beam is completely different. The oxide dispersion strengthened tungsten shows inferior thermal shock response due to the low melting point second phase of Ti and Y2O3, which results in the surface melting, boiling bubbles and cracking. While the carbide dispersion strengthened tungsten shows better thermal shock response than the commercial tungsten.展开更多
The effect of different concentrations of benzaldehyde on the electrodeposition of Ni–W alloy coatings on a mild steel substrate from a citrate electrolyte was investigated in this study. The electrolytic alkaline ba...The effect of different concentrations of benzaldehyde on the electrodeposition of Ni–W alloy coatings on a mild steel substrate from a citrate electrolyte was investigated in this study. The electrolytic alkaline bath(p H 8.0) contained stoichiometric amounts of nickel sulfate, sodium tungstate, and trisodium citrate as precursors. The corrosion resistance of the Ni–W-alloy-coated specimens in 0.2 mol/L H2SO4 was studied using various electrochemical techniques. Tafel polarization studies reveal that the alloy coatings obtained from the bath containing 50 ppm benzaldehyde exhibit a protection efficiency of 95.33%. The corrosion rate also decreases by 21.5 times compared with that of the blank. A higher charge-transfer resistance of 1159.40 ?·cm2 and a lower double-layer capacitance of 29.4 μF·cm-2 further confirm the better corrosion resistance of the alloy coating. X-ray diffraction studies reveal that the deposits on the mild steel surface are consisted of nanocrystals. A lower surface roughness value(Rmax) of the deposits is confirmed by atomic force microscopy.展开更多
Tungsten alloys were prepared with mechanically activated powder added microelement cobalt in order to improve the process and properties of alloys. Properties of alloys such as density, hardness and bending strength ...Tungsten alloys were prepared with mechanically activated powder added microelement cobalt in order to improve the process and properties of alloys. Properties of alloys such as density, hardness and bending strength were measured. The results show that through mechanical activation, cobalt can accelerate the sintering process of these alloys By the combination of mechanical activation and adding microelement cobalt, tungsten alloys with higher density and better properties can be obtained.展开更多
A comparative study was conducted by using solution combustion synthesis with three different doping routes(liquid-liquid(WL10), liquid-solid(WLNO) and solid-solid(WLO)) to produce nanoscale powders and further fabric...A comparative study was conducted by using solution combustion synthesis with three different doping routes(liquid-liquid(WL10), liquid-solid(WLNO) and solid-solid(WLO)) to produce nanoscale powders and further fabricate the ultrafine-grained W-1.0 wt.%La2O3 alloys by pressureless sintering. Compared with pure tungsten, W-1.0 wt.%La2O3 alloys exhibit ultrafine grains and excellent mechanical properties. After sintering, the average grain size of the WLO sample is larger than that of WL10 and WLNO samples;the microhardness values of WL10 and WLNO samples are similar but larger than the value of WLO sample. The optimized La2O3 particles are obtained in the WL10 sample after sintering at 1500 ℃ with the minimum mean size by comparing with WLNO and WLO samples, which are uniformly distributed either at grain boundaries or in the grain interior with the sizes of(57±29.7) and(27±13.1) nm, respectively. This study exhibits ultrafine microstructure and outperforming mechanical properties of the W-1.0 wt.%La2O3 alloy via the liquid-liquid doping route, as compared with conventionally-manufactured tungsten materials.展开更多
The effect of strain rate on ultimate strength and fractograph was investigated for tungsten alloy with four different technologies. As the strain rate rises, the ultimate strength increases and morphology of fracture...The effect of strain rate on ultimate strength and fractograph was investigated for tungsten alloy with four different technologies. As the strain rate rises, the ultimate strength increases and morphology of fracture surface gradually transits from detachment of interface between W pellets and matrices to cleavage of W pellets. Meanwhile, low strength tungsten alloy has higher sensitivity to strain rate.展开更多
The aim of this research was to examine the effect of microstructural parameters on the tensile properties of different compositions of tungsten heavy alloys. The microstructural parameters （grain size, connectivity,...The aim of this research was to examine the effect of microstructural parameters on the tensile properties of different compositions of tungsten heavy alloys. The microstructural parameters （grain size, connectivity, contiguity, and solid volume fraction） were measured and were found to have a significant effect on the tensile properties of tungsten-based heavy alloys. The microstructural parameters of W-Ni-Fe alloys are sufficiently different to present a range of mechanical properties. It is concluded that the mechanical properties of tungsten heavy alloys largely depend on the microstructural parameters and their ductility is particularly harmed when grains are contiguous.展开更多
The hardness variation of two kinds of alloys with 36 wt pct W content and 7/3, 9/1 Ni-to-Fe ratios during strain aging at 800℃ was studied. The microstructures of the aged alloys were analyzed by X-ray diffraction a...The hardness variation of two kinds of alloys with 36 wt pct W content and 7/3, 9/1 Ni-to-Fe ratios during strain aging at 800℃ was studied. The microstructures of the aged alloys were analyzed by X-ray diffraction and TEM. The results show that the strain aging hardness of W-Ni-Fe ternary alloy with 7/3 Ni-to-Fe ratio decreases monotonically with the increase of aging time. Under the same conditions, the hardness of 9/1 Ni-to-Fe ratio alloy decreases in the initial aging stage, but then increases as aging process goes on. X ray diffraction and TEM analysis show that there is not any precipitation depositing from the alloy with 7/3 Ni-to-Fe ratio during aging. The monotonic decrease in hardness of this alloy during aging process results from the recovery, recrystallization and solid solubility declining. In the alloy of 9/1 Ni-to-Fe ratio, the fine β phase precipitates dispersively during aging which hardens the alloy. The two different kinds of mechanisms (the softening one and the hardening one) decide the hardness variation of the alloy with 9/1 Ni-to-Fe ratio mentioned above.展开更多
The dynamic stress-strain curves of 93% tungsten (W) alloy in the forged state at strain rates up to (5 000 s^(-1)) and in the temperature range from 223 K to 473 K were measured with the split Hopkinson pressure bar ...The dynamic stress-strain curves of 93% tungsten (W) alloy in the forged state at strain rates up to (5 000 s^(-1)) and in the temperature range from 223 K to 473 K were measured with the split Hopkinson pressure bar (SHPB) technique. Based on the above experimental data a dynamic constitutive equation considering the effects of strain rate, temperature and the special microstructure of such a kind of W-alloy was proposed. The numerical simulation for the experimental process with this constitutive equation was also carried out, the results show that the constitutive relationship constructed in this paper is very satisfactory for representing the dynamic responsive behavior of material..展开更多
The effect of cryogenic temperature on adiabatic shear banding (ASBing) of tungsten heavy alloy (WHA) processed by hot-hydrostatic ex-trusion was investigated.Results show that,when the initial temperature is decrease...The effect of cryogenic temperature on adiabatic shear banding (ASBing) of tungsten heavy alloy (WHA) processed by hot-hydrostatic ex-trusion was investigated.Results show that,when the initial temperature is decreased,the dynamic flow stress,the critical failure time,and the dynamic failure energy of specimens show an increasing tendency,while the susceptibility to ASB of WHA shows a decreasing tendency,which is characterized by decreased shear strain and increased width of shear bands.Microstructure analysis shows that the number of mi-crocracks within ASB exhibits an increasing tendency with decreased initial temperature,and the dynamic recrystallization (DRX) process within ASB is evidently suppressed at the lower temperature.As a result of the lower temperature,the motion and rearrangement of disloca-tion are effectively suppressed,which is mainly responsible for the incomplete DRX process within ASB and decreases susceptibility to ASB.展开更多
The model describing the dependence of the mechanical properties on the chemical composition and as deformation techniques of tungsten heavy alloy is established by the method of improved the backpropagation neural ne...The model describing the dependence of the mechanical properties on the chemical composition and as deformation techniques of tungsten heavy alloy is established by the method of improved the backpropagation neural network. The mechanical properties＇ parameters of tungsten alloy and deformation techniques for tungsten alloy are used as the inputs. The chemical composition and deformation amount of tungsten alloy are used as the outputs. Then they are used for training the neural network. At the same time, the optimal number of the hidden neurons is obtained through the experiential equations, and the varied step learning method is adopted to ensure the stability of the training process. According to the requirements for mechanical properties, the chemical composition and the deformation condition for tungsten heavy alloy can be designed by this artificial neural network system.展开更多
High temperature treatment of tungsten alloy of W-5wt.% TM （transition metals, TM = Ni, Fe, Cu, Co） nanopowder was run under different temperatures to cover the oxidation rate at different temperatures. The correlat...High temperature treatment of tungsten alloy of W-5wt.% TM （transition metals, TM = Ni, Fe, Cu, Co） nanopowder was run under different temperatures to cover the oxidation rate at different temperatures. The correlation was developed for certain temperatures to find an equation for the relation between time and weight. The thermal treatment was done for different quantities at certain times. The proposed equation studies the correlation between temperature, time, and weight. For each temperature, a number of points were recorded from the measured oxidation curve. The shape of the curves is well-represented in this paper. The final results will present the highest temperature, the maximum weight, and the maximum time for full oxidation at high and low temperatures.展开更多
Porosity is a common phenomenon and can significantly hinder the quality of the coating.Here,the pore formation mechanism and the characteristics of the single tracks of the W-C coating using directed energy depositio...Porosity is a common phenomenon and can significantly hinder the quality of the coating.Here,the pore formation mechanism and the characteristics of the single tracks of the W-C coating using directed energy deposition(DED)are systematically investigated.The forming quality of the tracks,the distribution of the pores,and the elemental distribution near the pores are analyzed by the observations of the cross-sections of the tracks.The temperature field of the melt pool is discussed comprehensively to reveal the pore formation mechanism.The results confirm that Ni and Co evaporated during the DED process due to the high temperature of the melt pool.Pores were continuously produced adjacent to the fusion line when the melt pool was about to solidify since the temperature at the solidification front was higher than the boiling point of Ni.The vaporization area at the fusion line was proposed,where Ni could also evaporate at the time the melt pool started to solidify.The relationship between the solidification rate,the size of the vaporization area and the DED parameters(laser power and scanning speed)was established to discuss the causes of severe pores above the fusion line.This work contains a practical guide to reduce or eliminate the porosity in the coating preparation process on the surface of the tungsten alloy.展开更多
The effects of intermediate annealing （IA） on the microstructure and texture of Ni-9.3at%W substrates have been investigated by using electron backscattering diffraction and X-ray diffraction. Results suggest that I...The effects of intermediate annealing （IA） on the microstructure and texture of Ni-9.3at%W substrates have been investigated by using electron backscattering diffraction and X-ray diffraction. Results suggest that IA can optimize the homogeneity of deformation micro-structure. Higher IA temperatures （without undergoing recrystallization during IA） will increase the copper-type components of deformation texture and improve the content of cube texture after recrystallization. Sharp cube texture （97.2%） can be obtained at the optimum IA tem-perature of 650°C. The mechanism underlying the transition of deformation texture can be interpreted as that IA increases the dislocation slipping ability and suppresses the twinning deformation of Copper orientation in the subsequent rolling process. The observed strengthening of cube texture as a result of IA treatment is presumably attributed to the reduction of noncube nucleation and the optimization of preferential growth surrounding the cube nuclei.展开更多
The mixture of 90 wt%W, 7 wt%Ni and 3 wt%Fe elemental powders was milled in a planetary high-energy ball mill. The evolution of the structure during milling and the sintering behavior of the milled powders were tested...The mixture of 90 wt%W, 7 wt%Ni and 3 wt%Fe elemental powders was milled in a planetary high-energy ball mill. The evolution of the structure during milling and the sintering behavior of the milled powders were tested. The results showed that by mechanical alloying W(Ni, Fe) supersaturated solid solution with nano-meter size formed, which can enhance the sintering process. Fully dense alloy from the milled powders was obtained through solid state sintering. The tensile strength of the obtained alloy is over 900 MPa which is comparable to that of the alloy sintered by traditional liquid-phase sintering from un-milled powders of the same composition.展开更多
Amorphous metals are totally different from crystalline metals in regard to atom arrangement. Amorphous metals do not have grain boundaries and weak spots that crystalline materials contain, making them more resistant...Amorphous metals are totally different from crystalline metals in regard to atom arrangement. Amorphous metals do not have grain boundaries and weak spots that crystalline materials contain, making them more resistant to wear and corrosion. In this study, amorphous Fe-W alloy films were first prepared by an electroplating method and were then made hydrophobic by modification with a water repellent （heptadecafluoro-1,1,2,2-tetradecyl） trimethoxysilane. Hierarchical micro-nano structures can be obtained by slightly oxidizing the as-deposited alloy, accompanied by phase transformation from amorphous to crystalline during heat treatment. The mi-cro-nano structures can trap air to form an extremely thin cushion of air between the water and the film, which is critical to producing hydrophobicity in the film. Results show that the average values of capacitance, roughness factor, and impedance for specific surface areas of a 600°C heat-treated sample are greater than those of a sample treated at 500°C. Importantly, the coating can be fabricated on various metal substrates to act as a corrosion retardant.展开更多
95W?3.4Ni?1.6Fe heavy alloy was carburized by pack carburization. Microstructure and hardness of the carburized alloywere investigated by SEM, EDS XRD. Effect of carburization on the rolling contact fatigue (RCF) prop...95W?3.4Ni?1.6Fe heavy alloy was carburized by pack carburization. Microstructure and hardness of the carburized alloywere investigated by SEM, EDS XRD. Effect of carburization on the rolling contact fatigue (RCF) property of the alloy was studied.The results showed that the carburized layer was composed of the outer, porous WC layer and the modified subsurface layer witheach W grain surrounded by a WC shell. Carburization not only decreased the RCF performance of the alloy but also aggravated thewear of the counter balls. The untreated alloy was damaged by two modes of spalling and delamination under RCF condition. Thesubsurface main crack of the untreated alloy initiated where the maximum shear stress existed and preferentially propagated alongthe W?W interfaces. Spalling was the main failure mode of the carburized alloys, and the crumbling WC particles intensified theabrasion of the carburized surface.展开更多
文摘The mechanical properties of regenerated W-alloys relating to the chemical purity and size of reclamation powders of 93W-Ni-Fe-Co(Mn)alloy chips,the structure of main constituents of the powders,as well as microstrueture and fractograph of regenerated W-alloys made by the reclamation powders,composition of W particle and binder phase,content,structure and distribution of main impurity elements have been studied by means of optical microscope, SEM,XRES.XRD,TEM,AES and chemical analysis.The feasibility of oxidation-reduc- tion process for reclamation and the possibility of praetical application of regenerated W-al- loys have been discussed.
文摘The high-temperature mechanical properties of 95W-3.5Ni-1.5Fe and 95W-4.5Ni-0.5Co alloys were investigated in the temperature range of room temperature to1100℃. The yield strength and tensile strengths declined gradually, and the ductility of both alloys increased as the testing temperature was increased to 300℃. All the three properties reached a plateau at temperatures between 300 and 500℃ in the case of 95W-3.5Ni-l.5Fe and at temperatures between 350 and 700℃ in the case of 95W-4.5Ni-0.5Co. Thereafter, the ductility as well as yield and tensile strengths decreased considerably.
基金the National Key Research and Development Plan of China(2017YFB0310400)the National Natural Science Foundation of China(Nos.5167020705 and 51902233)the Self-determined and Innovative Research Funds of WHUT(2019III059XZ)。
文摘Ultrafine grain tungsten heavy alloys (WHAs) were successfully produced from the nano-crystalline powders using spark plasma sintering.The present study mainly discussed the effects of sintering temperature on the density,microstructure and mechanical properties of the alloys.The relative density of 98.12% was obtained at 1 050 ℃,and the tungsten grain size is about 871 nm.At 1 000 ℃-1 200 ℃,the mechanical properties of the alloys tend to first rise and then goes down.After SPS,the alloy exhibits improved hardness (84.3 HRA at 1 050 ℃) and bending strength (987.16 MPa at 1 100 ℃),due to the ultrafine-grained microstructure.The fracture mode after bending tests is mainly characterized as intergranular or intragranular fracture of W grains,interfacial debonding of W grains-binding phase and ductile tearing of binding phase.The EDS analysis reveals a certain proportion of solid solution between W and Ni-Fe binding phase.The good mechanical properties of the alloys can be attributed to grain refinement and solid solution strengthening.
基金Funded by the National Defense Technology Key Laboratory of Impact Environmental Materials。
文摘Against protection requirements for high-speed fragments on the ground weapons,we carried out the research work of crushing mechanism at different impact speeds ofφ8.7 mm spherical tungsten alloy,the penetration to 603 armor steel was completed by 20 mm ballistic gun,and the ANSYS/LS-DYNA software was used to complete the numerical calculation of the penetration.We find that there are different crushing mechanisms of spherical tungsten alloy with different speeds and low speed,the crushing mechanism of fragment is mainly controlled by overall plastic deformation,shearing stripping,and squeezing at a high pressure and a high speed.The crushing mechanism will have a spallation phenomenon in addition to the crushing mechanism under high pressure.
基金roject (50634060) supported by the National Natural Science Foundation of ChinaProject (2010GB109000) supported by the National Basic Research Program of China
文摘Pure tungsten, oxide dispersion strengthened tungsten and carbide dispersion strengthened tungsten were fabricated by high-energy ball milling and spark plasma sintering process. In order to evaluate the properties of the tungsten alloys under transient high heat flues, four tungsten samples with different grain sizes were tested by high-intensity pulsed ion beam with a heat flux as high as 160 MW/（m^2·s^-1/2）. Compared with the commercial tungsten, the surface modification of the oxide dispersion strengthened tungsten by high-intensity pulsed ion beam is completely different. The oxide dispersion strengthened tungsten shows inferior thermal shock response due to the low melting point second phase of Ti and Y2O3, which results in the surface melting, boiling bubbles and cracking. While the carbide dispersion strengthened tungsten shows better thermal shock response than the commercial tungsten.
文摘The effect of different concentrations of benzaldehyde on the electrodeposition of Ni–W alloy coatings on a mild steel substrate from a citrate electrolyte was investigated in this study. The electrolytic alkaline bath(p H 8.0) contained stoichiometric amounts of nickel sulfate, sodium tungstate, and trisodium citrate as precursors. The corrosion resistance of the Ni–W-alloy-coated specimens in 0.2 mol/L H2SO4 was studied using various electrochemical techniques. Tafel polarization studies reveal that the alloy coatings obtained from the bath containing 50 ppm benzaldehyde exhibit a protection efficiency of 95.33%. The corrosion rate also decreases by 21.5 times compared with that of the blank. A higher charge-transfer resistance of 1159.40 ?·cm2 and a lower double-layer capacitance of 29.4 μF·cm-2 further confirm the better corrosion resistance of the alloy coating. X-ray diffraction studies reveal that the deposits on the mild steel surface are consisted of nanocrystals. A lower surface roughness value(Rmax) of the deposits is confirmed by atomic force microscopy.
文摘Tungsten alloys were prepared with mechanically activated powder added microelement cobalt in order to improve the process and properties of alloys. Properties of alloys such as density, hardness and bending strength were measured. The results show that through mechanical activation, cobalt can accelerate the sintering process of these alloys By the combination of mechanical activation and adding microelement cobalt, tungsten alloys with higher density and better properties can be obtained.
基金Projects(2017YFB0306000,2017YFB0305600)supported by the National Key Research and Development Program of ChinaProjects(51774035,51604025,51574031,51574030,51574029,51604240)supported by the National Natural Science Foundation of China+2 种基金Project(2019JZZY010327)supported by the Shandong Key Research and Development Plan Project,ChinaProjects(2174079,2162027)supported by the Natural Science Foundation Program of Beijing,ChinaProjects(FRF-IDRY-19-025,FRF-TP-17-034A2,FRF-TP-19-015A3,FRF-IDRY-19-003C2)supported by the Fundamental Research Funds for the Central Universities of China。
文摘A comparative study was conducted by using solution combustion synthesis with three different doping routes(liquid-liquid(WL10), liquid-solid(WLNO) and solid-solid(WLO)) to produce nanoscale powders and further fabricate the ultrafine-grained W-1.0 wt.%La2O3 alloys by pressureless sintering. Compared with pure tungsten, W-1.0 wt.%La2O3 alloys exhibit ultrafine grains and excellent mechanical properties. After sintering, the average grain size of the WLO sample is larger than that of WL10 and WLNO samples;the microhardness values of WL10 and WLNO samples are similar but larger than the value of WLO sample. The optimized La2O3 particles are obtained in the WL10 sample after sintering at 1500 ℃ with the minimum mean size by comparing with WLNO and WLO samples, which are uniformly distributed either at grain boundaries or in the grain interior with the sizes of(57±29.7) and(27±13.1) nm, respectively. This study exhibits ultrafine microstructure and outperforming mechanical properties of the W-1.0 wt.%La2O3 alloy via the liquid-liquid doping route, as compared with conventionally-manufactured tungsten materials.
文摘The effect of strain rate on ultimate strength and fractograph was investigated for tungsten alloy with four different technologies. As the strain rate rises, the ultimate strength increases and morphology of fracture surface gradually transits from detachment of interface between W pellets and matrices to cleavage of W pellets. Meanwhile, low strength tungsten alloy has higher sensitivity to strain rate.
文摘The aim of this research was to examine the effect of microstructural parameters on the tensile properties of different compositions of tungsten heavy alloys. The microstructural parameters （grain size, connectivity, contiguity, and solid volume fraction） were measured and were found to have a significant effect on the tensile properties of tungsten-based heavy alloys. The microstructural parameters of W-Ni-Fe alloys are sufficiently different to present a range of mechanical properties. It is concluded that the mechanical properties of tungsten heavy alloys largely depend on the microstructural parameters and their ductility is particularly harmed when grains are contiguous.
基金This work was supported by the National Natural Science Foundation of China under grant No.59971007.
文摘The hardness variation of two kinds of alloys with 36 wt pct W content and 7/3, 9/1 Ni-to-Fe ratios during strain aging at 800℃ was studied. The microstructures of the aged alloys were analyzed by X-ray diffraction and TEM. The results show that the strain aging hardness of W-Ni-Fe ternary alloy with 7/3 Ni-to-Fe ratio decreases monotonically with the increase of aging time. Under the same conditions, the hardness of 9/1 Ni-to-Fe ratio alloy decreases in the initial aging stage, but then increases as aging process goes on. X ray diffraction and TEM analysis show that there is not any precipitation depositing from the alloy with 7/3 Ni-to-Fe ratio during aging. The monotonic decrease in hardness of this alloy during aging process results from the recovery, recrystallization and solid solubility declining. In the alloy of 9/1 Ni-to-Fe ratio, the fine β phase precipitates dispersively during aging which hardens the alloy. The two different kinds of mechanisms (the softening one and the hardening one) decide the hardness variation of the alloy with 9/1 Ni-to-Fe ratio mentioned above.
文摘The dynamic stress-strain curves of 93% tungsten (W) alloy in the forged state at strain rates up to (5 000 s^(-1)) and in the temperature range from 223 K to 473 K were measured with the split Hopkinson pressure bar (SHPB) technique. Based on the above experimental data a dynamic constitutive equation considering the effects of strain rate, temperature and the special microstructure of such a kind of W-alloy was proposed. The numerical simulation for the experimental process with this constitutive equation was also carried out, the results show that the constitutive relationship constructed in this paper is very satisfactory for representing the dynamic responsive behavior of material..
文摘The effect of cryogenic temperature on adiabatic shear banding (ASBing) of tungsten heavy alloy (WHA) processed by hot-hydrostatic ex-trusion was investigated.Results show that,when the initial temperature is decreased,the dynamic flow stress,the critical failure time,and the dynamic failure energy of specimens show an increasing tendency,while the susceptibility to ASB of WHA shows a decreasing tendency,which is characterized by decreased shear strain and increased width of shear bands.Microstructure analysis shows that the number of mi-crocracks within ASB exhibits an increasing tendency with decreased initial temperature,and the dynamic recrystallization (DRX) process within ASB is evidently suppressed at the lower temperature.As a result of the lower temperature,the motion and rearrangement of disloca-tion are effectively suppressed,which is mainly responsible for the incomplete DRX process within ASB and decreases susceptibility to ASB.
文摘The model describing the dependence of the mechanical properties on the chemical composition and as deformation techniques of tungsten heavy alloy is established by the method of improved the backpropagation neural network. The mechanical properties＇ parameters of tungsten alloy and deformation techniques for tungsten alloy are used as the inputs. The chemical composition and deformation amount of tungsten alloy are used as the outputs. Then they are used for training the neural network. At the same time, the optimal number of the hidden neurons is obtained through the experiential equations, and the varied step learning method is adopted to ensure the stability of the training process. According to the requirements for mechanical properties, the chemical composition and the deformation condition for tungsten heavy alloy can be designed by this artificial neural network system.
文摘High temperature treatment of tungsten alloy of W-5wt.% TM （transition metals, TM = Ni, Fe, Cu, Co） nanopowder was run under different temperatures to cover the oxidation rate at different temperatures. The correlation was developed for certain temperatures to find an equation for the relation between time and weight. The thermal treatment was done for different quantities at certain times. The proposed equation studies the correlation between temperature, time, and weight. For each temperature, a number of points were recorded from the measured oxidation curve. The shape of the curves is well-represented in this paper. The final results will present the highest temperature, the maximum weight, and the maximum time for full oxidation at high and low temperatures.
文摘Porosity is a common phenomenon and can significantly hinder the quality of the coating.Here,the pore formation mechanism and the characteristics of the single tracks of the W-C coating using directed energy deposition(DED)are systematically investigated.The forming quality of the tracks,the distribution of the pores,and the elemental distribution near the pores are analyzed by the observations of the cross-sections of the tracks.The temperature field of the melt pool is discussed comprehensively to reveal the pore formation mechanism.The results confirm that Ni and Co evaporated during the DED process due to the high temperature of the melt pool.Pores were continuously produced adjacent to the fusion line when the melt pool was about to solidify since the temperature at the solidification front was higher than the boiling point of Ni.The vaporization area at the fusion line was proposed,where Ni could also evaporate at the time the melt pool started to solidify.The relationship between the solidification rate,the size of the vaporization area and the DED parameters(laser power and scanning speed)was established to discuss the causes of severe pores above the fusion line.This work contains a practical guide to reduce or eliminate the porosity in the coating preparation process on the surface of the tungsten alloy.
基金financially supported by the National Natural Science Foundation of China(Nos.50671052 and 50971077)
文摘The effects of intermediate annealing （IA） on the microstructure and texture of Ni-9.3at%W substrates have been investigated by using electron backscattering diffraction and X-ray diffraction. Results suggest that IA can optimize the homogeneity of deformation micro-structure. Higher IA temperatures （without undergoing recrystallization during IA） will increase the copper-type components of deformation texture and improve the content of cube texture after recrystallization. Sharp cube texture （97.2%） can be obtained at the optimum IA tem-perature of 650°C. The mechanism underlying the transition of deformation texture can be interpreted as that IA increases the dislocation slipping ability and suppresses the twinning deformation of Copper orientation in the subsequent rolling process. The observed strengthening of cube texture as a result of IA treatment is presumably attributed to the reduction of noncube nucleation and the optimization of preferential growth surrounding the cube nuclei.
文摘The mixture of 90 wt%W, 7 wt%Ni and 3 wt%Fe elemental powders was milled in a planetary high-energy ball mill. The evolution of the structure during milling and the sintering behavior of the milled powders were tested. The results showed that by mechanical alloying W(Ni, Fe) supersaturated solid solution with nano-meter size formed, which can enhance the sintering process. Fully dense alloy from the milled powders was obtained through solid state sintering. The tensile strength of the obtained alloy is over 900 MPa which is comparable to that of the alloy sintered by traditional liquid-phase sintering from un-milled powders of the same composition.
基金financially supported by the National Magnetic Confinement Fusion Science Program(No.2010GB106003)the National Natural Science Founda-tion of China(No.91023037)
文摘Amorphous metals are totally different from crystalline metals in regard to atom arrangement. Amorphous metals do not have grain boundaries and weak spots that crystalline materials contain, making them more resistant to wear and corrosion. In this study, amorphous Fe-W alloy films were first prepared by an electroplating method and were then made hydrophobic by modification with a water repellent （heptadecafluoro-1,1,2,2-tetradecyl） trimethoxysilane. Hierarchical micro-nano structures can be obtained by slightly oxidizing the as-deposited alloy, accompanied by phase transformation from amorphous to crystalline during heat treatment. The mi-cro-nano structures can trap air to form an extremely thin cushion of air between the water and the film, which is critical to producing hydrophobicity in the film. Results show that the average values of capacitance, roughness factor, and impedance for specific surface areas of a 600°C heat-treated sample are greater than those of a sample treated at 500°C. Importantly, the coating can be fabricated on various metal substrates to act as a corrosion retardant.
基金Project(9140A18070114JW16001)supported by the Advanced Research Fund of Department of Defense,ChinaProject(2014M562171)supported by the China Postdoctoral Science Foundation
文摘95W?3.4Ni?1.6Fe heavy alloy was carburized by pack carburization. Microstructure and hardness of the carburized alloywere investigated by SEM, EDS XRD. Effect of carburization on the rolling contact fatigue (RCF) property of the alloy was studied.The results showed that the carburized layer was composed of the outer, porous WC layer and the modified subsurface layer witheach W grain surrounded by a WC shell. Carburization not only decreased the RCF performance of the alloy but also aggravated thewear of the counter balls. The untreated alloy was damaged by two modes of spalling and delamination under RCF condition. Thesubsurface main crack of the untreated alloy initiated where the maximum shear stress existed and preferentially propagated alongthe W?W interfaces. Spalling was the main failure mode of the carburized alloys, and the crumbling WC particles intensified theabrasion of the carburized surface.
