As a kind of green concrete,the mechanical properties and durability of cemented gangue backfill material(CGBM)will be affected if they are in acid mine water with sulfate ions in the long term.To improve the performa...As a kind of green concrete,the mechanical properties and durability of cemented gangue backfill material(CGBM)will be affected if they are in acid mine water with sulfate ions in the long term.To improve the performance of CGBM in acid mine water with sulfate ions,CGBM specimens with different doses of barium hydroxide were immersed in sulfuric acid solutions of different concentrations for 270 days.The changes of mass,ultrasonic pulse velocity(UPV)and compressive strength of the specimens at different ages were analyzed.Scanning electron microscopy(SEM)and X-ray diffraction(XRD)were used to analyze the microstructure and composition of the specimens.The results show that incorporation of barium hydroxide into CGBM specimen can promote the formation of barium sulfate precipitation and inhibit the generation of corrosion products such as ettringite.Meanwhile,barium sulfate precipitation blocks the pore channel invaded by sulfuric acid solution,delaying the progress of corrosion reaction and making the interior of CGBM specimen more complete.And the specimen with 2.0 kg/m^(3)barium hydroxide was more effective in improving performance.This study provides a basis for the ratio design of CGBM in acid mine water with sulfate ions.展开更多
An easy, safe, solvent free and effective method for the synthesis of pyrazole-substituted chalcones has been achieved by grinding pyrazole aldehydes and acetophenones in the presence of activated barium hydroxide （C...An easy, safe, solvent free and effective method for the synthesis of pyrazole-substituted chalcones has been achieved by grinding pyrazole aldehydes and acetophenones in the presence of activated barium hydroxide （C-200） in high yield within short span of time. All reactions were carried out just by grinding the two reactants in the presence of activated barium hydroxide （C-200）. Results are also compared with sodium hydroxide and potassium hydroxide.展开更多
基金sponsored by the National Natural Science Foundation of China(Grant No.51974192)the Distinguished Youth Funds of National Natural Science Foundation of China(Grant No.51925402)Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering Project(2021SX-TD001).
文摘As a kind of green concrete,the mechanical properties and durability of cemented gangue backfill material(CGBM)will be affected if they are in acid mine water with sulfate ions in the long term.To improve the performance of CGBM in acid mine water with sulfate ions,CGBM specimens with different doses of barium hydroxide were immersed in sulfuric acid solutions of different concentrations for 270 days.The changes of mass,ultrasonic pulse velocity(UPV)and compressive strength of the specimens at different ages were analyzed.Scanning electron microscopy(SEM)and X-ray diffraction(XRD)were used to analyze the microstructure and composition of the specimens.The results show that incorporation of barium hydroxide into CGBM specimen can promote the formation of barium sulfate precipitation and inhibit the generation of corrosion products such as ettringite.Meanwhile,barium sulfate precipitation blocks the pore channel invaded by sulfuric acid solution,delaying the progress of corrosion reaction and making the interior of CGBM specimen more complete.And the specimen with 2.0 kg/m^(3)barium hydroxide was more effective in improving performance.This study provides a basis for the ratio design of CGBM in acid mine water with sulfate ions.
文摘An easy, safe, solvent free and effective method for the synthesis of pyrazole-substituted chalcones has been achieved by grinding pyrazole aldehydes and acetophenones in the presence of activated barium hydroxide （C-200） in high yield within short span of time. All reactions were carried out just by grinding the two reactants in the presence of activated barium hydroxide （C-200）. Results are also compared with sodium hydroxide and potassium hydroxide.
