Through the development and calibration of a reference material which is 209.8 Ma old using a newly-developed Laser Ablation(LA)Multi-Collector Inductively Coupled Plasma Mass Spectrometry(MC-ICP-MS)technique,we succe...Through the development and calibration of a reference material which is 209.8 Ma old using a newly-developed Laser Ablation(LA)Multi-Collector Inductively Coupled Plasma Mass Spectrometry(MC-ICP-MS)technique,we successfully overcome the difficulty in sampling and dating ultra-low U-Pb ancient marine carbonates,which was previously untenable by isotope dilution(ID)methods.We developed the LA-MC-ICP-MS in situ U-Pb dating technique for ancient marine carbonates for the study of diagenesis-porosity evolution history in Sinian Dengying Formation,Sichuan Basin.By systematically dating of dolomitic cements from vugs,matrix pores and fractures,we found that the burial and diagenetic process of dolomite reservoirs in Sinian Dengying Formation was characterized by progressive filling-up of primary pores and epigenic dissolution vugs.The filling of vugs happened in three stages,early Caledonian,late Hercynian-Indosinian and Yanshanian-Himalayan,while the filling of matrix pores mainly took place in early Caledonian.The unfilled residual vugs,pores and fractures constitute the main reservoir sapce.Based on the above knowledge,we established the diagenesis-porosity evolution history of the dolomite reservoir in Sinian Dengying Formation,Sichuan Basin.These findings are highly consistent with the tectonic-burial and basin thermal histories of the study area.Our study confirmed the reliability of this in situ U-Pb dating technique,which provides an effective way for the investigation of diagenesis-porosity evolution history and evaluation of porosity in ancient marine carbonate reservoirs before hydrocarbon migration.展开更多
Ancient marine carbonates experienced complex modifications,making it difficult to identify reservoir genesis and effective porosity before hydrocarbon migration.To solve these issues,we used element mapping and carbo...Ancient marine carbonates experienced complex modifications,making it difficult to identify reservoir genesis and effective porosity before hydrocarbon migration.To solve these issues,we used element mapping and carbonate mineral laser U-Pb radiometric dating techniques to study the diagenetic environments based on geochemistry and diagenesis-porosity evolution based on geochronology of the dolomite reservoir of the Sinian Qigebrak Formation,northwest Tarim Basin.Two major understandings were obtained as follows:(1)Supported by petrographic observations,the element mapping,stable isotopes,strontium isotope,and cathodoluminescence tests were performed on different phases of dolomite cements precipitated in vugs and dissolved fissures.The results show that the dolomite reservoirs of the Qigebrak Formation went through freshwater,marine,extremely shallow burial,burial and hydrothermal diagenetic environments after synsedimentary dolomitization;the reservoir spaces were mainly formed in the synsedimentary period(primary pores)and freshwater environment(supergene dissolution pores)before burial;whereas the marine,burial and hydrothermal environments caused the gradual filling of reservoir space by dolomite cements.(2)Based on the above understandings,each phase of dolomite cement precipitated in the reservoir space was dated by the U-Pb radiometric dating technique,and the diagenesis-porosity evolution curves constrained by geochronology were established.The loss of reservoir porosity mainly occurred in the early Caledonian,and during the peak period of hydrocarbon generation of Yuertusi Formation source rock,the reservoirs still maintained at a porosity of 6%?10%.The above understandings provide a certain basis for the evaluation of accumulation effectiveness of the Sinian Qigebrak Formation,northwestern Tarim Basin,and provide a case for the application of mapping and dating techniques in the study of ancient carbonate reservoirs.展开更多
基金Suppored by the China National Science and Technology Major Project(2016ZX05004-002).
文摘Through the development and calibration of a reference material which is 209.8 Ma old using a newly-developed Laser Ablation(LA)Multi-Collector Inductively Coupled Plasma Mass Spectrometry(MC-ICP-MS)technique,we successfully overcome the difficulty in sampling and dating ultra-low U-Pb ancient marine carbonates,which was previously untenable by isotope dilution(ID)methods.We developed the LA-MC-ICP-MS in situ U-Pb dating technique for ancient marine carbonates for the study of diagenesis-porosity evolution history in Sinian Dengying Formation,Sichuan Basin.By systematically dating of dolomitic cements from vugs,matrix pores and fractures,we found that the burial and diagenetic process of dolomite reservoirs in Sinian Dengying Formation was characterized by progressive filling-up of primary pores and epigenic dissolution vugs.The filling of vugs happened in three stages,early Caledonian,late Hercynian-Indosinian and Yanshanian-Himalayan,while the filling of matrix pores mainly took place in early Caledonian.The unfilled residual vugs,pores and fractures constitute the main reservoir sapce.Based on the above knowledge,we established the diagenesis-porosity evolution history of the dolomite reservoir in Sinian Dengying Formation,Sichuan Basin.These findings are highly consistent with the tectonic-burial and basin thermal histories of the study area.Our study confirmed the reliability of this in situ U-Pb dating technique,which provides an effective way for the investigation of diagenesis-porosity evolution history and evaluation of porosity in ancient marine carbonate reservoirs before hydrocarbon migration.
基金Supported by the China National Science and Technology Major Project(2016ZX05004-002)the PetroChina Science and Technology Major Project(2018A-0103)
文摘Ancient marine carbonates experienced complex modifications,making it difficult to identify reservoir genesis and effective porosity before hydrocarbon migration.To solve these issues,we used element mapping and carbonate mineral laser U-Pb radiometric dating techniques to study the diagenetic environments based on geochemistry and diagenesis-porosity evolution based on geochronology of the dolomite reservoir of the Sinian Qigebrak Formation,northwest Tarim Basin.Two major understandings were obtained as follows:(1)Supported by petrographic observations,the element mapping,stable isotopes,strontium isotope,and cathodoluminescence tests were performed on different phases of dolomite cements precipitated in vugs and dissolved fissures.The results show that the dolomite reservoirs of the Qigebrak Formation went through freshwater,marine,extremely shallow burial,burial and hydrothermal diagenetic environments after synsedimentary dolomitization;the reservoir spaces were mainly formed in the synsedimentary period(primary pores)and freshwater environment(supergene dissolution pores)before burial;whereas the marine,burial and hydrothermal environments caused the gradual filling of reservoir space by dolomite cements.(2)Based on the above understandings,each phase of dolomite cement precipitated in the reservoir space was dated by the U-Pb radiometric dating technique,and the diagenesis-porosity evolution curves constrained by geochronology were established.The loss of reservoir porosity mainly occurred in the early Caledonian,and during the peak period of hydrocarbon generation of Yuertusi Formation source rock,the reservoirs still maintained at a porosity of 6%?10%.The above understandings provide a certain basis for the evaluation of accumulation effectiveness of the Sinian Qigebrak Formation,northwestern Tarim Basin,and provide a case for the application of mapping and dating techniques in the study of ancient carbonate reservoirs.
