Dense corundum-mullite brick for blast furnace ceramic pad was prepared using white fused corundum and tabular corundum as aggregates,andalusite fine powder,sillimanite fine powder,zircon sand powder and Guangxi soil ...Dense corundum-mullite brick for blast furnace ceramic pad was prepared using white fused corundum and tabular corundum as aggregates,andalusite fine powder,sillimanite fine powder,zircon sand powder and Guangxi soil as the matrix,and phosphate as the binder,introducing different amounts ofα-alumina micropowder,tabular corundum fine powder and fused corundum powder.The properties of the prepared brick were studied.The results show that,the brick with 10 mass%of tabular corundum fine powder fired at 1560℃for 3 h in a tunnel kiln has the bulk density of 3.08 g·cm^(-3),the apparent porosity of 13.2%,the cold compressive strength of 178 MPa,the molten iron corrosion rate of 0.6%,the slag corrosion rate of 6.4%,the alkali resistance strength decreasing rate of 7.5%,and the thermal shock resistance of 32 cycles,which is both dense and of good thermal shock resistance.The slag resistance simulation test was performed,which proved that the prepared corundum-mullite brick is better than those currently supplied in the market.展开更多
This study aims to provide the basic knowledge for furnace refractory design by investigating refractory property changes occurred in a hydrogen atmosphere.Since refractory bricks are thermodynamically stable in a hyd...This study aims to provide the basic knowledge for furnace refractory design by investigating refractory property changes occurred in a hydrogen atmosphere.Since refractory bricks are thermodynamically stable in a hydrogen atmosphere at 1100°C,we tried to find out the minute changes.In this experiment,a refractory brick was prepared by andalusite,mullite chamotte,and clay as raw materials and heated to 1100°C in a 100%hydrogen atmosphere for 72 h.It was found that the strength of the brick was decreased and the color was changed to black by the reduction of impurities.And in addition,this study covered research on the slaking risk of MgO raw materials because the minimum temperature is expected to 400°C in fluidized reduction furnaces unlike shaft furnaces.展开更多
With the progress of the times and the leap of science and technology,the application of brick materials and the research on the brick skin in modern architectural design have shown a dual-track development trend of r...With the progress of the times and the leap of science and technology,the application of brick materials and the research on the brick skin in modern architectural design have shown a dual-track development trend of returning to tradition and innovation.Based on the core collection database resources of Web of Science and the CiteSpace visual analysis tool,this paper constructed and analyzed the spatio-temporal map of keyword co-occurrence network,cluster structure,mutation phenomenon,time course and regional distribution map of building brick skin research.The study revealed that in recent years,the research on brick materials has spanned the study of single material properties and extensively involved in the broad world of construction,especially in the integration of green energy-saving technology,the innovation of fine construction technology of brick skin,and the frontier exploration of digital technology in brick masonry,which has shown particularly significant research vitality and development potential.展开更多
The aim of this study was to evaluate the compressive strength of clay bricks and their stability to water absorption by inserting stabilizers such as lime and cement of 0%, 4%, 6%, 8%, 10%, 12% to 14%. Spectrometric ...The aim of this study was to evaluate the compressive strength of clay bricks and their stability to water absorption by inserting stabilizers such as lime and cement of 0%, 4%, 6%, 8%, 10%, 12% to 14%. Spectrometric analysis was used to characterize the various stabilizers and the clay used, and tests of resistance and water absorption were also carried out. The clay was found to be an aluminosilicate (15.55% to 17.17% Al2O3 and 42.12% to 44.15% SiO2). The lime contains 90.84% CaO and the cement has 17.80% SiO2, 3.46% Al2O3, 2.43% Fe2O3 and 58.47% CaO in the combined form of tricalcium silicate, dicalcium silicate, tricalcium aluminate and ferro-tetra calcium aluminate. The results showed that the insertion of locally available stabilizers (lime and cement) improved the strength of the material by almost 80% when the lime was increased from 0% to 14% for 14 days. For compressed cement, a 65% increase in strength was observed under the same conditions. Strength increases with drying time, with a 52% increase in strength at 28 days compared to 14 days. Furthermore, compressed cement bricks have a more compact structure, absorbing very little water (32%). In view of all these results, cement appears to be the best stabilizer, and compression improves compressive strength and reduces water absorption.展开更多
Corundum-mullite porous ceramics(CMPCs)were fabricated using fly ash and aluminum ash as the raw materials,adding different amounts of starch(0,10%,20%,and 30%,by mass)as the pore-forming agent,molding and firing at 1...Corundum-mullite porous ceramics(CMPCs)were fabricated using fly ash and aluminum ash as the raw materials,adding different amounts of starch(0,10%,20%,and 30%,by mass)as the pore-forming agent,molding and firing at 1200℃ for 1 h.The apparent porosity,the bulk density,the cold compressive strength,the thermal shock resistance and the thermal conductivity of the CMPCs were tested.The phase composition and the microstructure of the CMPCs were characterized by XRD and SEM.The effect of the starch addition on the properties of the CMPCs was studied.The results show that:(1)the CMPCs with high porosity can be successfully prepared by adding starch as the pore-forming agent and firing at 1200℃ for 1 h;(2)with the starch addition increasing,the porosity increases;the cold compressive strength and the number of the quenching cycles of the CMPCs decrease,but they remain at high levels;meanwhile,the thermal conductivity decreases;(3)generally,when adding 20 mass%starch,the CMPC has the apparent porosity of 48.6%,the cold compressive strength of 52.1 MPa,the quenching cycles of 5 and the thermal conductivity of 1.63 W·m-1·K-1 and 1.52 W·m-1·K-1,respectively,at 25℃ and 500℃,showing good performance.展开更多
Conversion-type fluoride cathode can provide considerable energy density for Li batteries,however its scalable and facile synthesis strategies are still lacking.Here,a novel Fe-based deep eutectic solvent composed of ...Conversion-type fluoride cathode can provide considerable energy density for Li batteries,however its scalable and facile synthesis strategies are still lacking.Here,a novel Fe-based deep eutectic solvent composed of nitrite and methylsulfonylmethane is proposed as both the reaction medium and precursor to synthesize O-doped FeF3porous bricks.This method is cheaper,safe,mildly operable,environmentally friendly and recyclable for non-fluorinated metal cations.The homogenization of charge and mass transport in cathode network effectively mitigates the volume extrusion and electrode coarsening even for the micro-sized monolithic particles.The Co-solvation modulated fluoride cathode delivers high reversible capacity in a wide temperature range(486 and 235 mA h g^(-1)at 25℃ and-20℃ respectively),excellent rate performance(312 mA h g^(-1)at 1000 mA g^(-1)),corresponding to an energy density as high as672.1 W h kg^(-1)under a power density of 2154.3 W kg^(-1).The successful operation of fluoride pouchcell with a capacity exceeding 450 mA h g^(-1)(even under thin Li foil and lean electrolyte conditions) indicates its potentiality of commercial application.展开更多
Fuzhuan brick-tea(FZT)has long been consumed for its supposed weight loss and lipid-lowering benefi ts.In this study,we show that the regulation of fat storage in Caenorhabditis elegans from a water extract of FZT was...Fuzhuan brick-tea(FZT)has long been consumed for its supposed weight loss and lipid-lowering benefi ts.In this study,we show that the regulation of fat storage in Caenorhabditis elegans from a water extract of FZT was affected by cholesterol levels.We found that FZT signifi cantly decreased fat storage under normal cholesterol levels or in a cholesterol-free diet,while lipid accumulation was increased for a high cholesterol diet.Moreover,this mechanism may involve the conserved sterol regulatory element-binding protein(SREBP)/mediator-15(MDT-15)signaling pathway and the nuclear hormone receptor NHR-80.In addition,lipid synthesis-related genes inhibited by FZT were partially affected by a cholesterol-free diet.Thus,our fi ndings suggested that the potential lipid-lowering effects of FZT may depend on the cholesterol level,which may help to improve the consumption of FZT.展开更多
Due to differences in the properties of composition materials and construction techniques,unreinforced masonry is characterized by low strength,anisotropy,nonuniformity,and low ductility.In order to accurately simulat...Due to differences in the properties of composition materials and construction techniques,unreinforced masonry is characterized by low strength,anisotropy,nonuniformity,and low ductility.In order to accurately simulate the mechanical behavior of unreinforced brick masonry walls under static and dynamic loads,a new elastoplastic damage constitutive model was proposed and the corresponding subroutine was developed based on the concrete material constitutive model.In the proposed constitutive model,the Rankine strength theory and the Drucker-Prager strength theory were used to define the tensile and compressive yield surface function of materials,respectively.Moreover,the stress updating algorithm was modified to consider the tensile plastic permanent deformation of masonry materials.To verify the accuracy of the proposed constitutive model,numerical simulations of the brick masonry under monotonic and cyclic uniaxial tension and compression loads were carried out.Comparisons among the numerical and theoretical and experimental results show that the proposed model can properly reflect the masonry material mechanical properties.Furthermore,the numerical models of four pieces of masonry walls with different mortar strengths were established.Low cyclic loadings were applied and the results show that the proposed constitutive model can properly simulate the wall shear failure characteristics,and the force-displacement hysteretic curves obtained by numerical simulation are in good agreement with the tests.Overall,the proposed elastic-plastic damage constitutive model can simulate the nonlinear behavior of unreinforced brick masonry walls very well,and can be used to predict the structural response of masonry walls.展开更多
Fixed-bed operating experimental column conditions were studied to evaluate the performance of brick from Bangui Region (in Central African Republic), coated with iron oxyhydroxide (ferrihydrite) for the removal of ir...Fixed-bed operating experimental column conditions were studied to evaluate the performance of brick from Bangui Region (in Central African Republic), coated with iron oxyhydroxide (ferrihydrite) for the removal of iron(II) from aqueous solution. The prediction of theoretical breakthrough profiles using Bohart and Adams sorption model was employed to achieve characteristic parameters such as depth of exchange zone, time required for exchange zone to move vertically, moving rate for the exchange zone and adsorption capacity useful for fixed-bed column reactor was investigated under varying operating conditions. The effects of bed depth and flow rate on iron(II) adsorption were studied. Our finding revealed that the Brick from Bangui Region (in Central African Republic), coated with ferrihydrite was a very efficient media for the removal of Fe(II) ions from water. The experimental data showed that the depth and the moving rate (10.3 ± 0.6 cm) and (0.208 ± 0.006 cm/min) respectively of the exchange zone (adsorption zone) were independent of variability of the height of the adsorbent bed column, however the variations of the flow rate affect the moving rate of the exchange zone. The bed depth service time (BDST) model was used and permitted us to predict the service times of columns operated at various flow rates and bed depths and these predicted values were compared with the experimental values.展开更多
Taking an industrial sludge and its preparation of sludge wrap shell aggregates(WSAs)instead of sand to prepare baking-free brick as the research object,the development law of mechanical properties and the influence m...Taking an industrial sludge and its preparation of sludge wrap shell aggregates(WSAs)instead of sand to prepare baking-free brick as the research object,the development law of mechanical properties and the influence mechanism of macro and micro characteristic parameters of the bricks under different sludge and WSAs replacement rates were studied through the macroscopic mechanical properties test,with the help of nuclear magnetic resonance(NMR),transmission electron microscopy-energy spectrum and other testing technology and pores and cracks analysis system(PCAS)software.The results showed that the compressive strength of each sample decreased with the increase of sludge content.When the sludge content was less than 30%,it was mainly affected by the water-binder ratio.When the sludge content was more than 30%,it was mainly affected by the sludge content.At the age of 7 days,with the increase in replacement rate of WSAs,the compressive strength of the S10 and S30 groups was higher than that of the control group.The compressive strength of the S50 experimental group was 30.38 MPa,and the loss of compressive strength was slight compared with the control group.The water absorption rate of the 28 days S100 experimental group increased by 10.71%compared with the control group.When the content of WSAs was less than 50%,the holes above 0.1μm in the brick can be reduced and transformed into smaller holes,with a decreasing trend of the plane porosity of the brick.The microscopic results of the baking-free brick showed that the three-phase system of WSAs-interface transition area-mortar was poorly bonded and delaminated compared with the gravel aggregate-interface transition area-mortar system,and damage was more likely to occur in the WSAs and interface transition area.The above results show that it is feasible to use sludge and WSAs instead of sand for the preparation of baking-free bricks.This technology not only solves the problem of sludge disposal,but also protects the over-exploitation of mineral resources,and the technology has a broad application prospect and market value.展开更多
The current study deals Swith thermo-mechanical properties of stabilized soil small bricks with the help of organic binders of sugar cane molasses and cassava starch. Different formulations of soil concrete have been ...The current study deals Swith thermo-mechanical properties of stabilized soil small bricks with the help of organic binders of sugar cane molasses and cassava starch. Different formulations of soil concrete have been suggested after the geotechnical characterization of samples of soil was taken. From these, it arises that the studied soil is the most plastically clay (of type A<sub>3</sub>) according to GTR classification. Samples made of small bricks and measured out at 4%, 6% and 8% of binders (molasses, starch or molasses + starch) have been warmed up to different temperatures (100°C, 150°C, 200°C and 250°C) for the rising of the thermic behavior under different conditions and submitted to crushing testings for the estimation of characteristic resistances to the compression. According to the mechanical behavior, we note an improvement of resistances for small bricks measured 4%, 6% and 8%, of molasses respectively of 32.44%, 32.06% and 23.43% against the value of reference for small bricks without molasses. In the same way, the binder (molasses + starch) also reveals an improvement of resistance to the compression of 13.27%, 26.17% and 26.17%. On the contrary, the stabilization with the starch binder did not bring a significative improvement. According to the thermic influence, the heating at 100°C of stabilized small bricks at 4%, 6% and 8% of molasses, reveals a significative improvement of resistances. Moreover, the stabilization with the starch reveals on the contrary a good behavior for heatings at 150°C and 250°C. In short, for the binder (molasses + starch), it is the heating at 200°C that shows some improvements of remarkable resistances. Different analyses of realized statistics also show the effectivity of obtained results. For all realized formulations, the measuring out at 6% of binders (molasses, or molasses + starch) seems as optimal in front of the best thermo-mechanical revealed properties.展开更多
This paper reports the modeling of residual compressive strength of fired clay bricks submitted to elevated temperature. Five formulations were used and the explored temperatures were 95˚C, 200˚C, 550˚C, 700˚C and 950...This paper reports the modeling of residual compressive strength of fired clay bricks submitted to elevated temperature. Five formulations were used and the explored temperatures were 95˚C, 200˚C, 550˚C, 700˚C and 950˚C. The stress–strain relationships and the mechanical properties (including Young’s modulus and compressive strength) were assessed using a uniaxial compressive strength machine. A proposed model equation was established and found satisfying. The elastic modulus was evaluated and tested with one existing model together with two proposed models. The proposed model was both satisfying and even more precise than the existing one. The overall results show that the effect of temperature on the mechanical properties of clays can be accurately described through the definition of thermal damage using elastic modulus.展开更多
To reduce production costs and make full and reasonable use of raw materials,high alumina bricks were prepared using tabular corundum and mullite as aggregates,sillimanite as intermediate particles,and white fused cor...To reduce production costs and make full and reasonable use of raw materials,high alumina bricks were prepared using tabular corundum and mullite as aggregates,sillimanite as intermediate particles,and white fused corundum powder,α-alumina micropowder,and Suzhou soil as the matrix,firing at different temperatures(1420,1440,1460,1480,1500 and 1520℃)for 4 h.The apparent porosity(AP),the bulk density(BD),the cold crushing strength(CCS),the thermal shock resistance(TSR),the refractoriness under load(RUL)and the creep rate of the samples were tested.The effects of the firing temperature on the creep rate(1450℃×50 h,under a load of 0.2 MPa)of the samples were studied.The results show that with the sillimanite addition of 22.5 mass%,the sample fired at 1460℃for 4 h performs the best comprehensive properties:the AP of 17.5%,the BD of 2.75 g·cm^(-3),the CCS of 100.5 MPa,the TSR number of 35 cycles,the RUL of 1682℃,and the creep rate of-0.428%,which can prolong the service life of furnaces.展开更多
The present work investigated the effect of polyethylene terephthalate (PET) plastic waste on the physico-mechanical and thermal properties of cement-stabilized laterite bricks to see the durability of the modified br...The present work investigated the effect of polyethylene terephthalate (PET) plastic waste on the physico-mechanical and thermal properties of cement-stabilized laterite bricks to see the durability of the modified bricks (CSLB). Samples were formulated by mixing laterite, cement, and different percentages of PET (0%, 3%, 5%, and 7%) by volume. The bricks were produced using the M7MI Hydraform standard interlocking block and kept in the shade for a curing period of 28 days. The addition of 3% to 5% PET to the laterite stabilized with 10% cement results in a decrease in both dry and wet compressive strength, which is determined using the Controlab compression machine. However, the obtained results are in concordance with the standards. The thermal conductivity of CSLB, determined using the box method with the EI700 measurement cell, decreases as the PET content of the mixture increases. A decrease in bulk density from 1.67 to 1.58 g/cm<sup>3</sup> was observed.展开更多
This article deals with the characterization of local materials used in insulation building heat. These materials are bricks of earth compressed and stabilized with rice husks. Thermal conductivity, the specific heat ...This article deals with the characterization of local materials used in insulation building heat. These materials are bricks of earth compressed and stabilized with rice husks. Thermal conductivity, the specific heat and the thermal diffusivity of materials based on clay incorporating rate of 0, 2%, 4%, 6%, 8% and 10% are determined. The results showed that the clay blocks + rice balls had better thermal insulators than simple clay blocks. However, these composite materials used for the envelope of the building must have sufficient mechanical resistance when used in construction. The measurement of mechanical properties such as compressive strength showed an improvement of 6% and beyond, a drop in resistance when increasing rice husks in clay is observed. These results allow to specify the optimal conditions of use of these materials for the building envelope.展开更多
This paper presents an experimental study of the characterisation of local materials used in the construction and thermal insulation of buildings. These materials are compressed earth bricks stabilised with cement and...This paper presents an experimental study of the characterisation of local materials used in the construction and thermal insulation of buildings. These materials are compressed earth bricks stabilised with cement and sawdust. The thermal conductivity, diffusivity, effusivity, and specific heat of earth-based materials containing cement or sawdust have been determined. The results show that the blocks with earth + sawdust are better thermal insulators than the blocks with simple earth. We observe an improvement in thermal efficiency depending on the presence of sawdust or cement stabilisers. For cement stabilisation, the thermal conductivity increases (λ: 1.04 to 1.36 W·m<sup>-1</sup>·K<sup>-1</sup>), the diffusivity increases (from 4.32 × 10<sup>-7</sup> to 9.82 × 10<sup>-7</sup> m<sup>2</sup>·s<sup>-1</sup>), and the effusivity decreases (1404 - 1096 J·m<sup>-2</sup>·K<sup>-1</sup>·s<sup>-1/2</sup>). For sawdust stabilisation, the thermal conductivity decreases (λ: 1.04 to 0.64 W·m<sup>-1</sup>·K<sup>-1</sup>), the diffusivity increases (from 4.32 × 10<sup>-7</sup> to 5.9 × 10<sup>-7</sup> m<sup>2</sup>·s<sup>-1</sup>), and the effusivity decreases (1404 - 906 J·m<sup>-2</sup>·K<sup>-1</sup>·s<sup>-1/2</sup>). Improving the structural and thermal efficiency of BTC via stabilisation with derived binders or cement is beneficial for the load-bearing capacity and thermal performance of buildings.展开更多
Building construction using cement bricks on the one hand,and mud bricks on the other hand,presents problems of resistance and durability in the face of natural weathering in our country(Republic of Guinea).These diff...Building construction using cement bricks on the one hand,and mud bricks on the other hand,presents problems of resistance and durability in the face of natural weathering in our country(Republic of Guinea).These difficulties could be linked to non-compliance with standards and the failure to master certain physico-chemical,mechanical and technical parameters when constructing a building.In order to remedy this problem,a series of studies were carried out on samples of mud bricks used in the construction of century-old straw hut buildings in the urban commune of Kouroussa(Republic of Guinea).To this end,the compressive strength of the brick samples was assessed either:0.10 MPa,and sensory techniques of certain characteristics were carried out to evaluate the cohesion of the elements in the brick samples,such as:coward boule technique,hand washing test,withdrawal of a soil(pellet or ring test)and of the jar test.The physico-chemical analyses methods were carried out using XRF(X-Ray Fluorescence Spectrometry),granulometry and Atterberg limits in accordance with NF P 94-051.These results showed a high insoluble residue content(49.9%)and the sample had a clay-like appearance with a low PI(Plasticity Index)=8%.This study could be an alternative guide for the authorities in charge of housing and construction in the Kouroussa prefecture(Republic of Guinea).because,the majority of houses in Upper Guinea are built with mud raw bricks or fired bricks.展开更多
Phase change materials(PCMs)are an interesting technology due to their high density and isothermal behavior during phase change.Phase change material plays a major role in the energy saving of the buildings,which is g...Phase change materials(PCMs)are an interesting technology due to their high density and isothermal behavior during phase change.Phase change material plays a major role in the energy saving of the buildings,which is greatly aided by the incorporation of phase change material into building products such as bricks,cement,gypsum board,etc.In this study,an experiment has been conducted with three identical small chambers made up of normal,grooved and PCM-treated grooved bricks.Before the inclusion of PCM in grooved bricks,PCM material behavior has been studied by different techniques such as DSC,TG/DTA,SEM,and XRD.Thermal properties and thermal stability were investigated by differential scanning calorimeter(DSC)and thermogravimetric analyzer(TGA)respectively.Scanning electron microscopy(SEM)and X-ray diffraction(XRD)were used to determine the microstructure and crystalloid phase of the PCM before and after the accelerated thermal cycling test(0,60,120).These three identical model rooms built were exposed at a temperature just above 40°C with a heater.When the maximum outdoor temperature was 40-41°C,then the temperature of the PCM-treated grooved chamber was 32-33°C.The PCM-treated wall was tested and compared with a conventional and grooved wall.The difference between the PCM-treated grooved chamber and the untreated one was 8-9°C.PCM-treated bricks provided more efficient internal heat retention in summer when the outside temperature increased.展开更多
文摘Dense corundum-mullite brick for blast furnace ceramic pad was prepared using white fused corundum and tabular corundum as aggregates,andalusite fine powder,sillimanite fine powder,zircon sand powder and Guangxi soil as the matrix,and phosphate as the binder,introducing different amounts ofα-alumina micropowder,tabular corundum fine powder and fused corundum powder.The properties of the prepared brick were studied.The results show that,the brick with 10 mass%of tabular corundum fine powder fired at 1560℃for 3 h in a tunnel kiln has the bulk density of 3.08 g·cm^(-3),the apparent porosity of 13.2%,the cold compressive strength of 178 MPa,the molten iron corrosion rate of 0.6%,the slag corrosion rate of 6.4%,the alkali resistance strength decreasing rate of 7.5%,and the thermal shock resistance of 32 cycles,which is both dense and of good thermal shock resistance.The slag resistance simulation test was performed,which proved that the prepared corundum-mullite brick is better than those currently supplied in the market.
基金supported by the Korea Planning & Evaluation Institute of Industrial Technology (KEIT)the Ministry of Trade, Industry & Energy (MOTIE, Korea) of the Republic of Korea (No. RS2023-00262421)
文摘This study aims to provide the basic knowledge for furnace refractory design by investigating refractory property changes occurred in a hydrogen atmosphere.Since refractory bricks are thermodynamically stable in a hydrogen atmosphere at 1100°C,we tried to find out the minute changes.In this experiment,a refractory brick was prepared by andalusite,mullite chamotte,and clay as raw materials and heated to 1100°C in a 100%hydrogen atmosphere for 72 h.It was found that the strength of the brick was decreased and the color was changed to black by the reduction of impurities.And in addition,this study covered research on the slaking risk of MgO raw materials because the minimum temperature is expected to 400°C in fluidized reduction furnaces unlike shaft furnaces.
文摘With the progress of the times and the leap of science and technology,the application of brick materials and the research on the brick skin in modern architectural design have shown a dual-track development trend of returning to tradition and innovation.Based on the core collection database resources of Web of Science and the CiteSpace visual analysis tool,this paper constructed and analyzed the spatio-temporal map of keyword co-occurrence network,cluster structure,mutation phenomenon,time course and regional distribution map of building brick skin research.The study revealed that in recent years,the research on brick materials has spanned the study of single material properties and extensively involved in the broad world of construction,especially in the integration of green energy-saving technology,the innovation of fine construction technology of brick skin,and the frontier exploration of digital technology in brick masonry,which has shown particularly significant research vitality and development potential.
文摘The aim of this study was to evaluate the compressive strength of clay bricks and their stability to water absorption by inserting stabilizers such as lime and cement of 0%, 4%, 6%, 8%, 10%, 12% to 14%. Spectrometric analysis was used to characterize the various stabilizers and the clay used, and tests of resistance and water absorption were also carried out. The clay was found to be an aluminosilicate (15.55% to 17.17% Al2O3 and 42.12% to 44.15% SiO2). The lime contains 90.84% CaO and the cement has 17.80% SiO2, 3.46% Al2O3, 2.43% Fe2O3 and 58.47% CaO in the combined form of tricalcium silicate, dicalcium silicate, tricalcium aluminate and ferro-tetra calcium aluminate. The results showed that the insertion of locally available stabilizers (lime and cement) improved the strength of the material by almost 80% when the lime was increased from 0% to 14% for 14 days. For compressed cement, a 65% increase in strength was observed under the same conditions. Strength increases with drying time, with a 52% increase in strength at 28 days compared to 14 days. Furthermore, compressed cement bricks have a more compact structure, absorbing very little water (32%). In view of all these results, cement appears to be the best stabilizer, and compression improves compressive strength and reduces water absorption.
基金The authors gratefully acknowledged the supports of National Natural Science Foundation of China(Grant No.U1908227)open research fund for State Key Laboratory of Advanced Refractories(Grant No.SKLAR201904).
文摘Corundum-mullite porous ceramics(CMPCs)were fabricated using fly ash and aluminum ash as the raw materials,adding different amounts of starch(0,10%,20%,and 30%,by mass)as the pore-forming agent,molding and firing at 1200℃ for 1 h.The apparent porosity,the bulk density,the cold compressive strength,the thermal shock resistance and the thermal conductivity of the CMPCs were tested.The phase composition and the microstructure of the CMPCs were characterized by XRD and SEM.The effect of the starch addition on the properties of the CMPCs was studied.The results show that:(1)the CMPCs with high porosity can be successfully prepared by adding starch as the pore-forming agent and firing at 1200℃ for 1 h;(2)with the starch addition increasing,the porosity increases;the cold compressive strength and the number of the quenching cycles of the CMPCs decrease,but they remain at high levels;meanwhile,the thermal conductivity decreases;(3)generally,when adding 20 mass%starch,the CMPC has the apparent porosity of 48.6%,the cold compressive strength of 52.1 MPa,the quenching cycles of 5 and the thermal conductivity of 1.63 W·m-1·K-1 and 1.52 W·m-1·K-1,respectively,at 25℃ and 500℃,showing good performance.
基金supported by the National Natural Science Foundation of China(51772313,21975276 and 52102329)the Shanghai Science and Technology Committee(20520710800)support by the Program of Shanghai Academic Research Leader(21XD1424400)。
文摘Conversion-type fluoride cathode can provide considerable energy density for Li batteries,however its scalable and facile synthesis strategies are still lacking.Here,a novel Fe-based deep eutectic solvent composed of nitrite and methylsulfonylmethane is proposed as both the reaction medium and precursor to synthesize O-doped FeF3porous bricks.This method is cheaper,safe,mildly operable,environmentally friendly and recyclable for non-fluorinated metal cations.The homogenization of charge and mass transport in cathode network effectively mitigates the volume extrusion and electrode coarsening even for the micro-sized monolithic particles.The Co-solvation modulated fluoride cathode delivers high reversible capacity in a wide temperature range(486 and 235 mA h g^(-1)at 25℃ and-20℃ respectively),excellent rate performance(312 mA h g^(-1)at 1000 mA g^(-1)),corresponding to an energy density as high as672.1 W h kg^(-1)under a power density of 2154.3 W kg^(-1).The successful operation of fluoride pouchcell with a capacity exceeding 450 mA h g^(-1)(even under thin Li foil and lean electrolyte conditions) indicates its potentiality of commercial application.
基金supported by the National Natural Science Foundation of China(31801547)Some C.elegans strains were provided by CGC,which is funded by the NIH Office of Research Infrastructure Programs.
文摘Fuzhuan brick-tea(FZT)has long been consumed for its supposed weight loss and lipid-lowering benefi ts.In this study,we show that the regulation of fat storage in Caenorhabditis elegans from a water extract of FZT was affected by cholesterol levels.We found that FZT signifi cantly decreased fat storage under normal cholesterol levels or in a cholesterol-free diet,while lipid accumulation was increased for a high cholesterol diet.Moreover,this mechanism may involve the conserved sterol regulatory element-binding protein(SREBP)/mediator-15(MDT-15)signaling pathway and the nuclear hormone receptor NHR-80.In addition,lipid synthesis-related genes inhibited by FZT were partially affected by a cholesterol-free diet.Thus,our fi ndings suggested that the potential lipid-lowering effects of FZT may depend on the cholesterol level,which may help to improve the consumption of FZT.
基金National Key Research and Development Program of China under Grant Nos.2018YFC1504400 and 2019YFC1509301Natural Science Foundation of China under Grant No.52078471Scientific Research Fund of Institute of Engineering Mechanics,China Earthquake Administration under Grant No.2019EEEVL0402。
文摘Due to differences in the properties of composition materials and construction techniques,unreinforced masonry is characterized by low strength,anisotropy,nonuniformity,and low ductility.In order to accurately simulate the mechanical behavior of unreinforced brick masonry walls under static and dynamic loads,a new elastoplastic damage constitutive model was proposed and the corresponding subroutine was developed based on the concrete material constitutive model.In the proposed constitutive model,the Rankine strength theory and the Drucker-Prager strength theory were used to define the tensile and compressive yield surface function of materials,respectively.Moreover,the stress updating algorithm was modified to consider the tensile plastic permanent deformation of masonry materials.To verify the accuracy of the proposed constitutive model,numerical simulations of the brick masonry under monotonic and cyclic uniaxial tension and compression loads were carried out.Comparisons among the numerical and theoretical and experimental results show that the proposed model can properly reflect the masonry material mechanical properties.Furthermore,the numerical models of four pieces of masonry walls with different mortar strengths were established.Low cyclic loadings were applied and the results show that the proposed constitutive model can properly simulate the wall shear failure characteristics,and the force-displacement hysteretic curves obtained by numerical simulation are in good agreement with the tests.Overall,the proposed elastic-plastic damage constitutive model can simulate the nonlinear behavior of unreinforced brick masonry walls very well,and can be used to predict the structural response of masonry walls.
文摘Fixed-bed operating experimental column conditions were studied to evaluate the performance of brick from Bangui Region (in Central African Republic), coated with iron oxyhydroxide (ferrihydrite) for the removal of iron(II) from aqueous solution. The prediction of theoretical breakthrough profiles using Bohart and Adams sorption model was employed to achieve characteristic parameters such as depth of exchange zone, time required for exchange zone to move vertically, moving rate for the exchange zone and adsorption capacity useful for fixed-bed column reactor was investigated under varying operating conditions. The effects of bed depth and flow rate on iron(II) adsorption were studied. Our finding revealed that the Brick from Bangui Region (in Central African Republic), coated with ferrihydrite was a very efficient media for the removal of Fe(II) ions from water. The experimental data showed that the depth and the moving rate (10.3 ± 0.6 cm) and (0.208 ± 0.006 cm/min) respectively of the exchange zone (adsorption zone) were independent of variability of the height of the adsorbent bed column, however the variations of the flow rate affect the moving rate of the exchange zone. The bed depth service time (BDST) model was used and permitted us to predict the service times of columns operated at various flow rates and bed depths and these predicted values were compared with the experimental values.
基金the Natural Science Foundation of Henan Province(202300410270)Graduate Education Innovation Program fund of North China University of Water Resources and Electric Power(YK-2021-49).
文摘Taking an industrial sludge and its preparation of sludge wrap shell aggregates(WSAs)instead of sand to prepare baking-free brick as the research object,the development law of mechanical properties and the influence mechanism of macro and micro characteristic parameters of the bricks under different sludge and WSAs replacement rates were studied through the macroscopic mechanical properties test,with the help of nuclear magnetic resonance(NMR),transmission electron microscopy-energy spectrum and other testing technology and pores and cracks analysis system(PCAS)software.The results showed that the compressive strength of each sample decreased with the increase of sludge content.When the sludge content was less than 30%,it was mainly affected by the water-binder ratio.When the sludge content was more than 30%,it was mainly affected by the sludge content.At the age of 7 days,with the increase in replacement rate of WSAs,the compressive strength of the S10 and S30 groups was higher than that of the control group.The compressive strength of the S50 experimental group was 30.38 MPa,and the loss of compressive strength was slight compared with the control group.The water absorption rate of the 28 days S100 experimental group increased by 10.71%compared with the control group.When the content of WSAs was less than 50%,the holes above 0.1μm in the brick can be reduced and transformed into smaller holes,with a decreasing trend of the plane porosity of the brick.The microscopic results of the baking-free brick showed that the three-phase system of WSAs-interface transition area-mortar was poorly bonded and delaminated compared with the gravel aggregate-interface transition area-mortar system,and damage was more likely to occur in the WSAs and interface transition area.The above results show that it is feasible to use sludge and WSAs instead of sand for the preparation of baking-free bricks.This technology not only solves the problem of sludge disposal,but also protects the over-exploitation of mineral resources,and the technology has a broad application prospect and market value.
文摘The current study deals Swith thermo-mechanical properties of stabilized soil small bricks with the help of organic binders of sugar cane molasses and cassava starch. Different formulations of soil concrete have been suggested after the geotechnical characterization of samples of soil was taken. From these, it arises that the studied soil is the most plastically clay (of type A<sub>3</sub>) according to GTR classification. Samples made of small bricks and measured out at 4%, 6% and 8% of binders (molasses, starch or molasses + starch) have been warmed up to different temperatures (100°C, 150°C, 200°C and 250°C) for the rising of the thermic behavior under different conditions and submitted to crushing testings for the estimation of characteristic resistances to the compression. According to the mechanical behavior, we note an improvement of resistances for small bricks measured 4%, 6% and 8%, of molasses respectively of 32.44%, 32.06% and 23.43% against the value of reference for small bricks without molasses. In the same way, the binder (molasses + starch) also reveals an improvement of resistance to the compression of 13.27%, 26.17% and 26.17%. On the contrary, the stabilization with the starch binder did not bring a significative improvement. According to the thermic influence, the heating at 100°C of stabilized small bricks at 4%, 6% and 8% of molasses, reveals a significative improvement of resistances. Moreover, the stabilization with the starch reveals on the contrary a good behavior for heatings at 150°C and 250°C. In short, for the binder (molasses + starch), it is the heating at 200°C that shows some improvements of remarkable resistances. Different analyses of realized statistics also show the effectivity of obtained results. For all realized formulations, the measuring out at 6% of binders (molasses, or molasses + starch) seems as optimal in front of the best thermo-mechanical revealed properties.
文摘This paper reports the modeling of residual compressive strength of fired clay bricks submitted to elevated temperature. Five formulations were used and the explored temperatures were 95˚C, 200˚C, 550˚C, 700˚C and 950˚C. The stress–strain relationships and the mechanical properties (including Young’s modulus and compressive strength) were assessed using a uniaxial compressive strength machine. A proposed model equation was established and found satisfying. The elastic modulus was evaluated and tested with one existing model together with two proposed models. The proposed model was both satisfying and even more precise than the existing one. The overall results show that the effect of temperature on the mechanical properties of clays can be accurately described through the definition of thermal damage using elastic modulus.
文摘To reduce production costs and make full and reasonable use of raw materials,high alumina bricks were prepared using tabular corundum and mullite as aggregates,sillimanite as intermediate particles,and white fused corundum powder,α-alumina micropowder,and Suzhou soil as the matrix,firing at different temperatures(1420,1440,1460,1480,1500 and 1520℃)for 4 h.The apparent porosity(AP),the bulk density(BD),the cold crushing strength(CCS),the thermal shock resistance(TSR),the refractoriness under load(RUL)and the creep rate of the samples were tested.The effects of the firing temperature on the creep rate(1450℃×50 h,under a load of 0.2 MPa)of the samples were studied.The results show that with the sillimanite addition of 22.5 mass%,the sample fired at 1460℃for 4 h performs the best comprehensive properties:the AP of 17.5%,the BD of 2.75 g·cm^(-3),the CCS of 100.5 MPa,the TSR number of 35 cycles,the RUL of 1682℃,and the creep rate of-0.428%,which can prolong the service life of furnaces.
文摘The present work investigated the effect of polyethylene terephthalate (PET) plastic waste on the physico-mechanical and thermal properties of cement-stabilized laterite bricks to see the durability of the modified bricks (CSLB). Samples were formulated by mixing laterite, cement, and different percentages of PET (0%, 3%, 5%, and 7%) by volume. The bricks were produced using the M7MI Hydraform standard interlocking block and kept in the shade for a curing period of 28 days. The addition of 3% to 5% PET to the laterite stabilized with 10% cement results in a decrease in both dry and wet compressive strength, which is determined using the Controlab compression machine. However, the obtained results are in concordance with the standards. The thermal conductivity of CSLB, determined using the box method with the EI700 measurement cell, decreases as the PET content of the mixture increases. A decrease in bulk density from 1.67 to 1.58 g/cm<sup>3</sup> was observed.
文摘This article deals with the characterization of local materials used in insulation building heat. These materials are bricks of earth compressed and stabilized with rice husks. Thermal conductivity, the specific heat and the thermal diffusivity of materials based on clay incorporating rate of 0, 2%, 4%, 6%, 8% and 10% are determined. The results showed that the clay blocks + rice balls had better thermal insulators than simple clay blocks. However, these composite materials used for the envelope of the building must have sufficient mechanical resistance when used in construction. The measurement of mechanical properties such as compressive strength showed an improvement of 6% and beyond, a drop in resistance when increasing rice husks in clay is observed. These results allow to specify the optimal conditions of use of these materials for the building envelope.
文摘This paper presents an experimental study of the characterisation of local materials used in the construction and thermal insulation of buildings. These materials are compressed earth bricks stabilised with cement and sawdust. The thermal conductivity, diffusivity, effusivity, and specific heat of earth-based materials containing cement or sawdust have been determined. The results show that the blocks with earth + sawdust are better thermal insulators than the blocks with simple earth. We observe an improvement in thermal efficiency depending on the presence of sawdust or cement stabilisers. For cement stabilisation, the thermal conductivity increases (λ: 1.04 to 1.36 W·m<sup>-1</sup>·K<sup>-1</sup>), the diffusivity increases (from 4.32 × 10<sup>-7</sup> to 9.82 × 10<sup>-7</sup> m<sup>2</sup>·s<sup>-1</sup>), and the effusivity decreases (1404 - 1096 J·m<sup>-2</sup>·K<sup>-1</sup>·s<sup>-1/2</sup>). For sawdust stabilisation, the thermal conductivity decreases (λ: 1.04 to 0.64 W·m<sup>-1</sup>·K<sup>-1</sup>), the diffusivity increases (from 4.32 × 10<sup>-7</sup> to 5.9 × 10<sup>-7</sup> m<sup>2</sup>·s<sup>-1</sup>), and the effusivity decreases (1404 - 906 J·m<sup>-2</sup>·K<sup>-1</sup>·s<sup>-1/2</sup>). Improving the structural and thermal efficiency of BTC via stabilisation with derived binders or cement is beneficial for the load-bearing capacity and thermal performance of buildings.
文摘Building construction using cement bricks on the one hand,and mud bricks on the other hand,presents problems of resistance and durability in the face of natural weathering in our country(Republic of Guinea).These difficulties could be linked to non-compliance with standards and the failure to master certain physico-chemical,mechanical and technical parameters when constructing a building.In order to remedy this problem,a series of studies were carried out on samples of mud bricks used in the construction of century-old straw hut buildings in the urban commune of Kouroussa(Republic of Guinea).To this end,the compressive strength of the brick samples was assessed either:0.10 MPa,and sensory techniques of certain characteristics were carried out to evaluate the cohesion of the elements in the brick samples,such as:coward boule technique,hand washing test,withdrawal of a soil(pellet or ring test)and of the jar test.The physico-chemical analyses methods were carried out using XRF(X-Ray Fluorescence Spectrometry),granulometry and Atterberg limits in accordance with NF P 94-051.These results showed a high insoluble residue content(49.9%)and the sample had a clay-like appearance with a low PI(Plasticity Index)=8%.This study could be an alternative guide for the authorities in charge of housing and construction in the Kouroussa prefecture(Republic of Guinea).because,the majority of houses in Upper Guinea are built with mud raw bricks or fired bricks.
文摘Phase change materials(PCMs)are an interesting technology due to their high density and isothermal behavior during phase change.Phase change material plays a major role in the energy saving of the buildings,which is greatly aided by the incorporation of phase change material into building products such as bricks,cement,gypsum board,etc.In this study,an experiment has been conducted with three identical small chambers made up of normal,grooved and PCM-treated grooved bricks.Before the inclusion of PCM in grooved bricks,PCM material behavior has been studied by different techniques such as DSC,TG/DTA,SEM,and XRD.Thermal properties and thermal stability were investigated by differential scanning calorimeter(DSC)and thermogravimetric analyzer(TGA)respectively.Scanning electron microscopy(SEM)and X-ray diffraction(XRD)were used to determine the microstructure and crystalloid phase of the PCM before and after the accelerated thermal cycling test(0,60,120).These three identical model rooms built were exposed at a temperature just above 40°C with a heater.When the maximum outdoor temperature was 40-41°C,then the temperature of the PCM-treated grooved chamber was 32-33°C.The PCM-treated wall was tested and compared with a conventional and grooved wall.The difference between the PCM-treated grooved chamber and the untreated one was 8-9°C.PCM-treated bricks provided more efficient internal heat retention in summer when the outside temperature increased.
