Effective removal of adhesive and fine dusts from flue gas is very difficult. A new method of electrostatic precipitation of the corona discharges with spraying water(CDSW) was introduced. A new electrode configuratio...Effective removal of adhesive and fine dusts from flue gas is very difficult. A new method of electrostatic precipitation of the corona discharges with spraying water(CDSW) was introduced. A new electrode configuration and the circulation spraying of water were employed in the method. The efficient electrostatic precipitation for adhesive and fine dusts can be accomplished without any drain water during a long operating period. The fundamental structure, discharge characteristics, mechanism of spraying and precipitation principle of the electrostatic precipitation using CDSW were described and analyzed. The V I characteristics, spraying state, supplying water quantity, influence of temperature and clean of the electrodes were researched in series experiments. The treating effects of circulating spraying using the corona plasma at the same time of electrostatic precipitation were investigated. The fundamental theories and experimental data were proposed, in order to effectively remove the adhesive dusts from flue gas using CDSW in practice.展开更多
Large amounts of solid wastes and flue gases are generated in iron and steel production process,probably leading to serious environmental pollution without duly handle.An innovative and green process of simultaneous r...Large amounts of solid wastes and flue gases are generated in iron and steel production process,probably leading to serious environmental pollution without duly handle.An innovative and green process of simultaneous reduction of zinc-bearing dusts and activation of low-rank coal was developed and its mechanism was clarified in this paper.Under the optimal conditions,the reduced zinc-bearing dusts containing low harmful elements(0.02%Zn,0.015%K and 0.03%Na)could be made as high-quality burden for blast furnace while the low-rank coal was transferred into K,Na-embedded activated carbon,which can be used as effective adsorbent for purification of SO_(2) and NO-containing flue gases.The solid wastes were successfully utilized to treat the flue gases through the process.The synergetic activation and reduction mechanism in the process was revealed.The coupling effect between reduction reactions of metal oxides in the dusts and activation reaction of carbon in the coal promoted the simultaneous reduction and activation process.In the meanwhile,part of the potassium and sodium from the zinc-bearing dusts could be adsorbed by the activated carbon and played a catalytic role in the activation process.展开更多
By detecting the influence of six main ingredients of PM2.5 mineral dusts on the A549 cell morphology, proliferation inhibition rate, micronuclei and DNA damage, to explore the genotoxicity of PM2.5 mineral dusts. (1)...By detecting the influence of six main ingredients of PM2.5 mineral dusts on the A549 cell morphology, proliferation inhibition rate, micronuclei and DNA damage, to explore the genotoxicity of PM2.5 mineral dusts. (1) After exposure to six kinds of dusts of 200 μg/mL concentration for 24 hours, the morphology of A549 cells were observed using Wright-Giemsa staining. (2) After exposure to different concentrations of mineral dusts for 24 hours, the proliferation inhibition rate of A549 cells was detected by MTT assay. (3) Cells were exposed to PM2.5 mineral dusts at a concentration of 200 μg/mL for 24 h. After Wright-Giemsa staining, the rates of micronucleus cells were counted under oil microscope. (4) Observe Comet phenomenon by SCGE electrophoresis, the degree of DNA damage was observed by OTM. (1) Compared to the control group, membrane destruction, nuclear pyknosis and mineral surface adhesion were mainly seen in the Sericite group and Albite group. In the Quartz group and Montmorillonite group, enlarged cell gaps, loosely arranged cells, absorption of a large number of minerals on the cell surface, and cell pyknosis were observed. (2) The proliferation inhibition rate of the six kinds of dusts to A549 cells were (from large to small): KWC-M>Nano-SiO2>KWC-S>KWC-Q>KWC-A>KWC-C.The dust concentration was positively related to the inhibition of cell proliferation rate. (3) With the dusts concentration increased, the incidence of micronuclei gradually increased. The rate was positively correlated to exposure concentration. (4) The six mineral dusts can damage DNA of the A549 cells by dose-response relationship.The higher concentration of the mineral dusts, the more obvious of the DNA damagenation. There’s statistically significant compared with the control group. The six main ingredients of the PM2.5 mineral dusts can change A549 cell morphology from varying degrees, improve proliferation inhibition rate of the cells, increase the number of micronuclei cells, damage DNA.Then we come to the conclusion that PM2.5 mineral dusts can change the genotoxicity of the cells.展开更多
In vivo cytotoxicity including cellular metabolic activity, lysozyme content and total protein content in rat bronchoalveolar lavage, capacity of interleukin-1 released from rat pulmonary cells and fibrogenic effects ...In vivo cytotoxicity including cellular metabolic activity, lysozyme content and total protein content in rat bronchoalveolar lavage, capacity of interleukin-1 released from rat pulmonary cells and fibrogenic effects evaluated from rat lung dry weight, collagen content of the whole lung and pathological grading induced by mineral dust were assayed. The results showed that: (1) The relationship among in vivo cytotoxicity, interleukin-1 release,fibrogenic effects on the lung induced by mineral dusts correlated well with the free SiO2content in mineral dusts in most (but not all) cases; (2) The biological harmful effects of mixed dusts were not simply the additive effect of single dust. In the group of WO3-SiO2mixture, the fibrogenicity was mainly due to SiO2, tungsten trioxide (WO3) showed neither fibrogenic effect, nor significant potentiality to enhance SiO2 fibrogenicity, while in the group of SnO2-SiO2, SnO2 was suppressive to the effect of SiO2, although the contents of SiO2 in the two mixed dusts were similar展开更多
The paper analyzed the groups naked and the transformed of fibrous brucite, wollastonite, chrysotile asbestos, sepiolite, palygorskite, clinoptilolite, crocidolite and diatomaceous earth mineral dusts by using IR unde...The paper analyzed the groups naked and the transformed of fibrous brucite, wollastonite, chrysotile asbestos, sepiolite, palygorskite, clinoptilolite, crocidolite and diatomaceous earth mineral dusts by using IR under acid and alkali etched, strong mechanical and polarized molecular interaction. The results show that the active site focuses on ends in stick dusts and on defects or hole edges in pipe dusts. The inside active sites of dusts play the main role in small molecular substance. The shape of dusts affects their distributions and densities of active sites. The strong mechanical and weak chemical force make the active site feature of minerals change, the powder process brings about more naked surface groups and more combined types. The dust activity relates to the type, contribution, and naked level of surface groups. The studied dust surface groups are mainly as follows: OH?, Mg(OH)?, Si-O-Si, Ca-O-Si, -Mg-OH2,-Al(Si)-OH, -Mg(Ca)-OH2, Ca-O,-Si???OH, Mg(Fe)-OH. Due to the difference of surface composition and structure, the minerals have a large disparity on activity and character of surface groups. The one side surface group of chrysotile layer is the same as fibrous brucite and stripped layer with more naked group. The fibrous sepiolite and palygorskite surface OH? similar to crocidolite is naked with their surface structural defects and cleavage. The more development of mineral defects, the higher of OH? (H2O+) content, the main H2O+ of clinoptilolite is partly transformed into H+, NH 4 + or OH?. The acid etched process may change OH? concentration, distribution and increase the defects and porosity of mineral fiber surface. The alkali etched has no effect on Si-O, Si-OH etc. and destroyed Al-O, Al-OH? acid site of sepiolite, palygorskite and clinoptilolite. Some surface groups of remnant differ from original dusts. The surface process of small polarized molecular or middle moleular’s branch may produce ionation and new coordinate bond, and change the active properties and level of original dusts, such as the porous minerals producing展开更多
Fourteen samples of settled dust from two factories processing rice and wheat straw near Shanghai.China, were examined by dilution plating for total bacteria, gram-negative bacteria, thermophilic actinomycetes, and fu...Fourteen samples of settled dust from two factories processing rice and wheat straw near Shanghai.China, were examined by dilution plating for total bacteria, gram-negative bacteria, thermophilic actinomycetes, and fungi.They were also examined for atlatoxin endotoxin, and potential to stimulate production of human interleukin 1β (IL-1β) and to consume complement.The concentrations of total microorganisms were consistently greater than 10~7 CFU/g and ranged from 10~7 to 10~9 CFU/g.In general, the level of microbial contamination was greater in the hay dust samples than in the rice dust samples, with bacteria being the most numerous microorganisms observed followed by molds, thermophilic actinomycetes, and yeasts.The predominant fungi were species of Aspergillus, Cladosporium, Penicillium.Trichosporon, and Cryplococcus.No significant levels of aflatoxin were observed and the isolates of A.flavus examined lack significant aflatoxigenic potential.The levels of microorganisms in these samples, the types of organisms found, and the inflammatory mediators such as endotoxin suggest that workers exposed to these dusts may be at risk for respiratory illness. 1990 Academic Press.Inc.展开更多
Malignant transformation of hamsterembryo cells was induced in vitro by rareearth iron mineral dusts(MP),naturalthorium(Th02) and MP plus Th02.Dusts of MP,MP plus Th02 or Th02 were added into themedium with the final ...Malignant transformation of hamsterembryo cells was induced in vitro by rareearth iron mineral dusts(MP),naturalthorium(Th02) and MP plus Th02.Dusts of MP,MP plus Th02 or Th02 were added into themedium with the final concentration of 17.0,展开更多
This paper mainly investigated the antimony recovery from antimony-bearing dusts through reduction roasting process after the dust firstly oxidation roasted.CO–CO2 mixture gas was used as reducing agent,and the antim...This paper mainly investigated the antimony recovery from antimony-bearing dusts through reduction roasting process after the dust firstly oxidation roasted.CO–CO2 mixture gas was used as reducing agent,and the antimony-containing phase was reduced into Sb4O6,volatilized into smoke,and finally recovered through the cooling cylinder.The antimony recovery rate increased from 66.00 wt%to 73.81 wt%in temperature range of 650 to 800°C,and decreased with temperature increased further to 900°C due to the reduction of Sb4O6 to the nonvolatile Sb.Similarly,the CO partial pressure also played a double role in this test.Under optimized conditions of roasting temperature of 800°C,CO partial pressure of 7.5 vol%and roasting time of 120 min,98.40 wt%of arsenic removal rate and 80.40 wt%antimony recovery rate could be obtained.In addition,the“As2O3”product could be used for preparing ferric arsenate which realized the harmless treatment of it.展开更多
In order to compare the chemical compositions and physical properities of dusts on silicate bacteria S35, the chemical compositions of six kinds of mineral dusts have been analyzed and the changes of pH value, glucose...In order to compare the chemical compositions and physical properities of dusts on silicate bacteria S35, the chemical compositions of six kinds of mineral dusts have been analyzed and the changes of pH value, glucose （GLU）, electrolyte and Mn, Si, Fe before and after the dusts reacted with silicate bacteria S35 have been measured. The SEM analysis has been used to study the bacterial form and interface action status in the course of reaction between dusts and bacteria. The results show that these mineral dusts have different effects on experiment bacteria. Therefore, it is concluded that the effect of mineral dusts on silicate bacteria has correlation with the chemical compositions and physical properities of dusts.展开更多
This study investigated the volatilization kinetics of lead in pellets made of Zn-Pb-bearing dusts mixed with coal powder,in a nitrogen atmosphere and in the temperature range between 1 100 ℃ - 1 300℃ ,and showed th...This study investigated the volatilization kinetics of lead in pellets made of Zn-Pb-bearing dusts mixed with coal powder,in a nitrogen atmosphere and in the temperature range between 1 100 ℃ - 1 300℃ ,and showed that the reduction temperature has a significant effect on the volatilization rate of lead and that neither the particle size of the coal powder nor the extra carbon content has any effect on the volatilization rate. The obtained activation energy for the volatilization of lead is 88.74 kJ/mol. The volatilization rate of lead is controlled by both the lead evaporation reaction and the diffusion of gaseous lead through the gas boundary layer covering the surface of the reduced liquid lead.展开更多
Physical-chemical characteristics of the band sawing dusts regarding to recovery of pure silicon from them were investigated.The experimental results show 50vol%-60vol% amorphous phases exist in the dusts,which is mos...Physical-chemical characteristics of the band sawing dusts regarding to recovery of pure silicon from them were investigated.The experimental results show 50vol%-60vol% amorphous phases exist in the dusts,which is mostly amorphous silica.The as-received saw dusts are found to form hard agglomerates of larger than 50 microns in diameter.The iron-based inclusions collected by magnets are found to match well with the band saw material in XRD patterns.Weight loss in heating was observed by thermal gravity tests,up to 900 ℃,presumably due to reaction of the amorphous silica with carbon contaminant in the dusts.The saw dusts were variously treated to examine their physical-chemical responses,and the results were also presented.展开更多
A study was carried out on the volatilization kinetics of Zn in the pellets made of Zn-bearing dusts mixed with coal powder in a nitrogen atmosphere and within the temperature range between 1 100℃and 1 300℃. The stu...A study was carried out on the volatilization kinetics of Zn in the pellets made of Zn-bearing dusts mixed with coal powder in a nitrogen atmosphere and within the temperature range between 1 100℃and 1 300℃. The study shows that the reduction temperature has a significant effect on the volatilization rate of zinc and that either the coal particle size or the excess carbon content has no effect on the volatilization rate. The obtained activation energy for the volatilization of zinc is 79.42 kJ/mol. The volatilization rate of zinc is controlled by the reaction between the zinc oxides and CO.展开更多
This work describes the experimental results of pyrometallurgical removing of arsenic from the dust collected in the electrostatic copper precipitators within the gas cleaning system of a Copper Flash Smelting Furnace...This work describes the experimental results of pyrometallurgical removing of arsenic from the dust collected in the electrostatic copper precipitators within the gas cleaning system of a Copper Flash Smelting Furnace. The generation of dust in the copper smelting worldwide ranges from 2 - 15 wt% per ton of a copper concentrate. In Chile, copper smelters produce approximately 110 kt/y of dust with a concentration of arsenic between 1 and 15 wt%. The dust is a complex of metals oxides and sulfurs with copper concentrations greater than 10 wt% and relatively high silver concentrations. Since its high arsenic concentration, it is difficult to recover valuable metals through hydrometallurgical processes or by direct recirculation of the dust in a smelting furnace. Thus, the development of pyrometallurgical processes aimed at reducing the concentration of arsenic in the dust (<0.5 wt%) is the main objective of this study, giving particular attention to the production of a suitable material to be recirculated in operations of copper smelting. The work provides a detailed characterization of the dust including the Quantitative Evaluation of Minerals by Scanning Electron Microscopy (QEMSCAN), Scanning Electron Microscope-Energy Dispersive X-ray Analysis (SEM/EDS), X-Ray Diffraction (XRD), the elemental chemical analysis using Atomic Adsorption (AAS), and X-Ray Fluorescence (X-RF). By considering that arsenic volatilization requires a process of sulfidation-decomposition-oxidation, this work seeks to explore the roasting of mixtures of copper concentrate/dust, sulfur/dust, and pyrrhotite/dust. By the elemental chemical analysis of the mixture after and before the roasting process, the degree of arsenic volatilization was determined. The results indicated the effects of parameters such as roasting temperature, gas flow, gas composition, and the ratio of mixtures (concentrate/dust, sulfur/dust, or pyrrhotite/dust) on the volatilization of arsenic. According to the findings, the concentration of arsenic in the roasted Flash Smelting dust can be reduced to a relatively low level (<0.5 wt%), which allows its recirculation into an smelting process.展开更多
In order to study the damage mechanism of mineral dusts on the pulmonary alveolar macrophage （AM）, the changes in their death ratio, malandialdthyde （MDA） content and activities of lactate dehydrogenase （LDH） an...In order to study the damage mechanism of mineral dusts on the pulmonary alveolar macrophage （AM）, the changes in their death ratio, malandialdthyde （MDA） content and activities of lactate dehydrogenase （LDH） and superoxide dismutase （SOD） were measured, and the technique of cell culture in vitro was used to investigate the cytotoxicity of six mineral dusts （twelve crystal habits） from twelve mineral deposits. The results show that woUastonite and clinoptilolite have no AM cytotoxicity, while other fibrous and grainy mineral dusts damage pulmonary AM in various degrees. The cytotoxicity of fibrous mineral dusts was greater than that of the grainy ones, and the cytotoxicity of dusts was positively correlated with the active OH- content in dusts, but not necessarily so with its SiO2 content. The high pH values produced by dust was unfavorable for the survival of cells and the dusts with low bio-resistance were safe for cells. The content of variable valence elements in dusts might influence their cytotoxicity and the surface charge of dusts was not a stable factor for their toxicity. It is demonstrated that the shape of mineral dusts was one of the factors affecting cytotoxicity, and that the cytotoxicity of mineral dusts depends mainly on their properties.展开更多
This article describes the characteristics of natural dusts, artificial dusts and industrial dusts, such as mineral phases, chemical components, morphological observation and size. Quartz and calcite are the main phas...This article describes the characteristics of natural dusts, artificial dusts and industrial dusts, such as mineral phases, chemical components, morphological observation and size. Quartz and calcite are the main phases of natural dusts and industrial dusts with high SiO2, CaO and low K2O, Na2O on the chemical composition. Natural dusts are mainly irregular shaped and some particle aggregation made of small dusts on the surface of large dust. Industrial dusts are globular and blob-like, but artificial dusts are columnar and fibrous. The fine particles are mainly in the range of 0.3-5 μm,of which the dusts of less than 5 μm are over 99%.The dissolution and electrochemical action of dusts in glutamic acid liquor at the simulated human body temperature (37 ℃) in 32 hours were investigated. The changes of pH values and electric conductivity of those dusts were similar, increased slowly in first 8 hours, and then the pH values increased rapidly. The total amount of dissolved ions of K, Ca, Na, Mg was 35.4-429 mg/L, particularly Ca was maximal of 20-334 mg/L. The total amount of dissolved ions of Fe, Zn, Mn, Pb, Ba was 0.18-5.59 ppm and the Al, Si was 3.0-21.7 mg/L. Each element dissolved rapidly relatively in first 16 hours. The relative solubility order of dusts in glutamic acid are: wollastonite > serpentine > sepiolite, the cement plant industrial dusts > power plant industrial dusts, and natural dusts have similar solubility. The wollastonite and power plant industrial dusts have highest solubility, which have high content of CaO; this shows there are a poorer corrosion-resisting ability and lower bio-resistibility. Sepiolite and cement plant industrial dusts have lowest solubility, which have high content of SiO2; this shows there are a higher corrosion-resisting ability and stronger bio-resistibility.展开更多
Mechanical reclamation processes of spent moulding sands generate large amounts of postreclamation dusts mainly containing rubbed spent binding agents and quartz dusts. The amount of postreclamation dusts, depending i...Mechanical reclamation processes of spent moulding sands generate large amounts of postreclamation dusts mainly containing rubbed spent binding agents and quartz dusts. The amount of postreclamation dusts, depending in the reclamation system effi ciency and the reclaim dedusting system, can reach 5%-10% in relation to the total reclaimed spent moulding sand. The proper utilization of such material is a big problem facing foundries these days. This study presents the results of investigations of physicochemical properties of post- reclamation dusts. All tested dusts originated from various Polish cast steel plants applying the mechanical reclamation process of moulding sands with alkaline resins, obtained from different producers. Different dusts, delivered from foundries, were tested to determine their chemical composition, granular characterization, physicochemical and energetic properties. Presented results confi rmed assumptions that it is possible to utilize dusts generated during mechanical reclamation of used sands with organic resins as a source of energy.展开更多
Traditional wireless sensor networks(WSNs)are not suitable for rough terrains that are difficult or impossible to access by humans.Smart dust is a technology that works with the combination of many tiny sensors which ...Traditional wireless sensor networks(WSNs)are not suitable for rough terrains that are difficult or impossible to access by humans.Smart dust is a technology that works with the combination of many tiny sensors which is highly useful for obtaining remote sensing information from rough terrains.The tiny sensors are sprinkled in large numbers on rough terrains using airborne distribution through drones or aircraftwithout manually setting their locations.Although it is clear that a number of remote sensing applications can benefit from this technology,but the small size of smart dust fundamentally restricts the integration of advanced hardware on tiny sensors.This raises many challenges including how to estimate the location of events sensed by the smart dusts.Existing solutions on estimating the location of events sensed by the smart dusts are not suitable for monitoring rough terrains as these solutions depend on relay sensors and laser patterns which have their own limitations in terms of power constraint and uneven surfaces.The study proposes a novel machine learning based localization algorithm for estimating the location of events.The approach utilizes timestamps(time of arrival)of sensed events received at base stations by assembling them into a multidimensional vector and input to a machine learning classifier for estimating the location.Due to the unavailability of real smart dusts,we built a simulator for analysing the accuracy of the proposed approach formonitoring forest fire.The experiments on the simulator show reasonable accuracy of the approach.展开更多
Cement dust pollution is one of the sources of atmospheric pollution. The main impacts of the cement activity to the environment are the broadcasts of dusts and gases. The objective of this study is to determine the e...Cement dust pollution is one of the sources of atmospheric pollution. The main impacts of the cement activity to the environment are the broadcasts of dusts and gases. The objective of this study is to determine the effects of cement dust pollution on physico-chemical characteristics of the soil at the vicinity of the cement factory in Oujda-Taourirt corridor (Eastern Morocco) using Principal component analysis (PCA) and geographical information system (GIS). Forty one (41) surface soils (0 - 3 cm) were collected from the six rural townships surrounding the cement factory. The collected soil samples were analyzed for their chemical properties (CaO, Al2O3, Fe2O3, K2O, MgO, SO3 and SiO2) as well as their pH and Electric Conductivity. The results of the analysis showed that the dusts emitted by the cement plant are especially basic and contain a high free lime (43.03% CaO). The principal component analysis applied on the 41 superficial soil samples, allows deducting that the free lime and the sulfur oxide are the tracer elements of this form of pollution. Furthermore, the spatial projection of the factor scores of the principal component analysis using the geographical information system permits us to determine the spatial distribution of more polluted areas of soils as well as to estimate their impact at a zone of 2.5 km of beam around the factory.展开更多
The flame propagation processes of MgH_(2)dust clouds with four different particle sizes were recorded by a high-speed camera.The dynamic flame temperature distributions of MgH_(2)dust clouds were reconstructed by the...The flame propagation processes of MgH_(2)dust clouds with four different particle sizes were recorded by a high-speed camera.The dynamic flame temperature distributions of MgH_(2)dust clouds were reconstructed by the two-color pyrometer technique,and the chemical composition of solid combustion residues were analyzed.The experimental results showed that the average flame propagation velocities of 23μm,40μm,60μm and 103μm MgH_(2)dust clouds in the stable propagation stage were 3.7 m/s,2.8 m/s,2.1 m/s and 0.9 m/s,respectively.The dust clouds with smaller particle sizes had faster flame propagation velocity and stronger oscillation intensity,and their flame temperature distributions were more even and the temperature gradients were smaller.The flame structures of MgH_(2)dust clouds were significantly affected by the particle sinking velocity,and the combustion processes were accompanied by micro-explosion of particles.The falling velocities of 23μm and 40μm MgH_(2)particles were 2.24 cm/s and 6.71 cm/s,respectively.While the falling velocities of 60μm and 103μm MgH_(2)particles were as high as 15.07 cm/s and 44.42 cm/s,respectively,leading to a more rapid downward development and irregular shape of the flame.Furthermore,the dehydrogenation reaction had a significant effect on the combustion performance of MgH_(2)dust.The combustion of H_(2)enhanced the ignition and combustion characteristics of MgH_(2)dust,resulting in a much higher explosion power than the pure Mg dust.The micro-structure characteristics and combustion residues composition analysis of MgH_(2)dust indicated that the combustion control mechanism of MgH_(2)dust flame was mainly the heterogeneous reaction,which was affected by the dehydrogenation reaction.展开更多
文摘Effective removal of adhesive and fine dusts from flue gas is very difficult. A new method of electrostatic precipitation of the corona discharges with spraying water(CDSW) was introduced. A new electrode configuration and the circulation spraying of water were employed in the method. The efficient electrostatic precipitation for adhesive and fine dusts can be accomplished without any drain water during a long operating period. The fundamental structure, discharge characteristics, mechanism of spraying and precipitation principle of the electrostatic precipitation using CDSW were described and analyzed. The V I characteristics, spraying state, supplying water quantity, influence of temperature and clean of the electrodes were researched in series experiments. The treating effects of circulating spraying using the corona plasma at the same time of electrostatic precipitation were investigated. The fundamental theories and experimental data were proposed, in order to effectively remove the adhesive dusts from flue gas using CDSW in practice.
基金the National Natural Science Foundation of China (No. 51574281), which supplied us with the facilities and funds needed to completed the experiments
文摘Large amounts of solid wastes and flue gases are generated in iron and steel production process,probably leading to serious environmental pollution without duly handle.An innovative and green process of simultaneous reduction of zinc-bearing dusts and activation of low-rank coal was developed and its mechanism was clarified in this paper.Under the optimal conditions,the reduced zinc-bearing dusts containing low harmful elements(0.02%Zn,0.015%K and 0.03%Na)could be made as high-quality burden for blast furnace while the low-rank coal was transferred into K,Na-embedded activated carbon,which can be used as effective adsorbent for purification of SO_(2) and NO-containing flue gases.The solid wastes were successfully utilized to treat the flue gases through the process.The synergetic activation and reduction mechanism in the process was revealed.The coupling effect between reduction reactions of metal oxides in the dusts and activation reaction of carbon in the coal promoted the simultaneous reduction and activation process.In the meanwhile,part of the potassium and sodium from the zinc-bearing dusts could be adsorbed by the activated carbon and played a catalytic role in the activation process.
基金Project supported by the State Key Program of National Natural Science of China(No.41130746)
文摘By detecting the influence of six main ingredients of PM2.5 mineral dusts on the A549 cell morphology, proliferation inhibition rate, micronuclei and DNA damage, to explore the genotoxicity of PM2.5 mineral dusts. (1) After exposure to six kinds of dusts of 200 μg/mL concentration for 24 hours, the morphology of A549 cells were observed using Wright-Giemsa staining. (2) After exposure to different concentrations of mineral dusts for 24 hours, the proliferation inhibition rate of A549 cells was detected by MTT assay. (3) Cells were exposed to PM2.5 mineral dusts at a concentration of 200 μg/mL for 24 h. After Wright-Giemsa staining, the rates of micronucleus cells were counted under oil microscope. (4) Observe Comet phenomenon by SCGE electrophoresis, the degree of DNA damage was observed by OTM. (1) Compared to the control group, membrane destruction, nuclear pyknosis and mineral surface adhesion were mainly seen in the Sericite group and Albite group. In the Quartz group and Montmorillonite group, enlarged cell gaps, loosely arranged cells, absorption of a large number of minerals on the cell surface, and cell pyknosis were observed. (2) The proliferation inhibition rate of the six kinds of dusts to A549 cells were (from large to small): KWC-M>Nano-SiO2>KWC-S>KWC-Q>KWC-A>KWC-C.The dust concentration was positively related to the inhibition of cell proliferation rate. (3) With the dusts concentration increased, the incidence of micronuclei gradually increased. The rate was positively correlated to exposure concentration. (4) The six mineral dusts can damage DNA of the A549 cells by dose-response relationship.The higher concentration of the mineral dusts, the more obvious of the DNA damagenation. There’s statistically significant compared with the control group. The six main ingredients of the PM2.5 mineral dusts can change A549 cell morphology from varying degrees, improve proliferation inhibition rate of the cells, increase the number of micronuclei cells, damage DNA.Then we come to the conclusion that PM2.5 mineral dusts can change the genotoxicity of the cells.
文摘In vivo cytotoxicity including cellular metabolic activity, lysozyme content and total protein content in rat bronchoalveolar lavage, capacity of interleukin-1 released from rat pulmonary cells and fibrogenic effects evaluated from rat lung dry weight, collagen content of the whole lung and pathological grading induced by mineral dust were assayed. The results showed that: (1) The relationship among in vivo cytotoxicity, interleukin-1 release,fibrogenic effects on the lung induced by mineral dusts correlated well with the free SiO2content in mineral dusts in most (but not all) cases; (2) The biological harmful effects of mixed dusts were not simply the additive effect of single dust. In the group of WO3-SiO2mixture, the fibrogenicity was mainly due to SiO2, tungsten trioxide (WO3) showed neither fibrogenic effect, nor significant potentiality to enhance SiO2 fibrogenicity, while in the group of SnO2-SiO2, SnO2 was suppressive to the effect of SiO2, although the contents of SiO2 in the two mixed dusts were similar
文摘The paper analyzed the groups naked and the transformed of fibrous brucite, wollastonite, chrysotile asbestos, sepiolite, palygorskite, clinoptilolite, crocidolite and diatomaceous earth mineral dusts by using IR under acid and alkali etched, strong mechanical and polarized molecular interaction. The results show that the active site focuses on ends in stick dusts and on defects or hole edges in pipe dusts. The inside active sites of dusts play the main role in small molecular substance. The shape of dusts affects their distributions and densities of active sites. The strong mechanical and weak chemical force make the active site feature of minerals change, the powder process brings about more naked surface groups and more combined types. The dust activity relates to the type, contribution, and naked level of surface groups. The studied dust surface groups are mainly as follows: OH?, Mg(OH)?, Si-O-Si, Ca-O-Si, -Mg-OH2,-Al(Si)-OH, -Mg(Ca)-OH2, Ca-O,-Si???OH, Mg(Fe)-OH. Due to the difference of surface composition and structure, the minerals have a large disparity on activity and character of surface groups. The one side surface group of chrysotile layer is the same as fibrous brucite and stripped layer with more naked group. The fibrous sepiolite and palygorskite surface OH? similar to crocidolite is naked with their surface structural defects and cleavage. The more development of mineral defects, the higher of OH? (H2O+) content, the main H2O+ of clinoptilolite is partly transformed into H+, NH 4 + or OH?. The acid etched process may change OH? concentration, distribution and increase the defects and porosity of mineral fiber surface. The alkali etched has no effect on Si-O, Si-OH etc. and destroyed Al-O, Al-OH? acid site of sepiolite, palygorskite and clinoptilolite. Some surface groups of remnant differ from original dusts. The surface process of small polarized molecular or middle moleular’s branch may produce ionation and new coordinate bond, and change the active properties and level of original dusts, such as the porous minerals producing
文摘Fourteen samples of settled dust from two factories processing rice and wheat straw near Shanghai.China, were examined by dilution plating for total bacteria, gram-negative bacteria, thermophilic actinomycetes, and fungi.They were also examined for atlatoxin endotoxin, and potential to stimulate production of human interleukin 1β (IL-1β) and to consume complement.The concentrations of total microorganisms were consistently greater than 10~7 CFU/g and ranged from 10~7 to 10~9 CFU/g.In general, the level of microbial contamination was greater in the hay dust samples than in the rice dust samples, with bacteria being the most numerous microorganisms observed followed by molds, thermophilic actinomycetes, and yeasts.The predominant fungi were species of Aspergillus, Cladosporium, Penicillium.Trichosporon, and Cryplococcus.No significant levels of aflatoxin were observed and the isolates of A.flavus examined lack significant aflatoxigenic potential.The levels of microorganisms in these samples, the types of organisms found, and the inflammatory mediators such as endotoxin suggest that workers exposed to these dusts may be at risk for respiratory illness. 1990 Academic Press.Inc.
文摘Malignant transformation of hamsterembryo cells was induced in vitro by rareearth iron mineral dusts(MP),naturalthorium(Th02) and MP plus Th02.Dusts of MP,MP plus Th02 or Th02 were added into themedium with the final concentration of 17.0,
基金Project(51564034)supported by the National Science Fund for Distinguished Regional Scholars,China
文摘This paper mainly investigated the antimony recovery from antimony-bearing dusts through reduction roasting process after the dust firstly oxidation roasted.CO–CO2 mixture gas was used as reducing agent,and the antimony-containing phase was reduced into Sb4O6,volatilized into smoke,and finally recovered through the cooling cylinder.The antimony recovery rate increased from 66.00 wt%to 73.81 wt%in temperature range of 650 to 800°C,and decreased with temperature increased further to 900°C due to the reduction of Sb4O6 to the nonvolatile Sb.Similarly,the CO partial pressure also played a double role in this test.Under optimized conditions of roasting temperature of 800°C,CO partial pressure of 7.5 vol%and roasting time of 120 min,98.40 wt%of arsenic removal rate and 80.40 wt%antimony recovery rate could be obtained.In addition,the“As2O3”product could be used for preparing ferric arsenate which realized the harmless treatment of it.
基金the National Natural Science Foundation of China （Grant 40072020）；the Teaching and Research Award Program for Outstanding Young Teachers in Higher Education Institutions of MOE, P.R.C., the foundation of Key Laboratory of Solid Waste Treatment and the Resource Recycle of the Ministry of Education（Southwest University of Science and Technology）and the Support Item of Preeminence Youth Fund,Sichuan.
文摘In order to compare the chemical compositions and physical properities of dusts on silicate bacteria S35, the chemical compositions of six kinds of mineral dusts have been analyzed and the changes of pH value, glucose （GLU）, electrolyte and Mn, Si, Fe before and after the dusts reacted with silicate bacteria S35 have been measured. The SEM analysis has been used to study the bacterial form and interface action status in the course of reaction between dusts and bacteria. The results show that these mineral dusts have different effects on experiment bacteria. Therefore, it is concluded that the effect of mineral dusts on silicate bacteria has correlation with the chemical compositions and physical properities of dusts.
基金financially supported by the "Joint Fund(project number U1260202)for Iron and Steel Research"built by the National Natural Science Foundation of China and Baosteel Group Corporation
文摘This study investigated the volatilization kinetics of lead in pellets made of Zn-Pb-bearing dusts mixed with coal powder,in a nitrogen atmosphere and in the temperature range between 1 100 ℃ - 1 300℃ ,and showed that the reduction temperature has a significant effect on the volatilization rate of lead and that neither the particle size of the coal powder nor the extra carbon content has any effect on the volatilization rate. The obtained activation energy for the volatilization of lead is 88.74 kJ/mol. The volatilization rate of lead is controlled by both the lead evaporation reaction and the diffusion of gaseous lead through the gas boundary layer covering the surface of the reduced liquid lead.
基金Funded by the LDK Solar(TC-NU-0004)the Science & Technology Project of Education Department of Jiangxi Province(No.GJJ10034)
文摘Physical-chemical characteristics of the band sawing dusts regarding to recovery of pure silicon from them were investigated.The experimental results show 50vol%-60vol% amorphous phases exist in the dusts,which is mostly amorphous silica.The as-received saw dusts are found to form hard agglomerates of larger than 50 microns in diameter.The iron-based inclusions collected by magnets are found to match well with the band saw material in XRD patterns.Weight loss in heating was observed by thermal gravity tests,up to 900 ℃,presumably due to reaction of the amorphous silica with carbon contaminant in the dusts.The saw dusts were variously treated to examine their physical-chemical responses,and the results were also presented.
文摘A study was carried out on the volatilization kinetics of Zn in the pellets made of Zn-bearing dusts mixed with coal powder in a nitrogen atmosphere and within the temperature range between 1 100℃and 1 300℃. The study shows that the reduction temperature has a significant effect on the volatilization rate of zinc and that either the coal particle size or the excess carbon content has no effect on the volatilization rate. The obtained activation energy for the volatilization of zinc is 79.42 kJ/mol. The volatilization rate of zinc is controlled by the reaction between the zinc oxides and CO.
文摘This work describes the experimental results of pyrometallurgical removing of arsenic from the dust collected in the electrostatic copper precipitators within the gas cleaning system of a Copper Flash Smelting Furnace. The generation of dust in the copper smelting worldwide ranges from 2 - 15 wt% per ton of a copper concentrate. In Chile, copper smelters produce approximately 110 kt/y of dust with a concentration of arsenic between 1 and 15 wt%. The dust is a complex of metals oxides and sulfurs with copper concentrations greater than 10 wt% and relatively high silver concentrations. Since its high arsenic concentration, it is difficult to recover valuable metals through hydrometallurgical processes or by direct recirculation of the dust in a smelting furnace. Thus, the development of pyrometallurgical processes aimed at reducing the concentration of arsenic in the dust (<0.5 wt%) is the main objective of this study, giving particular attention to the production of a suitable material to be recirculated in operations of copper smelting. The work provides a detailed characterization of the dust including the Quantitative Evaluation of Minerals by Scanning Electron Microscopy (QEMSCAN), Scanning Electron Microscope-Energy Dispersive X-ray Analysis (SEM/EDS), X-Ray Diffraction (XRD), the elemental chemical analysis using Atomic Adsorption (AAS), and X-Ray Fluorescence (X-RF). By considering that arsenic volatilization requires a process of sulfidation-decomposition-oxidation, this work seeks to explore the roasting of mixtures of copper concentrate/dust, sulfur/dust, and pyrrhotite/dust. By the elemental chemical analysis of the mixture after and before the roasting process, the degree of arsenic volatilization was determined. The results indicated the effects of parameters such as roasting temperature, gas flow, gas composition, and the ratio of mixtures (concentrate/dust, sulfur/dust, or pyrrhotite/dust) on the volatilization of arsenic. According to the findings, the concentration of arsenic in the roasted Flash Smelting dust can be reduced to a relatively low level (<0.5 wt%), which allows its recirculation into an smelting process.
基金supported by the National Natural Science Foundation of China(No:40072020)the Teaching and Research Award Program for 0utstanding Young Teachers in Higher Education Institutions of the Ministry of Educationthe Support Item of Preeminence Youth Fund,Sichuan.
文摘In order to study the damage mechanism of mineral dusts on the pulmonary alveolar macrophage （AM）, the changes in their death ratio, malandialdthyde （MDA） content and activities of lactate dehydrogenase （LDH） and superoxide dismutase （SOD） were measured, and the technique of cell culture in vitro was used to investigate the cytotoxicity of six mineral dusts （twelve crystal habits） from twelve mineral deposits. The results show that woUastonite and clinoptilolite have no AM cytotoxicity, while other fibrous and grainy mineral dusts damage pulmonary AM in various degrees. The cytotoxicity of fibrous mineral dusts was greater than that of the grainy ones, and the cytotoxicity of dusts was positively correlated with the active OH- content in dusts, but not necessarily so with its SiO2 content. The high pH values produced by dust was unfavorable for the survival of cells and the dusts with low bio-resistance were safe for cells. The content of variable valence elements in dusts might influence their cytotoxicity and the surface charge of dusts was not a stable factor for their toxicity. It is demonstrated that the shape of mineral dusts was one of the factors affecting cytotoxicity, and that the cytotoxicity of mineral dusts depends mainly on their properties.
基金Project supported by National Natural Science Fundation of China (No. 41130746).
文摘This article describes the characteristics of natural dusts, artificial dusts and industrial dusts, such as mineral phases, chemical components, morphological observation and size. Quartz and calcite are the main phases of natural dusts and industrial dusts with high SiO2, CaO and low K2O, Na2O on the chemical composition. Natural dusts are mainly irregular shaped and some particle aggregation made of small dusts on the surface of large dust. Industrial dusts are globular and blob-like, but artificial dusts are columnar and fibrous. The fine particles are mainly in the range of 0.3-5 μm,of which the dusts of less than 5 μm are over 99%.The dissolution and electrochemical action of dusts in glutamic acid liquor at the simulated human body temperature (37 ℃) in 32 hours were investigated. The changes of pH values and electric conductivity of those dusts were similar, increased slowly in first 8 hours, and then the pH values increased rapidly. The total amount of dissolved ions of K, Ca, Na, Mg was 35.4-429 mg/L, particularly Ca was maximal of 20-334 mg/L. The total amount of dissolved ions of Fe, Zn, Mn, Pb, Ba was 0.18-5.59 ppm and the Al, Si was 3.0-21.7 mg/L. Each element dissolved rapidly relatively in first 16 hours. The relative solubility order of dusts in glutamic acid are: wollastonite > serpentine > sepiolite, the cement plant industrial dusts > power plant industrial dusts, and natural dusts have similar solubility. The wollastonite and power plant industrial dusts have highest solubility, which have high content of CaO; this shows there are a poorer corrosion-resisting ability and lower bio-resistibility. Sepiolite and cement plant industrial dusts have lowest solubility, which have high content of SiO2; this shows there are a higher corrosion-resisting ability and stronger bio-resistibility.
基金financed by The Polish National Centre for Research and Development within the project INNOTECH-K1/IN1/57/156360/NCBR/12
文摘Mechanical reclamation processes of spent moulding sands generate large amounts of postreclamation dusts mainly containing rubbed spent binding agents and quartz dusts. The amount of postreclamation dusts, depending in the reclamation system effi ciency and the reclaim dedusting system, can reach 5%-10% in relation to the total reclaimed spent moulding sand. The proper utilization of such material is a big problem facing foundries these days. This study presents the results of investigations of physicochemical properties of post- reclamation dusts. All tested dusts originated from various Polish cast steel plants applying the mechanical reclamation process of moulding sands with alkaline resins, obtained from different producers. Different dusts, delivered from foundries, were tested to determine their chemical composition, granular characterization, physicochemical and energetic properties. Presented results confi rmed assumptions that it is possible to utilize dusts generated during mechanical reclamation of used sands with organic resins as a source of energy.
基金This research is supported by Universiti Brunei Darussalam(UBD)under FIC allied research grant program.
文摘Traditional wireless sensor networks(WSNs)are not suitable for rough terrains that are difficult or impossible to access by humans.Smart dust is a technology that works with the combination of many tiny sensors which is highly useful for obtaining remote sensing information from rough terrains.The tiny sensors are sprinkled in large numbers on rough terrains using airborne distribution through drones or aircraftwithout manually setting their locations.Although it is clear that a number of remote sensing applications can benefit from this technology,but the small size of smart dust fundamentally restricts the integration of advanced hardware on tiny sensors.This raises many challenges including how to estimate the location of events sensed by the smart dusts.Existing solutions on estimating the location of events sensed by the smart dusts are not suitable for monitoring rough terrains as these solutions depend on relay sensors and laser patterns which have their own limitations in terms of power constraint and uneven surfaces.The study proposes a novel machine learning based localization algorithm for estimating the location of events.The approach utilizes timestamps(time of arrival)of sensed events received at base stations by assembling them into a multidimensional vector and input to a machine learning classifier for estimating the location.Due to the unavailability of real smart dusts,we built a simulator for analysing the accuracy of the proposed approach formonitoring forest fire.The experiments on the simulator show reasonable accuracy of the approach.
文摘Cement dust pollution is one of the sources of atmospheric pollution. The main impacts of the cement activity to the environment are the broadcasts of dusts and gases. The objective of this study is to determine the effects of cement dust pollution on physico-chemical characteristics of the soil at the vicinity of the cement factory in Oujda-Taourirt corridor (Eastern Morocco) using Principal component analysis (PCA) and geographical information system (GIS). Forty one (41) surface soils (0 - 3 cm) were collected from the six rural townships surrounding the cement factory. The collected soil samples were analyzed for their chemical properties (CaO, Al2O3, Fe2O3, K2O, MgO, SO3 and SiO2) as well as their pH and Electric Conductivity. The results of the analysis showed that the dusts emitted by the cement plant are especially basic and contain a high free lime (43.03% CaO). The principal component analysis applied on the 41 superficial soil samples, allows deducting that the free lime and the sulfur oxide are the tracer elements of this form of pollution. Furthermore, the spatial projection of the factor scores of the principal component analysis using the geographical information system permits us to determine the spatial distribution of more polluted areas of soils as well as to estimate their impact at a zone of 2.5 km of beam around the factory.
基金supported by the National Natural Science Foundation of China(Grant Nos.12272001,11972046)the Outstanding Youth Project of Natural Science Foundation of Anhui Province(Grant No.2108085Y02)the Major Project of Anhui University Natural Science Foundation(Grant No.KJ2020ZD30)。
文摘The flame propagation processes of MgH_(2)dust clouds with four different particle sizes were recorded by a high-speed camera.The dynamic flame temperature distributions of MgH_(2)dust clouds were reconstructed by the two-color pyrometer technique,and the chemical composition of solid combustion residues were analyzed.The experimental results showed that the average flame propagation velocities of 23μm,40μm,60μm and 103μm MgH_(2)dust clouds in the stable propagation stage were 3.7 m/s,2.8 m/s,2.1 m/s and 0.9 m/s,respectively.The dust clouds with smaller particle sizes had faster flame propagation velocity and stronger oscillation intensity,and their flame temperature distributions were more even and the temperature gradients were smaller.The flame structures of MgH_(2)dust clouds were significantly affected by the particle sinking velocity,and the combustion processes were accompanied by micro-explosion of particles.The falling velocities of 23μm and 40μm MgH_(2)particles were 2.24 cm/s and 6.71 cm/s,respectively.While the falling velocities of 60μm and 103μm MgH_(2)particles were as high as 15.07 cm/s and 44.42 cm/s,respectively,leading to a more rapid downward development and irregular shape of the flame.Furthermore,the dehydrogenation reaction had a significant effect on the combustion performance of MgH_(2)dust.The combustion of H_(2)enhanced the ignition and combustion characteristics of MgH_(2)dust,resulting in a much higher explosion power than the pure Mg dust.The micro-structure characteristics and combustion residues composition analysis of MgH_(2)dust indicated that the combustion control mechanism of MgH_(2)dust flame was mainly the heterogeneous reaction,which was affected by the dehydrogenation reaction.
