To explore ways to improve the accuracy of quantitative analysis of samples in the micrometer to nanometer range of magnitudes,we adopted analytical transmission electron microscopy(AEM/EDS)for qualitative and quantit...To explore ways to improve the accuracy of quantitative analysis of samples in the micrometer to nanometer range of magnitudes,we adopted analytical transmission electron microscopy(AEM/EDS)for qualitative and quantitative analysis of pyrite materials.Additionally,the k factor of pyrite is calculated experimentally.To develop an appropriate non-standard quantitative analysis model for pyrite materials,the experimentally calculated k factor is compared with that estimated from the non-standard quantitative analytical model of the instrument software.The experimental findings demonstrate that the EDS attached to a TEM can be employed for precise quantitative analysis of micro-and nanoscale regions of pyrite materials.Furthermore,it serves as a reference for improving the results of the EDS quantitative analysis of other sulfides.展开更多
In order to improve the properties of corundum based dispersive purging plugs,dispersive purging plug specimens were prepared using tabular corundum(1-0.15 and≤0.15 mm)as the aggregates,tabular corundum(≤0.044 mm)an...In order to improve the properties of corundum based dispersive purging plugs,dispersive purging plug specimens were prepared using tabular corundum(1-0.15 and≤0.15 mm)as the aggregates,tabular corundum(≤0.044 mm)andα-Al_(2)O_(3)micropowder(d_(50)=0.6μm)as the matrix,Secar 71 cement as the binder,introducing different amounts of nano-CaCO_(3),casting into shapes,and firing at different temperatures(1200 or 1600℃)for 4 h.The effects of the nano-CaCO_(3) extra-addition(0,0.5%,1.0%,1.5%and 2.0%,by mass)on the consistency of the castables as well as the properties and microstructure of the dispersive purging plug specimens were studied.The results show that:(1)with the fixed water addition,the consistency of the corundum castables decreases as the nano-CaCO_(3)addition increases;(2)with the increasing nano-CaCO_(3)addition,the bulk density of the specimens fired at different temperatures for 4 h decreases,the apparent porosity,the cold strength and the hot modulus of rupture all increase,the gas permeability does not change significantly;(3)the specimens fired at 1600℃ for 4 h have obviously better cold comprehensive performance than those fired at 1200℃for 4 h;(4)when the nano-CaCO_(3)addition is 1.5%,the comprehensive performance of the specimen is the optimal.展开更多
The high-fidelity reconstruction of sound speeds is crucial for predicting acoustic propagation in shallow water where internal solitary waves(ISWs)are prevalent.Mapping temperatures from time series to spatial fields...The high-fidelity reconstruction of sound speeds is crucial for predicting acoustic propagation in shallow water where internal solitary waves(ISWs)are prevalent.Mapping temperatures from time series to spatial fields is an approach widely used to reproduce the sound speed perturbed by deformed internal waves.However,wave-shape distortions are inherent in the modeling results.This paper analyzes the formation mechanism and dynamic behavior of the distorted waveform that is shown to arise from the mismatch between the modeled and real propagation speeds of individual solitons within an ISW packet.To mitigate distortions,a reconstruction method incorporating the dispersion property of an ISW train is proposed here.The principle is to assign each soliton a real speed observed in the experiment.Then,the modeled solitons propagate at their intrinsic speeds,and the packet disperses naturally with time.The method is applied to reconstruct the sound speed perturbed by ISWs in the South China Sea.The mean and median of the root-mean-square error between the reconstructed and measured sound speeds are below 2 m/s.The modeled shape deformations and packet dispersion agree well with observations,and the waveform distortion is reduced compared with the original method.This work ensures the high fidelity of waveguide-environment reconstructions and facilitates the investigation of sound propagation in the future.展开更多
High-order models with a dissipative term for nonlinear and dispersive wave in water of va-rying depth with an arbitrary sloping bottom are presented in this article.First,the formal derivations toany high order of μ...High-order models with a dissipative term for nonlinear and dispersive wave in water of va-rying depth with an arbitrary sloping bottom are presented in this article.First,the formal derivations toany high order of μ(=h/λ,depth to deep-water wave length ratio)and ε(=α/h,wave amplitude todepth ratio)for velocity potential,particle velocity vector,pressure and the Boussinesq-type equations forsurface elevation η and horizontal velocity vector U at any given level in water are given.Then,the exactexplicit expressions to the fourth order of μ are derived.Finally,the linear solutions of η,U,C(phase ce-lerity)and C_g(group velocity)for a constant water depth are obtained.Compared with the Airy theory,excellent results can be found even for a water depth as large as the wave legnth.The present high-ordermodels are applicable to nonlinear regular and irregular waves in water of any varying depth(from shal-low to deep)and bottom slope(from mild to steep).展开更多
In the present work,dispersive liquid-liquid microextraction(DLLME)was used to extract six synthetic cannabinoids(JWH-018,JWH-019,JWH-073,JWH-200,or WIN 55,225,JWH-250,and AM-694)from oral fluids.A rapid baseline sepa...In the present work,dispersive liquid-liquid microextraction(DLLME)was used to extract six synthetic cannabinoids(JWH-018,JWH-019,JWH-073,JWH-200,or WIN 55,225,JWH-250,and AM-694)from oral fluids.A rapid baseline separation of the analytes was achieved on a bidentate octadecyl silica hydride phase(Cogent Bidentate C18;4.6 mm×250 mm,4μm)maintained at 37℃,by eluting in isocratic conditions(water:acetonitrile(25:75,V/V)).Detection was performed using positive electrospray ionization-tandem mass spectrometry.The parameters affecting DLLME(pH and ionic strength of the aqueous phase,type and volume of the extractant and dispersive solvent,vortex and centrifugation time)were optimized for maximizing yields.In particular,using 0.5 mL of oral fluid,acetonitrile(1 mL),was identified as the best option,both as a solvent to precipitate proteins and as a dispersing solvent in the DLLME procedure.To select an extraction solvent,a low transition temperature mixture(LTTM;composed of sesamol and chlorine chloride with a molar ratio of 1:3)and dichloromethane were compared;the latter(100μL)was proved to be a better extractant,with recoveries ranging from 73%to 101%by vortexing for 2 min.The method was validated according to the guidelines of Food and Drug Administration bioanalytical methods:intra-day and inter-day precisions ranged between 4%and 18%depending on the spike level and analyte;limits of detection spanned from 2 to 18 ng/mL;matrixmatched calibration curves were characterized by determination coefficients greater than 0.9914.Finally,the extraction procedure was compared with previous methods and with innovative techniques,presenting superior reliability,rapidity,simplicity,inexpensiveness,and efficiency.展开更多
We investigate (2+1)-dimensional generalized modified dispersive water wave (GMDWW) equation by utilizing the bifurcation theory of dynamical systems. We give the phase portraits and bifurcation analysis of the plane ...We investigate (2+1)-dimensional generalized modified dispersive water wave (GMDWW) equation by utilizing the bifurcation theory of dynamical systems. We give the phase portraits and bifurcation analysis of the plane system corresponding to the GMDWW equation. By using the special orbits in the phase portraits, we analyze the existence of the traveling wave solutions. When some parameter takes special values, we obtain abundant exact kink wave solutions, singular wave solutions, periodic wave solutions, periodic singular wave solutions, and solitary wave solutions for the GMDWW equation.展开更多
Dispersive optics quantum key distribution(DO-QKD)based on energy-time entangled photon pairs is an important QKD scheme.In DO-QKD,the arrival time of photons is used in key generation and security analysis,which woul...Dispersive optics quantum key distribution(DO-QKD)based on energy-time entangled photon pairs is an important QKD scheme.In DO-QKD,the arrival time of photons is used in key generation and security analysis,which would be greatly affected by fiber dispersion.In this work,we establish a theoretical model of the entanglement-based DO-QKD system,considering the protocol,physical processes(such as fiber transmission and single-photon detection),and the analysis of security tests.Based on this theoretical model,we investigate the influence of chromatic dispersion introduced by transmission fibers on the performance of DO-QKD.By analyzing the benefits and costs of dispersion compensation,the system performance under G.652 and G.655 optical fibers are shown,respectively.The results show that dispersion compensation is unnecessary for DO-QKD systems in campus networks and even metro networks.Whereas,it is still required in DO-QKD systems with longer fiber transmission distances.展开更多
Using a simple homogeneous balance method,which is very concise and primary,we find the multiple soliton solutions of the dispersive long-wave equations.The method can be generalized to deal with the higher dimensiona...Using a simple homogeneous balance method,which is very concise and primary,we find the multiple soliton solutions of the dispersive long-wave equations.The method can be generalized to deal with the higher dimensional dispersive long-wave equations and other class of nonlinear equation.展开更多
Dispersive liquid-liquid microextraction (DLLME) followed by gas chromatography–flame ionization detection (GC-FID), as a simple, rapid and efficient method, was developed for the determination of amitraz in honey sa...Dispersive liquid-liquid microextraction (DLLME) followed by gas chromatography–flame ionization detection (GC-FID), as a simple, rapid and efficient method, was developed for the determination of amitraz in honey samples. This method involves the use of an appropriate mixture of the extraction and disperser solvents for the formation of a cloudy solution in 5.0 mL aqueous sample containing amitraz. After extraction, phase separation was performed by centrifugation and the concentrated amitraz in the sedimented phase was determined by gas chromatography—flame ionization detection (GC-FID). Some important parameters such as the type and volume of extraction and disperser solvents, and the effect of pH and salt on the extraction recovery of amitraz were investigated. Under the optimum conditions (13 μL of carbon tetrachloride as an extraction solvent, 1 mL of acetonitrile as a disperser solvent, no salt addition and pH 6) preconcentration factor and the extraction recovery were 955 and 95.5%, respectively. The linear range was 0.01 - 1.0 mg?kg–1 and the limit of detection was 0.0015 mg?kg–1. The relative standard deviation (RSD, n = 4) for 0.1 mg?kg–1 of amitraz was 3.2%. The recoveries of amitraz from honey samples at the spiking levels of 0.1 mg?kg-1 were 78.8 and 98.2%. The results indicated that DLLME is an efficient technique for the extraction of amitraz in honey samples.展开更多
The pulse with a rectangular envelop propagating through the caesium vapour with two gain lines used inthe Wang, Kuzmich, and Dogariu [Nature (London) 406 (2000) 277] experiment is studied. It is shown that there exis...The pulse with a rectangular envelop propagating through the caesium vapour with two gain lines used inthe Wang, Kuzmich, and Dogariu [Nature (London) 406 (2000) 277] experiment is studied. It is shown that there existsan obvious distortion for the pulse.展开更多
A class of three-level explicit difference schemes for the dispersive equationu<sub>1</sub>=au<sub>xxx</sub>are established These schemes have higher stability and involve four meshpoints at th...A class of three-level explicit difference schemes for the dispersive equationu<sub>1</sub>=au<sub>xxx</sub>are established These schemes have higher stability and involve four meshpoints at the middle level.Their local truncation errors are O（τ+h）and stabilityconditions are from|R|≤0.25 to|R|≤10,where|R|=|a|τ/h<sup>3</sup>,which is muchbetter than|R|≤0.25.展开更多
Isomeric triterpenic acids of oleanolic acid (OA) and ursolic acid (UA) both have very low ultraviolet absorption and always exist in the same plant, so the separation and simultaneous determination of them have been ...Isomeric triterpenic acids of oleanolic acid (OA) and ursolic acid (UA) both have very low ultraviolet absorption and always exist in the same plant, so the separation and simultaneous determination of them have been a difficult task. In this study, a sensitive method combining dispersive liquid-liquid microextraction (DLLME) with HPLC-UV was developed for the extraction and determination of OA and UA in traditional Chinese medicinal herbs (CMHs). Variables influencing DLLME such as type and volume of extraction solvent, volume of dispersive solvent, ionic strength, aqueous phase pH, extraction time, centrifugation speed and time, and sample volume were investigated and optimized. Under the optimum conditions, both OA and UA attained favorable extraction efficiencies with enrichment factors 1378 and 933, respectively. The linear dynamic ranges of 0.07 - 30.4 μg?mL–1 for OA and 0.08 - 33.6 μg?mL–1 for UA were obtained with square correlation coefficients of 0.9963. The detection limits of OA and UA were both 0.02 μg?mL–1. The method recoveries ranged between 88.2% - 116.2% for OA and 85.7% - 108.2% for UA with the RSDs (n = 5) lower than 8.6%. The proposed method was successfully applied to concentrate and simultaneously determine these two triterpenic acids in Hedyotis diffusa and Eriobotrya japonica samples.展开更多
To formulate a scientific basis for a reasonable spray dose and safe interval period of 20% flubendiamide water dispersible granule (WDG) on controlling vegetable pests, degradation dynamics of flubendiamide in cabbag...To formulate a scientific basis for a reasonable spray dose and safe interval period of 20% flubendiamide water dispersible granule (WDG) on controlling vegetable pests, degradation dynamics of flubendiamide in cabbage and soil was analyzed in this study. Dissipation and residue of flubendiamide in 20% flubendiamide WDG in cabbage and soil under field conditions were investigated by liquid chromatography-tandem mass spectrometry with dispersive solid phase extraction. Results showed that the degradation dynamic equations of flubendiamide in cabbage and soil were based on the first-order reaction dynamic equations. The half-lives of the degradation of flubendiamide were 3.51 d to 3.96 d and 3.43 d to 3.87 d in the cabbage of Yangzhou and Jingzhou, respectively, and 4.42 d to 5.13 d and 4.37 d to 4.99 d in the soil of Yangzhou and Jingzhou, respectively. The terminal residues of flubendiamide in the cabbage of Yangzhou and Jingzhou were 0.0247 mg·kg-1 to 0.0393 mg·kg-1 and 0.0225 mg·kg-1 to 0.0273 mg·kg-1, respectively, when 20% flubendiamide WDG was applied at a dose of0.050g·m-2. Flubendiamide is safe to be applied in cabbage fields at the recommended dose.展开更多
Enrichment of trace bioactive constituents and metabolites from complex biological samples is challenging.This study presented a one-pot synthesis of magnetic polydopamine nanoparticles(Fe3O4@-SiO2@PDA NPs)with multip...Enrichment of trace bioactive constituents and metabolites from complex biological samples is challenging.This study presented a one-pot synthesis of magnetic polydopamine nanoparticles(Fe3O4@-SiO2@PDA NPs)with multiple recognition sites for the magnetic dispersive solid-phase extraction(MDSPE)of ginsenosides from rat plasma treated with white ginseng.The extracted ginsenosides were characterized by combining an ultra-high-performance liquid chromatography coupled to a highresolution mass spectrometry with supplemental UNIFI libraries.Response surface methodology was statistically used to optimize the extraction procedure of the ginsenosides.The reusability of Fe3O4@-SiO2@PDA NPs was also examined and the results showed that the recovery rate exceeded 80%after recycling 6 times.Furthermore,the proposed method showed greater enrichment efficiency and could rapidly determine and characterize 23 ginsenoside prototypes and metabolites from plasma.In comparison,conventional methanol method can only detect 8 ginsenosides from the same plasma samples.The proposed approach can provide methodological reference for the trace determination and characterization of different bioactive ingredients and metabolites of traditional Chinese medicines and food.展开更多
A new method for the determination of cobalt was developed by dispersive liquid-liquid microextraction preconcentra-tion and flame atomic absorption spectrometry. In the proposed approach, 1,5-bis(di-2-pyridyl) methyl...A new method for the determination of cobalt was developed by dispersive liquid-liquid microextraction preconcentra-tion and flame atomic absorption spectrometry. In the proposed approach, 1,5-bis(di-2-pyridyl) methylene thiocarbohydrazide (DPTH) was used as a chelating agent, and chloroform and ethanol were selected as extraction and dispersive solvents. Some factors influencing the extraction efficiency of cobalt and its subsequent determination, including extraction and dispersive solvent type and volume, pH of sample solution, concentration of the chelating agent, and extraction time, were studied and optimized. Under the optimum conditions, a preconcentration factor of 8 was reached. The detection limit for cobalt was 12.4 ng?mL–1, and the relative standard deviation (RSD) was 3.42% (n = 7, c = 100 ng?mL–1). The method was successfully applied to the determination of cobalt in food, environmental and water samples.展开更多
Certain hybrid prototypes of dispersive optical solitons that we are looking for can correspond to new or future behaviors, observable or not, developed or will be developed by optical media that present the cubic-qui...Certain hybrid prototypes of dispersive optical solitons that we are looking for can correspond to new or future behaviors, observable or not, developed or will be developed by optical media that present the cubic-quintic-septic law coupled, with strong dispersions. The equation considered for this purpose is that of non-linear Schrödinger. The solutions are obtained using the Bogning-Djeumen Tchaho-Kofané method extended to the new implicit Bogning’ functions. Some of the obtained solutions show that their existence is due only to the Kerr law nonlinearity presence. Graphical representations plotted have confirmed the hybrid and multi-form character of the obtained dispersive optical solitons. We believe that a good understanding of the hybrid dispersive optical solitons highlighted in the context of this work allows to grasp the physical description of systems whose dynamics are governed by nonlinear Schrödinger equation as studied in this work, allowing thereby a relevant improvement of complex problems encountered in particular in nonliear optaics and in optical fibers.展开更多
Dispersive soils which occur in many parts of the world are easily erodible and segregate in water pose serious problems of stability of earth and earth retaining structures. The mechanism of dispersivity of soils is ...Dispersive soils which occur in many parts of the world are easily erodible and segregate in water pose serious problems of stability of earth and earth retaining structures. The mechanism of dispersivity of soils is reasonably well understood. However there is simple method to identify the dispersivity of the soils and even more difficult to quantify the dispersivity. Visual classification, Atterberg’s limits and particle size analysis do not provide sufficient basis to differentiate between dispersive clays and ordinary erosion resistant clays. Pinhole test and double hydrometer test are the only two tests that are in vogue to identify the dispersive soils. This paper explores the possibility of using other standard tests such as shrinkage limit and unconfined compressive strength tests to quantify the dispersivity of the soils. The rationale of using the methods and correlation between the dispersivity determined by various methods has been explained. It has been concluded that dispersivity ascertained from strength tests is more reliable.展开更多
Eight water bottles from Ebrie lagoon with pollution potency were studied using nuclear chemistry technique and Energy dispersive X-ray fluorescence. This pollution is characterized by pH and conductivity parameters, ...Eight water bottles from Ebrie lagoon with pollution potency were studied using nuclear chemistry technique and Energy dispersive X-ray fluorescence. This pollution is characterized by pH and conductivity parameters, concentrations average in mg/L of metals such Fe (0.731), Mn (0.345), Cr (0.070), Cu (0.014) and concentrations of nutrients known to be pollutants and toxic for living or-ganisms. These heavy metals are dangerous to the lives, the local inhabitants and also a threat to aquatic life since this water is essential for the economical town, Abidjan. According to the Manganese concentration average (0.345 mg) values that higher than WHO (0.05 mg) value, the main likely source of pollu-tants is anthropogenic, industrial and agricultural. This study also shows the use of materials and lubricants near the lagoon that pollute this water.展开更多
We present a high-dispersive multilayer mirror for pulse stretching in a femtosecond fiber laser amplification system.The designed mirror contains 54 layers with a total physical thickness of 7.3 μm, which can provid...We present a high-dispersive multilayer mirror for pulse stretching in a femtosecond fiber laser amplification system.The designed mirror contains 54 layers with a total physical thickness of 7.3 μm, which can provide a positive group delay dispersion(GDD) of 600 fs2and a high reflectance over 99.9% from 1010 to 1070 nm. The samples were prepared by dual ion beam sputtering. The measured transmittance matches well with the theoretical result. The GDD characteristics of samples were tested by home-made white light interferometer. The measured GDD is higher than the design results,an average GDD of +722 fs2from 1010 nm to 1070 nm. The mirrors were employed in a Yb-doped large-mode-area photonic crystal fiber amplification system. An input pulse compressed by the gratings with autocorrelation function of83 fs is obtained with a stretched FWHM of 1.29 ps after 28 bounces between the dispersive mirrors. The results show that the multilayer dispersive mirror could be an effective and promising technique for pulse stretching in femtosecond amplification systems.展开更多
The electromagnetic properties of wire medium are studied by analyzing its transmission coefficient,and a homogeneous uniaxial effective permittivity tensor with one spatially dispersive component is obtained.In order...The electromagnetic properties of wire medium are studied by analyzing its transmission coefficient,and a homogeneous uniaxial effective permittivity tensor with one spatially dispersive component is obtained.In order to evaluate the validity of the equivalent model for scattering problems,the bistatic and monostatic radar cross sections(RCS)of a block of wire medium are investigated with the finitedifference time-domain(FDTD)method.The difference of RCS from the physical wire medium and the corresponding equivalent model has been compared and analyzed under various parameters of wire medium,which clearly demonstrates the accuracy of the equivalent model of wire medium.展开更多
基金Funded by the International Science&Technology Cooperation Program of Hubei Province of China(No.2022EHB024)。
文摘To explore ways to improve the accuracy of quantitative analysis of samples in the micrometer to nanometer range of magnitudes,we adopted analytical transmission electron microscopy(AEM/EDS)for qualitative and quantitative analysis of pyrite materials.Additionally,the k factor of pyrite is calculated experimentally.To develop an appropriate non-standard quantitative analysis model for pyrite materials,the experimentally calculated k factor is compared with that estimated from the non-standard quantitative analytical model of the instrument software.The experimental findings demonstrate that the EDS attached to a TEM can be employed for precise quantitative analysis of micro-and nanoscale regions of pyrite materials.Furthermore,it serves as a reference for improving the results of the EDS quantitative analysis of other sulfides.
文摘In order to improve the properties of corundum based dispersive purging plugs,dispersive purging plug specimens were prepared using tabular corundum(1-0.15 and≤0.15 mm)as the aggregates,tabular corundum(≤0.044 mm)andα-Al_(2)O_(3)micropowder(d_(50)=0.6μm)as the matrix,Secar 71 cement as the binder,introducing different amounts of nano-CaCO_(3),casting into shapes,and firing at different temperatures(1200 or 1600℃)for 4 h.The effects of the nano-CaCO_(3) extra-addition(0,0.5%,1.0%,1.5%and 2.0%,by mass)on the consistency of the castables as well as the properties and microstructure of the dispersive purging plug specimens were studied.The results show that:(1)with the fixed water addition,the consistency of the corundum castables decreases as the nano-CaCO_(3)addition increases;(2)with the increasing nano-CaCO_(3)addition,the bulk density of the specimens fired at different temperatures for 4 h decreases,the apparent porosity,the cold strength and the hot modulus of rupture all increase,the gas permeability does not change significantly;(3)the specimens fired at 1600℃ for 4 h have obviously better cold comprehensive performance than those fired at 1200℃for 4 h;(4)when the nano-CaCO_(3)addition is 1.5%,the comprehensive performance of the specimen is the optimal.
基金Project supported by the National Natural Science Foundation of China (Grant Nos.11534009,11904342,and 12274348)。
文摘The high-fidelity reconstruction of sound speeds is crucial for predicting acoustic propagation in shallow water where internal solitary waves(ISWs)are prevalent.Mapping temperatures from time series to spatial fields is an approach widely used to reproduce the sound speed perturbed by deformed internal waves.However,wave-shape distortions are inherent in the modeling results.This paper analyzes the formation mechanism and dynamic behavior of the distorted waveform that is shown to arise from the mismatch between the modeled and real propagation speeds of individual solitons within an ISW packet.To mitigate distortions,a reconstruction method incorporating the dispersion property of an ISW train is proposed here.The principle is to assign each soliton a real speed observed in the experiment.Then,the modeled solitons propagate at their intrinsic speeds,and the packet disperses naturally with time.The method is applied to reconstruct the sound speed perturbed by ISWs in the South China Sea.The mean and median of the root-mean-square error between the reconstructed and measured sound speeds are below 2 m/s.The modeled shape deformations and packet dispersion agree well with observations,and the waveform distortion is reduced compared with the original method.This work ensures the high fidelity of waveguide-environment reconstructions and facilitates the investigation of sound propagation in the future.
文摘High-order models with a dissipative term for nonlinear and dispersive wave in water of va-rying depth with an arbitrary sloping bottom are presented in this article.First,the formal derivations toany high order of μ(=h/λ,depth to deep-water wave length ratio)and ε(=α/h,wave amplitude todepth ratio)for velocity potential,particle velocity vector,pressure and the Boussinesq-type equations forsurface elevation η and horizontal velocity vector U at any given level in water are given.Then,the exactexplicit expressions to the fourth order of μ are derived.Finally,the linear solutions of η,U,C(phase ce-lerity)and C_g(group velocity)for a constant water depth are obtained.Compared with the Airy theory,excellent results can be found even for a water depth as large as the wave legnth.The present high-ordermodels are applicable to nonlinear regular and irregular waves in water of any varying depth(from shal-low to deep)and bottom slope(from mild to steep).
基金supported by the Sapienza University of Rome through the project RICERCA 2019(protocol number:RG11916B6451D44A)。
文摘In the present work,dispersive liquid-liquid microextraction(DLLME)was used to extract six synthetic cannabinoids(JWH-018,JWH-019,JWH-073,JWH-200,or WIN 55,225,JWH-250,and AM-694)from oral fluids.A rapid baseline separation of the analytes was achieved on a bidentate octadecyl silica hydride phase(Cogent Bidentate C18;4.6 mm×250 mm,4μm)maintained at 37℃,by eluting in isocratic conditions(water:acetonitrile(25:75,V/V)).Detection was performed using positive electrospray ionization-tandem mass spectrometry.The parameters affecting DLLME(pH and ionic strength of the aqueous phase,type and volume of the extractant and dispersive solvent,vortex and centrifugation time)were optimized for maximizing yields.In particular,using 0.5 mL of oral fluid,acetonitrile(1 mL),was identified as the best option,both as a solvent to precipitate proteins and as a dispersing solvent in the DLLME procedure.To select an extraction solvent,a low transition temperature mixture(LTTM;composed of sesamol and chlorine chloride with a molar ratio of 1:3)and dichloromethane were compared;the latter(100μL)was proved to be a better extractant,with recoveries ranging from 73%to 101%by vortexing for 2 min.The method was validated according to the guidelines of Food and Drug Administration bioanalytical methods:intra-day and inter-day precisions ranged between 4%and 18%depending on the spike level and analyte;limits of detection spanned from 2 to 18 ng/mL;matrixmatched calibration curves were characterized by determination coefficients greater than 0.9914.Finally,the extraction procedure was compared with previous methods and with innovative techniques,presenting superior reliability,rapidity,simplicity,inexpensiveness,and efficiency.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 11361069 and 11775146).
文摘We investigate (2+1)-dimensional generalized modified dispersive water wave (GMDWW) equation by utilizing the bifurcation theory of dynamical systems. We give the phase portraits and bifurcation analysis of the plane system corresponding to the GMDWW equation. By using the special orbits in the phase portraits, we analyze the existence of the traveling wave solutions. When some parameter takes special values, we obtain abundant exact kink wave solutions, singular wave solutions, periodic wave solutions, periodic singular wave solutions, and solitary wave solutions for the GMDWW equation.
基金the National Key R&D Program of China under Grants No.2017YFA0303704 and No.2018YFB2200400Natural Science Foundation of Beijing under Grant No.Z180012National Natural Science Foundation of China under Grants No.61875101 and No.91750206.
文摘Dispersive optics quantum key distribution(DO-QKD)based on energy-time entangled photon pairs is an important QKD scheme.In DO-QKD,the arrival time of photons is used in key generation and security analysis,which would be greatly affected by fiber dispersion.In this work,we establish a theoretical model of the entanglement-based DO-QKD system,considering the protocol,physical processes(such as fiber transmission and single-photon detection),and the analysis of security tests.Based on this theoretical model,we investigate the influence of chromatic dispersion introduced by transmission fibers on the performance of DO-QKD.By analyzing the benefits and costs of dispersion compensation,the system performance under G.652 and G.655 optical fibers are shown,respectively.The results show that dispersion compensation is unnecessary for DO-QKD systems in campus networks and even metro networks.Whereas,it is still required in DO-QKD systems with longer fiber transmission distances.
文摘Using a simple homogeneous balance method,which is very concise and primary,we find the multiple soliton solutions of the dispersive long-wave equations.The method can be generalized to deal with the higher dimensional dispersive long-wave equations and other class of nonlinear equation.
文摘Dispersive liquid-liquid microextraction (DLLME) followed by gas chromatography–flame ionization detection (GC-FID), as a simple, rapid and efficient method, was developed for the determination of amitraz in honey samples. This method involves the use of an appropriate mixture of the extraction and disperser solvents for the formation of a cloudy solution in 5.0 mL aqueous sample containing amitraz. After extraction, phase separation was performed by centrifugation and the concentrated amitraz in the sedimented phase was determined by gas chromatography—flame ionization detection (GC-FID). Some important parameters such as the type and volume of extraction and disperser solvents, and the effect of pH and salt on the extraction recovery of amitraz were investigated. Under the optimum conditions (13 μL of carbon tetrachloride as an extraction solvent, 1 mL of acetonitrile as a disperser solvent, no salt addition and pH 6) preconcentration factor and the extraction recovery were 955 and 95.5%, respectively. The linear range was 0.01 - 1.0 mg?kg–1 and the limit of detection was 0.0015 mg?kg–1. The relative standard deviation (RSD, n = 4) for 0.1 mg?kg–1 of amitraz was 3.2%. The recoveries of amitraz from honey samples at the spiking levels of 0.1 mg?kg-1 were 78.8 and 98.2%. The results indicated that DLLME is an efficient technique for the extraction of amitraz in honey samples.
文摘The pulse with a rectangular envelop propagating through the caesium vapour with two gain lines used inthe Wang, Kuzmich, and Dogariu [Nature (London) 406 (2000) 277] experiment is studied. It is shown that there existsan obvious distortion for the pulse.
文摘A class of three-level explicit difference schemes for the dispersive equationu<sub>1</sub>=au<sub>xxx</sub>are established These schemes have higher stability and involve four meshpoints at the middle level.Their local truncation errors are O（τ+h）and stabilityconditions are from|R|≤0.25 to|R|≤10,where|R|=|a|τ/h<sup>3</sup>,which is muchbetter than|R|≤0.25.
文摘Isomeric triterpenic acids of oleanolic acid (OA) and ursolic acid (UA) both have very low ultraviolet absorption and always exist in the same plant, so the separation and simultaneous determination of them have been a difficult task. In this study, a sensitive method combining dispersive liquid-liquid microextraction (DLLME) with HPLC-UV was developed for the extraction and determination of OA and UA in traditional Chinese medicinal herbs (CMHs). Variables influencing DLLME such as type and volume of extraction solvent, volume of dispersive solvent, ionic strength, aqueous phase pH, extraction time, centrifugation speed and time, and sample volume were investigated and optimized. Under the optimum conditions, both OA and UA attained favorable extraction efficiencies with enrichment factors 1378 and 933, respectively. The linear dynamic ranges of 0.07 - 30.4 μg?mL–1 for OA and 0.08 - 33.6 μg?mL–1 for UA were obtained with square correlation coefficients of 0.9963. The detection limits of OA and UA were both 0.02 μg?mL–1. The method recoveries ranged between 88.2% - 116.2% for OA and 85.7% - 108.2% for UA with the RSDs (n = 5) lower than 8.6%. The proposed method was successfully applied to concentrate and simultaneously determine these two triterpenic acids in Hedyotis diffusa and Eriobotrya japonica samples.
文摘To formulate a scientific basis for a reasonable spray dose and safe interval period of 20% flubendiamide water dispersible granule (WDG) on controlling vegetable pests, degradation dynamics of flubendiamide in cabbage and soil was analyzed in this study. Dissipation and residue of flubendiamide in 20% flubendiamide WDG in cabbage and soil under field conditions were investigated by liquid chromatography-tandem mass spectrometry with dispersive solid phase extraction. Results showed that the degradation dynamic equations of flubendiamide in cabbage and soil were based on the first-order reaction dynamic equations. The half-lives of the degradation of flubendiamide were 3.51 d to 3.96 d and 3.43 d to 3.87 d in the cabbage of Yangzhou and Jingzhou, respectively, and 4.42 d to 5.13 d and 4.37 d to 4.99 d in the soil of Yangzhou and Jingzhou, respectively. The terminal residues of flubendiamide in the cabbage of Yangzhou and Jingzhou were 0.0247 mg·kg-1 to 0.0393 mg·kg-1 and 0.0225 mg·kg-1 to 0.0273 mg·kg-1, respectively, when 20% flubendiamide WDG was applied at a dose of0.050g·m-2. Flubendiamide is safe to be applied in cabbage fields at the recommended dose.
基金This work was supported by grants from the National Natural Science Foundation of China Key Program(NO.81530094)General Program(NO.81573574,81873193)the Science and Technology Development Project of Jilin Province(20190201283JC).
文摘Enrichment of trace bioactive constituents and metabolites from complex biological samples is challenging.This study presented a one-pot synthesis of magnetic polydopamine nanoparticles(Fe3O4@-SiO2@PDA NPs)with multiple recognition sites for the magnetic dispersive solid-phase extraction(MDSPE)of ginsenosides from rat plasma treated with white ginseng.The extracted ginsenosides were characterized by combining an ultra-high-performance liquid chromatography coupled to a highresolution mass spectrometry with supplemental UNIFI libraries.Response surface methodology was statistically used to optimize the extraction procedure of the ginsenosides.The reusability of Fe3O4@-SiO2@PDA NPs was also examined and the results showed that the recovery rate exceeded 80%after recycling 6 times.Furthermore,the proposed method showed greater enrichment efficiency and could rapidly determine and characterize 23 ginsenoside prototypes and metabolites from plasma.In comparison,conventional methanol method can only detect 8 ginsenosides from the same plasma samples.The proposed approach can provide methodological reference for the trace determination and characterization of different bioactive ingredients and metabolites of traditional Chinese medicines and food.
文摘A new method for the determination of cobalt was developed by dispersive liquid-liquid microextraction preconcentra-tion and flame atomic absorption spectrometry. In the proposed approach, 1,5-bis(di-2-pyridyl) methylene thiocarbohydrazide (DPTH) was used as a chelating agent, and chloroform and ethanol were selected as extraction and dispersive solvents. Some factors influencing the extraction efficiency of cobalt and its subsequent determination, including extraction and dispersive solvent type and volume, pH of sample solution, concentration of the chelating agent, and extraction time, were studied and optimized. Under the optimum conditions, a preconcentration factor of 8 was reached. The detection limit for cobalt was 12.4 ng?mL–1, and the relative standard deviation (RSD) was 3.42% (n = 7, c = 100 ng?mL–1). The method was successfully applied to the determination of cobalt in food, environmental and water samples.
文摘Certain hybrid prototypes of dispersive optical solitons that we are looking for can correspond to new or future behaviors, observable or not, developed or will be developed by optical media that present the cubic-quintic-septic law coupled, with strong dispersions. The equation considered for this purpose is that of non-linear Schrödinger. The solutions are obtained using the Bogning-Djeumen Tchaho-Kofané method extended to the new implicit Bogning’ functions. Some of the obtained solutions show that their existence is due only to the Kerr law nonlinearity presence. Graphical representations plotted have confirmed the hybrid and multi-form character of the obtained dispersive optical solitons. We believe that a good understanding of the hybrid dispersive optical solitons highlighted in the context of this work allows to grasp the physical description of systems whose dynamics are governed by nonlinear Schrödinger equation as studied in this work, allowing thereby a relevant improvement of complex problems encountered in particular in nonliear optaics and in optical fibers.
文摘Dispersive soils which occur in many parts of the world are easily erodible and segregate in water pose serious problems of stability of earth and earth retaining structures. The mechanism of dispersivity of soils is reasonably well understood. However there is simple method to identify the dispersivity of the soils and even more difficult to quantify the dispersivity. Visual classification, Atterberg’s limits and particle size analysis do not provide sufficient basis to differentiate between dispersive clays and ordinary erosion resistant clays. Pinhole test and double hydrometer test are the only two tests that are in vogue to identify the dispersive soils. This paper explores the possibility of using other standard tests such as shrinkage limit and unconfined compressive strength tests to quantify the dispersivity of the soils. The rationale of using the methods and correlation between the dispersivity determined by various methods has been explained. It has been concluded that dispersivity ascertained from strength tests is more reliable.
文摘Eight water bottles from Ebrie lagoon with pollution potency were studied using nuclear chemistry technique and Energy dispersive X-ray fluorescence. This pollution is characterized by pH and conductivity parameters, concentrations average in mg/L of metals such Fe (0.731), Mn (0.345), Cr (0.070), Cu (0.014) and concentrations of nutrients known to be pollutants and toxic for living or-ganisms. These heavy metals are dangerous to the lives, the local inhabitants and also a threat to aquatic life since this water is essential for the economical town, Abidjan. According to the Manganese concentration average (0.345 mg) values that higher than WHO (0.05 mg) value, the main likely source of pollu-tants is anthropogenic, industrial and agricultural. This study also shows the use of materials and lubricants near the lagoon that pollute this water.
基金Project supported by the National Natural Science Foundation of China(Grant No.61705194)。
文摘We present a high-dispersive multilayer mirror for pulse stretching in a femtosecond fiber laser amplification system.The designed mirror contains 54 layers with a total physical thickness of 7.3 μm, which can provide a positive group delay dispersion(GDD) of 600 fs2and a high reflectance over 99.9% from 1010 to 1070 nm. The samples were prepared by dual ion beam sputtering. The measured transmittance matches well with the theoretical result. The GDD characteristics of samples were tested by home-made white light interferometer. The measured GDD is higher than the design results,an average GDD of +722 fs2from 1010 nm to 1070 nm. The mirrors were employed in a Yb-doped large-mode-area photonic crystal fiber amplification system. An input pulse compressed by the gratings with autocorrelation function of83 fs is obtained with a stretched FWHM of 1.29 ps after 28 bounces between the dispersive mirrors. The results show that the multilayer dispersive mirror could be an effective and promising technique for pulse stretching in femtosecond amplification systems.
基金Supported by the National Natural Science Foundation of China(61102022)the Fundamental Research Foundation of Beijing Institute of Technology of China(20120542014)
文摘The electromagnetic properties of wire medium are studied by analyzing its transmission coefficient,and a homogeneous uniaxial effective permittivity tensor with one spatially dispersive component is obtained.In order to evaluate the validity of the equivalent model for scattering problems,the bistatic and monostatic radar cross sections(RCS)of a block of wire medium are investigated with the finitedifference time-domain(FDTD)method.The difference of RCS from the physical wire medium and the corresponding equivalent model has been compared and analyzed under various parameters of wire medium,which clearly demonstrates the accuracy of the equivalent model of wire medium.
