In this study,interconnected porous Mg-2Zn-xY alloys with different phase compositions were prepared by various Y additions(x=0.4,3,and 6 wt.%)to adjust the compressive properties and energy absorption characteristics...In this study,interconnected porous Mg-2Zn-xY alloys with different phase compositions were prepared by various Y additions(x=0.4,3,and 6 wt.%)to adjust the compressive properties and energy absorption characteristics.Several characterization methods were then applied to identify the microstructure of the porous Mg-Zn-Y and describe the details of the second phase.Compressive tests were performed at room temperature(RT),200℃,and 300℃to study the impact of the Y addition and testing temperature on the compressive properties of the porous Mg-Zn-Y.The experimental results showed that a high Y content promotes a microstructure refinement and increases the volume fraction of the second phase.When the Y content increases,different Mg-Zn-Y ternary phases appear:I-phase(Mg_(3)Zn_(6)Y),W-phase(Mg_(3)Zn_(3)Y_(2)),and LPSO phase(Mg_(12)ZnY).When the Y content ranges between 0.4%and 6%,the compressive strength increases from 6.30MPa to 9.23 MPa,and the energy absorption capacity increases from 7.33 MJ/m^(3)to 10.97 MJ/m^(3)at RT,which is mainly attributed to the phase composition and volume fraction of the second phase.However,the average energy absorption efficiency is independent of the Y content.In addition,the compressive deformation behaviors of the porous Mg-Zn-Y are altered by the testing temperature.The compressive strength and energy absorption capacity of the porous Mg-Zn-Y decrease due to the softening effect of the high temperature on the struts.The deformation behaviors at different temperatures are finally observed to reflect the failure mechanisms of the struts.展开更多
The non-isothermal leaching kinetics of primary titanium-rich material by microwave heating was investigated,and the temperature-pressure curves of leaching system and microwave absorption characteristics of mixture s...The non-isothermal leaching kinetics of primary titanium-rich material by microwave heating was investigated,and the temperature-pressure curves of leaching system and microwave absorption characteristics of mixture solutions before and after leaching were measured.The research of non-isothermal kinetics was evaluated by the leaching rate of Fe and the total apparent velocity equation of the non-isothermal kinetics of leaching for primary titanium-rich material by microwave heating was obtained.It is shown from the temperature-pressure curves that the high temperature and high pressure of closed leaching system are favorable to the enhancement of the leaching rate of Fe.Microwave absorption characteristics of mixture solutions before and after leaching show that there are abrupt changes of microwave absorption characteristics for 15%HCl solution and the mixture solution after leaching by 20%HCl.展开更多
The excellent response characteristics and detection sensitivity with much lower operational cost and the capability to discriminate between the isomer of some monoaromatic hydrocarbons （MAHCs） make differential opt...The excellent response characteristics and detection sensitivity with much lower operational cost and the capability to discriminate between the isomer of some monoaromatic hydrocarbons （MAHCs） make differential optical absorption spectroscopy （DOAS） a powerful tool to trace concentration variation of MAHCs. But due to the similarity in chemical structure, those MAHCs have the similar overlapped characteristic absorption structures, which make the selection of instrumental parameter critical to the accurate detection of MAHCs. Firstly, the spectral resolution used in DOAS system determines the nonlinear absorption of O2 and the mass dependence of characteristic absorption structure; thereby it determines the effect of elimination error of O2 absorption in the atmospheric spectra for the detection of MAHCs. Secondly, spectral resolution determines the differential absorption characteristics of twelve MAHCs representing major constituents in technical solvents used in the automobile industry and the interference of spectral overlapping. Thirdly, the spectral resolution determines the sensitivity, time resolution and linear range. So the spectral resolution range with the best ratio of signal to noise is used to determine the most suitable spectral resolution range, as well as the spectral resolution range that ensure the characteristic absorption structure of MAHCs and the minimization of O2 absorption interference. Finally, 0.15-0.16 nm （FWHM： full width at half maximum） is assumed to be closest to the optimum spectral resolution and it is confirmed by the results of practical measurement of MAHCs by DOAS.展开更多
In this paper, argon arc plasma is chosen as an example to study the absorption characteristics of arc plasma in the infrared region. Firstly, the phase and the attenuation constants are deduced for the given temperat...In this paper, argon arc plasma is chosen as an example to study the absorption characteristics of arc plasma in the infrared region. Firstly, the phase and the attenuation constants are deduced for the given temperature, pressure and probe wavelength regions. Based on those constants, the dependence of the attenuation constant on the temperature and pressure in the vicinity of a certain probe wavelength is found. Then, theoretical analysis and discussion are conducted. Maximal absorption occurs at the position where the contributions of neutral particles and electrons come to a balance in a physical point of view, which may provide some measures to take for decreasing or controlling the plasma absorption of electromagnetic waves.展开更多
This paper discusses the evolution regularity and the absorption characters of sulfide for bituminous briquette burned in a horizontal burning fornace. The evolution rate of sulphur is affected by some factors, such a...This paper discusses the evolution regularity and the absorption characters of sulfide for bituminous briquette burned in a horizontal burning fornace. The evolution rate of sulphur is affected by some factors, such as the sulphur content in the burning coal, burning time and the mean excess air coefficient in the furnace. With processing the experimental result, the calculation related expression has been obtained to predict the evolution rate of sulfide. The sulphur absorption efficiency of briquette is affected by tbe factors such as the character of the sulphur sorbent, the type of the coal and the operating parameters. By means of appropriately adjusting the calciumsulphur mole ratio, the mean excess air coefficient and the time-interval between pushing two layer briquettes, a high sulphur absorption efficiency (>74% ) can be obtained.展开更多
In this study,a batch of indium tin oxide(ITO)/Sn composites with different ratios was obtained based on the principle of thermal evaporation by an electron beam.The crystalline structure,surface shape,and optical cha...In this study,a batch of indium tin oxide(ITO)/Sn composites with different ratios was obtained based on the principle of thermal evaporation by an electron beam.The crystalline structure,surface shape,and optical characterization of the films were researched using an X-ray diffractometer,an atomic force microscope,a UV-Vis-NIR dual-beam spectrophotometer,and an open-hole Z-scan system.By varying the relative thickness ratio of the ITO/Sn bilayer film,tunable nonlinear optical properties were achieved.The nonlinear saturation absorption coefficientβmaximum of the ITO/Sn composites is−10.5×10^(−7)cm/W,approximately 21 and 1.72 times more enhanced compared to monolayer ITO and Sn,respectively.Moreover,the improvement of the sample nonlinear performance was verified using finite-difference in temporal domain simulations.展开更多
Carbonaceous matter has an important impact on glacial retreat in the Tibetan Plateau,further affecting the water resource supply.However,the related studies on carbonaceous matter are still scarce in Geladaindong(GLD...Carbonaceous matter has an important impact on glacial retreat in the Tibetan Plateau,further affecting the water resource supply.However,the related studies on carbonaceous matter are still scarce in Geladaindong(GLDD)region,the source of the Yangtze River.Therefore,the concentration,source and variations of carbonaceous matter at Ganglongjiama(GLJM)glacier in GLDD region were investigated during the melting period in 2017,which could deepen our understanding on carbonaceous matter contribution to glacier melting.The results showed that dissolved organic carbon(DOC)concentration of snowpit samples(283±200μg/L)was much lower than that of precipitation samples(624±361μg/L),indicating that large parts of DOC could be rapidly leached from the snowpit during the melting process.In contrast,refractory black carbon(rBC)concentration measured by Single Particle Soot Photometer of snowpit samples(4.27±3.15μg/L)was much higher than that of precipitation samples(0.97±0.49μg/L).Similarly,DOC with high mass absorption cross-section measured at 365 nm value was also likely to enrich in snowpit during the melting process.In addition,it was found that both r BC and DOC with high light-absorbing ability began to leach from the snowpit when melting process became stronger.Therefore,rBC and DOC with high light-absorbing ability exhibited similar behavior during the melting process.Based on relationship among DOC,rBC and K^+ in precipitation,the main source of carbonaceous matter in GLJM glacier was biomass burning during the study period.展开更多
基金supported by"The National Key Research and Development Program of China(No.2018 YFA0703300)""Science and Technology Project of Education Department of Jilin Province(No.JJKH20231086KJ)"Development Project of Jilin Province(No.2021C038-4)。
文摘In this study,interconnected porous Mg-2Zn-xY alloys with different phase compositions were prepared by various Y additions(x=0.4,3,and 6 wt.%)to adjust the compressive properties and energy absorption characteristics.Several characterization methods were then applied to identify the microstructure of the porous Mg-Zn-Y and describe the details of the second phase.Compressive tests were performed at room temperature(RT),200℃,and 300℃to study the impact of the Y addition and testing temperature on the compressive properties of the porous Mg-Zn-Y.The experimental results showed that a high Y content promotes a microstructure refinement and increases the volume fraction of the second phase.When the Y content increases,different Mg-Zn-Y ternary phases appear:I-phase(Mg_(3)Zn_(6)Y),W-phase(Mg_(3)Zn_(3)Y_(2)),and LPSO phase(Mg_(12)ZnY).When the Y content ranges between 0.4%and 6%,the compressive strength increases from 6.30MPa to 9.23 MPa,and the energy absorption capacity increases from 7.33 MJ/m^(3)to 10.97 MJ/m^(3)at RT,which is mainly attributed to the phase composition and volume fraction of the second phase.However,the average energy absorption efficiency is independent of the Y content.In addition,the compressive deformation behaviors of the porous Mg-Zn-Y are altered by the testing temperature.The compressive strength and energy absorption capacity of the porous Mg-Zn-Y decrease due to the softening effect of the high temperature on the struts.The deformation behaviors at different temperatures are finally observed to reflect the failure mechanisms of the struts.
基金Project(2007CB613606)supported by the National Basic Research Program of China
文摘The non-isothermal leaching kinetics of primary titanium-rich material by microwave heating was investigated,and the temperature-pressure curves of leaching system and microwave absorption characteristics of mixture solutions before and after leaching were measured.The research of non-isothermal kinetics was evaluated by the leaching rate of Fe and the total apparent velocity equation of the non-isothermal kinetics of leaching for primary titanium-rich material by microwave heating was obtained.It is shown from the temperature-pressure curves that the high temperature and high pressure of closed leaching system are favorable to the enhancement of the leaching rate of Fe.Microwave absorption characteristics of mixture solutions before and after leaching show that there are abrupt changes of microwave absorption characteristics for 15%HCl solution and the mixture solution after leaching by 20%HCl.
文摘The excellent response characteristics and detection sensitivity with much lower operational cost and the capability to discriminate between the isomer of some monoaromatic hydrocarbons （MAHCs） make differential optical absorption spectroscopy （DOAS） a powerful tool to trace concentration variation of MAHCs. But due to the similarity in chemical structure, those MAHCs have the similar overlapped characteristic absorption structures, which make the selection of instrumental parameter critical to the accurate detection of MAHCs. Firstly, the spectral resolution used in DOAS system determines the nonlinear absorption of O2 and the mass dependence of characteristic absorption structure; thereby it determines the effect of elimination error of O2 absorption in the atmospheric spectra for the detection of MAHCs. Secondly, spectral resolution determines the differential absorption characteristics of twelve MAHCs representing major constituents in technical solvents used in the automobile industry and the interference of spectral overlapping. Thirdly, the spectral resolution determines the sensitivity, time resolution and linear range. So the spectral resolution range with the best ratio of signal to noise is used to determine the most suitable spectral resolution range, as well as the spectral resolution range that ensure the characteristic absorption structure of MAHCs and the minimization of O2 absorption interference. Finally, 0.15-0.16 nm （FWHM： full width at half maximum） is assumed to be closest to the optimum spectral resolution and it is confirmed by the results of practical measurement of MAHCs by DOAS.
基金supported by the Young Scientists Fund of the National Natural Science Foundation of China (Grant No. 10804052)the Postgraduate Innovation Foundation of Jiangsu Provincethe Key Postgraduate Planting Plan of Nanjing University of Science and Technology,China
文摘In this paper, argon arc plasma is chosen as an example to study the absorption characteristics of arc plasma in the infrared region. Firstly, the phase and the attenuation constants are deduced for the given temperature, pressure and probe wavelength regions. Based on those constants, the dependence of the attenuation constant on the temperature and pressure in the vicinity of a certain probe wavelength is found. Then, theoretical analysis and discussion are conducted. Maximal absorption occurs at the position where the contributions of neutral particles and electrons come to a balance in a physical point of view, which may provide some measures to take for decreasing or controlling the plasma absorption of electromagnetic waves.
文摘This paper discusses the evolution regularity and the absorption characters of sulfide for bituminous briquette burned in a horizontal burning fornace. The evolution rate of sulphur is affected by some factors, such as the sulphur content in the burning coal, burning time and the mean excess air coefficient in the furnace. With processing the experimental result, the calculation related expression has been obtained to predict the evolution rate of sulfide. The sulphur absorption efficiency of briquette is affected by tbe factors such as the character of the sulphur sorbent, the type of the coal and the operating parameters. By means of appropriately adjusting the calciumsulphur mole ratio, the mean excess air coefficient and the time-interval between pushing two layer briquettes, a high sulphur absorption efficiency (>74% ) can be obtained.
基金supported by the National Natural Science Foundation of China(Nos.61775141 and 62075133).
文摘In this study,a batch of indium tin oxide(ITO)/Sn composites with different ratios was obtained based on the principle of thermal evaporation by an electron beam.The crystalline structure,surface shape,and optical characterization of the films were researched using an X-ray diffractometer,an atomic force microscope,a UV-Vis-NIR dual-beam spectrophotometer,and an open-hole Z-scan system.By varying the relative thickness ratio of the ITO/Sn bilayer film,tunable nonlinear optical properties were achieved.The nonlinear saturation absorption coefficientβmaximum of the ITO/Sn composites is−10.5×10^(−7)cm/W,approximately 21 and 1.72 times more enhanced compared to monolayer ITO and Sn,respectively.Moreover,the improvement of the sample nonlinear performance was verified using finite-difference in temporal domain simulations.
基金supported by the National Nature Science Foundation of China(Nos.41630754,41675130)the State Key Laboratory of Cryospheric Science(No.SKLCS-ZZ-2019)project funded by China Postdoctoral Science Foundation(No.2018M631215)
文摘Carbonaceous matter has an important impact on glacial retreat in the Tibetan Plateau,further affecting the water resource supply.However,the related studies on carbonaceous matter are still scarce in Geladaindong(GLDD)region,the source of the Yangtze River.Therefore,the concentration,source and variations of carbonaceous matter at Ganglongjiama(GLJM)glacier in GLDD region were investigated during the melting period in 2017,which could deepen our understanding on carbonaceous matter contribution to glacier melting.The results showed that dissolved organic carbon(DOC)concentration of snowpit samples(283±200μg/L)was much lower than that of precipitation samples(624±361μg/L),indicating that large parts of DOC could be rapidly leached from the snowpit during the melting process.In contrast,refractory black carbon(rBC)concentration measured by Single Particle Soot Photometer of snowpit samples(4.27±3.15μg/L)was much higher than that of precipitation samples(0.97±0.49μg/L).Similarly,DOC with high mass absorption cross-section measured at 365 nm value was also likely to enrich in snowpit during the melting process.In addition,it was found that both r BC and DOC with high light-absorbing ability began to leach from the snowpit when melting process became stronger.Therefore,rBC and DOC with high light-absorbing ability exhibited similar behavior during the melting process.Based on relationship among DOC,rBC and K^+ in precipitation,the main source of carbonaceous matter in GLJM glacier was biomass burning during the study period.
