The electrostrictive properties above Te max represented by the field-related and polarization-related M and Q coefficients have been measured for PbZr_(1-x)Sn_(x)O_(3)single crystals with ani-ferroelectric phase tran...The electrostrictive properties above Te max represented by the field-related and polarization-related M and Q coefficients have been measured for PbZr_(1-x)Sn_(x)O_(3)single crystals with ani-ferroelectric phase transitions.The investigations presented in this paper have proved that the M_(11)(T)and Q_(11)(T)runs bring direct information of the pre-transitional effects connected with the co-existence of local polar objects with nonpolar matrix.Due to this co-existence,nonlinear Q_(11)(T)dependence in the neighborhood of T_(C)has been detected.Observed even in a wide tem-perature above T_(C),this co-existence is a natural feature of the material with ABO_(3)perovskite structure that undergoes structural transition to po lar phase.展开更多
A new type of large-displacement actuator called reduced and internally biased oxide wafer （RAINBOW） is fabricated by chemical reduction of Pb（Sn, Zr, Ti）O3（PSZT） antiferroelectric ceramics and its properties ar...A new type of large-displacement actuator called reduced and internally biased oxide wafer （RAINBOW） is fabricated by chemical reduction of Pb（Sn, Zr, Ti）O3（PSZT） antiferroelectric ceramics and its properties are investigated. It is found that PSZT is easily reduced and the optimal conditions for producing RAINBOW samples are determined to be 870 ℃ for 2-3 h. The antiferroelectrics-ferroelectrics phase transitions occur at lower field strength in RAINBOW actuators compared with normal PSZT actuators. Large axial displacements are also obtained from the RAINBOW actuator by application of electric fields exceeding the phase switching level. However, the field-induced displacement of the RAINBOW actuator is dependent on the manner of applying load on the samples.展开更多
文摘The electrostrictive properties above Te max represented by the field-related and polarization-related M and Q coefficients have been measured for PbZr_(1-x)Sn_(x)O_(3)single crystals with ani-ferroelectric phase transitions.The investigations presented in this paper have proved that the M_(11)(T)and Q_(11)(T)runs bring direct information of the pre-transitional effects connected with the co-existence of local polar objects with nonpolar matrix.Due to this co-existence,nonlinear Q_(11)(T)dependence in the neighborhood of T_(C)has been detected.Observed even in a wide tem-perature above T_(C),this co-existence is a natural feature of the material with ABO_(3)perovskite structure that undergoes structural transition to po lar phase.
基金This project is supported by National Natural Science Foundation of China (No.50135030)Aeronautical Science Foundation of China(No.04G52042)Pre-research fund of Weapons & Equipments of China(No.51412010505HK0208).
文摘A new type of large-displacement actuator called reduced and internally biased oxide wafer （RAINBOW） is fabricated by chemical reduction of Pb（Sn, Zr, Ti）O3（PSZT） antiferroelectric ceramics and its properties are investigated. It is found that PSZT is easily reduced and the optimal conditions for producing RAINBOW samples are determined to be 870 ℃ for 2-3 h. The antiferroelectrics-ferroelectrics phase transitions occur at lower field strength in RAINBOW actuators compared with normal PSZT actuators. Large axial displacements are also obtained from the RAINBOW actuator by application of electric fields exceeding the phase switching level. However, the field-induced displacement of the RAINBOW actuator is dependent on the manner of applying load on the samples.
