Lithium–sulfur(Li–S) batteries have received widespread attention, and lean electrolyte Li–S batteries have attracted additional interest because of their higher energy densities. This review systematically analyze...Lithium–sulfur(Li–S) batteries have received widespread attention, and lean electrolyte Li–S batteries have attracted additional interest because of their higher energy densities. This review systematically analyzes the effect of the electrolyte-to-sulfur(E/S) ratios on battery energy density and the challenges for sulfur reduction reactions(SRR) under lean electrolyte conditions. Accordingly, we review the use of various polar transition metal sulfur hosts as corresponding solutions to facilitate SRR kinetics at low E/S ratios(< 10 μL mg~(-1)), and the strengths and limitations of different transition metal compounds are presented and discussed from a fundamental perspective. Subsequently, three promising strategies for sulfur hosts that act as anchors and catalysts are proposed to boost lean electrolyte Li–S battery performance. Finally, an outlook is provided to guide future research on high energy density Li–S batteries.展开更多
Boosting of rechargeable lithium metal batteries(LMBs) holds challenges because of lithium dendrites germination and high-reactive surface feature.Separators may experience structure-determined chemical deterioration ...Boosting of rechargeable lithium metal batteries(LMBs) holds challenges because of lithium dendrites germination and high-reactive surface feature.Separators may experience structure-determined chemical deterioration and worsen Li plating-stripping behaviors when smoothly shifting from lithium-ion batteries(LIBs) to LMBs.This study precisely regulations the crystal structure of β-polypropylene and separator porous construction to investigate the intrinsic porous structure and mechanical properties determined electrochemical performances and cycling durability of LMBs.Crystal structure characterizations,porous structure analyses,and electrochemical cycling tests uncover appropriate annealing thermal stimulation concentrates β-lamellae thickness and enhances lamellae thermal stability by rearranging molecular chain in inferior β-lamellae,maximally homogenizing biaxial tensile deformation and resultant porous constructions.These even pores with high connectivity lower ion migration barriers,alleviate heterogeneous Li^(+) flux dispersion,stabilize reversible Li plating-stripping behaviors,and hinder coursing and branching of Li dendrites,endowing steady cell cycling durability,especially at higher currents due to the highlighted uncontrollable cumulation of dead Li,which offers new insights for the current pursuit of high-power density battery and fast charging technology.The suggested separator structure-chemical nature functions in ensuring cyclic cell stability and builds reliable relationships between separator structure design and practical LMBs applications.展开更多
Betavoltaic nuclear batteries offer a promising alternative energy source that harnesses the power of beta particles emitted by radioisotopes.To satisfy the power demands of microelectromechanical systems(MEMS),3D str...Betavoltaic nuclear batteries offer a promising alternative energy source that harnesses the power of beta particles emitted by radioisotopes.To satisfy the power demands of microelectromechanical systems(MEMS),3D structures have been proposed as a potential solution.Accordingly,this paper introduces a novel 3D^(63)Ni–SiC-based P^(+)PNN^(+)structure with a multi-groove design,avoiding the need for PN junctions on the inner surface,and thus reducing leakage current and power losses.Monte Carlo simulations were performed considering the fully coupled physical model to extend the electron–hole pair generation rate to a 3D structure,enabling the efficient design and development of betavoltaic batteries with complex 3D structures.As a result,the proposed model produces the significantly higher maximum output power density of 19.74μW/cm^(2) and corresponding short-circuit current,open-circuit voltage,and conversion efficiency of 8.57μA/cm^(2),2.45 V,and4.58%,respectively,compared with conventional planar batteries.From analysis of the carrier transport and collection characteristics using the COMSOL Multiphysics code,we provide deep insights regarding power increase,and elucidate the discrepancies between the ideal and simulated performances of betavoltaic batteries.Our work offers a promising approach for the design and optimization of high-output betavoltaic nuclear batteries with a unique 3D design,and serves as a valuable reference for future device fabrication.展开更多
Four Mg-x Zn-y Sn(x=2,4 and y=1,3 wt.%)alloys are investigated as anode materials for magnesium-air(Mg-air)battery.The self-corrosion and battery discharge behavior of these four Mg-Zn-Sn alloys are analyzed by electr...Four Mg-x Zn-y Sn(x=2,4 and y=1,3 wt.%)alloys are investigated as anode materials for magnesium-air(Mg-air)battery.The self-corrosion and battery discharge behavior of these four Mg-Zn-Sn alloys are analyzed by electrochemical measurements and Mg-air battery tests.The results show that addition of Sn stimulates the electrochemical activity and significantly improves the anodic efficiency and specific capacity of Mg-Zn alloy anodes.Among the four alloy anodes,Mg-2Zn-3Sn(ZT23)shows the best battery discharge performance at low current densities(≤5 m A cm^(-2)),achieving high energy density of 1367 m Wh g^(-1)at 2 mA cm^(-2).After battery discharging,the surface morphology and electrochemical measurement results illustrate that a ZnO and SnO/SnO_(2)mixed film on alloy anode surface decreases self-corrosion and improves anodic efficiency during discharging.The excessive intermetallic phases lead to the failure of passivation films,acting as micro-cathodes to accelerate self-corrosion.展开更多
Lithium-sulfur batteries(LSBs)are being recognized as potential successor to ubiquitous LIBs in daily life due to their higher theoretical energy density and lower cost effectiveness.However,the development of the LSB...Lithium-sulfur batteries(LSBs)are being recognized as potential successor to ubiquitous LIBs in daily life due to their higher theoretical energy density and lower cost effectiveness.However,the development of the LSB is beset with some tenacious issues,mainly including the insulation nature of the S or Li_(2)S(the discharged product),the unavoidable dissolution of the reaction intermediate products(mainly as lithium polysulfides(LiPSs)),and the subsequent LiPSs shuttling across the separator,resulting in the continuous loss of active material,anode passivation,and low coulombic efficiency.Containment methods by introducing the high-electrical conductivity host are commonly used in improving the electrochemical performances of LSBs.However,such prevalent technologies are in the price of reduced energy density since they require more addition of amount of host materials.Adding trace of catalysts that catalyze the redox reaction between S/Li_(2)S and Li_(2)Sn(3<n≤8),shows ingenious design,which not only accelerates the conversion reaction between the solid S species and dissolved S species,alleviating the shuttle effect,but also expedites the electron transport thus reducing the polarization of the electrode.In this review,the redox reaction process during Li-S chemistry are firstly highlighted.Recent developed catalysts,including transitionmetal oxides,chalcogenides,phosphides,nitrides,and carbides/borides are then outlined to better understand the role of catalyst additives during the polysulfide conversion.Finally,the critical issues,challenges,and perspectives are discussed to demonstrate the potential development of LSBs.展开更多
Lithium–sulfur (Li–S) batteries are great candidates for energy storage systems, but need to overcome theissues of low sulfur utilization and polysulfide shuttling for use in large-scale commercial applications.Rece...Lithium–sulfur (Li–S) batteries are great candidates for energy storage systems, but need to overcome theissues of low sulfur utilization and polysulfide shuttling for use in large-scale commercial applications.Recently, quaternized polymers have received much attention for their polysulfide trapping propertiesdue to electrostatic interaction. In this work, we report a series of polyarylether sulfone (PSF) binderswith different cation structures including imidazolium (Im), triethylammonium (Tr), and morpholinium(Mo). The ability of the these quaternized binders and the conventional poly(vinylidene fluoride) or PVDFbinder to capture polysulfide increases in the order of PVDF << PSF-Mo < PSF-Tr< PSF-Im. The delocalizedcharge on the imidazolium cation may promote the interaction between PSF-Im and polysulfide asindicated by an X-ray photoelectron spectroscopic study. The PSF-Im based cathodes showed the highestcapacity retention (77% at 0.2 C after 100 cycles and 84% at 0.5 C after 120 cycles), and the bestrate capability. This work demonstrates the importance of the cation structure in the design of efficientquaternized binders for high performance Li–S batteries.展开更多
Dear editor,This letter focuses on modeling the electrode heterogeneity by extending the pseudo-two-dimensional model(P2D)with actual particle-size distributions(PSD).The effects of different particle characterization...Dear editor,This letter focuses on modeling the electrode heterogeneity by extending the pseudo-two-dimensional model(P2D)with actual particle-size distributions(PSD).The effects of different particle characterization techniques,including the area-weighted,volume-weighted,and number-based methods on cell dynamics are compared.展开更多
The development of aqueous zinc ion battery cathode materials with high capacity and high magnification is still a challenge.Herein,porous vanadium oxide/carbon(p-VO_(x)@C,mainly VO_(2) with a small amount of V_(2)O_(...The development of aqueous zinc ion battery cathode materials with high capacity and high magnification is still a challenge.Herein,porous vanadium oxide/carbon(p-VO_(x)@C,mainly VO_(2) with a small amount of V_(2)O_(3)) core/shell microspheres with oxygen vacancies are facilely fabricated by using a vanadium-based metal-organic framework(MIL-100(V)) as a sacrificial template.This unique structure can improve the conductivity of the VO_(x),accelerate electrolyte diffusion,and suppress structural collapse during circulation.Subsequently,H_(2)O molecules are introduced into the interlayer of VO_(x) through a highly efficient in-situ electrochemical activation process,facilitating the intercalation and diffusion of zinc ions.After the activation,an optimal sample exhibits a high specific capacity of 464.3 mA h g^(-1) at0.2 A g^(-1) and 395.2 mA h g^(-1) at 10 A g^(-1),indicating excellent rate performance.Moreover,the optimal sample maintains a capacity retention of about 89.3% after 2500 cycles at 10 A g^(-1).Density functional theory calculation demonstrates that the presence of oxygen vacancies and intercalated water molecules can significantly reduce the diffusion barrier for zinc ions.In addition,it is proved that the storage of zinc ions in the cathode is achieved by reversible intercalation/extraction during the charge and discharge process through various ex-situ analysis technologies.This work demonstrates that the p-VO_(x)@C has great potential for applications in aqueous ZIBs after electrochemical activation.展开更多
The construction of stable cathode electrolyte interphase(CEI)is the key to improve the NCM811 particle structure and interfacial stability via electrolyte engineering.In He’s work,lithium hexamethyldisilazide(LiHMDS...The construction of stable cathode electrolyte interphase(CEI)is the key to improve the NCM811 particle structure and interfacial stability via electrolyte engineering.In He’s work,lithium hexamethyldisilazide(LiHMDS)as the electrolyte additive is proposed to facilitate the generation of stable CEI on NCM811 cathode surface and eliminate H_(2)O and HF in the electrolyte at the same time,which boosts the cycling performance of Li||NCM811 battery up to 1000 or 500 cycles with 4.5 V cut-off voltage at 25 or 60℃.展开更多
Sophisticated efficient electrocatalysts are essential to rectifying the shuttle effect and realizing the high performance of flexible lithium-sulfur batteries(LSBs).Phase transformation of MoSe_(2) from the 2H phase ...Sophisticated efficient electrocatalysts are essential to rectifying the shuttle effect and realizing the high performance of flexible lithium-sulfur batteries(LSBs).Phase transformation of MoSe_(2) from the 2H phase to the 1T phase has been proven to be a significant method to improve the catalytic activity.However,precisely controllable phase engineering of MoSe_(2) has rarely been reported.Herein,by in situ Li ions intercalation in MoSe_(2),a precisely controllable phase evolution from 2H-MoSe_(2) to 1T-MoSe_(2) was realized.More importantly,the definite functional relationship between cut-off voltage and phase structure was first identified for phase engineering through in situ observation and modulation methods.The sulfur host(CNFs/1T-MoSe_(2))presents high charge density,strong polysulfides adsorption,and catalytic kinetics.Moreover,Li-S cells based on it display capacity retention of 875.3mAh g^(-1) after 500 cycles at 1 C and an areal capacity of 8.71mAh cm^(-2) even at a high sulfur loading of 8.47mg cm^(-2).Furthermore,the flexible pouch cell exhibiting decent performance will endow a promising potential in the wearable energy storage field.This study proposes an effective strategy to precisely control the phase structure of MoSe_(2),which may provide the reference to fabricate the highly efficient electrocatalysts for LSBs and other energy systems.展开更多
Efficient synthesis of transition metal hydroxides on conductive substrate is essential for enhancing their merits in industrialization of energy storage field.However,most of the synthetic routes at present mainly re...Efficient synthesis of transition metal hydroxides on conductive substrate is essential for enhancing their merits in industrialization of energy storage field.However,most of the synthetic routes at present mainly rely on traditional bottom-up method,which involves tedious steps,time-consuming treatments,or additional alkaline media,and is unfavorable for high-efficiency production.Herein,we present a facile,ultrafast and general avenue to synthesize transition metal hydroxides on carbon substrate within 13 s by Joule-heating method.With high reaction kinetics caused by the instantaneous high temperature,seven kinds of transition metal-layered hydroxides(TM-LDHs)are formed on carbon cloth.Therein,the fastest synthesis rate reaches~0.46 cm^(2)s^(-1).Density functional theory calculations further demonstrate the nucleation energy barriers and potential mechanism for the formation of metal-based hydroxides on carbon substrates.This efficient approach avoids the use of extra agents,multiple steps,and long production time and endows the LDHs@carbon cloth with outstanding flexibility and machinability,showing practical advantages in both common and micro-zinc ion-based energy storage devices.To prove its utility,as a cathode in rechargeable aqueous alkaline Zn(micro-)battery,the NiCo LDH@carbon cloth exhibits a high energy density,superior to most transition metal LDH materials reported so far.展开更多
The lithium-sulfur(Li-S)battery,as one of the energy storage devices,has been in the limelight due to its high theoretical energy density.However,the poor redox kinetics and the"shuttle effect"of polysulfide...The lithium-sulfur(Li-S)battery,as one of the energy storage devices,has been in the limelight due to its high theoretical energy density.However,the poor redox kinetics and the"shuttle effect"of polysulfides severely restrict the use of Li-S batteries in practical applications.Herein,a novel bimetallic LaNiO_(3) functional material with high electrical conductivity and catalytic property is prepared to act as a high-efficiency polysulfide shuttling stopper.The three LaNiO_(3) samples with different physical/chemical characteristics are obtained by controlling the calcination temperature.In conjunction with the high electrical conductivity and excellent catalytic properties of the as-prepared materials,the appropriate chemisorption toward polysulfides offers great potential to enhance electrochemical stability for highperformance Li-S batteries.Particularly,the Li-S cell with the separator modified by such functional material gives a specific capacity of 658 mA h g^(-1) after 500 cycles at a high current density of 2 C.Even with high sulfur loading of 6.05 mg cm^(-2),the Li-S battery still exhibits an areal specific capacity of 2.81 m A h cm^(-2)after 150 cycles.This work paves a new avenue for the rational design of materials for separator modification in high-performance Li-S batteries.展开更多
Halide electrolytes in solid-state batteries with excellent oxidative stability and high ionic conductivity have been well reported recently.However,the high-cost rare-earth elements and long duration of highrotation ...Halide electrolytes in solid-state batteries with excellent oxidative stability and high ionic conductivity have been well reported recently.However,the high-cost rare-earth elements and long duration of highrotation milling procure are the major obstacles.Herein,we have successfully synthesized the low cost Li_(2.25)Zr_(0.75)Fe_(0.25)Cl_(6)electrolyte consisting of abundant elements with comparable Li-ion conductivity in a short milling duration of 4 h.Phase transition of the annealed sample was also carefully investigated.Li Ni_(0.6)Co_(0.2)Mn_(0.2)O_(2)/Li_(2.25)Zr_(0.75)Fe_(0.25)Cl_(6)/Li_(5.5)PS_(4.5)Cl_(1.5)/In-Li batteries using different halide electrolytes were constructed and cycled at different voltage windows.Solid-state battery using Li_(2.25)Zr_(0.75)Fe_(0.25)Cl_(6)electrolyte obtained from long milling duration delivers higher discharge capacities and superior capacity retention than shorter milling time between 3.0 and 4.3 V.It delivers much higher discharge capacity when cycled at elevated temperature(60℃)and suffers fast capacity degradation when the upper cut-off voltage increases to 4.5 V at the same current density.This work provides an efficiency synthesis strategy for halide solid electrolyte and studies its applications in all-solid-state batteries in a wide temperature range.展开更多
Solid-state batteries have been considered as a good choice for substituting traditional batteries with liquid electrolytes because of their high energy density and safe property.However,a little amount of flammable n...Solid-state batteries have been considered as a good choice for substituting traditional batteries with liquid electrolytes because of their high energy density and safe property.However,a little amount of flammable non-aqueous liquid electrolyte or polymer electrolyte is usually required to improve the interfacial contact,which is adverse to safety.Here,a nonflammable gel is prepared by hydrogen-bond interaction and applied as an interfacial layer to improve the performance of solid-state batteries.The prepared multilayer hybrid electrolyte(MHE)composed of gel and CPE shows a wide electrochemical window(5.3 V vs Li/Li+),high ionic transference number(0.57),and ionic conductivity(7.18×10^(−4) S cm^(−1))at room temperature.Thus,the assembled Li symmetric cell with MHE can cycle over 650 h at 0.5 mA cm^(−2) with a lower overpotential of~61 mV.The LiFePO_(4)|MHE|Li cell exhibits a higher discharge capacity of 107.8 mAh g−1 even cycled at 5 C.It also shows superior capacity retention of 96.4%after 1000 cycles at 0.5 C.This work provides a promising strategy for designing high-performance solid-state batteries.展开更多
Novel small sulfur heterocyclic quinones(6a,16adihydrobenzo[b]naphtho[2′,3′:5,6][1,4]dithiino[2,3-i]thianthrene-5,7,9,14,16,18-hexaone(4S6Q)and benzo[b]naphtho[2′,3′:5,6][1,4]dithiino[2,3-i]thianthrene-5,9,14,18-t...Novel small sulfur heterocyclic quinones(6a,16adihydrobenzo[b]naphtho[2′,3′:5,6][1,4]dithiino[2,3-i]thianthrene-5,7,9,14,16,18-hexaone(4S6Q)and benzo[b]naphtho[2′,3′:5,6][1,4]dithiino[2,3-i]thianthrene-5,9,14,18-tetraone(4S4Q))are developed by molecule structural design method and as cathode for aqueous zincorganic batteries.The conjugated thioether(–S–)bonds as connected units not only improve the conductivity of compounds but also inhibit their dissolution by both extendedπ-conjugated plane and constructed flexible molecular skeleton.Hence,the Zn//4S6Q and Zn//4S4Q batteries exhibit satisfactory electrochemical performance based on 3.5 mol L-1(M)Zn(ClO4)2electrolyte.For instance,the Zn//4S6Q battery obtains 240 and 208.6 mAh g^(-1)of discharge capacity at 150 mA g^(-1)and 30 A g^(-1),respectively.The excellent rate capability is ascribed to the fast reaction kinetics.This system displays a superlong life of 20,000 cycles with no capacity fading at 3 A g^(-1).Additionally,the H+-storage mechanism of the 4S6Q compound is demonstrated by ex situ analyses and density functional theory calculations.Impressively,the battery can normally work at-60℃benefiting from the anti-freezing electrolyte and maintain a high discharge capacity of 201.7 mAh g^(-1),which is 86.2%of discharge capacity at 25℃.The cutting-edge electrochemical performances of these novel compounds make them alternative electrode materials for Zn-organic batteries.展开更多
Aqueous Mg ion batteries(AMIBs)show great potential in energy storage for their advantages of high capacity,abundant resource,and environmental friendliness.However,the development of AMIBs is limited due to the scarc...Aqueous Mg ion batteries(AMIBs)show great potential in energy storage for their advantages of high capacity,abundant resource,and environmental friendliness.However,the development of AMIBs is limited due to the scarcity of suitable anode materials.In this study,a new polymer anode material(PNTAQ)with flower-like nanosheet structure is synthesized for aqueous Mg-Na hybrid-ion battery(AMNHIB).PNTAQ possess carbonyl functional groups which can be oxidized and reduced reversibly in aqueous solution containing alkaline metal ions.PNTAQ displays a discharge specific capacity of 245 mAh g^(−1)at 50 mA g^(−1)in 1 M MgCl_(2)+0.5 M NaCl electrolyte,which is much higher than that in single 1 M MgCl_(2)or 0.5 M NaCl electrolyte.Even cycling at 1000 mA g^(−1)for 1000 times,the capacity retention can still maintain at 87.2%.A full Mg-Na hybrid-ion cell is assembled by employingβ-MnO_(2)as cathode and PNTAQ as anode material,it exhibits a specific capacity of 91.6 mAh g^(−1)at 100 mA g^(−1).The polymer electrode material well maintains its framework structure during the discharge/charge cycling process of the hybrid-ion battery.展开更多
The main bottleneck against industrial utilization of sodium ion batteries(SIBs)is the lack of high-capacity electrodes to rival those of the benchmark lithium ion batteries(LIBs).Here in this work,we have developed a...The main bottleneck against industrial utilization of sodium ion batteries(SIBs)is the lack of high-capacity electrodes to rival those of the benchmark lithium ion batteries(LIBs).Here in this work,we have developed an economical method for in situ fabrication of nanocomposites made of crystalline few-layer graphene sheets loaded with ultrafine SnO_(2)nanocrystals,using short exposure of microwave to xerogel of graphene oxide(GO)and tin tetrachloride containing minute catalyzing dispersoids of chemically reduced GO(RGO).The resultant nanocomposites(SnO_(2)@MWG)enabled significantly quickened redox processes as SIB anode,which led to remarkable full anode-specific capacity reaching 538 mAh g^(−1)at 0.05 A g^(−1)(about 1.45 times of the theoretical capacity of graphite for the LIB),in addition to outstanding rate performance over prolonged charge–discharge cycling.Anodes based on the optimized SnO_(2)@MWG delivered stable performance over 2000 cycles even at a high current density of 5 A g^(−1),and capacity retention of over 70.4%was maintained at a high areal loading of 3.4 mg cm^(−2),highly desirable for high energy density SIBs to rival the current benchmark LIBs.展开更多
Current lithium-ion batteries(LIBs)rely on organic liquid electrolytes that pose significant risks due to their flammability and toxicity.The potential for environmental pollution and explosions resulting from battery...Current lithium-ion batteries(LIBs)rely on organic liquid electrolytes that pose significant risks due to their flammability and toxicity.The potential for environmental pollution and explosions resulting from battery damage or fracture is a critical concern.Water-based(aqueous)electrolytes have been receiving attention as an alternative to organic electrolytes.However,a narrow electrochemicalstability window,water decomposition,and the consequent low battery operating voltage and energy density hinder the practical use of aqueous electrolytes.Therefore,developing novel aqueous electrolytes for sustainable,safe,high-performance LIBs remains challenging.This Review first commences by summarizing the roles and requirements of electrolytes–separators and then delineates the progression of aqueous electrolytes for LIBs,encompassing aqueous liquid and gel electrolyte development trends along with detailed principles of the electrolytes.These aqueous electrolytes are progressed based on strategies using superconcentrated salts,concentrated diluents,polymer additives,polymer networks,and artificial passivation layers,which are used for suppressing water decomposition and widening the electrochemical stability window of water of the electrolytes.In addition,this Review discusses potential strategies for the implementation of aqueous Li-metal batteries with improved electrolyte–electrode interfaces.A comprehensive understanding of each strategy in the aqueous system will assist in the design of an aqueous electrolyte and the development of sustainable and safe high-performance batteries.展开更多
An open quantum battery(QB)model of a single qubit system charging in a coherent auxiliary bath(CAB)consisting of a series of independent coherent ancillae is considered.According to the collision charging protocol we...An open quantum battery(QB)model of a single qubit system charging in a coherent auxiliary bath(CAB)consisting of a series of independent coherent ancillae is considered.According to the collision charging protocol we derive a quantum master equation and obtain the analytical solution of QB in a steady state.We find that the full charging capacity(or the maximal extractable work(MEW))of QB,in the weak QB-ancilla coupling limit,is positively correlated with the coherence magnitude of ancilla.Combining with the numerical simulations we compare with the charging properties of QB at finite coupling strength,such as the MEW,average charging power and the charging efficiency,when considering the bath to be a thermal auxiliary bath(TAB)and a CAB,respectively.We find that when the QB with CAB,in the weak coupling regime,is in fully charging,both its capacity and charging efficiency can go beyond its classical counterpart,and they increase with the increase of coherence magnitude of ancilla.In addition,the MEW of QB in the regime of relative strong coupling and strong coherent magnitude shows the oscillatory behavior with the charging time increasing,and the first peak value can even be larger than the full charging MEW of QB.This also leads to a much larger average charging power than that of QB with TAB in a short-time charging process.These features suggest that with the help of quantum coherence of CAB it becomes feasible to switch the charging schemes between the long-time slow charging protocol with large capacity and high efficiency and the short-time rapid charging protocol with highly charging power only by adjusting the coupling strength of QB-ancilla.This work clearly demonstrates that the quantum coherence of bath can not only serve as the role of“fuel”of QB to be utilized to improve the QB's charging performance but also provide an alternative way to integrate the different charging protocols into a single QB.展开更多
基金the Research Foundation-Flanders (FWO) for a Research Project (G0B3218N)the financial support by the National Natural Science Foundation of China (22005054)+3 种基金Natural Science Foundation of Fujian Province (2021J01149)State Key Laboratory of Structural Chemistry (20200007)Sichuan Science and Technology Program (project No.: 2022ZYD0016 and 2023JDRC0013)the National Natural Science Foundation of China (project No. 21776120)。
文摘Lithium–sulfur(Li–S) batteries have received widespread attention, and lean electrolyte Li–S batteries have attracted additional interest because of their higher energy densities. This review systematically analyzes the effect of the electrolyte-to-sulfur(E/S) ratios on battery energy density and the challenges for sulfur reduction reactions(SRR) under lean electrolyte conditions. Accordingly, we review the use of various polar transition metal sulfur hosts as corresponding solutions to facilitate SRR kinetics at low E/S ratios(< 10 μL mg~(-1)), and the strengths and limitations of different transition metal compounds are presented and discussed from a fundamental perspective. Subsequently, three promising strategies for sulfur hosts that act as anchors and catalysts are proposed to boost lean electrolyte Li–S battery performance. Finally, an outlook is provided to guide future research on high energy density Li–S batteries.
基金the Natural Science Foundation of Shandong Province (ZR2022QB050)the Liaocheng University Doctoral Initial Fund (318052137) for Financial Support。
文摘Boosting of rechargeable lithium metal batteries(LMBs) holds challenges because of lithium dendrites germination and high-reactive surface feature.Separators may experience structure-determined chemical deterioration and worsen Li plating-stripping behaviors when smoothly shifting from lithium-ion batteries(LIBs) to LMBs.This study precisely regulations the crystal structure of β-polypropylene and separator porous construction to investigate the intrinsic porous structure and mechanical properties determined electrochemical performances and cycling durability of LMBs.Crystal structure characterizations,porous structure analyses,and electrochemical cycling tests uncover appropriate annealing thermal stimulation concentrates β-lamellae thickness and enhances lamellae thermal stability by rearranging molecular chain in inferior β-lamellae,maximally homogenizing biaxial tensile deformation and resultant porous constructions.These even pores with high connectivity lower ion migration barriers,alleviate heterogeneous Li^(+) flux dispersion,stabilize reversible Li plating-stripping behaviors,and hinder coursing and branching of Li dendrites,endowing steady cell cycling durability,especially at higher currents due to the highlighted uncontrollable cumulation of dead Li,which offers new insights for the current pursuit of high-power density battery and fast charging technology.The suggested separator structure-chemical nature functions in ensuring cyclic cell stability and builds reliable relationships between separator structure design and practical LMBs applications.
基金supported by Anhui Provincial Key R&D Program(No.202104g0102007)Jiangxi Provincial Department of Education Science and Technology Research Youth Project(GJJ200763)+3 种基金Hubei Provincial Natural Science Foundation of China(No.2022CFB575)Hefei Municipal Natural Science Foundation(No.2022011)Ministry of Education Industry-Education Cooperation Project(No.202102647014)Science Island Graduate Innovation and Entrepreneurship Fund Project(No.KY-2022-SC-04)。
文摘Betavoltaic nuclear batteries offer a promising alternative energy source that harnesses the power of beta particles emitted by radioisotopes.To satisfy the power demands of microelectromechanical systems(MEMS),3D structures have been proposed as a potential solution.Accordingly,this paper introduces a novel 3D^(63)Ni–SiC-based P^(+)PNN^(+)structure with a multi-groove design,avoiding the need for PN junctions on the inner surface,and thus reducing leakage current and power losses.Monte Carlo simulations were performed considering the fully coupled physical model to extend the electron–hole pair generation rate to a 3D structure,enabling the efficient design and development of betavoltaic batteries with complex 3D structures.As a result,the proposed model produces the significantly higher maximum output power density of 19.74μW/cm^(2) and corresponding short-circuit current,open-circuit voltage,and conversion efficiency of 8.57μA/cm^(2),2.45 V,and4.58%,respectively,compared with conventional planar batteries.From analysis of the carrier transport and collection characteristics using the COMSOL Multiphysics code,we provide deep insights regarding power increase,and elucidate the discrepancies between the ideal and simulated performances of betavoltaic batteries.Our work offers a promising approach for the design and optimization of high-output betavoltaic nuclear batteries with a unique 3D design,and serves as a valuable reference for future device fabrication.
基金partially supported by the Marsden Fund managed by the Royal Society of New Zealand Te Apārangi(FastStart Marsden Grant project No.UOA1817)the scholarship from China Scholarship Council(No.201808060410)
文摘Four Mg-x Zn-y Sn(x=2,4 and y=1,3 wt.%)alloys are investigated as anode materials for magnesium-air(Mg-air)battery.The self-corrosion and battery discharge behavior of these four Mg-Zn-Sn alloys are analyzed by electrochemical measurements and Mg-air battery tests.The results show that addition of Sn stimulates the electrochemical activity and significantly improves the anodic efficiency and specific capacity of Mg-Zn alloy anodes.Among the four alloy anodes,Mg-2Zn-3Sn(ZT23)shows the best battery discharge performance at low current densities(≤5 m A cm^(-2)),achieving high energy density of 1367 m Wh g^(-1)at 2 mA cm^(-2).After battery discharging,the surface morphology and electrochemical measurement results illustrate that a ZnO and SnO/SnO_(2)mixed film on alloy anode surface decreases self-corrosion and improves anodic efficiency during discharging.The excessive intermetallic phases lead to the failure of passivation films,acting as micro-cathodes to accelerate self-corrosion.
基金supported by the National Natural Science Foundation of China(21601089,21905140)the Six Talent Peaks Project of Jiangsu Province in China(2016-XCL-047)Jiangsu SpeciallyAppointed Professor program。
文摘Lithium-sulfur batteries(LSBs)are being recognized as potential successor to ubiquitous LIBs in daily life due to their higher theoretical energy density and lower cost effectiveness.However,the development of the LSB is beset with some tenacious issues,mainly including the insulation nature of the S or Li_(2)S(the discharged product),the unavoidable dissolution of the reaction intermediate products(mainly as lithium polysulfides(LiPSs)),and the subsequent LiPSs shuttling across the separator,resulting in the continuous loss of active material,anode passivation,and low coulombic efficiency.Containment methods by introducing the high-electrical conductivity host are commonly used in improving the electrochemical performances of LSBs.However,such prevalent technologies are in the price of reduced energy density since they require more addition of amount of host materials.Adding trace of catalysts that catalyze the redox reaction between S/Li_(2)S and Li_(2)Sn(3<n≤8),shows ingenious design,which not only accelerates the conversion reaction between the solid S species and dissolved S species,alleviating the shuttle effect,but also expedites the electron transport thus reducing the polarization of the electrode.In this review,the redox reaction process during Li-S chemistry are firstly highlighted.Recent developed catalysts,including transitionmetal oxides,chalcogenides,phosphides,nitrides,and carbides/borides are then outlined to better understand the role of catalyst additives during the polysulfide conversion.Finally,the critical issues,challenges,and perspectives are discussed to demonstrate the potential development of LSBs.
基金supported by the Science and Technology Innovation Fund of Dalian(2018J12GX052)the National Natural Science Foundation of China(Grant No.21776042)the Fundamental Research Funds for the Central Universities of China(Grant no.DUT19ZD214)。
文摘Lithium–sulfur (Li–S) batteries are great candidates for energy storage systems, but need to overcome theissues of low sulfur utilization and polysulfide shuttling for use in large-scale commercial applications.Recently, quaternized polymers have received much attention for their polysulfide trapping propertiesdue to electrostatic interaction. In this work, we report a series of polyarylether sulfone (PSF) binderswith different cation structures including imidazolium (Im), triethylammonium (Tr), and morpholinium(Mo). The ability of the these quaternized binders and the conventional poly(vinylidene fluoride) or PVDFbinder to capture polysulfide increases in the order of PVDF << PSF-Mo < PSF-Tr< PSF-Im. The delocalizedcharge on the imidazolium cation may promote the interaction between PSF-Im and polysulfide asindicated by an X-ray photoelectron spectroscopic study. The PSF-Im based cathodes showed the highestcapacity retention (77% at 0.2 C after 100 cycles and 84% at 0.5 C after 120 cycles), and the bestrate capability. This work demonstrates the importance of the cation structure in the design of efficientquaternized binders for high performance Li–S batteries.
文摘Dear editor,This letter focuses on modeling the electrode heterogeneity by extending the pseudo-two-dimensional model(P2D)with actual particle-size distributions(PSD).The effects of different particle characterization techniques,including the area-weighted,volume-weighted,and number-based methods on cell dynamics are compared.
基金supported by the National Natural Science Foundation of China(Nos.92163118,51972234)。
文摘The development of aqueous zinc ion battery cathode materials with high capacity and high magnification is still a challenge.Herein,porous vanadium oxide/carbon(p-VO_(x)@C,mainly VO_(2) with a small amount of V_(2)O_(3)) core/shell microspheres with oxygen vacancies are facilely fabricated by using a vanadium-based metal-organic framework(MIL-100(V)) as a sacrificial template.This unique structure can improve the conductivity of the VO_(x),accelerate electrolyte diffusion,and suppress structural collapse during circulation.Subsequently,H_(2)O molecules are introduced into the interlayer of VO_(x) through a highly efficient in-situ electrochemical activation process,facilitating the intercalation and diffusion of zinc ions.After the activation,an optimal sample exhibits a high specific capacity of 464.3 mA h g^(-1) at0.2 A g^(-1) and 395.2 mA h g^(-1) at 10 A g^(-1),indicating excellent rate performance.Moreover,the optimal sample maintains a capacity retention of about 89.3% after 2500 cycles at 10 A g^(-1).Density functional theory calculation demonstrates that the presence of oxygen vacancies and intercalated water molecules can significantly reduce the diffusion barrier for zinc ions.In addition,it is proved that the storage of zinc ions in the cathode is achieved by reversible intercalation/extraction during the charge and discharge process through various ex-situ analysis technologies.This work demonstrates that the p-VO_(x)@C has great potential for applications in aqueous ZIBs after electrochemical activation.
基金the support from the National Natural Science Foundation of China(Grant No.51971090 and U21A20311)。
文摘The construction of stable cathode electrolyte interphase(CEI)is the key to improve the NCM811 particle structure and interfacial stability via electrolyte engineering.In He’s work,lithium hexamethyldisilazide(LiHMDS)as the electrolyte additive is proposed to facilitate the generation of stable CEI on NCM811 cathode surface and eliminate H_(2)O and HF in the electrolyte at the same time,which boosts the cycling performance of Li||NCM811 battery up to 1000 or 500 cycles with 4.5 V cut-off voltage at 25 or 60℃.
基金National Natural Science Foundation of China,Grant/Award Numbers:U2004172,51972287 and 51502269the Foundation for University Key Teachers of Henan Province,Grant/Award Number:2020GGJS009Natural Science Foundation of Henan Province,Grant/Award Number:202300410368。
文摘Sophisticated efficient electrocatalysts are essential to rectifying the shuttle effect and realizing the high performance of flexible lithium-sulfur batteries(LSBs).Phase transformation of MoSe_(2) from the 2H phase to the 1T phase has been proven to be a significant method to improve the catalytic activity.However,precisely controllable phase engineering of MoSe_(2) has rarely been reported.Herein,by in situ Li ions intercalation in MoSe_(2),a precisely controllable phase evolution from 2H-MoSe_(2) to 1T-MoSe_(2) was realized.More importantly,the definite functional relationship between cut-off voltage and phase structure was first identified for phase engineering through in situ observation and modulation methods.The sulfur host(CNFs/1T-MoSe_(2))presents high charge density,strong polysulfides adsorption,and catalytic kinetics.Moreover,Li-S cells based on it display capacity retention of 875.3mAh g^(-1) after 500 cycles at 1 C and an areal capacity of 8.71mAh cm^(-2) even at a high sulfur loading of 8.47mg cm^(-2).Furthermore,the flexible pouch cell exhibiting decent performance will endow a promising potential in the wearable energy storage field.This study proposes an effective strategy to precisely control the phase structure of MoSe_(2),which may provide the reference to fabricate the highly efficient electrocatalysts for LSBs and other energy systems.
基金the NSFC(22075019)National Key R&D Program of China(2017YFB1104300)。
文摘Efficient synthesis of transition metal hydroxides on conductive substrate is essential for enhancing their merits in industrialization of energy storage field.However,most of the synthetic routes at present mainly rely on traditional bottom-up method,which involves tedious steps,time-consuming treatments,or additional alkaline media,and is unfavorable for high-efficiency production.Herein,we present a facile,ultrafast and general avenue to synthesize transition metal hydroxides on carbon substrate within 13 s by Joule-heating method.With high reaction kinetics caused by the instantaneous high temperature,seven kinds of transition metal-layered hydroxides(TM-LDHs)are formed on carbon cloth.Therein,the fastest synthesis rate reaches~0.46 cm^(2)s^(-1).Density functional theory calculations further demonstrate the nucleation energy barriers and potential mechanism for the formation of metal-based hydroxides on carbon substrates.This efficient approach avoids the use of extra agents,multiple steps,and long production time and endows the LDHs@carbon cloth with outstanding flexibility and machinability,showing practical advantages in both common and micro-zinc ion-based energy storage devices.To prove its utility,as a cathode in rechargeable aqueous alkaline Zn(micro-)battery,the NiCo LDH@carbon cloth exhibits a high energy density,superior to most transition metal LDH materials reported so far.
基金supported by the National Natural Science Foundation of China(51972184,22005169)the Key Basic Research Project of Shandong Province(ZR2019ZD49)+2 种基金the Natural Science Foundation of Shandong Province(ZR2020QB121)the Taishan Scholars Project of Shandong Provincethe Taishan Scholar Young Talent Program(tsqn201909114)。
文摘The lithium-sulfur(Li-S)battery,as one of the energy storage devices,has been in the limelight due to its high theoretical energy density.However,the poor redox kinetics and the"shuttle effect"of polysulfides severely restrict the use of Li-S batteries in practical applications.Herein,a novel bimetallic LaNiO_(3) functional material with high electrical conductivity and catalytic property is prepared to act as a high-efficiency polysulfide shuttling stopper.The three LaNiO_(3) samples with different physical/chemical characteristics are obtained by controlling the calcination temperature.In conjunction with the high electrical conductivity and excellent catalytic properties of the as-prepared materials,the appropriate chemisorption toward polysulfides offers great potential to enhance electrochemical stability for highperformance Li-S batteries.Particularly,the Li-S cell with the separator modified by such functional material gives a specific capacity of 658 mA h g^(-1) after 500 cycles at a high current density of 2 C.Even with high sulfur loading of 6.05 mg cm^(-2),the Li-S battery still exhibits an areal specific capacity of 2.81 m A h cm^(-2)after 150 cycles.This work paves a new avenue for the rational design of materials for separator modification in high-performance Li-S batteries.
基金supported by the National Key Research and Development Program(Nos.2021YFB2500200,2021YFB2400300)the National Natural Science Foundation of China(No.52177214)the Certificate of China Post-doctoral Science Foundation(No.2019M652634)。
文摘Halide electrolytes in solid-state batteries with excellent oxidative stability and high ionic conductivity have been well reported recently.However,the high-cost rare-earth elements and long duration of highrotation milling procure are the major obstacles.Herein,we have successfully synthesized the low cost Li_(2.25)Zr_(0.75)Fe_(0.25)Cl_(6)electrolyte consisting of abundant elements with comparable Li-ion conductivity in a short milling duration of 4 h.Phase transition of the annealed sample was also carefully investigated.Li Ni_(0.6)Co_(0.2)Mn_(0.2)O_(2)/Li_(2.25)Zr_(0.75)Fe_(0.25)Cl_(6)/Li_(5.5)PS_(4.5)Cl_(1.5)/In-Li batteries using different halide electrolytes were constructed and cycled at different voltage windows.Solid-state battery using Li_(2.25)Zr_(0.75)Fe_(0.25)Cl_(6)electrolyte obtained from long milling duration delivers higher discharge capacities and superior capacity retention than shorter milling time between 3.0 and 4.3 V.It delivers much higher discharge capacity when cycled at elevated temperature(60℃)and suffers fast capacity degradation when the upper cut-off voltage increases to 4.5 V at the same current density.This work provides an efficiency synthesis strategy for halide solid electrolyte and studies its applications in all-solid-state batteries in a wide temperature range.
基金The authors acknowledge the financial support of China University of Mining&Technology(Beijing),Beijing National Laboratory for Condensed Matter Physicsthe National Natural Science Founda-tion of China(Nos.51672029 and 51372271).
文摘Solid-state batteries have been considered as a good choice for substituting traditional batteries with liquid electrolytes because of their high energy density and safe property.However,a little amount of flammable non-aqueous liquid electrolyte or polymer electrolyte is usually required to improve the interfacial contact,which is adverse to safety.Here,a nonflammable gel is prepared by hydrogen-bond interaction and applied as an interfacial layer to improve the performance of solid-state batteries.The prepared multilayer hybrid electrolyte(MHE)composed of gel and CPE shows a wide electrochemical window(5.3 V vs Li/Li+),high ionic transference number(0.57),and ionic conductivity(7.18×10^(−4) S cm^(−1))at room temperature.Thus,the assembled Li symmetric cell with MHE can cycle over 650 h at 0.5 mA cm^(−2) with a lower overpotential of~61 mV.The LiFePO_(4)|MHE|Li cell exhibits a higher discharge capacity of 107.8 mAh g−1 even cycled at 5 C.It also shows superior capacity retention of 96.4%after 1000 cycles at 0.5 C.This work provides a promising strategy for designing high-performance solid-state batteries.
基金the National Natural Science Foundation of China(22279063 and 21835004)the National Key R&D Program of China(2016YFB0901500)+1 种基金Ministry of Education of China(B12015 and IRT13R30)the Haihe Laboratory of Sustainable Chemical Transformations for financial support。
文摘Novel small sulfur heterocyclic quinones(6a,16adihydrobenzo[b]naphtho[2′,3′:5,6][1,4]dithiino[2,3-i]thianthrene-5,7,9,14,16,18-hexaone(4S6Q)and benzo[b]naphtho[2′,3′:5,6][1,4]dithiino[2,3-i]thianthrene-5,9,14,18-tetraone(4S4Q))are developed by molecule structural design method and as cathode for aqueous zincorganic batteries.The conjugated thioether(–S–)bonds as connected units not only improve the conductivity of compounds but also inhibit their dissolution by both extendedπ-conjugated plane and constructed flexible molecular skeleton.Hence,the Zn//4S6Q and Zn//4S4Q batteries exhibit satisfactory electrochemical performance based on 3.5 mol L-1(M)Zn(ClO4)2electrolyte.For instance,the Zn//4S6Q battery obtains 240 and 208.6 mAh g^(-1)of discharge capacity at 150 mA g^(-1)and 30 A g^(-1),respectively.The excellent rate capability is ascribed to the fast reaction kinetics.This system displays a superlong life of 20,000 cycles with no capacity fading at 3 A g^(-1).Additionally,the H+-storage mechanism of the 4S6Q compound is demonstrated by ex situ analyses and density functional theory calculations.Impressively,the battery can normally work at-60℃benefiting from the anti-freezing electrolyte and maintain a high discharge capacity of 201.7 mAh g^(-1),which is 86.2%of discharge capacity at 25℃.The cutting-edge electrochemical performances of these novel compounds make them alternative electrode materials for Zn-organic batteries.
基金supported by the China Postdoctoral Science Foundation(2018 M630340,2019 T120254)the Fundamental Research Funds for the Central University
文摘Aqueous Mg ion batteries(AMIBs)show great potential in energy storage for their advantages of high capacity,abundant resource,and environmental friendliness.However,the development of AMIBs is limited due to the scarcity of suitable anode materials.In this study,a new polymer anode material(PNTAQ)with flower-like nanosheet structure is synthesized for aqueous Mg-Na hybrid-ion battery(AMNHIB).PNTAQ possess carbonyl functional groups which can be oxidized and reduced reversibly in aqueous solution containing alkaline metal ions.PNTAQ displays a discharge specific capacity of 245 mAh g^(−1)at 50 mA g^(−1)in 1 M MgCl_(2)+0.5 M NaCl electrolyte,which is much higher than that in single 1 M MgCl_(2)or 0.5 M NaCl electrolyte.Even cycling at 1000 mA g^(−1)for 1000 times,the capacity retention can still maintain at 87.2%.A full Mg-Na hybrid-ion cell is assembled by employingβ-MnO_(2)as cathode and PNTAQ as anode material,it exhibits a specific capacity of 91.6 mAh g^(−1)at 100 mA g^(−1).The polymer electrode material well maintains its framework structure during the discharge/charge cycling process of the hybrid-ion battery.
基金funded by the Zhengzhou Materials Genome Institute,the National Talents Program of China,and Key Innovation Projects of the Zhengzhou Municipal City of China.
文摘The main bottleneck against industrial utilization of sodium ion batteries(SIBs)is the lack of high-capacity electrodes to rival those of the benchmark lithium ion batteries(LIBs).Here in this work,we have developed an economical method for in situ fabrication of nanocomposites made of crystalline few-layer graphene sheets loaded with ultrafine SnO_(2)nanocrystals,using short exposure of microwave to xerogel of graphene oxide(GO)and tin tetrachloride containing minute catalyzing dispersoids of chemically reduced GO(RGO).The resultant nanocomposites(SnO_(2)@MWG)enabled significantly quickened redox processes as SIB anode,which led to remarkable full anode-specific capacity reaching 538 mAh g^(−1)at 0.05 A g^(−1)(about 1.45 times of the theoretical capacity of graphite for the LIB),in addition to outstanding rate performance over prolonged charge–discharge cycling.Anodes based on the optimized SnO_(2)@MWG delivered stable performance over 2000 cycles even at a high current density of 5 A g^(−1),and capacity retention of over 70.4%was maintained at a high areal loading of 3.4 mg cm^(−2),highly desirable for high energy density SIBs to rival the current benchmark LIBs.
基金the National Research Foundation(NRF)of Korea(No.2022R1A2B5B02002097),funded by the Korea government(MSIT).
文摘Current lithium-ion batteries(LIBs)rely on organic liquid electrolytes that pose significant risks due to their flammability and toxicity.The potential for environmental pollution and explosions resulting from battery damage or fracture is a critical concern.Water-based(aqueous)electrolytes have been receiving attention as an alternative to organic electrolytes.However,a narrow electrochemicalstability window,water decomposition,and the consequent low battery operating voltage and energy density hinder the practical use of aqueous electrolytes.Therefore,developing novel aqueous electrolytes for sustainable,safe,high-performance LIBs remains challenging.This Review first commences by summarizing the roles and requirements of electrolytes–separators and then delineates the progression of aqueous electrolytes for LIBs,encompassing aqueous liquid and gel electrolyte development trends along with detailed principles of the electrolytes.These aqueous electrolytes are progressed based on strategies using superconcentrated salts,concentrated diluents,polymer additives,polymer networks,and artificial passivation layers,which are used for suppressing water decomposition and widening the electrochemical stability window of water of the electrolytes.In addition,this Review discusses potential strategies for the implementation of aqueous Li-metal batteries with improved electrolyte–electrode interfaces.A comprehensive understanding of each strategy in the aqueous system will assist in the design of an aqueous electrolyte and the development of sustainable and safe high-performance batteries.
基金Project supported by the National Natural Science Foundation of China (Grant Nos.11775019 and 62173213)the Natural Science Foundation of Shandong Province,China (Grant No.ZR2011FL009)the Shandong Provincial Science and Technology Support Program of Youth Innovation Team in Colleges (Grant Nos.2019KJN041 and 2020KJN005)。
文摘An open quantum battery(QB)model of a single qubit system charging in a coherent auxiliary bath(CAB)consisting of a series of independent coherent ancillae is considered.According to the collision charging protocol we derive a quantum master equation and obtain the analytical solution of QB in a steady state.We find that the full charging capacity(or the maximal extractable work(MEW))of QB,in the weak QB-ancilla coupling limit,is positively correlated with the coherence magnitude of ancilla.Combining with the numerical simulations we compare with the charging properties of QB at finite coupling strength,such as the MEW,average charging power and the charging efficiency,when considering the bath to be a thermal auxiliary bath(TAB)and a CAB,respectively.We find that when the QB with CAB,in the weak coupling regime,is in fully charging,both its capacity and charging efficiency can go beyond its classical counterpart,and they increase with the increase of coherence magnitude of ancilla.In addition,the MEW of QB in the regime of relative strong coupling and strong coherent magnitude shows the oscillatory behavior with the charging time increasing,and the first peak value can even be larger than the full charging MEW of QB.This also leads to a much larger average charging power than that of QB with TAB in a short-time charging process.These features suggest that with the help of quantum coherence of CAB it becomes feasible to switch the charging schemes between the long-time slow charging protocol with large capacity and high efficiency and the short-time rapid charging protocol with highly charging power only by adjusting the coupling strength of QB-ancilla.This work clearly demonstrates that the quantum coherence of bath can not only serve as the role of“fuel”of QB to be utilized to improve the QB's charging performance but also provide an alternative way to integrate the different charging protocols into a single QB.