The polymerization of fused-ring acceptors(FRAs) to afford their corresponding polymeric acceptors for high-performance all-polymer solar cells(all-PSCs) has achieved remarkable progress in the past few years.However,...The polymerization of fused-ring acceptors(FRAs) to afford their corresponding polymeric acceptors for high-performance all-polymer solar cells(all-PSCs) has achieved remarkable progress in the past few years.However,due to the high degree of synthetic complexity for the monomer,the high-cost of these polymeric acceptors may limit their commercial applications.Thus,it is urgent to develop inexpensive and high-performance polymeric acceptors for all-PSCs.Herein,two novel polymeric acceptors(PBTzO and PBTzO-2F) have been designed and synthesized by copolymerization of noncovalently fused ring acceptors(NFRAs),which were employed in all-PSCs for the first time.Upon introducing the “noncovalently conformational locks(NoCLs)” in the backbone and selective fluorination of the end-group,photophysical and electrical properties,and solidstate packing properties of the NFRAs have been rationally tuned.As a result,the PBDB-T:PBTzO-2F based devices presented an excellent power conversion efficiency(PCE) of 11.04%,much higher than that of PBTzO based ones due to the increased charge generation and extraction,improved hole transfer and carrier mobilities,and reduced energy loss.More importantly,PBTzO-2F exhibited a much lower synthetic complexity(SC) index and higher figure-of-merit(FOM) values than the high-performance fused-ring acceptor based polymer acceptors(FRA-PAs) due to the simpler structures and more effective synthesis.This contribution provided a novel idea to achieve low-cost and high-performance all-PSCs.展开更多
1 Results Several methods have been elaborated in this laboratory allowing preparation of macromolecules with phosphodiester bonds,and having sequence of atoms similar as in the chains of biomacromolecules - nucleic o...1 Results Several methods have been elaborated in this laboratory allowing preparation of macromolecules with phosphodiester bonds,and having sequence of atoms similar as in the chains of biomacromolecules - nucleic or teichoic acids (TA),namely:-(C)n-O-PO-,where n=2 (for teichoic acids) or 3.These methods,to be discussed in the lecture,are based on the ring-opening polymerization,transesterification,and recently elaborated direct addition of phosphoric acid to diepoxides.For the first time an attempt h...展开更多
There has been immense research interest in quantum entanglement due to its ability to generate stronger-thanclassical nonlocal correlations.^([1,2])These strong,nonlocal correlations form the backbone of various quan...There has been immense research interest in quantum entanglement due to its ability to generate stronger-thanclassical nonlocal correlations.^([1,2])These strong,nonlocal correlations form the backbone of various quantum information protocols.One of the core principles of quantum entanglement is quantum coherence,which provides deep insights into the statistical correlations among quantum particles.^([3–5])Quantum coherence reflects the wavelike properties of quantum particles,enabling them to exhibit interference and unique quantum behaviors.展开更多
Building well-developed ion-conductive highways is highly desirable for anion exchange membranes(AEMs).Grafting side chain is a highly effective approach for constructing a well-defined phaseseparated morphological st...Building well-developed ion-conductive highways is highly desirable for anion exchange membranes(AEMs).Grafting side chain is a highly effective approach for constructing a well-defined phaseseparated morphological structure and forming unblocked ion pathways in AEMs for fast ion transport.Fluorination of side chains can further enhance phase separation due to the superhydrophobic nature of fluorine groups.However,their electronic effect on the alkaline stability of side chains and membranes is rarely reported.Here,fluorine-containing and fluorine-free side chains are introduced into the polyaromatic backbone in proper configuration to investigate the impact of the fluorine terminal group on the stability of the side chains and membrane properties.The poly(binaphthyl-co-p-terphenyl piperidinium)AEM(QBNp TP)has the highest molecular weight and most dimensional stability due to its favorable backbone arrangement among ortho-and meta-terphenyl based AEMs.Importantly,by introducing both a fluorinated piperidinium side chain and a hexane chain into the p-terphenyl-based backbone,the prepared AEM(QBNp TP-QFC)presents an enhanced conductivity(150.6 m S cm^(-1))and a constrained swelling at 80℃.The electronic effect of fluorinated side chains is contemplated by experiments and simulations.The results demonstrate that the presence of strong electro-withdrawing fluorine groups weakens the electronic cloud of adjacent C atoms,increasing OH^(-)attack on the C atom and improving the stability of piperidinium cations.Hence QBNp TP-QFC possesses a robust alkaline stability at 80℃(95.3%conductivity retention after testing in 2 M Na OH for 2160 h).An excellent peak power density of 1.44 W cm^(-2)and a remarkable durability at 80℃(4.5%voltage loss after 100 h)can be observed.展开更多
A central axis represents the core of a city’s culture,signifying its features and identity.STRETCHING from the Bell Tower and the Drum Tower in the north,to the Yongding Gate in the south,the 7.8 kilometer Beijing C...A central axis represents the core of a city’s culture,signifying its features and identity.STRETCHING from the Bell Tower and the Drum Tower in the north,to the Yongding Gate in the south,the 7.8 kilometer Beijing Central Axis has been the“cultural backbone”of the city for hundreds of years.Seen from the Drum Tower,the Central Axis is like a scroll of historical stories unfolding along its route,engendering a string of emotions in its many viewers.展开更多
BAIC BJEV’s high-end new energy vehicle brand is ready for the European market.ARCFOX is a high-end new-energy vehicle(NEV)brand of the Beijing Electric Vehicle Co.,Ltd.,(BJEV),a subsidiary of the Beijing Automotive ...BAIC BJEV’s high-end new energy vehicle brand is ready for the European market.ARCFOX is a high-end new-energy vehicle(NEV)brand of the Beijing Electric Vehicle Co.,Ltd.,(BJEV),a subsidiary of the Beijing Automotive Group Co.,Ltd.(BAIC Group),a backbone enterprise in China’s automobile industry headquartered in Beijing.This year,with the NEV market booming,Arcfox has begun its foray into the European market.展开更多
Beijing Central Axis is the backbone of the ancient capital,a cultural spine shaped by the passage of time and spatial changes.Its successful inscription as a World Heritage site presents new opportunities for the con...Beijing Central Axis is the backbone of the ancient capital,a cultural spine shaped by the passage of time and spatial changes.Its successful inscription as a World Heritage site presents new opportunities for the conservation of the Central Axis cultural heritage,while also offering a fresh chance to link cultural and tourism sites along the Axis,fostering coordinated development.展开更多
Ralstonia solanacearum, the causative agent of bacterial wilt, is a soil-borne pathogen that poses a widespread threat to plants in the Solanaceae family. To elucidate the mechanism by which limonene exerts its effect...Ralstonia solanacearum, the causative agent of bacterial wilt, is a soil-borne pathogen that poses a widespread threat to plants in the Solanaceae family. To elucidate the mechanism by which limonene exerts its effects on R. solanacearum, we first assessed the impact of limonene on the physiological indicators of the pathogen and subsequently analyzed its transcriptome and metabolome. Our findings indicate that limonene has a potent inhibitory effect on R. solanacearum, and it also suppresses the formation of the bacterial community biofilm. Limonene primarily regulates the terpene biosynthesis pathway in R. solanacearum, thereby potentially affecting signal transduction in the pathogen and disrupting its normal growth and development. These results significantly enhance our understanding of limonene’s response to the induction of bacterial wilt and provide a reference for further prevention and control of R. solanacearum.展开更多
National food security is the backbone of any economy,and achieving food security is essential for the prosperity of a nation.During my study in China at the Institute of South-South Cooperation and Development,Peking...National food security is the backbone of any economy,and achieving food security is essential for the prosperity of a nation.During my study in China at the Institute of South-South Cooperation and Development,Peking University,from September 2022 to July 2023,I leant how China has managed to achieve food security despite its large population of around 1.4 billion and numerous other challenges by means of strategic planning,e"ective policy execution,technological advancement and global collaboration.展开更多
Optical transport networks are now the basic infrastructure of modern communications systems, including the SDH and WDM backbone network of local network operators, in the case of Cameroon. Given the colossal investme...Optical transport networks are now the basic infrastructure of modern communications systems, including the SDH and WDM backbone network of local network operators, in the case of Cameroon. Given the colossal investments required to deploy these networks, particularly related to the cost of equipment (optical fibers, transponders and multiplexers), the optimization of bandwidth and dynamic allocation of resources is essential to control operating costs and ensure continuity of service. Automatic switching technology for optical networks brings intelligence to the control plane to fully facilitate bandwidth utilization, traffic redirection, and automatic configuration of end-to-end services. This paper considers a local network operator’s WDM network without the implementation of the automatic switching technology, develops a network modeling software platform called Graphic Networks and using graph theory integrates a particularity of the automatic switching technology, which is the automatic rerouting of traffic in case of incident in the network. The incidents considered here are those links or route failures and node failures.展开更多
Fractals play an important role in mathematics, aesthetic, science, and engineering. The representative Sierpinski-triangle fractals have been successfully constructed by V-shape molecules in experiments. The molecula...Fractals play an important role in mathematics, aesthetic, science, and engineering. The representative Sierpinski-triangle fractals have been successfully constructed by V-shape molecules in experiments. The molecular Sierpinski triangles formed by molecules with linear backbones have been theoretically predicted but not experimentally discovered. To achieve this goal in the experiment, we used[1,1’;4’,1’’;4’’,1’’’]-quaterphenyl-3,40 0-dicarbonitrile molecules as building blocks and employed cobalt atoms as cements, then successfully obtained metal-organic Sierpinski triangles with an order up to 2 on the Au（111） surface. There are twenty-four types of three-fold coordination nodes formed between the metal atom and organic ligands via coordinate interactions. The coexistence of various nodes is responsible for that the highest order of Sierpinski triangles is limited to 2.展开更多
Dear Editor,Underwater distributed antenna systems(DAS) are stationary infrastructures consisting of multiple geographically distributed antenna elements(DAEs) which are interconnected through high-rate backbone netwo...Dear Editor,Underwater distributed antenna systems(DAS) are stationary infrastructures consisting of multiple geographically distributed antenna elements(DAEs) which are interconnected through high-rate backbone networks [1]. Compared to centralized systems, the DAS could provide a larger coverage area and higher throughput for underwater acoustic(UWA) transmissions. In this work, exploiting the low sound speed in water, a multi-agent reinforcement learning(MARL)-based approach is proposed to secure underwater DAS against eavesdropping at the physical layer.展开更多
Single-ion conducting polymer electrolytes(SIPEs)are promising candidates for high-energy and highsafety lithium-metal batteries(LMBs).However,their insufficient ionic conductivity and electrochemical stability hinder...Single-ion conducting polymer electrolytes(SIPEs)are promising candidates for high-energy and highsafety lithium-metal batteries(LMBs).However,their insufficient ionic conductivity and electrochemical stability hinder their practical application.Herein,three new SIPEs,i.e.,poly(1,4-phenylene ether ether sulfone)-Li(PEES-Li),polysulfone-Li(PSF-Li),and hexafluoropolysulfone-Li(6FPSF-Li),all containing covalently tethered perfluorinated ionic side chains,have been designed,synthesized,and compared to investigate the influence of the backbone chemistry and the concentration of the ionic group on their electrochemical properties and cell performance.Especially,the trifluoromethyl group in the backbone and the concentration of the ionic function appear to play an essential role for the charge transport and stability towards oxidation,and the combination of both yields the best-performing SIPE with high ionic conductivity of ca.2.5×10^(-4)S cm^(-1),anodic stability of more than 4.8 V,and the by far highest capacity retention in Li‖LiNi0.6Co0.2Mn0.2O2cells.展开更多
IEC publishes implementation guidelines for city service continuity Electricity is the backbone to modern Llife.It powers the many systems in our cities,from street lights to hospitals and transportation networks.As n...IEC publishes implementation guidelines for city service continuity Electricity is the backbone to modern Llife.It powers the many systems in our cities,from street lights to hospitals and transportation networks.As natural catastrophes,such as hurricanes,earthquakes and flooding occur more frequently and with greater intensity,they can have a devastating impact on cities and the many services that rely upon electricity.展开更多
Self-assembled molecules(SAMs) have shown great potential in replacing bulk charge selective contact layers in high-performance perovskite solar cells(PSCs) due to their low material consumption and simple processing....Self-assembled molecules(SAMs) have shown great potential in replacing bulk charge selective contact layers in high-performance perovskite solar cells(PSCs) due to their low material consumption and simple processing. Herein, we design and synthesize a series of donor-acceptor(D-A) type SAMs(MPA-BTCA, MPA-BT-BA, and MPA-BT-RA, where MPA is 4-methoxy-N-(4-methoxyphenyl)-N-phenylaniline;BT is benzo[c][1,2,5]-thiadiazole;CA is 2-cyanoacrylic acid, BA is benzoic acid, RA is rhodanine-3-propionic acid) with distinct anchoring groups, which show dramatically different properties. MPA-BTCA with CA anchoring groups exhibited stronger dipole moments and formed a homogeneous monolayer on the indium tin oxide(ITO) surface by adopting an upstanding self-assembling mode. However, the MPA-BT-RA molecules tend to aggregate severely in solid state due to the sp~3 hybridization of the carbon atom on the RA group, which is not favorable for achieving a long-range ordered self-assembled layer.Consequently, benefiting from high dipole moment, as well as dense and uniform self-assembled film,the device based on MPA-BT-CA yielded a remarkable power conversion efficiency(PCE) of 21.81%.Encouragingly, an impressive PCE approaching 20% can still be obtained for the MPA-BT-CA-based PSCs as the device area is increased to 0.80 cm^(2). Our work sheds light on the design principles for developing hole selecting SAMs, which will pave a way for realizing highly efficient, flexible, and large-area PSCs.展开更多
基金supported by the National Natural Science Foundation of China (52103352, 52120105006, 21774130, 51925306)the National Key R&D Program of China (2018FYA 0305800)+1 种基金the Key Research Program of the Chinese Academy of Sciences (XDPB082)the Strategic Priority Research Program of Chinese Academy of Sciences (XDB28000000)。
文摘The polymerization of fused-ring acceptors(FRAs) to afford their corresponding polymeric acceptors for high-performance all-polymer solar cells(all-PSCs) has achieved remarkable progress in the past few years.However,due to the high degree of synthetic complexity for the monomer,the high-cost of these polymeric acceptors may limit their commercial applications.Thus,it is urgent to develop inexpensive and high-performance polymeric acceptors for all-PSCs.Herein,two novel polymeric acceptors(PBTzO and PBTzO-2F) have been designed and synthesized by copolymerization of noncovalently fused ring acceptors(NFRAs),which were employed in all-PSCs for the first time.Upon introducing the “noncovalently conformational locks(NoCLs)” in the backbone and selective fluorination of the end-group,photophysical and electrical properties,and solidstate packing properties of the NFRAs have been rationally tuned.As a result,the PBDB-T:PBTzO-2F based devices presented an excellent power conversion efficiency(PCE) of 11.04%,much higher than that of PBTzO based ones due to the increased charge generation and extraction,improved hole transfer and carrier mobilities,and reduced energy loss.More importantly,PBTzO-2F exhibited a much lower synthetic complexity(SC) index and higher figure-of-merit(FOM) values than the high-performance fused-ring acceptor based polymer acceptors(FRA-PAs) due to the simpler structures and more effective synthesis.This contribution provided a novel idea to achieve low-cost and high-performance all-PSCs.
文摘1 Results Several methods have been elaborated in this laboratory allowing preparation of macromolecules with phosphodiester bonds,and having sequence of atoms similar as in the chains of biomacromolecules - nucleic or teichoic acids (TA),namely:-(C)n-O-PO-,where n=2 (for teichoic acids) or 3.These methods,to be discussed in the lecture,are based on the ring-opening polymerization,transesterification,and recently elaborated direct addition of phosphoric acid to diepoxides.For the first time an attempt h...
文摘There has been immense research interest in quantum entanglement due to its ability to generate stronger-thanclassical nonlocal correlations.^([1,2])These strong,nonlocal correlations form the backbone of various quantum information protocols.One of the core principles of quantum entanglement is quantum coherence,which provides deep insights into the statistical correlations among quantum particles.^([3–5])Quantum coherence reflects the wavelike properties of quantum particles,enabling them to exhibit interference and unique quantum behaviors.
基金the financial support from the National Natural Science Foundation of China(22078272&22278340)。
文摘Building well-developed ion-conductive highways is highly desirable for anion exchange membranes(AEMs).Grafting side chain is a highly effective approach for constructing a well-defined phaseseparated morphological structure and forming unblocked ion pathways in AEMs for fast ion transport.Fluorination of side chains can further enhance phase separation due to the superhydrophobic nature of fluorine groups.However,their electronic effect on the alkaline stability of side chains and membranes is rarely reported.Here,fluorine-containing and fluorine-free side chains are introduced into the polyaromatic backbone in proper configuration to investigate the impact of the fluorine terminal group on the stability of the side chains and membrane properties.The poly(binaphthyl-co-p-terphenyl piperidinium)AEM(QBNp TP)has the highest molecular weight and most dimensional stability due to its favorable backbone arrangement among ortho-and meta-terphenyl based AEMs.Importantly,by introducing both a fluorinated piperidinium side chain and a hexane chain into the p-terphenyl-based backbone,the prepared AEM(QBNp TP-QFC)presents an enhanced conductivity(150.6 m S cm^(-1))and a constrained swelling at 80℃.The electronic effect of fluorinated side chains is contemplated by experiments and simulations.The results demonstrate that the presence of strong electro-withdrawing fluorine groups weakens the electronic cloud of adjacent C atoms,increasing OH^(-)attack on the C atom and improving the stability of piperidinium cations.Hence QBNp TP-QFC possesses a robust alkaline stability at 80℃(95.3%conductivity retention after testing in 2 M Na OH for 2160 h).An excellent peak power density of 1.44 W cm^(-2)and a remarkable durability at 80℃(4.5%voltage loss after 100 h)can be observed.
文摘A central axis represents the core of a city’s culture,signifying its features and identity.STRETCHING from the Bell Tower and the Drum Tower in the north,to the Yongding Gate in the south,the 7.8 kilometer Beijing Central Axis has been the“cultural backbone”of the city for hundreds of years.Seen from the Drum Tower,the Central Axis is like a scroll of historical stories unfolding along its route,engendering a string of emotions in its many viewers.
文摘BAIC BJEV’s high-end new energy vehicle brand is ready for the European market.ARCFOX is a high-end new-energy vehicle(NEV)brand of the Beijing Electric Vehicle Co.,Ltd.,(BJEV),a subsidiary of the Beijing Automotive Group Co.,Ltd.(BAIC Group),a backbone enterprise in China’s automobile industry headquartered in Beijing.This year,with the NEV market booming,Arcfox has begun its foray into the European market.
文摘Beijing Central Axis is the backbone of the ancient capital,a cultural spine shaped by the passage of time and spatial changes.Its successful inscription as a World Heritage site presents new opportunities for the conservation of the Central Axis cultural heritage,while also offering a fresh chance to link cultural and tourism sites along the Axis,fostering coordinated development.
文摘Ralstonia solanacearum, the causative agent of bacterial wilt, is a soil-borne pathogen that poses a widespread threat to plants in the Solanaceae family. To elucidate the mechanism by which limonene exerts its effects on R. solanacearum, we first assessed the impact of limonene on the physiological indicators of the pathogen and subsequently analyzed its transcriptome and metabolome. Our findings indicate that limonene has a potent inhibitory effect on R. solanacearum, and it also suppresses the formation of the bacterial community biofilm. Limonene primarily regulates the terpene biosynthesis pathway in R. solanacearum, thereby potentially affecting signal transduction in the pathogen and disrupting its normal growth and development. These results significantly enhance our understanding of limonene’s response to the induction of bacterial wilt and provide a reference for further prevention and control of R. solanacearum.
文摘National food security is the backbone of any economy,and achieving food security is essential for the prosperity of a nation.During my study in China at the Institute of South-South Cooperation and Development,Peking University,from September 2022 to July 2023,I leant how China has managed to achieve food security despite its large population of around 1.4 billion and numerous other challenges by means of strategic planning,e"ective policy execution,technological advancement and global collaboration.
文摘Optical transport networks are now the basic infrastructure of modern communications systems, including the SDH and WDM backbone network of local network operators, in the case of Cameroon. Given the colossal investments required to deploy these networks, particularly related to the cost of equipment (optical fibers, transponders and multiplexers), the optimization of bandwidth and dynamic allocation of resources is essential to control operating costs and ensure continuity of service. Automatic switching technology for optical networks brings intelligence to the control plane to fully facilitate bandwidth utilization, traffic redirection, and automatic configuration of end-to-end services. This paper considers a local network operator’s WDM network without the implementation of the automatic switching technology, develops a network modeling software platform called Graphic Networks and using graph theory integrates a particularity of the automatic switching technology, which is the automatic rerouting of traffic in case of incident in the network. The incidents considered here are those links or route failures and node failures.
基金supported by the National Natural Science Foundation of China (Nos. 21522301, 21373020, 21403008, 61621061, 21433011, 61271050)the Ministry of Science and Technology (Nos. 2014CB239302 and 2013CB933404)
文摘Fractals play an important role in mathematics, aesthetic, science, and engineering. The representative Sierpinski-triangle fractals have been successfully constructed by V-shape molecules in experiments. The molecular Sierpinski triangles formed by molecules with linear backbones have been theoretically predicted but not experimentally discovered. To achieve this goal in the experiment, we used[1,1’;4’,1’’;4’’,1’’’]-quaterphenyl-3,40 0-dicarbonitrile molecules as building blocks and employed cobalt atoms as cements, then successfully obtained metal-organic Sierpinski triangles with an order up to 2 on the Au（111） surface. There are twenty-four types of three-fold coordination nodes formed between the metal atom and organic ligands via coordinate interactions. The coexistence of various nodes is responsible for that the highest order of Sierpinski triangles is limited to 2.
基金supported in part by the National Natural Science Foundation of China(62201248)the Startup Foundation of the University of South China(200XQD056)。
文摘Dear Editor,Underwater distributed antenna systems(DAS) are stationary infrastructures consisting of multiple geographically distributed antenna elements(DAEs) which are interconnected through high-rate backbone networks [1]. Compared to centralized systems, the DAS could provide a larger coverage area and higher throughput for underwater acoustic(UWA) transmissions. In this work, exploiting the low sound speed in water, a multi-agent reinforcement learning(MARL)-based approach is proposed to secure underwater DAS against eavesdropping at the physical layer.
基金the financial support from the Federal Ministry of Education and Research(BMBF)within the Fest Batt project(03XP0175B)the FB2-Poly project(03XP0429B)the financial support from the Helmholtz Association。
文摘Single-ion conducting polymer electrolytes(SIPEs)are promising candidates for high-energy and highsafety lithium-metal batteries(LMBs).However,their insufficient ionic conductivity and electrochemical stability hinder their practical application.Herein,three new SIPEs,i.e.,poly(1,4-phenylene ether ether sulfone)-Li(PEES-Li),polysulfone-Li(PSF-Li),and hexafluoropolysulfone-Li(6FPSF-Li),all containing covalently tethered perfluorinated ionic side chains,have been designed,synthesized,and compared to investigate the influence of the backbone chemistry and the concentration of the ionic group on their electrochemical properties and cell performance.Especially,the trifluoromethyl group in the backbone and the concentration of the ionic function appear to play an essential role for the charge transport and stability towards oxidation,and the combination of both yields the best-performing SIPE with high ionic conductivity of ca.2.5×10^(-4)S cm^(-1),anodic stability of more than 4.8 V,and the by far highest capacity retention in Li‖LiNi0.6Co0.2Mn0.2O2cells.
文摘IEC publishes implementation guidelines for city service continuity Electricity is the backbone to modern Llife.It powers the many systems in our cities,from street lights to hospitals and transportation networks.As natural catastrophes,such as hurricanes,earthquakes and flooding occur more frequently and with greater intensity,they can have a devastating impact on cities and the many services that rely upon electricity.
基金financial support from the National Natural Science Foundation of China (NSFC)(21805128)the National Natural Science Foundation of China (21774055)+3 种基金the financial support from the National Natural Science Foundation of China(21975260)the Shenzhen Science and Technology Innovation Commission(JCYJ20180504165709042)financial support of Guangdong Provincial Key Laboratory Program(2021B1212040001) from the Department of Science and Technology of Guangdong Provincethe NSFC-CNR exchange program of NSFC(22011530391)。
文摘Self-assembled molecules(SAMs) have shown great potential in replacing bulk charge selective contact layers in high-performance perovskite solar cells(PSCs) due to their low material consumption and simple processing. Herein, we design and synthesize a series of donor-acceptor(D-A) type SAMs(MPA-BTCA, MPA-BT-BA, and MPA-BT-RA, where MPA is 4-methoxy-N-(4-methoxyphenyl)-N-phenylaniline;BT is benzo[c][1,2,5]-thiadiazole;CA is 2-cyanoacrylic acid, BA is benzoic acid, RA is rhodanine-3-propionic acid) with distinct anchoring groups, which show dramatically different properties. MPA-BTCA with CA anchoring groups exhibited stronger dipole moments and formed a homogeneous monolayer on the indium tin oxide(ITO) surface by adopting an upstanding self-assembling mode. However, the MPA-BT-RA molecules tend to aggregate severely in solid state due to the sp~3 hybridization of the carbon atom on the RA group, which is not favorable for achieving a long-range ordered self-assembled layer.Consequently, benefiting from high dipole moment, as well as dense and uniform self-assembled film,the device based on MPA-BT-CA yielded a remarkable power conversion efficiency(PCE) of 21.81%.Encouragingly, an impressive PCE approaching 20% can still be obtained for the MPA-BT-CA-based PSCs as the device area is increased to 0.80 cm^(2). Our work sheds light on the design principles for developing hole selecting SAMs, which will pave a way for realizing highly efficient, flexible, and large-area PSCs.
