Flash boiling atomization(FBA)is a promising approach for enhancing spray atomization,which can generate a fine and more evenly distributed spray by increasing the fuel injection temperature or reducing the ambient pr...Flash boiling atomization(FBA)is a promising approach for enhancing spray atomization,which can generate a fine and more evenly distributed spray by increasing the fuel injection temperature or reducing the ambient pressure.However,when the outlet speed of the nozzle exceeds 400 m/s,investigating high-speed flash boiling atomization(HFBA)becomes quite challenging.This difficulty arises fromthe involvement ofmany complex physical processes and the requirement for a very fine mesh in numerical simulations.In this study,an HFBA model for gasoline direct injection(GDI)is established.This model incorporates primary and secondary atomization,as well as vaporization and boilingmodels,to describe the development process of the flash boiling spray.Compared to lowspeed FBA,these physical processes significantly impact HFBA.In this model,the Eulerian description is utilized for modeling the gas,and the Lagrangian description is applied to model the droplets,which effectively captures the movement of the droplets and avoids excessive mesh in the Eulerian coordinates.Under various conditions,numerical solutions of the Sauter mean diameter(SMD)for GDI show good agreement with experimental data,validating the proposed model’s performance.Simulations based on this HFBA model investigate the influences of fuel injection temperature and ambient pressure on the atomization process.Numerical analyses of the velocity field,temperature field,vapor mass fraction distribution,particle size distribution,and spray penetration length under different superheat degrees reveal that high injection temperature or low ambient pressure significantly affects the formation of small and dispersed droplet distribution.This effect is conducive to the refinement of spray particles and enhances atomization.展开更多
Various enhanced surfaces have been proposed over the years to improve boiling heat transfer. This paper introduces an experimental setup designed for boiling demonstration in the graduate-level Heat Transfer course. ...Various enhanced surfaces have been proposed over the years to improve boiling heat transfer. This paper introduces an experimental setup designed for boiling demonstration in the graduate-level Heat Transfer course. The pool boiling performance of water under atmospheric pressure of 1.025 bar is investigated by using several structured surfaces at heat fluxes of 28 and 35 kW/m<sup>2</sup>. Surfaces with holes, rectangular grooves, and mushroom fins are manufactured by an NC-controlled vertical milling machine. The heat flux versus excess temperature graph is plotted by using thermocouple measurements of water and base temperatures of the boiling vessel. The separation, rise, and growth of individual vapor bubbles from the surface during boiling were recorded with a digital camera. The results for the plain surface are compared to the Rohsenow correlation. The enhancement of heat transfer coefficient (h) ranged between 15% - 44.5% for all structured surfaces. The highest heat transfer coefficient enhancement is observed between 41% - 56.5% for holed surface-3 (405 holes) compared to the plain surface. The excess temperature dropped around 29% - 34% for holed surface-3 (405 holes) compared to the plain surface. The heat transfer coefficient increases as the spacing between channels or holes decreases. While the bubbles on holed and mushroomed surfaces were spherical, the bubbles on the flat and grooved surfaces were observed as formless. The suggested economical test design could be appropriate to keep students focused and participating in the classroom.展开更多
A Zr-Gd alloy with neutron poisoning properties and resistance to boiling concentrated HNO3 corrosion was developed based on a corrosion-resistant Zr-702 alloy to meet the demand for neutron shielding in the closed-lo...A Zr-Gd alloy with neutron poisoning properties and resistance to boiling concentrated HNO3 corrosion was developed based on a corrosion-resistant Zr-702 alloy to meet the demand for neutron shielding in the closed-loop treatment of spent fuel and the nuclear chemical industry.In this study,1 wt.%,3 wt.%,5 wt.%,7 wt.%,and 9 wt.%Zr-Gd alloys were designed and fabricated with Zr-702 as the control element.The electrochemical behavior of the Zr-Gd alloys in boiling concentrated HNO3 was investigated,and the neutron shielding effect on plate thickness and Gd content was simulated.The experimental results demonstrate that the corrosion resistance of the alloy decreased slightly before~7-9 wt.%with increasing Gd content;this is the inflection point of its corrosion resistance.The alloy uniformly dissolved the Gd content that could not be dissolved in the Zr lattice,resulting in numerous micropores on the passivation coating,which deteriorated and accelerated the corrosion rate.The MCNP simulation demonstrated that when the Gd content was increased to 5 wt.%,a 2-mm-thick plate can shield 99.9%neutrons;an alloy with a Gd content≥7 wt.%required only a 1-mm-thick plate,thereby showing that the addition of Gd provides an excellent neutron poisoning effect.Thus,the corrosion resistance and neutron shielding performance of the Zr-Gd alloy can meet the harsh service requirements of the nuclear industry.展开更多
We use the phase field method to track the gas-liquid interface based on the gas-liquid two-phase flow in the pool boiling process,and study the bubble nucleation,growth,deformation,departure and other dynamic behavio...We use the phase field method to track the gas-liquid interface based on the gas-liquid two-phase flow in the pool boiling process,and study the bubble nucleation,growth,deformation,departure and other dynamic behaviors on the heating surface under microgravity.By simulating the correlation between liquid undercooling and bubble dynamics,we find that the bubble growth time increases with the increase of liquid undercooling,but the effect of liquid undercooling on bubble height is not significant.Meanwhile,the gas-liquid-solid three-phase contact angle and the gravity level will also have an effect on the bubble growth time and bubble height.With the increase of the contact angle,the bubble growth time and bubble height when the bubble departs also increase.While the effect of gravity level is on the contrary,the smaller the gravity level is,the larger the bubble height and bubble growth time when the bubble separates.展开更多
Computational fluid dynamics was used and a numerical simulation analysis of boiling heat transfer in microchannels with three depths and three cross-sectional profiles was conducted.The heat transfer coefficient and ...Computational fluid dynamics was used and a numerical simulation analysis of boiling heat transfer in microchannels with three depths and three cross-sectional profiles was conducted.The heat transfer coefficient and bubble generation process of three microchannel structures with a width of 80μm and a depth of 40,60,and 80μm were compared during the boiling process,and the factors influencing bubble generation were studied.A visual test bench was built,and test substrates of different sizes were prepared using a micro-nano laser.During the test,the behavior characteristics of the bubbles on the boiling surface and the temperature change of the heated wall were collected with a high-speed camera and a temperature sensor.It was found that the microchannel with a depth of 80μm had the largest heat transfer coefficient and shortest bubble growth period,the rectangular channel had a larger peak heat transfer coefficient and a lower frequency of bubble occurrence,while the V-shaped channel had the shortest growth period,i.e.,the highest frequency of bubble occurrence,but its heat transfer coefficient was smaller than that of the rectangular channel.展开更多
The boiling heat transfer technology with cavity surfaces can provide higher heat flux under lower wall superheat,which is of great significance for the cooling of electronic chips and microelectromechanical devices.I...The boiling heat transfer technology with cavity surfaces can provide higher heat flux under lower wall superheat,which is of great significance for the cooling of electronic chips and microelectromechanical devices.In this paper,the boiling characteristics of the cavity surfaces are investigated based on the lattice Boltzmann(LB)method,focusing on the effects of cavity shapes,sizes,and heater thermal conductivity on the heat transfer performance.The results show that the triangular cavity has the best boiling performance since it has less residual vapor and higher bubble departure frequency than those of the trapezoidal and rectangular cavities.As the cavity size increases,the enhancement of heat transfer by the cavity mouth is suppressed by the heat accumulation effect at the heater bottom.The liquid rewetting process during bubble departure is the reason for the fluctuation of the space-averaged heat flux,and the heater thermal conductivity determines the fluctuation amplitude.The evaporation of liquid in the cavity with high thermal conductivity walls is more intense,resulting in shorter waiting time and higher bubble departure frequency.展开更多
Phong,a 42-year-old Vietnamese motorcyclist begins his busy day at 5 a.m.In Hanoi,light motorcycles are an important mode of transportation.Countless motorcycles shuttle through the streets and alleys of the city,tran...Phong,a 42-year-old Vietnamese motorcyclist begins his busy day at 5 a.m.In Hanoi,light motorcycles are an important mode of transportation.Countless motorcycles shuttle through the streets and alleys of the city,transporting parcels,goods,and passengers to various destinations.Phong usually works for 12 hours straight with little rest.However,the unprecedented heat waves this summer had often pushed daytime temperatures to above 40 degrees Celsius,making it extremely difficult for Phong to complete his daily routine.Phong prepared a hat,a wet handkerchief,and more drinking water.He even installed a small umbrella above his mobile phone rack to prevent the phone from overheating in the sun because it is his only source of work.Despite all the equipment,he is still worried.“If I suffer heat stroke or anything else,I will be unable to work,”he said.“I can’t afford it.”展开更多
Based on the superposition principle of the nucleate boiling and convective heat transfer terms,a new correlation is developed for flow boiling heat transfer characteristics in helically coiled tubes.The effects of th...Based on the superposition principle of the nucleate boiling and convective heat transfer terms,a new correlation is developed for flow boiling heat transfer characteristics in helically coiled tubes.The effects of the geometric and system parameters on heat transfer characteristics in helically coiled tubes are investigated by collecting large amounts of experimental data and analyzing the heat transfer mechanisms. The existing correlations are divided into two categories,and they are calculated with the experimental data.The Dn factor is introduced to take into account the effect of a complex geometrical structure on flow boiling heat transfer.A new correlation is developed for predicting the flow boiling heat transfer coefficients in the helically coiled tubes,which is validated by the experimental data of R134a flow boiling heat transfer in them;and the average relative error and root mean square error of the new correlation are calculated.The results show that the new correlation agrees well with the experimental data,indicating that the new correlation can be used for predicting flow boiling heat transfer characteristics in the helically coiled tubes.展开更多
Two types of tube bundles are designed,which are,respectively,composed of six tubes arranged in the boiling chamber.The nucleate pool boiling performance of smooth tube bundles and sintered porous surface tube bundles...Two types of tube bundles are designed,which are,respectively,composed of six tubes arranged in the boiling chamber.The nucleate pool boiling performance of smooth tube bundles and sintered porous surface tube bundles with deionized water as a medium are experimentally studied at atmospheric and sub-atmospheric pressures,respectively.The experimental results indicate that the boiling heat transfer coefficients of the two types of tube bundles increase with the increase in pressure under vacuum conditions as they behave under ordinary pressure.As the pressure varies from 10 to 100 kPa,it also can be seen that the heat transfer coefficient of the sintered porous surface tube is increased by 0.2 to 4 times compared with the smooth one under the same operating parameters.In addition,the experimental data show that a definite bundle effect exists in both sintered porous surface tubes and smooth tubes under vacuum conditions.展开更多
Rice husk high boiling solvent lignin （RHL） was prepared by high boiling solvent method, and its characteristics was analyzed by using chemical composition analysis, infrared spectroscopy, and ^1H-NMR and ^13C-NMR s...Rice husk high boiling solvent lignin （RHL） was prepared by high boiling solvent method, and its characteristics was analyzed by using chemical composition analysis, infrared spectroscopy, and ^1H-NMR and ^13C-NMR spectroscopy. The optimum prepared condition was that the rice husk with 70%-90% aqueous solution of 1, 4-butanediol was mixed with autoclave, under a certain weight ratio of solid raw material and solvent, heated to 200-220℃ for 1.0-3.0 h, then water-insoluble RHL was separated from the liquor reaction mixture by water precipitation. Results suggested that the lower digestion temperature and concentration of 1,4-butanediol were both unfavorable for extracting lignin. Chemical weight-average molecular weight of RHL was 1939 g·mol^-1, and the residual polysaccharide content was 5.12%. The ^1H-NMR spectra of RHL showed the relative intensity ratio, aliphatic over aromatic methoxyl groups, situated at 3.5-3.8 and 3.8-4.0 ppm, respectively. The results from ^13C-NMR spectra showed that β-O-4 bond and β-5 carbon-carbon linkage were the major linkages between RHL units. The C9-formula of RHL was calculated by the experiment data.展开更多
Heat transfer coefficients in nucleate pool boiling were measured on a horizontal copper surface for refrigerants, HFC-134a, HFC-32, and HFC-125, their binary and ternary mixtures under saturated conditions at 0.9MPa....Heat transfer coefficients in nucleate pool boiling were measured on a horizontal copper surface for refrigerants, HFC-134a, HFC-32, and HFC-125, their binary and ternary mixtures under saturated conditions at 0.9MPa. Compared to pure components, both binary and ternary mixtures showed lower heat transfer coefficients.This deterioration was more pronounced as heat flux was increased. Experimental data were compared with some empirical and semi-empirical correlations available in literature. For binary mixture, the accuracy of the correlations varied considerably with mixtures and the heat flux. Experimental data for HFC-32/134a/125 were also compared with available correlated equation obtained by Thome. For ternary mixture, the boiling range of binary mixture composed by the pure fluids with the lowest and the medium boiling points, and their concentration difference had important effects on boiling heat transfer coefficients.展开更多
The experiments of the onset of nucleate boiling using R134a as working fluid were conducted in vertical helically-coiled tubes. The experiments were carried out with a range of pressure from 450 to 850 kPa, inlet sub...The experiments of the onset of nucleate boiling using R134a as working fluid were conducted in vertical helically-coiled tubes. The experiments were carried out with a range of pressure from 450 to 850 kPa, inlet subcooling from 4.7 to 15.0℃, heat flux from 0.11 to 8.9 kW/m2 and mass flux from 218. 2 to 443. 7 kg/（ m2 · s ）. The heat flux, superheat and temperature undershoot at the ONB are analyzed in vertical helically-coiled tubes. Also, the effects of mass flux, system pressure, inlet subcooling and geometric parameters on the ONB are studied. The results demonstrate that the inception heat flux and superheat increase with increasing mass flux and inlet subcooling, but decrease with increasing system pressure and helix diameter. The pitch of the helical coil has a slight effect on the wall superheat and heat flux at the ONB. The correlation of heat flux at the ONB of subcooled flow boiling in helical coil is developed based on the experimental data, and it shows a good agreement with the experimental data.展开更多
The main drawback in the utilization of geothermal resources arises from the precipitation of secondary minerals within wells, pipelines, steam separators, turbines and other surface equipment in form of scales. Scale...The main drawback in the utilization of geothermal resources arises from the precipitation of secondary minerals within wells, pipelines, steam separators, turbines and other surface equipment in form of scales. Scale formation is an outcome of the alteration of various rocks dissolved in geothermal fluids that find their way into a reservoir. Once geothermal fluids ascend to the surface, hydrostatic pressure decreases toward a phase separation level that permits the dissolved gases such as CO<sub>2</sub>, H<sub>2</sub>S and H<sub>2</sub>, and steam to separate from the liquid phase by “boiling”. Stripping of these volatiles may increase fluid pH, leading to precipitation and deposition of secondary minerals. The study sought to establish the relationship between water-rock interaction and secondary mineral precipitates at the surface and deep fluid at different temperatures during depressurisation boiling and cooling. Samples were collected from selected Olkaria wells;OW-38A, OW-910 and OW-910A. The analysis of the results outlined deep fluid Alkali-Chloride waters and surface steam-heated Alkali-Bicarbonate and acidic Sulphate-Chloride waters. Various models suggested adiabatic boiling, conductive cooling and possible mixing and dilution in the wells. Hydrothermal alteration minerals were found to be in equilibrium with the geothermal fluids at varying temperatures, and the secondary minerals controlled the chemistry of the reservoir. Silica-saturated solutions precipitated silica in OW-910 and OW-910A, which may have resulted from rapid cooling following mixing with cold surface water.展开更多
A new position group contribution model is proposed for the estimation of normal boiling data of organic compounds involving a carbon chain from C2 to C18.The characteristic of this method is the use of position distr...A new position group contribution model is proposed for the estimation of normal boiling data of organic compounds involving a carbon chain from C2 to C18.The characteristic of this method is the use of position distribution function.It could distinguish most of isomers that include cis-or trans-structure from organic compounds.Contributions for hydrocarbons and hydrocarbon derivatives containing oxygen,nitrogen,chlorine,bromine and sulfur,are given.Compared with the predictions,results made use of the most common existing group contribution methods,the overall average absolute difference of boiling point predictions of 417 organic compounds is 4.2 K;and the average absolute percent derivation is 1.0%,which is compared with 12.3 K and 3.2% with the method of Joback,12.1 K and 3.1% with the method of Constantinou-Gani.This new position contribution groups method is not only much more accurate but also has the advantages of simplicity and stability.展开更多
The molecular transformations of carboxylic acids in heavy acidic SL crude before and after true boiling point distillation were examined by ultra-high resolution negative-ion electrospray ionization(ESI) Fourier tran...The molecular transformations of carboxylic acids in heavy acidic SL crude before and after true boiling point distillation were examined by ultra-high resolution negative-ion electrospray ionization(ESI) Fourier transform ion cyclotron resonance mass spectrometry(FT-ICR MS). The acid class(heteroatom number), type(z numbers) and carbon number distributions were positively characterized. It was found out that the total acid number(TAN) of SL crude decreased after true boiling point distillation, and the abundance of O2 class in mass spectra was also found to be reduced from 67.6% to 34.5% in SL TBP mixed crude as measured by MS spectra, indicating to a potential carboxylic acid decomposition. However, it was interesting that the carboxylic acids type distribution in both oils was almost the same although their relative abundance in SL TBP mixed crude turned to be much lower, suggesting that various petroleum carboxylic acid types have the similar thermal decomposition reaction behavior. Furthermore, for each O2 type of acids in SL TBP mixed crude, the abundance of carboxylic acids with carbon number higher than 35 was reduced greatly, especially for those with carbon number higher than 60, the mass peaks of which were nearly totally removed, indicating that the large carboxylic acid molecules in heavy fractions decomposed more significantly because of longer heating time during the true boiling point distillation process. As a result, the reduction of TAN may be caused by the thermal decomposition of carboxylic acids especially those with high carbon number, suggesting that quick distillation or much lower pressure is required to avoid the thermal decomposition.展开更多
This paper proposed a new experimental rig of testing flow boiling heat transfer of refrigerant and lubricant oil mixture. The quantity of oil in the test section can be controlled and regulated conveniently and accur...This paper proposed a new experimental rig of testing flow boiling heat transfer of refrigerant and lubricant oil mixture. The quantity of oil in the test section can be controlled and regulated conveniently and accurately by connecting separate lubricant oil circuit with test section in parallel. It was built up by retrofitting a multiple air-conditioner and installing three oil-separators in serials at the compressor outlet. And so the lubricant oil in the discharged refrigerant gas of compressor can be removed completely.The refrigerant flow rate through test section can be bypassed by the by-path circuit of indoor unit.This experimental rig has advantages such as on-line and continuous oil injection, short time of obtaining stability, flexible operation, simple control, which lead to high efficiency in the research of flow boiling heat transfer of refrigerant and lubricant oil mixture.展开更多
Fouling of heat transfer surfaces during subcooled flow boiling is a frequent engineering problem in process industries. It has been generally observed that the deposits in such industrial systems consist mainly of ca...Fouling of heat transfer surfaces during subcooled flow boiling is a frequent engineering problem in process industries. It has been generally observed that the deposits in such industrial systems consist mainly of calcium carbonate （CaCO3）, which has inverse solubility characteristics. This investigation focused on the mechanism to control deposition and the morphology of crystalline deposits. A series of experiments were carried out at different surface and bulk temperatures, fluid velocities and salt ion concentrations. It is shown that the deposition rate is controlled by different mechanism in the range of experimental parameters, depending on salt ion concentration. At higher ion concentration, the fouling rate increases linearly with surface temperature and the effect of flow velocity on deposition rate is quite strong, suggesting that mass diffusion controls the fouling process. On the contrary, at lower ion concentration, the fouling rate increases exponentially with surface temperature and is independent of the velocity, illustrating that surface reaction controls the fouling process. By analysis of the morphology of scale, two types of crystal （calcite and aragonite） are formed. The lower the temperature and ion concentration, the longer the induction period and the higher the percentage of calcite nreciDitated.展开更多
Prediction of primary quality variables in real time with adaptation capability for varying process conditions is a critical task in process industries.This article focuses on the development of non-linear adaptive so...Prediction of primary quality variables in real time with adaptation capability for varying process conditions is a critical task in process industries.This article focuses on the development of non-linear adaptive soft sensors for prediction of naphtha initial boiling point(IBP)and end boiling point(EBP)in crude distillation unit.In this work,adaptive inferential sensors with linear and non-linear local models are reported based on recursive just in time learning(JITL)approach.The different types of local models designed are locally weighted regression(LWR),multiple linear regression(MLR),partial least squares regression(PLS)and support vector regression(SVR).In addition to model development,the effect of relevant dataset size on model prediction accuracy and model computation time is also investigated.Results show that the JITL model based on support vector regression with iterative single data algorithm optimization(ISDA)local model(JITL-SVR:ISDA)yielded best prediction accuracy in reasonable computation time.展开更多
The surfactant additive octadecylamine (ODA) was used to enhance the flow boiling heat transfer of water in vertical copper tube, and the effects of the aqueous solution properties, mass fraction of ODA, mass flux and...The surfactant additive octadecylamine (ODA) was used to enhance the flow boiling heat transfer of water in vertical copper tube, and the effects of the aqueous solution properties, mass fraction of ODA, mass flux and heat flux etc. on flow boiling heat transfer were investigated. In order to analyze the mechanism of enhancement on boiling heat transfer with ODA, the copper surface was detected by XPS, and the diagram of binding energy was obtained. The results show that ODA can be adsorbed on the surface of the copper wall, and affects the properties of the heating surfaces and enhances the flow boiling heat transfer of water. Only in low heat flux and in a suitable range of concentration, can ODA aqueous solution enhance flow boiling heat transfer, and the suitable mass fraction of ODA is in the range of 1×10 -5 5×10 -5 . In addition, compared with water, ODA aqueous solution does not increase the flow drag under the same experimental conditions.展开更多
Multiple size group （MUSIG） model combined with a threedimensional twofluid model were em ployed to predict subcooled boiling flow of liquid nitrogen in a vertical upward tube. Based on the mechanism of boiling heat...Multiple size group （MUSIG） model combined with a threedimensional twofluid model were em ployed to predict subcooled boiling flow of liquid nitrogen in a vertical upward tube. Based on the mechanism of boiling heat transfer, some important bubble model parameters were amended to be applicable to the modeling of liquid nitrogen. The distribution of different discrete bubble classes was demonstrated numerically and the distribu tion patterns of void fraction in the wallheated tube were analyzed. It was found that the average void fraction in creases nonlinearly along the axial direction with wall heat flux and it decreases with inlet mass flow rate and sub cooled temperature. The local void fraction exhibited a Ushape distribution in the radial direction. The partition of the wall heat flux along the tube was obtained. The results showed that heat flux consumed on evaporation is the leading part of surface heat transfer at the rear region of subcooled boiling. The turning point in the pressure drop curve reflects the instability of bubbly flow. Good agreement was achieved on the local heat transfer coefficient aalnst experimental measurements, which demonstrated the accuracy of the numerical model.展开更多
基金supported by the National Natural Science Foundation of China(Project Nos.12272270,11972261).
文摘Flash boiling atomization(FBA)is a promising approach for enhancing spray atomization,which can generate a fine and more evenly distributed spray by increasing the fuel injection temperature or reducing the ambient pressure.However,when the outlet speed of the nozzle exceeds 400 m/s,investigating high-speed flash boiling atomization(HFBA)becomes quite challenging.This difficulty arises fromthe involvement ofmany complex physical processes and the requirement for a very fine mesh in numerical simulations.In this study,an HFBA model for gasoline direct injection(GDI)is established.This model incorporates primary and secondary atomization,as well as vaporization and boilingmodels,to describe the development process of the flash boiling spray.Compared to lowspeed FBA,these physical processes significantly impact HFBA.In this model,the Eulerian description is utilized for modeling the gas,and the Lagrangian description is applied to model the droplets,which effectively captures the movement of the droplets and avoids excessive mesh in the Eulerian coordinates.Under various conditions,numerical solutions of the Sauter mean diameter(SMD)for GDI show good agreement with experimental data,validating the proposed model’s performance.Simulations based on this HFBA model investigate the influences of fuel injection temperature and ambient pressure on the atomization process.Numerical analyses of the velocity field,temperature field,vapor mass fraction distribution,particle size distribution,and spray penetration length under different superheat degrees reveal that high injection temperature or low ambient pressure significantly affects the formation of small and dispersed droplet distribution.This effect is conducive to the refinement of spray particles and enhances atomization.
文摘Various enhanced surfaces have been proposed over the years to improve boiling heat transfer. This paper introduces an experimental setup designed for boiling demonstration in the graduate-level Heat Transfer course. The pool boiling performance of water under atmospheric pressure of 1.025 bar is investigated by using several structured surfaces at heat fluxes of 28 and 35 kW/m<sup>2</sup>. Surfaces with holes, rectangular grooves, and mushroom fins are manufactured by an NC-controlled vertical milling machine. The heat flux versus excess temperature graph is plotted by using thermocouple measurements of water and base temperatures of the boiling vessel. The separation, rise, and growth of individual vapor bubbles from the surface during boiling were recorded with a digital camera. The results for the plain surface are compared to the Rohsenow correlation. The enhancement of heat transfer coefficient (h) ranged between 15% - 44.5% for all structured surfaces. The highest heat transfer coefficient enhancement is observed between 41% - 56.5% for holed surface-3 (405 holes) compared to the plain surface. The excess temperature dropped around 29% - 34% for holed surface-3 (405 holes) compared to the plain surface. The heat transfer coefficient increases as the spacing between channels or holes decreases. While the bubbles on holed and mushroomed surfaces were spherical, the bubbles on the flat and grooved surfaces were observed as formless. The suggested economical test design could be appropriate to keep students focused and participating in the classroom.
基金supported by the National Natural Science Foundation of China (Nos.52201021 and 52101099)Key Research and Development Program of Shaanxi (2021GY-249,2021GY-233)+1 种基金Natural Science Basic Research Program of Shaanxi (No.2020JC-50)Shaanxi Provincial Natural Science Youth Foundation (2022JQ-410).
文摘A Zr-Gd alloy with neutron poisoning properties and resistance to boiling concentrated HNO3 corrosion was developed based on a corrosion-resistant Zr-702 alloy to meet the demand for neutron shielding in the closed-loop treatment of spent fuel and the nuclear chemical industry.In this study,1 wt.%,3 wt.%,5 wt.%,7 wt.%,and 9 wt.%Zr-Gd alloys were designed and fabricated with Zr-702 as the control element.The electrochemical behavior of the Zr-Gd alloys in boiling concentrated HNO3 was investigated,and the neutron shielding effect on plate thickness and Gd content was simulated.The experimental results demonstrate that the corrosion resistance of the alloy decreased slightly before~7-9 wt.%with increasing Gd content;this is the inflection point of its corrosion resistance.The alloy uniformly dissolved the Gd content that could not be dissolved in the Zr lattice,resulting in numerous micropores on the passivation coating,which deteriorated and accelerated the corrosion rate.The MCNP simulation demonstrated that when the Gd content was increased to 5 wt.%,a 2-mm-thick plate can shield 99.9%neutrons;an alloy with a Gd content≥7 wt.%required only a 1-mm-thick plate,thereby showing that the addition of Gd provides an excellent neutron poisoning effect.Thus,the corrosion resistance and neutron shielding performance of the Zr-Gd alloy can meet the harsh service requirements of the nuclear industry.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.52161002,51661020,and11364024)the Postdoctoral Science Foundation of China(Grant No.2014M560371)the Funds for Distinguished Young Scientists of Lanzhou University of Technology of China(Grant No.J201304)。
文摘We use the phase field method to track the gas-liquid interface based on the gas-liquid two-phase flow in the pool boiling process,and study the bubble nucleation,growth,deformation,departure and other dynamic behaviors on the heating surface under microgravity.By simulating the correlation between liquid undercooling and bubble dynamics,we find that the bubble growth time increases with the increase of liquid undercooling,but the effect of liquid undercooling on bubble height is not significant.Meanwhile,the gas-liquid-solid three-phase contact angle and the gravity level will also have an effect on the bubble growth time and bubble height.With the increase of the contact angle,the bubble growth time and bubble height when the bubble departs also increase.While the effect of gravity level is on the contrary,the smaller the gravity level is,the larger the bubble height and bubble growth time when the bubble separates.
基金supported by the National Natural Science Foundation of China Youth Program(Grant No.51905328).
文摘Computational fluid dynamics was used and a numerical simulation analysis of boiling heat transfer in microchannels with three depths and three cross-sectional profiles was conducted.The heat transfer coefficient and bubble generation process of three microchannel structures with a width of 80μm and a depth of 40,60,and 80μm were compared during the boiling process,and the factors influencing bubble generation were studied.A visual test bench was built,and test substrates of different sizes were prepared using a micro-nano laser.During the test,the behavior characteristics of the bubbles on the boiling surface and the temperature change of the heated wall were collected with a high-speed camera and a temperature sensor.It was found that the microchannel with a depth of 80μm had the largest heat transfer coefficient and shortest bubble growth period,the rectangular channel had a larger peak heat transfer coefficient and a lower frequency of bubble occurrence,while the V-shaped channel had the shortest growth period,i.e.,the highest frequency of bubble occurrence,but its heat transfer coefficient was smaller than that of the rectangular channel.
基金Project supported by the National Natural Science Foundation of China(Nos.11872083,12172017,12202021)。
文摘The boiling heat transfer technology with cavity surfaces can provide higher heat flux under lower wall superheat,which is of great significance for the cooling of electronic chips and microelectromechanical devices.In this paper,the boiling characteristics of the cavity surfaces are investigated based on the lattice Boltzmann(LB)method,focusing on the effects of cavity shapes,sizes,and heater thermal conductivity on the heat transfer performance.The results show that the triangular cavity has the best boiling performance since it has less residual vapor and higher bubble departure frequency than those of the trapezoidal and rectangular cavities.As the cavity size increases,the enhancement of heat transfer by the cavity mouth is suppressed by the heat accumulation effect at the heater bottom.The liquid rewetting process during bubble departure is the reason for the fluctuation of the space-averaged heat flux,and the heater thermal conductivity determines the fluctuation amplitude.The evaporation of liquid in the cavity with high thermal conductivity walls is more intense,resulting in shorter waiting time and higher bubble departure frequency.
文摘Phong,a 42-year-old Vietnamese motorcyclist begins his busy day at 5 a.m.In Hanoi,light motorcycles are an important mode of transportation.Countless motorcycles shuttle through the streets and alleys of the city,transporting parcels,goods,and passengers to various destinations.Phong usually works for 12 hours straight with little rest.However,the unprecedented heat waves this summer had often pushed daytime temperatures to above 40 degrees Celsius,making it extremely difficult for Phong to complete his daily routine.Phong prepared a hat,a wet handkerchief,and more drinking water.He even installed a small umbrella above his mobile phone rack to prevent the phone from overheating in the sun because it is his only source of work.Despite all the equipment,he is still worried.“If I suffer heat stroke or anything else,I will be unable to work,”he said.“I can’t afford it.”
基金The National Natural Science Foundation of China(No.50776055,51076084)
文摘Based on the superposition principle of the nucleate boiling and convective heat transfer terms,a new correlation is developed for flow boiling heat transfer characteristics in helically coiled tubes.The effects of the geometric and system parameters on heat transfer characteristics in helically coiled tubes are investigated by collecting large amounts of experimental data and analyzing the heat transfer mechanisms. The existing correlations are divided into two categories,and they are calculated with the experimental data.The Dn factor is introduced to take into account the effect of a complex geometrical structure on flow boiling heat transfer.A new correlation is developed for predicting the flow boiling heat transfer coefficients in the helically coiled tubes,which is validated by the experimental data of R134a flow boiling heat transfer in them;and the average relative error and root mean square error of the new correlation are calculated.The results show that the new correlation agrees well with the experimental data,indicating that the new correlation can be used for predicting flow boiling heat transfer characteristics in the helically coiled tubes.
基金The National Natural Science Foundation of China(No.50706012)
文摘Two types of tube bundles are designed,which are,respectively,composed of six tubes arranged in the boiling chamber.The nucleate pool boiling performance of smooth tube bundles and sintered porous surface tube bundles with deionized water as a medium are experimentally studied at atmospheric and sub-atmospheric pressures,respectively.The experimental results indicate that the boiling heat transfer coefficients of the two types of tube bundles increase with the increase in pressure under vacuum conditions as they behave under ordinary pressure.As the pressure varies from 10 to 100 kPa,it also can be seen that the heat transfer coefficient of the sintered porous surface tube is increased by 0.2 to 4 times compared with the smooth one under the same operating parameters.In addition,the experimental data show that a definite bundle effect exists in both sintered porous surface tubes and smooth tubes under vacuum conditions.
基金This study was sponsored by the Research Funding for Key Laboratory of Cellulose and Ligno cellulosics Chemistry, Guangzhou Institute of Chemistry, Chinese Academy of Sciences (No. LCLC-2004-158)the National Natural Science Foundation of Fujian(No. Z0513015)
文摘Rice husk high boiling solvent lignin （RHL） was prepared by high boiling solvent method, and its characteristics was analyzed by using chemical composition analysis, infrared spectroscopy, and ^1H-NMR and ^13C-NMR spectroscopy. The optimum prepared condition was that the rice husk with 70%-90% aqueous solution of 1, 4-butanediol was mixed with autoclave, under a certain weight ratio of solid raw material and solvent, heated to 200-220℃ for 1.0-3.0 h, then water-insoluble RHL was separated from the liquor reaction mixture by water precipitation. Results suggested that the lower digestion temperature and concentration of 1,4-butanediol were both unfavorable for extracting lignin. Chemical weight-average molecular weight of RHL was 1939 g·mol^-1, and the residual polysaccharide content was 5.12%. The ^1H-NMR spectra of RHL showed the relative intensity ratio, aliphatic over aromatic methoxyl groups, situated at 3.5-3.8 and 3.8-4.0 ppm, respectively. The results from ^13C-NMR spectra showed that β-O-4 bond and β-5 carbon-carbon linkage were the major linkages between RHL units. The C9-formula of RHL was calculated by the experiment data.
基金Century Programme of Chinese Academy of Sciences.
文摘Heat transfer coefficients in nucleate pool boiling were measured on a horizontal copper surface for refrigerants, HFC-134a, HFC-32, and HFC-125, their binary and ternary mixtures under saturated conditions at 0.9MPa. Compared to pure components, both binary and ternary mixtures showed lower heat transfer coefficients.This deterioration was more pronounced as heat flux was increased. Experimental data were compared with some empirical and semi-empirical correlations available in literature. For binary mixture, the accuracy of the correlations varied considerably with mixtures and the heat flux. Experimental data for HFC-32/134a/125 were also compared with available correlated equation obtained by Thome. For ternary mixture, the boiling range of binary mixture composed by the pure fluids with the lowest and the medium boiling points, and their concentration difference had important effects on boiling heat transfer coefficients.
基金The National Natural Science Foundation of China(No.50776055,51076084)the Natural Science Foundation of Shandong Province(No.ZR2016YL005)
文摘The experiments of the onset of nucleate boiling using R134a as working fluid were conducted in vertical helically-coiled tubes. The experiments were carried out with a range of pressure from 450 to 850 kPa, inlet subcooling from 4.7 to 15.0℃, heat flux from 0.11 to 8.9 kW/m2 and mass flux from 218. 2 to 443. 7 kg/（ m2 · s ）. The heat flux, superheat and temperature undershoot at the ONB are analyzed in vertical helically-coiled tubes. Also, the effects of mass flux, system pressure, inlet subcooling and geometric parameters on the ONB are studied. The results demonstrate that the inception heat flux and superheat increase with increasing mass flux and inlet subcooling, but decrease with increasing system pressure and helix diameter. The pitch of the helical coil has a slight effect on the wall superheat and heat flux at the ONB. The correlation of heat flux at the ONB of subcooled flow boiling in helical coil is developed based on the experimental data, and it shows a good agreement with the experimental data.
文摘The main drawback in the utilization of geothermal resources arises from the precipitation of secondary minerals within wells, pipelines, steam separators, turbines and other surface equipment in form of scales. Scale formation is an outcome of the alteration of various rocks dissolved in geothermal fluids that find their way into a reservoir. Once geothermal fluids ascend to the surface, hydrostatic pressure decreases toward a phase separation level that permits the dissolved gases such as CO<sub>2</sub>, H<sub>2</sub>S and H<sub>2</sub>, and steam to separate from the liquid phase by “boiling”. Stripping of these volatiles may increase fluid pH, leading to precipitation and deposition of secondary minerals. The study sought to establish the relationship between water-rock interaction and secondary mineral precipitates at the surface and deep fluid at different temperatures during depressurisation boiling and cooling. Samples were collected from selected Olkaria wells;OW-38A, OW-910 and OW-910A. The analysis of the results outlined deep fluid Alkali-Chloride waters and surface steam-heated Alkali-Bicarbonate and acidic Sulphate-Chloride waters. Various models suggested adiabatic boiling, conductive cooling and possible mixing and dilution in the wells. Hydrothermal alteration minerals were found to be in equilibrium with the geothermal fluids at varying temperatures, and the secondary minerals controlled the chemistry of the reservoir. Silica-saturated solutions precipitated silica in OW-910 and OW-910A, which may have resulted from rapid cooling following mixing with cold surface water.
文摘A new position group contribution model is proposed for the estimation of normal boiling data of organic compounds involving a carbon chain from C2 to C18.The characteristic of this method is the use of position distribution function.It could distinguish most of isomers that include cis-or trans-structure from organic compounds.Contributions for hydrocarbons and hydrocarbon derivatives containing oxygen,nitrogen,chlorine,bromine and sulfur,are given.Compared with the predictions,results made use of the most common existing group contribution methods,the overall average absolute difference of boiling point predictions of 417 organic compounds is 4.2 K;and the average absolute percent derivation is 1.0%,which is compared with 12.3 K and 3.2% with the method of Joback,12.1 K and 3.1% with the method of Constantinou-Gani.This new position contribution groups method is not only much more accurate but also has the advantages of simplicity and stability.
基金financially supported by the National Key Basic Research Development Program "973" Project (2006CB202501)
文摘The molecular transformations of carboxylic acids in heavy acidic SL crude before and after true boiling point distillation were examined by ultra-high resolution negative-ion electrospray ionization(ESI) Fourier transform ion cyclotron resonance mass spectrometry(FT-ICR MS). The acid class(heteroatom number), type(z numbers) and carbon number distributions were positively characterized. It was found out that the total acid number(TAN) of SL crude decreased after true boiling point distillation, and the abundance of O2 class in mass spectra was also found to be reduced from 67.6% to 34.5% in SL TBP mixed crude as measured by MS spectra, indicating to a potential carboxylic acid decomposition. However, it was interesting that the carboxylic acids type distribution in both oils was almost the same although their relative abundance in SL TBP mixed crude turned to be much lower, suggesting that various petroleum carboxylic acid types have the similar thermal decomposition reaction behavior. Furthermore, for each O2 type of acids in SL TBP mixed crude, the abundance of carboxylic acids with carbon number higher than 35 was reduced greatly, especially for those with carbon number higher than 60, the mass peaks of which were nearly totally removed, indicating that the large carboxylic acid molecules in heavy fractions decomposed more significantly because of longer heating time during the true boiling point distillation process. As a result, the reduction of TAN may be caused by the thermal decomposition of carboxylic acids especially those with high carbon number, suggesting that quick distillation or much lower pressure is required to avoid the thermal decomposition.
文摘This paper proposed a new experimental rig of testing flow boiling heat transfer of refrigerant and lubricant oil mixture. The quantity of oil in the test section can be controlled and regulated conveniently and accurately by connecting separate lubricant oil circuit with test section in parallel. It was built up by retrofitting a multiple air-conditioner and installing three oil-separators in serials at the compressor outlet. And so the lubricant oil in the discharged refrigerant gas of compressor can be removed completely.The refrigerant flow rate through test section can be bypassed by the by-path circuit of indoor unit.This experimental rig has advantages such as on-line and continuous oil injection, short time of obtaining stability, flexible operation, simple control, which lead to high efficiency in the research of flow boiling heat transfer of refrigerant and lubricant oil mixture.
基金Supported by the Special Funds for Major State Basic Research Projects of China (G2000026304)
文摘Fouling of heat transfer surfaces during subcooled flow boiling is a frequent engineering problem in process industries. It has been generally observed that the deposits in such industrial systems consist mainly of calcium carbonate （CaCO3）, which has inverse solubility characteristics. This investigation focused on the mechanism to control deposition and the morphology of crystalline deposits. A series of experiments were carried out at different surface and bulk temperatures, fluid velocities and salt ion concentrations. It is shown that the deposition rate is controlled by different mechanism in the range of experimental parameters, depending on salt ion concentration. At higher ion concentration, the fouling rate increases linearly with surface temperature and the effect of flow velocity on deposition rate is quite strong, suggesting that mass diffusion controls the fouling process. On the contrary, at lower ion concentration, the fouling rate increases exponentially with surface temperature and is independent of the velocity, illustrating that surface reaction controls the fouling process. By analysis of the morphology of scale, two types of crystal （calcite and aragonite） are formed. The lower the temperature and ion concentration, the longer the induction period and the higher the percentage of calcite nreciDitated.
文摘Prediction of primary quality variables in real time with adaptation capability for varying process conditions is a critical task in process industries.This article focuses on the development of non-linear adaptive soft sensors for prediction of naphtha initial boiling point(IBP)and end boiling point(EBP)in crude distillation unit.In this work,adaptive inferential sensors with linear and non-linear local models are reported based on recursive just in time learning(JITL)approach.The different types of local models designed are locally weighted regression(LWR),multiple linear regression(MLR),partial least squares regression(PLS)and support vector regression(SVR).In addition to model development,the effect of relevant dataset size on model prediction accuracy and model computation time is also investigated.Results show that the JITL model based on support vector regression with iterative single data algorithm optimization(ISDA)local model(JITL-SVR:ISDA)yielded best prediction accuracy in reasonable computation time.
基金The Natural Science Foundation of Tianjin(No.94220)
文摘The surfactant additive octadecylamine (ODA) was used to enhance the flow boiling heat transfer of water in vertical copper tube, and the effects of the aqueous solution properties, mass fraction of ODA, mass flux and heat flux etc. on flow boiling heat transfer were investigated. In order to analyze the mechanism of enhancement on boiling heat transfer with ODA, the copper surface was detected by XPS, and the diagram of binding energy was obtained. The results show that ODA can be adsorbed on the surface of the copper wall, and affects the properties of the heating surfaces and enhances the flow boiling heat transfer of water. Only in low heat flux and in a suitable range of concentration, can ODA aqueous solution enhance flow boiling heat transfer, and the suitable mass fraction of ODA is in the range of 1×10 -5 5×10 -5 . In addition, compared with water, ODA aqueous solution does not increase the flow drag under the same experimental conditions.
基金Supported by the National Natural Science Foundation of China （51106119, 81100707）, the Fundamental Research Funds for the Central University of China, Doctoral Fund of Ministry of Education （20110201120052） and the National Science and Technology Sur0orting Item （2012BAA08B03）.
文摘Multiple size group （MUSIG） model combined with a threedimensional twofluid model were em ployed to predict subcooled boiling flow of liquid nitrogen in a vertical upward tube. Based on the mechanism of boiling heat transfer, some important bubble model parameters were amended to be applicable to the modeling of liquid nitrogen. The distribution of different discrete bubble classes was demonstrated numerically and the distribu tion patterns of void fraction in the wallheated tube were analyzed. It was found that the average void fraction in creases nonlinearly along the axial direction with wall heat flux and it decreases with inlet mass flow rate and sub cooled temperature. The local void fraction exhibited a Ushape distribution in the radial direction. The partition of the wall heat flux along the tube was obtained. The results showed that heat flux consumed on evaporation is the leading part of surface heat transfer at the rear region of subcooled boiling. The turning point in the pressure drop curve reflects the instability of bubbly flow. Good agreement was achieved on the local heat transfer coefficient aalnst experimental measurements, which demonstrated the accuracy of the numerical model.
