Grooving corrosion is a major form of corrosion and is prone to occur when high-frequency electric resistance welded （HFW） pipes are being used. Therefore,grooving corrosion is one of the performance indexes of HFW ...Grooving corrosion is a major form of corrosion and is prone to occur when high-frequency electric resistance welded （HFW） pipes are being used. Therefore,grooving corrosion is one of the performance indexes of HFW products. Grooving corrosion usually occurs along the welding fusion line, resulting in one or more corrosion grooves. The main factors affecting grooving corrosion include the contents of alloying elements and impurities （especially sulphur） in the steel,the microstructure of the welds and the steel substrate, welding parameters and the service environment as well. In this study, the existing methods for assessing grooving corrosion were systematically reviewed, improvements and new methods were proposed and developed to overcome the shortcomings of the existing methods, such as inaccuracy and excessive research time. By comparison with the existing methods, the operational procedures and the characteristics of the new methods are introduced, and issues regarding the behavior of grooving corrosion and their assessment methods, which both need further research,are discussed in this study.展开更多
The corrosion mechanism of the S135 drill pipes was investigated through observation of the corrosion morphology and analysis of the corrosion products by scanning electronic microscope （ SEM）, energy dispersive spe...The corrosion mechanism of the S135 drill pipes was investigated through observation of the corrosion morphology and analysis of the corrosion products by scanning electronic microscope （ SEM）, energy dispersive spectrum （EDS） and X-ray diffraction （XRD）. The results show that the localized corrosion on the outer surface of the drill pipes was caused by oxygen corrosion due to the action of retained slurry. Cl - contained in slurry accelerated the corrosion and promoted the development of corrosion pits. Suggestions for mitigating or preventing such corrosion of the drill pipes are proposed based on the research results.展开更多
Compared with the traditional wet-type de-dusting technology ,the dry-type de-dusting technology is considered to be environmentally friendly and energy-saving. However, the pipes carrying the de-dusted blast fiLrnace...Compared with the traditional wet-type de-dusting technology ,the dry-type de-dusting technology is considered to be environmentally friendly and energy-saving. However, the pipes carrying the de-dusted blast fiLrnace gas （BFG） tends to be corrosive more quickly and seriously. In order to investigate the reasons for the quick corrosion, the gas pipes and auxiliary bellows installed in Baosteel＇ s newly built BFG dry-type de-dusting system are studied. The corrosive properties of the condensed water, such as the pH value, are measured and analyzed. Meanwhile, various factors that may influence the corrosion rate of the pipes are studied by experiment. On the basis of the investigation and research, the causes of corrosion and leakage on the pipes are discovered. It is the process of dry de-dusting that is responsible ,to a large extent, for the quick corrosion of the pipes. The equipment of spray tower is introduced and its effects are then discussed. This tower is designed to eliminate most of chloridion and neutralized the acid by spraying the alkaline water to the dedusted gas flow. The practical operation shows that the tower helps to lessen the corrosiveness of the dry de-dusted gas effectively. The last part of this study analyzes the possible impacts of the dry-type de-dusting process of the newly built blast furnace （BF） on the main BFG piping which has been in the state of being corroded for years by estimating its potential corrosion rate, and some suggestions on maintenance are given as well.展开更多
In high sour gas reservoir drilling process, it happens occasionally that high-strength drill pipe suffers brittle fracture failure due to stress corrosion cracking, and poses serious hazard to drilling safety. To sol...In high sour gas reservoir drilling process, it happens occasionally that high-strength drill pipe suffers brittle fracture failure due to stress corrosion cracking, and poses serious hazard to drilling safety. To solve this problem, this paper studied the stress corrosion cracking mechanism and infl uencing factors of highstrength drill pipe in sour environment with hydrogen permeation experiments and tensile tests. We simulated practical conditions in laboratory and evaluated the stress corrosion cracking performance of the high-strength drill pipe under conditions of high stress level. For the problems occurring in use of high-strength drill pipe on site, the paper proposed a technical measure for slower stress corrosion cracking.展开更多
The epoxy powder exterior anti-corrosion coating production line for bent pipes with a single (double) course production is a technologically advanced bent pipe anti corrosion method with cost efficiency, environment ...The epoxy powder exterior anti-corrosion coating production line for bent pipes with a single (double) course production is a technologically advanced bent pipe anti corrosion method with cost efficiency, environment friendliness and stable coating quality. The quality of the coating on the bent pipe fully meets the requirements of the current national and industrial standards. The application of the technology has filled the gap in the bent pipe anti corrosion coating area of China, and leads the world technologically. With this technology the coating quality of the bent pipe has greatly improved, resulting in significant social and economic benefits. With the use of the technology in various large scale pipeline projects such as the "West to East Gas Pipeline Project", it will exhibite a greater potential in the future pipeline projects with a broad application prospect.展开更多
The corrosion under insulation dominates metal loss in the case of API （American Petroleum Institute） 5L Grade B geothermal pipeline, whereas, the other possible corrosion causes, such as stress corrosion and therma...The corrosion under insulation dominates metal loss in the case of API （American Petroleum Institute） 5L Grade B geothermal pipeline, whereas, the other possible corrosion causes, such as stress corrosion and thermal cracking, did not serve a role as critical factors regarding to pipeline degradation during 26-years working operation. Actually, the header pipe diameter 32 inches and 40 inches require priority for inspection due to higher corrosion rate compared to smaller pipe diameters. By simulation method on similar heavy duty service condition in which the working pressure of 15 bars and temperature of 183 ℃, it was proved that corrosion rate will severely occur at corrosion rate more than 10 mpy in the pipe diameters of 20 inches, 32 inches and 40 inches. Further,condensation factor may contribute more significant in the case of corrosion under insulation. Practically, the metal loss at a half initial thickness requires priority for inspection, intensive maintenance or possible partial replacement.展开更多
Flow accelerated corrosion（FAC） is the main failure cause of the secondary circuit carbon steel piping in nuclear power plants.The piping failures caused by FAC have resulted in numerous unplanned outages and tragic...Flow accelerated corrosion（FAC） is the main failure cause of the secondary circuit carbon steel piping in nuclear power plants.The piping failures caused by FAC have resulted in numerous unplanned outages and tragic fatalities.The existing researches focus on the main factors contributing to FAC,which include metallurgical factors,environmental factors and hydrodynamic factors. Some effective FAC management methods and programs with long term monitoring and inspection data analysis are recommended.But a comprehensive FAC management system should be developed in order to mitigate and manage FAC systematically.In this paper,the FAC influencing factors are analyzed in combination with the operating conditions of the secondary circuit piping in the Third Qinshan Nuclear Power Plant（TQNPP）,China（Third Qinshan Nuclear Power Company Limited,China）.A comprehensive FAC mitigation and management system is developed for TQNPP secondary circuit piping.The system is composed of five processes,viz.materials substitution,water chemical optimization,long-term monitor strategy for the susceptible piping,integrity evaluation of the local thinning defects,and repair or replacement.With the implementation of the five processes,the material of FAC sensitive pipe fittings are modified from carbon steel to stainless steel,N_2H_4 and NH_3 are finally selected as the water chemical regulator of secondary circuit,the secondary circuit pips are classified according to FAC susceptibility in order to conduct long term monitoring strategy,and an integrity evaluation flow for local thinning caused by FAC in carbon steel piping is developed.If the component with local thinning defects is not fit-for-service,corresponding repair or replacement should be conducted.The comprehensive FAC mitigation and management system with five interrelated processes would be a cost-effective method of increasing personnel safety,plant safety and availability.展开更多
Three kinds of single layer coatings of Zn,Zn15Al,316L stainless steel and two kinds of double layer coatings with inner layer of Zn or Zn15Al and outer layer of 316L stainless steel by arc spraying were developed to ...Three kinds of single layer coatings of Zn,Zn15Al,316L stainless steel and two kinds of double layer coatings with inner layer of Zn or Zn15Al and outer layer of 316L stainless steel by arc spraying were developed to protect the metal ends of prestressed high-strength concrete(PHC)pipe piles against soil corrosion.The corrosion behaviors of the coated Q235 steel samples in the simulated Dagang soil solution were investigated by potentiodynamic polarization,electrochemical impedance spectroscopy(EIS) and natural immersion tests.The results show that the corrosion of the matrix Q235 steel is effectively inhibited by Zn,Zn15Al, Zn+316L and Zn15Al+316L coatings.The corrosion rate value of Zn15Al coated samples is negative.The corrosion products on Zn and Zn15Al coated samples are compact and firm.The corrosion resistance indexes of both Zn and Zn15Al coated samples are improved significantly with corrosion time,and the latter are more outstanding than the former.But the corrosion resistance of 316L coated samples is decreased quickly with the increase in immersion time.When the coatings are sealed with epoxy resin,the corrosion resistance of the coatings will be enhanced significantly.展开更多
文摘Grooving corrosion is a major form of corrosion and is prone to occur when high-frequency electric resistance welded （HFW） pipes are being used. Therefore,grooving corrosion is one of the performance indexes of HFW products. Grooving corrosion usually occurs along the welding fusion line, resulting in one or more corrosion grooves. The main factors affecting grooving corrosion include the contents of alloying elements and impurities （especially sulphur） in the steel,the microstructure of the welds and the steel substrate, welding parameters and the service environment as well. In this study, the existing methods for assessing grooving corrosion were systematically reviewed, improvements and new methods were proposed and developed to overcome the shortcomings of the existing methods, such as inaccuracy and excessive research time. By comparison with the existing methods, the operational procedures and the characteristics of the new methods are introduced, and issues regarding the behavior of grooving corrosion and their assessment methods, which both need further research,are discussed in this study.
文摘The corrosion mechanism of the S135 drill pipes was investigated through observation of the corrosion morphology and analysis of the corrosion products by scanning electronic microscope （ SEM）, energy dispersive spectrum （EDS） and X-ray diffraction （XRD）. The results show that the localized corrosion on the outer surface of the drill pipes was caused by oxygen corrosion due to the action of retained slurry. Cl - contained in slurry accelerated the corrosion and promoted the development of corrosion pits. Suggestions for mitigating or preventing such corrosion of the drill pipes are proposed based on the research results.
文摘Compared with the traditional wet-type de-dusting technology ,the dry-type de-dusting technology is considered to be environmentally friendly and energy-saving. However, the pipes carrying the de-dusted blast fiLrnace gas （BFG） tends to be corrosive more quickly and seriously. In order to investigate the reasons for the quick corrosion, the gas pipes and auxiliary bellows installed in Baosteel＇ s newly built BFG dry-type de-dusting system are studied. The corrosive properties of the condensed water, such as the pH value, are measured and analyzed. Meanwhile, various factors that may influence the corrosion rate of the pipes are studied by experiment. On the basis of the investigation and research, the causes of corrosion and leakage on the pipes are discovered. It is the process of dry de-dusting that is responsible ,to a large extent, for the quick corrosion of the pipes. The equipment of spray tower is introduced and its effects are then discussed. This tower is designed to eliminate most of chloridion and neutralized the acid by spraying the alkaline water to the dedusted gas flow. The practical operation shows that the tower helps to lessen the corrosiveness of the dry de-dusted gas effectively. The last part of this study analyzes the possible impacts of the dry-type de-dusting process of the newly built blast furnace （BF） on the main BFG piping which has been in the state of being corroded for years by estimating its potential corrosion rate, and some suggestions on maintenance are given as well.
基金Funded by the Program for National Science Fund for Distinguished Young Scholars of China(No.51125019)the National Natural Science Foundation of China(Nos.50904050,51244007)+2 种基金the Basic Projects of Sichuan Province(2011JY0106)the Department of Education Science and Technology Innovation Team Program of Sichuan Province(13TD0026)the Sichuan Distinguished Youth Fund(2013JQ0037)
文摘In high sour gas reservoir drilling process, it happens occasionally that high-strength drill pipe suffers brittle fracture failure due to stress corrosion cracking, and poses serious hazard to drilling safety. To solve this problem, this paper studied the stress corrosion cracking mechanism and infl uencing factors of highstrength drill pipe in sour environment with hydrogen permeation experiments and tensile tests. We simulated practical conditions in laboratory and evaluated the stress corrosion cracking performance of the high-strength drill pipe under conditions of high stress level. For the problems occurring in use of high-strength drill pipe on site, the paper proposed a technical measure for slower stress corrosion cracking.
文摘The epoxy powder exterior anti-corrosion coating production line for bent pipes with a single (double) course production is a technologically advanced bent pipe anti corrosion method with cost efficiency, environment friendliness and stable coating quality. The quality of the coating on the bent pipe fully meets the requirements of the current national and industrial standards. The application of the technology has filled the gap in the bent pipe anti corrosion coating area of China, and leads the world technologically. With this technology the coating quality of the bent pipe has greatly improved, resulting in significant social and economic benefits. With the use of the technology in various large scale pipeline projects such as the "West to East Gas Pipeline Project", it will exhibite a greater potential in the future pipeline projects with a broad application prospect.
文摘The corrosion under insulation dominates metal loss in the case of API （American Petroleum Institute） 5L Grade B geothermal pipeline, whereas, the other possible corrosion causes, such as stress corrosion and thermal cracking, did not serve a role as critical factors regarding to pipeline degradation during 26-years working operation. Actually, the header pipe diameter 32 inches and 40 inches require priority for inspection due to higher corrosion rate compared to smaller pipe diameters. By simulation method on similar heavy duty service condition in which the working pressure of 15 bars and temperature of 183 ℃, it was proved that corrosion rate will severely occur at corrosion rate more than 10 mpy in the pipe diameters of 20 inches, 32 inches and 40 inches. Further,condensation factor may contribute more significant in the case of corrosion under insulation. Practically, the metal loss at a half initial thickness requires priority for inspection, intensive maintenance or possible partial replacement.
文摘Flow accelerated corrosion（FAC） is the main failure cause of the secondary circuit carbon steel piping in nuclear power plants.The piping failures caused by FAC have resulted in numerous unplanned outages and tragic fatalities.The existing researches focus on the main factors contributing to FAC,which include metallurgical factors,environmental factors and hydrodynamic factors. Some effective FAC management methods and programs with long term monitoring and inspection data analysis are recommended.But a comprehensive FAC management system should be developed in order to mitigate and manage FAC systematically.In this paper,the FAC influencing factors are analyzed in combination with the operating conditions of the secondary circuit piping in the Third Qinshan Nuclear Power Plant（TQNPP）,China（Third Qinshan Nuclear Power Company Limited,China）.A comprehensive FAC mitigation and management system is developed for TQNPP secondary circuit piping.The system is composed of five processes,viz.materials substitution,water chemical optimization,long-term monitor strategy for the susceptible piping,integrity evaluation of the local thinning defects,and repair or replacement.With the implementation of the five processes,the material of FAC sensitive pipe fittings are modified from carbon steel to stainless steel,N_2H_4 and NH_3 are finally selected as the water chemical regulator of secondary circuit,the secondary circuit pips are classified according to FAC susceptibility in order to conduct long term monitoring strategy,and an integrity evaluation flow for local thinning caused by FAC in carbon steel piping is developed.If the component with local thinning defects is not fit-for-service,corresponding repair or replacement should be conducted.The comprehensive FAC mitigation and management system with five interrelated processes would be a cost-effective method of increasing personnel safety,plant safety and availability.
基金Projects(20080440043)supported by China Postdoctoral Science FoundationProject supported by Guangdong Sanhe Pipe-pile Co.Ltd.,China
文摘Three kinds of single layer coatings of Zn,Zn15Al,316L stainless steel and two kinds of double layer coatings with inner layer of Zn or Zn15Al and outer layer of 316L stainless steel by arc spraying were developed to protect the metal ends of prestressed high-strength concrete(PHC)pipe piles against soil corrosion.The corrosion behaviors of the coated Q235 steel samples in the simulated Dagang soil solution were investigated by potentiodynamic polarization,electrochemical impedance spectroscopy(EIS) and natural immersion tests.The results show that the corrosion of the matrix Q235 steel is effectively inhibited by Zn,Zn15Al, Zn+316L and Zn15Al+316L coatings.The corrosion rate value of Zn15Al coated samples is negative.The corrosion products on Zn and Zn15Al coated samples are compact and firm.The corrosion resistance indexes of both Zn and Zn15Al coated samples are improved significantly with corrosion time,and the latter are more outstanding than the former.But the corrosion resistance of 316L coated samples is decreased quickly with the increase in immersion time.When the coatings are sealed with epoxy resin,the corrosion resistance of the coatings will be enhanced significantly.
