In this paper,the effects of different mineral admixtures and sulfate solution types on the appearance,mass change rate,relative dynamic elastic modulus,and corrosion resistance coefficient of concrete were systematic...In this paper,the effects of different mineral admixtures and sulfate solution types on the appearance,mass change rate,relative dynamic elastic modulus,and corrosion resistance coefficient of concrete were systematically studied.X-ray Diffraction(XRD),Mercury Intrusion Porosimetry(MIP),Scanning Electron Microscopy(SEM),and X-ray Computed Tomography(X-CT)were used to explore and analyze the changes in the microstructure and the corrosion products of concrete in the sulfate solution.The results show that the existence of magnesium ions accelerates concrete deterioration.There is a critical dosage of fly ash for magnesium sulfate resistance of concrete.The magnesium sulfate resistance of concrete is improved when the fly ash content is less than 20%.Slag can significantly improve the corrosion resistance of concrete to magnesium sulfate.The diffusion of sulfate ions into concrete is a gradual process.In the early stages of corrosion,sulfate ion content in the concrete immersed in the magnesium sulfate solution is slightly less than that of the concrete immersed in the sodium sulfate solution.However,in the later stage of corrosion,the sulfate ion content in the concrete immersed in the magnesium sulfate solution is significantly higher than that of the concrete immersed in the sodium sulfate solution.展开更多
基金supported by“the National Natural Science Foundation of China(Grant No.52008146)”“the Research Fund of Henan Key Laboratory of Materials on Deep-Earth Engineering(Grant No.MDE2020-01,Henan Polytechnic University)”+1 种基金“the Fundamental Research Funds for the Central Universities of China(Grant Nos.JZ2021HGTB0089,JZ2020HGQA0205)”“State Key Laboratory of High Performance Civil Engineering Materials(2021CEM003)”.
文摘In this paper,the effects of different mineral admixtures and sulfate solution types on the appearance,mass change rate,relative dynamic elastic modulus,and corrosion resistance coefficient of concrete were systematically studied.X-ray Diffraction(XRD),Mercury Intrusion Porosimetry(MIP),Scanning Electron Microscopy(SEM),and X-ray Computed Tomography(X-CT)were used to explore and analyze the changes in the microstructure and the corrosion products of concrete in the sulfate solution.The results show that the existence of magnesium ions accelerates concrete deterioration.There is a critical dosage of fly ash for magnesium sulfate resistance of concrete.The magnesium sulfate resistance of concrete is improved when the fly ash content is less than 20%.Slag can significantly improve the corrosion resistance of concrete to magnesium sulfate.The diffusion of sulfate ions into concrete is a gradual process.In the early stages of corrosion,sulfate ion content in the concrete immersed in the magnesium sulfate solution is slightly less than that of the concrete immersed in the sodium sulfate solution.However,in the later stage of corrosion,the sulfate ion content in the concrete immersed in the magnesium sulfate solution is significantly higher than that of the concrete immersed in the sodium sulfate solution.
