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A Novel Green Preparation of a, a'-Bis (substituted benzylidene)-cycloalkanones Promoted by FeCl_3 6H-2O in Ionic Liquid 被引量:5
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作者 Xin Ying ZHANG, Xue Sen FAN, Hong Ying NIU, Jian Ji WANGSchool of Chemical and Environmental Sciences, Henan Normal University, Key Laboratory ofEnvironmental Science and Engineering of Henan Education Department,Xinxiang 453002 《Chinese Chemical Letters》 SCIE CAS CSCD 2003年第10期1005-1007,共3页
a, a'-Bis(substituted benzylidene)cycloalkanones were efficiently prepared from cycloalkanones and benzaldehydes in [bmim][BF4] by using iron(III) chloride hexahydrate as a catalyst. It is shown that [bmim][BF4] a... a, a'-Bis(substituted benzylidene)cycloalkanones were efficiently prepared from cycloalkanones and benzaldehydes in [bmim][BF4] by using iron(III) chloride hexahydrate as a catalyst. It is shown that [bmim][BF4] and iron(III) chloride hexahydrate can be quantitatively recovered and be reused effectively for many times. Compared with the known methods, this novel process has the advantage of being an envkonmentally benign process together with good yields and mild reaction conditions. 展开更多
关键词 Ionic liquid a a'-bis(substituted benzylidene)cycloalkanones iron(III) chloride hexahydrate.
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A New Solvent-free Synthesis of a, a'-Dibenzylidenecycloalkanones from Acetals with Cycloalkanones under Microwave Irradiation 被引量:1
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作者 Dan Feng HUANG Jin Xian WANG Yu Lai HU 《Chinese Chemical Letters》 SCIE CAS CSCD 2003年第4期333-334,共2页
A new rapid synthetic method is described for synthesis of a, a-dibenzylidene- cycloalkanones by the reaction of acetals and cycloalkanones without solvent using BF3稥t2O as catalyst under microwave irradiation.
关键词 cycloalkanone ACETAL Lewis acid microwave irradiation.
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The Effective Catalyst (Cobalt Salt/Lewis Acid) for Beckmann Rearrangement of Cycloalkanone Oximes to Lactams under Mild Conditions 被引量:2
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作者 Masahiro Komeda Ayana Ozaki +4 位作者 Keita Hayashi Michinori Sumimoto Kenji Hori Tsunemi Sugimoto Hidetoshi Yamamoto 《International Journal of Organic Chemistry》 2015年第2期57-62,共6页
The Beckmann rearrangement of cyclohexanone oxime was achieved by the combined use of cobalt salt and Lewis acids co-catalysts (each 10 mol%). Various combinations of cobalt salts and Lewis acids gave lactams in a sat... The Beckmann rearrangement of cyclohexanone oxime was achieved by the combined use of cobalt salt and Lewis acids co-catalysts (each 10 mol%). Various combinations of cobalt salts and Lewis acids gave lactams in a satisfactory yield under mild conditions. This method makes it possible to reduce undesirable byproducts. 展开更多
关键词 Beckmann REARRANGEMENT cycloalkanone OXIMES LACTAM Cobalt Catalysts Lewis ACIDS
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InCl_3·4H_2O Catalyzed Aldol Condensation of Cycloalkanones with Aromatic Aldehydes
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作者 Gui Sheng DENG Tie Gang REN 《Chinese Chemical Letters》 SCIE CAS CSCD 2001年第10期859-860,共2页
InCl34H2O catalyzes the cross-aldol condensation of cycloalkanones with aromatic aldehydes in sealed tube under solvent free condition to afford an efficient method for the synthesis of a, a-bis(substituted)benzyliden... InCl34H2O catalyzes the cross-aldol condensation of cycloalkanones with aromatic aldehydes in sealed tube under solvent free condition to afford an efficient method for the synthesis of a, a-bis(substituted)benzylidenecycloalkanones. 展开更多
关键词 Aldol condensation cycloalkanone indium trichloride catalysis.
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Formation of α,α'-Bis(substituted benzylidene)cycloalkanones from Masked Aldehydes Promoted by Samarium(III) Triiodide
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作者 XiaoXiaWANG YongMinZHANG 《Chinese Chemical Letters》 SCIE CAS CSCD 2004年第5期511-514,共4页
Diacetates 1 and N-[(1-benzotriazol-l-yl)alkyl]amides 2, both masked forms of aldehydes, could undergo deprotection and condensation with cycloalkanones in a one-pot procedure promoted by samarium(III) iodide (SmI3) ... Diacetates 1 and N-[(1-benzotriazol-l-yl)alkyl]amides 2, both masked forms of aldehydes, could undergo deprotection and condensation with cycloalkanones in a one-pot procedure promoted by samarium(III) iodide (SmI3) to afford α,α'-bis(substituted benzylidene) cycloalkanones in good yields. 展开更多
关键词 Samarium(III) triiodide α α'-bis(substituted benzylidene)cycloalkanone 1 1-diacetate N-[(l-benzotriazol-1-yl)alkyl]amide. Quinolone antibacterial agents have emerged as one of the dominant classes
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Low Environmental Load Process for the Beckmann Rearrangement of Cycloalkanone Oximes by Bronsted Acid Catalyst with Cobalt Salts
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作者 Hidetoshi Yamamoto Masahiro Komeda +3 位作者 Ayana Ozaki Michinori Sumimoto Kenji Hori Tsunemi Sugimoto 《International Journal of Organic Chemistry》 2015年第3期147-152,共6页
Beckmann rearrangements of oximes to lactams often require harsh conditions and/or the use of large amounts of acid catalyst. To reduce the amount of Bronsted acid required, and to avoid the formation of a large amoun... Beckmann rearrangements of oximes to lactams often require harsh conditions and/or the use of large amounts of acid catalyst. To reduce the amount of Bronsted acid required, and to avoid the formation of a large amount of undesirable byproducts under mild reaction conditions, a low environmental load process was developed. Beckmann rearrangements of cyclohexanone oxime and cyclooctanone oxime were achieved using a combination of a Bronsted acid and cobalt tetra-fluoroborate hexahydrate. Various Bronsted acid catalysts (10 - 20 mol%) were used to obtain the corresponding lactams in high yields at 80℃. 展开更多
关键词 Beckmann Rearrangement cycloalkanone Oximes LACTAM Cobalt Catalysts Bronsted Acids
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Sodium-Modified Fluorapatite: A Mild and Efficient Reusable Catalyst for the Synthesis of <i>α,α</i>’-Bis(Substituted Benzylidene) Cycloalkanones under Conventional Heating and Microwave Irradiation
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作者 Bahija Mounir Fathallaah Bazi +2 位作者 Abddelfetah Mounir Mohamed Zahouily Hamid Toufik 《Green and Sustainable Chemistry》 2018年第2期156-166,共11页
A versatile and environmentally friendly method for α,α’-bis(substituted ben-zylidene) cycloalkanones has been developed using a heterogeneous catalysis technology. We have synthesized a series of the α,α’-bis(s... A versatile and environmentally friendly method for α,α’-bis(substituted ben-zylidene) cycloalkanones has been developed using a heterogeneous catalysis technology. We have synthesized a series of the α,α’-bis(substituted benzylidene) cycloalkanones, a biologically important class of compounds, via the cross aldol condensation between arylaldehydes and cycloketones using sodium-modified fluorapatite (Na/FAP) as a highly efficient solid catalyst under conventional heating in aqueous media and solventless conditions under microwave. Catalyst reuse, ease of separation of the pure product, and high yields are some of the unique features of this process. Shorter reaction times (4 - 7 min) and higher yields (80% - 94%) were achieved under microwave irradiation conditions. 展开更多
关键词 Green Chemistry α α’-Bis(Substituted Benzylidene) cycloalkanoneS Microwaves Irradiation Conventional Heating Aqueous Media FLUORAPATITE Activated by SODIUM Nitrate (Na/FAP)
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Solvent Free Synthesis of α,α-Bis(Substituted-benzylidene)cycloalkanones Using Covalently Anchored Sulfonic Acid on Silica Gel(SiO_(2)-R-SO_(3)H)as an Efficient and Reusable Heterogeneous Catalyst
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作者 Azizollah Habibi Enayatollah Sheikhhosseini +2 位作者 Mohammadali Bigdeli Saeed Balalaie Elinaz Farrokhi 《International Journal of Organic Chemistry》 2011年第4期143-147,共5页
We wish to report a mild and efficient Crossed-Aldol reaction for the synthesis of α, ?-bis(substituted-ben- zylidene)cycloalkanones in the presence of catalytic amounts of covalently anchored sulfonic acid onto sil-... We wish to report a mild and efficient Crossed-Aldol reaction for the synthesis of α, ?-bis(substituted-ben- zylidene)cycloalkanones in the presence of catalytic amounts of covalently anchored sulfonic acid onto sil- ica gel under heterogeneous and solvent-free conditions. The present methodology offers several advantages such as excellent yields, simple procedure and work up steps, short reaction times and easy recovery of the catalyst. We have also demonstrated that the catalyst can be reused successfully. 展开更多
关键词 Crossed-Aldol Condensation Heterogeneous Catalysis α α-Bis(substituted-benzylidene)cycloalkanones SiO_(2)-R-SO_(3)H Solvent-Free
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Palladium(0)catalyzed reactions of propargylic carbonates and dialkyl cycloalkanone-α,α-dicarboxylates
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作者 GENG,Li-Feng LU,Xi-Yan Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032 《Chinese Journal of Chemistry》 SCIE CAS CSCD 1993年第1期91-94,共8页
Propargylic carbonates reacted with dialkyl cycloalkanone-α,α′-dicarboxylates under the catalysis of Pd(0)complex to give bicyclic compounds in high yields.The two electron-withdrawing groups at α and α′position... Propargylic carbonates reacted with dialkyl cycloalkanone-α,α′-dicarboxylates under the catalysis of Pd(0)complex to give bicyclic compounds in high yields.The two electron-withdrawing groups at α and α′positions of cycloalkanone rings are essential for the annulation reaction. 展开更多
关键词 DICARBOXYLATES catalyzed reactions of propargylic carbonates and dialkyl cycloalkanone PALLADIUM
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