Sub-molten salt was applied to the decomposition of zircon sand(ZrSiO4).The kinetics of the decomposition of zircon sand and the effects of reaction temperature,reaction time,NaOH content,agitation speed,and the NaOH/...Sub-molten salt was applied to the decomposition of zircon sand(ZrSiO4).The kinetics of the decomposition of zircon sand and the effects of reaction temperature,reaction time,NaOH content,agitation speed,and the NaOH/ore mass ratio on the decomposition rate of zircon sand in NaOH sub-molten salt were investigated.The results indicate that the decomposition rate of zircon sand increases with the increase in the reaction temperature,reaction time,and NaOH content.The shrinking-core model with surface chemical reaction-controlled process is the most applicable for the decomposition of zircon sand,with the apparent activation energy of 77.98 kJ/mol.The decomposition product is sodium zirconium silicate(Na2ZrSiO5),and the decomposition rate is higher than 99%under the optimal conditions.展开更多
This paper deals with the recovery of zircon minerals from beach sand and red sediments of bad land topography and flow sheets with material balance are suggested. The experimental data reveal that the total heavy min...This paper deals with the recovery of zircon minerals from beach sand and red sediments of bad land topography and flow sheets with material balance are suggested. The experimental data reveal that the total heavy mineral content of red sediment sample is 43.9% in which zircon mineral concentrate is 2.75% by weight, where as for beach-dune sand sample the THM content is 16.7% in which zircon mineral concentrate is 0.16% by weight. It is found that U and Th and REE elements contents are much higher in red sediment zircon sample than beach sand zircon. Zircon concentrates recovered from beach-dune sand and red sediments contain 98 to 98.1% zircon with 79.6 to 80% recovery respectively. These zircon minerals from both the sources are suitable for industrial applications.展开更多
海南岛西部近岸海域海砂资源丰富、经济价值巨大,对其物质来源却缺乏系统研究。为解决这一科学问题,为该区域海砂资源的开发利用提供科学依据,对海南岛西部近岸海域和昌化江入海口1 471粒碎屑锆石开展了U-Pb同位素年代学和微区元素地球...海南岛西部近岸海域海砂资源丰富、经济价值巨大,对其物质来源却缺乏系统研究。为解决这一科学问题,为该区域海砂资源的开发利用提供科学依据,对海南岛西部近岸海域和昌化江入海口1 471粒碎屑锆石开展了U-Pb同位素年代学和微区元素地球化学研究。海南岛西部近岸海域年龄范围在3.45 Ga~82 Ma,具有99、241、252 Ma 3个主要年龄峰值,以及113、155、325、357 Ma 4个次要年龄峰值;昌化江入海口具有2.3 Ga~96 Ma的年龄范围,存在101、244、254 Ma 3个主要年龄峰值,以及122、266、281、307、342 Ma 4个次要年龄峰值。结果表明:海南岛西部近岸海域沉积物以具有~99 Ma的显著年龄峰,并缺乏晋宁期、加里东期和喜山期年龄峰为识别标志,海南岛应是其主要物源区,区内丰富的海砂资源来源于海南岛内岩浆岩和沉积岩的风化剥蚀和搬运沉积;海南岛西部近岸海域与昌化江沉积物年龄峰值的差异,指示海南岛西部近岸海域沉积物并非单纯来源于近源昌化江输入,也在北部湾逆时针环流的作用下接受琼西南部河流的物源贡献;更新昌化江入海口的碎屑锆石年龄组成,新识别出的380~310 Ma年龄群,可作为昌化江流域物源的识别标志;本次碎屑锆石年龄频谱特征与海南岛经历的多次重要地质事件相吻合,有助于了解海南岛复杂的地质演化历史。展开更多
基金Project(51704270)supported by the National Natural Science Foundation of ChinaProject(ZDRW-ZS-2018-1)supported by the Key Research Program of Chinese Academy of SciencesProject(KFJ-STS-ZDTP-040)supported by the Science and Technology Service Network Plan of Chinese Academy of Sciences
文摘Sub-molten salt was applied to the decomposition of zircon sand(ZrSiO4).The kinetics of the decomposition of zircon sand and the effects of reaction temperature,reaction time,NaOH content,agitation speed,and the NaOH/ore mass ratio on the decomposition rate of zircon sand in NaOH sub-molten salt were investigated.The results indicate that the decomposition rate of zircon sand increases with the increase in the reaction temperature,reaction time,and NaOH content.The shrinking-core model with surface chemical reaction-controlled process is the most applicable for the decomposition of zircon sand,with the apparent activation energy of 77.98 kJ/mol.The decomposition product is sodium zirconium silicate(Na2ZrSiO5),and the decomposition rate is higher than 99%under the optimal conditions.
文摘This paper deals with the recovery of zircon minerals from beach sand and red sediments of bad land topography and flow sheets with material balance are suggested. The experimental data reveal that the total heavy mineral content of red sediment sample is 43.9% in which zircon mineral concentrate is 2.75% by weight, where as for beach-dune sand sample the THM content is 16.7% in which zircon mineral concentrate is 0.16% by weight. It is found that U and Th and REE elements contents are much higher in red sediment zircon sample than beach sand zircon. Zircon concentrates recovered from beach-dune sand and red sediments contain 98 to 98.1% zircon with 79.6 to 80% recovery respectively. These zircon minerals from both the sources are suitable for industrial applications.
文摘海南岛西部近岸海域海砂资源丰富、经济价值巨大,对其物质来源却缺乏系统研究。为解决这一科学问题,为该区域海砂资源的开发利用提供科学依据,对海南岛西部近岸海域和昌化江入海口1 471粒碎屑锆石开展了U-Pb同位素年代学和微区元素地球化学研究。海南岛西部近岸海域年龄范围在3.45 Ga~82 Ma,具有99、241、252 Ma 3个主要年龄峰值,以及113、155、325、357 Ma 4个次要年龄峰值;昌化江入海口具有2.3 Ga~96 Ma的年龄范围,存在101、244、254 Ma 3个主要年龄峰值,以及122、266、281、307、342 Ma 4个次要年龄峰值。结果表明:海南岛西部近岸海域沉积物以具有~99 Ma的显著年龄峰,并缺乏晋宁期、加里东期和喜山期年龄峰为识别标志,海南岛应是其主要物源区,区内丰富的海砂资源来源于海南岛内岩浆岩和沉积岩的风化剥蚀和搬运沉积;海南岛西部近岸海域与昌化江沉积物年龄峰值的差异,指示海南岛西部近岸海域沉积物并非单纯来源于近源昌化江输入,也在北部湾逆时针环流的作用下接受琼西南部河流的物源贡献;更新昌化江入海口的碎屑锆石年龄组成,新识别出的380~310 Ma年龄群,可作为昌化江流域物源的识别标志;本次碎屑锆石年龄频谱特征与海南岛经历的多次重要地质事件相吻合,有助于了解海南岛复杂的地质演化历史。
