期刊文献+
共找到1,798篇文章
< 1 2 90 >
每页显示 20 50 100
Adjustment mechanism of blasting dynamic-static action in the water decoupling charge
1
作者 Hao Zhang Xueyang Xing +3 位作者 Yiteng Du Tingchun Li Jianxin Yu Qingwen Zhu 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第6期821-836,共16页
Water decoupling charge blasting excels in rock breaking,relying on its uniform pressure transmission and low energy dissipation.The water decoupling coefficients can adjust the contributions of the stress wave and qu... Water decoupling charge blasting excels in rock breaking,relying on its uniform pressure transmission and low energy dissipation.The water decoupling coefficients can adjust the contributions of the stress wave and quasi-static pressure.However,the quantitative relationship between the two contributions is unclear,and it is difficult to provide reasonable theoretical support for the design of water decoupling blasting.In this study,a theoretical model of blasting fracturing partitioning is established.The mechanical mechanism and determination method of the optimal decoupling coefficient are obtained.The reliability is verified through model experiments and a field test.The results show that with the increasing of decoupling coefficient,the rock breaking ability of blasting dynamic action decreases,while quasi-static action increases and then decreases.The ability of quasi-static action to wedge into cracks changes due to the spatial adjustment of the blast hole and crushed zone.The quasi-static action plays a leading role in the fracturing range,determining an optimal decoupling coefficient.The optimal water decoupling coefficient is not a fixed value,which can be obtained by the proposed theoretical model.Compared with the theoretical results,the maximum error in the model experiment results is 8.03%,and the error in the field test result is 3.04%. 展开更多
关键词 water decoupling blasting Blasting dynamic-static action Optimal decoupling coefficient adjustment mechanism
下载PDF
A SIMULTANEOUS APPROACH TO WATER - RESOURCE PROTECTION AND ECONOMIC STRUCTURAL ADJUSTMENT—A Case Study of Guanzhong Region in the Huanghe River Basin, China 被引量:1
2
作者 WANGXi-qin LIUChang-ming 《Chinese Geographical Science》 SCIE CSCD 2002年第1期35-43,共9页
A regional multiple objective water resource and economic optimization model was developed using a quantitative method of systematic analysis. Input to the model includes indexes of economic structure and development,... A regional multiple objective water resource and economic optimization model was developed using a quantitative method of systematic analysis. Input to the model includes indexes of economic structure and development, water resource utilization, wastewater and pollutant discharge, and investment in wastewater treatment. The model, which consists of production structure and industrial structure optimization modules, was applied to the Guanzhong region in the middle reaches of the Huanghe (Yellow) River basin in China. By evaluating several alternative production and industrialization schemes, the modal indicate that water pollution will get worsen though wastewater treatment improves if the economy continues to develop at the planned speed without structural adjustment. However, the results also show that not only economic goals but also water resource protection and pollution control targets can be achieved under an alternative, recommended production and industrial structure. This example illustrates that economic development and environmental protection can be improved coordinately by the regional multiple objective water resource and economic optimization model. It provides an operable approach to the simultaneous sustained development of water resources and economic growth. 展开更多
关键词 water resource PROTECTION economic structure adjustment
下载PDF
Study of the Optimization and Adjustment ofthe IndustrialStructure Subjected to Water Resource in the Drainage Area of the Yellow River 被引量:1
3
作者 Wang Haiying, Fan Zhenjun, Hou Xiaoli, Dong SuochengInstitute of Geographical Sciences and Natural Resources Research, CAS, Beijing 100101, China 《Chinese Journal of Population,Resources and Environment》 2004年第1期48-53,共6页
Since the 1990s, the Yellow River stream has been temporarily interrupted for several years, which affects the development of society, the economy and human life, limits the economic potential of the drainage areas, a... Since the 1990s, the Yellow River stream has been temporarily interrupted for several years, which affects the development of society, the economy and human life, limits the economic potential of the drainage areas, and especially causes great harm to regions on the lower reaches. Based on the analysis of the relationship between the development of society and economy and water scarcity, the author thinks it is necessary to optimize and adjust the industrial structure that has extravagantly consumed enormous amounts of water, and to develop ecological agriculture, industry and tourism which are balanced with the ecological environment. Finally, the author puts forward several pieces of advice and countermeasures about how to build the economic systems by which water can be used economically. 展开更多
关键词 drainage areas of the Yellow River water scarcity industrial structure optimize and adjust
下载PDF
Switching mechanism and optimisation research on a pressure-attitude adaptive adjusting coal seam water jet slotter 被引量:1
4
作者 Yiyu Lu Yangkai Zhang +1 位作者 Jiren Tang Qi Yao 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2022年第6期1167-1179,共13页
To investigate the attitude-switching mechanisms of existing jet slotters,which integrate drilling,punching and slotting operations,and to improve its fracture ability,we used the power bond diagram theory to analyse ... To investigate the attitude-switching mechanisms of existing jet slotters,which integrate drilling,punching and slotting operations,and to improve its fracture ability,we used the power bond diagram theory to analyse the dynamic flow pressure,and force of slotters.A mathematical model was developed for the dynamic characteristics of slotter systems.Furthermore,to study the effect of the main characteristic parameters on the ability of the nozzle to erode sandstone,multi-orthogonal experiments were carried out.And the optimised slots were applied in later practical operations.The research results show that the inlet fluid passed through the time-varying orifice to generate pressure differential thrust,which overcame the spring force,pushed the valve core to open the side nozzle,and closed the rear cavity channel thereby realising the switch of the slotter attitude.An optimal plan was established to balance the diameter,depth,and volume of punching,and a rock-breaking plan was developed for the slotter.Subsequently,the optimised water jet slotter was practically used in coal seam gas drainage.Compared with conventional dense drilling,water jet slotting technology significantly improves the ability,efficiency,and effect of increasing the permeability of the coal seam. 展开更多
关键词 Gas drainage water jet slotting Pressure-attitude adaptive adjustment Power bond diagram Multi-index orthogonal test Gas drainage practice
下载PDF
Areal differentiation of virtual water for agricultural products and its effect on regional agricultural structure adjustment in China: 1995-2007 被引量:3
5
作者 QIN Li-jie ZONG Sheng-wei CHANG Yong-zhi 《Ecological Economy》 2010年第1期80-87,共8页
With a vast territory, the space-time distribution of water resources is uneven in China. There is a great dif ference in natural conditions and farmland management of agricuttural production in different regions. The... With a vast territory, the space-time distribution of water resources is uneven in China. There is a great dif ference in natural conditions and farmland management of agricuttural production in different regions. The areal differentiation of agricultural products virtual water is obvious. Comparison with the agricultural products virtual water from 1995 to 2007 in China shows an increase in the first ten vears and a little decrease in recent years. There has been a tendency of increase all the time in Northeast and Northwest. but a decrease after an increase firstly in other regions. The virtual water offood crops is the maximum which accounts for more than 70% in China. and that of vegetables is in a fast growth. The proportion of agricultural products virtual water to the total water resources in each region has a large difference, showing the imbalance of agricultural water in different regions, which accounts for 50%-90% in Northeast, and 125%-185% in North China. Under the guidance of virtual water strategy, based on the differences of resource endowment, each region should adjust agricultural structure, decide production by water, and select water suitable crops. In water-rich region, agricultural produets of high water consumption should be planted appropriately, which will make full use of the abundant local water resources. In water-shortage region the crop production of high water consumption and low efficiency should be depressed, and that of low water consumption and high efficiency should be supported and increased. It will achieve reasonable disposition of water resources, promote ecological restoration and environmental protection, as welt as ensure food security. 展开更多
关键词 Virtual water Areal differentiation adjustment of agricultural structure
下载PDF
Osmotic adjustment of winter wheat leaves under different soil water stress
6
作者 郭晓维 李鸿祥 赵春江 《华北农学报》 CSCD 北大核心 1994年第S2期81-85,共5页
Two varieties of winter wheat,Bei Nong 2(B. N. 2)and Jing 411(J. 411),were selected for osmotic adjustment study. At wheat growing stages,from recovery period to mature period,leaf relative water content(LRWC) ,water ... Two varieties of winter wheat,Bei Nong 2(B. N. 2)and Jing 411(J. 411),were selected for osmotic adjustment study. At wheat growing stages,from recovery period to mature period,leaf relative water content(LRWC) ,water potential(LWP)and saturated osmotic potential (LSOP) were positively correlated to soil relative water content (SRWC) and decreased as SRWC descended at each growth stage,and the decreasing range exhibited B. N. 2【J. 411. The turgor pressure(TP)of both the varieties decreased less than LRWC and LWP. It was shown that both varieties had a osmotic adjustment ability(OAA) ,and the decreasing range presented B. N. 2【J. 411. Both the varieties had a TP tubercle in TP vs SRWC graph at heading and filling stages,and their OAA was the strongest at these two stages. 展开更多
关键词 OSMOTIC adjustment .winter WHEAT SOIL water STRESS
下载PDF
Leak-off behavior and water shut-off performance of a polymer/chromium(Cr^(3+)) gel in fractured media
7
作者 LI Jun-jian XIONG Chun-ming +3 位作者 BAI Ying-rui JIANG Ru-yi WEI Fa-lin ZHANG Miao 《Journal of Central South University》 SCIE EI CAS CSCD 2017年第6期1418-1429,共12页
During gel treatments for fractures, the leak-off behavior of gelant has a great effect on the water shut-off performance of gel. Experiments were carried out using a polymer/chromium(Cr^(3+)) gel system to explore th... During gel treatments for fractures, the leak-off behavior of gelant has a great effect on the water shut-off performance of gel. Experiments were carried out using a polymer/chromium(Cr^(3+)) gel system to explore the leak-off behavior and the water shut-off performance of gel in fractured media. Results of the gelant leak-off study show that the gelant leak-off from fracture into matrix contributes to the formation of the gelant leak-off layer during the gelant injection. Moreover, because of the gradual formation of the gelant leak-off layer along fracture, the initial leak-off ratio of gelant is relatively high, but it declines and finally levels off with the increase of the injection volume. The polymer concentration of gelant has a great effect on the chromium output in fluids produced from fractures. With the increase of the polymer concentration, the chromium concentration first decreases and then increases, and the leak-off depth of gelant into matrix is gradually reduced. Results of the water shut-off study present that the decrease of the chromium concentration inside the fracture greatly reduces the water shut-off performance after the gel formation. Therefore, because of the relatively high degree of chromium leak-off, enough injection volume of gelant is essential to ensure the sufficient chromium concentration inside the fracture and to further achieve a favorable water shut-off performance. On the premise of gel strength assurance inside the fracture, the water shut-off performance of gel gradually declines with the extension of the distance from the fracture inlet, and different leak-off degrees of gelant along the fracture are responsible for this phenomenon. Therefore, a proper degree of gelant leak-off contributes to enhancing the water shut-off performance of gel for fractures. 展开更多
关键词 POLYMER gelant GEL leak-off water shut-off FRACTURE
下载PDF
Ion Accumulation, Water Relations and Osmotic Adjustment in Atriplex argentina, A. crenatifolia, A.lampa and A. nummularia under Saline Conditions
8
作者 Nadia Barcena Monica Ruiz Carlos Parera 《Journal of Agricultural Science and Technology(A)》 2016年第5期324-334,共11页
Salinity is a major stress that adversely affects growth and productivity in plants. There are species that tolerate this stresswithin the genus Atriplex. Four species, A. lampa, A. crenatifolia, A. nummularia and A. ... Salinity is a major stress that adversely affects growth and productivity in plants. There are species that tolerate this stresswithin the genus Atriplex. Four species, A. lampa, A. crenatifolia, A. nummularia and A. argentina were compared for their ionaccumulation and water relations under saline conditions. A greenhouse study was conducted by irrigating the four species with NaCIsolutions at concentrations 0%, 1%, 2% and 4% starting when plants were six months old. Plants were harvested 45 d after startingthe salinity treatments and analyzed for their ion contents. In the four Atriplex species, Na^+ and Cl^- contents in plants increased, whileCa^2+ and Mg^2+ decreased with the increase of salinity in the irrigation solution. The results suggested that A. argentina and A.nummularia were able to maintain a higher leaf relative water content (RWC) at low leaf water potential, which was associated witha greater capacity of osmotic adjustment. A. lampa showed lower ion accumulation and minor osmotic adjustment than the otherspecies. It can be concluded that the accumulation of ions favors the lower osmotic potential and contributes to osmotic adjustment inthese halophytes. 展开更多
关键词 ATRIPLEX sp. SALINITY stress OSMOTIC adjustment ion accumulation water relations.
下载PDF
Improved Water Network Macroscopic Model Utilising Auto-Control Adjusting Valve by PLS
9
作者 李霞 赵新华 王晓东 《Transactions of Tianjin University》 EI CAS 2005年第6期452-457,共6页
In order to overcome the low precision and weak applicability problems of the current municipal water network state simulation model, the water network structure is studied. Since the telemetry system has been applied... In order to overcome the low precision and weak applicability problems of the current municipal water network state simulation model, the water network structure is studied. Since the telemetry system has been applied increasingly in the water network, and in order to reflect the network operational condition more accurately, a new water network macroscopic model is developed by taking the auto-control adjusting valve opening state into consideration. Then for highly correlated or collinear independent variables in the model, the partial least squares (PLS) regression method provides a model solution which can distinguish between the system information and the noisy data. Finally, a hypothetical water network is introduced for validating the model. The simulation results show that the relative error is less than 5.2%, indicating that the model is efficient and feasible, and has better generalization performance. 展开更多
关键词 water supply network state simulation macroscopic model auto-control adjusting valve partial least squares PLS) regression
下载PDF
Theory of an Optimal Dynamical Water Resource Management Policy
10
作者 Muhammad Ashfaq Ahmed Nasreen Nawaz 《Journal of Water Resource and Protection》 CAS 2023年第3期85-113,共29页
Water markets even though not perfect and require a lot of effort to establish are considered as a robust tool to address water management issues around the world. However, the existing literature does not provide an ... Water markets even though not perfect and require a lot of effort to establish are considered as a robust tool to address water management issues around the world. However, the existing literature does not provide an optimal water resource management policy. To create a perfect water market, the government needs to identify the potential number of suppliers/producers and consumers of water against various extraction/supply/production rates of water, i.e., to identify a supply and a demand curve for number of suppliers/producers of water against each production rate in economy. This article presents a theory which is practically applicable for an optimal dynamical water resource management policy (JEL H20, H23, H27). 展开更多
关键词 water Market Production Rate Dynamic Efficiency adjustment Path EQUILIBRIUM
下载PDF
南水北调西线工程水源区可调水量“十问” 被引量:3
11
作者 胡鹏 王浩 +13 位作者 赵勇 宁远 蒋云钟 刘欢 曾庆慧 杨泽凡 周毓彦 董宁澎 闫龙 阿膺兰 张丰博 唐家璇 王玉莲 王建华 《中国工程科学》 CSCD 北大核心 2024年第2期210-223,共14页
南水北调西线工程是我国“四横三纵”国家水网主骨架尚待建设的最后一环,而水源区可调水量是西线工程规划论证面临的焦点和难点问题。本文从水资源本底条件与演变趋势,生态环境与经济社会发展需水,调蓄水库与输水工程规模,调水对水源区... 南水北调西线工程是我国“四横三纵”国家水网主骨架尚待建设的最后一环,而水源区可调水量是西线工程规划论证面临的焦点和难点问题。本文从水资源本底条件与演变趋势,生态环境与经济社会发展需水,调蓄水库与输水工程规模,调水对水源区及其下游水资源开发利用、水生态环境、水力发电、航运等方面影响的角度,提出了与水源区可调水量相关的10个问题;以长江上游分布式水文模型为基础,建立了南水北调西线工程水源区可调水量模拟分析模型,力图系统、定量地回答所提问题。本文的主要研究结论有:在仅考虑满足水源区河道内外生态环境和经济社会需水的前提下,“上线+下线”组合方案多年平均可调水量为1.59×10^(10)m^(3),“完全下线”方案在建设岗托水库进行联调时,多年平均可调水量将达到1.74×10^(10)m^(3);在综合考虑调水对水源区水平衡、水力发电和航运影响及其可接受程度后,南水北调西线水源区可调水量为1.22×10^(10)~1.26×10^(10)m^(3)。长远来看,应谋划西南片区水网与国家水网主骨架、“大动脉”的连接与融合,在减小南水北调西线工程调水影响的同时,提高南水北调西线工程的整体供水能力以及对气候变化等外部条件的适应性。 展开更多
关键词 南水北调西线工程 水源区 可调水量 生态需水 跨流域调水
下载PDF
坚持“四水四定”推动经济社会高质量发展——以宁夏回族自治区“四水四定”创新实践为例 被引量:1
12
作者 夏朋 杨研 《水利发展研究》 2024年第3期81-84,共4页
坚持“四水四定”,强化水资源刚性约束,既是缓解我国水资源供需矛盾、保障水安全的必然选择,也是推动高质量发展、建设美丽中国的客观要求。文章以宁夏回族自治区为例,深入分析了宁夏回族自治区“四水四定”改革实践,总结了相关经验启示... 坚持“四水四定”,强化水资源刚性约束,既是缓解我国水资源供需矛盾、保障水安全的必然选择,也是推动高质量发展、建设美丽中国的客观要求。文章以宁夏回族自治区为例,深入分析了宁夏回族自治区“四水四定”改革实践,总结了相关经验启示,为探索以水资源节约集约利用推动经济社会高质量发展提供了参考。 展开更多
关键词 四水四定 水资源刚性约束 高质量发展
下载PDF
黄河下游花园口以上河段滞沙能力分析 被引量:1
13
作者 申冠卿 王平 张武欣 《泥沙研究》 CAS CSCD 北大核心 2024年第2期48-55,47,共9页
黄河下游河床调整主要取决于来水来沙和河床边界条件,河床调整沿程不均衡特征明显,花园口以上河段床演变对水沙条件的变化响应尤为突出,泥沙冲淤调整幅度最大。基于河道冲淤及水沙演进特性、滞沙可行性、河槽几何特性等分析,提出了花园... 黄河下游河床调整主要取决于来水来沙和河床边界条件,河床调整沿程不均衡特征明显,花园口以上河段床演变对水沙条件的变化响应尤为突出,泥沙冲淤调整幅度最大。基于河道冲淤及水沙演进特性、滞沙可行性、河槽几何特性等分析,提出了花园口以上河段可作为泥沙天然反调节“库”概念,结合黄河下游实测洪水资料,采用水力计算方法,计算了花园口以上河段的河槽排洪能力及不同河槽规模条件下河槽允许滞沙量,提出了反调“库”滞沙能力,可为小浪底水库排沙指标的确定提供依据,对维持小浪底水库有效库容、弥补后续清水河床沙源不足、改善黄河下游河槽冲淤不均衡现象具有重要意义。 展开更多
关键词 不均衡调整 河槽动态库容 滞沙能力 泥沙反调节库 水沙调控 黄河下游
原文传递
水利工程供水价格常态化调整机制探索
14
作者 杨柠 李淼 +4 位作者 郭悦 姚玉琴 高玉屏 刘品 王小娜 《水利发展研究》 2024年第1期66-69,共4页
为纠正水利工程供水成本长期大幅偏离价格,激励水利工程单位主动强化成本管理,需要建立水利工程供水价格常态化调整机制。水价调整既要考虑外围价格环境的传导作用引起的成本刚性增长,也要考虑供水服务质量和管理单位成本控制因素,构建... 为纠正水利工程供水成本长期大幅偏离价格,激励水利工程单位主动强化成本管理,需要建立水利工程供水价格常态化调整机制。水价调整既要考虑外围价格环境的传导作用引起的成本刚性增长,也要考虑供水服务质量和管理单位成本控制因素,构建水利工程供水价格与生产管理要素价格的联动机制。 展开更多
关键词 供水价格 调整要素 调整模型 调整机制
下载PDF
海洋贝类对盐度胁迫适应机制的研究进展
15
作者 牛东红 王宏蕾 李家乐 《水产学报》 CAS CSCD 北大核心 2024年第4期33-45,共13页
盐度是影响海洋贝类存活、生长、发育、繁殖等生命活动的关键因素,其生命活动时刻受到海洋局部环境中盐度变化的影响。对海洋贝类适应盐度胁迫机制的研究是学术界长期关注的问题。大量研究表明,盐度胁迫会对海洋贝类的生长、渗透调节、... 盐度是影响海洋贝类存活、生长、发育、繁殖等生命活动的关键因素,其生命活动时刻受到海洋局部环境中盐度变化的影响。对海洋贝类适应盐度胁迫机制的研究是学术界长期关注的问题。大量研究表明,盐度胁迫会对海洋贝类的生长、渗透调节、能量代谢和免疫反应等生物学过程产生影响。近年来,随着基因组、转录组等组学技术的发展和广泛应用,许多研究从分子水平来探讨海洋贝类适应盐度胁迫的机制。本文综述了海洋贝类在盐度胁迫过程中的调控机制,包括渗透调节、能量代谢、免疫反应,以及转录组和基因组在海洋贝类盐度胁迫机制研究中的应用,提出了广盐性海洋贝类在盐碱水领域中的开发潜力,为海洋贝类抗逆品种选育以及绿色养殖提供重要参考。 展开更多
关键词 海洋贝类 盐度胁迫 盐碱水 渗透调节 能量代谢 免疫反应
原文传递
基于模型参考自适应的水肥一体化控制系统设计
16
作者 张艳丽 石统宇 +3 位作者 孟庆祥 张征征 邢晨泰 鲁振宇 《节水灌溉》 北大核心 2024年第10期34-40,共7页
针对水肥混合过程中水肥EC值精准控制的问题,设计一个基于模型参考自适应的水肥一体化决策和控制系统。建立母液动态调控模型,并通过该模型设计模型参考自适应控制器。仿真试验结果显示,模型参考自适应控制相较于模糊PID控制,在跟踪试... 针对水肥混合过程中水肥EC值精准控制的问题,设计一个基于模型参考自适应的水肥一体化决策和控制系统。建立母液动态调控模型,并通过该模型设计模型参考自适应控制器。仿真试验结果显示,模型参考自适应控制相较于模糊PID控制,在跟踪试验中超调量降低1.2%,调整时间减少12.6 s,阶跃试验中超调量降低14.4%,调整时间减少超过2 s,抗干扰能力优于模糊PID控制。通过3种方式进行田间试验,对比模糊PID控制和人工灌溉方式,采用模型参考自适应控制能够使番茄株高分别提高15.7%和35.6%,茎粗分别增长11.1%和18.6%,产量分别提升23.3%和48.1%,结果表明,模型参考自适应控制优于模糊PID控制和人工灌溉方式,从而验证模型参考自适应控制的有效性,为精准施肥灌溉提供技术支持。 展开更多
关键词 水肥一体化 模型参考自适应 控制系统 水肥混合动态模型 超调量 调整时间
下载PDF
胜利山柳沟北部油区长8致密砂岩开发对策研究
17
作者 舒维 申太志 高磊 《化工设计通讯》 CAS 2024年第4期38-40,共3页
胜利山柳沟北部油区存在油层能量利用不足、井场状态不理想、注采井网不完善等问题,在很大程度上影响了油田的开发效果。基于此,针对低渗透油藏的特征,通过考虑地层压力的合理维持、采用菱形反九点井网形式、综合经济评价确定井网密度,... 胜利山柳沟北部油区存在油层能量利用不足、井场状态不理想、注采井网不完善等问题,在很大程度上影响了油田的开发效果。基于此,针对低渗透油藏的特征,通过考虑地层压力的合理维持、采用菱形反九点井网形式、综合经济评价确定井网密度,以及物质平衡方法计算合理注采比等措施,实现了更加经济高效的油田开发。最终提出的开发调整方案有助于提高地层压力、优化井网结构,以及保障油田的可持续开发。这些调整为新建产能提供了可行的方案。 展开更多
关键词 长8 胜利山柳沟 开发 注水 调整
下载PDF
大庆油田调整井固井技术研究
18
作者 杨秀天 《西部探矿工程》 CAS 2024年第7期28-31,35,共5页
大庆油田经过多年的调整开发,受地层非均质性、井网加密、动态注采开发等影响,已改变了原始井下环境。针对大庆油田异常高压层油水侵、高渗低压层界面胶结质量差两方面难题,以“地质先行,一井一策”为指导思想,开展了钻井地质、水泥浆... 大庆油田经过多年的调整开发,受地层非均质性、井网加密、动态注采开发等影响,已改变了原始井下环境。针对大庆油田异常高压层油水侵、高渗低压层界面胶结质量差两方面难题,以“地质先行,一井一策”为指导思想,开展了钻井地质、水泥浆体系、固井工具等技术攻关,形成注水开采油田调整井固井配套技术。现场应用取得了良好效果,为大庆油田原油产能建设提供井筒保障。 展开更多
关键词 注水开采 调整井 地质预测 固井技术
下载PDF
Accelerating Oxygen Electrocatalysis Kinetics on Metal-Organic Frameworks via Bond Length Optimization 被引量:2
19
作者 Fan He Yingnan Liu +10 位作者 Xiaoxuan Yang Yaqi Chen Cheng‑Chieh Yang Chung‑Li Dong Qinggang He Bin Yang Zhongjian Li Yongbo Kuang Lecheng Lei Liming Dai Yang Hou 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第9期279-290,共12页
Metal-organic frameworks(MOFs)have been developed as an ideal platform for exploration of the relationship between intrinsic structure and catalytic activity,but the limited catalytic activity and stability has hamper... Metal-organic frameworks(MOFs)have been developed as an ideal platform for exploration of the relationship between intrinsic structure and catalytic activity,but the limited catalytic activity and stability has hampered their practical use in water splitting.Herein,we develop a bond length adjustment strategy for optimizing naphthalene-based MOFs that synthesized by acid etching Co-naphthalenedicarboxylic acid-based MOFs(donated as AE-CoNDA)to serve as efficient catalyst for water splitting.AE-CoNDA exhibits a low overpotential of 260 mV to reach 10 mA cm^(−2)and a small Tafel slope of 62 mV dec^(−1)with excellent stability over 100 h.After integrated AE-CoNDA onto BiVO_(4),photocurrent density of 4.3 mA cm^(−2)is achieved at 1.23 V.Experimental investigations demonstrate that the stretched Co-O bond length was found to optimize the orbitals hybridization of Co 3d and O 2p,which accounts for the fast kinetics and high activity.Theoretical calculations reveal that the stretched Co-O bond length strengthens the adsorption of oxygen-contained intermediates at the Co active sites for highly efficient water splitting. 展开更多
关键词 Metal-organic frameworks Bond length adjustment Spin state transition Orbitals hybridization water splitting
下载PDF
南水北调西线工程生态环境影响及应对的关键科学问题
20
作者 景来红 严登明 +2 位作者 崔萌 耿雷华 敖燕辉 《水科学进展》 EI CAS CSCD 北大核心 2024年第4期521-529,共9页
南水北调西线工程涉及生态环境脆弱区,减缓生态环境影响是工程可行性论证的核心问题之一。本文提出了当前西线工程调水对生态环境影响研究的实践需求,识别了新形势下西线工程在调水阈值和调水扰动的适应性调控中的关键科学问题,构建了... 南水北调西线工程涉及生态环境脆弱区,减缓生态环境影响是工程可行性论证的核心问题之一。本文提出了当前西线工程调水对生态环境影响研究的实践需求,识别了新形势下西线工程在调水阈值和调水扰动的适应性调控中的关键科学问题,构建了西线工程生态环境影响及应对的总体研究框架,并提出重点研究方向:水源区水资源-水生态-经济社会协同演变机制、水源区生态环境需水评估方法与动态调配技术、变化环境下水源区水资源禀赋与可调水量阈值、调水生态补偿机制及生物入侵风险分析,以及系统视角下调水影响综合评估及方案优化等。南水北调西线工程须妥善协调生态保护与调水工程间的潜在冲突,坚持生态优先,确保综合效益在水源区与受水区公平共享。 展开更多
关键词 生态需水 可调水量 生态环境 南水北调西线工程
下载PDF
上一页 1 2 90 下一页 到第
使用帮助 返回顶部