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Synthesis, Crystal Structure and Biological Evaluation of Acridine-1,2,3-triazole Derivatives 被引量:1
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作者 霍丽妮 陈睿 +4 位作者 廖艳芳 刘华钢 李培源 卢汝梅 钟振国 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2016年第5期698-704,共7页
A series of acridine-1,2,3-triazole derivatives were designed, synthesized and characterized by NMR. 1-(2-methylacridinyl)-4-(4-methyl phenyl)-1,2,3-triazole(4f), C_(23)H_(18)N_4, was structurally determined... A series of acridine-1,2,3-triazole derivatives were designed, synthesized and characterized by NMR. 1-(2-methylacridinyl)-4-(4-methyl phenyl)-1,2,3-triazole(4f), C_(23)H_(18)N_4, was structurally determined by single-crystal X-ray diffraction. It crystallizes in the triclinic system, space group P1 with a = 9.585(4), b = 9.684(4), c = 11.339(5) A, β = 88.250(7)o, V = 925.3(6), Z = 2, D_c = 1.258 g/cm^3, F(000) = 368, μ = 0.077 mm^(-1), the final R = 0.0808 and wR = 0.2218 for 3386 observed reflections(I 〉 2σ(I)). X-ray analysis indicates that the acridine ring is almost vertical to triazole ring with the dihedral angle nearly to be 75°. The crystal packing of the compound is stabilized mainly by π-π interaction. The preliminary biological tests display that some of the title compounds possess a good anti-tumour activity against MGC-803 and T24. 展开更多
关键词 acridine-1 2 3-triazole crystal structure antitumor activities
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Hydrothermal Synthesis and Crystal Structure of a Zinc Complex:[Zn_(2.5)(phen)(BDC)_2(OH)] (phen = 1,10-Phenanthroline, BDC = Benzene-1,4-dicarboxylic Acid) 被引量:10
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作者 王庆伟 李秀梅 史林芳 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2008年第1期11-14,共4页
A metal-organic coordination polymer [ZnE.s(phen)(BDC)2(OH)]2 (phen = 1,10- phenanthroline, BDC = benzene-1,4-dicarboxylic acid) 1 has been hydrothermally synthesized and structurally characterized by single-c... A metal-organic coordination polymer [ZnE.s(phen)(BDC)2(OH)]2 (phen = 1,10- phenanthroline, BDC = benzene-1,4-dicarboxylic acid) 1 has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, elemental analyses and IR spectroscopy. The complex crystallizes in the triclinic system, space group PI with a = 11.199(2), b = 11.593(2), c = 11.865(3)/A, α= 99.330(1), β = 111.506(1), γ = 104.804(1)^o, V= 1328.4(5)A^3, Dc= 1.722 g/cm^3, Z = 1, Mr = 1377.82, F(000) = 692,μ(MoKa) = 2.306 mm^-1, S = 1.093, R= 0.0281 and wR = 0.0756 for 4179 observed reflections (I 〉 2σ(/)). The coordination polyhedron around Zn(II) can be described as a tetrahedron, trigonal bipyramid and octahedron. It is worth noting that the crystal structure of 1 is composed of tetranuclear zinc clusters linked by {ZnO6} units. 展开更多
关键词 zinc complex hydrothermal synthesis crystal structure tetranuclear zinc cluster
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Hydrothermal Synthesis, Crystal Structure and Photoluminescent Property of a Zinc(II) Coordination Polymer Assembled by Phthalate and 4,4′-Bipyridine 被引量:6
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作者 LI Xiu-Mei WANG Qing-Wei +3 位作者 CUI Yun-Cheng LI Chuan-Bi WANG Ren-Zhang LIU Bo 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2006年第5期621-625,共5页
A metal-organic coordination polymer {[Zn(Pht)(4,4'-bipy)(H2O)2]·2H2O}n (Pht = phthalate, 4,4'-bipy = 4,4'-bipyridine) 1 has been hydrothermally synthesized and characterized by elemental analysis, IR,... A metal-organic coordination polymer {[Zn(Pht)(4,4'-bipy)(H2O)2]·2H2O}n (Pht = phthalate, 4,4'-bipy = 4,4'-bipyridine) 1 has been hydrothermally synthesized and characterized by elemental analysis, IR, TG, fluorescence spectrum and single-crystal X-ray diffraction. Yellow crystals crystallize in the monoclinic system, space group P2/n, a = 7.6346(14), b = 11.316(2), c = 10.8133(19) ,A, β = 92.A.A,A.(3)°, V = 933.3(3) A^3, C18H20N2O8Zn, Mr = 457.73, Dc = 1.629 g/cm^3, F(000) = 472, Z = 2,μ(MoKa) = 1.367 mm^-1, the final R = 0.0323 and wR = 0.0821 for 1859 observed reflections (Ⅰ〉 2σ(Ⅰ)). The structure of 1 exhibits a two-dimensional bilayer framework formed by hydrogen bonding interactions. Furthermore, 1 shows yellow photoluminescent property at room temperature. 展开更多
关键词 hydrothermal synthesis crystal structure coordination polymer LUMINESCENCE
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Hydrothermal Synthesis, Crystal Structure and Photoluminescent Property of a New Isophthalate- bridged Zinc(II) Polymer with One-dimensional Chain Structure: [Zn(ipt)(im)_2]_(2n)·3nH_2O (ipt = Isophthalate, im = Imidazole) 被引量:6
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作者 李秀梅 崔运成 +3 位作者 王庆伟 李传碧 王仁章 高广刚 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2006年第4期481-484,共4页
A new metal-organic coordination polymer [Zn(ipt)(im)2]2n·3nH2O 1 has been obtained by using hydrothermal synthesis and characterized by elemental analysis, IR, TG, fluorescence spectrum and single-crystal X-... A new metal-organic coordination polymer [Zn(ipt)(im)2]2n·3nH2O 1 has been obtained by using hydrothermal synthesis and characterized by elemental analysis, IR, TG, fluorescence spectrum and single-crystal X-ray diffraction. The complex crystallizes in monoclinic, space group P2(1/n) with a = 10.653(3), b = 17.891(6), c = 10.743(4)A^°,β= 117.093(5)°, V= 1822.9(10) A^°3, Mr= 413.65, Dc = 1.507 g/cm^3,/t(MoKa) = 1.390 mm^-1, F(000) = 840, Z = 4, the final R = 0.0444 and wR = 0.1066 for 2434 observed reflections (I〉 2σ(I)). Furthermore, compound 1 shows blue photoluminescent property at room temperature. 展开更多
关键词 coordination polymer hydrothermal synthesis crystal structure luminescence
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Hydrothermal Synthesis,Crystal Structure and Thermal Stability of a Binuclear Copper(Ⅱ) Complex with 3-(Pyridin-2-yl)-1,2,4-triazole 被引量:7
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作者 李昶红 谭雄文 +1 位作者 李薇 杨颖群 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2011年第2期289-292,共4页
One novel binuclear copper(Ⅱ) complex [Cu 2 (Hpt) 2 (CO 3) 2 (H 2 O) 2 ]·H 2 O with copper carbonate and 3-(pyridin-2-yl)-1,2,4-triazole (Hpt) was hydrothermally synthesized and characterized by IR a... One novel binuclear copper(Ⅱ) complex [Cu 2 (Hpt) 2 (CO 3) 2 (H 2 O) 2 ]·H 2 O with copper carbonate and 3-(pyridin-2-yl)-1,2,4-triazole (Hpt) was hydrothermally synthesized and characterized by IR and X-ray diffraction analysis.The complex crystallizes in triclinic,space group P2 1 /n with a=0.6862(1),b=0.7805(1),c=1.1983(2) nm,α=72.03(2),β=107.72(3),γ=75.28(2)o,V=0.5884 nm 3,D c=2.105 g/cm 3,Z=1,F(000)=357,GOOF=1.041,the final R=0.01859 and wR=0.04348.The whole molecule is composed of two cooper ions,two Hpt molecules,two carbonate and three water molecules,forming a binuclear structure.The crystal structure shows that the cooper ion is coordinated with three nitrogen atoms from two Hpt molecules,two oxygen atoms from one carbonic acid and one water molecule,forming a distorted square pyramidal geometry.The TG analysis result shows that the title complex is stable under 131.0 ℃. 展开更多
关键词 copper(Ⅱ) complex hydrothermal synthesis crystal structure thermal stability analysis
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Hydrothermal Synthesis and Crystal Structure of a New Three-dimensional Heterometallic Coordination Polymer 被引量:5
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作者 薛丽平 李召好 苗少斌 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2012年第6期791-796,共6页
A new 3d-4fheterometallic polymer {[Sm2Cu(PDC)2(SO4)2(H20)6]·2H2O}n 1 has been synthesized by Sm2O3, Cu(SO4)2·5H2O and pyridine-3,5-dicarboxylic acid under hydrothermal conditions. The compound cryst... A new 3d-4fheterometallic polymer {[Sm2Cu(PDC)2(SO4)2(H20)6]·2H2O}n 1 has been synthesized by Sm2O3, Cu(SO4)2·5H2O and pyridine-3,5-dicarboxylic acid under hydrothermal conditions. The compound crystallizes in triclinic system, space group Pi, with a = 6.352(7), b = 10.040(10), c = 10.315(11) A, α = 94.958(14), β = 95.556(7), γ = 99.747(14)°, V = 641.7(12)A3, Z = 1, M, = 1030.63, Dc= 2.651 Mg/m3,μ = 5.615 mm-1, F(000) = 491, the final R = 0.0491 and wR = 0.1345 for 2098 observed reflections with I 〉 2σ(I). The compound is a three-dimensional network structure in which infinite lanthanide-carboxylate chains are linked by [Cu($04)2]2- metalloligands to form a mixed-metal coordination network. 展开更多
关键词 hydrothermal synthesis crystal structure 3d-4fhybrid polymer thermal property
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Hydrothermal Synthesis and Crystal Structure of a Cobalt(II) Coordination Polymer: [Co(C_2O_4)(bix)]_n (bix = 1,4-Bis(imidazol-1-ylmethyl)-benzene) 被引量:6
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作者 王志涛 纪建业 +3 位作者 李秀梅 牛艳玲 王庆伟 刘博 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2013年第2期296-300,共5页
A new two-dimensional cobalt coordination polymer has been prepared and fully characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. The compound [Co(C2O4)(bix)]n 1 crystallizes in the m... A new two-dimensional cobalt coordination polymer has been prepared and fully characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. The compound [Co(C2O4)(bix)]n 1 crystallizes in the monoclinic system, space group C2/c, with a = 11.549(3), b = 15.700(3), c = 9.260(2) A, β = 102.984(3)°, V = 1636.0(6) A^3, C16HIaCON4O4, Mr= 383.23, Dc = 1.556 g/cm^3, μ(MoKa) = 1.078 mm^-1, F(000) = 780, Z = 4, the final R = 0.0455 and wR = 0.1286 for 1483 observed reflections (I 〉 2σ(I)). Of the compound, the Co center is octahedrally coordinated with oxalate acting as a tetra-dentate ligand coordinated to the cobalt atom and each bix serving as a bridging ligand by employing two N-donors to coordinate with the Co center. An infinite {Co2(C2O4)2}∞ chain is formed along the α axis. Furthermore, the 1D chains are held together via bix ligands to generate a two-dimensional network structure with 1D coronal-like channels (ca. 5.691A × 15.700A). 展开更多
关键词 hydrothermal synthesis crystal structure coordination polymer
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Hydrothermal Synthesis and Crystal Structure of a New Nickel(Ⅱ) Complex with 3,4-Pyridinedicarboxylic Acid and 1,4-Bis(imidazol-1-ylmethyl)-benzene Ligands 被引量:6
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作者 王庆伟 国佳 +3 位作者 芦廷峰 李秀梅 刘博 王志涛 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2012年第11期1575-1579,共5页
A metal-organic coordination polymer [Ni(PDB)(bix)(H20)]n (H2PDB = 3,4-pyri- dinedicarboxylic acid, bix = 1,4-bis(imidazol-l-ylmethyl)-benzene) 1 has been hydrothermally synthesized and characterized by elem... A metal-organic coordination polymer [Ni(PDB)(bix)(H20)]n (H2PDB = 3,4-pyri- dinedicarboxylic acid, bix = 1,4-bis(imidazol-l-ylmethyl)-benzene) 1 has been hydrothermally synthesized and characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. Blue crystals crystallize in the triclinic system, space group PI with a = 9.1849(8), b = 9.2065(9), c = 12.9308(12) °, a = 103.3070(10), β = 104.7160(10), y = 90.5900(10)°, V = 1026.42(16)/k3, C21H19NsNiOs, Mr = 480.12, Dc = 1.553 g/cm3, F(000) = 496, Z = 2,/l(MoKa) = 0.991 mm-1, the final R = 0.0325 and wR = 0.0799 for 3561 observed reflections (I 〉 2σ(I)). The structure of 1 exhibits a two-dimensional network structure. 展开更多
关键词 hydrothermal synthesis crystal structure coordination polymer
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Hydrothermal Synthesis and Crystal Structure of a Novel Isophthalate-bridged Copper(II) Polymer with Two-dimensional Network Structure: [Cu_2(phen)(ipt)_2]_(2n)·nH_2O (ipt = isophthalate, phen = 1,10-phenanthroline) 被引量:4
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作者 CUI Yun-Cheng LI Xiu-Mei +3 位作者 LI Chuan-Bi WANG Qing-Wei LIU Bo LI Guo-Feng 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2005年第12期1411-1415,共5页
A novel metal-organic coordination polymer [Cu2(phen)(ipt)2]2n-nH2O 1 has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction. The complex crystallizes in monoclinic,... A novel metal-organic coordination polymer [Cu2(phen)(ipt)2]2n-nH2O 1 has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction. The complex crystallizes in monoclinic, space group P21/c with a = 12.338(3), b = 12.167(3), c = 18.167(4)A, β= 111.686(14)°, V = 2534.1(10)A^3, C28H18Cu2N2O9, Mr = 653.52, Dc = 1.713 g/cm^3,μ(MoKα) = 1.740 mm^-1, F(000) = 1320, Z = 4, the final R = 0.0443 and wR = 0.0853 for 3543 observed reflections (1 〉 2σ(I)). It exhibits a novel two-dimensional network with tetra-Cu-ipt-as building units. 展开更多
关键词 ISOPHTHALATE coordination polymer hydrothermal synthesis crystal structure
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Hydrothermal Synthesis,Crystal Structure and Fluorescence Spectrum Studies of a Supramolecular Compound {[2-(2-Pyridyl)benzimidazoleH_2]^(2+)·[SbCl_5]^(2-)}_2 被引量:5
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作者 郭应臣 卓立宏 +2 位作者 赵一阳 姚兴芝 黄群增 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2008年第11期1333-1338,共6页
A new supramolecular compound, { [2-(2-pyridyl)benzimidazoleH2]2+.[SBC15]2-}2, was synthesized by the hydrothermal reaction of o-diaminobenzene, 2-pyridinecarboxylie acid and SbCl3 in 1:1 HC1 solution, and charact... A new supramolecular compound, { [2-(2-pyridyl)benzimidazoleH2]2+.[SBC15]2-}2, was synthesized by the hydrothermal reaction of o-diaminobenzene, 2-pyridinecarboxylie acid and SbCl3 in 1:1 HC1 solution, and characterized by chemical analysis, elemental analysis, IR spectra, thermogravimetfic analysis and fluorescence spectra. The crystal structure was deter- mined by X-ray single-crystal diffraction. The crystal belongs to the monoclinic system, space group P211c, with a = 16.0397(13), b = 14.3189(12), c = 15.6370(13) A, β = 105.8980(10)°, V = 3454.0(5) A3, Z = 4, C24H22Cl10N6Sb2, Mr = 992.48, Dc = 1.909 g/cm3,/z = 2.366 mm-1, S = 1.010, F(000) = 1920, R = 0.0254 and wR = 0.0555. The coordination anion, [SbCl5]2- which is a distorted tetragonal pyramid, is composed by coordinating action with Sb3+ ion and five adjacent chloride ions. Every four coordination anions of [SbCl5]2- form a biquaternion ring structure through the secondary bonding of Sb...Cl. Moreover, the compound adopts a three-dimensional network supramolecular structure because of the hydrogen bonds and π-π stacking between the rings and the 2-(2-pyridyl)benzimidazole divalent cations. The title compound also shows good fluorescent behaviors. 展开更多
关键词 2.(2-pyridyl)benzimidazole supramolecular compound hydrothermal synthesis crystal structure fluorescence spectrum
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Urothermal Synthesis and Crystal Structure of a Zn(Ⅱ) Coordination Polymer with a 3-D Supramolecular Structure 被引量:5
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作者 陈顺玉 杨娥 +1 位作者 刘子生 叶小龙 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2012年第4期535-538,共4页
A new metal-organic coordination polymer [Zn(hfipbb)(e-urea)]n(1,H2hfipbb = 4,4'-(hexafluoroisopropylidene)bis(benzoic acid),e-urea = ethylene urea) has been urothermally synthesized and characterized by el... A new metal-organic coordination polymer [Zn(hfipbb)(e-urea)]n(1,H2hfipbb = 4,4'-(hexafluoroisopropylidene)bis(benzoic acid),e-urea = ethylene urea) has been urothermally synthesized and characterized by elemental analysis and single-crystal X-ray diffraction.The title complex crystallizes in monoclinic,space group P21/c with a = 13.302(4),b = 10.981(3),c = 13.804(4) ,β = 93.587(5)°,V = 2012.3(10) 3,C20H14N2O5F6Zn,Mr = 541.72,Z = 4,Dc = 0.447 g/cm3, = 0.328 mm-1,F(000) = 272,R = 0.0340 and wR = 0.1107 for 4528 observed reflections(I 〉2σ(I)).In the structure of compound 1,two Zn(Ⅱ) ions are bridged by two carboxylate groups from two hfipbb ligands to form a dinuclear unit,and each dinuclear Zn(Ⅱ) unit is linked with its two adjacent dinuclear units through four hfipbb ligands into an infinite one-dimensional double-chain.The interesting structural feature of compound 1 is that the one-D double-chains are self-interconnected into a three-D supramolecular structure through hydrogen bonds between the coordinated e-urea molecules and carboxylate oxygen atoms(N1 and O2,N2 and O4). 展开更多
关键词 Zn(Ⅱ) coordination polymer urothermal synthesis crystal structure
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Hydrothermal Synthesis and Crystal Structure of a Zinc(II) Polymer with a Two-dimensional Layer Structure: [Zn(pzdc)(phen)]_n·nH_2O 被引量:4
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作者 李秀梅 王志涛 +2 位作者 刘博 王庆伟 周实 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2009年第10期1257-1260,共4页
A metal-organic coordination compound formulated as [Zn(pzdc)(phen)]n·nH2O 1 (H2pzdc = pyrazine-2,3-dicarboxylic acid, phen = 1,10-phenanthroline) has been hydrothermally synthesized and structurally charac... A metal-organic coordination compound formulated as [Zn(pzdc)(phen)]n·nH2O 1 (H2pzdc = pyrazine-2,3-dicarboxylic acid, phen = 1,10-phenanthroline) has been hydrothermally synthesized and structurally characterized by elemental analysis, IR, fluorescence spectrum and single-crystal X-ray diffraction. The title compound crystallizes in the monoclinic system, space group P21/n with a = 11.607(2), b = 11.719(2), c = 13.140(3)A^°, β = 110.707(3)°, V= 1671.9(6)A^°3, C18H12ZnN4O5, Mr= 429.69, De = 1.707 g/cm^3,μ(MoKa) = 1.511 mm^-1, F(000) = 872, Z = 4, the final R = 0.0356 and wR = 0.0853 for 2713 observed reflections (I 〉 2σ(I)). It exhibits an interesting two-dimensional layer structure and shows yellow photoluminescent property at room temperature. 展开更多
关键词 coordination polymer hydrothermal synthesis crystal structure LUMINESCENCE
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Hydrothermal Synthesis and Crystal Structure of a Cadmium(II) Polymer with One-dimensional Chain Structure: [Cd(bpy)(BDC)]_n·nbpy 被引量:4
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作者 LI Xiu-Mei NIU Yan-Ling +2 位作者 WANG Qing-Wei CUI Yun-Cheng LIUBo 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2007年第5期537-540,共4页
A metal-organic coordination polymer [Cd(bpy)(BDC)]n·nbpy (bpy = 2,2-bipyri-dine, H2BDC = terephthalic acid) has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spec... A metal-organic coordination polymer [Cd(bpy)(BDC)]n·nbpy (bpy = 2,2-bipyri-dine, H2BDC = terephthalic acid) has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, TG and single-crystal X-ray diffraction. The complex crystallizes in monoclinic, space group C2/c with a = 15.723(5), b = 21.695(5), c = 7.576(5) A, β = 116.171(7)°, V = 2319.3(18)A^3, C28H20CdN4O4, Mr = 588.88, Dc = 1.686 g/cm^3, μ(MoKα) = 0.987 mm^-1, F(000) = 1184, Z = 4, the final R = 0.0464 and wR = 0.0831 for 1882 observed reflections (Ⅰ〉 2σ(Ⅰ)). It exhibits a three-dimensional network with channels constructed from one-dimensional coordination chains via C–H…O hydrogen bonds and significant aromatic π-π stacking interactions. 展开更多
关键词 hydrothermal synthesis crystal structure coordination polymer
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Hydrothermal Synthesis and Crystal Structure of a Lead(Ⅱ) Polymer with a Two-dimensional Network Structure:[Pb_2(PDB)_2(phen)]_n·nH_2O 被引量:5
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作者 李秀梅 王庆伟 +2 位作者 李传碧 王志涛 刘博 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2010年第5期757-761,共5页
A new metal-organic complex [Pb2(PDB)2(phen)]n·nH2O (H2PDB=pyridine-3,4-dicarboxylic acid,phen=1,10-phenanthroline) 1 has been hydrothermally synthesized and structurally characterized by elemental analysis... A new metal-organic complex [Pb2(PDB)2(phen)]n·nH2O (H2PDB=pyridine-3,4-dicarboxylic acid,phen=1,10-phenanthroline) 1 has been hydrothermally synthesized and structurally characterized by elemental analysis,IR spectrum,TG and single-crystal X-ray diffraction.The compound crystallizes in triclinic,space group P1 with a=7.2472(5),b=10.6966(8),c=16.2376(12),α=98.2960(10),β=91.6430(10),γ=97.4810(10)o,V=1233.53(16)3,C26H16O9N4Pb2,Mr=942.81,Dc=2.538 g/cm3,μ(MoKα)=13.697 mm-1,F(000)=872,Z=2,the final R=0.0247 and wR=0.0654 for 3886 observed reflections (I 〉 2σ(I)).In the crystal structure,the Pb(1) atom is six-coordinated with four carboxylate oxygen atoms from three different PDB ligands and two nitrogen atoms from phen ligand,showing a distorted octahedral geometry;the Pb(2) atom is four-coordinated with four carboxylate oxygen atoms from four different PDB ligands,showing a distorted tetrahedral geometry.It exhibits a three-dimensional supramolecular network structure formed by hydrogen bonds and π-π interactions. 展开更多
关键词 hydrothermal synthesis crystal structure lead(II) complex
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Hydrothermal Synthesis, Crystal Structure and Fluorescent Property of a Cd(Ⅱ) Complex Based on Biimidazole and Isonicotinate-N-oxide 被引量:4
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作者 毛稳玲 胡宗球 丁瑜 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2010年第4期587-591,共5页
A new complex [Cd(H2biim)2(H2O)2]·(ino)2·4H2O (H2biim = 2,2'-biimidazole, ino = isonicotinate-N-oxide) has been prepared and characterized by single-crystal X-ray diffraction analysis, IR and fluore... A new complex [Cd(H2biim)2(H2O)2]·(ino)2·4H2O (H2biim = 2,2'-biimidazole, ino = isonicotinate-N-oxide) has been prepared and characterized by single-crystal X-ray diffraction analysis, IR and fluorescence spectra analysis. The crystal is of triclinic system, space group P1 with a = 7.5380(6), b = 8.0402(7), c = 13.5094(11) , α = 104.269(1), β = 93.604(1), γ = 98.349(1)°, V = 780.93(11) 3, Mr = 765.00, Dc = 1.627 g/cm3, F(000) = 390, μ = 0.776 mm-1 and Z = 1. The final R = 0.0322 and wR = 0.0825 for 7038 observed reflections with I 2σ(I) and R = 0.0341 and wR = 0.0832 for all data. The title complex exhibits an infinite chain-like structure through bridging isonicotinate-N-oxide. Strong interchain hydrogen bonds between isonicotinate-N-oxide and H2biim result in the robust 3-D supramolecular architecture. Moreover, the complex shows strong photoluminescence with emission maximum at λ = 401 nm upon λex = 330 nm. 展开更多
关键词 cadmium(Ⅱ) complex crystal structure 2 2-biimidazole isonicotinc acid N-oxide hydrothermal synthesis fluorescent property
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Hydrothermal Synthesis and Crystal Structure of a Three-dimensional Cadmium(Ⅱ) Complex 被引量:3
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作者 李秀梅 纪建业 +1 位作者 王志涛 刘博 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2012年第10期1464-1468,共5页
A metal-organic coordination polymer [Cd2(PDC)2(bix)(H2O)2]n·nH2O (H2PDC = 2,4-pyridinedicarboxylic acid, bix = 1,4-bis(imidazol-l-ylmethyl)-benzene) 1 has been hydrother- mally synthesized and characte... A metal-organic coordination polymer [Cd2(PDC)2(bix)(H2O)2]n·nH2O (H2PDC = 2,4-pyridinedicarboxylic acid, bix = 1,4-bis(imidazol-l-ylmethyl)-benzene) 1 has been hydrother- mally synthesized and characterized by elemental analysis, IR, TG, fluorescence spectrum and single-crystal X-ray diffraction. Brown crystals crystallize in the orthorhombic system, space group P212121 with a = 11.741(3), b = 14.190(4), c = 18.963(5) A, V= 3159.4(14) A3, C28H26Cd2N6O11, Mr= 847.35, Dc = 1.781 g/cm3, F(000) = 1680, Z = 4,μ(MoKa) = 1.415 mm-1, the final R = 0.0381 and wR = 0.0882 for 5472 observed reflections (1 〉 2σ(I)). The structure of 1 exhibits a threedimensional network structure. 展开更多
关键词 hydrothermal synthesis crystal structure coordination polymer
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Hydrothermal Synthesis,Crystal Structure and Thermal Analysis of a Dinuclear Complex Cd_2(3,5-Dinitrobenzoate)_4(pyridine)_4 被引量:2
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作者 GUO Jin-Yu ZHANG Tong-Lai ZHANG Jian-Guo LIU Yan-Hong QIAO Xiao-Jing YANG Li 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2006年第11期1297-1302,共6页
A dinuclear complex Cd2(dnba)4(pyridine)4 (dnba = 3,5-dinitrobenzoate) has been synthesized by hydrothermal method and characterized by X-ray single-crystal diffraction, elemental analysis, FT-IR spectroscopy, D... A dinuclear complex Cd2(dnba)4(pyridine)4 (dnba = 3,5-dinitrobenzoate) has been synthesized by hydrothermal method and characterized by X-ray single-crystal diffraction, elemental analysis, FT-IR spectroscopy, DSC and TG-DTG techniques. The complex with empirical formula C48H32Cd2NI2024 (Mr = 692.83) crystallizes in monoclinic, space group P21/n with a - 12.0344(14), b = 10.5752(13), c = 21.578(3) A, β = 104.150(2)°, V = 2662.8(6) A^3, Z = 2, D, = 1.728 g/cm^3,μ(MoKa) = 0.897 mm^-1, F(000) = 1384, S = 1.016 and (△/σ)max = 0.001. R = 0.0638 and wR = 0.0737 for all data; the final R = 0.0337 and wR = 0.0644. In this complex, four carboxylates are bidentate-or chelate-coordinated with the Cd(Ⅱ) centers to give the dinuclear structure. The other coordination positions of Cd(Ⅱ) are occupied by the lone pair electrons from N of four pyridines. Thermal analyses DSC and TG-DTG have been used to determine the thermal decomposition mechanism of the title complex. 展开更多
关键词 hydrothermal synthesis dinuclear complex crystal structure thermal analysis
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Hydrothermal Synthesis and Crystal Structure of Zinc(Ⅱ) Dinicotinate Complex [Zn(nic)_2(H_2O)_4](nic=nicotinic acid):A Three-dimensional Hydrogen-bond Network 被引量:2
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作者 MAOHong-yan ZHANGZong-pei +4 位作者 ZHANGHong-yun XUChen WANGEn-bo WUQing-an ZHUYu 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2004年第3期377-379,共3页
关键词 Nicotinic acid Zinc(Ⅱ) complex crystal structure Hydrothermal synthesis
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Solvothermal Synthesis and Crystal Structure of a Layered Thioantimonate(Ⅲ) [C_4H_9NH_3]_2Sb_4S_7 被引量:2
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作者 朱爱美 贾定先 +1 位作者 王鹏 张勇 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2007年第11期1298-1302,共5页
An inorganic-organic hybrid thioantimonate(Ⅲ) [CH3(CH2)3NH3]2Sb4S7 1 with layered structure was synthesized by solvothermal method. 1 crystallizes in the triclinic system, space group P1 with a = 7.0124(11), b ... An inorganic-organic hybrid thioantimonate(Ⅲ) [CH3(CH2)3NH3]2Sb4S7 1 with layered structure was synthesized by solvothermal method. 1 crystallizes in the triclinic system, space group P1 with a = 7.0124(11), b = 11.919(2), c =14.879(3)A, α = 108.791(3), β= 102.441(3), γ = 92.846(2)°, V= 1140.1(3)A3, Mr = 859.71, Z= 2, Do = 2.504 g/cm^3 ,μ = 5.324 mm^-1, F(000) = 804, S = 1.013, the Final R = 0.0297 and wR = 0.0618 for 3534 observed reflections with Ⅰ 〉 2 σ(Ⅰ). 1 consists of [C4HgNH3]+ cations and two-dimensional [Sb4ST]n^2n- anion which is composed of three SbS3 trigonal pyranaids and one SbS4 unit joined by sharing common comers. The anionic layers are stacked perpendicularly to the c axis of the unit cell forming two-dimensional channels between the layers. The [C4H9NH3]^+ cations interdigitate in a bilayer and reside in the 2D channels leading to a sandwich-like arrangement of the anion and cations. 展开更多
关键词 solvothermal synthesis crystal structure two-dimensional channel thioantimonate
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Hydrothermal Synthesis, Crystal Structure and Photoluminescent Property of a Zinc(II) Complex with 2,2′-Diphenic Acid and 2,2′-Bipyridine Ligands 被引量:2
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作者 王秀艳 李秀梅 +3 位作者 牛艳玲 王庆伟 刘博 王志涛 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2010年第11期1702-1706,共5页
A new dinuclear complex [Zn(dpa)(bipy)(H2O)]2 (dpa = 2,2'-diphenic acid, bipy = 2,2'-bipyridine) 1 has been hydrothermally synthesized and structurally characterized by elemental analysis, IR, fluorescence s... A new dinuclear complex [Zn(dpa)(bipy)(H2O)]2 (dpa = 2,2'-diphenic acid, bipy = 2,2'-bipyridine) 1 has been hydrothermally synthesized and structurally characterized by elemental analysis, IR, fluorescence spectrum and single-crystal X-ray diffraction. The complex crystallizes in monoclinic, space group P21/c with a = 10.960(2), b = 9.4841(18), c = 20.599(4), β = 104.452(3)o, V = 2073.4(7)3, C48H36N4O10Zn2, Mr = 959.55, Dc = 1.537 g/cm3, μ(MoKα) = 1.225 mm-1, F(000) = 984, Z = 2, the final R = 0.0364 and wR = 0.0843 for 2788 observed reflections (I 〉 2σ(I)). In the crystal structure, the zinc atom is five-coordinated with two carboxylate oxygen atoms from different dpas, one coordinated water molecule and two nitrogen atoms from bipy ligands, showing a slightly distorted triangular bipyramidal geometry. Furthermore, it exhibits a zero-dimensional network structure with a sixteen-membered ring and shows yellow photoluminescent property at room temperature. 展开更多
关键词 hydrothermal synthesis crystal structure zinc(II) complex LUMINESCENCE
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