The Mg isotopic compositions of siliciclastic components(δ^(26)Mg_(sili))of sediments and sedimentary rocks have been commonly used to constrain the intensity of continental weathering,based on observations of,(1)an ...The Mg isotopic compositions of siliciclastic components(δ^(26)Mg_(sili))of sediments and sedimentary rocks have been commonly used to constrain the intensity of continental weathering,based on observations of,(1)an upward enrichment of26Mg in modern weathering profiles,(2)preferential uptake of26Mg in soil clays,and(3)general positive correlations between weathering intensities andδ^(26)Mg_(sili)values.However,not all weathering profiles display an upward increase ofδ^(26)Mg_(sili),and not all soil clays enrich in26Mg,complicating the interpretations ofδ^(26)Mg_(sili)data of sediments and sedimentary rocks.To further explore the controls ofδ^(26)Mg_(sili)of sediments and sedimentary rocks,here we measuredδ^(26)Mg_(sili),mineralogical compositions and major element compositions of deep sea sediments from South China Sea(SCS)and carbonate rock samples from two late Paleozoic sections in South China.Carbonate samples show decreasing trends of both normalized Mg concentration(Mgnorm)andδ^(26)Mg_(sili)values with the increase of weathering intensity,while SCS sediments samples do not show any correlation between Mgnormorδ^(26)Mg_(sili)values and weathering intensity.A three-stages weathering model is developed to explain the observed Mgnorm andδ^(26)Mg_(sili)data.In the new model,weathering can be divided into three stages,(1)the preliminary weathering stage characterized by dissolution of primary minerals and formation of secondary clay minerals in saprolite,(2)the transitional stage with massive vermiculite and chlorite formation on the bottom of soil,and(3)the advanced stage showing dissolution of vermiculite and chlorite in the top of soil.The new model explains anδ^(26)Mg_(sili)increase and Mgnormdecrease with an increase weathering intensity in preliminary weathering stage and decrease of Mgnormandδ^(26)Mg_(sili)with increase weathering intensity in advanced weathering stage.The revised weathering model warrants the application of Mg isotope in the study of continental weathering in deep time.展开更多
This study is thefirst attempt to assess the nature of the soil,especially on the western side of the Porali Plain in Balochistan;a new emerging agriculture hub,using weathering and pollution indices supplemented by mu...This study is thefirst attempt to assess the nature of the soil,especially on the western side of the Porali Plain in Balochistan;a new emerging agriculture hub,using weathering and pollution indices supplemented by multi-variate analysis based on geochemical data.The outcomes of this study are expected to help farmers in soil manage-ment and selecting suitable crops for the region.Twenty-five soil samples were collected,mainly from the arable land of the Porali Plain.After drying and coning-quarter-ing,soil samples were analyzed for major and trace ele-ments using the XRF technique;sieving and hydrometric methods were employed for granulometric analysis.Esti-mated data were analyzed using Excel,SPSS,and Surfer software to calculate various indices,correlation matrix,and spatial distribution.The granulometric analysis showed that 76%of the samples belonged to loam types of soil,12%to sand type,and 8%to silt type.Weathering indices:CIA,CIW,PIA,PWI,WIP,CIX,and ICV were calculated to infer the level of alteration.These indices reflect mod-erate to intense weathering;supported by K_(2)O/AI_(2)O_(3),Rb/K_(2)O,Rb/Ti,and Rb/Sr ratios.Assessment of the geo-ac-cumulation and Nemerow Pollution indices pinpoint rela-tively high concentrations of Pb,Ni,and Cr concentration in the soils.The correlation matrix and Principal Compo-nent Analysis show that the soil in this study area is mainly derived from the weathering of igneous rocks of Bela Ophiolite(Cretaceous age)and Jurassic sedimentary rocks of Mor Range having SEDEX/MVT type mineralization.Weathering may result in the undesirable accumulation of certain trace elements which adversely affects crops.展开更多
This study aims to investigate characteristics of continental shelf wave(CSW)on the northwestern continental shelf of the South China Sea(SCS)induced by winter storms in 2021.Mooring and cruise observations,tidal gaug...This study aims to investigate characteristics of continental shelf wave(CSW)on the northwestern continental shelf of the South China Sea(SCS)induced by winter storms in 2021.Mooring and cruise observations,tidal gauge data at stations Hong Kong,Zhapo and Qinglan and sea surface wind data from January 1 to February 28,2021 are used to examine the relationship between along-shelf wind and sea level fluctuation.Two events of CSWs driven by the along-shelf sea surface wind are detected from wavelet spectra of tidal gauge data.The signals are triply peaked at periods of 56 h,94 h and 180 h,propagating along the coast with phase speed ranging from 6.9 m/s to18.9 m/s.The dispersion relation shows their property of the Kelvin mode of CSW.We develop a simple method to estimate amplitude of sea surface fluctuation by along-shelf wind.The results are comparable with the observation data,suggesting it is effective.The mode 2 CSWs fits very well with the mooring current velocity data.The results from rare current help to understand wave-current interaction in the northwestern SCS.展开更多
Wooden buildings play a very important role in China’s construction and landscape architecture industry.In order to explore the weathering characteristics of the surface layer of landscape wooden buildings,the main c...Wooden buildings play a very important role in China’s construction and landscape architecture industry.In order to explore the weathering characteristics of the surface layer of landscape wooden buildings,the main causes of weathering were analyzed on the basis of summarizing the common types of weathering characterization.The results showed that the weathering characterization was mainly reflected in the surface defects of wood structures,such as cracking,discoloration,peeling,wind erosion wear,and so on.The coating technology on the surface of constructions was the main artificial factor affecting the surface defects of constructions.In the case of similar surface decoration conditions,sunlight and moisture were the main natural factors affecting the weathering of wooden buildings,which will promote the process of weathering.展开更多
The West African Monsoon (WAM) is characterized by strong decadal and multi-decadal variability and the impacts can be catastrophic for the local populations. One of the factors put forward to explain this variability...The West African Monsoon (WAM) is characterized by strong decadal and multi-decadal variability and the impacts can be catastrophic for the local populations. One of the factors put forward to explain this variability involves the role of atmospheric dynamics, linked in particular to the Saharan Heat Low (SHL). This article addresses this question by comparing the sets of preindustrial control and historical simulation data from climate models carried out in the framework of the CMIP5 project and observations data over the 20<sup>th</sup> century. Through multivariate statistical analyses, it was established that decadal modes of ocean variability and decadal variability of Saharan atmospheric dynamics significantly influence decadal variability of monsoon precipitation. These results also suggest the existence of external anthropogenic forcing, which is superimposed on the decadal natural variability inducing an intensification of the signal in the historical simulations compared to preindustrial control simulations. We have also shown that decadal rainfall variability in the Sahel, once the influence of oceanic modes has been eliminated, appears to be driven mainly by the activity of the Arabian Heat Low (AHL) in the central Sahel, and by the structure of the meridional temperature gradient over the inter-tropical Atlantic in the western Sahel.展开更多
Petrographical and geochemical methods were combined to investigate the provenance, geodynamic and weathering history of the Shurijeh sandstones, Kopet-Dagh Basin. The point-counting method and XRF technique are used ...Petrographical and geochemical methods were combined to investigate the provenance, geodynamic and weathering history of the Shurijeh sandstones, Kopet-Dagh Basin. The point-counting method and XRF technique are used for modal and geochemical analyses. Based on petrographical examinations, it seems that the Shurijeh sandstones are mainly deposited in the craton interior and recycled orogen belts. In addition to petrographical investigation, geochemical analyses (major oxides and trace elements) of Late Jurassic-Early Cretaceous rocks reveal that the sedimentation processes are performed in a passive continental margin. Such interpretation is supported with geodynamic and paleogeographical studies of the Kopeh-Dagh basin during this time. The geochemical investigations suggested that the composition of probable source rocks mostly was acidic-intermediate with minor mafic igneous rocks. Based on the above, Paleo-Tethys remnants and their collision-related granitoids, in the south and west of Mashhad, may have been the source area for these rocks. CIA values, which range from 63.8 to 94.9 in samples, are suggesting a moderate to relatively high degree of alteration (weathering) in the source area. Therefore, petrographical and paleogeographical studies of siliciclastic rocks can be used for the provenance, tectonic setting and paleoweathering studies in the source area.展开更多
As the key link connecting the earth’s spheres,continental weathering plays an important role in regulating the global biogeochemical cycle and long-term climate change.Siliciclastic sediments derived from large rive...As the key link connecting the earth’s spheres,continental weathering plays an important role in regulating the global biogeochemical cycle and long-term climate change.Siliciclastic sediments derived from large river basins can record continental weathering and erosion signals,and are thus widely used to investigate weathering processes.However,sediment grain size,hydrodynamic sorting and sedimentary recycling complicate the interpretation of sediment weathering proxies.This study presents elemental and lithium isotope compositions of estuarine surface sediments(SS)and suspended particulate matters(SPM)collected from the Changjiang(Yangtze River)Estuary.Based on a simple mass balance model,the proportions of different end-members(i.e.,igneous rocks,modern weathering products and inherited weathering products)in sediments were quantitatively calculated and thus the silicate weathering process can be estimated.Overall,the sediments in the Changjiang Estuary are mainly eroded from un-weathered rock fragments(>60%),while modern weathering products account for less than 40%.The fine-grained SPM contain more shale components(52–66%),and the modern weathering products account for 21–40%.Comparatively,the coarse-grained surface sediments contain more un-weathered igneous rock fragments(63–84%)and less modern weathering products(only 4–18%).The comparison ofδ^(7)Li values with the weathering proxy(Chemical Index of Alteration,CIA)suggests that sediment weathering intensity declines with increasing proportion of un-weathered igneous rock fragments.Additionally,the occurrence of inherited weathering products(i.e.,shale)in modern sediments makes it a challenge to simply use CIA andδ^(7)Li as indicators of weathering intensity.This study confirms that fine-grained particles are more suitable for tracing contemporary weathering process,albeit with the influence of sedimentary recycling.Lithium isotopes combining with the mass balance model can quantitatively constrain the continental weathering processes in large river basins.展开更多
Cenozoic potassic-ultrapotassic igneous rocks are widespread in the southeastern Tibetan Plateau.Their petrogenesis and magmatic processes remain subject to debate in spite of numerous publications.Almost all of the C...Cenozoic potassic-ultrapotassic igneous rocks are widespread in the southeastern Tibetan Plateau.Their petrogenesis and magmatic processes remain subject to debate in spite of numerous publications.Almost all of the Cenozoic extrusive and intrusive rocks in the Yao’an area,western Yunnan Province,SW China,are geochemically shoshonitic,collectively termed here the Yao’an Shoshonitic Complex(YSC).The YSC is located in the(south)easternmost part of the ENE-WSW-trending,~550 km-long and~250 km-wide Cenozoic magmatic zone;the latter separates the orthogonal and oblique collision belts of the India-Eurasia collision orogen.Previously published geochronological and thermochronological data revealed that the rocks of the YSC were emplaced over a short timespan of 34-32 Ma.This and our new data suggest that the primary magma of the YSC likely was formed by partial melting of ancient continental lithospheric mantle beneath the Yangtze Block.This part of the continental lithospheric mantle had likely not been modified by any oceanic subduction.Fractionation crystallization of an Mg-and Ca-bearing mineral and TiFe oxides during the magmatic evolution probably account for the variable lithologies of the YSC.展开更多
Based on the typical dissection of various onshore tight oil fields in China,the tight oil migration and accumulation mechanism and enrichment-controlling factors in continental lake basins are analyzed through nuclea...Based on the typical dissection of various onshore tight oil fields in China,the tight oil migration and accumulation mechanism and enrichment-controlling factors in continental lake basins are analyzed through nuclear magnetic resonance(NMR)displacement physical simulation and Lattice Boltzmann numerical simulation by using the samples of source rock,reservoir rock and crude oil.In continental lake basins,the dynamic forces driving hydrocarbon generation and expulsion of high-quality source rocks are the foundational power that determines the charging efficiency and accumulation effect of tight oil,the oil migration resistance is a key element that influences the charging efficiency and accumulation effect of tight oil,and the coupling of charging force with pore-throat resistance in tight reservoir controls the tight oil accumulation and sweet spot enrichment.The degree of tight oil enrichment in continental lake basins is controlled by four factors:source rock,reservoir pore-throat size,anisotropy of reservoir structure,and fractures.The high-quality source rocks control the near-source distribution of tight oil,reservoir physical properties and pore-throat size are positively correlated with the degree of tight oil enrichment,the anisotropy of reservoir structure reveals that the parallel migration rate is the highest,and intralayer fractures can improve the migration and accumulation efficiency and the oil saturation.展开更多
Weathering has always been a concerned around the world,as the first and most important step in the global cycle of elements,which leads to the fractionation of isotopes on the scale of geological age.The Middle Ordov...Weathering has always been a concerned around the world,as the first and most important step in the global cycle of elements,which leads to the fractionation of isotopes on the scale of geological age.The Middle Ordovician Majiagou Formation in Daniudi area of the Ordos Basin had experienced weathering for>130 Myr.Through thin section observation,major and trace element analysis,carbon,oxygen,and magnesium isotopes composition analysis,the dolomitization modes and weathering of ancient dolo-mite in Daniudi area were analyzed in detail.The results showed that the Sabkha and brine-reflux dolomitization modes had developed,and the Mg isotopes in different layers of the karst crust were fractionated by various factors.The vertical vadose zone was affected by weathering,the Mg isotope of dolomite(δ^(26)Mgdol)showed a downward decreasing trend;the horizontal underflow zone was controlled by diagenesis and formation fluid,δ^(26)Mgdol showed a vertical invariance and negative;the main reason for Mg isotope fractionation in the deep slow-flow zone was the brine-reflux dolomitization mode during early burial period,which showed a vertical downward increase.Finally,the Mg isotope characteristic data of the ancient weathering crust were provided and the process of Mg isotope frac-tionationinthekarstcrust was explained.展开更多
An electrical resistivity survey was carried out on the household and industrial waste disposal site (landfill) of Akouédo (Central Abidjan) with a view to searching for a possible layer of clay in the stratifica...An electrical resistivity survey was carried out on the household and industrial waste disposal site (landfill) of Akouédo (Central Abidjan) with a view to searching for a possible layer of clay in the stratification which could constitute a protective screen of the aquifer of the Continental Terminal of Abidjan against the migration of leachate. Electrical surveys (SE) carried out according to the Schlumberger configuration showed that the stratigraphy of the area is composed of three to four geoelectric layers depending on the SE positions. The correlation with the lithology of two piezometric boreholes carried out indicates that the lithology of the study area is dominated by clayey sand, sand, sandy clay and clay. The average thickness of accumulated waste varies between 30 and 40 m. The virtual absence of a continuous layer of clay under the waste exposes the Continental Terminal aquifer to contamination by leachate from waste accumulated over several decades in the Akouedo area.展开更多
The middle Eocene climatic optimum(MECO,ca.-42 Ma)is a key time period for understanding Cenozoic cooling of the global climate.Still,midlatitude terrestrial records of climate evolution during MEcO epoch are rare.In ...The middle Eocene climatic optimum(MECO,ca.-42 Ma)is a key time period for understanding Cenozoic cooling of the global climate.Still,midlatitude terrestrial records of climate evolution during MEcO epoch are rare.In this study,continuous high-resolution record of shale sediments in mid-Eocene Shahejie Formation(MES shales)in the Bohai Bay Basin were performed with major-element and wavelet analysis.The midlatitude paleoweathering and paleoclimatic evolution during MEcO epoch were analyzed in this study.The MES shales experienced weak-moderate paleoweathering under a subtropical monsoon paleoclimate with mean annual temperature of 8.3-12.9℃ and mean annual precipitation of 685-1100 mm/yr.The MES shales record a mixed provenance involving intermediate igneous rocks,and low compositional maturity.The nutrient-rich environment led to enrichment in organic matter in the MES shales.Wavelet analysis revealed good periodicity about the paleoclimate and weathering during MECO epoch.In the stage I of MES shales depositional process,the paleolake was high in nutrients,and the MES shales experienced high chemical weathering due to a relatively warmer and more humid climate.In contrast,the climate in stage II was relatively cold and dry,and the maturity of the MES shales was relatively high during this stage,suggesting a relatively stable tectonic background.This work provides more terrestrial records of MEco epoch for midlatitude region,and is benefit for better understanding of the palaeoenvironment when MES shales formed.The implication of organic matters enrichment in this study is meaningful for the shale oil/gas exploration in Nanpu Sag.展开更多
According to the drive of planetary-scale upper magma fluid motions associated with the core-magma angular momentum exchange in the early Earth’s interior, this paper reviewed the results of continental drift studied...According to the drive of planetary-scale upper magma fluid motions associated with the core-magma angular momentum exchange in the early Earth’s interior, this paper reviewed the results of continental drift studied over the last three decades. The theoretical speculation is in good fit to the traces of geological events left on the Earth’s surface. A northeastward drift directionality of the Australian, African, and South American continents relative to the Antarctica Continent in the Southern Hemisphere is reanalyzed according to the slowing down of the early Earth’s rotation. Six traces of significant back-and-forth drifts of the Australian and Asian continents left respectively on the Southwest and Northwest Pacific seafloors are reidentified according to the gradually decreasing amplitude of core-magma angular momentum exchange during early geological evolution. Finally, the thickening and shortening of different continents during the early drift processes are re-simulated by using a simple magma fluid dynamical model.展开更多
This study aims to characterize the different lithofacies of the Ct<sup>3</sup> formation in the Niamey region, and to determine the distribution of major and trace elements, in order to highlight the cond...This study aims to characterize the different lithofacies of the Ct<sup>3</sup> formation in the Niamey region, and to determine the distribution of major and trace elements, in order to highlight the conditions for the establishment of iron mineralization. A lithological column, synthesizing sections of selected outcrops in the vicinity of Niamey, was produced. The chemical compositions of the selected samples were determined by X-ray fluorescence (XRF) spectrometry. Microscopic analysis of the thin sections determined the gœthitic nature of the oolitic iron ore. The oolites show a quartz, limonitic or gœthitic nucleus. Sometimes the nucleus is absent. From a morphoscopic point of view, two types of oolites have been distinguished: spherical-shaped and ellipsoidal-shaped oolites. The oolites are either contiguous or disseminated, as the case may be, in a limonitic to goethitic cement or in a fine sandstone matrix. The larger oolites (pisolites) are relatively friable. They reflect the influence of a relatively turbulent to submerged environment. The hardground of the iron mineralized horizons are covered by quartz grains. They are indicative of a submerged or emergent environment. X-ray fluorescence analysis shows high Fe<sub>2</sub>O<sub>3</sub> contents<sub> </sub>(50% to 80%) and variable contents of major elements SiO<sub>2</sub>, Al<sub>2</sub>O<sub>3</sub>, TiO<sub>2</sub>, MnO, MgO, CaO, K<sub>2</sub>O and P<sub>2</sub>O<sub>5</sub> associated with certain trace elements such as Th, U, V, Y, Zn, Zr and As. The results of the study are an important tool for decision-makers to adopt effective prevention/remediation measures for groundwater contamination in the Continental terminal aquifer systems.展开更多
The clay mineral content of Daqing Gulong shale is in the range of about 35%–45%,with particle sizes less than 0.0039 mm.The horizontal fluidity of oil in Gulong shale is poor,with near-zero vertical flowability.As a...The clay mineral content of Daqing Gulong shale is in the range of about 35%–45%,with particle sizes less than 0.0039 mm.The horizontal fluidity of oil in Gulong shale is poor,with near-zero vertical flowability.As a result,Gulong shale has been considered to lack commercial value.In recent years,however,interdisciplinary research in geoscience,percolation mechanics,thermodynamics,and surface mechanics has demonstrated that Gulong shale oil has a high degree of maturity and a high residual hydrocarbon content.The expulsion efficiency of Gulong shale in the high mature stage is 32%–48%.Favorable storage spaces in Gulong shale include connecting pores and lamellar fractures developed between and within organic matter and clay mineral complexes.The shale oil mainly occurs in micro-and nano-pores,bedding fractures,and lamellar fractures,with a high gas–oil ratio and medium–high movable oil saturation.Gulong shale has the characteristics of high hardness,a high elastic modulus,and high fracture toughness.This study achieves breakthroughs in the exploration and development of Gulong shale,including the theories of hydrocarbon generation and accumulation,the technologies of mobility and fracturing,and recoverability.It confirms the major transition of Gulong shale from oil generation to oil production,which has extremely significant scientific value and application potential for China’s petroleum industry.展开更多
Past hydroclimatic conditions in southern China are poorly constrained owing to the lack of high-resolution marine-sediment records. In this study, we present high-resolution geochemical and grain-size records of mari...Past hydroclimatic conditions in southern China are poorly constrained owing to the lack of high-resolution marine-sediment records. In this study, we present high-resolution geochemical and grain-size records of marine sediments from the coastal shelf of the northern South China Sea to investigate regional hydrological variations.Results suggest a warm and humid climate during the interval 9 200–7 600 cal a BP, followed by a cold and dry climate from 7 600 cal a BP to 6 500 cal a BP, and progressive humidification during the period 6 500–6 200 cal a BP.A prominent hydrological anomaly occurred during 7 600–6 500 cal a BP. This abrupt event corresponds closely to tropical Pacific and interhemispheric temperature gradients, suggesting that moisture variations in southern China may have been driven by interhemispheric and zonal Pacific temperature gradients via modulation of the intensity and location of the West Pacific subtropical high.展开更多
The(ultra-)mafic mine tailings pond revealed a weathering discrepancy in the tailings profile,which provided a valuable analog to assess the role of carbonate and silicate weathering of the basalt.In this study,drill-...The(ultra-)mafic mine tailings pond revealed a weathering discrepancy in the tailings profile,which provided a valuable analog to assess the role of carbonate and silicate weathering of the basalt.In this study,drill-cores samples were selected from the Wanniangou V–Ti–Fe mine tailings pond(Sichuan province,China)to investigate the mineralogicand geochemical characteristics in the tailings profile.The results reveal(1)the tailings pond profile consist of upper and lower layers.The upper layer is composed of carbonate weathering(1.4%),which was formed in the initial stages of tailings exposure and represented a minimal weathering degree.(2)The lower layer was primarily observed at the aquifer zone of the tailings pond,and was consistent with 0.45%carbonate weathering and 48.4%silicate weathering.(3)The weathering discrepancy in the tailings profile could be due to the sulfide oxidation and aerobic/flowing aquifer,which facilitate the water-tailings reactions.The tailings profile provides an analog to studying basalt weathering,as it spans both carbonate and silicate weathering.This research reinforces the idea that silicate weathering is predominant in basaltic areas and plays a crucial role in regulating atmospheric CO_(2)(carbon dioxide)levels on Earth.展开更多
Weathering crust reservoirs have obvious vertical zonation,which is the focus of weathering crust reservoir research,but there is a lack of quantitative characterization indexes.To achieve the quantitative characteriz...Weathering crust reservoirs have obvious vertical zonation,which is the focus of weathering crust reservoir research,but there is a lack of quantitative characterization indexes.To achieve the quantitative characterization of granite weathering crust reservoir and provide the basis for oil exploration of granite weathering crust buried hill reservoir,in this paper,the vertical zonation of granite weathering crust reservoir is quantitatively divided by testing and analyzing the uniaxial compressive strength(UCS),magnetic susceptibility(MS),permeability,and chemical index of alteration(CIA)of the Mesozoic granite weathering crust in the coastal area of eastern Fujian.The results show that the granite weathering crust reservoir can be divided into four zones vertically:a soil zone(SZ),weathered and dissolved zone(WDZ),fracture zone(FZ),and bedrock zone(BZ).A cataclastic area is developed in the FZ and BZ,in which structural fractures are well-developed,the fracture surface density is usually greater than 200 m/m^(2),and the contribution to the fractures in the rock mass is up to about 50%,making this the sweet spot of the reservoir.In the SZ,the rocks are loose,and the pores are well-developed.The UCS is less than 10 MPa,and the average rate of change of the UCS(Δ_(σ))is 0.90.The average permeability is 2823.00 mD,and the average rate of change of the permeability(Δ_(κ))is 5.13.The average CIA is 74.9%.The average clay mineral content is 7%.The rocks in the WDZ have been significantly weathered by physical and chemical processes,and the weathering fractures and dissolution pores are well-developed.The average UCS is 18.2 MPa,and the averageΔ_(σ)is 0.70.The average permeability is 143.80 mD,and averageΔ_(κ)is 4.17.The average CIA is 65.3%.The average clay mineral content is 4%.Under the influence of tectonic movement and physical weathering,the rocks in the FZ have developed structural fractures and a few weathered fractures.The average UCS is 57.9 MPa,and the averageΔ_(σ)is 0.18.The average permeability is 5.50 mD,and the averageΔ_(κ)is 2.55.The average CIA is 61.6%.The average clay mineral content is 2%.In the BZ,the rocks are intact and hard.The average UCS is 69.9 MPa,and the average Ds is 0.13.The average permeability is 1.46 mD,and the averageΔ_(κ)is 1.43.The average CIA is 57.8%.The average clay mineral content is less than 1%.The multi-parameter combination of the UCS,Δ_(σ),permeability,Δ_(κ),CIA,and clay mineral content achieved good results in the division of the zones of the weathering crust.The UCS increases gradually from top to bottom,while Ds,permeability,Δ_(κ),CIA,and clay mineral content all decrease gradually.In addition,based on the petrophysical parameters of the rocks,including the density,resistivity,and acoustic velocity,a good division effect was also achieved,which can provide a basis for the vertical zonation of the granite buried-hill weathering crust reservoir.展开更多
The conventional lithofacies and facies model of subaerial and marine pyroclastic rocks cannot reflect the characteristics of subaqueous volcanic edifice in lacustrine basins.In order to solve this problem,the lithofa...The conventional lithofacies and facies model of subaerial and marine pyroclastic rocks cannot reflect the characteristics of subaqueous volcanic edifice in lacustrine basins.In order to solve this problem,the lithofacies of subaqueous eruptive pyroclastic rocks is discussed and the facies model is established by taking the tuff cone of Cretaceous Huoshiling Formation in the Chaganhua area of the Changling fault depression,Songliao Basin as the research object.The results indicate that the subaqueous eruptive pyroclastic rocks in the Songliao Basin can be divided into two facies and four subfacies.The two facies are the subaqueous explosive facies and the volcanic sedimentary facies that is formed during the eruption interval.The subaqueous explosive facies can be further divided into three subfacies:gas-supported hot pyroclastic flow subfacies,water-laid density current subfacies and subaqueous fallout subfacies.The volcanic sedimentary facies consists of pyroclastic sedimentary rocks containing terrigenous clast subfacies.A typical facies model of the tuff cone that is formed by subaqueous eruptions in the Songliao Basin was established.The tuff cone is generally composed of multiple subaqueous eruption depositional units and can be divided into two facies associations:near-source facies association and far-source facies association.The complete vertical succession of one depositional unit of the near-source facies association is composed of pyroclastic sedimentary rocks containing terrigenous clast subfacies,gas-supported hot pyroclastic flow subfacies,water-laid density current subfacies and subaqueous fallout subfacies from bottom to top.The depositional unit of the far-source facies association is dominated by the subaqueous fallout subfacies and contains several thin interlayered deposits of the water-laid density current subfacies.The gas-supported hot pyroclastic flow subfacies and the pyroclastic sedimentary rocks containing terrigenous clast subfacies are favorable subaqueous eruptive facies for reservoirs in continental lacustrine basins.展开更多
This research presents the variation of the gravity field and associated gravity field components over the continental area of Nigeria to provide data for geoscience research,geodetic and engineering works,aerodynamic...This research presents the variation of the gravity field and associated gravity field components over the continental area of Nigeria to provide data for geoscience research,geodetic and engineering works,aerodynamic studies and deep crustal inferences.Accurate positions and elevations were observed at 58 of the 59 base stations of the Primary Gravity Network of Nigeria(PGNN),whose absolute gravity values had been accurately determined.The absolute gravity values were plotted against their respective positions to reveal the distribution pattern and strength of the gravity field within the study area.Theoretical gravity values at each base station were generated using the Somigliana's equation.The free-air gravity and free-air anomaly gravity values were generated with respect to the World Geodetic System 1984(WGS84)ellipsoid using GPS-derived elevation data.Then,the perturbing potential,free-air gravity with respect to the geoid,and the indirect effects were evaluated.The average of the indirect effects was used to adjust the WGS84 gravity formula to produce a gravity formula that better approximates the geoid across the continental area of Nigeria,compatible with the heights measured relative to the geoid,which can serve as a reference for establishing a vertical height control.The Bouguer gravity and Bouguer gravity anomalies across Nigeria revealed a“trans-southern gravity high strip”interpreted to be associated with mantle upwelling.Two new major mega-lineaments related to mantle upwelling were mapped.A batholith province trending NWeSE was delineated,occurring from north central Nigeria to the north western region and containing closures of“Bouguer gravity lows”interpreted as batholiths.A separate closure of“Bouguer gravity low”was detected at Azare,north eastern Nigeria,which may be due to the presence of intrusive granitic body.It is recommended that the mantle structure beneath“the trans-southern gravity high strip”,“delineated batholith province”and“isolated gravity closures”around the northeast of Nigeria should be studied from seismic shear wave splitting analysis for better understanding of the deep lithospheric structures and moho relief.展开更多
基金supported by the National Key Research and Development Program(Grant Nos.2022YFF0800200 and 2021YFA0718200)the National Natural Science Foundation of China(Grant No.42225304)。
文摘The Mg isotopic compositions of siliciclastic components(δ^(26)Mg_(sili))of sediments and sedimentary rocks have been commonly used to constrain the intensity of continental weathering,based on observations of,(1)an upward enrichment of26Mg in modern weathering profiles,(2)preferential uptake of26Mg in soil clays,and(3)general positive correlations between weathering intensities andδ^(26)Mg_(sili)values.However,not all weathering profiles display an upward increase ofδ^(26)Mg_(sili),and not all soil clays enrich in26Mg,complicating the interpretations ofδ^(26)Mg_(sili)data of sediments and sedimentary rocks.To further explore the controls ofδ^(26)Mg_(sili)of sediments and sedimentary rocks,here we measuredδ^(26)Mg_(sili),mineralogical compositions and major element compositions of deep sea sediments from South China Sea(SCS)and carbonate rock samples from two late Paleozoic sections in South China.Carbonate samples show decreasing trends of both normalized Mg concentration(Mgnorm)andδ^(26)Mg_(sili)values with the increase of weathering intensity,while SCS sediments samples do not show any correlation between Mgnormorδ^(26)Mg_(sili)values and weathering intensity.A three-stages weathering model is developed to explain the observed Mgnorm andδ^(26)Mg_(sili)data.In the new model,weathering can be divided into three stages,(1)the preliminary weathering stage characterized by dissolution of primary minerals and formation of secondary clay minerals in saprolite,(2)the transitional stage with massive vermiculite and chlorite formation on the bottom of soil,and(3)the advanced stage showing dissolution of vermiculite and chlorite in the top of soil.The new model explains anδ^(26)Mg_(sili)increase and Mgnormdecrease with an increase weathering intensity in preliminary weathering stage and decrease of Mgnormandδ^(26)Mg_(sili)with increase weathering intensity in advanced weathering stage.The revised weathering model warrants the application of Mg isotope in the study of continental weathering in deep time.
基金supported by the Dean Faculty of Science,University of Karachi research grant.
文摘This study is thefirst attempt to assess the nature of the soil,especially on the western side of the Porali Plain in Balochistan;a new emerging agriculture hub,using weathering and pollution indices supplemented by multi-variate analysis based on geochemical data.The outcomes of this study are expected to help farmers in soil manage-ment and selecting suitable crops for the region.Twenty-five soil samples were collected,mainly from the arable land of the Porali Plain.After drying and coning-quarter-ing,soil samples were analyzed for major and trace ele-ments using the XRF technique;sieving and hydrometric methods were employed for granulometric analysis.Esti-mated data were analyzed using Excel,SPSS,and Surfer software to calculate various indices,correlation matrix,and spatial distribution.The granulometric analysis showed that 76%of the samples belonged to loam types of soil,12%to sand type,and 8%to silt type.Weathering indices:CIA,CIW,PIA,PWI,WIP,CIX,and ICV were calculated to infer the level of alteration.These indices reflect mod-erate to intense weathering;supported by K_(2)O/AI_(2)O_(3),Rb/K_(2)O,Rb/Ti,and Rb/Sr ratios.Assessment of the geo-ac-cumulation and Nemerow Pollution indices pinpoint rela-tively high concentrations of Pb,Ni,and Cr concentration in the soils.The correlation matrix and Principal Compo-nent Analysis show that the soil in this study area is mainly derived from the weathering of igneous rocks of Bela Ophiolite(Cretaceous age)and Jurassic sedimentary rocks of Mor Range having SEDEX/MVT type mineralization.Weathering may result in the undesirable accumulation of certain trace elements which adversely affects crops.
基金The National Key R&D Program of China under contract No.2022YFC3104805the National Natural Science Foundation of China under contract Nos 42276019,41706025 and 41976200+4 种基金the Innovation Team Plan for Universities in Guangdong Province under contract No.2019KCXTF021the First-class Discipline Plan of Guangdong Province under contract Nos 080503032101and 231420003the Program for Scientific Research Start-up Funds of Guangdong Ocean University under contract No.060302032106the Open Fund Project of Key Laboratory of Marine Environmental Information Technology(2019)Ministry of Natural Resources。
文摘This study aims to investigate characteristics of continental shelf wave(CSW)on the northwestern continental shelf of the South China Sea(SCS)induced by winter storms in 2021.Mooring and cruise observations,tidal gauge data at stations Hong Kong,Zhapo and Qinglan and sea surface wind data from January 1 to February 28,2021 are used to examine the relationship between along-shelf wind and sea level fluctuation.Two events of CSWs driven by the along-shelf sea surface wind are detected from wavelet spectra of tidal gauge data.The signals are triply peaked at periods of 56 h,94 h and 180 h,propagating along the coast with phase speed ranging from 6.9 m/s to18.9 m/s.The dispersion relation shows their property of the Kelvin mode of CSW.We develop a simple method to estimate amplitude of sea surface fluctuation by along-shelf wind.The results are comparable with the observation data,suggesting it is effective.The mode 2 CSWs fits very well with the mooring current velocity data.The results from rare current help to understand wave-current interaction in the northwestern SCS.
基金Science and technology research projects of colleges and universities in Inner Mongolia(NJZY22511)Funds for basic scientific research in universities of Inner Mongolia:Key project of Philosophy and Social Science Foundation of Inner Mongolia Agricultural University(BR220603)。
文摘Wooden buildings play a very important role in China’s construction and landscape architecture industry.In order to explore the weathering characteristics of the surface layer of landscape wooden buildings,the main causes of weathering were analyzed on the basis of summarizing the common types of weathering characterization.The results showed that the weathering characterization was mainly reflected in the surface defects of wood structures,such as cracking,discoloration,peeling,wind erosion wear,and so on.The coating technology on the surface of constructions was the main artificial factor affecting the surface defects of constructions.In the case of similar surface decoration conditions,sunlight and moisture were the main natural factors affecting the weathering of wooden buildings,which will promote the process of weathering.
文摘The West African Monsoon (WAM) is characterized by strong decadal and multi-decadal variability and the impacts can be catastrophic for the local populations. One of the factors put forward to explain this variability involves the role of atmospheric dynamics, linked in particular to the Saharan Heat Low (SHL). This article addresses this question by comparing the sets of preindustrial control and historical simulation data from climate models carried out in the framework of the CMIP5 project and observations data over the 20<sup>th</sup> century. Through multivariate statistical analyses, it was established that decadal modes of ocean variability and decadal variability of Saharan atmospheric dynamics significantly influence decadal variability of monsoon precipitation. These results also suggest the existence of external anthropogenic forcing, which is superimposed on the decadal natural variability inducing an intensification of the signal in the historical simulations compared to preindustrial control simulations. We have also shown that decadal rainfall variability in the Sahel, once the influence of oceanic modes has been eliminated, appears to be driven mainly by the activity of the Arabian Heat Low (AHL) in the central Sahel, and by the structure of the meridional temperature gradient over the inter-tropical Atlantic in the western Sahel.
文摘Petrographical and geochemical methods were combined to investigate the provenance, geodynamic and weathering history of the Shurijeh sandstones, Kopet-Dagh Basin. The point-counting method and XRF technique are used for modal and geochemical analyses. Based on petrographical examinations, it seems that the Shurijeh sandstones are mainly deposited in the craton interior and recycled orogen belts. In addition to petrographical investigation, geochemical analyses (major oxides and trace elements) of Late Jurassic-Early Cretaceous rocks reveal that the sedimentation processes are performed in a passive continental margin. Such interpretation is supported with geodynamic and paleogeographical studies of the Kopeh-Dagh basin during this time. The geochemical investigations suggested that the composition of probable source rocks mostly was acidic-intermediate with minor mafic igneous rocks. Based on the above, Paleo-Tethys remnants and their collision-related granitoids, in the south and west of Mashhad, may have been the source area for these rocks. CIA values, which range from 63.8 to 94.9 in samples, are suggesting a moderate to relatively high degree of alteration (weathering) in the source area. Therefore, petrographical and paleogeographical studies of siliciclastic rocks can be used for the provenance, tectonic setting and paleoweathering studies in the source area.
基金funded by the National Natural Science Foundation of China(Grant Nos.41991324,41730531,40830107)The sampling cruise(No.YEC2017)was supported by the State Key Laboratory of Marine Geology,Tongji University.
文摘As the key link connecting the earth’s spheres,continental weathering plays an important role in regulating the global biogeochemical cycle and long-term climate change.Siliciclastic sediments derived from large river basins can record continental weathering and erosion signals,and are thus widely used to investigate weathering processes.However,sediment grain size,hydrodynamic sorting and sedimentary recycling complicate the interpretation of sediment weathering proxies.This study presents elemental and lithium isotope compositions of estuarine surface sediments(SS)and suspended particulate matters(SPM)collected from the Changjiang(Yangtze River)Estuary.Based on a simple mass balance model,the proportions of different end-members(i.e.,igneous rocks,modern weathering products and inherited weathering products)in sediments were quantitatively calculated and thus the silicate weathering process can be estimated.Overall,the sediments in the Changjiang Estuary are mainly eroded from un-weathered rock fragments(>60%),while modern weathering products account for less than 40%.The fine-grained SPM contain more shale components(52–66%),and the modern weathering products account for 21–40%.Comparatively,the coarse-grained surface sediments contain more un-weathered igneous rock fragments(63–84%)and less modern weathering products(only 4–18%).The comparison ofδ^(7)Li values with the weathering proxy(Chemical Index of Alteration,CIA)suggests that sediment weathering intensity declines with increasing proportion of un-weathered igneous rock fragments.Additionally,the occurrence of inherited weathering products(i.e.,shale)in modern sediments makes it a challenge to simply use CIA andδ^(7)Li as indicators of weathering intensity.This study confirms that fine-grained particles are more suitable for tracing contemporary weathering process,albeit with the influence of sedimentary recycling.Lithium isotopes combining with the mass balance model can quantitatively constrain the continental weathering processes in large river basins.
基金financially supported by the Ministry of Sciences and Technology of China(Grant No.2022YFF0800901)the Natural Science Foundation of China(Grant Nos.92055206 and 42163007)。
文摘Cenozoic potassic-ultrapotassic igneous rocks are widespread in the southeastern Tibetan Plateau.Their petrogenesis and magmatic processes remain subject to debate in spite of numerous publications.Almost all of the Cenozoic extrusive and intrusive rocks in the Yao’an area,western Yunnan Province,SW China,are geochemically shoshonitic,collectively termed here the Yao’an Shoshonitic Complex(YSC).The YSC is located in the(south)easternmost part of the ENE-WSW-trending,~550 km-long and~250 km-wide Cenozoic magmatic zone;the latter separates the orthogonal and oblique collision belts of the India-Eurasia collision orogen.Previously published geochronological and thermochronological data revealed that the rocks of the YSC were emplaced over a short timespan of 34-32 Ma.This and our new data suggest that the primary magma of the YSC likely was formed by partial melting of ancient continental lithospheric mantle beneath the Yangtze Block.This part of the continental lithospheric mantle had likely not been modified by any oceanic subduction.Fractionation crystallization of an Mg-and Ca-bearing mineral and TiFe oxides during the magmatic evolution probably account for the variable lithologies of the YSC.
基金Supported by the National Science and Technology Major Project of China(2016ZX05046-001).
文摘Based on the typical dissection of various onshore tight oil fields in China,the tight oil migration and accumulation mechanism and enrichment-controlling factors in continental lake basins are analyzed through nuclear magnetic resonance(NMR)displacement physical simulation and Lattice Boltzmann numerical simulation by using the samples of source rock,reservoir rock and crude oil.In continental lake basins,the dynamic forces driving hydrocarbon generation and expulsion of high-quality source rocks are the foundational power that determines the charging efficiency and accumulation effect of tight oil,the oil migration resistance is a key element that influences the charging efficiency and accumulation effect of tight oil,and the coupling of charging force with pore-throat resistance in tight reservoir controls the tight oil accumulation and sweet spot enrichment.The degree of tight oil enrichment in continental lake basins is controlled by four factors:source rock,reservoir pore-throat size,anisotropy of reservoir structure,and fractures.The high-quality source rocks control the near-source distribution of tight oil,reservoir physical properties and pore-throat size are positively correlated with the degree of tight oil enrichment,the anisotropy of reservoir structure reveals that the parallel migration rate is the highest,and intralayer fractures can improve the migration and accumulation efficiency and the oil saturation.
基金supported by the National Natural Science Foundation of China(42072177)National Natural Science Foundation of China(U19B6003)Frontier Project of Chinese Academy of Sciences(XDA14010201).
文摘Weathering has always been a concerned around the world,as the first and most important step in the global cycle of elements,which leads to the fractionation of isotopes on the scale of geological age.The Middle Ordovician Majiagou Formation in Daniudi area of the Ordos Basin had experienced weathering for>130 Myr.Through thin section observation,major and trace element analysis,carbon,oxygen,and magnesium isotopes composition analysis,the dolomitization modes and weathering of ancient dolo-mite in Daniudi area were analyzed in detail.The results showed that the Sabkha and brine-reflux dolomitization modes had developed,and the Mg isotopes in different layers of the karst crust were fractionated by various factors.The vertical vadose zone was affected by weathering,the Mg isotope of dolomite(δ^(26)Mgdol)showed a downward decreasing trend;the horizontal underflow zone was controlled by diagenesis and formation fluid,δ^(26)Mgdol showed a vertical invariance and negative;the main reason for Mg isotope fractionation in the deep slow-flow zone was the brine-reflux dolomitization mode during early burial period,which showed a vertical downward increase.Finally,the Mg isotope characteristic data of the ancient weathering crust were provided and the process of Mg isotope frac-tionationinthekarstcrust was explained.
文摘An electrical resistivity survey was carried out on the household and industrial waste disposal site (landfill) of Akouédo (Central Abidjan) with a view to searching for a possible layer of clay in the stratification which could constitute a protective screen of the aquifer of the Continental Terminal of Abidjan against the migration of leachate. Electrical surveys (SE) carried out according to the Schlumberger configuration showed that the stratigraphy of the area is composed of three to four geoelectric layers depending on the SE positions. The correlation with the lithology of two piezometric boreholes carried out indicates that the lithology of the study area is dominated by clayey sand, sand, sandy clay and clay. The average thickness of accumulated waste varies between 30 and 40 m. The virtual absence of a continuous layer of clay under the waste exposes the Continental Terminal aquifer to contamination by leachate from waste accumulated over several decades in the Akouedo area.
基金funded by Science Foundation of China University of Petroleum,Beijing(No.2462022XKBH005)China Postdoctoral Science Foundation(2022M723487)+1 种基金the National Science and Technology Major Project of the Ministry of Science and Technology of China(2016ZX05006-006)PetroChina Project(2021DJ0704).
文摘The middle Eocene climatic optimum(MECO,ca.-42 Ma)is a key time period for understanding Cenozoic cooling of the global climate.Still,midlatitude terrestrial records of climate evolution during MEcO epoch are rare.In this study,continuous high-resolution record of shale sediments in mid-Eocene Shahejie Formation(MES shales)in the Bohai Bay Basin were performed with major-element and wavelet analysis.The midlatitude paleoweathering and paleoclimatic evolution during MEcO epoch were analyzed in this study.The MES shales experienced weak-moderate paleoweathering under a subtropical monsoon paleoclimate with mean annual temperature of 8.3-12.9℃ and mean annual precipitation of 685-1100 mm/yr.The MES shales record a mixed provenance involving intermediate igneous rocks,and low compositional maturity.The nutrient-rich environment led to enrichment in organic matter in the MES shales.Wavelet analysis revealed good periodicity about the paleoclimate and weathering during MECO epoch.In the stage I of MES shales depositional process,the paleolake was high in nutrients,and the MES shales experienced high chemical weathering due to a relatively warmer and more humid climate.In contrast,the climate in stage II was relatively cold and dry,and the maturity of the MES shales was relatively high during this stage,suggesting a relatively stable tectonic background.This work provides more terrestrial records of MEco epoch for midlatitude region,and is benefit for better understanding of the palaeoenvironment when MES shales formed.The implication of organic matters enrichment in this study is meaningful for the shale oil/gas exploration in Nanpu Sag.
文摘According to the drive of planetary-scale upper magma fluid motions associated with the core-magma angular momentum exchange in the early Earth’s interior, this paper reviewed the results of continental drift studied over the last three decades. The theoretical speculation is in good fit to the traces of geological events left on the Earth’s surface. A northeastward drift directionality of the Australian, African, and South American continents relative to the Antarctica Continent in the Southern Hemisphere is reanalyzed according to the slowing down of the early Earth’s rotation. Six traces of significant back-and-forth drifts of the Australian and Asian continents left respectively on the Southwest and Northwest Pacific seafloors are reidentified according to the gradually decreasing amplitude of core-magma angular momentum exchange during early geological evolution. Finally, the thickening and shortening of different continents during the early drift processes are re-simulated by using a simple magma fluid dynamical model.
文摘This study aims to characterize the different lithofacies of the Ct<sup>3</sup> formation in the Niamey region, and to determine the distribution of major and trace elements, in order to highlight the conditions for the establishment of iron mineralization. A lithological column, synthesizing sections of selected outcrops in the vicinity of Niamey, was produced. The chemical compositions of the selected samples were determined by X-ray fluorescence (XRF) spectrometry. Microscopic analysis of the thin sections determined the gœthitic nature of the oolitic iron ore. The oolites show a quartz, limonitic or gœthitic nucleus. Sometimes the nucleus is absent. From a morphoscopic point of view, two types of oolites have been distinguished: spherical-shaped and ellipsoidal-shaped oolites. The oolites are either contiguous or disseminated, as the case may be, in a limonitic to goethitic cement or in a fine sandstone matrix. The larger oolites (pisolites) are relatively friable. They reflect the influence of a relatively turbulent to submerged environment. The hardground of the iron mineralized horizons are covered by quartz grains. They are indicative of a submerged or emergent environment. X-ray fluorescence analysis shows high Fe<sub>2</sub>O<sub>3</sub> contents<sub> </sub>(50% to 80%) and variable contents of major elements SiO<sub>2</sub>, Al<sub>2</sub>O<sub>3</sub>, TiO<sub>2</sub>, MnO, MgO, CaO, K<sub>2</sub>O and P<sub>2</sub>O<sub>5</sub> associated with certain trace elements such as Th, U, V, Y, Zn, Zr and As. The results of the study are an important tool for decision-makers to adopt effective prevention/remediation measures for groundwater contamination in the Continental terminal aquifer systems.
基金supported by the National Natural Science Foundation of China(72088101 and 42090025)the China National Petroleum Corporation(2019E-26 and YGJ2020-3)。
文摘The clay mineral content of Daqing Gulong shale is in the range of about 35%–45%,with particle sizes less than 0.0039 mm.The horizontal fluidity of oil in Gulong shale is poor,with near-zero vertical flowability.As a result,Gulong shale has been considered to lack commercial value.In recent years,however,interdisciplinary research in geoscience,percolation mechanics,thermodynamics,and surface mechanics has demonstrated that Gulong shale oil has a high degree of maturity and a high residual hydrocarbon content.The expulsion efficiency of Gulong shale in the high mature stage is 32%–48%.Favorable storage spaces in Gulong shale include connecting pores and lamellar fractures developed between and within organic matter and clay mineral complexes.The shale oil mainly occurs in micro-and nano-pores,bedding fractures,and lamellar fractures,with a high gas–oil ratio and medium–high movable oil saturation.Gulong shale has the characteristics of high hardness,a high elastic modulus,and high fracture toughness.This study achieves breakthroughs in the exploration and development of Gulong shale,including the theories of hydrocarbon generation and accumulation,the technologies of mobility and fracturing,and recoverability.It confirms the major transition of Gulong shale from oil generation to oil production,which has extremely significant scientific value and application potential for China’s petroleum industry.
基金The National Natural Science Foundation of China under contract No. 42001078the College Student Innovation and Training Project of Guangdong Ocean University under contract No. S20211056601+3 种基金the Guangdong Natural Science Foundation of China under contract No. 2021A1515011157the Innovative Team Project of Guangdong Universities under contract No.2019KCXTF021the First-class Discipline Plan of Guangdong Province under contract Nos 080503032101 and 231420003the Marine Science Research Team Project of Guangdong Ocean University under contract No. 002026002004。
文摘Past hydroclimatic conditions in southern China are poorly constrained owing to the lack of high-resolution marine-sediment records. In this study, we present high-resolution geochemical and grain-size records of marine sediments from the coastal shelf of the northern South China Sea to investigate regional hydrological variations.Results suggest a warm and humid climate during the interval 9 200–7 600 cal a BP, followed by a cold and dry climate from 7 600 cal a BP to 6 500 cal a BP, and progressive humidification during the period 6 500–6 200 cal a BP.A prominent hydrological anomaly occurred during 7 600–6 500 cal a BP. This abrupt event corresponds closely to tropical Pacific and interhemispheric temperature gradients, suggesting that moisture variations in southern China may have been driven by interhemispheric and zonal Pacific temperature gradients via modulation of the intensity and location of the West Pacific subtropical high.
基金financially supported by Sichuan Science and Technology Program(No.2023YFS0408)。
文摘The(ultra-)mafic mine tailings pond revealed a weathering discrepancy in the tailings profile,which provided a valuable analog to assess the role of carbonate and silicate weathering of the basalt.In this study,drill-cores samples were selected from the Wanniangou V–Ti–Fe mine tailings pond(Sichuan province,China)to investigate the mineralogicand geochemical characteristics in the tailings profile.The results reveal(1)the tailings pond profile consist of upper and lower layers.The upper layer is composed of carbonate weathering(1.4%),which was formed in the initial stages of tailings exposure and represented a minimal weathering degree.(2)The lower layer was primarily observed at the aquifer zone of the tailings pond,and was consistent with 0.45%carbonate weathering and 48.4%silicate weathering.(3)The weathering discrepancy in the tailings profile could be due to the sulfide oxidation and aerobic/flowing aquifer,which facilitate the water-tailings reactions.The tailings profile provides an analog to studying basalt weathering,as it spans both carbonate and silicate weathering.This research reinforces the idea that silicate weathering is predominant in basaltic areas and plays a crucial role in regulating atmospheric CO_(2)(carbon dioxide)levels on Earth.
基金supported by the Key Research and Development Program of Jilin Province(grant No.20230203107SF)the National Natural Science Foundation of China(Grant No.41790453)+1 种基金the National Key Research and Development Program of China(Grant No.2019YFC0605402)the National Major Science and Technology Project of the Ministry of Science and Technology of China(Grant No.2016ZX05026-004-001).
文摘Weathering crust reservoirs have obvious vertical zonation,which is the focus of weathering crust reservoir research,but there is a lack of quantitative characterization indexes.To achieve the quantitative characterization of granite weathering crust reservoir and provide the basis for oil exploration of granite weathering crust buried hill reservoir,in this paper,the vertical zonation of granite weathering crust reservoir is quantitatively divided by testing and analyzing the uniaxial compressive strength(UCS),magnetic susceptibility(MS),permeability,and chemical index of alteration(CIA)of the Mesozoic granite weathering crust in the coastal area of eastern Fujian.The results show that the granite weathering crust reservoir can be divided into four zones vertically:a soil zone(SZ),weathered and dissolved zone(WDZ),fracture zone(FZ),and bedrock zone(BZ).A cataclastic area is developed in the FZ and BZ,in which structural fractures are well-developed,the fracture surface density is usually greater than 200 m/m^(2),and the contribution to the fractures in the rock mass is up to about 50%,making this the sweet spot of the reservoir.In the SZ,the rocks are loose,and the pores are well-developed.The UCS is less than 10 MPa,and the average rate of change of the UCS(Δ_(σ))is 0.90.The average permeability is 2823.00 mD,and the average rate of change of the permeability(Δ_(κ))is 5.13.The average CIA is 74.9%.The average clay mineral content is 7%.The rocks in the WDZ have been significantly weathered by physical and chemical processes,and the weathering fractures and dissolution pores are well-developed.The average UCS is 18.2 MPa,and the averageΔ_(σ)is 0.70.The average permeability is 143.80 mD,and averageΔ_(κ)is 4.17.The average CIA is 65.3%.The average clay mineral content is 4%.Under the influence of tectonic movement and physical weathering,the rocks in the FZ have developed structural fractures and a few weathered fractures.The average UCS is 57.9 MPa,and the averageΔ_(σ)is 0.18.The average permeability is 5.50 mD,and the averageΔ_(κ)is 2.55.The average CIA is 61.6%.The average clay mineral content is 2%.In the BZ,the rocks are intact and hard.The average UCS is 69.9 MPa,and the average Ds is 0.13.The average permeability is 1.46 mD,and the averageΔ_(κ)is 1.43.The average CIA is 57.8%.The average clay mineral content is less than 1%.The multi-parameter combination of the UCS,Δ_(σ),permeability,Δ_(κ),CIA,and clay mineral content achieved good results in the division of the zones of the weathering crust.The UCS increases gradually from top to bottom,while Ds,permeability,Δ_(κ),CIA,and clay mineral content all decrease gradually.In addition,based on the petrophysical parameters of the rocks,including the density,resistivity,and acoustic velocity,a good division effect was also achieved,which can provide a basis for the vertical zonation of the granite buried-hill weathering crust reservoir.
基金Supported by the National Natural Science Foundation of China (41790453,41972313)。
文摘The conventional lithofacies and facies model of subaerial and marine pyroclastic rocks cannot reflect the characteristics of subaqueous volcanic edifice in lacustrine basins.In order to solve this problem,the lithofacies of subaqueous eruptive pyroclastic rocks is discussed and the facies model is established by taking the tuff cone of Cretaceous Huoshiling Formation in the Chaganhua area of the Changling fault depression,Songliao Basin as the research object.The results indicate that the subaqueous eruptive pyroclastic rocks in the Songliao Basin can be divided into two facies and four subfacies.The two facies are the subaqueous explosive facies and the volcanic sedimentary facies that is formed during the eruption interval.The subaqueous explosive facies can be further divided into three subfacies:gas-supported hot pyroclastic flow subfacies,water-laid density current subfacies and subaqueous fallout subfacies.The volcanic sedimentary facies consists of pyroclastic sedimentary rocks containing terrigenous clast subfacies.A typical facies model of the tuff cone that is formed by subaqueous eruptions in the Songliao Basin was established.The tuff cone is generally composed of multiple subaqueous eruption depositional units and can be divided into two facies associations:near-source facies association and far-source facies association.The complete vertical succession of one depositional unit of the near-source facies association is composed of pyroclastic sedimentary rocks containing terrigenous clast subfacies,gas-supported hot pyroclastic flow subfacies,water-laid density current subfacies and subaqueous fallout subfacies from bottom to top.The depositional unit of the far-source facies association is dominated by the subaqueous fallout subfacies and contains several thin interlayered deposits of the water-laid density current subfacies.The gas-supported hot pyroclastic flow subfacies and the pyroclastic sedimentary rocks containing terrigenous clast subfacies are favorable subaqueous eruptive facies for reservoirs in continental lacustrine basins.
文摘This research presents the variation of the gravity field and associated gravity field components over the continental area of Nigeria to provide data for geoscience research,geodetic and engineering works,aerodynamic studies and deep crustal inferences.Accurate positions and elevations were observed at 58 of the 59 base stations of the Primary Gravity Network of Nigeria(PGNN),whose absolute gravity values had been accurately determined.The absolute gravity values were plotted against their respective positions to reveal the distribution pattern and strength of the gravity field within the study area.Theoretical gravity values at each base station were generated using the Somigliana's equation.The free-air gravity and free-air anomaly gravity values were generated with respect to the World Geodetic System 1984(WGS84)ellipsoid using GPS-derived elevation data.Then,the perturbing potential,free-air gravity with respect to the geoid,and the indirect effects were evaluated.The average of the indirect effects was used to adjust the WGS84 gravity formula to produce a gravity formula that better approximates the geoid across the continental area of Nigeria,compatible with the heights measured relative to the geoid,which can serve as a reference for establishing a vertical height control.The Bouguer gravity and Bouguer gravity anomalies across Nigeria revealed a“trans-southern gravity high strip”interpreted to be associated with mantle upwelling.Two new major mega-lineaments related to mantle upwelling were mapped.A batholith province trending NWeSE was delineated,occurring from north central Nigeria to the north western region and containing closures of“Bouguer gravity lows”interpreted as batholiths.A separate closure of“Bouguer gravity low”was detected at Azare,north eastern Nigeria,which may be due to the presence of intrusive granitic body.It is recommended that the mantle structure beneath“the trans-southern gravity high strip”,“delineated batholith province”and“isolated gravity closures”around the northeast of Nigeria should be studied from seismic shear wave splitting analysis for better understanding of the deep lithospheric structures and moho relief.
